#------------------------------------------------------------------------------
#$Date: 2017-03-04 04:20:42 +0200 (Sat, 04 Mar 2017) $
#$Revision: 193006 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/54/4345490.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4345490
loop_
_publ_author_name
'Cesari, Cristiana'
'Ciabatti, Iacopo'
'Femoni, Cristina'
'Iapalucci, Maria Carmela'
'Mancini, Federica'
'Zacchini, Stefano'
_publ_section_title
;
 Heteroleptic Chini-Type Platinum Clusters: Synthesis and Characterization
 of Bis-Phospine Derivatives of [Pt3n(CO)6n](2-) (n = 2-4).
;
_journal_issue                   3
_journal_name_full               'Inorganic chemistry'
_journal_page_first              1655
_journal_page_last               1668
_journal_paper_doi               10.1021/acs.inorgchem.6b02750
_journal_volume                  56
_journal_year                    2017
_chemical_formula_sum            'C94 H83 N3 O20 P4 Pt12'
_chemical_formula_weight         4039.59
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                95.293(2)
_cell_angle_beta                 104.089(2)
_cell_angle_gamma                112.579(2)
_cell_formula_units_Z            1
_cell_length_a                   13.4798(5)
_cell_length_b                   13.9719(6)
_cell_length_c                   14.6962(6)
_cell_measurement_reflns_used    9955
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      26.464
_cell_measurement_theta_min      2.193
_cell_volume                     2424.94(18)
_computing_cell_refinement       'APEX2 (Bruker AXS, 2006)'
_computing_data_collection       'APEX2 (Bruker AXS, 2006)'
_computing_data_reduction        'SAINT (Bruker AXS, 2004)'
_computing_molecular_graphics    'SCHAKAL99 (Keller, 1999)'
_computing_publication_material  'XCIF (Bruker AXS, 2001)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0651
_diffrn_reflns_av_sigmaI/netI    0.0635
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            38438
_diffrn_reflns_theta_full        26.51
_diffrn_reflns_theta_max         26.51
_diffrn_reflns_theta_min         1.46
_exptl_absorpt_coefficient_mu    17.365
_exptl_absorpt_correction_T_max  0.3040
_exptl_absorpt_correction_T_min  0.1804
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details
;
 Data were corrected for Lorentz polarization and absorption
 effects (empirical absorption corrections SADABS).
 R(int) = 0.1579 (selected reflections only, before parameter refinement)
 R(int) = 0.0683 (selected reflections only, after parameter refinement)
;
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    2.766
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1824
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.09
_refine_diff_density_max         2.965
_refine_diff_density_min         -3.266
_refine_diff_density_rms         0.388
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.053
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     538
_refine_ls_number_reflns         9972
_refine_ls_number_restraints     299
_refine_ls_restrained_S_all      1.046
_refine_ls_R_factor_all          0.0788
_refine_ls_R_factor_gt           0.0508
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0892P)²+26.8524P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1369
_refine_ls_wR_factor_ref         0.1625
_reflns_number_gt                7318
_reflns_number_total             9972
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic6b02750_si_002.cif
_cod_data_source_block           '[TMBA]2[Pt12(CO)20(dppe)2]'
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/home/data/users/saulius/crontab/automatic-downloads/current/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 
;
_cod_original_cell_volume        2424.94(17)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4345490
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.38084(4) 0.47949(5) 0.32366(4) 0.02883(15) Uani 1 1 d . . .
Pt2 Pt 0.33738(5) 0.41429(5) 0.48118(4) 0.03130(15) Uani 1 1 d . . .
Pt3 Pt 0.14190(5) 0.28139(5) 0.23221(4) 0.03376(16) Uani 1 1 d . . .
Pt4 Pt 0.48575(5) 0.37160(5) 0.41559(4) 0.03059(15) Uani 1 1 d . . .
Pt5 Pt 0.27875(5) 0.18570(5) 0.27807(4) 0.03397(16) Uani 1 1 d . . .
Pt6 Pt 0.14833(5) 0.19574(5) 0.38674(4) 0.03608(16) Uani 1 1 d . . .
C1 C 0.4846(12) 0.4236(16) 0.2838(11) 0.047(5) Uani 1 1 d . . .
C2 C 0.5911(15) 0.3145(16) 0.4173(12) 0.051(5) Uani 1 1 d . . .
C3 C 0.4127(13) 0.3115(13) 0.5178(10) 0.038(4) Uani 1 1 d . . .
C4 C 0.2533(13) 0.4122(12) 0.5651(10) 0.033(3) Uani 1 1 d . . .
C5 C 0.2694(12) 0.4961(13) 0.3860(11) 0.040(4) Uani 1 1 d . . .
C6 C 0.2337(12) 0.2460(13) 0.1554(10) 0.037(4) Uani 1 1 d . . .
C7 C 0.3850(14) 0.1440(16) 0.2467(11) 0.047(4) Uani 1 1 d . . .
C8 C 0.2302(13) 0.0991(13) 0.3765(12) 0.041(4) Uani 1 1 d . . .
C9 C 0.0928(14) 0.1617(16) 0.4901(14) 0.051(5) Uani 1 1 d . . .
C10 C 0.0479(13) 0.2745(14) 0.3203(14) 0.048(4) Uani 1 1 d . . .
O1 O 0.5236(9) 0.4122(10) 0.2229(8) 0.045(3) Uani 1 1 d . . .
O2 O 0.6549(12) 0.2786(13) 0.4158(11) 0.075(5) Uani 1 1 d . . .
O3 O 0.4082(10) 0.2496(10) 0.5650(8) 0.049(3) Uani 1 1 d . . .
O4 O 0.2003(11) 0.4104(12) 0.6163(9) 0.060(4) Uani 1 1 d . . .
O5 O 0.2007(9) 0.5284(9) 0.3828(8) 0.041(3) Uani 1 1 d . . .
O6 O 0.2534(9) 0.2491(9) 0.0834(8) 0.043(3) Uani 1 1 d . . .
O7 O 0.4483(10) 0.1172(12) 0.2270(9) 0.058(4) Uani 1 1 d . . .
O8 O 0.2393(11) 0.0276(10) 0.4086(9) 0.053(3) Uani 1 1 d . . .
O9 O 0.0577(12) 0.1382(12) 0.5512(11) 0.067(4) Uani 1 1 d . . .
O10 O -0.0206(12) 0.2919(14) 0.3377(11) 0.077(5) Uani 1 1 d . . .
P1 P 0.3744(3) 0.5752(3) 0.2073(3) 0.0320(8) Uani 1 1 d . . .
P2 P 0.0576(3) 0.3498(4) 0.1214(3) 0.0371(9) Uani 1 1 d . . .
C101 C 0.3558(11) 0.6987(8) 0.2346(7) 0.049(3) Uani 1 1 d GU . .
C102 C 0.3568(10) 0.7354(9) 0.3261(7) 0.049(3) Uani 1 1 d GU . .
H102 H 0.3726 0.7003 0.3764 0.058 Uiso 1 1 calc R . .
C103 C 0.3346(10) 0.8235(9) 0.3441(7) 0.054(4) Uani 1 1 d GU . .
H103 H 0.3353 0.8485 0.4067 0.065 Uiso 1 1 calc R . .
C104 C 0.3115(11) 0.8748(8) 0.2705(9) 0.058(4) Uani 1 1 d GU . .
H104 H 0.2964 0.9350 0.2828 0.070 Uiso 1 1 calc R . .
C105 C 0.3105(11) 0.8381(9) 0.1789(8) 0.066(4) Uani 1 1 d GU . .
H105 H 0.2947 0.8732 0.1286 0.079 Uiso 1 1 calc R . .
C106 C 0.3326(11) 0.7500(10) 0.1610(6) 0.064(4) Uani 1 1 d GU . .
H106 H 0.3320 0.7250 0.0984 0.077 Uiso 1 1 calc R . .
C107 C 0.4972(7) 0.6185(12) 0.1635(8) 0.050(4) Uani 1 1 d GU . .
