#------------------------------------------------------------------------------
#$Date: 2018-01-16 10:32:00 +0200 (Tue, 16 Jan 2018) $
#$Revision: 205244 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/59/4345983.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4345983
loop_
_publ_author_name
'Sylvia Eller'
'Barbara Trettenbrein'
'Dennis Oberhuber'
'Christof Strabler'
'Rene Gutmann'
'Wytze E. van der Veer'
'Markus Ruetz'
'Holger Kopacka'
'Dagmar Obendorf'
'Peter Bruggeller'
_publ_section_title
;
 Oxidative quenching within photosensitizer-acceptor dyads based on
 bis(bidentate) phosphine-connected osmium(II) bipyridyl light absorbers
 and reactive metal sites
;
_journal_name_full               'Inorganic Chemistry Communications'
_journal_page_first              41
_journal_page_last               45
_journal_paper_doi               10.1016/j.inoche.2012.06.001
_journal_volume                  23
_journal_year                    2012
_chemical_formula_moiety         'C72 H60 Cl2 N4 Os P4 Pt, 2(F6 Sb)'
_chemical_formula_sum            'C72 H60 Cl2 F12 N4 Os P4 Pt Sb2'
_chemical_formula_weight         2032.85
_chemical_name_systematic        '[Os(bpy)2(dppcb)PtCl2](SbF6)2'
_space_group_IT_number           13
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yc'
_symmetry_space_group_name_H-M   'P 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 117.9798(6)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   25.3679(3)
_cell_length_b                   13.5811(2)
_cell_length_c                   26.1203(3)
_cell_measurement_reflns_used    262911
_cell_measurement_temperature    243(2)
_cell_measurement_theta_max      27.485
_cell_measurement_theta_min      0.998
_cell_volume                     7947.20(18)
_computing_cell_refinement       'Denzo and Scalepack'
_computing_data_collection       'Kappa CCD'
_computing_data_reduction        'Denzo and Scalepack'
_computing_molecular_graphics    'SHELXTL-NT V6.1'
_computing_publication_material  'SHELXTL-NT V6.1'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      243(2)
_diffrn_measured_fraction_theta_full 1.00
_diffrn_measurement_device_type  'Kappa CCD'
_diffrn_measurement_method       'phi- and omega-scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0199
_diffrn_reflns_av_sigmaI/netI    0.0631
_diffrn_reflns_limit_h_max       33
_diffrn_reflns_limit_h_min       -33
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_number            35750
_diffrn_reflns_theta_full        28.37
_diffrn_reflns_theta_max         28.37
_diffrn_reflns_theta_min         1.75
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  120
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    4.238
_exptl_absorpt_correction_T_max  0.665
_exptl_absorpt_correction_T_min  0.620
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Otwinowski et al, 1997'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.699
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             3912
_exptl_crystal_size_max          0.17
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.330
_refine_diff_density_min         -0.960
_refine_diff_density_rms         0.100
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.030
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     916
_refine_ls_number_reflns         17959
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.030
_refine_ls_R_factor_all          0.0924
_refine_ls_R_factor_gt           0.0469
_refine_ls_shift/su_max          0.015
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0512P)²+3.0939P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1160
_refine_ls_wR_factor_ref         0.1933
_reflns_number_gt                12050
_reflns_number_total             19916
_reflns_threshold_expression     >3sigma(I)
_cod_data_source_file            Inor-Chem-Comm-2012-23-41-45-1.cif
_cod_data_source_block           1
_cod_original_sg_symbol_H-M      'P 2/c'
_cod_database_code               4345983
_diffrn_measured_fraction        0.982
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Os1 Os 0.226931(19) 0.38359(3) 0.52367(2) 0.04922(13) Uani 1 1 d . . .
Pt1 Pt 0.32784(2) -0.12543(3) 0.54577(3) 0.07122(19) Uani 1 1 d . . .
Cl1 Cl 0.3961(2) -0.2020(3) 0.5239(3) 0.153(3) Uani 1 1 d . . .
Cl2 Cl 0.32741(17) -0.2648(2) 0.59941(19) 0.0897(11) Uani 1 1 d . . .
P1 P 0.23741(12) 0.25913(19) 0.58987(13) 0.0503(7) Uani 1 1 d . . .
P2 P 0.30832(15) 0.3141(2) 0.52514(19) 0.0749(11) Uani 1 1 d . . .
P3 P 0.32130(17) 0.0028(2) 0.4893(2) 0.0822(12) Uani 1 1 d . . .
P4 P 0.26003(12) -0.05820(19) 0.56243(14) 0.0506(7) Uani 1 1 d . . .
N1 N 0.1525(4) 0.4594(7) 0.5168(5) 0.059(2) Uani 1 1 d . . .
N2 N 0.2605(5) 0.4811(7) 0.5957(4) 0.065(3) Uani 1 1 d . . .
N3 N 0.2228(4) 0.4923(6) 0.4629(4) 0.058(2) Uani 1 1 d . . .
N4 N 0.1728(4) 0.3185(7) 0.4415(4) 0.056(2) Uani 1 1 d . . .
C1 C 0.2833(5) 0.1573(7) 0.5861(5) 0.057(3) Uani 1 1 d . . .
H1 H 0.3110 0.1305 0.6248 0.068 Uiso 1 1 calc R . .
C2 C 0.3156(6) 0.1836(8) 0.5496(7) 0.074(4) Uani 1 1 d . . .
H2 H 0.3583 0.1653 0.5712 0.089 Uiso 1 1 calc R . .
C3 C 0.2804(5) 0.1032(7) 0.5030(6) 0.066(3) Uani 1 1 d . . .
H3 H 0.2512 0.1339 0.4662 0.080 Uiso 1 1 calc R . .
C4 C 0.2505(5) 0.0740(7) 0.5398(5) 0.049(2) Uani 1 1 d . . .
H4 H 0.2073 0.0895 0.5183 0.059 Uiso 1 1 calc R . .
C11 C 0.2753(6) 0.2941(8) 0.6701(5) 0.062(3) Uani 1 1 d . . .
C12 C 0.2430(7) 0.3483(9) 0.6914(6) 0.070(3) Uani 1 1 d . . .
H12 H 0.2028 0.3630 0.6662 0.084 Uiso 1 1 calc R . .
C13 C 0.2677(10) 0.3815(12) 0.7484(8) 0.100(5) Uani 1 1 d . . .
H13 H 0.2449 0.4198 0.7607 0.120 Uiso 1 1 calc R . .
C14 C 0.3232(13) 0.3591(17) 0.7850(8) 0.123(7) Uani 1 1 d . . .
H14 H 0.3399 0.3805 0.8237 0.148 Uiso 1 1 calc R . .
C15 C 0.3559(8) 0.3058(15) 0.7671(10) 0.124(8) Uani 1 1 d . . .
H15 H 0.3954 0.2896 0.7939 0.149 Uiso 1 1 calc R . .
C16 C 0.3322(6) 0.2721(10) 0.7075(6) 0.087(4) Uani 1 1 d . . .
H16 H 0.3561 0.2359 0.6954 0.104 Uiso 1 1 calc R . .
C21 C 0.1761(4) 0.1948(7) 0.5905(5) 0.046(2) Uani 1 1 d . . .
C22 C 0.1853(5) 0.1263(8) 0.6337(5) 0.055(3) Uani 1 1 d . . .
H22 H 0.2246 0.1123 0.6619 0.066 Uiso 1 1 calc R . .
C23 C 0.1401(5) 0.0796(9) 0.6366(5) 0.062(3) Uani 1 1 d . . .
