#------------------------------------------------------------------------------
#$Date: 2017-03-04 03:55:40 +0200 (Sat, 04 Mar 2017) $
#$Revision: 192949 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/53/4345391.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4345391
loop_
_publ_author_name
'Ueno, Takahiro'
'Fujinami, Takeshi'
'Matsumoto, Naohide'
'Furusawa, Masaki'
'Irie, Ryo'
'Re, Nazzareno'
'Kanetomo, Takuya'
'Ishida, Takayuki'
'Sunatsuki, Yukinari'
_publ_section_title
;
 Circular and Chainlike Copper(II)-Lanthanide(III) Complexes Generated by
 Assembly Reactions of Racemic and Chiral Copper(II) Cross-Linking Ligand
 Complexes with Ln(III)(NO3)3·6H2O (Ln(III) = Gd(III), Tb(III),
 Dy(III)).
;
_journal_issue                   3
_journal_name_full               'Inorganic chemistry'
_journal_page_first              1679
_journal_page_last               1695
_journal_paper_doi               10.1021/acs.inorgchem.6b02668
_journal_volume                  56
_journal_year                    2017
_chemical_formula_moiety         'C32 H28 Cu Dy N5 O10'
_chemical_formula_sum            'C32 H28 Cu Dy N5 O10'
_chemical_formula_weight         868.65
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      14
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.0000
_cell_angle_beta                 106.6400(10)
_cell_angle_gamma                90.0000
_cell_formula_units_Z            4
_cell_length_a                   13.1609(4)
_cell_length_b                   16.3506(4)
_cell_length_c                   16.2739(5)
_cell_measurement_reflns_used    25597
_cell_measurement_temperature    150
_cell_measurement_theta_max      27.43
_cell_measurement_theta_min      3.05
_cell_volume                     3355.31(17)
_computing_cell_refinement       'RAPID AUTO'
_computing_data_collection       'RAPID AUTO (Rigaku, ????)'
_computing_data_reduction        'RAPID AUTO'
_computing_molecular_graphics    'CrystalStructure 4.0'
_computing_publication_material  'CrystalStructure 4.0 (Rigaku, 2010)'
_computing_structure_refinement  'CRYSTALS (Carruthers, et al., 1999)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      150
_diffrn_detector_area_resol_mean 10.000
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71075
_diffrn_reflns_av_R_equivalents  0.0361
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            30134
_diffrn_reflns_theta_full        27.43
_diffrn_reflns_theta_max         27.43
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.911
_exptl_absorpt_correction_T_max  0.392
_exptl_absorpt_correction_T_min  0.366
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'NUMABS (Rigaku, 1999)'
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.719
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1720.00
_exptl_crystal_size_max          0.486
_exptl_crystal_size_mid          0.326
_exptl_crystal_size_min          0.322
_refine_diff_density_max         1.600
_refine_diff_density_min         -1.040
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.248
_refine_ls_hydrogen_treatment    constr
_refine_ls_number_parameters     470
_refine_ls_number_reflns         6783
_refine_ls_R_factor_gt           0.0337
_refine_ls_shift/su_max          0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
    Chebychev polynomial with 3 parameters (Carruthers & Watkin, 1979)
    685.2730    931.8110    255.8640
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0389
_reflns_number_gt                6783
_reflns_number_total             7590
_reflns_threshold_expression     F²>2.0σ(F²)
_cod_data_source_file            ic6b02668_si_003.cif
_cod_data_source_block           Cu(RR)(SS)Dy(NO3)2-150K
_cod_original_cell_volume        3355.32(16)
_cod_database_code               4345391
loop_
_symmetry_equiv_pos_site_id
_symmetry_equiv_pos_as_xyz
1 +X,+Y,+Z
2 1/2-X,1/2+Y,1/2-Z
3 -X,-Y,-Z
4 1/2+X,1/2-Y,1/2+Z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Dy1 Dy 0.367220(10) 0.322420(10) 0.069520(10) 0.02565(3) Uani 1.0 4 d .
Cu1 Cu 0.33403(2) 0.52575(2) 0.05931(2) 0.02382(8) Uani 1.0 4 d .
O1 O 0.45049(14) 0.44843(11) 0.09903(12) 0.0276(5) Uani 1.0 4 d .
O2 O 0.25211(14) 0.42718(12) 0.02246(12) 0.0312(5) Uani 1.0 4 d .
O3 O 0.43196(13) 0.32490(12) -0.04232(11) 0.0292(5) Uani 1.0 4 d .
O4 O 0.20252(16) 0.28347(12) -0.04110(15) 0.0430(6) Uani 1.0 4 d .
O5 O 0.3962(2) 0.3222(2) 0.22176(15) 0.0661(9) Uani 1.0 4 d .
O6 O 0.2430(3) 0.2861(3) 0.1466(2) 0.0911(12) Uani 1.0 4 d .
O7 O 0.2884(3) 0.2734(3) 0.2862(3) 0.1087(15) Uani 1.0 4 d .
O8 O 0.52548(19) 0.23900(14) 0.13382(16) 0.0533(7) Uani 1.0 4 d .
O9 O 0.37988(18) 0.17637(15) 0.07762(18) 0.0567(7) Uani 1.0 4 d .
O10 O 0.5179(3) 0.10655(14) 0.14543(18) 0.0634(9) Uani 1.0 4 d .
N1 N 0.41975(16) 0.62211(14) 0.06812(14) 0.0256(6) Uani 1.0 4 d .
N2 N 0.21517(16) 0.59566(13) 0.00170(13) 0.0245(6) Uani 1.0 4 d .
N3 N 0.3072(3) 0.2928(3) 0.2210(3) 0.0612(11) Uani 1.0 4 d .
N4 N 0.4752(2) 0.17154(17) 0.12112(16) 0.0412(7) Uani 1.0 4 d .
N5 N 0.3029(2) 0.5241(2) 0.19836(17) 0.0487(9) Uani 1.0 4 d .
C1 C 0.55146(19) 0.47287(17) 0.13578(16) 0.0262(7) Uani 1.0 4 d .
C2 C 0.6230(3) 0.41735(18) 0.18646(19) 0.0346(8) Uani 1.0 4 d .
C3 C 0.7284(3) 0.4381(2) 0.2250(2) 0.0397(9) Uani 1.0 4 d .
C4 C 0.7644(2) 0.5152(2) 0.21306(19) 0.0370(8) Uani 1.0 4 d .
C5 C 0.6944(2) 0.57070(19) 0.16229(17) 0.0312(7) Uani 1.0 4 d .
C6 C 0.58756(19) 0.55173(16) 0.12301(16) 0.0253(7) Uani 1.0 4 d .
C7 C 0.5217(2) 0.61887(16) 0.07327(17) 0.0269(7) Uani 1.0 4 d .
C8 C 0.36089(19) 0.69512(15) 0.02727(17) 0.0264(7) Uani 1.0 4 d .
C9 C 0.4003(2) 0.77361(18) 0.0771(2) 0.0342(8) Uani 1.0 4 d .
C10 C 0.4239(3) 0.7742(2) 0.1647(2) 0.0491(10) Uani 1.0 4 d .
C11 C 0.4583(3) 0.8467(3) 0.2105(3) 0.0625(12) Uani 1.0 4 d .
C12 C 0.4668(3) 0.9165(3) 0.1684(3) 0.0618(12) Uani 1.0 4 d .
C13 C 0.4399(4) 0.9182(3) 0.0792(3) 0.0618(13) Uani 1.0 4 d .
C14 C 0.4067(3) 0.84517(19) 0.0325(3) 0.0499(11) Uani 1.0 4 d .