C108 C 0.6032(9) 0.6596(12) 0.2312(6) 0.057(4) Uani 1 1 d GU . .
H108 H 0.6097 0.6641 0.2975 0.069 Uiso 1 1 calc R . .
C109 C 0.6995(7) 0.6940(12) 0.2020(7) 0.059(4) Uani 1 1 d GU . .
H109 H 0.7719 0.7220 0.2483 0.071 Uiso 1 1 calc R . .
C110 C 0.6899(8) 0.6873(13) 0.1051(8) 0.072(5) Uani 1 1 d GU . .
H110 H 0.7557 0.7109 0.0851 0.087 Uiso 1 1 calc R . .
C111 C 0.5840(9) 0.6463(14) 0.0373(6) 0.082(5) Uani 1 1 d GU . .
H111 H 0.5774 0.6418 -0.0289 0.099 Uiso 1 1 calc R . .
C112 C 0.4876(7) 0.6119(13) 0.0666(7) 0.072(5) Uani 1 1 d GU . .
H112 H 0.4152 0.5839 0.0203 0.086 Uiso 1 1 calc R . .
C113 C 0.2540(11) 0.5032(14) 0.0989(10) 0.037(3) Uani 1 1 d U . .
H11A H 0.2637 0.5432 0.0471 0.044 Uiso 1 1 calc R . .
H11B H 0.2524 0.4332 0.0774 0.044 Uiso 1 1 calc R . .
C201 C 0.0191(10) 0.2785(10) -0.0024(6) 0.056(4) Uani 1 1 d GU . .
C202 C -0.0156(10) 0.1694(10) -0.0174(7) 0.067(4) Uani 1 1 d GU . .
H202 H -0.0198 0.1346 0.0350 0.080 Uiso 1 1 calc R . .
C203 C -0.0441(10) 0.1112(8) -0.1091(9) 0.071(4) Uani 1 1 d GU . .
H203 H -0.0678 0.0366 -0.1194 0.085 Uiso 1 1 calc R . .
C204 C -0.0379(11) 0.1620(11) -0.1859(7) 0.073(5) Uani 1 1 d GU . .
H204 H -0.0574 0.1222 -0.2485 0.088 Uiso 1 1 calc R . .
C205 C -0.0031(10) 0.2712(11) -0.1709(7) 0.068(4) Uani 1 1 d GU . .
H205 H 0.0011 0.3059 -0.2233 0.081 Uiso 1 1 calc R . .
C206 C 0.0254(9) 0.3294(8) -0.0792(8) 0.058(4) Uani 1 1 d GU . .
H206 H 0.0491 0.4040 -0.0689 0.069 Uiso 1 1 calc R . .
C207 C -0.0708(9) 0.3559(12) 0.1350(10) 0.064(4) Uani 1 1 d GU . .
C208 C -0.1755(11) 0.2739(11) 0.0862(9) 0.073(4) Uani 1 1 d GU . .
H208 H -0.1806 0.2156 0.0436 0.087 Uiso 1 1 calc R . .
C209 C -0.2727(9) 0.2771(11) 0.0999(10) 0.080(4) Uani 1 1 d GU . .
H209 H -0.3442 0.2210 0.0666 0.096 Uiso 1 1 calc R . .
C210 C -0.2653(10) 0.3623(13) 0.1623(11) 0.077(4) Uani 1 1 d GU . .
H210 H -0.3317 0.3645 0.1716 0.093 Uiso 1 1 calc R . .
C211 C -0.1606(12) 0.4444(11) 0.2110(10) 0.085(5) Uani 1 1 d GU . .
H211 H -0.1555 0.5027 0.2536 0.102 Uiso 1 1 calc R . .
C212 C -0.0634(9) 0.4412(11) 0.1973(10) 0.079(4) Uani 1 1 d GU . .
H212 H 0.0081 0.4973 0.2306 0.094 Uiso 1 1 calc R . .
C213 C 0.1412(12) 0.4873(14) 0.1166(11) 0.039(3) Uani 1 1 d U . .
H21A H 0.0968 0.5083 0.0647 0.046 Uiso 1 1 calc R . .
H21B H 0.1565 0.5342 0.1779 0.046 Uiso 1 1 calc R . .
N1 N 0.7304(17) 0.0468(16) 0.3550(15) 0.108(5) Uani 1 1 d DU . .
C301 C 0.789(2) -0.0232(19) 0.370(2) 0.094(7) Uani 1 1 d DU . .
H30A H 0.8629 0.0098 0.3596 0.141 Uiso 1 1 calc R . .
H30B H 0.7440 -0.0916 0.3255 0.141 Uiso 1 1 calc R . .
H30C H 0.8001 -0.0343 0.4363 0.141 Uiso 1 1 calc R . .
C302 C 0.794(2) 0.133(2) 0.443(2) 0.134(9) Uani 1 1 d DU . .
H30D H 0.8687 0.1769 0.4393 0.201 Uiso 1 1 calc RD . .
H30E H 0.8010 0.1015 0.4998 0.201 Uiso 1 1 calc RD . .
H30F H 0.7524 0.1768 0.4475 0.201 Uiso 1 1 calc R . .
C303 C 0.623(2) -0.007(2) 0.373(2) 0.120(8) Uani 1 1 d DU . .
H30G H 0.6328 -0.0422 0.4262 0.180 Uiso 1 1 calc R . .
H30H H 0.5687 -0.0591 0.3149 0.180 Uiso 1 1 calc R . .
H30I H 0.5943 0.0456 0.3883 0.180 Uiso 1 1 calc R . .
C304 C 0.729(3) 0.103(2) 0.2751(15) 0.103(5) Uani 1 1 d DU . .
H30J H 0.7991 0.1684 0.2923 0.123 Uiso 1 1 calc R . .
H30K H 0.6646 0.1226 0.2643 0.123 Uiso 1 1 calc R . .
C305 C 0.7185(19) 0.0360(17) 0.1849(13) 0.105(5) Uani 1 1 d GDU . .
C306 C 0.8131(15) 0.0261(17) 0.1720(14) 0.115(6) Uani 1 1 d GU . .
H306 H 0.8815 0.0540 0.2235 0.137 Uiso 1 1 calc R . .
C307 C 0.8079(17) -0.0245(18) 0.0839(17) 0.128(6) Uani 1 1 d GU . .
H307 H 0.8726 -0.0313 0.0750 0.153 Uiso 1 1 calc R . .
C308 C 0.708(2) -0.0653(18) 0.0086(13) 0.135(6) Uani 1 1 d GU . .
H308 H 0.7043 -0.0999 -0.0517 0.163 Uiso 1 1 calc R . .
C309 C 0.6132(17) -0.0554(18) 0.0215(14) 0.137(6) Uani 1 1 d GU . .
H309 H 0.5449 -0.0833 -0.0299 0.164 Uiso 1 1 calc R . .
C310 C 0.6185(16) -0.0048(18) 0.1097(17) 0.121(6) Uani 1 1 d GU . .
H310 H 0.5538 0.0020 0.1185 0.145 Uiso 1 1 calc R . .
N2 N 0.964(4) 0.446(3) 0.489(3) 0.099(13) Uiso 0.50 1 d PDU A -1
C401 C 0.936(5) 0.368(4) 0.522(3) 0.108(14) Uiso 0.50 1 d PDU A -1
C402 C 0.943(6) 0.324(3) 0.610(3) 0.16(2) Uiso 0.50 1 d PDU A -1
H40A H 0.8979 0.2469 0.5928 0.233 Uiso 0.50 1 calc PRD A -1
H40B H 0.9137 0.3559 0.6532 0.233 Uiso 0.50 1 calc PR A -1
H40C H 1.0217 0.3394 0.6424 0.233 Uiso 0.50 1 calc PR A -1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C5 Pt1 C1 161.3(8) . .
C5 Pt1 P1 103.0(5) . .
C1 Pt1 P1 94.9(6) . .
C5 Pt1 Pt2 51.9(5) . .
C1 Pt1 Pt2 110.7(5) . .
P1 Pt1 Pt2 154.28(10) . .
