#------------------------------------------------------------------------------
#$Date: 2017-03-04 04:20:42 +0200 (Sat, 04 Mar 2017) $
#$Revision: 193006 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/54/4345488.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4345488
loop_
_publ_author_name
'Cesari, Cristiana'
'Ciabatti, Iacopo'
'Femoni, Cristina'
'Iapalucci, Maria Carmela'
'Mancini, Federica'
'Zacchini, Stefano'
_publ_section_title
;
 Heteroleptic Chini-Type Platinum Clusters: Synthesis and Characterization
 of Bis-Phospine Derivatives of [Pt3n(CO)6n](2-) (n = 2-4).
;
_journal_issue                   3
_journal_name_full               'Inorganic chemistry'
_journal_page_first              1655
_journal_page_last               1668
_journal_paper_doi               10.1021/acs.inorgchem.6b02750
_journal_volume                  56
_journal_year                    2017
_chemical_formula_sum            'C52 H64 N2 O10 P2 Pt6'
_chemical_formula_weight         2109.53
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 116.1000(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   25.2580(7)
_cell_length_b                   11.2170(3)
_cell_length_c                   21.8096(6)
_cell_measurement_reflns_used    7574
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      26.310
_cell_measurement_theta_min      2.451
_cell_volume                     5549.0(3)
_computing_cell_refinement       'APEX2 (Bruker AXS, 2006)'
_computing_data_collection       'APEX2 (Bruker AXS, 2006)'
_computing_data_reduction        'SAINT (Bruker AXS, 2004)'
_computing_molecular_graphics    'SCHAKAL99 (Keller, 1999)'
_computing_publication_material  'XCIF (Bruker AXS, 2001)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0953
_diffrn_reflns_av_unetI/netI     0.0523
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            38717
_diffrn_reflns_theta_full        25.02
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         1.80
_exptl_absorpt_coefficient_mu    15.183
_exptl_absorpt_correction_T_max  0.2860
_exptl_absorpt_correction_T_min  0.2091
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details
;
 Data were corrected for Lorentz polarization and absorption
 effects (empirical absorption corrections SADABS).
 R(int) = 0.1491 (selected reflections only, before parameter refinement)
 R(int) = 0.0782 (selected reflections only, after parameter refinement)
;
_exptl_crystal_colour            red-orange
_exptl_crystal_density_diffrn    2.525
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             3872
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.11
_refine_diff_density_max         4.217
_refine_diff_density_min         -1.900
_refine_diff_density_rms         0.348
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.119
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     325
_refine_ls_number_reflns         4906
_refine_ls_number_restraints     12
_refine_ls_restrained_S_all      1.121
_refine_ls_R_factor_all          0.0715
_refine_ls_R_factor_gt           0.0479
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0516P)²+238.4587P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1115
_refine_ls_wR_factor_ref         0.1261
_reflns_number_gt                3862
_reflns_number_total             4906
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic6b02750_si_002.cif
_cod_data_source_block           '[NEt4]2[Pt6(CO)10(dppe)]'
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/home/data/users/saulius/crontab/automatic-downloads/current/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 
;
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               4345488
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pt1 Pt 0.03941(2) 0.46484(5) 0.32655(2) 0.02207(17) Uani 1 1 d .
Pt2 Pt -0.05293(2) 0.32547(6) 0.30217(3) 0.02413(17) Uani 1 1 d .
Pt3 Pt 0.05207(2) 0.22944(5) 0.32941(2) 0.02318(17) Uani 1 1 d .
C1 C -0.0379(6) 0.5036(15) 0.3283(6) 0.025(3) Uani 1 1 d U
C2 C -0.1324(6) 0.3104(16) 0.2781(7) 0.032(4) Uani 1 1 d .
C3 C -0.0226(7) 0.1532(14) 0.3265(7) 0.028(3) Uani 1 1 d .
C4 C 0.1023(7) 0.1071(16) 0.3389(7) 0.031(4) Uani 1 1 d .
C5 C 0.1145(7) 0.3751(14) 0.3682(7) 0.028(3) Uani 1 1 d .
