#------------------------------------------------------------------------------
#$Date: 2017-07-25 02:22:46 +0300 (Tue, 25 Jul 2017) $
#$Revision: 198943 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/59/4345918.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4345918
loop_
_publ_author_name
'Schneider, Leon'
'Sivchik, Vasily'
'Chung, Kun-You'
'Chen, Yi-Ting'
'Karttunen, Antti J.'
'Chou, Pi-Tai'
'Koshevoy, Igor O.'
_publ_section_title
;
 Cyclometalated Platinum(II) Cyanometallates: Luminescent Blocks for
 Coordination Self-Assembly.
;
_journal_name_full               'Inorganic chemistry'
_journal_paper_doi               10.1021/acs.inorgchem.7b00006
_journal_year                    2017
_chemical_formula_moiety         'C98 H72 Ag2 F4 N6 P4 Pt2'
_chemical_formula_sum            'C98 H72 Ag2 F4 N6 P4 Pt2'
_chemical_formula_weight         2139.41
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_cell_angle_alpha                98.394(2)
_cell_angle_beta                 97.515(2)
_cell_angle_gamma                114.462(2)
_cell_formula_units_Z            1
_cell_length_a                   11.2906(4)
_cell_length_b                   12.7098(5)
_cell_length_c                   17.2980(6)
_cell_measurement_reflns_used    9832
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      34.54
_cell_measurement_theta_min      2.36
_cell_volume                     2184.27(15)
_computing_cell_refinement       'SAINT (Bruker AXS, 2009)'
_computing_data_collection       'APEX2 (Bruker AXS, 2010)'
_computing_data_reduction        'SAINT (Bruker AXS, 2009)'
_computing_molecular_graphics    'Diamond v.4.03 (Brandenburg, 2014)'
_computing_publication_material  'SHELXL-2014 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-2014 (Sheldrick, 2014)'
_diffrn_ambient_temperature      150(2)
_diffrn_detector_area_resol_mean 16
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device       '62mm x 62mm CCD camera on κ-goniostat'
_diffrn_measurement_device_type  'Bruker KAPPA APEX II DUO CCD'
_diffrn_measurement_method       'φ scans and ω scans with κ offset'
_diffrn_radiation_monochromator  'curved graphite crystal'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0439
_diffrn_reflns_av_unetI/netI     0.0198
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            226439
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         35.002
_diffrn_reflns_theta_min         1.218
_exptl_absorpt_coefficient_mu    3.766
_exptl_absorpt_correction_T_max  0.810
_exptl_absorpt_correction_T_min  0.650
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2008)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.626
_exptl_crystal_description       block
_exptl_crystal_F_000             1048
_exptl_crystal_size_max          0.117
_exptl_crystal_size_mid          0.107
_exptl_crystal_size_min          0.056
_refine_diff_density_max         1.956
_refine_diff_density_min         -0.952
_refine_diff_density_rms         0.100
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.046
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     555
_refine_ls_number_reflns         19160
_refine_ls_number_restraints     7
_refine_ls_restrained_S_all      1.048
_refine_ls_R_factor_all          0.0322
_refine_ls_R_factor_gt           0.0244
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0284P)²+1.4522P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0566
_refine_ls_wR_factor_ref         0.0591
_reflns_Friedel_coverage         0.000
_reflns_number_gt                16845
_reflns_number_total             19160
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic7b00006_si_003.cif
_cod_data_source_block           8
_cod_original_cell_volume        2184.27(14)
_cod_database_code               4345918
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.667
_shelx_estimated_absorpt_t_max   0.817
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C2 C 0.3526(2) 0.08028(18) 0.40735(12) 0.0267(3) Uani 1 1 d . . . . .
C1 C 0.4622(2) 0.21130(17) 0.56685(12) 0.0280(4) Uani 1 1 d . . . . .
C4 C 0.2392(2) 0.19688(19) 0.29289(11) 0.0271(4) Uani 1 1 d . . . . .