C5 Pt1 Pt4 111.2(5) . .
C1 Pt1 Pt4 51.6(5) . .
P1 Pt1 Pt4 145.45(10) . .
Pt2 Pt1 Pt4 59.34(2) . .
C5 Pt1 Pt3 70.5(4) . .
C1 Pt1 Pt3 101.5(5) . .
P1 Pt1 Pt3 99.53(10) . .
Pt2 Pt1 Pt3 78.88(2) . .
Pt4 Pt1 Pt3 95.90(2) . .
C4 Pt2 C3 105.7(6) . .
C4 Pt2 C5 96.9(6) . .
C3 Pt2 C5 154.8(6) . .
C4 Pt2 Pt4 155.0(4) . .
C3 Pt2 Pt4 49.8(5) . .
C5 Pt2 Pt4 108.1(5) . .
C4 Pt2 Pt1 144.6(4) . .
C3 Pt2 Pt1 109.2(5) . .
C5 Pt2 Pt1 47.8(5) . .
Pt4 Pt2 Pt1 60.36(2) . .
C4 Pt2 Pt4 92.3(5) . 2_666
C3 Pt2 Pt4 104.4(4) . 2_666
C5 Pt2 Pt4 85.6(4) . 2_666
Pt4 Pt2 Pt4 90.43(2) . 2_666
Pt1 Pt2 Pt4 84.66(2) . 2_666
C4 Pt2 Pt6 83.6(5) . .
C3 Pt2 Pt6 76.6(4) . .
C5 Pt2 Pt6 95.2(4) . .
Pt4 Pt2 Pt6 93.17(2) . .
Pt1 Pt2 Pt6 98.87(2) . .
Pt4 Pt2 Pt6 175.88(3) 2_666 .
C10 Pt3 C6 162.3(7) . .
C10 Pt3 P2 97.7(5) . .
C6 Pt3 P2 96.4(5) . .
C10 Pt3 Pt6 53.1(5) . .
C6 Pt3 Pt6 111.4(5) . .
P2 Pt3 Pt6 150.35(10) . .
C10 Pt3 Pt5 113.5(5) . .
C6 Pt3 Pt5 51.4(5) . .
P2 Pt3 Pt5 147.71(10) . .
Pt6 Pt3 Pt5 60.40(2) . .
C10 Pt3 Pt1 108.8(5) . .
C6 Pt3 Pt1 79.1(4) . .
P2 Pt3 Pt1 99.86(12) . .
Pt6 Pt3 Pt1 95.63(2) . .
Pt5 Pt3 Pt1 78.47(2) . .
C2 Pt4 C3 104.0(7) . .
C2 Pt4 C1 97.5(7) . .
C3 Pt4 C1 154.0(5) . .
C2 Pt4 Pt2 154.4(6) . .
C3 Pt4 Pt2 50.8(4) . .
C1 Pt4 Pt2 107.9(4) . .
C2 Pt4 Pt1 145.3(6) . .
C3 Pt4 Pt1 110.2(4) . .
C1 Pt4 Pt1 47.9(4) . .
Pt2 Pt4 Pt1 60.30(2) . .
C2 Pt4 Pt2 93.1(6) . 2_666
C3 Pt4 Pt2 104.0(4) . 2_666
C1 Pt4 Pt2 89.0(5) . 2_666
Pt2 Pt4 Pt2 89.57(2) . 2_666
Pt1 Pt4 Pt2 84.24(2) . 2_666
C2 Pt4 Pt5 98.1(6) . .
C3 Pt4 Pt5 83.2(4) . .
C1 Pt4 Pt5 79.6(5) . .
Pt2 Pt4 Pt5 84.76(2) . .
Pt1 Pt4 Pt5 80.80(2) . .
Pt2 Pt4 Pt5 164.90(3) 2_666 .
C7 Pt5 C8 104.1(7) . .
C7 Pt5 C6 99.1(6) . .
C8 Pt5 C6 148.8(6) . .
C7 Pt5 Pt3 147.4(5) . .
C8 Pt5 Pt3 107.3(5) . .
C6 Pt5 Pt3 48.4(4) . .
C7 Pt5 Pt6 152.8(5) . .
C8 Pt5 Pt6 49.6(5) . .
C6 Pt5 Pt6 107.7(4) . .
Pt3 Pt5 Pt6 59.74(2) . .
C7 Pt5 Pt4 84.2(6) . .
C8 Pt5 Pt4 98.1(4) . .
C6 Pt5 Pt4 104.8(4) . .
Pt3 Pt5 Pt4 99.56(3) . .
Pt6 Pt5 Pt4 92.38(2) . .
C9 Pt6 C8 102.8(8) . .
C9 Pt6 C10 101.3(8) . .
C8 Pt6 C10 150.6(7) . .
C9 Pt6 Pt3 149.1(6) . .
C8 Pt6 Pt3 106.7(5) . .
C10 Pt6 Pt3 47.7(5) . .
C9 Pt6 Pt5 151.0(6) . .
C8 Pt6 Pt5 48.9(5) . .
C10 Pt6 Pt5 107.5(5) . .
Pt3 Pt6 Pt5 59.86(2) . .
C9 Pt6 Pt2 99.7(6) . .
C8 Pt6 Pt2 104.4(4) . .
C10 Pt6 Pt2 87.7(5) . .
Pt3 Pt6 Pt2 81.93(2) . .
Pt5 Pt6 Pt2 84.54(2) . .
O1 C1 Pt1 145.1(14) . .
O1 C1 Pt4 134.2(14) . .
Pt1 C1 Pt4 80.5(6) . .
O2 C2 Pt4 178.3(16) . .
O3 C3 Pt4 141.0(14) . .
O3 C3 Pt2 139.4(14) . .
Pt4 C3 Pt2 79.4(6) . .
O4 C4 Pt2 179.3(15) . .
O5 C5 Pt1 145.8(13) . .
O5 C5 Pt2 133.9(13) . .
Pt1 C5 Pt2 80.3(6) . .
O6 C6 Pt3 143.7(13) . .
O6 C6 Pt5 136.1(13) . .
Pt3 C6 Pt5 80.1(6) . .
O7 C7 Pt5 178.9(18) . .
O8 C8 Pt5 139.8(14) . .
O8 C8 Pt6 138.6(14) . .
Pt5 C8 Pt6 81.5(7) . .
O9 C9 Pt6 178.0(19) . .
O10 C10 Pt3 148.1(16) . .
O10 C10 Pt6 132.7(16) . .
Pt3 C10 Pt6 79.2(6) . .
C107 P1 C113 104.5(6) . .
C107 P1 C101 103.4(7) . .
C113 P1 C101 100.8(6) . .
C107 P1 Pt1 115.5(4) . .
C113 P1 Pt1 113.3(6) . .
C101 P1 Pt1 117.6(4) . .
C207 P2 C213 101.8(7) . .
C207 P2 C201 105.7(6) . .
C213 P2 C201 102.8(7) . .
C207 P2 Pt3 115.4(5) . .
C213 P2 Pt3 116.0(5) . .
C201 P2 Pt3 113.6(4) . .
C102 C101 C106 120.0 . .
C102 C101 P1 120.5(6) . .
C106 C101 P1 119.4(6) . .
C101 C102 C103 120.0 . .
C101 C102 H102 120.0 . .
C103 C102 H102 120.0 . .
C104 C103 C102 120.0 . .
C104 C103 H103 120.0 . .
C102 C103 H103 120.0 . .
C103 C104 C105 120.0 . .
C103 C104 H104 120.0 . .
C105 C104 H104 120.0 . .
C104 C105 C106 120.0 . .
C104 C105 H105 120.0 . .
C106 C105 H105 120.0 . .
C105 C106 C101 120.0 . .
C105 C106 H106 120.0 . .
C101 C106 H106 120.0 . .
C108 C107 C112 120.0 . .
C108 C107 P1 117.6(6) . .
C112 C107 P1 122.4(6) . .
C107 C108 C109 120.0 . .
C107 C108 H108 120.0 . .
C109 C108 H108 120.0 . .