O1 O -0.0632(4) 0.5825(10) 0.3406(5) 0.032(2) Uani 1 1 d .
O2 O -0.1827(5) 0.3049(13) 0.2612(6) 0.053(3) Uani 1 1 d U
O3 O -0.0393(5) 0.0583(10) 0.3356(5) 0.034(3) Uani 1 1 d .
O4 O 0.1346(5) 0.0291(13) 0.3421(6) 0.052(3) Uani 1 1 d .
O5 O 0.1665(4) 0.3769(10) 0.3997(5) 0.031(3) Uani 1 1 d .
P1 P 0.07140(16) 0.6547(4) 0.33864(18) 0.0261(9) Uani 1 1 d .
C101 C 0.0334(6) 0.7554(14) 0.2651(6) 0.027(3) Uani 1 1 d .
H10A H 0.0476 0.8377 0.2796 0.032 Uiso 1 1 calc R
H10B H 0.0450 0.7330 0.2288 0.032 Uiso 1 1 calc R
C102 C 0.1493(5) 0.6791(13) 0.3557(6) 0.020(3) Uani 1 1 d .
C103 C 0.1851(7) 0.7579(15) 0.4026(7) 0.031(4) Uani 1 1 d .
H103 H 0.1710 0.8007 0.4300 0.037 Uiso 1 1 calc R
C104 C 0.2421(7) 0.7770(18) 0.4110(8) 0.042(5) Uani 1 1 d .
H104 H 0.2667 0.8332 0.4437 0.051 Uiso 1 1 calc R
C105 C 0.2629(7) 0.7146(18) 0.3720(8) 0.043(5) Uani 1 1 d .
H105 H 0.3022 0.7255 0.3782 0.052 Uiso 1 1 calc R
C106 C 0.2263(6) 0.6366(17) 0.3243(7) 0.038(4) Uani 1 1 d .
H106 H 0.2398 0.5964 0.2955 0.045 Uiso 1 1 calc R
C107 C 0.1688(6) 0.6142(16) 0.3166(7) 0.032(4) Uani 1 1 d .
H107 H 0.1444 0.5560 0.2852 0.038 Uiso 1 1 calc R
C108 C 0.0665(6) 0.7310(14) 0.4106(7) 0.026(3) Uani 1 1 d .
C109 C 0.0462(6) 0.8459(14) 0.4078(8) 0.027(3) Uani 1 1 d .
H109 H 0.0341 0.8905 0.3668 0.033 Uiso 1 1 calc R
C110 C 0.0433(8) 0.8984(17) 0.4655(8) 0.041(4) Uani 1 1 d .
H110 H 0.0290 0.9773 0.4635 0.049 Uiso 1 1 calc R
C111 C 0.0621(7) 0.8310(15) 0.5256(7) 0.031(4) Uani 1 1 d .
H111 H 0.0608 0.8643 0.5649 0.038 Uiso 1 1 calc R
C112 C 0.0826(6) 0.7158(15) 0.5274(7) 0.031(4) Uani 1 1 d .
H112 H 0.0953 0.6713 0.5686 0.037 Uiso 1 1 calc R
C113 C 0.0851(7) 0.6631(17) 0.4711(7) 0.035(4) Uani 1 1 d .
H113 H 0.0990 0.5838 0.4732 0.042 Uiso 1 1 calc R
N1 N 0.8430(5) 0.7661(12) 0.4092(6) 0.029(3) Uani 1 1 d .
C201 C 0.8859(7) 0.7213(19) 0.4777(8) 0.045(5) Uani 1 1 d .
H20A H 0.8634 0.6790 0.4985 0.054 Uiso 1 1 calc R
H20B H 0.9049 0.7910 0.5070 0.054 Uiso 1 1 calc R
C202 C 0.9338(7) 0.6391(18) 0.4796(9) 0.048(5) Uani 1 1 d .
H20C H 0.9590 0.6157 0.5269 0.071 Uiso 1 1 calc R
H20D H 0.9576 0.6803 0.4607 0.071 Uiso 1 1 calc R
H20E H 0.9160 0.5678 0.4523 0.071 Uiso 1 1 calc R
C203 C 0.8767(7) 0.8449(16) 0.3824(8) 0.039(4) Uani 1 1 d .