H23 H 0.1470 0.0345 0.6664 0.075 Uiso 1 1 calc R . .
C24 C 0.0838(6) 0.1003(9) 0.5944(6) 0.070(3) Uani 1 1 d . . .
H24 H 0.0512 0.0673 0.5944 0.084 Uiso 1 1 calc R . .
C25 C 0.0734(5) 0.1691(10) 0.5514(6) 0.067(3) Uani 1 1 d . . .
H25 H 0.0340 0.1829 0.5233 0.081 Uiso 1 1 calc R . .
C26 C 0.1192(5) 0.2164(8) 0.5494(5) 0.056(3) Uani 1 1 d . . .
H26 H 0.1122 0.2633 0.5204 0.067 Uiso 1 1 calc R . .
C31 C 0.3769(6) 0.3727(10) 0.5752(10) 0.117(7) Uani 1 1 d . . .
C32 C 0.4211(9) 0.3314(15) 0.6247(15) 0.192(19) Uani 1 1 d . . .
H32 H 0.4170 0.2655 0.6332 0.230 Uiso 1 1 calc R . .
C33 C 0.4710(11) 0.383(2) 0.662(2) 0.238(4) Uani 1 1 d . . .
H33 H 0.5013 0.3557 0.6967 0.286 Uiso 1 1 calc R . .
C34 C 0.4724(11) 0.4837(19) 0.644(2) 0.235(3) Uani 1 1 d . . .
H34 H 0.5069 0.5208 0.6668 0.282 Uiso 1 1 calc R . .
C35 C 0.4298(9) 0.5276(14) 0.5984(14) 0.196(14) Uani 1 1 d . . .
H35 H 0.4329 0.5941 0.5903 0.235 Uiso 1 1 calc R . .
C36 C 0.3818(7) 0.4736(10) 0.5638(9) 0.111(6) Uani 1 1 d . . .
H36 H 0.3506 0.5034 0.5312 0.134 Uiso 1 1 calc R . .
C41 C 0.3096(11) 0.3102(10) 0.4525(12) 0.152(8) Uani 1 1 d . . .
C42 C 0.2664(12) 0.2716(14) 0.4028(9) 0.164(8) Uani 1 1 d . . .
H42 H 0.2338 0.2410 0.4041 0.197 Uiso 1 1 calc R . .
C43 C 0.2670(16) 0.2744(14) 0.3495(13) 0.203(16) Uani 1 1 d . . .
H43 H 0.2358 0.2462 0.3162 0.244 Uiso 1 1 calc R . .
C44 C 0.313(3) 0.318(2) 0.347(2) 0.21(3) Uani 1 1 d . . .
H44 H 0.3139 0.3250 0.3114 0.252 Uiso 1 1 calc R . .
C45 C 0.362(3) 0.355(2) 0.400(3) 0.21(4) Uani 1 1 d . . .
H45 H 0.3962 0.3813 0.4000 0.252 Uiso 1 1 calc R . .
C46 C 0.3592(15) 0.3517(14) 0.4513(17) 0.17(17) Uani 1 1 d . . .
H46 H 0.3905 0.3774 0.4854 0.204 Uiso 1 1 calc R . .
C51 C 0.2760(11) -0.0316(11) 0.4100(9) 0.112(7) Uani 1 1 d . . .
C52 C 0.3043(13) -0.0859(12) 0.3827(12) 0.141(9) Uani 1 1 d . . .
H52 H 0.3460 -0.0940 0.4022 0.169 Uiso 1 1 calc R . .
C53 C 0.272(2) -0.1261(19) 0.3291(17) 0.176(17) Uani 1 1 d . . .
H53 H 0.2908 -0.1654 0.3125 0.211 Uiso 1 1 calc R . .
C54 C 0.213(2) -0.108(2) 0.3006(13) 0.196(19) Uani 1 1 d . . .
H54 H 0.1910 -0.1340 0.2631 0.235 Uiso 1 1 calc R . .
C55 C 0.1839(15) -0.053(2) 0.3236(12) 0.187(12) Uani 1 1 d . . .
H55 H 0.1431 -0.0388 0.3015 0.224 Uiso 1 1 calc R . .
C56 C 0.2160(11) -0.0205(18) 0.3805(10) 0.135(8) Uani 1 1 d . . .
H56 H 0.1958 0.0099 0.3986 0.162 Uiso 1 1 calc R . .
C61 C 0.3897(9) 0.0548(9) 0.5001(11) 0.115(7) Uani 1 1 d . . .
C62 C 0.4365(8) 0.0461(14) 0.5539(14) 0.153(11) Uani 1 1 d . . .
H62 H 0.4327 0.0113 0.5831 0.183 Uiso 1 1 calc R . .
C63 C 0.4904(11) 0.0898(16) 0.5650(18) 0.204(16) Uani 1 1 d . . .
H63 H 0.5240 0.0904 0.6018 0.244 Uiso 1 1 calc R . .
C64 C 0.4898(19) 0.134(3) 0.515(3) 0.24(4) Uani 1 1 d . . .
H64 H 0.5263 0.1600 0.5200 0.288 Uiso 1 1 calc R . .
C65 C 0.444(2) 0.143(3) 0.462(3) 0.24(3) Uani 1 1 d . . .
H65 H 0.4489 0.1755 0.4326 0.284 Uiso 1 1 calc R . .
C66 C 0.3911(11) 0.1039(11) 0.4508(13) 0.158(11) Uani 1 1 d . . .
H66 H 0.3574 0.1079 0.4142 0.189 Uiso 1 1 calc R . .
C71 C 0.1879(5) -0.1061(7) 0.5144(5) 0.055(3) Uani 1 1 d . . .
C72 C 0.1375(5) -0.0606(12) 0.5073(6) 0.075(4) Uani 1 1 d . . .
H72 H 0.1403 -0.0053 0.5301 0.090 Uiso 1 1 calc R . .
C73 C 0.0834(6) -0.0931(12) 0.4682(7) 0.088(4) Uani 1 1 d . . .
H73 H 0.0488 -0.0587 0.4622 0.105 Uiso 1 1 calc R . .
C74 C 0.0790(6) -0.1774(13) 0.4369(8) 0.103(5) Uani 1 1 d . . .
H74 H 0.0410 -0.2021 0.4114 0.123 Uiso 1 1 calc R . .
C75 C 0.1264(7) -0.2242(12) 0.4416(8) 0.103(5) Uani 1 1 d . . .
H75 H 0.1228 -0.2796 0.4186 0.124 Uiso 1 1 calc R . .
C76 C 0.1812(6) -0.1898(10) 0.4810(7) 0.084(4) Uani 1 1 d . . .
H76 H 0.2155 -0.2237 0.4857 0.101 Uiso 1 1 calc R . .
C81 C 0.2727(5) -0.0692(7) 0.6386(5) 0.055(3) Uani 1 1 d . . .
C82 C 0.2318(5) -0.1102(8) 0.6517(5) 0.060(3) Uani 1 1 d . . .
H82 H 0.1953 -0.1320 0.6214 0.072 Uiso 1 1 calc R . .
C83 C 0.2428(6) -0.1212(9) 0.7104(6) 0.073(4) Uani 1 1 d . . .
H83 H 0.2134 -0.1503 0.7178 0.088 Uiso 1 1 calc R . .
C84 C 0.2944(9) -0.0906(11) 0.7552(7) 0.096(5) Uani 1 1 d . . .
H84 H 0.3011 -0.0949 0.7938 0.115 Uiso 1 1 calc R . .