C110 C109 C108 120.0 . .
C110 C109 H109 120.0 . .
C108 C109 H109 120.0 . .
C109 C110 C111 120.0 . .
C109 C110 H110 120.0 . .
C111 C110 H110 120.0 . .
C110 C111 C112 120.0 . .
C110 C111 H111 120.0 . .
C112 C111 H111 120.0 . .
C111 C112 C107 120.0 . .
C111 C112 H112 120.0 . .
C107 C112 H112 120.0 . .
C213 C113 P1 111.9(10) . .
C213 C113 H11A 109.2 . .
P1 C113 H11A 109.2 . .
C213 C113 H11B 109.2 . .
P1 C113 H11B 109.2 . .
H11A C113 H11B 107.9 . .
C202 C201 C206 120.0 . .
C202 C201 P2 117.2(7) . .
C206 C201 P2 122.8(7) . .
C201 C202 C203 120.0 . .
C201 C202 H202 120.0 . .
C203 C202 H202 120.0 . .
C204 C203 C202 120.0 . .
C204 C203 H203 120.0 . .
C202 C203 H203 120.0 . .
C203 C204 C205 120.0 . .
C203 C204 H204 120.0 . .
C205 C204 H204 120.0 . .
C206 C205 C204 120.0 . .
C206 C205 H205 120.0 . .
C204 C205 H205 120.0 . .
C205 C206 C201 120.0 . .
C205 C206 H206 120.0 . .
C201 C206 H206 120.0 . .
C208 C207 C212 120.0 . .
C208 C207 P2 120.3(8) . .
C212 C207 P2 119.6(8) . .
C209 C208 C207 120.0 . .
C209 C208 H208 120.0 . .
C207 C208 H208 120.0 . .
C208 C209 C210 120.0 . .
C208 C209 H209 120.0 . .
C210 C209 H209 120.0 . .
C211 C210 C209 120.0 . .
C211 C210 H210 120.0 . .
C209 C210 H210 120.0 . .
C210 C211 C212 120.0 . .
C210 C211 H211 120.0 . .
C212 C211 H211 120.0 . .
C211 C212 C207 120.0 . .
C211 C212 H212 120.0 . .
C207 C212 H212 120.0 . .
C113 C213 P2 112.6(12) . .
C113 C213 H21A 109.1 . .
P2 C213 H21A 109.1 . .
C113 C213 H21B 109.1 . .
P2 C213 H21B 109.1 . .
H21A C213 H21B 107.8 . .
C303 N1 C304 116(2) . .
C303 N1 C301 106.6(18) . .
C304 N1 C301 123(2) . .
C303 N1 C302 101.2(18) . .
C304 N1 C302 105(2) . .
C301 N1 C302 102.0(17) . .
N1 C301 H30A 109.5 . .
N1 C301 H30B 109.5 . .
H30A C301 H30B 109.5 . .
N1 C301 H30C 109.5 . .
H30A C301 H30C 109.5 . .
H30B C301 H30C 109.5 . .
N1 C302 H30D 109.5 . .
N1 C302 H30E 109.5 . .
H30D C302 H30E 109.5 . .
N1 C302 H30F 109.5 . .
H30D C302 H30F 109.5 . .
H30E C302 H30F 109.5 . .
N1 C303 H30G 109.5 . .
N1 C303 H30H 109.5 . .
H30G C303 H30H 109.5 . .
N1 C303 H30I 109.5 . .
H30G C303 H30I 109.5 . .
H30H C303 H30I 109.5 . .
N1 C304 C305 112(2) . .
N1 C304 H30J 109.2 . .
C305 C304 H30J 109.2 . .
N1 C304 H30K 109.2 . .
C305 C304 H30K 109.2 . .
H30J C304 H30K 107.9 . .
C306 C305 C310 120.0 . .
C306 C305 C304 119.5(19) . .
C310 C305 C304 120.0(19) . .
C305 C306 C307 120.0 . .
C305 C306 H306 120.0 . .
C307 C306 H306 120.0 . .
C308 C307 C306 120.0 . .
C308 C307 H307 120.0 . .
C306 C307 H307 120.0 . .
C307 C308 C309 120.0 . .
C307 C308 H308 120.0 . .
C309 C308 H308 120.0 . .
C310 C309 C308 120.0 . .
C310 C309 H309 120.0 . .
C308 C309 H309 120.0 . .
C309 C310 C305 120.0 . .
C309 C310 H310 120.0 . .
C305 C310 H310 120.0 . .
N2 C401 C402 146(4) . .
C401 C402 H40A 109.5 . .
C401 C402 H40B 109.5 . .
H40A C402 H40B 109.5 . .
C401 C402 H40C 109.5 . .
H40A C402 H40C 109.5 . .
H40B C402 H40C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 C5 2.012(17) .
Pt1 C1 2.016(16) .
Pt1 P1 2.272(4) .
Pt1 Pt2 2.6779(8) .
Pt1 Pt4 2.6795(7) .
Pt1 Pt3 3.1939(8) .
Pt2 C4 1.863(15) .
Pt2 C3 2.092(15) .
Pt2 C5 2.139(16) .
Pt2 Pt4 2.6520(8) .
Pt2 Pt4 2.9765(8) 2_666
Pt2 Pt6 3.0439(8) .
Pt3 C10 2.005(19) .
Pt3 C6 2.023(15) .
Pt3 P2 2.254(4) .
Pt3 Pt6 2.6612(9) .
Pt3 Pt5 2.6644(8) .
Pt4 C2 1.874(17) .
Pt4 C3 2.061(17) .
Pt4 C1 2.129(18) .
Pt4 Pt2 2.9765(8) 2_666
Pt4 Pt5 3.0557(8) .
Pt5 C7 1.875(17) .
Pt5 C8 2.040(18) .
Pt5 C6 2.114(17) .
Pt5 Pt6 2.6788(9) .
Pt6 C9 1.87(2) .
Pt6 C8 2.062(17) .
Pt6 C10 2.167(17) .
C1 O1 1.170(19) .
C2 O2 1.15(2) .
C3 O3 1.152(19) .
C4 O4 1.152(19) .
C5 O5 1.169(19) .
C6 O6 1.153(18) .
C7 O7 1.140(19) .
C8 O8 1.18(2) .
C9 O9 1.13(2) .
C10 O10 1.12(2) .
P1 C107 1.828(9) .
P1 C113 1.837(14) .
P1 C101 1.859(9) .
P2 C207 1.822(9) .
P2 C213 1.834(18) .
P2 C201 1.839(9) .
C101 C102 1.3900 .
C101 C106 1.3900 .
C102 C103 1.3900 .
C102 H102 0.9500 .
C103 C104 1.3900 .
C103 H103 0.9500 .
C104 C105 1.3900 .
C104 H104 0.9500 .
C105 C106 1.3900 .
C105 H105 0.9500 .
C106 H106 0.9500 .
C107 C108 1.3900 .
C107 C112 1.3900 .
C108 C109 1.3900 .
C108 H108 0.9500 .
C109 C110 1.3900 .
C109 H109 0.9500 .
C110 C111 1.3900 .
C110 H110 0.9500 .
C111 C112 1.3900 .
C111 H111 0.9500 .
C112 H112 0.9500 .
C113 C213 1.54(2) .
C113 H11A 0.9900 .
C113 H11B 0.9900 .
C201 C202 1.3900 .
C201 C206 1.3900 .
C202 C203 1.3900 .
C202 H202 0.9500 .
C203 C204 1.3900 .
C203 H203 0.9500 .
C204 C205 1.3900 .
C204 H204 0.9500 .
C205 C206 1.3900 .
C205 H205 0.9500 .
C206 H206 0.9500 .
C207 C208 1.3900 .
C207 C212 1.3900 .
C208 C209 1.3900 .
C208 H208 0.9500 .
C209 C210 1.3900 .
C209 H209 0.9500 .
C210 C211 1.3900 .
C210 H210 0.9500 .
C211 C212 1.3900 .
C211 H211 0.9500 .
C212 H212 0.9500 .
C213 H21A 0.9900 .