H20F H 0.9086 0.7971 0.3799 0.047 Uiso 1 1 calc R
H20G H 0.8954 0.9098 0.4157 0.047 Uiso 1 1 calc R
C204 C 0.8401(8) 0.9005(19) 0.3125(10) 0.053(5) Uani 1 1 d .
H20H H 0.8658 0.9480 0.2989 0.079 Uiso 1 1 calc R
H20I H 0.8097 0.9519 0.3147 0.079 Uiso 1 1 calc R
H20J H 0.8213 0.8372 0.2788 0.079 Uiso 1 1 calc R
C205 C 0.7943(7) 0.8320(16) 0.4163(8) 0.036(4) Uani 1 1 d .
H20K H 0.7728 0.7745 0.4316 0.044 Uiso 1 1 calc R
H20L H 0.7662 0.8606 0.3705 0.044 Uiso 1 1 calc R
C206 C 0.8121(7) 0.9376(19) 0.4648(9) 0.048(5) Uani 1 1 d .
H20M H 0.7769 0.9725 0.4657 0.072 Uiso 1 1 calc R
H20N H 0.8316 0.9975 0.4492 0.072 Uiso 1 1 calc R
H20O H 0.8392 0.9108 0.5108 0.072 Uiso 1 1 calc R
C207 C 0.8160(7) 0.6647(15) 0.3589(8) 0.037(4) Uani 1 1 d .
H20P H 0.7854 0.6984 0.3160 0.044 Uiso 1 1 calc R
H20Q H 0.8470 0.6298 0.3484 0.044 Uiso 1 1 calc R
C208 C 0.7887(8) 0.5668(18) 0.3816(9) 0.049(5) Uani 1 1 d .
H20R H 0.7725 0.5065 0.3455 0.073 Uiso 1 1 calc R
H20S H 0.7570 0.5994 0.3909 0.073 Uiso 1 1 calc R
H20T H 0.8187 0.5303 0.4232 0.073 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C5 Pt1 C1 147.2(6) . .
C5 Pt1 P1 101.8(5) . .
C1 Pt1 P1 95.4(5) . .
C5 Pt1 Pt3 53.3(5) . .
C1 Pt1 Pt3 108.7(5) . .
P1 Pt1 Pt3 154.66(10) . .
C5 Pt1 Pt2 111.8(5) . .
C1 Pt1 Pt2 50.2(5) . .
P1 Pt1 Pt2 144.81(10) . .
Pt3 Pt1 Pt2 60.43(2) . .
C5 Pt1 Pt1 122.4(4) . 2
C1 Pt1 Pt1 81.3(4) . 2
P1 Pt1 Pt1 98.99(9) . 2
Pt3 Pt1 Pt1 92.269(15) . 2
Pt2 Pt1 Pt1 71.81(2) . 2
C2 Pt2 C3 102.8(7) . .
C2 Pt2 C1 102.2(7) . .
C3 Pt2 C1 146.4(5) . .
C2 Pt2 Pt1 149.2(6) . .
C3 Pt2 Pt1 107.8(4) . .
C1 Pt2 Pt1 48.6(4) . .
C2 Pt2 Pt3 150.9(6) . .
C3 Pt2 Pt3 49.1(4) . .
C1 Pt2 Pt3 106.5(4) . .
Pt1 Pt2 Pt3 59.74(2) . .
C2 Pt2 Pt3 99.0(5) . 2
C3 Pt2 Pt3 76.0(4) . 2
C1 Pt2 Pt3 121.4(4) . 2
Pt1 Pt2 Pt3 91.54(2) . 2
Pt3 Pt2 Pt3 69.69(2) . 2
C4 Pt3 C3 106.0(7) . .
C4 Pt3 C5 100.0(6) . .
C3 Pt3 C5 146.0(6) . .
C4 Pt3 Pt1 145.4(5) . .
C3 Pt3 Pt1 108.3(5) . .