C15 C 0.24204(18) 0.68318(17) 0.02250(15) 0.0243(6) Uani 1.0 4 d .
C16 C 0.1738(2) 0.74481(17) -0.03855(17) 0.0293(7) Uani 1.0 4 d .
C17 C 0.1770(3) 0.7514(2) -0.12209(19) 0.0423(9) Uani 1.0 4 d .
C18 C 0.1216(3) 0.8117(3) -0.1763(3) 0.0514(10) Uani 1.0 4 d .
C19 C 0.0639(4) 0.8690(4) -0.1446(4) 0.0871(17) Uani 1.0 4 d .
C20 C 0.0612(5) 0.8641(4) -0.0598(4) 0.104(2) Uani 1.0 4 d .
C21 C 0.1140(3) 0.8015(3) -0.0075(3) 0.0656(13) Uani 1.0 4 d .
C22 C 0.1219(2) 0.57301(18) -0.04047(15) 0.0262(7) Uani 1.0 4 d .
C23 C 0.08941(19) 0.48922(17) -0.06235(16) 0.0265(7) Uani 1.0 4 d .
C24 C -0.0125(2) 0.4742(2) -0.12006(17) 0.0320(7) Uani 1.0 4 d .
C25 C -0.0431(3) 0.3976(2) -0.14952(19) 0.0386(8) Uani 1.0 4 d .
C26 C 0.0256(2) 0.3315(2) -0.12544(19) 0.0392(8) Uani 1.0 4 d .
C27 C 0.1247(3) 0.34299(16) -0.0683(2) 0.0331(7) Uani 1.0 4 d .
C28 C 0.15654(19) 0.42205(18) -0.03404(16) 0.0272(7) Uani 1.0 4 d .
C29 C 0.1994(3) 0.2098(2) -0.1011(3) 0.0585(11) Uani 1.0 4 d .
C30 C 0.1448(4) 0.1397(3) -0.0718(3) 0.0650(13) Uani 1.0 4 d .
C31 C 0.2984(3) 0.5150(3) 0.2658(3) 0.0489(10) Uani 1.0 4 d .
C32 C 0.2917(5) 0.5010(5) 0.3523(3) 0.131(3) Uani 1.0 4 d .
H1 H 0.5994 0.3655 0.1957 0.0395 Uiso 1.0 4 calc R
H2 H 0.7750 0.3999 0.2579 0.0446 Uiso 1.0 4 calc R
H3 H 0.8345 0.5301 0.2390 0.0423 Uiso 1.0 4 calc R
H4 H 0.7190 0.6223 0.1534 0.0369 Uiso 1.0 4 calc R
H5 H 0.3676 0.7006 -0.0309 0.0314 Uiso 1.0 4 calc R
H6 H 0.4181 0.7262 0.1936 0.0527 Uiso 1.0 4 calc R
H7 H 0.4737 0.8469 0.2700 0.0666 Uiso 1.0 4 calc R
H8 H 0.4928 0.9638 0.1991 0.0710 Uiso 1.0 4 calc R
H9 H 0.4439 0.9671 0.0512 0.0783 Uiso 1.0 4 calc R
H10 H 0.3887 0.8455 -0.0271 0.0638 Uiso 1.0 4 calc R
H11 H 0.2348 0.6940 0.0798 0.0284 Uiso 1.0 4 calc R
H12 H 0.2168 0.7143 -0.1433 0.0497 Uiso 1.0 4 calc R
H13 H 0.1229 0.8150 -0.2331 0.0580 Uiso 1.0 4 calc R
H14 H 0.0261 0.9095 -0.1809 0.1023 Uiso 1.0 4 calc R
H15 H 0.0243 0.9038 -0.0390 0.1287 Uiso 1.0 4 calc R
H16 H 0.1127 0.7985 0.0492 0.0815 Uiso 1.0 4 calc R
H17 H 0.0705 0.6133 -0.0587 0.0314 Uiso 1.0 4 calc R
H18 H -0.0590 0.5179 -0.1372 0.0379 Uiso 1.0 4 calc R
H19 H -0.1108 0.3894 -0.1863 0.0439 Uiso 1.0 4 calc R
H20 H 0.0056 0.2796 -0.1476 0.0443 Uiso 1.0 4 calc R
H21 H 0.2709 0.1926 -0.1005 0.0665 Uiso 1.0 4 calc R
H22 H 0.1589 0.2246 -0.1597 0.0664 Uiso 1.0 4 calc R
H23 H 0.0730 0.1564 -0.0725 0.0767 Uiso 1.0 4 calc R
H24 H 0.1406 0.0926 -0.1099 0.0766 Uiso 1.0 4 calc R
H25 H 0.1850 0.1245 -0.0133 0.0767 Uiso 1.0 4 calc R
H26 H 0.3634 0.4929 0.3907 0.1571 Uiso 1.0 4 calc R
H27 H 0.2586 0.5477 0.3722 0.1571 Uiso 1.0 4 calc R
H28 H 0.2493 0.4517 0.3523 0.1571 Uiso 1.0 4 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
H H 0.0000 0.0000
;
International Tables for Crystallography
(1992, Vol. C, Table 6.1.1.4)
;
N N 0.0061 0.0033
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
O O 0.0106 0.0060
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Dy Dy -0.1892 4.4098
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
Cu Cu 0.3201 1.2651
;
International Tables for Crystallography
(1992, Vol. C, Tables 4.2.6.8 and 6.1.1.4)
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Dy1 O2 68.25(7) yes . .
O1 Dy1 O3 83.34(8) yes . .
O1 Dy1 O4 130.07(7) yes . .
O1 Dy1 O5 82.01(10) yes . .
O1 Dy1 O6 117.59(11) yes . .
O1 Dy1 O8 96.45(7) yes . .
O1 Dy1 O9 148.59(7) yes . .
O1 Dy1 N3 101.79(9) yes . .
O1 Dy1 N4 122.80(7) yes . .
O2 Dy1 O3 94.90(7) yes . .
O2 Dy1 O4 65.63(7) yes . .
O2 Dy1 O5 104.07(10) yes . .
O2 Dy1 O6 82.78(11) yes . .
O2 Dy1 O8 164.69(7) yes . .
O2 Dy1 O9 143.16(7) yes . .
O2 Dy1 N3 95.56(9) yes . .
O2 Dy1 N4 168.75(8) yes . .
O3 Dy1 O4 82.53(8) yes . .
O3 Dy1 O5 149.63(8) yes . .
O3 Dy1 O6 155.63(9) yes . .
O3 Dy1 O8 83.21(8) yes . .
O3 Dy1 O9 91.51(9) yes . .
O3 Dy1 N3 169.46(9) yes . .
O3 Dy1 N4 88.92(8) yes . .
O4 Dy1 O5 126.83(9) yes . .
O4 Dy1 O6 74.39(9) yes . .
O4 Dy1 O8 128.78(7) yes . .
O4 Dy1 O9 79.39(7) yes . .
O4 Dy1 N3 100.63(9) yes . .
O4 Dy1 N4 104.53(7) yes . .
O5 Dy1 O6 52.45(10) yes . .
O5 Dy1 O8 72.21(10) yes . .
O5 Dy1 O9 87.35(11) yes . .
O5 Dy1 N3 26.25(10) yes . .
O5 Dy1 N4 77.05(10) yes . .
O6 Dy1 O8 105.12(11) yes . .
O6 Dy1 O9 76.82(13) yes . .
O6 Dy1 N3 26.34(9) yes . .
O6 Dy1 N4 89.37(12) yes . .
O8 Dy1 O9 52.14(8) yes . .
O8 Dy1 N3 87.04(10) yes . .
O8 Dy1 N4 26.42(8) yes . .