C213 H21B 0.9900 .
N1 C303 1.454(13) .
N1 C304 1.467(17) .
N1 C301 1.479(13) .
N1 C302 1.495(14) .
C301 H30A 0.9800 .
C301 H30B 0.9800 .
C301 H30C 0.9800 .
C302 H30D 0.9800 .
C302 H30E 0.9800 .
C302 H30F 0.9800 .
C303 H30G 0.9800 .
C303 H30H 0.9800 .
C303 H30I 0.9800 .
C304 C305 1.491(17) .
C304 H30J 0.9900 .
C304 H30K 0.9900 .
C305 C306 1.3900 .
C305 C310 1.3900 .
C306 C307 1.3900 .
C306 H306 0.9500 .
C307 C308 1.3900 .
C307 H307 0.9500 .
C308 C309 1.3900 .
C308 H308 0.9500 .
C309 C310 1.3900 .
C309 H309 0.9500 .
C310 H310 0.9500 .
N2 C401 1.196(19) .
C401 C402 1.490(19) .
C402 H40A 0.9800 .
C402 H40B 0.9800 .
C402 H40C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C5 Pt1 Pt2 C4 -2.4(10) . .
C1 Pt1 Pt2 C4 -174.5(10) . .
P1 Pt1 Pt2 C4 12.7(9) . .
Pt4 Pt1 Pt2 C4 180.0(8) . .
Pt3 Pt1 Pt2 C4 -76.2(8) . .
C5 Pt1 Pt2 C3 167.8(7) . .
C1 Pt1 Pt2 C3 -4.3(7) . .
P1 Pt1 Pt2 C3 -177.1(5) . .
Pt4 Pt1 Pt2 C3 -9.8(4) . .
Pt3 Pt1 Pt2 C3 94.0(4) . .
C1 Pt1 Pt2 C5 -172.1(8) . .
P1 Pt1 Pt2 C5 15.1(6) . .
Pt4 Pt1 Pt2 C5 -177.6(6) . .
Pt3 Pt1 Pt2 C5 -73.8(6) . .
C5 Pt1 Pt2 Pt4 177.6(6) . .
C1 Pt1 Pt2 Pt4 5.5(5) . .
P1 Pt1 Pt2 Pt4 -167.3(2) . .
Pt3 Pt1 Pt2 Pt4 103.78(2) . .
C5 Pt1 Pt2 Pt4 -88.8(6) . 2_666
C1 Pt1 Pt2 Pt4 99.1(5) . 2_666
P1 Pt1 Pt2 Pt4 -73.8(2) . 2_666
Pt4 Pt1 Pt2 Pt4 93.55(2) . 2_666
Pt3 Pt1 Pt2 Pt4 -162.67(2) . 2_666
C5 Pt1 Pt2 Pt6 89.0(6) . .
C1 Pt1 Pt2 Pt6 -83.1(5) . .
P1 Pt1 Pt2 Pt6 104.1(2) . .
Pt4 Pt1 Pt2 Pt6 -88.60(2) . .
Pt3 Pt1 Pt2 Pt6 15.18(2) . .
C5 Pt1 Pt3 C10 -17.8(7) . .
C1 Pt1 Pt3 C10 144.7(8) . .
P1 Pt1 Pt3 C10 -118.3(6) . .
Pt2 Pt1 Pt3 C10 35.6(5) . .
Pt4 Pt1 Pt3 C10 92.7(5) . .
C5 Pt1 Pt3 C6 178.6(7) . .
C1 Pt1 Pt3 C6 -18.9(7) . .
P1 Pt1 Pt3 C6 78.1(5) . .
Pt2 Pt1 Pt3 C6 -128.0(5) . .
Pt4 Pt1 Pt3 C6 -70.9(5) . .
C5 Pt1 Pt3 P2 84.0(5) . .
C1 Pt1 Pt3 P2 -113.6(5) . .
P1 Pt1 Pt3 P2 -16.58(15) . .
Pt2 Pt1 Pt3 P2 137.32(10) . .
Pt4 Pt1 Pt3 P2 -165.55(10) . .
C5 Pt1 Pt3 Pt6 -70.7(5) . .
C1 Pt1 Pt3 Pt6 91.8(5) . .
P1 Pt1 Pt3 Pt6 -171.20(10) . .
Pt2 Pt1 Pt3 Pt6 -17.30(2) . .
Pt4 Pt1 Pt3 Pt6 39.83(3) . .
C5 Pt1 Pt3 Pt5 -128.9(5) . .
C1 Pt1 Pt3 Pt5 33.6(5) . .
P1 Pt1 Pt3 Pt5 130.59(10) . .
Pt2 Pt1 Pt3 Pt5 -75.52(2) . .
Pt4 Pt1 Pt3 Pt5 -18.39(2) . .
C4 Pt2 Pt4 C2 -0.2(17) . .
C3 Pt2 Pt4 C2 -12.4(14) . .
C5 Pt2 Pt4 C2 -178.3(14) . .
Pt1 Pt2 Pt4 C2 179.8(13) . .
Pt4 Pt2 Pt4 C2 96.2(13) 2_666 .
Pt6 Pt2 Pt4 C2 -81.8(13) . .
C4 Pt2 Pt4 C3 12.2(12) . .
C5 Pt2 Pt4 C3 -166.0(7) . .
Pt1 Pt2 Pt4 C3 -167.8(5) . .
Pt4 Pt2 Pt4 C3 108.6(5) 2_666 .
Pt6 Pt2 Pt4 C3 -69.4(5) . .
C4 Pt2 Pt4 C1 174.9(12) . .
C3 Pt2 Pt4 C1 162.7(7) . .
C5 Pt2 Pt4 C1 -3.3(7) . .
Pt1 Pt2 Pt4 C1 -5.2(5) . .
Pt4 Pt2 Pt4 C1 -88.8(5) 2_666 .
Pt6 Pt2 Pt4 C1 93.2(5) . .
C4 Pt2 Pt4 Pt1 -180.0(11) . .
C3 Pt2 Pt4 Pt1 167.8(5) . .
C5 Pt2 Pt4 Pt1 1.9(4) . .
Pt4 Pt2 Pt4 Pt1 -83.61(2) 2_666 .
Pt6 Pt2 Pt4 Pt1 98.40(2) . .
C4 Pt2 Pt4 Pt2 -96.4(11) . 2_666
C3 Pt2 Pt4 Pt2 -108.6(5) . 2_666
C5 Pt2 Pt4 Pt2 85.5(4) . 2_666
Pt1 Pt2 Pt4 Pt2 83.61(2) . 2_666
Pt4 Pt2 Pt4 Pt2 0.0 2_666 2_666
Pt6 Pt2 Pt4 Pt2 -177.99(3) . 2_666
C4 Pt2 Pt4 Pt5 97.6(11) . .
C3 Pt2 Pt4 Pt5 85.4(5) . .
C5 Pt2 Pt4 Pt5 -80.5(4) . .
Pt1 Pt2 Pt4 Pt5 -82.38(2) . .
Pt4 Pt2 Pt4 Pt5 -165.99(3) 2_666 .
Pt6 Pt2 Pt4 Pt5 16.02(2) . .
C5 Pt1 Pt4 C2 178.1(11) . .
C1 Pt1 Pt4 C2 6.8(12) . .
P1 Pt1 Pt4 C2 -9.5(10) . .
Pt2 Pt1 Pt4 C2 -179.8(10) . .
Pt3 Pt1 Pt4 C2 106.8(10) . .
C5 Pt1 Pt4 C3 8.0(6) . .
C1 Pt1 Pt4 C3 -163.3(8) . .
P1 Pt1 Pt4 C3 -179.6(5) . .
Pt2 Pt1 Pt4 C3 10.0(4) . .
Pt3 Pt1 Pt4 C3 -63.3(4) . .
C5 Pt1 Pt4 C1 171.4(8) . .
P1 Pt1 Pt4 C1 -16.3(7) . .
Pt2 Pt1 Pt4 C1 173.4(6) . .