H4 H 0.2506 0.1268 0.2804 0.033 Uiso 1 1 calc R U . A 1
C3 C 0.27381(17) 0.25914(16) 0.37129(10) 0.0214(3) Uani 0.818(3) 1 d . . P B 1
C5 C 0.1882(2) 0.2364(2) 0.23264(12) 0.0354(5) Uani 0.818(3) 1 d . . P B 1
C7 C 0.2040(2) 0.3992(2) 0.32445(14) 0.0319(4) Uani 0.818(3) 1 d . . P B 1
C10 C 0.2996(2) 0.53588(18) 0.50174(14) 0.0310(4) Uani 0.818(3) 1 d . . P B 1
H10 H 0.2612 0.5703 0.4672 0.037 Uiso 0.818(3) 1 calc R U P B 1
C12 C 0.4041(2) 0.53867(19) 0.63077(14) 0.0331(4) Uani 0.818(3) 1 d . . P B 1
H12 H 0.4395 0.5752 0.6859 0.040 Uiso 0.818(3) 1 calc R U P B 1
N3 N 0.35962(16) 0.38061(14) 0.52138(10) 0.0225(3) Uani 0.818(3) 1 d . . P B 1
F2 F 0.1864(2) 0.49982(17) 0.33939(11) 0.0448(5) Uani 0.818(3) 1 d . . P B 1
F1 F 0.1607(2) 0.17866(19) 0.15637(10) 0.0468(5) Uani 0.818(3) 1 d . . P B 1
C3A C 0.35962(16) 0.38061(14) 0.52138(10) 0.0225(3) Uani 0.182(3) 1 d . . P B 2
C5A C 0.4041(2) 0.53867(19) 0.63077(14) 0.0331(4) Uani 0.182(3) 1 d D . P B 2
C7A C 0.2996(2) 0.53588(18) 0.50174(14) 0.0310(4) Uani 0.182(3) 1 d . . P B 2
C10A C 0.2040(2) 0.3992(2) 0.32445(14) 0.0319(4) Uani 0.182(3) 1 d . . P B 2
H10A H 0.1923 0.4693 0.3356 0.038 Uiso 0.182(3) 1 calc R U P B 2
C12A C 0.1882(2) 0.2364(2) 0.23264(12) 0.0354(5) Uani 0.182(3) 1 d . . P B 2
H12A H 0.1665 0.1929 0.1791 0.042 Uiso 0.182(3) 1 calc R U P B 2
N3A N 0.27381(17) 0.25914(16) 0.37129(10) 0.0214(3) Uani 0.182(3) 1 d . . P B 2
F1A F 0.4565(8) 0.5970(7) 0.7013(4) 0.0387(19) Uani 0.182(3) 1 d D . P B 2
F2A F 0.2394(8) 0.5764(7) 0.4430(5) 0.043(2) Uani 0.182(3) 1 d . . P B 2
C6 C 0.1673(3) 0.3362(2) 0.24699(14) 0.0388(5) Uani 1 1 d . . . . .
H6 H 0.1291 0.3604 0.2049 0.047 Uiso 1 1 calc R U . B 1
C8 C 0.25792(18) 0.36458(16) 0.38755(11) 0.0230(3) Uani 1 1 d . . . . .
C9 C 0.30465(18) 0.43057(16) 0.47113(12) 0.0235(3) Uani 1 1 d . . . . .
C11 C 0.3496(2) 0.59062(19) 0.58139(15) 0.0353(5) Uani 1 1 d . . . . .
H11 H 0.3466 0.6628 0.6021 0.042 Uiso 1 1 calc R U . B 1
C13 C 0.4070(2) 0.43355(18) 0.59970(12) 0.0277(4) Uani 1 1 d . . . . .
H13 H 0.4433 0.3977 0.6343 0.033 Uiso 1 1 calc R U . B 1
C14 C 0.07783(17) -0.36740(15) 0.20335(10) 0.0203(3) Uani 1 1 d . . . . .
C15 C 0.0342(2) -0.3210(2) 0.26566(13) 0.0307(4) Uani 1 1 d . . . . .
H15 H 0.0845 -0.2407 0.2937 0.037 Uiso 1 1 calc R U . . .