O9 Dy1 N3 79.30(11) yes . .
O9 Dy1 N4 25.84(8) yes . .
N3 Dy1 N4 80.55(10) yes . .
O1 Cu1 O2 83.00(8) yes . .
O1 Cu1 N1 96.78(9) yes . .
O1 Cu1 N2 170.92(9) yes . .
O2 Cu1 N1 165.87(10) yes . .
O2 Cu1 N2 92.30(8) yes . .
N1 Cu1 N2 85.87(9) yes . .
Dy1 O1 Cu1 103.15(8) yes . .
Dy1 O1 C1 134.48(16) yes . .
Cu1 O1 C1 122.34(17) yes . .
Dy1 O2 Cu1 105.37(8) yes . .
Dy1 O2 C28 126.36(18) yes . .
Cu1 O2 C28 126.76(18) yes . .
Dy1 O3 C7 132.22(18) yes . 3_665
Dy1 O4 C27 117.64(16) yes . .
Dy1 O4 C29 121.38(17) yes . .
C27 O4 C29 117.4(3) yes . .
Dy1 O5 N3 96.8(2) yes . .
Dy1 O6 N3 96.4(3) yes . .
Dy1 O8 N4 94.26(17) yes . .
Dy1 O9 N4 97.84(19) yes . .
Cu1 N1 C7 122.44(19) yes . .
Cu1 N1 C8 114.17(15) yes . .
C7 N1 C8 117.0(3) yes . .
Cu1 N2 C15 110.41(14) yes . .
Cu1 N2 C22 127.2(2) yes . .
C15 N2 C22 122.0(3) yes . .
Dy1 N3 O5 56.97(19) yes . .
Dy1 N3 O6 57.3(3) yes . .
Dy1 N3 O7 173.3(4) yes . .
O5 N3 O6 113.8(4) yes . .
O5 N3 O7 121.2(4) yes . .
O6 N3 O7 125.0(4) yes . .
Dy1 N4 O8 59.32(15) yes . .
Dy1 N4 O9 56.32(16) yes . .
Dy1 N4 O10 176.9(3) yes . .
O8 N4 O9 115.2(3) yes . .
O8 N4 O10 122.4(3) yes . .
O9 N4 O10 122.3(3) yes . .
O1 C1 C2 118.7(3) yes . .
O1 C1 C6 122.3(3) yes . .
C2 C1 C6 118.9(3) yes . .
C1 C2 C3 121.7(3) yes . .
C2 C3 C4 119.8(3) yes . .
C3 C4 C5 119.1(3) yes . .
C4 C5 C6 122.4(3) yes . .
C1 C6 C5 118.1(3) yes . .
C1 C6 C7 125.9(3) yes . .
C5 C6 C7 115.9(3) yes . .
O3 C7 N1 122.3(3) yes 3_665 .
O3 C7 C6 118.3(3) yes 3_665 .
N1 C7 C6 119.2(3) yes . .
N1 C8 C9 112.7(2) yes . .
N1 C8 C15 108.2(2) yes . .
C9 C8 C15 108.4(3) yes . .
C8 C9 C10 120.0(3) yes . .
C8 C9 C14 119.5(3) yes . .
C10 C9 C14 120.5(3) yes . .
C9 C10 C11 120.1(4) yes . .
C10 C11 C12 120.3(4) yes . .
C11 C12 C13 120.7(4) yes . .
C12 C13 C14 119.4(4) yes . .
C9 C14 C13 119.0(4) yes . .
N2 C15 C8 107.6(2) yes . .
N2 C15 C16 115.61(18) yes . .
C8 C15 C16 110.3(3) yes . .
C15 C16 C17 121.3(3) yes . .
C15 C16 C21 119.5(3) yes . .
C17 C16 C21 118.9(3) yes . .
C16 C17 C18 121.8(4) yes . .
C17 C18 C19 119.0(4) yes . .
C18 C19 C20 119.9(5) yes . .
C19 C20 C21 120.0(6) yes . .
C16 C21 C20 120.2(5) yes . .
N2 C22 C23 125.2(3) yes . .
C22 C23 C24 118.8(3) yes . .
C22 C23 C28 123.1(2) yes . .
C24 C23 C28 117.9(3) yes . .
C23 C24 C25 121.3(3) yes . .
C24 C25 C26 120.9(3) yes . .
C25 C26 C27 119.8(3) yes . .
O4 C27 C26 125.9(3) yes . .
O4 C27 C28 113.8(3) yes . .
C26 C27 C28 120.2(3) yes . .
O2 C28 C23 124.0(3) yes . .
O2 C28 C27 116.2(3) yes . .
C23 C28 C27 119.7(2) yes . .
O4 C29 C30 108.9(4) yes . .
N5 C31 C32 178.4(5) yes . .
C1 C2 H1 119.187 no . .
C3 C2 H1 119.088 no . .
C2 C3 H2 120.334 no . .
C4 C3 H2 119.826 no . .
C3 C4 H3 120.782 no . .
C5 C4 H3 120.130 no . .
C4 C5 H4 119.035 no . .
C6 C5 H4 118.592 no . .
N1 C8 H5 109.184 no . .
C9 C8 H5 108.951 no . .
C15 C8 H5 109.342 no . .
C9 C10 H6 119.575 no . .
C11 C10 H6 120.326 no . .
C10 C11 H7 119.829 no . .
C12 C11 H7 119.885 no . .
C11 C12 H8 119.994 no . .
C13 C12 H8 119.278 no . .
C12 C13 H9 119.596 no . .
C14 C13 H9 120.985 no . .
C9 C14 H10 120.858 no . .
C13 C14 H10 120.137 no . .
N2 C15 H11 107.937 no . .
C8 C15 H11 107.479 no . .
C16 C15 H11 107.629 no . .
C16 C17 H12 119.670 no . .
C18 C17 H12 118.531 no . .
C17 C18 H13 121.306 no . .
C19 C18 H13 119.647 no . .
C18 C19 H14 119.394 no . .
C20 C19 H14 120.659 no . .
C19 C20 H15 118.908 no . .
C21 C20 H15 121.038 no . .
C16 C21 H16 119.677 no . .
C20 C21 H16 120.028 no . .
N2 C22 H17 117.670 no . .
C23 C22 H17 117.137 no . .
C23 C24 H18 118.794 no . .
C25 C24 H18 119.861 no . .
C24 C25 H19 119.466 no . .
C26 C25 H19 119.674 no . .
C25 C26 H20 120.676 no . .
C27 C26 H20 119.555 no . .
O4 C29 H21 111.474 no . .
O4 C29 H22 109.415 no . .
C30 C29 H21 108.868 no . .
C30 C29 H22 108.704 no . .
H21 C29 H22 109.440 no . .
C29 C30 H23 109.275 no . .
C29 C30 H24 110.110 no . .
C29 C30 H25 109.110 no . .
H23 C30 H24 109.443 no . .
H23 C30 H25 109.440 no . .
H24 C30 H25 109.447 no . .
C31 C32 H26 108.955 no . .
C31 C32 H27 110.678 no . .
C31 C32 H28 108.867 no . .
H26 C32 H27 109.452 no . .
H26 C32 H28 109.431 no . .
H27 C32 H28 109.438 no . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
_geom_bond_site_symmetry_2
Dy1 O1 2.3185(18) yes .
Dy1 O2 2.2696(19) yes .
Dy1 O3 2.220(2) yes .
Dy1 O4 2.4719(19) yes .
Dy1 O5 2.396(3) yes .
Dy1 O6 2.403(4) yes .
Dy1 O8 2.459(3) yes .
Dy1 O9 2.395(3) yes .