C5 Pt3 Pt1 47.1(4) . .
C4 Pt3 Pt2 154.6(5) . .
C3 Pt3 Pt2 49.6(5) . .
C5 Pt3 Pt2 105.2(4) . .
Pt1 Pt3 Pt2 59.84(2) . .
C4 Pt3 Pt2 94.6(4) . 2
C3 Pt3 Pt2 120.2(4) . 2
C5 Pt3 Pt2 78.3(4) . 2
Pt1 Pt3 Pt2 71.34(2) . 2
Pt2 Pt3 Pt2 93.73(2) . 2
O1 C1 Pt1 141.7(13) . .
O1 C1 Pt2 136.9(11) . .
Pt1 C1 Pt2 81.3(6) . .
O2 C2 Pt2 177.1(15) . .
O3 C3 Pt3 139.0(12) . .
O3 C3 Pt2 139.6(12) . .
Pt3 C3 Pt2 81.3(6) . .
O4 C4 Pt3 176.9(13) . .
O5 C5 Pt1 148.4(13) . .
O5 C5 Pt3 132.0(12) . .
Pt1 C5 Pt3 79.6(5) . .
C108 P1 C101 104.6(7) . .
C108 P1 C102 103.0(6) . .
C101 P1 C102 100.6(6) . .
C108 P1 Pt1 112.6(5) . .
C101 P1 Pt1 117.0(5) . .
C102 P1 Pt1 117.2(5) . .
C101 C101 P1 115.5(10) 2 .
C101 C101 H10A 108.4 2 .
P1 C101 H10A 108.4 . .
C101 C101 H10B 108.4 2 .
P1 C101 H10B 108.4 . .
H10A C101 H10B 107.5 . .
C103 C102 C107 121.0(13) . .
C103 C102 P1 123.1(12) . .
C107 C102 P1 115.9(11) . .
C102 C103 C104 120.8(16) . .
C102 C103 H103 119.6 . .
C104 C103 H103 119.6 . .
C105 C104 C103 119.8(17) . .
C105 C104 H104 120.1 . .
C103 C104 H104 120.1 . .
C106 C105 C104 119.0(16) . .
C106 C105 H105 120.5 . .
C104 C105 H105 120.5 . .
C105 C106 C107 121.5(16) . .
C105 C106 H106 119.2 . .
C107 C106 H106 119.2 . .
C102 C107 C106 117.7(15) . .
C102 C107 H107 121.1 . .
C106 C107 H107 121.1 . .
C109 C108 C113 120.7(14) . .
C109 C108 P1 124.0(11) . .
C113 C108 P1 115.2(12) . .
C108 C109 C110 120.7(14) . .
C108 C109 H109 119.7 . .
C110 C109 H109 119.7 . .
C111 C110 C109 118.5(16) . .
C111 C110 H110 120.8 . .
C109 C110 H110 120.8 . .
C112 C111 C110 119.9(14) . .
C112 C111 H111 120.0 . .
C110 C111 H111 120.0 . .
C111 C112 C113 122.1(14) . .
C111 C112 H112 119.0 . .
C113 C112 H112 119.0 . .
C112 C113 C108 118.1(16) . .
C112 C113 H113 121.0 . .
C108 C113 H113 121.0 . .
C201 N1 C205 109.2(12) . .
C201 N1 C203 107.5(12) . .
C205 N1 C203 112.3(13) . .
C201 N1 C207 111.6(14) . .
C205 N1 C207 108.3(11) . .
C203 N1 C207 108.0(11) . .
N1 C201 C202 116.9(13) . .
N1 C201 H20A 108.1 . .
C202 C201 H20A 108.1 . .
N1 C201 H20B 108.1 . .
C202 C201 H20B 108.1 . .
H20A C201 H20B 107.3 . .
C201 C202 H20C 109.5 . .
C201 C202 H20D 109.5 . .
H20C C202 H20D 109.5 . .
C201 C202 H20E 109.5 . .
H20C C202 H20E 109.5 . .
H20D C202 H20E 109.5 . .
N1 C203 C204 115.4(13) . .
N1 C203 H20F 108.4 . .
