#------------------------------------------------------------------------------
#$Date: 2018-01-16 10:32:23 +0200 (Tue, 16 Jan 2018) $
#$Revision: 205245 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/59/4345984.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4345984
loop_
_publ_author_name
'Sylvia Eller'
'Barbara Trettenbrein'
'Dennis Oberhuber'
'Christof Strabler'
'Rene Gutmann'
'Wytze E. van der Veer'
'Markus Ruetz'
'Holger Kopacka'
'Dagmar Obendorf'
'Peter Bruggeller'
_publ_section_title
;
 Oxidative quenching within photosensitizer-acceptor dyads based on
 bis(bidentate) phosphine-connected osmium(II) bipyridyl light absorbers
 and reactive metal sites
;
_journal_name_full               'Inorganic Chemistry Communications'
_journal_page_first              41
_journal_page_last               45
_journal_paper_doi               10.1016/j.inoche.2012.06.001
_journal_volume                  23
_journal_year                    2012
_chemical_formula_moiety
'C72 H60 Cl2 N4 Os P4 Pd, 2(F6 Sb), 2(C H2 Cl2), 1.75(C Cl2)'
_chemical_formula_sum            'C75.75 H64 Cl9.5 F12 N4 Os P4 Pd Sb2'
_chemical_formula_weight         2259.12
_chemical_name_systematic        '[Os(bpy)2(dppcb)PdCl2](SbF6)2'
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                107.9141(9)
_cell_angle_beta                 97.9066(8)
_cell_angle_gamma                97.4720(9)
_cell_formula_units_Z            2
_cell_length_a                   14.2521(2)
_cell_length_b                   15.3117(2)
_cell_length_c                   20.8233(3)
_cell_measurement_reflns_used    80299
_cell_measurement_temperature    243(2)
_cell_measurement_theta_max      26.022
_cell_measurement_theta_min      0.998
_cell_volume                     4210.51(11)
_computing_cell_refinement       'Denzo and Scalepack'
_computing_data_collection       'Kappa CCD'
_computing_data_reduction        'Denzo and Scalepack'
_computing_molecular_graphics    'SHELXTL-NT V6.1'
_computing_publication_material  'SHELXTL-NT V6.1'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      243(2)
_diffrn_measured_fraction_theta_full 1.00
_diffrn_measurement_device_type  'Kappa CCD'
_diffrn_measurement_method       'phi- and omega-scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0310
_diffrn_reflns_av_sigmaI/netI    0.0623
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            29047
_diffrn_reflns_theta_full        26.07
_diffrn_reflns_theta_max         26.07
_diffrn_reflns_theta_min         1.47
_diffrn_standards_decay_%        0
_diffrn_standards_interval_time  120
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    2.797
_exptl_absorpt_correction_T_max  0.776
_exptl_absorpt_correction_T_min  0.740
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Otwinowski et al, 1997'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.782
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             2200
_exptl_crystal_size_max          0.27
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.500
_refine_diff_density_min         -1.730
_refine_diff_density_rms         0.120
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.027
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1001
_refine_ls_number_reflns         15815
_refine_ls_number_restraints     14
_refine_ls_restrained_S_all      1.032
_refine_ls_R_factor_all          0.1075
_refine_ls_R_factor_gt           0.0728
_refine_ls_shift/su_max          0.025
_refine_ls_shift/su_mean         0.009
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0700P)²+3.2316P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1709
_refine_ls_wR_factor_ref         0.2489
_reflns_number_gt                10763
_reflns_number_total             16668
_reflns_threshold_expression     >3sigma(I)
_cod_data_source_file            Inor-Chem-Comm-2012-23-41-45-2.cif
_cod_data_source_block           2
_cod_original_formula_sum        'C75.75 H64 Cl9.50 F12 N4 Os P4 Pd Sb2'
_cod_database_code               4345984
_diffrn_measured_fraction        0.975
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Os1 Os 0.69921(5) 0.27245(4) 0.66567(3) 0.0817(3) Uani 1 1 d . . .