C85 C 0.3374(7) -0.0521(12) 0.7413(8) 0.105(6) Uani 1 1 d . . .
H85 H 0.3743 -0.0312 0.7714 0.126 Uiso 1 1 calc R . .
C86 C 0.3270(6) -0.0437(9) 0.6831(6) 0.075(4) Uani 1 1 d . . .
H86 H 0.3575 -0.0207 0.6753 0.090 Uiso 1 1 calc R . .
C1A C 0.0981(7) 0.4464(10) 0.4734(7) 0.080(4) Uani 1 1 d . . .
H1AA H 0.0910 0.3937 0.4477 0.096 Uiso 1 1 calc R . .
C2A C 0.0523(7) 0.5068(11) 0.4651(8) 0.099(5) Uani 1 1 d . . .
H2AA H 0.0137 0.4955 0.4347 0.119 Uiso 1 1 calc R . .
C3A C 0.0638(10) 0.5858(13) 0.5023(11) 0.120(7) Uani 1 1 d . . .
H3AA H 0.0326 0.6292 0.4967 0.144 Uiso 1 1 calc R . .
C4A C 0.1185(9) 0.6014(11) 0.5463(9) 0.103(5) Uani 1 1 d . . .
H4AA H 0.1262 0.6553 0.5713 0.124 Uiso 1 1 calc R . .
C5A C 0.1635(7) 0.5360(9) 0.5538(7) 0.072(4) Uani 1 1 d . . .
C1B C 0.3160(7) 0.4818(11) 0.6420(7) 0.095(5) Uani 1 1 d . . .
H1BA H 0.3442 0.4366 0.6424 0.114 Uiso 1 1 calc R . .
C2B C 0.3336(11) 0.5462(16) 0.6893(9) 0.133(9) Uani 1 1 d . . .
H2BA H 0.3727 0.5436 0.7202 0.160 Uiso 1 1 calc R . .
C3B C 0.2938(15) 0.6121(16) 0.6900(10) 0.140(10) Uani 1 1 d . . .
H3BA H 0.3051 0.6576 0.7205 0.168 Uiso 1 1 calc R . .
C4B C 0.2385(10) 0.6109(10) 0.6468(8) 0.101(6) Uani 1 1 d . . .
H4BA H 0.2100 0.6541 0.6474 0.121 Uiso 1 1 calc R . .
C5B C 0.2220(8) 0.5457(9) 0.5997(6) 0.079(4) Uani 1 1 d . . .
C1C C 0.2515(7) 0.5775(10) 0.4749(7) 0.079(4) Uani 1 1 d . . .
H1CA H 0.2731 0.5962 0.5140 0.095 Uiso 1 1 calc R . .
C2C C 0.2516(8) 0.6416(10) 0.4328(8) 0.091(5) Uani 1 1 d . . .
H2CA H 0.2737 0.7004 0.4442 0.109 Uiso 1 1 calc R . .
C3C C 0.2196(11) 0.6187(12) 0.3752(10) 0.121(8) Uani 1 1 d . . .
H3CA H 0.2203 0.6607 0.3469 0.146 Uiso 1 1 calc R . .
C4C C 0.1861(9) 0.5326(13) 0.3590(7) 0.105(5) Uani 1 1 d . . .
H4CA H 0.1623 0.5162 0.3197 0.126 Uiso 1 1 calc R . .
C5C C 0.1895(7) 0.4711(9) 0.4036(7) 0.076(4) Uani 1 1 d . . .
C1D C 0.1459(5) 0.2299(9) 0.4316(5) 0.059(3) Uani 1 1 d . . .
H1DA H 0.1532 0.1906 0.4638 0.071 Uiso 1 1 calc R . .
C2D C 0.1093(6) 0.1941(12) 0.3786(6) 0.079(4) Uani 1 1 d . . .
H2DA H 0.0935 0.1303 0.3747 0.095 Uiso 1 1 calc R . .
C3D C 0.0945(8) 0.2518(16) 0.3287(8) 0.108(5) Uani 1 1 d . . .
H3DA H 0.0681 0.2276 0.2917 0.129 Uiso 1 1 calc R . .
C4D C 0.1192(8) 0.3432(17) 0.3352(7) 0.109(6) Uani 1 1 d . . .
H4DA H 0.1100 0.3833 0.3027 0.131 Uiso 1 1 calc R . .
C5D C 0.1594(7) 0.3772(11) 0.3924(6) 0.079(4) Uani 1 1 d . . .
Sb1 Sb 0.05913(5) 0.79062(8) 0.64309(5) 0.0856(3) Uani 1 1 d . . .
F1 F 0.1059(6) 0.8800(10) 0.7006(6) 0.167(5) Uani 1 1 d . . .
F2 F 0.0037(5) 0.8891(8) 0.6083(6) 0.148(4) Uani 1 1 d . . .
F3 F 0.0270(5) 0.7489(12) 0.6895(4) 0.165(6) Uani 1 1 d . . .
F4 F 0.0102(5) 0.7066(8) 0.5835(4) 0.134(4) Uani 1 1 d . . .
F5 F 0.0923(5) 0.8271(10) 0.5954(5) 0.150(5) Uani 1 1 d . . .
F6 F 0.1160(6) 0.6985(11) 0.6759(7) 0.190(6) Uani 1 1 d . . .
Sb2 Sb 0.5000 0.09413(13) 0.7500 0.1747(17) Uani 1 2 d SP . .
F7 F 0.4725(7) 0.1886(17) 0.7781(14) 0.45(3) Uani 1 1 d . . .
F8 F 0.4288(4) 0.0965(8) 0.6788(7) 0.186(7) Uani 1 1 d . . .
F9 F 0.5260(6) -0.0052(15) 0.7218(9) 0.257(10) Uani 1 1 d . . .
Sb3 Sb 0.0651(2) 0.3624(4) 0.7035(2) 0.237(3) Uani 0.50 1 d P . .
F10 F 0.051(4) 0.367(5) 0.636(2) 0.69(11) Uani 0.50 1 d P . .
F11 F 0.059(2) 0.481(2) 0.7136(19) 0.28(2) Uani 0.50 1 d P . .
F12 F 0.0120(10) 0.3810(12) 0.7339(10) 0.119(11) Uani 0.50 1 d P . .
F13 F 0.067(4) 0.325(5) 0.784(3) 0.75(10) Uani 0.50 1 d P . .
F14 F 0.052(3) 0.214(8) 0.695(4) 0.76(11) Uani 0.50 1 d P . .
F15 F 0.1388(15) 0.373(11) 0.7298(18) 0.76(13) Uani 0.50 1 d P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Os Os -1.2165 7.6030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Os1 N4 89.3(4) . .
N1 Os1 N2 74.8(4) . .
N4 Os1 N2 162.7(4) . .
N1 Os1 N3 82.4(3) . .
N4 Os1 N3 75.7(4) . .
N2 Os1 N3 95.0(4) . .
N1 Os1 P2 173.9(3) . .
N4 Os1 P2 89.8(3) . .
N2 Os1 P2 105.2(3) . .
N3 Os1 P2 91.6(2) . .
N1 Os1 P1 101.8(3) . .
N4 Os1 P1 104.0(3) . .
N2 Os1 P1 86.4(3) . .
N3 Os1 P1 175.8(2) . .
P2 Os1 P1 84.24(11) . .
P4 Pt1 P3 89.08(11) . .
P4 Pt1 Cl1 176.84(19) . .
P3 Pt1 Cl1 91.14(14) . .