C204 C203 H20F 108.4 . .
N1 C203 H20G 108.4 . .
C204 C203 H20G 108.4 . .
H20F C203 H20G 107.5 . .
C203 C204 H20H 109.5 . .
C203 C204 H20I 109.5 . .
H20H C204 H20I 109.5 . .
C203 C204 H20J 109.5 . .
H20H C204 H20J 109.5 . .
H20I C204 H20J 109.5 . .
N1 C205 C206 116.8(13) . .
N1 C205 H20K 108.1 . .
C206 C205 H20K 108.1 . .
N1 C205 H20L 108.1 . .
C206 C205 H20L 108.1 . .
H20K C205 H20L 107.3 . .
C205 C206 H20M 109.5 . .
C205 C206 H20N 109.5 . .
H20M C206 H20N 109.5 . .
C205 C206 H20O 109.5 . .
H20M C206 H20O 109.5 . .
H20N C206 H20O 109.5 . .
C208 C207 N1 116.0(14) . .
C208 C207 H20P 108.3 . .
N1 C207 H20P 108.3 . .
C208 C207 H20Q 108.3 . .
N1 C207 H20Q 108.3 . .
H20P C207 H20Q 107.4 . .
C207 C208 H20R 109.5 . .
C207 C208 H20S 109.5 . .
H20R C208 H20S 109.5 . .
C207 C208 H20T 109.5 . .
H20R C208 H20T 109.5 . .
H20S C208 H20T 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 C5 1.980(16) .
Pt1 C1 2.017(13) .
Pt1 P1 2.251(4) .
Pt1 Pt3 2.6573(8) .
Pt1 Pt2 2.6600(8) .
Pt1 Pt1 3.0437(10) 2
Pt2 C2 1.847(15) .
Pt2 C3 2.060(16) .
Pt2 C1 2.067(17) .
Pt2 Pt3 2.6758(8) .
Pt2 Pt3 3.0741(7) 2
Pt3 C4 1.818(19) .
Pt3 C3 2.046(16) .
Pt3 C5 2.167(16) .
Pt3 Pt2 3.0741(7) 2
C1 O1 1.188(17) .
C2 O2 1.157(18) .
C3 O3 1.193(18) .
C4 O4 1.18(2) .
C5 O5 1.185(17) .
P1 C108 1.841(15) .
P1 C101 1.848(15) .
P1 C102 1.855(13) .
C101 C101 1.52(3) 2
C101 H10A 0.9900 .
C101 H10B 0.9900 .
C102 C103 1.35(2) .
C102 C107 1.37(2) .
C103 C104 1.38(2) .
C103 H103 0.9500 .
C104 C105 1.37(3) .
C104 H104 0.9500 .
C105 C106 1.36(3) .
C105 H105 0.9500 .
C106 C107 1.41(2) .
C106 H106 0.9500 .
C107 H107 0.9500 .
C108 C109 1.38(2) .
C108 C113 1.41(2) .
C109 C110 1.42(2) .
C109 H109 0.9500 .
C110 C111 1.40(2) .
C110 H110 0.9500 .
C111 C112 1.39(2) .
C111 H111 0.9500 .
C112 C113 1.39(2) .
C112 H112 0.9500 .
C113 H113 0.9500 .
N1 C201 1.495(19) .
N1 C205 1.501(19) .
N1 C203 1.510(19) .
N1 C207 1.52(2) .
C201 C202 1.51(3) .
C201 H20A 0.9900 .
C201 H20B 0.9900 .
C202 H20C 0.9800 .
C202 H20D 0.9800 .
C202 H20E 0.9800 .
C203 C204 1.53(2) .
C203 H20F 0.9900 .
C203 H20G 0.9900 .
C204 H20H 0.9800 .
C204 H20I 0.9800 .
C204 H20J 0.9800 .
C205 C206 1.52(2) .
C205 H20K 0.9900 .
C205 H20L 0.9900 .
C206 H20M 0.9800 .
C206 H20N 0.9800 .
C206 H20O 0.9800 .
C207 C208 1.49(2) .
C207 H20P 0.9900 .