Dy1 N3 2.838(4) yes .
Dy1 N4 2.851(3) yes .
Cu1 O1 1.9488(18) yes .
Cu1 O2 1.9363(19) yes .
Cu1 N1 1.919(3) yes .
Cu1 N2 1.947(2) yes .
O1 C1 1.352(3) yes .
O2 C28 1.331(3) yes .
O3 C7 1.283(4) yes 3_665
O4 C27 1.390(4) yes .
O4 C29 1.543(5) yes .
O5 N3 1.264(5) yes .
O6 N3 1.267(5) yes .
O7 N3 1.198(6) yes .
O8 N4 1.272(4) yes .
O9 N4 1.254(4) yes .
O10 N4 1.214(4) yes .
N1 C7 1.321(4) yes .
N1 C8 1.474(4) yes .
N2 C15 1.490(4) yes .
N2 C22 1.278(3) yes .
N5 C31 1.126(5) yes .
C1 C2 1.395(4) yes .
C1 C6 1.410(4) yes .
C2 C3 1.390(4) yes .
C3 C4 1.380(5) yes .
C4 C5 1.386(4) yes .
C5 C6 1.402(4) yes .
C6 C7 1.487(4) yes .
C8 C9 1.527(4) yes .
C8 C15 1.556(4) yes .
C9 C10 1.369(5) yes .
C9 C14 1.392(5) yes .
C10 C11 1.404(5) yes .
C11 C12 1.353(6) yes .
C12 C13 1.392(7) yes .
C13 C14 1.415(6) yes .
C15 C16 1.516(4) yes .
C16 C17 1.376(5) yes .
C16 C21 1.400(6) yes .
C17 C18 1.383(5) yes .
C18 C19 1.396(7) yes .
C19 C20 1.392(9) yes .
C20 C21 1.385(7) yes .
C22 C23 1.449(4) yes .
C23 C24 1.421(4) yes .
C23 C28 1.402(4) yes .
C24 C25 1.361(5) yes .
C25 C26 1.391(5) yes .
C26 C27 1.381(4) yes .
C27 C28 1.423(4) yes .
C29 C30 1.502(6) yes .
C31 C32 1.453(7) yes .
C2 H1 0.930 no .
C3 H2 0.930 no .
C4 H3 0.930 no .
C5 H4 0.930 no .
C8 H5 0.980 no .
C10 H6 0.930 no .
C11 H7 0.930 no .
C12 H8 0.930 no .
C13 H9 0.930 no .
C14 H10 0.930 no .
C15 H11 0.980 no .
C17 H12 0.930 no .
C18 H13 0.930 no .
C19 H14 0.930 no .
C20 H15 0.930 no .
C21 H16 0.930 no .
C22 H17 0.930 no .
C24 H18 0.930 no .
C25 H19 0.930 no .
C26 H20 0.930 no .
C29 H21 0.980 no .
C29 H22 0.980 no .
C30 H23 0.980 no .
C30 H24 0.980 no .
C30 H25 0.980 no .
C32 H26 0.980 no .
C32 H27 0.980 no .
C32 H28 0.980 no .
loop_
_geom_contact_atom_site_label_1
_geom_contact_atom_site_label_2
_geom_contact_distance
_geom_contact_publ_flag
_geom_contact_site_symmetry_2
Cu1 C6 3.226(3) no .
Cu1 C23 3.315(3) no .
O1 C6 3.503(4) no 3_665
O1 C7 3.007(4) no .
O1 C7 3.130(4) no 3_665
O2 C5 3.279(4) no 3_665
O2 C22 2.944(4) no .
O3 C5 2.762(4) no 3_665
O3 C8 2.687(3) no 3_665
O3 C9 2.916(4) no 3_665
O3 C10 3.514(5) no 3_665
O3 C14 3.474(4) no 3_665
O3 C29 3.485(4) no .
O4 C5 3.598(4) no 3_665
O5 C2 3.556(5) no .
O6 C27 3.522(5) no .
O8 C2 3.203(4) no .
O8 C8 3.538(4) no 3_665
O8 C14 3.377(6) no 3_665
O9 C29 3.232(5) no .
O9 C30 3.397(5) no .
O10 C14 3.412(6) no 3_665
N1 C1 3.013(4) no .
N1 C5 3.598(4) no .
N1 C10 2.934(4) no .
N2 C17 3.197(4) no .
N2 C28 2.955(4) no .
N4 C14 3.312(6) no 3_665
C1 C4 2.810(4) no .
C1 C7 3.588(4) no 3_665
C2 C5 2.745(5) no .
C3 C6 2.807(4) no .
C4 C23 3.525(5) no 3_665
C4 C28 3.516(5) no 3_665
C5 C27 3.476(5) no 3_665
C5 C28 3.250(5) no 3_665
C7 C9 3.002(4) no .
C7 C10 3.378(5) no .
C8 C17 3.040(4) no .
C8 C21 3.584(5) no .
C9 C12 2.773(5) no .
C9 C16 3.072(4) no .
C10 C13 2.772(6) no .
C10 C15 3.182(4) no .
C11 C14 2.779(6) no .
C14 C15 3.397(5) no .
C14 C16 3.376(5) no .
C16 C19 2.787(6) no .
C16 C22 2.889(4) no .
C17 C20 2.762(8) no .
C17 C22 3.370(5) no .
C18 C21 2.782(6) no .
C23 C26 2.814(5) no .
C24 C27 2.775(4) no .
C25 C28 2.787(4) no .
C26 C29 2.971(5) no .
C26 C30 3.504(5) no .
C27 C30 3.336(5) no .
Cu1 N5 2.412(3) no .
Cu1 C31 3.528(4) no .
O1 N5 3.117(4) no .
O2 N5 3.171(4) no .
O5 N5 3.505(5) no .
O5 C31 3.555(6) no .
O7 C10 3.120(6) no 2_545
O7 C11 3.476(6) no 2_545
O7 C15 3.570(5) no 2_545
O7 C21 3.491(6) no 2_545
O7 C25 3.535(6) no 4_555
O7 C26 3.490(5) no 4_555
O10 C4 3.459(4) no 2_645
O10 C12 3.223(5) no 1_545
O10 C13 3.327(5) no 1_545
N1 N5 3.360(4) no .
N2 N5 3.291(4) no .
N5 Cu1 2.412(3) no .
N5 O1 3.117(4) no .
N5 O2 3.171(4) no .
N5 O5 3.505(5) no .
N5 N1 3.360(4) no .
N5 N2 3.291(4) no .
N5 C25 3.523(4) no 3_565
C4 O10 3.459(4) no 2_655
C5 C18 3.599(5) no 4_565
C10 O7 3.120(6) no 2_555
C10 C18 3.403(5) no 4_565
C11 O7 3.476(6) no 2_555
C11 C18 3.529(5) no 4_565
C12 O10 3.223(5) no 1_565
C12 C32 3.598(8) no 2_555
C13 O10 3.327(5) no 1_565
C15 O7 3.570(5) no 2_555
C18 C5 3.599(5) no 4_464
C18 C10 3.403(5) no 4_464
C18 C11 3.529(5) no 4_464
C21 O7 3.491(6) no 2_555
C22 C24 3.413(5) no 3_565
C22 C25 3.564(5) no 3_565
C23 C23 3.538(4) no 3_565
C23 C24 3.452(5) no 3_565
C24 C22 3.413(5) no 3_565
C24 C23 3.452(5) no 3_565
C25 O7 3.535(6) no 4_454
C25 N5 3.523(4) no 3_565
C25 C22 3.564(5) no 3_565
C26 O7 3.490(5) no 4_454
C31 Cu1 3.528(4) no .