P4 Pt1 Cl2 89.63(12) . .
P3 Pt1 Cl2 175.48(16) . .
Cl1 Pt1 Cl2 89.91(14) . .
C21 P1 C1 102.0(4) . .
C21 P1 C11 95.9(5) . .
C1 P1 C11 103.9(6) . .
C21 P1 Os1 124.1(4) . .
C1 P1 Os1 111.0(4) . .
C11 P1 Os1 117.0(3) . .
C31 P2 C2 105.4(7) . .
C31 P2 C41 105.8(10) . .
C2 P2 C41 105.5(6) . .
C31 P2 Os1 113.2(6) . .
C2 P2 Os1 110.3(4) . .
C41 P2 Os1 115.9(6) . .
C61 P3 C3 105.8(6) . .
C61 P3 C51 108.6(10) . .
C3 P3 C51 106.7(8) . .
C61 P3 Pt1 116.2(7) . .
C3 P3 Pt1 108.8(4) . .
C51 P3 Pt1 110.3(5) . .
C71 P4 C81 109.1(5) . .
C71 P4 C4 100.9(5) . .
C81 P4 C4 110.2(5) . .
C71 P4 Pt1 110.7(4) . .
C81 P4 Pt1 115.1(4) . .
C4 P4 Pt1 109.8(3) . .
C1A N1 C5A 119.6(11) . .
C1A N1 Os1 123.2(9) . .
C5A N1 Os1 116.3(9) . .
C5B N2 C1B 114.2(13) . .
C5B N2 Os1 118.0(9) . .
C1B N2 Os1 127.6(11) . .
C1C N3 C5C 114.8(11) . .
C1C N3 Os1 126.8(10) . .
C5C N3 Os1 118.2(8) . .
C1D N4 C5D 116.5(11) . .
C1D N4 Os1 126.5(8) . .
C5D N4 Os1 116.7(9) . .
C2 C1 C4 86.3(9) . .
C2 C1 P1 112.8(7) . .
C4 C1 P1 117.3(7) . .
C2 C1 H1 112.6 . .
C4 C1 H1 112.6 . .
P1 C1 H1 112.6 . .
C1 C2 C3 92.5(8) . .
C1 C2 P2 115.5(8) . .
C3 C2 P2 118.0(9) . .
C1 C2 H2 109.9 . .
C3 C2 H2 109.9 . .
P2 C2 H2 109.9 . .
C4 C3 C2 87.9(9) . .
C4 C3 P3 114.8(7) . .
C2 C3 P3 119.9(8) . .
C4 C3 H3 110.8 . .
C2 C3 H3 110.8 . .
P3 C3 H3 110.8 . .
C3 C4 C1 93.2(8) . .
C3 C4 P4 114.7(7) . .
C1 C4 P4 120.2(7) . .
C3 C4 H4 109.2 . .
C1 C4 H4 109.2 . .
P4 C4 H4 109.2 . .
C16 C11 C12 117.4(13) . .
C16 C11 P1 123.8(12) . .
C12 C11 P1 118.7(10) . .
C13 C12 C11 122.8(15) . .
C13 C12 H12 118.6 . .
C11 C12 H12 118.6 . .
C14 C13 C12 119.7(19) . .
C14 C13 H13 120.1 . .
C12 C13 H13 120.2 . .
C13 C14 C15 120(2) . .
C13 C14 H14 120.1 . .
C15 C14 H14 120.0 . .
C14 C15 C16 122.1(17) . .
C14 C15 H15 119.0 . .
C16 C15 H15 119.0 . .
C11 C16 C15 118.0(17) . .
C11 C16 H16 121.0 . .
C15 C16 H16 121.0 . .
C26 C21 C22 119.6(10) . .
C26 C21 P1 119.3(8) . .
C22 C21 P1 121.1(8) . .
C23 C22 C21 122.5(11) . .
C23 C22 H22 118.8 . .
C21 C22 H22 118.8 . .
C22 C23 C24 117.1(11) . .
C22 C23 H23 121.4 . .
C24 C23 H23 121.5 . .
C23 C24 C25 121.5(11) . .
C23 C24 H24 119.2 . .
C25 C24 H24 119.2 . .
C26 C25 C24 120.7(11) . .
C26 C25 H25 119.6 . .
C24 C25 H25 119.6 . .
C25 C26 C21 118.5(11) . .
C25 C26 H26 120.7 . .
C21 C26 H26 120.7 . .
C32 C31 C36 118.6(17) . .
C32 C31 P2 126.0(12) . .
C36 C31 P2 115.1(13) . .
C31 C32 C33 123(2) . .
C31 C32 H32 118.8 . .
C33 C32 H32 118.7 . .
C32 C33 C34 113(3) . .
C32 C33 H33 123.2 . .
C34 C33 H33 123.3 . .
C35 C34 C33 126(2) . .
C35 C34 H34 117.0 . .
C33 C34 H34 117.0 . .
C34 C35 C36 117.5(18) . .
C34 C35 H35 121.3 . .
C36 C35 H35 121.3 . .
C35 C36 C31 121.8(17) . .
C35 C36 H36 119.1 . .
C31 C36 H36 119.1 . .
C42 C41 C46 118(2) . .
C42 C41 P2 125.4(14) . .
C46 C41 P2 117(2) . .
C41 C42 C43 124(3) . .
C41 C42 H42 117.9 . .
C43 C42 H42 117.9 . .
C44 C43 C42 119(3) . .
C44 C43 H43 120.7 . .
C42 C43 H43 120.7 . .
C43 C44 C45 118(3) . .
C43 C44 H44 120.9 . .
C45 C44 H44 120.8 . .
C46 C45 C44 121(3) . .
C46 C45 H45 119.6 . .
C44 C45 H45 121.00 . .
C45 C46 C41 120(4) . .
C45 C46 H46 120.1 . .
C41 C46 H46 120.1 . .
C56 C51 C52 118(2) . .
C56 C51 P3 122.5(15) . .
C52 C51 P3 119(2) . .
C53 C52 C51 122(3) . .
C53 C52 H52 119.2 . .
C51 C52 H52 119.3 . .
C54 C53 C52 118(3) . .
C54 C53 H53 121.0 . .
C52 C53 H53 121.0 . .
C53 C54 C55 123(3) . .
C53 C54 H54 118.5 . .
C55 C54 H54 118.4 . .
C54 C55 C56 118(3) . .
C54 C55 H55 120.8 . .
C56 C55 H55 120.8 . .
C51 C56 C55 121(2) . .
C51 C56 H56 119.6 . .
C55 C56 H56 119.6 . .
C62 C61 C66 125.4(18) . .
C62 C61 P3 116.6(15) . .
C66 C61 P3 118.0(19) . .
C61 C62 C63 119(3) . .
C61 C62 H62 120.8 . .
C63 C62 H62 120.7 . .
C62 C63 C64 114(3) . .
C62 C63 H63 123.2 . .
C64 C63 H63 123.2 . .
C65 C64 C63 128(4) . .
C65 C64 H64 115.9 . .
C63 C64 H64 115.9 . .
C64 C65 C66 119(5) . .
C64 C65 H65 120.6 . .
C66 C65 H65 120.5 . .
C65 C66 C61 115(3) . .
C65 C66 H66 122.4 . .
C61 C66 H66 122.4 . .
C72 C71 C76 117.2(12) . .
C72 C71 P4 121.4(10) . .
C76 C71 P4 121.4(9) . .
C73 C72 C71 121.1(14) . .
C73 C72 H72 119.4 . .