C16 C -0.0835(3) -0.3926(3) 0.28687(16) 0.0432(6) Uani 1 1 d . . . . .
H16 H -0.1140 -0.3607 0.3287 0.052 Uiso 1 1 calc R U . . .
C17 C -0.1556(2) -0.5100(2) 0.24702(16) 0.0442(6) Uani 1 1 d . . . . .
H17 H -0.2354 -0.5585 0.2618 0.053 Uiso 1 1 calc R U . . .
C18 C -0.1123(2) -0.5573(2) 0.18555(14) 0.0366(5) Uani 1 1 d . . . . .
H18 H -0.1619 -0.6381 0.1585 0.044 Uiso 1 1 calc R U . . .
C19 C 0.00376(19) -0.48629(16) 0.16364(11) 0.0255(3) Uani 1 1 d . . . . .
H19 H 0.0331 -0.5187 0.1214 0.031 Uiso 1 1 calc R U . . .
C20 C 0.16639(16) -0.21038(14) 0.09895(10) 0.0180(3) Uani 1 1 d . . . . .
C21 C 0.23460(19) -0.08992(16) 0.09966(12) 0.0257(3) Uani 1 1 d . . . . .
H21 H 0.3127 -0.0409 0.1396 0.031 Uiso 1 1 calc R U . . .
C22 C 0.1895(2) -0.04097(18) 0.04260(14) 0.0335(4) Uani 1 1 d . . . . .
H22 H 0.2372 0.0409 0.0434 0.040 Uiso 1 1 calc R U . . .
C23 C 0.0751(2) -0.1114(2) -0.01554(13) 0.0317(4) Uani 1 1 d . . . . .
H23 H 0.0445 -0.0779 -0.0546 0.038 Uiso 1 1 calc R U . . .
C24 C 0.0052(2) -0.23111(19) -0.01661(12) 0.0287(4) Uani 1 1 d . . . . .
H24 H -0.0736 -0.2793 -0.0563 0.034 Uiso 1 1 calc R U . . .
C25 C 0.05026(18) -0.28041(16) 0.04029(11) 0.0231(3) Uani 1 1 d . . . . .
H25 H 0.0019 -0.3622 0.0394 0.028 Uiso 1 1 calc R U . . .
C26 C 0.28376(18) -0.37097(15) 0.12521(11) 0.0216(3) Uani 1 1 d . . . . .
C27 C 0.2603(2) -0.40854(17) 0.04266(12) 0.0271(4) Uani 1 1 d . . . . .
H27 H 0.2135 -0.3799 0.0084 0.033 Uiso 1 1 calc R U . . .
C28 C 0.3057(2) -0.4888(2) 0.01010(15) 0.0362(5) Uani 1 1 d . . . . .
H28 H 0.2896 -0.5145 -0.0463 0.043 Uiso 1 1 calc R U . . .
C29 C 0.3737(3) -0.5305(2) 0.05934(18) 0.0432(6) Uani 1 1 d . . . . .
H29 H 0.4038 -0.5852 0.0369 0.052 Uiso 1 1 calc R U . . .
C30 C 0.3980(3) -0.4928(3) 0.14126(19) 0.0512(7) Uani 1 1 d . . . . .
H30 H 0.4450 -0.5218 0.1751 0.061 Uiso 1 1 calc R U . . .
C31 C 0.3543(3) -0.4128(2) 0.17450(15) 0.0384(5) Uani 1 1 d . . . . .
H31 H 0.3724 -0.3864 0.2309 0.046 Uiso 1 1 calc R U . . .
C32 C 0.59936(18) 0.10932(16) 0.19128(11) 0.0235(3) Uani 1 1 d . . . . .
C33 C 0.5304(2) 0.17616(17) 0.20931(13) 0.0278(4) Uani 1 1 d . . . . .
H33 H 0.5068 0.1828 0.2599 0.033 Uiso 1 1 calc R U . . .
C34 C 0.4964(2) 0.23287(19) 0.15348(14) 0.0344(4) Uani 1 1 d . . . . .
H34 H 0.4501 0.2785 0.1662 0.041 Uiso 1 1 calc R U . . .