C31 O5 3.555(6) no .
C32 C12 3.598(8) no 2_545
Dy1 H1 3.2333 no .
Dy1 H4 3.5923 no 3_665
Dy1 H21 3.4285 no .
Cu1 H5 3.3011 no .
Cu1 H11 3.1038 no .
O1 H1 2.5272 no .
O2 H4 3.0998 no 3_665
O3 H4 2.4298 no 3_665
O3 H5 2.5981 no 3_665
O3 H21 2.9859 no .
O4 H4 2.8033 no 3_665
O4 H20 2.6746 no .
O4 H23 2.6424 no .
O4 H24 3.3365 no .
O4 H25 2.6600 no .
O5 H1 2.9119 no .
O8 H1 2.3825 no .
O8 H5 2.6661 no 3_665
O8 H10 2.7074 no 3_665
O8 H12 3.4374 no 3_665
O9 H10 3.3941 no 3_665
O9 H21 2.8544 no .
O9 H25 2.7039 no .
O10 H9 3.5869 no 3_665
O10 H10 2.6820 no 3_665
N1 H6 2.6623 no .
N1 H11 2.7583 no .
N2 H5 2.8040 no .
N2 H12 3.0596 no .
N4 H5 3.5412 no 3_665
N4 H10 2.6832 no 3_665
N5 H26 3.0439 no .
N5 H27 3.0721 no .
N5 H28 3.0319 no .
C1 H2 3.2682 no .
C1 H4 3.2486 no .
C2 H3 3.2414 no .
C2 H5 3.2127 no 3_665
C2 H12 3.2279 no 3_665
C3 H4 3.2197 no .
C3 H12 3.0075 no 3_665
C4 H1 3.2298 no .
C5 H2 3.2252 no .
C6 H1 3.2541 no .
C6 H3 3.2760 no .
C7 H4 2.5514 no .
C7 H5 2.6080 no .
C7 H6 3.2088 no .
C8 H6 2.6423 no .
C8 H10 2.6735 no .
C8 H12 2.8962 no .
C9 H7 3.2382 no .
C9 H9 3.2640 no .
C9 H11 2.5493 no .
C10 H5 3.2826 no .
C10 H8 3.2331 no .
C10 H10 3.2373 no .
C10 H11 2.8030 no .
C11 H9 3.2172 no .
C12 H6 3.2281 no .
C12 H10 3.2632 no .
C13 H7 3.2246 no .
C14 H5 2.5716 no .
C14 H6 3.2329 no .
C14 H8 3.2605 no .
C14 H11 3.5803 no .
C15 H6 3.1495 no .
C15 H10 3.5087 no .
C15 H12 2.6716 no .
C15 H16 2.6577 no .
C15 H17 2.5371 no .
C16 H5 2.6194 no .
C16 H10 3.2307 no .
C16 H13 3.2518 no .
C16 H15 3.2593 no .
C16 H17 2.5143 no .
C17 H2 3.4935 no 3_665
C17 H5 2.6560 no .
C17 H10 3.1703 no .
C17 H11 3.2897 no .
C17 H14 3.2326 no .
C17 H16 3.2297 no .
C17 H17 2.9927 no .
C18 H15 3.2465 no .
C19 H12 3.2292 no .
C19 H16 3.2448 no .
C20 H13 3.2506 no .
C21 H11 2.5181 no .
C21 H12 3.2332 no .
C21 H14 3.2470 no .
C21 H17 3.1952 no .
C22 H11 2.8784 no .
C22 H12 3.3007 no .
C22 H18 2.6103 no .
C23 H3 3.3187 no 3_665
C23 H19 3.2609 no .
C24 H3 3.4403 no 3_665
C24 H17 2.5967 no .
C24 H20 3.2313 no .
C26 H4 3.5983 no 3_665
C26 H18 3.2309 no .
C26 H22 2.6469 no .
C26 H23 3.0033 no .
C27 H4 2.8455 no 3_665
C27 H19 3.2344 no .
C27 H21 3.2552 no .
C27 H22 2.5584 no .
C27 H23 3.1220 no .
C28 H3 3.4604 no 3_665
C28 H4 2.9664 no 3_665
C28 H17 3.3115 no .
C28 H18 3.2548 no .
C28 H20 3.2687 no .
C29 H4 3.1519 no 3_665
C29 H20 2.6973 no .
C30 H20 2.9695 no .
H1 H2 2.3117 no .
H1 H5 3.0354 no 3_665
H1 H12 3.0765 no 3_665
H2 H3 2.3187 no .
H2 H12 2.6629 no 3_665
H3 H4 2.3041 no .
H4 H21 3.1591 no 3_665
H4 H22 2.9605 no 3_665
H5 H6 3.5455 no .
H5 H10 2.3842 no .
H5 H11 2.8491 no .
H5 H12 2.2935 no .
H6 H7 2.3367 no .
H6 H11 2.6398 no .
H7 H8 2.2824 no .
H8 H9 2.3066 no .
H9 H10 2.3606 no .
H10 H12 3.2941 no .
H11 H12 3.5854 no .
H11 H16 2.2998 no .
H11 H17 2.9494 no .
H12 H13 2.3106 no .
H12 H17 3.1378 no .
H13 H14 2.3129 no .
H14 H15 2.3165 no .
H15 H16 2.3295 no .
H16 H17 3.4630 no .
H17 H18 2.3939 no .
H18 H19 2.2813 no .
H19 H20 2.3260 no .
H20 H22 2.2695 no .
H20 H23 2.3911 no .
H20 H24 3.5009 no .
H21 H23 2.8323 no .
H21 H24 2.3428 no .
H21 H25 2.3353 no .
H22 H23 2.3353 no .
H22 H24 2.3411 no .
H22 H25 2.8295 no .
O3 H13 3.5208 no 2_544
O5 H20 2.7591 no 4_555
O5 H22 3.5271 no 4_555
O5 H23 3.5054 no 4_555
O7 H6 2.9336 no 2_545
O7 H7 3.5187 no 2_545
O7 H11 2.6300 no 2_545
O7 H16 2.6534 no 2_545
O7 H19 2.9496 no 4_555
O7 H20 2.8833 no 4_555
O7 H28 3.2007 no .
O8 H22 3.3693 no 4_555
O9 H9 3.5788 no 1_545
O9 H27 3.0441 no 2_545
O10 H3 2.6047 no 2_645
O10 H8 2.5467 no 1_545
O10 H9 2.7646 no 1_545
N3 H16 3.5836 no 2_545
N3 H19 3.3731 no 4_555
N3 H20 3.0974 no 4_555
N3 H28 3.5816 no .
N4 H9 3.5169 no 1_545
N5 H11 3.3542 no .