C71 C72 H72 119.4 . .
C72 C73 C74 119.5(14) . .
C72 C73 H73 120.3 . .
C74 C73 H73 120.3 . .
C75 C74 C73 122.0(14) . .
C75 C74 H74 119.0 . .
C73 C74 H74 119.0 . .
C74 C75 C76 117.9(15) . .
C74 C75 H75 121.0 . .
C76 C75 H75 121.1 . .
C75 C76 C71 122.2(13) . .
C75 C76 H76 118.9 . .
C71 C76 H76 118.9 . .
C82 C81 C86 118.4(12) . .
C82 C81 P4 122.1(9) . .
C86 C81 P4 119.3(10) . .
C81 C82 C83 121.7(12) . .
C81 C82 H82 119.1 . .
C83 C82 H82 119.2 . .
C84 C83 C82 121.3(13) . .
C84 C83 H83 119.3 . .
C82 C83 H83 119.3 . .
C83 C84 C85 116.4(15) . .
C83 C84 H84 121.8 . .
C85 C84 H84 121.8 . .
C84 C85 C86 122.1(14) . .
C84 C85 H85 119.0 . .
C86 C85 H85 118.9 . .
C81 C86 C85 119.8(13) . .
C81 C86 H86 120.1 . .
C85 C86 H86 120.1 . .
N1 C1A C2A 121.9(15) . .
N1 C1A H1AA 119.1 . .
C2A C1A H1AA 119.1 . .
C1A C2A C3A 118.5(17) . .
C1A C2A H2AA 120.8 . .
C3A C2A H2AA 120.8 . .
C4A C3A C2A 121.0(15) . .
C4A C3A H3AA 119.5 . .
C2A C3A H3AA 119.5 . .
C3A C4A C5A 118.3(16) . .
C3A C4A H4AA 120.8 . .
C5A C4A H4AA 120.8 . .
N1 C5A C4A 120.7(15) . .
N1 C5A C5B 117.4(11) . .
C4A C5A C5B 121.9(15) . .
N2 C1B C2B 123.8(19) . .
N2 C1B H1BA 118.1 . .
C2B C1B H1BA 118.1 . .
C3B C2B C1B 119(2) . .
C3B C2B H2BA 120.3 . .
C1B C2B H2BA 120.3 . .
C4B C3B C2B 118(2) . .
C4B C3B H3BA 120.8 . .
C2B C3B H3BA 120.8 . .
C3B C4B C5B 121(2) . .
C3B C4B H4BA 119.5 . .
C5B C4B H4BA 119.5 . .
N2 C5B C4B 123.0(16) . .
N2 C5B C5A 112.5(11) . .
C4B C5B C5A 124.4(16) . .
N3 C1C C2C 124.0(15) . .
N3 C1C H1CA 118.0 . .
C2C C1C H1CA 118.0 . .
C3C C2C C1C 120.1(15) . .
C3C C2C H2CA 119.9 . .
C1C C2C H2CA 119.9 . .
C2C C3C C4C 119.3(14) . .
C2C C3C H3CA 120.4 . .
C4C C3C H3CA 120.3 . .
C3C C4C C5C 117.2(17) . .
C3C C4C H4CA 121.4 . .
C5C C4C H4CA 121.4 . .
N3 C5C C4C 124.5(14) . .
N3 C5C C5D 113.1(11) . .
C4C C5C C5D 122.4(15) . .
C2D C1D N4 124.3(12) . .
C2D C1D H1DA 117.9 . .
N4 C1D H1DA 117.8 . .
C1D C2D C3D 120.3(15) . .
C1D C2D H2DA 119.8 . .
C3D C2D H2DA 119.8 . .
C4D C3D C2D 118.9(16) . .
C4D C3D H3DA 120.5 . .
C2D C3D H3DA 120.6 . .
C3D C4D C5D 118.9(16) . .
C3D C4D H4DA 120.6 . .
C5D C4D H4DA 120.6 . .
N4 C5D C4D 121.0(15) . .
N4 C5D C5C 115.8(13) . .
C4D C5D C5C 123.1(14) . .
F6 Sb1 F3 88.6(7) . .
F6 Sb1 F2 176.7(6) . .
F3 Sb1 F2 94.4(6) . .
F6 Sb1 F4 92.5(6) . .
F3 Sb1 F4 92.0(5) . .
F2 Sb1 F4 88.7(6) . .
F6 Sb1 F1 90.2(7) . .
F3 Sb1 F1 88.9(6) . .
F2 Sb1 F1 88.5(7) . .
F4 Sb1 F1 177.2(6) . .
F6 Sb1 F5 89.5(7) . .
F3 Sb1 F5 177.4(7) . .
F2 Sb1 F5 87.5(6) . .
F4 Sb1 F5 86.3(5) . .
F1 Sb1 F5 92.9(6) . .
F7 Sb2 F7 87(3) . 2_656
F7 Sb2 F9 94.7(15) . 2_656
F7 Sb2 F9 177.7(13) 2_656 2_656
F7 Sb2 F9 177.7(13) . .
F7 Sb2 F9 94.7(15) 2_656 .
F9 Sb2 F9 83.1(15) 2_656 .
F7 Sb2 F8 87.7(8) . 2_656
F7 Sb2 F8 90.8(8) 2_656 2_656
F9 Sb2 F8 88.5(7) 2_656 2_656
F9 Sb2 F8 92.9(6) . 2_656
F7 Sb2 F8 90.8(8) . .
F7 Sb2 F8 87.7(8) 2_656 .
F9 Sb2 F8 92.9(6) 2_656 .
F9 Sb2 F8 88.5(7) . .
F8 Sb2 F8 178.0(7) 2_656 .
F10 Sb3 F11 99(3) . .
F10 Sb3 F15 95(4) . .
F11 Sb3 F15 92(5) . .
F10 Sb3 F12 128(3) . .
F11 Sb3 F12 69.7(19) . .
F15 Sb3 F12 134.7(17) . .
F10 Sb3 F14 88(4) . .
F11 Sb3 F14 163(3) . .
F15 Sb3 F14 103(5) . .
F12 Sb3 F14 94(3) . .
F10 Sb3 F13 165(4) . .
F11 Sb3 F13 92(3) . .
F15 Sb3 F13 96(3) . .
F12 Sb3 F13 46(3) . .
F14 Sb3 F13 79(4) . .
F12 F12 F13 88(5) 2_556 .
F12 F12 Sb3 164(2) 2_556 .
F13 F12 Sb3 76(5) . .
F12 F13 Sb3 58(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Os1 N1 2.082(9) .
Os1 N4 2.124(9) .
Os1 N2 2.125(10) .
Os1 N3 2.134(9) .
Os1 P2 2.254(3) .
Os1 P1 2.342(3) .
Pt1 P4 2.164(3) .
Pt1 P3 2.238(3) .
Pt1 Cl1 2.310(4) .
Pt1 Cl2 2.359(3) .
P1 C21 1.792(10) .
P1 C1 1.840(11) .
P1 C11 1.911(11) .
P2 C31 1.799(17) .
P2 C2 1.864(10) .
P2 C41 1.91(2) .
P3 C61 1.769(16) .
P3 C3 1.847(11) .
P3 C51 1.90(2) .
P4 C71 1.786(11) .
P4 C81 1.866(12) .
P4 C4 1.869(9) .
N1 C1A 1.325(17) .
N1 C5A 1.357(15) .
N2 C5B 1.352(17) .
N2 C1B 1.360(17) .
N3 C1C 1.324(16) .