C35 C 0.5299(2) 0.2230(2) 0.07920(15) 0.0388(5) Uani 1 1 d . . . . .
H35 H 0.5063 0.2616 0.0411 0.047 Uiso 1 1 calc R U . . .
C36 C 0.5974(3) 0.1571(2) 0.06108(14) 0.0389(5) Uani 1 1 d . . . . .
H36 H 0.6202 0.1501 0.0102 0.047 Uiso 1 1 calc R U . . .
C37 C 0.6324(2) 0.1007(2) 0.11659(13) 0.0320(4) Uani 1 1 d . . . . .
H37 H 0.6793 0.0558 0.1035 0.038 Uiso 1 1 calc R U . . .
C38 C 0.7201(3) -0.0436(2) 0.22411(19) 0.0225(5) Uani 0.793(9) 1 d . . P C 1
C39 C 0.6517(4) -0.1460(4) 0.1649(3) 0.0533(14) Uani 0.793(9) 1 d . . P C 1
H39 H 0.5585 -0.1754 0.1462 0.064 Uiso 0.793(9) 1 calc R U P C 1
C40 C 0.7188(4) -0.2065(5) 0.1326(3) 0.0640(17) Uani 0.793(9) 1 d . . P C 1
H40 H 0.6705 -0.2771 0.0923 0.077 Uiso 0.793(9) 1 calc R U P C 1
C41 C 0.8526(5) -0.1658(4) 0.1581(3) 0.0520(11) Uani 0.793(9) 1 d . . P C 1
H41 H 0.8980 -0.2069 0.1355 0.062 Uiso 0.793(9) 1 calc R U P C 1
C42 C 0.9206(4) -0.0643(4) 0.2170(4) 0.0659(16) Uani 0.793(9) 1 d . . P C 1
H42 H 1.0136 -0.0359 0.2360 0.079 Uiso 0.793(9) 1 calc R U P C 1
C43 C 0.8554(3) -0.0025(3) 0.2491(4) 0.0520(12) Uani 0.793(9) 1 d . . P C 1
H43 H 0.9046 0.0689 0.2887 0.062 Uiso 0.793(9) 1 calc R U P C 1
C38A C 0.7186(10) -0.0563(7) 0.2204(8) 0.0356(18) Uani 0.207(9) 1 d G U P C 2
C39A C 0.6523(7) -0.1794(8) 0.1996(8) 0.0356(18) Uani 0.207(9) 1 d G . P C 2
H39A H 0.5628 -0.2192 0.2051 0.043 Uiso 0.207(9) 1 calc R U P C 2
C40A C 0.7169(9) -0.2441(6) 0.1708(9) 0.0356(18) Uani 0.207(9) 1 d G . P C 2
H40A H 0.6716 -0.3282 0.1566 0.043 Uiso 0.207(9) 1 calc R U P C 2
C41A C 0.8479(9) -0.1858(8) 0.1627(9) 0.0356(18) Uani 0.207(9) 1 d G . P C 2
H41A H 0.8921 -0.2300 0.1429 0.043 Uiso 0.207(9) 1 calc R U P C 2
C42A C 0.9142(8) -0.0627(8) 0.1834(8) 0.0356(18) Uani 0.207(9) 1 d G . P C 2
H42A H 1.0037 -0.0228 0.1779 0.043 Uiso 0.207(9) 1 calc R U P C 2
C43A C 0.8495(10) 0.0020(6) 0.2123(9) 0.0356(18) Uani 0.207(9) 1 d G . P C 2
H43A H 0.8948 0.0862 0.2265 0.043 Uiso 0.207(9) 1 calc R U P C 2
C44 C 0.73364(18) 0.13845(16) 0.35158(11) 0.0232(3) Uani 1 1 d . . . . .
C45 C 0.8397(2) 0.24331(17) 0.34572(13) 0.0290(4) Uani 1 1 d . . . . .
H45 H 0.8554 0.2574 0.2947 0.035 Uiso 1 1 calc R U . . .
C46 C 0.9217(2) 0.32638(19) 0.41453(15) 0.0353(5) Uani 1 1 d . . . . .