Pt3 Pt1 Pt4 C1 100.0(6) . .
C5 Pt1 Pt4 Pt2 -2.0(5) . .
C1 Pt1 Pt4 Pt2 -173.4(6) . .
P1 Pt1 Pt4 Pt2 170.32(18) . .
Pt3 Pt1 Pt4 Pt2 -73.35(2) . .
C5 Pt1 Pt4 Pt2 -94.8(5) . 2_666
C1 Pt1 Pt4 Pt2 93.8(6) . 2_666
P1 Pt1 Pt4 Pt2 77.52(18) . 2_666
Pt2 Pt1 Pt4 Pt2 -92.80(2) . 2_666
Pt3 Pt1 Pt4 Pt2 -166.15(2) . 2_666
C5 Pt1 Pt4 Pt5 87.2(5) . .
C1 Pt1 Pt4 Pt5 -84.2(6) . .
P1 Pt1 Pt4 Pt5 -100.49(18) . .
Pt2 Pt1 Pt4 Pt5 89.19(2) . .
Pt3 Pt1 Pt4 Pt5 15.84(2) . .
C10 Pt3 Pt5 C7 176.3(12) . .
C6 Pt3 Pt5 C7 7.1(12) . .
P2 Pt3 Pt5 C7 12.2(11) . .
Pt6 Pt3 Pt5 C7 178.6(11) . .
Pt1 Pt3 Pt5 C7 -78.1(11) . .
C10 Pt3 Pt5 C8 12.2(7) . .
C6 Pt3 Pt5 C8 -157.0(7) . .
P2 Pt3 Pt5 C8 -151.9(5) . .
Pt6 Pt3 Pt5 C8 14.5(4) . .
Pt1 Pt3 Pt5 C8 117.9(4) . .
C10 Pt3 Pt5 C6 169.2(8) . .
P2 Pt3 Pt5 C6 5.1(6) . .
Pt6 Pt3 Pt5 C6 171.5(5) . .
Pt1 Pt3 Pt5 C6 -85.1(5) . .
C10 Pt3 Pt5 Pt6 -2.3(5) . .
C6 Pt3 Pt5 Pt6 -171.5(5) . .
P2 Pt3 Pt5 Pt6 -166.4(2) . .
Pt1 Pt3 Pt5 Pt6 103.36(2) . .
C10 Pt3 Pt5 Pt4 -89.4(5) . .
C6 Pt3 Pt5 Pt4 101.3(5) . .
P2 Pt3 Pt5 Pt4 106.4(2) . .
Pt6 Pt3 Pt5 Pt4 -87.16(3) . .
Pt1 Pt3 Pt5 Pt4 16.20(2) . .
C2 Pt4 Pt5 C7 -16.8(8) . .
C3 Pt4 Pt5 C7 -120.1(7) . .
C1 Pt4 Pt5 C7 79.4(7) . .
Pt2 Pt4 Pt5 C7 -171.3(6) . .
Pt1 Pt4 Pt5 C7 128.0(6) . .
Pt2 Pt4 Pt5 C7 120.4(6) 2_666 .
C2 Pt4 Pt5 C8 86.6(8) . .
C3 Pt4 Pt5 C8 -16.6(6) . .
C1 Pt4 Pt5 C8 -177.1(7) . .
Pt2 Pt4 Pt5 C8 -67.8(5) . .
Pt1 Pt4 Pt5 C8 -128.5(5) . .
Pt2 Pt4 Pt5 C8 -136.1(5) 2_666 .
C2 Pt4 Pt5 C6 -114.8(7) . .
C3 Pt4 Pt5 C6 141.9(6) . .
C1 Pt4 Pt5 C6 -18.6(6) . .
Pt2 Pt4 Pt5 C6 90.8(4) . .
Pt1 Pt4 Pt5 C6 30.1(4) . .
Pt2 Pt4 Pt5 C6 22.5(4) 2_666 .
C2 Pt4 Pt5 Pt3 -164.2(6) . .
C3 Pt4 Pt5 Pt3 92.6(4) . .
C1 Pt4 Pt5 Pt3 -67.9(5) . .
Pt2 Pt4 Pt5 Pt3 41.44(3) . .
Pt1 Pt4 Pt5 Pt3 -19.27(3) . .
Pt2 Pt4 Pt5 Pt3 -26.90(11) 2_666 .
C2 Pt4 Pt5 Pt6 136.1(6) . .
C3 Pt4 Pt5 Pt6 32.9(4) . .
C1 Pt4 Pt5 Pt6 -127.6(5) . .
Pt2 Pt4 Pt5 Pt6 -18.27(3) . .
Pt1 Pt4 Pt5 Pt6 -78.98(3) . .
Pt2 Pt4 Pt5 Pt6 -86.60(11) 2_666 .
C10 Pt3 Pt6 C9 1.2(13) . .
C6 Pt3 Pt6 C9 -169.1(12) . .
P2 Pt3 Pt6 C9 -10.9(11) . .
Pt5 Pt3 Pt6 C9 -176.2(11) . .
Pt1 Pt3 Pt6 C9 110.5(11) . .
C10 Pt3 Pt6 C8 163.1(8) . .
C6 Pt3 Pt6 C8 -7.2(6) . .
P2 Pt3 Pt6 C8 151.0(5) . .
Pt5 Pt3 Pt6 C8 -14.3(4) . .
Pt1 Pt3 Pt6 C8 -87.6(4) . .
C6 Pt3 Pt6 C10 -170.3(8) . .
P2 Pt3 Pt6 C10 -12.1(7) . .
Pt5 Pt3 Pt6 C10 -177.4(6) . .
Pt1 Pt3 Pt6 C10 109.3(6) . .
C10 Pt3 Pt6 Pt5 177.4(6) . .
C6 Pt3 Pt6 Pt5 7.1(4) . .
P2 Pt3 Pt6 Pt5 165.3(2) . .
Pt1 Pt3 Pt6 Pt5 -73.32(2) . .
C10 Pt3 Pt6 Pt2 -94.3(6) . .
C6 Pt3 Pt6 Pt2 95.5(4) . .
P2 Pt3 Pt6 Pt2 -106.4(2) . .
Pt5 Pt3 Pt6 Pt2 88.35(2) . .
Pt1 Pt3 Pt6 Pt2 15.03(2) . .
C7 Pt5 Pt6 C9 -2.4(17) . .
C8 Pt5 Pt6 C9 14.3(13) . .
C6 Pt5 Pt6 C9 169.3(12) . .
Pt3 Pt5 Pt6 C9 175.9(11) . .
Pt4 Pt5 Pt6 C9 -84.4(11) . .
C7 Pt5 Pt6 C8 -16.6(13) . .
C6 Pt5 Pt6 C8 155.0(7) . .
Pt3 Pt5 Pt6 C8 161.7(5) . .
Pt4 Pt5 Pt6 C8 -98.6(5) . .
C7 Pt5 Pt6 C10 -176.3(13) . .
C8 Pt5 Pt6 C10 -159.7(7) . .
C6 Pt5 Pt6 C10 -4.6(7) . .
Pt3 Pt5 Pt6 C10 2.0(5) . .
Pt4 Pt5 Pt6 C10 101.7(5) . .
C7 Pt5 Pt6 Pt3 -178.3(12) . .
C8 Pt5 Pt6 Pt3 -161.7(5) . .
C6 Pt5 Pt6 Pt3 -6.7(4) . .
Pt4 Pt5 Pt6 Pt3 99.68(3) . .
C7 Pt5 Pt6 Pt2 97.8(12) . .
C8 Pt5 Pt6 Pt2 114.5(5) . .
C6 Pt5 Pt6 Pt2 -90.5(4) . .
Pt3 Pt5 Pt6 Pt2 -83.83(2) . .
Pt4 Pt5 Pt6 Pt2 15.85(2) . .
C4 Pt2 Pt6 C9 -22.5(7) . .
C3 Pt2 Pt6 C9 85.3(8) . .
C5 Pt2 Pt6 C9 -118.8(7) . .
Pt4 Pt2 Pt6 C9 132.7(6) . .