C207 H20Q 0.9900 .
C208 H20R 0.9800 .
C208 H20S 0.9800 .
C208 H20T 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C5 Pt1 Pt2 C2 169.4(9) . .
C1 Pt1 Pt2 C2 21.6(10) . .
P1 Pt1 Pt2 C2 7.3(9) . .
Pt3 Pt1 Pt2 C2 -175.8(8) . .
Pt1 Pt1 Pt2 C2 -72.3(8) 2 .
C5 Pt1 Pt2 C3 -4.4(6) . .
C1 Pt1 Pt2 C3 -152.1(6) . .
P1 Pt1 Pt2 C3 -166.4(4) . .
Pt3 Pt1 Pt2 C3 10.5(4) . .
Pt1 Pt1 Pt2 C3 114.0(4) 2 .
C5 Pt1 Pt2 C1 147.7(6) . .
P1 Pt1 Pt2 C1 -14.3(5) . .
Pt3 Pt1 Pt2 C1 162.6(5) . .
Pt1 Pt1 Pt2 C1 -93.9(5) 2 .
C5 Pt1 Pt2 Pt3 -14.8(4) . .
C1 Pt1 Pt2 Pt3 -162.6(5) . .
P1 Pt1 Pt2 Pt3 -176.84(16) . .
Pt1 Pt1 Pt2 Pt3 103.56(2) 2 .
C5 Pt1 Pt2 Pt3 -80.1(4) . 2
C1 Pt1 Pt2 Pt3 132.1(5) . 2
P1 Pt1 Pt2 Pt3 117.85(16) . 2
Pt3 Pt1 Pt2 Pt3 -65.31(2) . 2
Pt1 Pt1 Pt2 Pt3 38.249(17) 2 2
C5 Pt1 Pt3 C4 -21.2(9) . .
C1 Pt1 Pt3 C4 -169.9(9) . .
P1 Pt1 Pt3 C4 -8.2(8) . .
Pt2 Pt1 Pt3 C4 176.0(8) . .
Pt1 Pt1 Pt3 C4 108.5(8) 2 .
C5 Pt1 Pt3 C3 152.2(6) . .
C1 Pt1 Pt3 C3 3.5(5) . .
P1 Pt1 Pt3 C3 165.2(5) . .
Pt2 Pt1 Pt3 C3 -10.6(4) . .
Pt1 Pt1 Pt3 C3 -78.1(4) 2 .
C1 Pt1 Pt3 C5 -148.7(6) . .
P1 Pt1 Pt3 C5 13.0(5) . .
Pt2 Pt1 Pt3 C5 -162.8(5) . .
Pt1 Pt1 Pt3 C5 129.7(5) 2 .
C5 Pt1 Pt3 Pt2 162.8(5) . .
C1 Pt1 Pt3 Pt2 14.1(4) . .
P1 Pt1 Pt3 Pt2 175.7(2) . .
Pt1 Pt1 Pt3 Pt2 -67.56(2) 2 .
C5 Pt1 Pt3 Pt2 -91.2(5) . 2
C1 Pt1 Pt3 Pt2 120.1(4) . 2
P1 Pt1 Pt3 Pt2 -78.3(2) . 2
Pt2 Pt1 Pt3 Pt2 105.997(19) . 2
Pt1 Pt1 Pt3 Pt2 38.44(2) 2 2
C2 Pt2 Pt3 C4 0.9(14) . .
C3 Pt2 Pt3 C4 18.5(12) . .
C1 Pt2 Pt3 C4 171.7(11) . .
Pt1 Pt2 Pt3 C4 -174.7(10) . .
Pt3 Pt2 Pt3 C4 -70.3(10) 2 .
C2 Pt2 Pt3 C3 -17.6(10) . .
C1 Pt2 Pt3 C3 153.2(6) . .
Pt1 Pt2 Pt3 C3 166.8(5) . .
Pt3 Pt2 Pt3 C3 -88.8(5) 2 .
C2 Pt2 Pt3 C5 -171.4(9) . .
C3 Pt2 Pt3 C5 -153.8(6) . .