H46 H 0.9937 0.3972 0.4105 0.042 Uiso 1 1 calc R U . . .
C47 C 0.8990(2) 0.3066(2) 0.48905(15) 0.0400(5) Uani 1 1 d . . . . .
H47 H 0.9565 0.3632 0.5359 0.048 Uiso 1 1 calc R U . . .
C48 C 0.7928(3) 0.2043(2) 0.49563(14) 0.0407(5) Uani 1 1 d . . . . .
H48 H 0.7764 0.1918 0.5468 0.049 Uiso 1 1 calc R U . . .
C49 C 0.7104(2) 0.12019(19) 0.42689(12) 0.0316(4) Uani 1 1 d . . . . .
H49 H 0.6379 0.0500 0.4313 0.038 Uiso 1 1 calc R U . . .
N2 N 0.3434(2) -0.00560(18) 0.36857(11) 0.0337(4) Uani 1 1 d . . . . .
N1 N 0.5241(2) 0.20786(18) 0.62385(12) 0.0371(4) Uani 1 1 d . . . . .
P1 P 0.22955(4) -0.26794(4) 0.17662(2) 0.01653(7) Uani 1 1 d . . . . .
P2 P 0.62248(4) 0.02447(4) 0.26388(3) 0.01982(8) Uani 1 1 d . . . . .
Ag1 Ag 0.40650(2) -0.11950(2) 0.28503(2) 0.01828(2) Uani 1 1 d . . . . .
Pt1 Pt 0.36268(2) 0.22659(2) 0.46790(2) 0.02054(2) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 C2 Pt1 176.89(18) . .
N1 C1 Pt1 176.7(2) . .
C12A C4 N3A 120.10(19) . .
C5 C4 C3 120.10(19) . .
C5 C4 H4 119.9 . .
C3 C4 H4 119.9 . .
C4 C3 C8 118.46(16) . .
C4 C3 Pt1 127.38(14) . .
C8 C3 Pt1 113.90(12) . .
F1 C5 C6 117.5(2) . .
F1 C5 C4 119.7(2) . .
C6 C5 C4 122.7(2) . .
F2 C7 C6 117.87(19) . .
F2 C7 C8 119.5(2) . .
C6 C7 C8 122.6(2) . .
C11 C10 C9 120.8(2) . .
C11 C10 H10 119.6 . .
C9 C10 H10 119.6 . .
C13 C12 C11 119.8(2) . .
C13 C12 H12 120.1 . .
C11 C12 H12 120.1 . .
C13 N3 C9 119.73(17) . .
C13 N3 Pt1 125.01(13) . .
C9 N3 Pt1 115.27(12) . .
C13 C3A C9 119.73(17) . .
C13 C3A Pt1 125.01(13) . .
C9 C3A Pt1 115.27(12) . .
F1A C5A C13 124.4(4) . .
F1A C5A C11 115.7(4) . .
C13 C5A C11 119.8(2) . .
C11 C7A C9 120.8(2) . .
C11 C7A F2A 126.1(4) . .
C9 C7A F2A 113.1(4) . .
C6 C10A C8 122.6(2) . .
C6 C10A H10A 118.7 . .
C8 C10A H10A 118.7 . .
C6 C12A C4 122.7(2) . .
C6 C12A H12A 118.6 . .
C4 C12A H12A 118.6 . .
C4 N3A C8 118.46(16) . .
C4 N3A Pt1 127.38(14) . .
C8 N3A Pt1 113.90(12) . .
C10A C6 C12A 117.19(19) . .
C7 C6 C5 117.19(19) . .
C7 C6 H6 121.4 . .
C5 C6 H6 121.4 . .
C10A C8 N3A 118.89(18) . .
C7 C8 C3 118.89(18) . .
C10A C8 C9 125.36(18) . .
C7 C8 C9 125.36(18) . .
N3A C8 C9 115.73(16) . .
C3 C8 C9 115.73(16) . .
C3A C9 C7A 119.44(18) . .
N3 C9 C10 119.44(18) . .
C3A C9 C8 114.15(16) . .
N3 C9 C8 114.15(16) . .