N5 H14 3.2190 no 4_565
N5 H18 3.1520 no 3_565
N5 H19 2.8549 no 3_565
C2 H22 3.3468 no 4_555
C2 H24 3.2594 no 4_555
C3 H8 3.5465 no 2_645
C3 H21 3.4691 no 4_555
C3 H22 3.5229 no 4_555
C3 H24 3.2528 no 4_555
C4 H8 3.2169 no 2_645
C4 H13 3.5889 no 4_565
C5 H13 2.8624 no 4_565
C6 H13 3.1343 no 4_565
C6 H14 3.5670 no 4_565
C7 H13 3.2357 no 4_565
C10 H13 3.0425 no 4_565
C11 H2 3.5086 no 2_655
C11 H13 3.3750 no 4_565
C11 H18 3.3798 no 4_565
C11 H28 3.1395 no 2_555
C12 H2 3.2743 no 2_655
C12 H3 3.2093 no 2_655
C12 H18 3.4489 no 4_565
C12 H27 3.5656 no 2_555
C12 H28 2.8263 no 2_555
C13 H9 3.4963 no 3_675
C13 H28 3.0549 no 2_555
C17 H7 3.1842 no 4_464
C18 H4 3.5389 no 4_464
C18 H6 2.9653 no 4_464
C18 H7 3.2104 no 4_464
C19 H6 3.1857 no 4_464
C20 H23 3.1694 no 3_565
C20 H26 3.3800 no 2_555
C20 H26 3.4196 no 4_464
C21 H20 3.5888 no 3_565
C21 H23 3.1725 no 3_565
C22 H7 3.4039 no 4_464
C22 H18 3.5525 no 3_565
C23 H18 3.3856 no 3_565
C24 H7 3.4063 no 4_464
C24 H8 3.1326 no 4_464
C24 H17 3.5162 no 3_565
C25 H8 3.4784 no 4_464
C25 H11 3.3961 no 3_565
C25 H17 3.5129 no 3_565
C26 H16 3.2649 no 3_565
C28 H18 3.5251 no 3_565
C29 H1 3.4202 no 4_454
C29 H2 3.2840 no 4_454
C30 H15 3.3183 no 3_565
C30 H27 3.4734 no 2_545
C31 H14 3.1253 no 4_565
C31 H18 3.2891 no 3_565
C31 H19 2.8959 no 3_565
C32 H14 3.5920 no 4_565
C32 H15 3.4385 no 4_565
C32 H19 3.5350 no 3_565
C32 H25 3.2522 no 2_555
H1 C29 3.4202 no 4_555
H1 H21 3.5660 no 4_555
H1 H22 2.6960 no 4_555
H1 H24 3.1290 no 4_555
H2 C11 3.5086 no 2_645
H2 C12 3.2743 no 2_645
H2 C29 3.2840 no 4_555
H2 H7 3.5705 no 2_645
H2 H8 3.1141 no 2_645
H2 H21 2.7702 no 4_555
H2 H22 3.0738 no 4_555
H2 H24 3.1546 no 4_555
H3 O10 2.6047 no 2_655
H3 C12 3.2093 no 2_645
H3 H8 2.4596 no 2_645
H4 C18 3.5389 no 4_565
H4 H13 2.7214 no 4_565
H6 O7 2.9336 no 2_555
H6 C18 2.9653 no 4_565
H6 C19 3.1857 no 4_565
H6 H13 2.7016 no 4_565
H6 H14 3.0741 no 4_565
H7 O7 3.5187 no 2_555
H7 C17 3.1842 no 4_565
H7 C18 3.2104 no 4_565
H7 C22 3.4039 no 4_565
H7 C24 3.4063 no 4_565
H7 H2 3.5705 no 2_655
H7 H12 3.2616 no 4_565
H7 H13 3.3052 no 4_565
H7 H17 2.7907 no 4_565
H7 H18 2.7802 no 4_565
H7 H28 3.4881 no 2_555
H8 O10 2.5467 no 1_565
H8 C3 3.5465 no 2_655
H8 C4 3.2169 no 2_655
H8 C24 3.1326 no 4_565
H8 C25 3.4784 no 4_565
H8 H2 3.1141 no 2_655
H8 H3 2.4596 no 2_655
H8 H18 2.9487 no 4_565
H8 H19 3.5432 no 4_565
H8 H27 3.4599 no 2_555
H8 H28 3.0598 no 2_555
H9 O9 3.5788 no 1_565
H9 O10 2.7646 no 1_565
H9 N4 3.5169 no 1_565
H9 C13 3.4963 no 3_675
H9 H9 2.7439 no 3_675
H9 H27 3.5057 no 2_555
H9 H28 3.3579 no 2_555
H11 O7 2.6300 no 2_555
H11 N5 3.3542 no .
H11 C25 3.3961 no 3_565
H11 H19 3.0247 no 3_565
H12 H7 3.2616 no 4_464
H13 O3 3.5208 no 2_554
H13 C4 3.5889 no 4_464
H13 C5 2.8624 no 4_464
H13 C6 3.1343 no 4_464
H13 C7 3.2357 no 4_464
H13 C10 3.0425 no 4_464
H13 C11 3.3750 no 4_464
H13 H4 2.7214 no 4_464
H13 H6 2.7016 no 4_464
H13 H7 3.3052 no 4_464
H14 N5 3.2190 no 4_464
H14 C6 3.5670 no 4_464
H14 C31 3.1253 no 4_464
H14 C32 3.5920 no 4_464
H14 H6 3.0741 no 4_464
H14 H24 3.4024 no 1_565
H14 H26 3.1494 no 4_464
H15 C30 3.3183 no 3_565
H15 C32 3.4385 no 4_464
H15 H15 3.5187 no 3_575
H15 H23 2.6902 no 3_565
H15 H25 3.1424 no 3_565
H15 H26 2.8438 no 2_555
H15 H26 2.6946 no 4_464
H15 H27 3.4721 no 4_464
H16 O7 2.6534 no 2_555
H16 N3 3.5836 no 2_555
H16 C26 3.2649 no 3_565
H16 H20 2.8354 no 3_565
H16 H23 2.6818 no 3_565
H16 H26 3.3138 no 2_555
H16 H28 3.2369 no 2_555
H17 C24 3.5162 no 3_565
H17 C25 3.5129 no 3_565
H17 H7 2.7907 no 4_464
H18 N5 3.1520 no 3_565
H18 C11 3.3798 no 4_464
H18 C12 3.4489 no 4_464
H18 C22 3.5525 no 3_565
H18 C23 3.3856 no 3_565
H18 C28 3.5251 no 3_565
H18 C31 3.2891 no 3_565
H18 H7 2.7802 no 4_464
H18 H8 2.9487 no 4_464
H19 O7 2.9496 no 4_454
H19 N3 3.3731 no 4_454
H19 N5 2.8549 no 3_565
H19 C31 2.8959 no 3_565
H19 C32 3.5350 no 3_565
H19 H8 3.5432 no 4_464
H19 H11 3.0247 no 3_565
H19 H27 3.2590 no 3_565
H20 O5 2.7591 no 4_454
H20 O7 2.8833 no 4_454
H20 N3 3.0974 no 4_454
H20 C21 3.5888 no 3_565
H20 H16 2.8354 no 3_565
H21 C3 3.4691 no 4_454
H21 H1 3.5660 no 4_454
H21 H2 2.7702 no 4_454
H22 O5 3.5271 no 4_454
H22 O8 3.3693 no 4_454
H22 C2 3.3468 no 4_454
H22 C3 3.5229 no 4_454
H22 H1 2.6960 no 4_454
H22 H2 3.0738 no 4_454
H23 O5 3.5054 no 4_454
H23 C20 3.1694 no 3_565
H23 C21 3.1725 no 3_565
H23 H15 2.6902 no 3_565
H23 H16 2.6818 no 3_565
H24 C2 3.2594 no 4_454
H24 C3 3.2528 no 4_454
H24 H1 3.1290 no 4_454
H24 H2 3.1546 no 4_454
H24 H14 3.4024 no 1_545
H25 C32 3.2522 no 2_545
H25 H15 3.1424 no 3_565
H25 H26 3.1217 no 2_545
H25 H27 2.5342 no 2_545
H26 C20 3.3800 no 2_545
H26 C20 3.4196 no 4_565
H26 H14 3.1494 no 4_565
H26 H15 2.8438 no 2_545
H26 H15 2.6946 no 4_565
H26 H16 3.3138 no 2_545
H26 H25 3.1217 no 2_555
H27 O9 3.0441 no 2_555
H27 C12 3.5656 no 2_545
H27 C30 3.4734 no 2_555
H27 H8 3.4599 no 2_545
H27 H9 3.5057 no 2_545
H27 H15 3.4721 no 4_565
H27 H19 3.2590 no 3_565
H27 H25 2.5342 no 2_555
H28 O7 3.2007 no .