C1 Pt2 Pt3 C5 -0.6(5) . .
Pt1 Pt2 Pt3 C5 13.0(4) . .
Pt3 Pt2 Pt3 C5 117.4(4) 2 .
C2 Pt2 Pt3 Pt1 175.6(9) . .
C3 Pt2 Pt3 Pt1 -166.8(5) . .
C1 Pt2 Pt3 Pt1 -13.6(4) . .
Pt3 Pt2 Pt3 Pt1 104.43(2) 2 .
C2 Pt2 Pt3 Pt2 109.7(9) . 2
C3 Pt2 Pt3 Pt2 127.3(5) . 2
C1 Pt2 Pt3 Pt2 -79.4(4) . 2
Pt1 Pt2 Pt3 Pt2 -65.88(2) . 2
Pt3 Pt2 Pt3 Pt2 38.55(3) 2 2
C5 Pt1 C1 O1 110.4(18) . .
P1 Pt1 C1 O1 -11.5(17) . .
Pt3 Pt1 C1 O1 160.7(15) . .
Pt2 Pt1 C1 O1 176.7(19) . .
Pt1 Pt1 C1 O1 -109.8(17) 2 .
C5 Pt1 C1 Pt2 -66.3(12) . .
P1 Pt1 C1 Pt2 171.8(3) . .
Pt3 Pt1 C1 Pt2 -16.0(4) . .
Pt1 Pt1 C1 Pt2 73.5(3) 2 .
C2 Pt2 C1 O1 14.1(16) . .
C3 Pt2 C1 O1 -123.3(15) . .
Pt1 Pt2 C1 O1 -177.0(17) . .
Pt3 Pt2 C1 O1 -161.3(14) . .
Pt3 Pt2 C1 O1 122.7(14) 2 .
C2 Pt2 C1 Pt1 -168.9(5) . .
C3 Pt2 C1 Pt1 53.7(11) . .
Pt3 Pt2 C1 Pt1 15.7(4) . .
Pt3 Pt2 C1 Pt1 -60.2(4) 2 .
C3 Pt2 C2 O2 -149(32) . .
C1 Pt2 C2 O2 53(33) . .
Pt1 Pt2 C2 O2 37(33) . .
Pt3 Pt2 C2 O2 -135(32) . .
Pt3 Pt2 C2 O2 -72(33) 2 .
C4 Pt3 C3 O3 9.3(18) . .
C5 Pt3 C3 O3 -129.1(16) . .
Pt1 Pt3 C3 O3 -166.8(15) . .
Pt2 Pt3 C3 O3 -178.8(19) . .
Pt2 Pt3 C3 O3 114.6(16) 2 .
C4 Pt3 C3 Pt2 -171.9(5) . .
C5 Pt3 C3 Pt2 49.7(11) . .
Pt1 Pt3 C3 Pt2 12.0(4) . .
Pt2 Pt3 C3 Pt2 -66.6(5) 2 .
C2 Pt2 C3 O3 -9.9(18) . .
C1 Pt2 C3 O3 127.5(15) . .
Pt1 Pt2 C3 O3 166.8(15) . .
Pt3 Pt2 C3 O3 178.8(19) . .
Pt3 Pt2 C3 O3 -106.1(17) 2 .
C2 Pt2 C3 Pt3 171.3(5) . .
C1 Pt2 C3 Pt3 -51.3(11) . .
Pt1 Pt2 C3 Pt3 -12.0(4) . .
Pt3 Pt2 C3 Pt3 75.1(3) 2 .
C3 Pt3 C4 O4 114(26) . .
C5 Pt3 C4 O4 -89(26) . .
Pt1 Pt3 C4 O4 -73(26) . .
Pt2 Pt3 C4 O4 99(26) . .
Pt2 Pt3 C4 O4 -10(26) 2 .
C1 Pt1 C5 O5 -112(2) . .
P1 Pt1 C5 O5 9(2) . .
Pt3 Pt1 C5 O5 -177(2) . .
Pt2 Pt1 C5 O5 -160.9(19) . .
Pt1 Pt1 C5 O5 117(2) 2 .