C7A C9 C8 126.40(18) . .
C10 C9 C8 126.40(18) . .
C10 C11 C12 118.74(19) . .
C7A C11 C5A 118.74(19) . .
C10 C11 H11 120.6 . .
C12 C11 H11 120.6 . .
C3A C13 C5A 121.51(19) . .
N3 C13 C12 121.51(19) . .
N3 C13 H13 119.2 . .
C12 C13 H13 119.2 . .
C15 C14 C19 119.26(17) . .
C15 C14 P1 117.80(14) . .
C19 C14 P1 122.94(14) . .
C14 C15 C16 120.0(2) . .
C14 C15 H15 120.0 . .
C16 C15 H15 120.0 . .
C17 C16 C15 120.1(2) . .
C17 C16 H16 120.0 . .
C15 C16 H16 120.0 . .
C16 C17 C18 120.4(2) . .
C16 C17 H17 119.8 . .
C18 C17 H17 119.8 . .
C19 C18 C17 119.9(2) . .
C19 C18 H18 120.1 . .
C17 C18 H18 120.1 . .
C18 C19 C14 120.5(2) . .
C18 C19 H19 119.8 . .
C14 C19 H19 119.8 . .
C21 C20 C25 118.60(16) . .
C21 C20 P1 118.35(13) . .
C25 C20 P1 123.02(13) . .
C22 C21 C20 120.74(17) . .
C22 C21 H21 119.6 . .
C20 C21 H21 119.6 . .
C23 C22 C21 120.09(19) . .
C23 C22 H22 120.0 . .
C21 C22 H22 120.0 . .
C22 C23 C24 119.96(18) . .
C22 C23 H23 120.0 . .
C24 C23 H23 120.0 . .
C23 C24 C25 120.07(18) . .
C23 C24 H24 120.0 . .
C25 C24 H24 120.0 . .
C24 C25 C20 120.53(17) . .
C24 C25 H25 119.7 . .
C20 C25 H25 119.7 . .
C27 C26 C31 119.25(18) . .
C27 C26 P1 124.98(15) . .
C31 C26 P1 115.77(15) . .
C26 C27 C28 119.8(2) . .
C26 C27 H27 120.1 . .
C28 C27 H27 120.1 . .
C29 C28 C27 120.3(2) . .
C29 C28 H28 119.8 . .
C27 C28 H28 119.8 . .
C28 C29 C30 120.1(2) . .
C28 C29 H29 120.0 . .
C30 C29 H29 120.0 . .
C29 C30 C31 120.3(2) . .
C29 C30 H30 119.8 . .
C31 C30 H30 119.8 . .
C30 C31 C26 120.2(2) . .
C30 C31 H31 119.9 . .
C26 C31 H31 119.9 . .
C37 C32 C33 118.67(18) . .
C37 C32 P2 124.08(16) . .
C33 C32 P2 116.84(15) . .
C34 C33 C32 120.3(2) . .
C34 C33 H33 119.9 . .
C32 C33 H33 119.9 . .
C35 C34 C33 120.3(2) . .
C35 C34 H34 119.9 . .
C33 C34 H34 119.9 . .
C36 C35 C34 119.7(2) . .
C36 C35 H35 120.2 . .
C34 C35 H35 120.2 . .
C35 C36 C37 120.5(2) . .
C35 C36 H36 119.8 . .
C37 C36 H36 119.8 . .
C36 C37 C32 120.6(2) . .
C36 C37 H37 119.7 . .
C32 C37 H37 119.7 . .
C43 C38 C39 118.3(3) . .
C43 C38 P2 125.0(2) . .
C39 C38 P2 116.6(2) . .
C38 C39 C40 120.4(3) . .
C38 C39 H39 119.8 . .
C40 C39 H39 119.8 . .
C41 C40 C39 121.0(3) . .
C41 C40 H40 119.5 . .
C39 C40 H40 119.5 . .
C40 C41 C42 118.7(3) . .
C40 C41 H41 120.6 . .
C42 C41 H41 120.6 . .
C41 C42 C43 121.0(4) . .
C41 C42 H42 119.5 . .