Pd1 Pd 0.92351(7) 0.63735(6) 0.98881(4) 0.0473(2) Uani 1 1 d . . .
Cl1 Cl 1.0724(2) 0.7384(3) 1.0204(2) 0.0782(11) Uani 1 1 d . . .
Cl2 Cl 0.9415(5) 0.6138(4) 1.0955(2) 0.119(2) Uani 1 1 d . . .
P1 P 0.6503(3) 0.3309(2) 0.76916(18) 0.0637(10) Uani 1 1 d . . .
P2 P 0.8117(3) 0.4100(3) 0.70044(15) 0.0604(9) Uani 1 1 d . . .
P3 P 0.9001(2) 0.65815(19) 0.88649(14) 0.0426(6) Uani 1 1 d . . .
P4 P 0.7679(2) 0.57049(19) 0.95878(15) 0.0442(7) Uani 1 1 d . . .
N1 N 0.7542(12) 0.2192(7) 0.5747(6) 0.090(5) Uani 1 1 d D . .
N2 N 0.6002(8) 0.2998(7) 0.5976(5) 0.131(3) Uani 1 1 d D . .
N3 N 0.6068(10) 0.1401(7) 0.6342(6) 0.071(3) Uani 1 1 d . . .
N4 N 0.777(2) 0.1988(14) 0.7151(11) 0.074(2) Uani 1 1 d . . .
C1 C 0.7506(8) 0.4241(7) 0.8303(6) 0.042(2) Uani 1 1 d . . .
H1 H 0.7818 0.4004 0.8654 0.051 Uiso 1 1 calc R . .
C2 C 0.8281(8) 0.4647(7) 0.7961(6) 0.047(3) Uani 1 1 d . . .
H2 H 0.8934 0.4623 0.8183 0.056 Uiso 1 1 calc R . .
C3 C 0.8040(7) 0.5641(7) 0.8269(5) 0.037(2) Uani 1 1 d . . .
H3 H 0.7702 0.5846 0.7908 0.044 Uiso 1 1 calc R . .
C4 C 0.7316(8) 0.5235(7) 0.8651(5) 0.047(3) Uani 1 1 d . . .
H4 H 0.6647 0.5296 0.8496 0.056 Uiso 1 1 calc R . .
C11 C 0.5423(10) 0.3861(8) 0.7816(10) 0.077(5) Uani 1 1 d . . .
C12 C 0.5286(12) 0.4516(16) 0.7517(14) 0.128(9) Uani 1 1 d . . .
H12 H 0.5722 0.4667 0.7251 0.154 Uiso 1 1 calc R . .
C13 C 0.4484(15) 0.4976(17) 0.7606(18) 0.149(12) Uani 1 1 d . . .
H13 H 0.4378 0.5404 0.7375 0.179 Uiso 1 1 calc R . .
C14 C 0.3887(18) 0.4817(15) 0.8001(12) 0.116(7) Uani 1 1 d . . .
H14 H 0.3349 0.5110 0.8059 0.139 Uiso 1 1 calc R . .
C15 C 0.4104(19) 0.4201(15) 0.8321(11) 0.123(8) Uani 1 1 d . . .
H15 H 0.3729 0.4131 0.8646 0.147 Uiso 1 1 calc R . .
C16 C 0.4774(18) 0.3694(13) 0.8229(10) 0.106(7) Uani 1 1 d . . .
H16 H 0.4819 0.3230 0.8435 0.127 Uiso 1 1 calc R . .
C21 C 0.6252(11) 0.2396(8) 0.8091(7) 0.069(4) Uani 1 1 d . . .
C22 C 0.5454(10) 0.1737(9) 0.7803(7) 0.070(4) Uani 1 1 d . . .
H22 H 0.5029 0.1792 0.7436 0.084 Uiso 1 1 calc R . .
C23 C 0.5233(11) 0.0990(9) 0.8020(7) 0.069(4) Uani 1 1 d . . .
H23 H 0.4646 0.0569 0.7834 0.082 Uiso 1 1 calc R . .