Pt1 Pt2 Pt6 C9 -166.9(6) . .
Pt4 Pt2 Pt6 C9 -18.1(7) 2_666 .
C4 Pt2 Pt6 C8 -128.4(7) . .
C3 Pt2 Pt6 C8 -20.6(7) . .
C5 Pt2 Pt6 C8 135.2(7) . .
Pt4 Pt2 Pt6 C8 26.7(5) . .
Pt1 Pt2 Pt6 C8 87.2(5) . .
Pt4 Pt2 Pt6 C8 -124.1(6) 2_666 .
C4 Pt2 Pt6 C10 78.6(7) . .
C3 Pt2 Pt6 C10 -173.5(7) . .
C5 Pt2 Pt6 C10 -17.7(7) . .
Pt4 Pt2 Pt6 C10 -126.2(5) . .
Pt1 Pt2 Pt6 C10 -65.7(5) . .
Pt4 Pt2 Pt6 C10 83.0(6) 2_666 .
C4 Pt2 Pt6 Pt3 126.2(4) . .
C3 Pt2 Pt6 Pt3 -125.9(5) . .
C5 Pt2 Pt6 Pt3 29.9(5) . .
Pt4 Pt2 Pt6 Pt3 -78.63(2) . .
Pt1 Pt2 Pt6 Pt3 -18.15(2) . .
Pt4 Pt2 Pt6 Pt3 130.6(4) 2_666 .
C4 Pt2 Pt6 Pt5 -173.5(4) . .
C3 Pt2 Pt6 Pt5 -65.7(5) . .
C5 Pt2 Pt6 Pt5 90.2(5) . .
Pt4 Pt2 Pt6 Pt5 -18.36(2) . .
Pt1 Pt2 Pt6 Pt5 42.12(3) . .
Pt4 Pt2 Pt6 Pt5 -169.1(4) 2_666 .
C5 Pt1 C1 O1 148(2) . .
P1 Pt1 C1 O1 -15(3) . .
Pt2 Pt1 C1 O1 168(2) . .
Pt4 Pt1 C1 O1 174(3) . .
Pt3 Pt1 C1 O1 86(3) . .
C5 Pt1 C1 Pt4 -26(2) . .
P1 Pt1 C1 Pt4 170.8(4) . .
Pt2 Pt1 C1 Pt4 -6.1(6) . .
Pt3 Pt1 C1 Pt4 -88.4(4) . .
C2 Pt4 C1 O1 8(2) . .
C3 Pt4 C1 O1 -137.7(16) . .
Pt2 Pt4 C1 O1 -169.5(17) . .
Pt1 Pt4 C1 O1 -176(2) . .
Pt2 Pt4 C1 O1 101.3(19) 2_666 .
Pt5 Pt4 C1 O1 -88.5(19) . .
C2 Pt4 C1 Pt1 -176.1(7) . .
C3 Pt4 C1 Pt1 37.8(18) . .
Pt2 Pt4 C1 Pt1 6.0(6) . .
Pt2 Pt4 C1 Pt1 -83.2(4) 2_666 .
Pt5 Pt4 C1 Pt1 87.0(4) . .
C3 Pt4 C2 O2 131(68) . .
C1 Pt4 C2 O2 -35(68) . .
Pt2 Pt4 C2 O2 141(67) . .
Pt1 Pt4 C2 O2 -40(68) . .
Pt2 Pt4 C2 O2 -124(68) 2_666 .
Pt5 Pt4 C2 O2 46(68) . .
C2 Pt4 C3 O3 -11(2) . .
C1 Pt4 C3 O3 134.7(19) . .
Pt2 Pt4 C3 O3 175(2) . .
Pt1 Pt4 C3 O3 163.7(17) . .
Pt2 Pt4 C3 O3 -107.4(19) 2_666 .
Pt5 Pt4 C3 O3 86.2(19) . .
C2 Pt4 C3 Pt2 174.5(6) . .
C1 Pt4 C3 Pt2 -40.3(17) . .
Pt1 Pt4 C3 Pt2 -11.3(5) . .
Pt2 Pt4 C3 Pt2 77.7(3) 2_666 .
Pt5 Pt4 C3 Pt2 -88.8(3) . .
C4 Pt2 C3 O3 10.2(19) . .
C5 Pt2 C3 O3 -142.3(17) . .
Pt4 Pt2 C3 O3 -175(2) . .
Pt1 Pt2 C3 O3 -163.9(17) . .
Pt4 Pt2 C3 O3 106.8(18) 2_666 .
Pt6 Pt2 C3 O3 -69.1(18) . .
C4 Pt2 C3 Pt4 -174.7(5) . .
C5 Pt2 C3 Pt4 32.8(15) . .
Pt1 Pt2 C3 Pt4 11.2(5) . .
Pt4 Pt2 C3 Pt4 -78.1(3) 2_666 .
Pt6 Pt2 C3 Pt4 106.1(4) . .
C3 Pt2 C4 O4 -111(100) . .
C5 Pt2 C4 O4 57(100) . .
Pt4 Pt2 C4 O4 -121(100) . .
Pt1 Pt2 C4 O4 59(100) . .
Pt4 Pt2 C4 O4 143(100) 2_666 .
Pt6 Pt2 C4 O4 -37(100) . .
C1 Pt1 C5 O5 -156(2) . .
P1 Pt1 C5 O5 7(2) . .
Pt2 Pt1 C5 O5 -180(3) . .
Pt4 Pt1 C5 O5 -178(2) . .
Pt3 Pt1 C5 O5 -89(2) . .
C1 Pt1 C5 Pt2 24(2) . .
P1 Pt1 C5 Pt2 -173.3(3) . .
Pt4 Pt1 C5 Pt2 2.2(5) . .
Pt3 Pt1 C5 Pt2 91.0(4) . .
C4 Pt2 C5 O5 -1.6(18) . .
C3 Pt2 C5 O5 151.9(16) . .
Pt4 Pt2 C5 O5 177.7(16) . .
Pt1 Pt2 C5 O5 180(2) . .
Pt4 Pt2 C5 O5 -93.3(17) 2_666 .
Pt6 Pt2 C5 O5 82.6(17) . .
C4 Pt2 C5 Pt1 178.6(6) . .
C3 Pt2 C5 Pt1 -28.0(16) . .
Pt4 Pt2 C5 Pt1 -2.2(5) . .
Pt4 Pt2 C5 Pt1 86.8(4) 2_666 .
Pt6 Pt2 C5 Pt1 -97.2(4) . .
C10 Pt3 C6 O6 143(2) . .
P2 Pt3 C6 O6 0(2) . .
Pt6 Pt3 C6 O6 169(2) . .
Pt5 Pt3 C6 O6 177(2) . .
Pt1 Pt3 C6 O6 -99(2) . .
C10 Pt3 C6 Pt5 -34(2) . .
P2 Pt3 C6 Pt5 -177.3(3) . .
Pt6 Pt3 C6 Pt5 -7.9(5) . .
Pt1 Pt3 C6 Pt5 83.9(3) . .
C7 Pt5 C6 O6 6.4(19) . .
C8 Pt5 C6 O6 -131.4(17) . .
Pt3 Pt5 C6 O6 -177(2) . .
Pt6 Pt5 C6 O6 -169.7(16) . .
Pt4 Pt5 C6 O6 92.8(17) . .
C7 Pt5 C6 Pt3 -176.1(7) . .
C8 Pt5 C6 Pt3 46.0(13) . .
Pt6 Pt5 C6 Pt3 7.7(5) . .
Pt4 Pt5 C6 Pt3 -89.7(4) . .
C8 Pt5 C7 O7 66(86) . .
C6 Pt5 C7 O7 -93(86) . .
Pt3 Pt5 C7 O7 -99(86) . .
Pt6 Pt5 C7 O7 79(86) . .
Pt4 Pt5 C7 O7 162(86) . .
C7 Pt5 C8 O8 -11(2) . .
C6 Pt5 C8 O8 126.2(19) . .
Pt3 Pt5 C8 O8 160.5(18) . .