C43 C42 H42 119.5 . .
C38 C43 C42 120.6(3) . .
C38 C43 H43 119.7 . .
C42 C43 H43 119.7 . .
C39A C38A C43A 120.0 . .
C39A C38A P2 116.6(5) . .
C43A C38A P2 123.3(5) . .
C40A C39A C38A 120.0 . .
C40A C39A H39A 120.0 . .
C38A C39A H39A 120.0 . .
C41A C40A C39A 120.0 . .
C41A C40A H40A 120.0 . .
C39A C40A H40A 120.0 . .
C40A C41A C42A 120.0 . .
C40A C41A H41A 120.0 . .
C42A C41A H41A 120.0 . .
C43A C42A C41A 120.0 . .
C43A C42A H42A 120.0 . .
C41A C42A H42A 120.0 . .
C42A C43A C38A 120.0 . .
C42A C43A H43A 120.0 . .
C38A C43A H43A 120.0 . .
C49 C44 C45 119.36(18) . .
C49 C44 P2 118.18(14) . .
C45 C44 P2 122.45(15) . .
C46 C45 C44 119.9(2) . .
C46 C45 H45 120.0 . .
C44 C45 H45 120.0 . .
C47 C46 C45 120.3(2) . .
C47 C46 H46 119.9 . .
C45 C46 H46 119.9 . .
C46 C47 C48 120.4(2) . .
C46 C47 H47 119.8 . .
C48 C47 H47 119.8 . .
C47 C48 C49 119.7(2) . .
C47 C48 H48 120.1 . .
C49 C48 H48 120.2 . .
C48 C49 C44 120.3(2) . .
C48 C49 H49 119.8 . .
C44 C49 H49 119.8 . .
C2 N2 Ag1 156.33(18) . .
C1 N1 Ag1 156.23(18) . 2_656
C20 P1 C14 102.76(8) . .
C20 P1 C26 105.83(8) . .
C14 P1 C26 102.53(8) . .
C20 P1 Ag1 115.60(5) . .
C14 P1 Ag1 117.29(6) . .
C26 P1 Ag1 111.38(6) . .
C38 P2 C44 105.77(12) . .
C38 P2 C32 104.67(12) . .
C44 P2 C32 103.67(8) . .
C44 P2 C38A 108.1(4) . .
C32 P2 C38A 105.8(4) . .
C38 P2 Ag1 113.77(9) . .
C44 P2 Ag1 116.07(6) . .
C32 P2 Ag1 111.78(6) . .
C38A P2 Ag1 110.8(3) . .
N2 Ag1 N1 98.83(7) . 2_656
N2 Ag1 P1 115.35(5) . .
N1 Ag1 P1 110.81(5) 2_656 .
N2 Ag1 P2 103.72(5) . .
N1 Ag1 P2 101.39(6) 2_656 .
P1 Ag1 P2 123.262(15) . .
C2 Pt1 C1 91.32(8) . .
C2 Pt1 N3A 93.06(7) . .
C1 Pt1 N3A 174.43(8) . .
C2 Pt1 C3 93.06(7) . .
C1 Pt1 C3 174.43(8) . .
C2 Pt1 N3 173.86(7) . .
C1 Pt1 N3 94.74(7) . .
C3 Pt1 N3 80.94(7) . .
C2 Pt1 C3A 173.86(7) . .
C1 Pt1 C3A 94.74(7) . .
N3A Pt1 C3A 80.94(7) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C2 N2 1.152(3) .
C2 Pt1 1.947(2) .
C1 N1 1.149(3) .
C1 Pt1 2.001(2) .
C4 C12A 1.381(3) .
C4 C5 1.381(3) .
C4 N3A 1.382(2) .
C4 C3 1.382(2) .
C4 H4 0.9500 .
C3 C8 1.418(3) .
C3 Pt1 2.0194(17) .
C5 F1 1.341(3) .
C5 C6 1.378(3) .
C7 F2 1.367(3) .
C7 C6 1.369(3) .
C7 C8 1.394(3) .
C10 C11 1.376(3) .
C10 C9 1.393(3) .