C24 C 0.5916(11) 0.0874(9) 0.8532(8) 0.071(4) Uani 1 1 d . . .
H24 H 0.5811 0.0347 0.8672 0.085 Uiso 1 1 calc R . .
C25 C 0.6743(11) 0.1544(9) 0.8828(8) 0.075(4) Uani 1 1 d . . .
H25 H 0.7194 0.1483 0.9178 0.090 Uiso 1 1 calc R . .
C26 C 0.6897(11) 0.2283(8) 0.8609(7) 0.069(4) Uani 1 1 d . . .
H26 H 0.7459 0.2736 0.8814 0.082 Uiso 1 1 calc R . .
C31 C 0.7971(10) 0.5097(10) 0.6706(6) 0.063(4) Uani 1 1 d . . .
C32 C 0.8736(11) 0.5695(11) 0.6646(8) 0.079(4) Uani 1 1 d . . .
H32 H 0.9362 0.5566 0.6713 0.095 Uiso 1 1 calc R . .
C33 C 0.8588(16) 0.6487(13) 0.6485(9) 0.097(6) Uani 1 1 d . . .
H33 H 0.9110 0.6906 0.6453 0.116 Uiso 1 1 calc R . .
C34 C 0.7663(16) 0.6647(13) 0.6374(9) 0.096(6) Uani 1 1 d . . .
H34 H 0.7561 0.7188 0.6272 0.115 Uiso 1 1 calc R . .
C35 C 0.6921(14) 0.6075(15) 0.6405(10) 0.100(6) Uani 1 1 d . . .
H35 H 0.6300 0.6202 0.6309 0.119 Uiso 1 1 calc R . .
C36 C 0.7030(13) 0.5274(14) 0.6579(8) 0.092(6) Uani 1 1 d . . .
H36 H 0.6494 0.4870 0.6609 0.111 Uiso 1 1 calc R . .
C41 C 0.9321(12) 0.3918(11) 0.6805(7) 0.079(4) Uani 1 1 d . . .
C42 C 1.0054(10) 0.3834(12) 0.7271(7) 0.075(4) Uani 1 1 d . . .
H42 H 0.9980 0.3939 0.7728 0.090 Uiso 1 1 calc R . .
C43 C 1.0914(12) 0.3593(13) 0.7074(8) 0.089(5) Uani 1 1 d . . .
H43 H 1.1422 0.3545 0.7393 0.107 Uiso 1 1 calc R . .
C44 C 1.0987(16) 0.3430(16) 0.6393(11) 0.115(7) Uani 1 1 d . . .
H44 H 1.1544 0.3243 0.6242 0.137 Uiso 1 1 calc R . .
C45 C 1.0269(15) 0.3536(15) 0.5941(9) 0.102(6) Uani 1 1 d . . .
H45 H 1.0354 0.3478 0.5491 0.123 Uiso 1 1 calc R . .
C46 C 0.9412(14) 0.3730(12) 0.6139(6) 0.087(5) Uani 1 1 d . . .
H46 H 0.8889 0.3731 0.5810 0.104 Uiso 1 1 calc R . .
C51 C 1.0011(8) 0.6591(10) 0.8432(6) 0.059(3) Uani 1 1 d . . .
C52 C 1.0204(12) 0.7143(16) 0.8054(9) 0.100(6) Uani 1 1 d . . .
H52 H 0.9807 0.7575 0.8013 0.119 Uiso 1 1 calc R . .
C53 C 1.0971(17) 0.708(2) 0.7732(12) 0.129(10) Uani 1 1 d . . .
H53 H 1.1071 0.7474 0.7473 0.154 Uiso 1 1 calc R . .
C54 C 1.159(2) 0.651(3) 0.7746(15) 0.128(2) Uani 1 1 d . . .
H54 H 1.2117 0.6489 0.7515 0.154 Uiso 1 1 calc R . .
C55 C 1.1408(13) 0.598(2) 0.8111(13) 0.133(14) Uani 1 1 d . . .
H55 H 1.1828 0.5563 0.8147 0.160 Uiso 1 1 calc R . .