H28 N3 3.5816 no .
H28 C11 3.1395 no 2_545
H28 C12 2.8263 no 2_545
H28 C13 3.0549 no 2_545
H28 H7 3.4881 no 2_545
H28 H8 3.0598 no 2_545
H28 H9 3.3579 no 2_545
H28 H16 3.2369 no 2_545
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_publ_flag
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
O1 Dy1 O2 Cu1 -3.55(8) no . .
O1 Dy1 O2 C28 163.14(19) no . .
O2 Dy1 O1 Cu1 3.49(8) no . .
O2 Dy1 O1 C1 -178.2(2) no . .
O1 Dy1 O3 C7 -8.76(14) no . 3_665
O3 Dy1 O1 Cu1 101.49(9) no . .
O3 Dy1 O1 C1 -80.19(18) no . .
O1 Dy1 O4 C27 -28.9(2) no . .
O1 Dy1 O4 C29 129.40(13) no . .
O4 Dy1 O1 Cu1 27.11(15) no . .
O4 Dy1 O1 C1 -154.56(16) no . .
O1 Dy1 O5 N3 138.69(18) no . .
O5 Dy1 O1 Cu1 -105.19(11) no . .
O5 Dy1 O1 C1 73.13(19) no . .
O1 Dy1 O6 N3 -57.6(3) no . .
O6 Dy1 O1 Cu1 -65.34(12) no . .
O6 Dy1 O1 C1 112.98(19) no . .
O1 Dy1 O8 N4 176.17(14) no . .
O8 Dy1 O1 Cu1 -176.15(10) no . .
O8 Dy1 O1 C1 2.2(2) no . .
O1 Dy1 O9 N4 4.7(3) no . .
O9 Dy1 O1 Cu1 -176.58(15) no . .
O9 Dy1 O1 C1 1.7(3) no . .
O1 Dy1 N3 O5 -41.90(17) no . .
O1 Dy1 N3 O6 130.14(15) no . .
N3 Dy1 O1 Cu1 -87.84(10) no . .
N3 Dy1 O1 C1 90.48(19) no . .
O1 Dy1 N4 O8 -4.53(17) no . .
O1 Dy1 N4 O9 -177.06(11) no . .
N4 Dy1 O1 Cu1 -174.12(8) no . .
N4 Dy1 O1 C1 4.2(3) no . .
O2 Dy1 O3 C7 58.64(14) no . 3_665
O3 Dy1 O2 Cu1 -84.37(10) no . .
O3 Dy1 O2 C28 82.32(17) no . .
O2 Dy1 O4 C27 -4.78(14) no . .
O2 Dy1 O4 C29 153.52(18) no . .
O4 Dy1 O2 Cu1 -163.88(13) no . .
O4 Dy1 O2 C28 2.81(15) no . .
O2 Dy1 O5 N3 73.59(18) no . .
O5 Dy1 O2 Cu1 71.72(12) no . .
O5 Dy1 O2 C28 -121.59(17) no . .
O2 Dy1 O6 N3 -118.4(3) no . .
O6 Dy1 O2 Cu1 120.03(12) no . .
O6 Dy1 O2 C28 -73.28(18) no . .
O2 Dy1 O9 N4 -175.37(11) no . .
O9 Dy1 O2 Cu1 176.51(13) no . .
O9 Dy1 O2 C28 -16.8(3) no . .
O2 Dy1 N3 O5 -110.80(15) no . .
O2 Dy1 N3 O6 61.24(16) no . .
N3 Dy1 O2 Cu1 96.95(11) no . .
N3 Dy1 O2 C28 -96.36(17) no . .
O3 Dy1 O4 C27 -103.63(16) no . .
O3 Dy1 O4 C29 54.66(15) no . .
O4 Dy1 O3 C7 123.23(15) no . 3_665
O3 Dy1 O5 N3 -159.41(12) no . .
O5 Dy1 O3 C7 -70.3(3) no . 3_665
O3 Dy1 O6 N3 155.65(13) no . .
O6 Dy1 O3 C7 142.0(3) no . 3_665
O3 Dy1 O8 N4 -101.36(14) no . .
O8 Dy1 O3 C7 -106.09(14) no . 3_665
O3 Dy1 O9 N4 84.40(16) no . .
O9 Dy1 O3 C7 -157.68(14) no . 3_665
O3 Dy1 N4 O8 76.83(13) no . .
O3 Dy1 N4 O9 -95.70(13) no . .
N4 Dy1 O3 C7 -131.96(14) no . 3_665
O4 Dy1 O5 N3 3.7(3) no . .
O5 Dy1 O4 C27 84.89(19) no . .
O5 Dy1 O4 C29 -116.82(17) no . .
O4 Dy1 O6 N3 174.9(3) no . .
O6 Dy1 O4 C27 84.27(19) no . .
O6 Dy1 O4 C29 -117.44(18) no . .
O4 Dy1 O8 N4 -26.6(2) no . .
O8 Dy1 O4 C27 -178.67(14) no . .
O8 Dy1 O4 C29 -20.4(2) no . .
O4 Dy1 O9 N4 166.51(18) no . .
O9 Dy1 O4 C27 163.41(18) no . .
O9 Dy1 O4 C29 -38.30(15) no . .
O4 Dy1 N3 O5 -176.99(14) no . .
O4 Dy1 N3 O6 -4.95(17) no . .
N3 Dy1 O4 C27 86.55(17) no . .
N3 Dy1 O4 C29 -115.16(16) no . .
O4 Dy1 N4 O8 158.83(12) no . .
O4 Dy1 N4 O9 -13.70(15) no . .
N4 Dy1 O4 C27 169.44(15) no . .
N4 Dy1 O4 C29 -32.27(17) no . .
O5 Dy1 O6 N3 -4.43(17) no . .
O6 Dy1 O5 N3 4.45(16) no . .
O5 Dy1 O8 N4 96.72(16) no . .
O8 Dy1 O5 N3 -121.86(19) no . .
O5 Dy1 O9 N4 -65.23(17) no . .
O9 Dy1 O5 N3 -70.94(18) no . .
O5 Dy1 N3 O5 -0.00(18) no . .
O5 Dy1 N3 O6 172.0(4) no . .
N3 Dy1 O5 N3 0.00(17) no . .
O5 Dy1 N4 O8 -76.01(13) no . .
O5 Dy1 N4 O9 111.46(15) no . .
N4 Dy1 O5 N3 -94.90(18) no . .
O6 Dy1 O8 N4 55.28(17) no . .
O8 Dy1 O6 N3 48.2(3) no . .
O6 Dy1 O9 N4 -117.22(18) no . .
O9 Dy1 O6 N3 92.5(2) no . .
O6 Dy1 N3 O5 -172.0(4) no . .
O6 Dy1 N3 O6 -0.0(3) no . .
N3 Dy1 O6 N3 -0.00(17) no . .
O6 Dy1 N4 O8 -127.48(14) no . .
O6 Dy1 N4 O9 59.99(15) no . .
N4 Dy1 O6 N3 69.7(2) no . .
O8 Dy1 O9 N4 4.20(13) no . .
O9 Dy1 O8 N4 -4.12(13) no . .
O8 Dy1 N3 O5 54.07(16) no . .
O8 Dy1 N3 O6 -133.89(16) no . .
N3 Dy1 O8 N4 74.62(15) no . .