N3 C5C 1.403(17) .
N4 C1D 1.347(14) .
N4 C5D 1.411(15) .
C1 C2 1.563(16) .
C1 C4 1.579(15) .
C1 H1 0.9900 .
C2 C3 1.565(19) .
C2 H2 0.9900 .
C3 C4 1.531(14) .
C3 H3 0.9900 .
C4 H4 0.9900 .
C11 C16 1.344(17) .
C11 C12 1.397(18) .
C12 C13 1.39(2) .
C12 H12 0.9400 .
C13 C14 1.31(3) .
C13 H13 0.9400 .
C14 C15 1.34(3) .
C14 H14 0.9400 .
C15 C16 1.46(3) .
C15 H15 0.9400 .
C16 H16 0.9400 .
C21 C26 1.365(14) .
C21 C22 1.396(14) .
C22 C23 1.343(15) .
C22 H22 0.9400 .
C23 C24 1.362(17) .
C23 H23 0.9400 .
C24 C25 1.388(17) .
C24 H24 0.9400 .
C25 C26 1.351(16) .
C25 H25 0.9400 .
C26 H26 0.9400 .
C31 C32 1.37(3) .
C31 C36 1.419(18) .
C32 C33 1.38(3) .
C32 H32 0.9400 .
C33 C34 1.46(3) .
C33 H33 0.9400 .
C34 C35 1.32(4) .
C34 H34 0.9400 .
C35 C36 1.34(3) .
C35 H35 0.9400 .
C36 H36 0.9400 .
C41 C42 1.35(3) .
C41 C46 1.39(3) .
C42 C43 1.40(2) .
C42 H42 0.9400 .
C43 C44 1.35(5) .
C43 H43 0.9400 .
C44 C45 1.45(8) .
C44 H44 0.9400 .
C45 C46 1.37(4) .
C45 H45 0.9400 .
C46 H46 0.9400 .
C51 C56 1.36(3) .
C51 C52 1.43(2) .
C52 C53 1.36(4) .
C52 H52 0.9400 .
C53 C54 1.35(5) .
C53 H53 0.9400 .
C54 C55 1.37(4) .
C54 H54 0.9400 .
C55 C56 1.39(3) .
C55 H55 0.9400 .
C56 H56 0.9400 .
C61 C62 1.35(3) .
C61 C66 1.46(3) .
C62 C63 1.39(3) .
C62 H62 0.9400 .
C63 C64 1.44(6) .
C63 H63 0.9400 .
C64 C65 1.33(9) .
C64 H64 0.9400 .
C65 C66 1.34(4) .
C65 H65 0.9400 .
C66 H66 0.9400 .
C71 C72 1.353(15) .
C71 C76 1.394(17) .
C72 C73 1.344(18) .
C72 H72 0.9400 .
C73 C74 1.38(2) .
C73 H73 0.9400 .
C74 C75 1.31(2) .
C74 H74 0.9400 .
C75 C76 1.366(19) .
C75 H75 0.9400 .
C76 H76 0.9400 .
C81 C82 1.357(15) .
C81 C86 1.366(16) .
C82 C83 1.432(17) .
C82 H82 0.9400 .
C83 C84 1.35(2) .
C83 H83 0.9400 .
C84 C85 1.40(2) .
C84 H84 0.9400 .
C85 C86 1.42(2) .
C85 H85 0.9400 .
C86 H86 0.9400 .
C1A C2A 1.353(17) .
C1A H1AA 0.9400 .
C2A C3A 1.38(2) .
C2A H2AA 0.9400 .
C3A C4A 1.34(2) .
C3A H3AA 0.9400 .
C4A C5A 1.385(19) .
C4A H4AA 0.9400 .
C5A C5B 1.41(2) .
C1B C2B 1.40(3) .
C1B H1BA 0.9400 .
C2B C3B 1.36(3) .
C2B H2BA 0.9400 .
C3B C4B 1.32(3) .
C3B H3BA 0.9400 .
C4B C5B 1.409(19) .
C4B H4BA 0.9400 .
C1C C2C 1.404(19) .
C1C H1CA 0.9400 .
C2C C3C 1.37(3) .
C2C H2CA 0.9400 .
C3C C4C 1.39(3) .
C3C H3CA 0.9400 .
C4C C5C 1.403(19) .
C4C H4CA 0.9400 .
C5C C5D 1.44(2) .
C1D C2D 1.346(17) .
C1D H1DA 0.9400 .
C2D C3D 1.41(2) .
C2D H2DA 0.9400 .
C3D C4D 1.37(2) .
C3D H3DA 0.9400 .
C4D C5D 1.43(2) .
C4D H4DA 0.9400 .
Sb1 F6 1.795(13) .
Sb1 F3 1.839(9) .
Sb1 F2 1.841(11) .
Sb1 F4 1.858(9) .
Sb1 F1 1.860(11) .
Sb1 F5 1.867(9) .
Sb2 F7 1.775(19) .
Sb2 F7 1.77(2) 2_656
Sb2 F9 1.804(18) 2_656
Sb2 F9 1.804(18) .
Sb2 F8 1.890(12) 2_656
Sb2 F8 1.890(12) .
Sb3 F10 1.63(8) .
Sb3 F11 1.65(3) .
Sb3 F15 1.67(4) .
Sb3 F12 1.87(2) .
Sb3 F14 2.04(11) .
Sb3 F13 2.14(11) .
F12 F12 1.25(4) 2_556
F12 F13 1.59(5) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
N1 Os1 P1 C21 39.1(5) . . . .
N4 Os1 P1 C21 -53.1(5) . . . .
N2 Os1 P1 C21 112.8(5) . . . .
P2 Os1 P1 C21 -141.5(4) . . . .
N1 Os1 P1 C1 161.1(5) . . . .
N4 Os1 P1 C1 68.8(5) . . . .
N2 Os1 P1 C1 -125.2(5) . . . .
P2 Os1 P1 C1 -19.5(4) . . . .
N1 Os1 P1 C11 -79.9(6) . . . .
N4 Os1 P1 C11 -172.2(5) . . . .
N2 Os1 P1 C11 -6.2(6) . . . .
P2 Os1 P1 C11 99.5(5) . . . .
N4 Os1 P2 C31 160.6(7) . . . .
N2 Os1 P2 C31 -10.7(7) . . . .
N3 Os1 P2 C31 84.8(7) . . . .
P1 Os1 P2 C31 -95.4(7) . . . .
N4 Os1 P2 C2 -81.7(6) . . . .
N2 Os1 P2 C2 107.0(6) . . . .
N3 Os1 P2 C2 -157.4(6) . . . .
P1 Os1 P2 C2 22.4(5) . . . .
N4 Os1 P2 C41 38.1(7) . . . .
N2 Os1 P2 C41 -133.2(7) . . . .
N3 Os1 P2 C41 -37.6(7) . . . .
P1 Os1 P2 C41 142.1(6) . . . .
P4 Pt1 P3 C61 133.7(7) . . . .
Cl1 Pt1 P3 C61 -49.5(7) . . . .
P4 Pt1 P3 C3 14.4(5) . . . .
Cl1 Pt1 P3 C3 -168.7(5) . . . .
P4 Pt1 P3 C51 -102.2(7) . . . .
Cl1 Pt1 P3 C51 74.6(7) . . . .
P3 Pt1 P4 C71 95.6(4) . . . .
Cl2 Pt1 P4 C71 -80.0(4) . . . .
P3 Pt1 P4 C81 -140.0(4) . . . .
Cl2 Pt1 P4 C81 44.3(4) . . . .