C10 H10 0.9500 .
C12 C13 1.381(3) .
C12 C11 1.382(3) .
C12 H12 0.9500 .
N3 C13 1.349(2) .
N3 C9 1.375(2) .
N3 Pt1 2.0554(16) .
C3A C13 1.349(2) .
C3A C9 1.375(2) .
C3A Pt1 2.0554(16) .
C5A F1A 1.253(6) .
C5A C13 1.381(3) .
C5A C11 1.382(3) .
C7A C11 1.376(3) .
C7A C9 1.393(3) .
C7A F2A 1.423(8) .
C10A C6 1.369(3) .
C10A C8 1.394(3) .
C10A H10A 0.9500 .
C12A C6 1.378(3) .
C12A H12A 0.9500 .
N3A C8 1.418(3) .
N3A Pt1 2.0194(17) .
C6 H6 0.9500 .
C8 C9 1.467(3) .
C11 H11 0.9500 .
C13 H13 0.9500 .
C14 C15 1.395(3) .
C14 C19 1.398(2) .
C14 P1 1.8251(17) .
C15 C16 1.398(3) .
C15 H15 0.9500 .
C16 C17 1.382(4) .
C16 H16 0.9500 .
C17 C18 1.388(4) .
C17 H17 0.9500 .
C18 C19 1.387(3) .
C18 H18 0.9500 .
C19 H19 0.9500 .
C20 C21 1.397(2) .
C20 C25 1.401(2) .
C20 P1 1.8212(17) .
C21 C22 1.389(3) .
C21 H21 0.9500 .
C22 C23 1.386(3) .
C22 H22 0.9500 .
C23 C24 1.389(3) .
C23 H23 0.9500 .
C24 C25 1.391(3) .
C24 H24 0.9500 .
C25 H25 0.9500 .
C26 C27 1.391(3) .
C26 C31 1.396(3) .
C26 P1 1.8293(18) .
C27 C28 1.401(3) .
C27 H27 0.9500 .
C28 C29 1.375(4) .
C28 H28 0.9500 .
C29 C30 1.380(4) .
C29 H29 0.9500 .
C30 C31 1.389(3) .
C30 H30 0.9500 .
C31 H31 0.9500 .
C32 C37 1.393(3) .
C32 C33 1.399(3) .
C32 P2 1.8306(19) .
C33 C34 1.391(3) .
C33 H33 0.9500 .
C34 C35 1.389(4) .
C34 H34 0.9500 .
C35 C36 1.377(4) .
C35 H35 0.9500 .
C36 C37 1.389(3) .
C36 H36 0.9500 .
C37 H37 0.9500 .
C38 C43 1.376(4) .
C38 C39 1.382(4) .
C38 P2 1.803(3) .
C39 C40 1.394(5) .
C39 H39 0.9500 .
C40 C41 1.362(6) .
C40 H40 0.9500 .
C41 C42 1.372(6) .
C41 H41 0.9500 .
C42 C43 1.388(5) .
C42 H42 0.9500 .
C43 H43 0.9500 .
C38A C39A 1.3900 .
C38A C43A 1.3900 .
C38A P2 1.926(6) .
C39A C40A 1.3900 .
C39A H39A 0.9500 .
C40A C41A 1.3900 .
C40A H40A 0.9500 .
C41A C42A 1.3900 .
C41A H41A 0.9500 .
C42A C43A 1.3900 .
C42A H42A 0.9500 .
C43A H43A 0.9500 .
C44 C49 1.395(3) .
C44 C45 1.404(3) .
C44 P2 1.8248(18) .
C45 C46 1.387(3) .
C45 H45 0.9500 .
C46 C47 1.385(4) .
C46 H46 0.9500 .
C47 C48 1.388(4) .
C47 H47 0.9500 .
C48 C49 1.392(3) .
C48 H48 0.9500 .
C49 H49 0.9500 .
N2 Ag1 2.2814(18) .
N1 Ag1 2.2983(18) 2_656
P1 Ag1 2.4358(4) .
P2 Ag1 2.4824(5) .
Ag1 N1 2.2982(18) 2_656