C56 C 1.0639(10) 0.5978(13) 0.8449(9) 0.085(5) Uani 1 1 d . . .
H56 H 1.0543 0.5559 0.8692 0.102 Uiso 1 1 calc R . .
C61 C 0.8592(9) 0.7672(8) 0.8922(7) 0.058(3) Uani 1 1 d . . .
C62 C 0.7966(11) 0.7772(10) 0.8378(9) 0.079(5) Uani 1 1 d . . .
H62 H 0.7737 0.7268 0.7968 0.095 Uiso 1 1 calc R . .
C63 C 0.7694(13) 0.8623(13) 0.8455(12) 0.105(6) Uani 1 1 d . . .
H63 H 0.7274 0.8700 0.8094 0.125 Uiso 1 1 calc R . .
C64 C 0.8021(19) 0.9347(13) 0.9040(11) 0.128(9) Uani 1 1 d . . .
H64 H 0.7845 0.9929 0.9078 0.154 Uiso 1 1 calc R . .
C65 C 0.8582(19) 0.9251(12) 0.9558(11) 0.139(10) Uani 1 1 d . . .
H65 H 0.8781 0.9758 0.9969 0.166 Uiso 1 1 calc R . .
C66 C 0.8889(13) 0.8409(9) 0.9510(8) 0.085(5) Uani 1 1 d . . .
H66 H 0.9300 0.8354 0.9884 0.102 Uiso 1 1 calc R . .
C71 C 0.7167(8) 0.4800(8) 0.9897(5) 0.045(3) Uani 1 1 d . . .
C72 C 0.6162(10) 0.4611(9) 0.9834(7) 0.061(3) Uani 1 1 d . . .
H72 H 0.5774 0.4976 0.9668 0.073 Uiso 1 1 calc R . .
C73 C 0.5754(11) 0.3881(10) 1.0021(9) 0.076(4) Uani 1 1 d . . .
H73 H 0.5081 0.3749 0.9978 0.092 Uiso 1 1 calc R . .
C74 C 0.6310(12) 0.3342(10) 1.0268(7) 0.067(4) Uani 1 1 d . . .
H74 H 0.6022 0.2865 1.0413 0.080 Uiso 1 1 calc R . .
C75 C 0.7276(13) 0.3502(10) 1.0301(9) 0.089(5) Uani 1 1 d . . .
H75 H 0.7657 0.3120 1.0451 0.106 Uiso 1 1 calc R . .
C76 C 0.7704(12) 0.4230(10) 1.0112(9) 0.079(5) Uani 1 1 d . . .
H76 H 0.8374 0.4332 1.0133 0.095 Uiso 1 1 calc R . .
C81 C 0.7022(9) 0.6654(8) 0.9863(6) 0.054(3) Uani 1 1 d . . .
C82 C 0.7126(12) 0.7091(11) 1.0576(8) 0.086(5) Uani 1 1 d . . .
H82 H 0.7497 0.6875 1.0884 0.103 Uiso 1 1 calc R . .
C83 C 0.6673(15) 0.7849(12) 1.0822(10) 0.105(6) Uani 1 1 d . . .
H83 H 0.6720 0.8133 1.1297 0.126 Uiso 1 1 calc R . .
C84 C 0.6149(14) 0.8186(11) 1.0360(11) 0.098(6) Uani 1 1 d . . .
H84 H 0.5856 0.8705 1.0529 0.118 Uiso 1 1 calc R . .
C85 C 0.6055(11) 0.7764(10) 0.9655(8) 0.072(4) Uani 1 1 d . . .
H85 H 0.5705 0.7989 0.9343 0.086 Uiso 1 1 calc R . .
C86 C 0.6498(9) 0.6994(8) 0.9427(8) 0.058(3) Uani 1 1 d . . .
H86 H 0.6433 0.6697 0.8951 0.070 Uiso 1 1 calc R . .
C1A C 0.8306(15) 0.1724(10) 0.5720(8) 0.086(5) Uani 1 1 d . . .