C1 Pt1 C5 Pt3 65.3(12) . .
P1 Pt1 C5 Pt3 -174.4(2) . .
Pt2 Pt1 C5 Pt3 16.1(4) . .
Pt1 Pt1 C5 Pt3 -65.6(5) 2 .
C4 Pt3 C5 O5 -14.1(15) . .
C3 Pt3 C5 O5 125.5(14) . .
Pt1 Pt3 C5 O5 177.9(16) . .
Pt2 Pt3 C5 O5 162.5(13) . .
Pt2 Pt3 C5 O5 -106.8(14) 2 .
C4 Pt3 C5 Pt1 168.0(5) . .
C3 Pt3 C5 Pt1 -52.4(11) . .
Pt2 Pt3 C5 Pt1 -15.4(4) . .
Pt2 Pt3 C5 Pt1 75.3(3) 2 .
C5 Pt1 P1 C108 -101.3(6) . .
C1 Pt1 P1 C108 50.7(6) . .
Pt3 Pt1 P1 C108 -111.9(5) . .
Pt2 Pt1 P1 C108 61.6(5) . .
Pt1 Pt1 P1 C108 132.7(5) 2 .
C5 Pt1 P1 C101 137.5(7) . .
C1 Pt1 P1 C101 -70.5(6) . .
Pt3 Pt1 P1 C101 126.9(5) . .
Pt2 Pt1 P1 C101 -59.5(6) . .
Pt1 Pt1 P1 C101 11.5(5) 2 .
C5 Pt1 P1 C102 17.8(6) . .
C1 Pt1 P1 C102 169.8(6) . .
Pt3 Pt1 P1 C102 7.2(6) . .
Pt2 Pt1 P1 C102 -179.2(4) . .
Pt1 Pt1 P1 C102 -108.1(5) 2 .
C108 P1 C101 C101 -75.6(10) . 2
C102 P1 C101 C101 177.9(10) . 2
Pt1 P1 C101 C101 49.7(11) . 2
C108 P1 C102 C103 -12.6(14) . .
C101 P1 C102 C103 95.2(13) . .
Pt1 P1 C102 C103 -136.8(11) . .
C108 P1 C102 C107 169.0(11) . .
C101 P1 C102 C107 -83.2(12) . .
Pt1 P1 C102 C107 44.8(12) . .
C107 C102 C103 C104 1(2) . .
P1 C102 C103 C104 -176.8(12) . .
C102 C103 C104 C105 -1(2) . .
C103 C104 C105 C106 2(2) . .
C104 C105 C106 C107 -3(3) . .
C103 C102 C107 C106 -3(2) . .
P1 C102 C107 C106 175.3(11) . .
C105 C106 C107 C102 4(2) . .
C101 P1 C108 C109 -8.7(13) . .
C102 P1 C108 C109 96.0(13) . .
Pt1 P1 C108 C109 -136.8(11) . .
C101 P1 C108 C113 171.2(11) . .
C102 P1 C108 C113 -84.0(12) . .
Pt1 P1 C108 C113 43.2(12) . .
C113 C108 C109 C110 0(2) . .
P1 C108 C109 C110 179.5(12) . .
C108 C109 C110 C111 1(2) . .
C109 C110 C111 C112 0(2) . .
C110 C111 C112 C113 0(2) . .
C111 C112 C113 C108 0(2) . .
C109 C108 C113 C112 0(2) . .
P1 C108 C113 C112 179.9(11) . .
C205 N1 C201 C202 172.2(15) . .
C203 N1 C201 C202 -66(2) . .
C207 N1 C201 C202 52.6(19) . .
C201 N1 C203 C204 -179.6(16) . .
C205 N1 C203 C204 -59.5(18) . .
C207 N1 C203 C204 59.9(19) . .
C201 N1 C205 C206 58(2) . .
C203 N1 C205 C206 -60.9(18) . .
C207 N1 C205 C206 179.9(14) . .
C201 N1 C207 C208 52.9(18) . .
C205 N1 C207 C208 -67.3(18) . .
C203 N1 C207 C208 170.9(15) . .