Pt6 Pt5 C8 O8 177(2) . .
Pt4 Pt5 C8 O8 -96.8(19) . .
C7 Pt5 C8 Pt6 172.3(6) . .
C6 Pt5 C8 Pt6 -50.8(12) . .
Pt3 Pt5 C8 Pt6 -16.5(5) . .
Pt4 Pt5 C8 Pt6 86.2(4) . .
C9 Pt6 C8 O8 10(2) . .
C10 Pt6 C8 O8 -134.6(18) . .
Pt3 Pt6 C8 O8 -160.6(18) . .
Pt5 Pt6 C8 O8 -177(2) . .
Pt2 Pt6 C8 O8 113.6(18) . .
C9 Pt6 C8 Pt5 -173.0(6) . .
C10 Pt6 C8 Pt5 42.5(14) . .
Pt3 Pt6 C8 Pt5 16.5(5) . .
Pt2 Pt6 C8 Pt5 -69.3(4) . .
C8 Pt6 C9 O9 -56(50) . .
C10 Pt6 C9 O9 107(50) . .
Pt3 Pt6 C9 O9 106(50) . .
Pt5 Pt6 C9 O9 -67(50) . .
Pt2 Pt6 C9 O9 -164(50) . .
C6 Pt3 C10 O10 -147(3) . .
P2 Pt3 C10 O10 -4(3) . .
Pt6 Pt3 C10 O10 -178(3) . .
Pt5 Pt3 C10 O10 -175(3) . .
Pt1 Pt3 C10 O10 99(3) . .
C6 Pt3 C10 Pt6 31(2) . .
P2 Pt3 C10 Pt6 174.0(3) . .
Pt5 Pt3 C10 Pt6 2.5(6) . .
Pt1 Pt3 C10 Pt6 -82.8(4) . .
C9 Pt6 C10 O10 -1(2) . .
C8 Pt6 C10 O10 144(2) . .
Pt3 Pt6 C10 O10 178(3) . .
Pt5 Pt6 C10 O10 176(2) . .
Pt2 Pt6 C10 O10 -100(2) . .
C9 Pt6 C10 Pt3 -179.4(7) . .
C8 Pt6 C10 Pt3 -34.6(15) . .
Pt5 Pt6 C10 Pt3 -2.4(6) . .
Pt2 Pt6 C10 Pt3 81.2(4) . .
C5 Pt1 P1 C107 159.0(7) . .
C1 Pt1 P1 C107 -26.4(7) . .
Pt2 Pt1 P1 C107 146.8(5) . .
Pt4 Pt1 P1 C107 -13.7(6) . .
Pt3 Pt1 P1 C107 -129.0(5) . .
C5 Pt1 P1 C113 -80.6(7) . .
C1 Pt1 P1 C113 93.9(7) . .
Pt2 Pt1 P1 C113 -92.8(6) . .
Pt4 Pt1 P1 C113 106.7(5) . .
Pt3 Pt1 P1 C113 -8.6(5) . .
C5 Pt1 P1 C101 36.4(7) . .
C1 Pt1 P1 C101 -149.1(7) . .
Pt2 Pt1 P1 C101 24.2(6) . .
Pt4 Pt1 P1 C101 -136.3(5) . .
Pt3 Pt1 P1 C101 108.4(5) . .
C10 Pt3 P2 C207 -8.9(8) . .
C6 Pt3 P2 C207 160.4(7) . .
Pt6 Pt3 P2 C207 0.8(7) . .
Pt5 Pt3 P2 C207 156.4(5) . .
Pt1 Pt3 P2 C207 -119.6(6) . .
C10 Pt3 P2 C213 109.9(8) . .
C6 Pt3 P2 C213 -80.7(7) . .
Pt6 Pt3 P2 C213 119.7(6) . .
Pt5 Pt3 P2 C213 -84.7(6) . .
Pt1 Pt3 P2 C213 -0.7(6) . .
C10 Pt3 P2 C201 -131.2(7) . .
C6 Pt3 P2 C201 38.2(6) . .
Pt6 Pt3 P2 C201 -121.4(5) . .
Pt5 Pt3 P2 C201 34.2(6) . .
Pt1 Pt3 P2 C201 118.1(5) . .
C107 P1 C101 C102 -122.6(7) . .
C113 P1 C101 C102 129.6(8) . .
Pt1 P1 C101 C102 6.0(9) . .
C107 P1 C101 C106 62.1(7) . .
C113 P1 C101 C106 -45.8(9) . .
Pt1 P1 C101 C106 -169.4(5) . .
C106 C101 C102 C103 0.0 . .
P1 C101 C102 C103 -175.3(9) . .
C101 C102 C103 C104 0.0 . .
C102 C103 C104 C105 0.0 . .
C103 C104 C105 C106 0.0 . .
C104 C105 C106 C101 0.0 . .
C102 C101 C106 C105 0.0 . .
P1 C101 C106 C105 175.4(9) . .
C113 P1 C107 C108 -169.0(9) . .
C101 P1 C107 C108 85.9(9) . .
Pt1 P1 C107 C108 -44.0(10) . .
C113 P1 C107 C112 11.1(11) . .
C101 P1 C107 C112 -93.9(9) . .
Pt1 P1 C107 C112 136.2(8) . .
C112 C107 C108 C109 0.0 . .
P1 C107 C108 C109 -179.8(11) . .
C107 C108 C109 C110 0.0 . .
C108 C109 C110 C111 0.0 . .
C109 C110 C111 C112 0.0 . .
C110 C111 C112 C107 0.0 . .
C108 C107 C112 C111 0.0 . .
P1 C107 C112 C111 179.8(12) . .
C107 P1 C113 C213 -164.1(12) . .
C101 P1 C113 C213 -57.1(13) . .
Pt1 P1 C113 C213 69.5(12) . .
C207 P2 C201 C202 -92.3(8) . .
C213 P2 C201 C202 161.3(7) . .
Pt3 P2 C201 C202 35.1(7) . .
C207 P2 C201 C206 88.7(8) . .
C213 P2 C201 C206 -17.6(8) . .
Pt3 P2 C201 C206 -143.9(6) . .
C206 C201 C202 C203 0.0 . .
P2 C201 C202 C203 -179.0(8) . .
C201 C202 C203 C204 0.0 . .
C202 C203 C204 C205 0.0 . .
C203 C204 C205 C206 0.0 . .
C204 C205 C206 C201 0.0 . .
C202 C201 C206 C205 0.0 . .
P2 C201 C206 C205 178.9(9) . .
C213 P2 C207 C208 140.0(8) . .
C201 P2 C207 C208 32.9(9) . .
Pt3 P2 C207 C208 -93.4(7) . .
C213 P2 C207 C212 -42.5(9) . .
C201 P2 C207 C212 -149.6(8) . .
Pt3 P2 C207 C212 84.0(8) . .
C212 C207 C208 C209 0.0 . .
P2 C207 C208 C209 177.4(10) . .
C207 C208 C209 C210 0.0 . .
C208 C209 C210 C211 0.0 . .
C209 C210 C211 C212 0.0 . .
C210 C211 C212 C207 0.0 . .
C208 C207 C212 C211 0.0 . .
P2 C207 C212 C211 -177.5(10) . .
P1 C113 C213 P2 -107.1(11) . .
C207 P2 C213 C113 -176.5(10) . .
C201 P2 C213 C113 -67.2(11) . .
Pt3 P2 C213 C113 57.4(11) . .
C303 N1 C304 C305 -96(3) . .
C301 N1 C304 C305 39(3) . .
C302 N1 C304 C305 154(2) . .
N1 C304 C305 C306 -79(3) . .
N1 C304 C305 C310 109(2) . .
C310 C305 C306 C307 0.0 . .
C304 C305 C306 C307 -172(2) . .
C305 C306 C307 C308 0.0 . .
C306 C307 C308 C309 0.0 . .
C307 C308 C309 C310 0.0 . .
C308 C309 C310 C305 0.0 . .
C306 C305 C310 C309 0.0 . .
C304 C305 C310 C309 172(2) . .