H1A H 0.8592 0.1631 0.6122 0.103 Uiso 1 1 calc R . .
C2A C 0.866(2) 0.1394(13) 0.5144(10) 0.125(8) Uani 1 1 d . . .
H2A H 0.9144 0.1026 0.5118 0.150 Uiso 1 1 calc R . .
C3A C 0.823(3) 0.1658(17) 0.4551(9) 0.164(15) Uani 1 1 d . . .
H3A H 0.8436 0.1523 0.4125 0.197 Uiso 1 1 calc R . .
C4A C 0.745(2) 0.216(2) 0.474(2) 0.172(17) Uani 1 1 d . . .
H4A H 0.7175 0.2322 0.4359 0.206 Uiso 1 1 calc R . .
C5A C 0.696(3) 0.2492(16) 0.5277(11) 0.162(4) Uani 1 1 d D . .
C1B C 0.5167(14) 0.3309(13) 0.6064(11) 0.128(9) Uani 1 1 d D . .
H1B H 0.4978 0.3418 0.6492 0.154 Uiso 1 1 calc R . .
C2B C 0.455(2) 0.348(2) 0.551(2) 0.194(16) Uani 1 1 d D . .
H2B H 0.3907 0.3543 0.5524 0.233 Uiso 1 1 calc R . .
C3B C 0.498(4) 0.354(4) 0.496(2) 0.212(4) Uani 1 1 d D . .
H3B H 0.4766 0.3883 0.4684 0.270 Uiso 1 1 calc R . .
C4B C 0.568(4) 0.311(2) 0.4837(15) 0.22(2) Uani 1 1 d . . .
H4B H 0.5824 0.2878 0.4394 0.270 Uiso 1 1 calc R . .
C5B C 0.6185(16) 0.301(3) 0.5372(15) 0.169(3) Uani 1 1 d DU . .
C1C C 0.5156(17) 0.1192(15) 0.5969(7) 0.097(6) Uani 1 1 d . . .
H1C H 0.4923 0.1655 0.5817 0.116 Uiso 1 1 calc R . .
C2C C 0.4566(15) 0.036(2) 0.5804(9) 0.113(8) Uani 1 1 d . . .
H2C H 0.3927 0.0257 0.5571 0.136 Uiso 1 1 calc R . .
C3C C 0.4931(17) -0.0341(19) 0.5988(10) 0.113(7) Uani 1 1 d . . .
H3C H 0.4551 -0.0935 0.5882 0.135 Uiso 1 1 calc R . .
C4C C 0.5831(14) -0.0146(11) 0.6319(9) 0.086(5) Uani 1 1 d . . .
H4C H 0.6098 -0.0638 0.6404 0.104 Uiso 1 1 calc R . .
C5C C 0.6405(11) 0.0713(9) 0.6545(7) 0.069(4) Uani 1 1 d . . .
C1D C 0.8532(12) 0.2287(10) 0.7657(7) 0.076(4) Uani 1 1 d . . .
H1D H 0.8729 0.2938 0.7847 0.091 Uiso 1 1 calc R . .
C2D C 0.907(2) 0.1771(14) 0.7937(12) 0.136(14) Uani 1 1 d . . .
H2D H 0.9693 0.2006 0.8196 0.163 Uiso 1 1 calc R . .
C3D C 0.853(2) 0.0746(19) 0.7788(14) 0.136(9) Uani 1 1 d . . .
H3D H 0.8792 0.0362 0.8014 0.163 Uiso 1 1 calc R . .
C4D C 0.769(2) 0.0420(15) 0.7332(12) 0.121(7) Uani 1 1 d . . .
H4D H 0.7393 -0.0208 0.7211 0.145 Uiso 1 1 calc R . .
C5D C 0.7255(16) 0.1016(13) 0.7037(9) 0.100(6) Uani 1 1 d . . .
Sb1 Sb 0.52618(13) 0.24129(12) 0.27009(11) 0.1314(6) Uani 1 1 d D . .