O8 Dy1 N4 O8 -0.00(15) no . .
O8 Dy1 N4 O9 -172.5(3) no . .
N4 Dy1 O8 N4 -0.00(13) no . .
O9 Dy1 N3 O5 106.08(16) no . .
O9 Dy1 N3 O6 -81.88(16) no . .
N3 Dy1 O9 N4 -90.40(17) no . .
O9 Dy1 N4 O8 172.5(3) no . .
O9 Dy1 N4 O9 0.00(17) no . .
N4 Dy1 O9 N4 -0.00(14) no . .
N3 Dy1 N4 O8 -102.54(14) no . .
N3 Dy1 N4 O9 84.93(14) no . .
N4 Dy1 N3 O5 79.86(16) no . .
N4 Dy1 N3 O6 -108.11(16) no . .
O1 Cu1 O2 Dy1 3.95(9) no . .
O1 Cu1 O2 C28 -162.67(19) no . .
O2 Cu1 O1 Dy1 -3.83(9) no . .
O2 Cu1 O1 C1 177.59(17) no . .
O1 Cu1 N1 C7 17.71(18) no . .
O1 Cu1 N1 C8 168.76(15) no . .
N1 Cu1 O1 Dy1 -169.60(10) no . .
N1 Cu1 O1 C1 11.82(17) no . .
O2 Cu1 N2 C15 173.75(14) no . .
O2 Cu1 N2 C22 1.3(2) no . .
N2 Cu1 O2 Dy1 176.15(10) no . .
N2 Cu1 O2 C28 9.53(18) no . .
N1 Cu1 N2 C15 -20.28(14) no . .
N1 Cu1 N2 C22 167.3(2) no . .
N2 Cu1 N1 C7 -153.57(18) no . .
N2 Cu1 N1 C8 -2.52(15) no . .
Dy1 O1 C1 C2 -18.4(4) no . .
Dy1 O1 C1 C6 160.02(16) no . .
Cu1 O1 C1 C2 159.67(16) no . .
Cu1 O1 C1 C6 -21.9(4) no . .
Dy1 O2 C28 C23 -178.55(16) no . .
Dy1 O2 C28 C27 -0.5(4) no . .
Cu1 O2 C28 C23 -14.6(4) no . .
Cu1 O2 C28 C27 163.37(15) no . .
Dy1 O3 C7 N1 109.5(3) no 3_665 3_665
Dy1 O3 C7 C6 -75.8(3) no 3_665 3_665
Dy1 O4 C27 C26 -175.9(3) no . .
Dy1 O4 C27 C28 6.3(4) no . .
Dy1 O4 C29 C30 104.1(3) no . .
C27 O4 C29 C30 -97.6(3) no . .
C29 O4 C27 C26 24.9(5) no . .
C29 O4 C27 C28 -152.9(3) no . .
Dy1 O5 N3 Dy1 -0.0 no . .
Dy1 O5 N3 O6 -7.3(4) no . .
Dy1 O5 N3 O7 172.3(3) no . .
Dy1 O6 N3 Dy1 0.0 no . .
Dy1 O6 N3 O5 7.3(4) no . .
Dy1 O6 N3 O7 -172.4(3) no . .
Dy1 O8 N4 Dy1 0.0 no . .
Dy1 O8 N4 O9 6.9(3) no . .
Dy1 O8 N4 O10 -176.9(3) no . .
Dy1 O9 N4 Dy1 0.0 no . .
Dy1 O9 N4 O8 -7.1(3) no . .
Dy1 O9 N4 O10 176.7(3) no . .
Cu1 N1 C7 O3 148.38(19) no . 3_665
Cu1 N1 C7 C6 -37.0(3) no . .
Cu1 N1 C8 C9 143.28(16) no . .
Cu1 N1 C8 C15 23.4(3) no . .
C7 N1 C8 C9 -64.0(3) no . .
C7 N1 C8 C15 176.1(2) no . .
C8 N1 C7 O3 -1.9(4) no . 3_665
C8 N1 C7 C6 172.7(2) no . .
Cu1 N2 C15 C8 37.1(2) no . .
Cu1 N2 C15 C16 160.83(15) no . .
Cu1 N2 C22 C23 -7.7(4) no . .
C15 N2 C22 C23 -179.3(2) no . .
C22 N2 C15 C8 -150.1(3) no . .
C22 N2 C15 C16 -26.3(4) no . .
O1 C1 C2 C3 179.0(3) no . .
O1 C1 C6 C5 -178.5(3) no . .
O1 C1 C6 C7 3.5(5) no . .
C2 C1 C6 C5 -0.1(4) no . .
C2 C1 C6 C7 -178.1(3) no . .
C6 C1 C2 C3 0.5(5) no . .
C1 C2 C3 C4 -0.4(5) no . .
C2 C3 C4 C5 -0.2(5) no . .
C3 C4 C5 C6 0.6(5) no . .
C4 C5 C6 C1 -0.4(5) no . .
C4 C5 C6 C7 177.8(3) no . .
C1 C6 C7 O3 -156.3(3) no . 3_665
C1 C6 C7 N1 28.9(4) no . .
C5 C6 C7 O3 25.7(4) no . 3_665
C5 C6 C7 N1 -149.2(3) no . .
N1 C8 C9 C10 -42.4(4) no . .
N1 C8 C9 C14 141.0(3) no . .
N1 C8 C15 N2 -38.4(3) no . .
N1 C8 C15 C16 -165.33(18) no . .
C9 C8 C15 N2 -160.95(19) no . .
C9 C8 C15 C16 72.1(3) no . .
C15 C8 C9 C10 77.4(3) no . .
C15 C8 C9 C14 -99.3(3) no . .
C8 C9 C10 C11 -178.8(3) no . .
C8 C9 C14 C13 177.9(3) no . .
C10 C9 C14 C13 1.2(5) no . .
C14 C9 C10 C11 -2.1(5) no . .
C9 C10 C11 C12 0.9(6) no . .
C10 C11 C12 C13 1.3(6) no . .
C11 C12 C13 C14 -2.2(6) no . .
C12 C13 C14 C9 0.9(6) no . .
N2 C15 C16 C17 -67.0(3) no . .
N2 C15 C16 C21 119.2(3) no . .
C8 C15 C16 C17 55.3(3) no . .
C8 C15 C16 C21 -118.5(3) no . .
C15 C16 C17 C18 -174.7(3) no . .
C15 C16 C21 C20 172.4(3) no . .
C17 C16 C21 C20 -1.5(5) no . .
C21 C16 C17 C18 -0.9(5) no . .
C16 C17 C18 C19 2.2(5) no . .
C17 C18 C19 C20 -1.1(6) no . .
C18 C19 C20 C21 -1.3(7) no . .
C19 C20 C21 C16 2.6(7) no . .
N2 C22 C23 C24 -170.9(3) no . .
N2 C22 C23 C28 4.5(5) no . .
C22 C23 C24 C25 173.4(3) no . .
C22 C23 C28 O2 7.3(5) no . .
C22 C23 C28 C27 -170.7(3) no . .
C24 C23 C28 O2 -177.3(3) no . .
C24 C23 C28 C27 4.8(4) no . .
C28 C23 C24 C25 -2.2(5) no . .
C23 C24 C25 C26 -1.4(5) no . .
C24 C25 C26 C27 2.5(5) no . .
C25 C26 C27 O4 -177.5(3) no . .
C25 C26 C27 C28 0.1(5) no . .
O4 C27 C28 O2 -4.0(4) no . .
O4 C27 C28 C23 174.1(3) no . .
C26 C27 C28 O2 178.1(3) no . .
C26 C27 C28 C23 -3.8(5) no . .