P3 Pt1 P4 C4 -15.0(4) . . . .
Cl2 Pt1 P4 C4 169.4(4) . . . .
N4 Os1 N1 C1A 4.6(10) . . . .
N2 Os1 N1 C1A 177.6(10) . . . .
N3 Os1 N1 C1A 80.3(10) . . . .
P1 Os1 N1 C1A -99.5(10) . . . .
N4 Os1 N1 C5A -164.4(9) . . . .
N2 Os1 N1 C5A 8.6(8) . . . .
N3 Os1 N1 C5A -88.7(9) . . . .
P1 Os1 N1 C5A 91.5(8) . . . .
N1 Os1 N2 C5B -5.0(8) . . . .
N4 Os1 N2 C5B 19.3(17) . . . .
N3 Os1 N2 C5B 75.7(9) . . . .
P2 Os1 N2 C5B 168.7(8) . . . .
P1 Os1 N2 C5B -108.3(8) . . . .
N1 Os1 N2 C1B 169.0(11) . . . .
N4 Os1 N2 C1B -166.7(11) . . . .
N3 Os1 N2 C1B -110.2(10) . . . .
P2 Os1 N2 C1B -17.2(10) . . . .
P1 Os1 N2 C1B 65.8(10) . . . .
N1 Os1 N3 C1C 93.2(10) . . . .
N4 Os1 N3 C1C -175.6(10) . . . .
N2 Os1 N3 C1C 19.2(10) . . . .
P2 Os1 N3 C1C -86.2(9) . . . .
N1 Os1 N3 C5C -91.2(8) . . . .
N4 Os1 N3 C5C 0.1(8) . . . .
N2 Os1 N3 C5C -165.1(8) . . . .
P2 Os1 N3 C5C 89.4(8) . . . .
N1 Os1 N4 C1D -95.3(9) . . . .
N2 Os1 N4 C1D -118.7(13) . . . .
N3 Os1 N4 C1D -177.7(9) . . . .
P2 Os1 N4 C1D 90.7(9) . . . .
P1 Os1 N4 C1D 6.7(9) . . . .
N1 Os1 N4 C5D 78.8(8) . . . .
N2 Os1 N4 C5D 55.4(16) . . . .
N3 Os1 N4 C5D -3.5(8) . . . .
P2 Os1 N4 C5D -95.2(8) . . . .
P1 Os1 N4 C5D -179.2(7) . . . .
C21 P1 C1 C2 145.4(9) . . . .
C11 P1 C1 C2 -115.3(9) . . . .
Os1 P1 C1 C2 11.3(10) . . . .
C21 P1 C1 C4 47.4(9) . . . .
C11 P1 C1 C4 146.7(8) . . . .
Os1 P1 C1 C4 -86.6(7) . . . .
C4 C1 C2 C3 2.1(8) . . . .
P1 C1 C2 C3 -116.0(8) . . . .
C4 C1 C2 P2 124.9(9) . . . .
P1 C1 C2 P2 6.8(13) . . . .
C31 P2 C2 C1 99.8(12) . . . .
C41 P2 C2 C1 -148.6(12) . . . .
Os1 P2 C2 C1 -22.7(11) . . . .
C31 P2 C2 C3 -152.2(10) . . . .
C41 P2 C2 C3 -40.6(12) . . . .
Os1 P2 C2 C3 85.3(9) . . . .
C1 C2 C3 C4 -2.2(8) . . . .
P2 C2 C3 C4 -123.0(8) . . . .
C1 C2 C3 P3 -119.8(8) . . . .
P2 C2 C3 P3 119.4(8) . . . .
C61 P3 C3 C4 -135.9(12) . . . .
C51 P3 C3 C4 108.6(10) . . . .
Pt1 P3 C3 C4 -10.4(11) . . . .
C61 P3 C3 C2 -33.3(13) . . . .
C51 P3 C3 C2 -148.8(9) . . . .
Pt1 P3 C3 C2 92.3(8) . . . .
C2 C3 C4 C1 2.2(8) . . . .
P3 C3 C4 C1 124.4(9) . . . .
C2 C3 C4 P4 -123.3(8) . . . .
P3 C3 C4 P4 -1.1(13) . . . .
C2 C1 C4 C3 -2.2(8) . . . .
P1 C1 C4 C3 111.6(8) . . . .
C2 C1 C4 P4 118.9(8) . . . .
P1 C1 C4 P4 -127.3(7) . . . .
C71 P4 C4 C3 -104.3(9) . . . .
C81 P4 C4 C3 140.4(9) . . . .
Pt1 P4 C4 C3 12.6(10) . . . .
C71 P4 C4 C1 145.9(8) . . . .
C81 P4 C4 C1 30.6(9) . . . .
Pt1 P4 C4 C1 -97.2(8) . . . .
C21 P1 C11 C16 124.7(10) . . . .
C1 P1 C11 C16 20.7(11) . . . .
Os1 P1 C11 C16 -102.1(10) . . . .
C21 P1 C11 C12 -57.3(9) . . . .
C1 P1 C11 C12 -161.3(9) . . . .
Os1 P1 C11 C12 76.0(9) . . . .
C16 C11 C12 C13 1.6(18) . . . .
P1 C11 C12 C13 -176.6(10) . . . .
C11 C12 C13 C14 -2(2) . . . .
C12 C13 C14 C15 1(3) . . . .
C13 C14 C15 C16 1(3) . . . .
C12 C11 C16 C15 0.2(18) . . . .
P1 C11 C16 C15 178.2(11) . . . .
C14 C15 C16 C11 -1(3) . . . .
C1 P1 C21 C26 -124.2(9) . . . .
C11 P1 C21 C26 130.2(9) . . . .
Os1 P1 C21 C26 1.7(10) . . . .
C1 P1 C21 C22 58.7(10) . . . .
C11 P1 C21 C22 -46.9(9) . . . .
Os1 P1 C21 C22 -175.4(7) . . . .
C26 C21 C22 C23 0.4(17) . . . .
P1 C21 C22 C23 177.5(9) . . . .
C21 C22 C23 C24 1.2(18) . . . .
C22 C23 C24 C25 -2.1(19) . . . .
C23 C24 C25 C26 1(2) . . . .
C24 C25 C26 C21 0.3(18) . . . .
C22 C21 C26 C25 -1.2(16) . . . .
P1 C21 C26 C25 -178.3(9) . . . .
C2 P2 C31 C32 -7(3) . . . .
C41 P2 C31 C32 -119(3) . . . .
Os1 P2 C31 C32 113(2) . . . .
C2 P2 C31 C36 178.5(15) . . . .
C41 P2 C31 C36 67.0(16) . . . .
Os1 P2 C31 C36 -60.9(17) . . . .
C36 C31 C32 C33 -3(5) . . . .
P2 C31 C32 C33 -177(4) . . . .
C31 C32 C33 C34 -1(7) . . . .
C32 C33 C34 C35 4(8) . . . .
C33 C34 C35 C36 -3(8) . . . .
C34 C35 C36 C31 -1(5) . . . .
C32 C31 C36 C35 4(4) . . . .
P2 C31 C36 C35 178(2) . . . .
C31 P2 C41 C42 179.7(15) . . . .
C2 P2 C41 C42 68.4(17) . . . .
Os1 P2 C41 C42 -54.0(15) . . . .
C31 P2 C41 C46 -1.0(16) . . . .
C2 P2 C41 C46 -112.4(15) . . . .
Os1 P2 C41 C46 125.3(15) . . . .