F1 F 0.6063(13) 0.1940(15) 0.3136(15) 0.327(19) Uani 1 1 d D . .
F2 F 0.4195(11) 0.1927(12) 0.3044(10) 0.188(8) Uani 1 1 d . . .
F3 F 0.5402(12) 0.3447(15) 0.3424(6) 0.186(2) Uani 1 1 d D . .
F4 F 0.4982(17) 0.1366(12) 0.1909(12) 0.238(10) Uani 1 1 d . . .
F5 F 0.6204(12) 0.2905(12) 0.2348(15) 0.243(12) Uani 1 1 d . . .
F6 F 0.4338(9) 0.2916(10) 0.2243(7) 0.142(5) Uani 1 1 d . . .
Sb2 Sb 0.1726(2) 0.12417(15) 0.46270(14) 0.1902(14) Uani 1 1 d D . .
F7 F 0.0988(12) 0.0963(12) 0.5216(8) 0.172(6) Uani 1 1 d . . .
F8 F 0.2499(14) 0.0461(13) 0.4767(11) 0.194(7) Uani 1 1 d . . .
F9 F 0.238(2) 0.1437(14) 0.3987(14) 0.36(2) Uani 1 1 d . . .
F10 F 0.0703(13) 0.1589(16) 0.4206(12) 0.44(3) Uani 1 1 d D . .
F11 F 0.193(2) 0.2360(13) 0.5006(14) 0.325(19) Uani 1 1 d . . .
F12 F 0.098(2) 0.0016(15) 0.3955(11) 0.254(11) Uani 1 1 d . . .
C5 C 0.300(5) 0.882(4) 0.897(3) 0.35(4) Uani 1 1 d . . .
Cl3 Cl 0.2907(17) 0.9408(12) 0.8399(11) 0.232(9) Uani 0.56 1 d P . .
Cl3A Cl 0.2171(10) 0.8625(7) 0.9371(5) 0.096(3) Uani 0.44 1 d P . .
Cl4 Cl 0.4057(12) 0.9355(8) 0.9647(7) 0.268(6) Uani 1 1 d . . .
C6 C 0.021(4) 0.983(4) 0.844(3) 0.25(3) Uani 0.75 1 d P . .
Cl5 Cl 0.006(2) 0.9176(16) 0.7415(15) 0.44(2) Uani 0.75 1 d P . .
Cl6 Cl 0.0996(13) 1.0556(13) 0.8585(8) 0.237(7) Uani 0.75 1 d P . .
C7 C 0.200(3) 0.115(3) 0.683(3) 0.69(11) Uani 1 1 d D . .
H7A H 0.1649 0.0964 0.6353 0.823 Uiso 1 1 calc R . .
H7B H 0.1541 0.1265 0.7144 0.823 Uiso 1 1 calc R . .
Cl7 Cl 0.2905(9) 0.2078(11) 0.7019(8) 0.304(8) Uani 1 1 d . . .
Cl8 Cl 0.2673(10) 0.0330(12) 0.6952(7) 0.291(8) Uani 1 1 d D . .
C8 C 0.210(5) 0.566(3) 0.5979(16) 0.34(4) Uani 1 1 d . . .
H8A H 0.2613 0.6199 0.6243 0.407 Uiso 1 1 calc R . .
H8B H 0.2003 0.5260 0.6258 0.407 Uiso 1 1 calc R . .
Cl9 Cl 0.0963(8) 0.6071(9) 0.5750(6) 0.221(5) Uani 1 1 d . . .
Cl10 Cl 0.2397(11) 0.5084(9) 0.5254(6) 0.254(6) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Os Os -1.2165 7.6030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Os1 N4 160.5(7) . .
N2 Os1 N1 80.4(5) . .
N4 Os1 N1 91.9(9) . .
N2 Os1 N3 83.9(4) . .
N4 Os1 N3 77.7(9) . .
N1 Os1 N3 86.1(5) . .
N2 Os1 P1 103.5(3) . .
N4 Os1 P1 84.8(8) . .
N1 Os1 P1 175.8(4) . .