C46 C41 C42 C43 -3(3) . . . .
P2 C41 C42 C43 176.5(12) . . . .
C41 C42 C43 C44 0(3) . . . .
C42 C43 C44 C45 4(5) . . . .
C43 C44 C45 C46 -5(6) . . . .
C44 C45 C46 C41 2(6) . . . .
C42 C41 C46 C45 2(4) . . . .
P2 C41 C46 C45 -177(3) . . . .
C61 P3 C51 C56 -142.2(16) . . . .
C3 P3 C51 C56 -28.6(18) . . . .
Pt1 P3 C51 C56 89.4(17) . . . .
C61 P3 C51 C52 48.3(14) . . . .
C3 P3 C51 C52 161.9(11) . . . .
Pt1 P3 C51 C52 -80.2(12) . . . .
C56 C51 C52 C53 -1(3) . . . .
P3 C51 C52 C53 169.4(17) . . . .
C51 C52 C53 C54 4(4) . . . .
C52 C53 C54 C55 -2(5) . . . .
C53 C54 C55 C56 -4(5) . . . .
C52 C51 C56 C55 -5(3) . . . .
P3 C51 C56 C55 -175(2) . . . .
C54 C55 C56 C51 8(4) . . . .
C3 P3 C61 C62 92.7(14) . . . .
C51 P3 C61 C62 -153.1(15) . . . .
Pt1 P3 C61 C62 -28.1(16) . . . .
C3 P3 C61 C66 -87.0(13) . . . .
C51 P3 C61 C66 27.2(13) . . . .
Pt1 P3 C61 C66 152.2(9) . . . .
C66 C61 C62 C63 2(3) . . . .
P3 C61 C62 C63 -177.1(16) . . . .
C61 C62 C63 C64 -4(3) . . . .
C62 C63 C64 C65 4(7) . . . .
C63 C64 C65 C66 -2(9) . . . .
C64 C65 C66 C61 0(6) . . . .
C62 C61 C66 C65 0(3) . . . .
P3 C61 C66 C65 179(2) . . . .
C81 P4 C71 C72 67.5(11) . . . .
C4 P4 C71 C72 -48.6(11) . . . .
Pt1 P4 C71 C72 -164.8(9) . . . .
C81 P4 C71 C76 -115.0(11) . . . .
C4 P4 C71 C76 128.9(11) . . . .
Pt1 P4 C71 C76 12.7(11) . . . .
C76 C71 C72 C73 -2(2) . . . .
P4 C71 C72 C73 175.4(11) . . . .
C71 C72 C73 C74 3(2) . . . .
C72 C73 C74 C75 -4(3) . . . .
C73 C74 C75 C76 3(3) . . . .
C74 C75 C76 C71 -2(3) . . . .
C72 C71 C76 C75 1(2) . . . .
P4 C71 C76 C75 -176.1(13) . . . .
C71 P4 C81 C82 1.4(11) . . . .
C4 P4 C81 C82 111.3(9) . . . .
Pt1 P4 C81 C82 -123.8(9) . . . .
C71 P4 C81 C86 175.1(9) . . . .
C4 P4 C81 C86 -74.9(10) . . . .
Pt1 P4 C81 C86 49.9(10) . . . .
C86 C81 C82 C83 4.1(17) . . . .
P4 C81 C82 C83 177.9(9) . . . .
C81 C82 C83 C84 0(2) . . . .
C82 C83 C84 C85 -3(2) . . . .
C83 C84 C85 C86 1(2) . . . .
C82 C81 C86 C85 -5.7(19) . . . .
P4 C81 C86 C85 -179.7(11) . . . .
C84 C85 C86 C81 3(2) . . . .
C5A N1 C1A C2A -0.9(19) . . . .
Os1 N1 C1A C2A -169.5(11) . . . .
N1 C1A C2A C3A 2(2) . . . .
C1A C2A C3A C4A -1(3) . . . .
C2A C3A C4A C5A 0(3) . . . .
C1A N1 C5A C4A -0.8(19) . . . .
Os1 N1 C5A C4A 168.6(11) . . . .
C1A N1 C5A C5B 179.2(12) . . . .
Os1 N1 C5A C5B -11.4(14) . . . .
C3A C4A C5A N1 1(2) . . . .
C3A C4A C5A C5B -178.6(16) . . . .
C5B N2 C1B C2B -2.5(18) . . . .
Os1 N2 C1B C2B -176.8(11) . . . .
N2 C1B C2B C3B 0(3) . . . .
C1B C2B C3B C4B 2(3) . . . .
C2B C3B C4B C5B -3(3) . . . .
C1B N2 C5B C4B 2.3(17) . . . .
Os1 N2 C5B C4B 177.2(10) . . . .
C1B N2 C5B C5A -174.0(11) . . . .
Os1 N2 C5B C5A 0.8(14) . . . .
C3B C4B C5B N2 0(2) . . . .
C3B C4B C5B C5A 176.2(16) . . . .
N1 C5A C5B N2 6.8(17) . . . .
C4A C5A C5B N2 -173.2(13) . . . .
N1 C5A C5B C4B -169.5(12) . . . .
C4A C5A C5B C4B 10(2) . . . .
C5C N3 C1C C2C -2.5(17) . . . .
Os1 N3 C1C C2C 173.3(10) . . . .
N3 C1C C2C C3C 2(2) . . . .
C1C C2C C3C C4C 1(3) . . . .
C2C C3C C4C C5C -3(3) . . . .
C1C N3 C5C C4C 0.7(18) . . . .
Os1 N3 C5C C4C -175.5(11) . . . .
C1C N3 C5C C5D 179.4(10) . . . .
Os1 N3 C5C C5D 3.2(13) . . . .
C3C C4C C5C N3 2(2) . . . .
C3C C4C C5C C5D -176.6(14) . . . .
C5D N4 C1D C2D 2.0(17) . . . .
Os1 N4 C1D C2D 176.2(10) . . . .
N4 C1D C2D C3D -3(2) . . . .
C1D C2D C3D C4D 2(2) . . . .
C2D C3D C4D C5D 0(3) . . . .
C1D N4 C5D C4D 0.1(17) . . . .
Os1 N4 C5D C4D -174.7(11) . . . .
C1D N4 C5D C5C -178.8(10) . . . .
Os1 N4 C5D C5C 6.4(14) . . . .
C3D C4D C5D N4 -1(2) . . . .
C3D C4D C5D C5C 177.7(15) . . . .
N3 C5C C5D N4 -6.1(16) . . . .
C4C C5C C5D N4 172.6(13) . . . .
N3 C5C C5D C4D 175.0(13) . . . .
C4C C5C C5D C4D -6(2) . . . .
F10 Sb3 F12 F12 161(6) . . . 2_556
F11 Sb3 F12 F12 -114(5) . . . 2_556
F15 Sb3 F12 F12 -43(9) . . . 2_556
F14 Sb3 F12 F12 70(5) . . . 2_556
F13 Sb3 F12 F12 0(5) . . . 2_556
F10 Sb3 F12 F13 161(4) . . . .
F11 Sb3 F12 F13 -114(3) . . . .
F15 Sb3 F12 F13 -42(8) . . . .
F14 Sb3 F12 F13 70(3) . . . .
F12 F12 F13 Sb3 179.9(15) 2_556 . . .
F10 Sb3 F13 F12 -74(13) . . . .
F11 Sb3 F13 F12 59(3) . . . .
F15 Sb3 F13 F12 151(5) . . . .
F14 Sb3 F13 F12 -107(3) . . . .