N3 Os1 P1 95.7(3) . .
N2 Os1 P2 100.1(3) . .
N4 Os1 P2 98.0(9) . .
N1 Os1 P2 91.5(4) . .
N3 Os1 P2 174.9(3) . .
P1 Os1 P2 86.44(12) . .
P4 Pd1 P3 84.20(11) . .
P4 Pd1 Cl1 166.80(13) . .
P3 Pd1 Cl1 90.41(13) . .
P4 Pd1 Cl2 93.61(17) . .
P3 Pd1 Cl2 177.77(18) . .
Cl1 Pd1 Cl2 91.65(17) . .
C21 P1 C11 99.5(7) . .
C21 P1 C1 107.3(5) . .
C11 P1 C1 102.5(5) . .
C21 P1 Os1 111.8(4) . .
C11 P1 Os1 125.5(6) . .
C1 P1 Os1 108.7(4) . .
C31 P2 C41 100.1(7) . .
C31 P2 C2 102.2(5) . .
C41 P2 C2 107.0(6) . .
C31 P2 Os1 124.0(5) . .
C41 P2 Os1 113.2(5) . .
C2 P2 Os1 108.8(4) . .
C51 P3 C61 105.4(7) . .
C51 P3 C3 106.1(5) . .
C61 P3 C3 106.5(5) . .
C51 P3 Pd1 117.6(4) . .
C61 P3 Pd1 111.5(4) . .
C3 P3 Pd1 109.2(3) . .
C71 P4 C81 105.7(5) . .
C71 P4 C4 105.4(5) . .
C81 P4 C4 105.4(5) . .
C71 P4 Pd1 123.1(4) . .
C81 P4 Pd1 105.4(4) . .
C4 P4 Pd1 110.5(4) . .
C1A N1 C5A 135.5(19) . .
C1A N1 Os1 123.0(9) . .
C5A N1 Os1 101.5(16) . .
C5B N2 C1B 108.7(17) . .
C5B N2 Os1 121.0(13) . .
C1B N2 Os1 129.8(12) . .
C1C N3 C5C 117.4(14) . .
C1C N3 Os1 125.1(11) . .
C5C N3 Os1 117.5(10) . .
C1D N4 C5D 114.3(18) . .
C1D N4 Os1 130.2(16) . .
C5D N4 Os1 113.5(16) . .
C4 C1 C2 90.2(8) . .
C4 C1 P1 120.2(8) . .
C2 C1 P1 115.3(7) . .
C4 C1 H1 109.9 . .
C2 C1 H1 109.9 . .
P1 C1 H1 109.9 . .
C1 C2 C3 90.0(8) . .
C1 C2 P2 115.5(7) . .
C3 C2 P2 119.3(7) . .
C1 C2 H2 110.2 . .
C3 C2 H2 110.2 . .
P2 C2 H2 110.2 . .
C2 C3 C4 89.3(8) . .
C2 C3 P3 118.6(7) . .
C4 C3 P3 112.5(7) . .
C2 C3 H3 111.5 . .
C4 C3 H3 111.5 . .
P3 C3 H3 111.5 . .
C1 C4 C3 90.3(8) . .
C1 C4 P4 115.9(7) . .
C3 C4 P4 113.1(7) . .
C1 C4 H4 111.9 . .
C3 C4 H4 111.9 . .
P4 C4 H4 111.9 . .
C12 C11 C16 117.3(16) . .
C12 C11 P1 117.6(15) . .
C16 C11 P1 125.0(11) . .
C11 C12 C13 120.2(18) . .
C11 C12 H12 119.9 . .
C13 C12 H12 119.9 . .
C14 C13 C12 121.7(17) . .
C14 C13 H13 119.2 . .
C12 C13 H13 119.2 . .
C13 C14 C15 115(2) . .
C13 C14 H14 122.5 . .
C15 C14 H14 122.5 . .
C16 C15 C14 127(2) . .
C16 C15 H15 116.3 . .
C14 C15 H15 116.3 . .
C15 C16 C11 118.0(18) . .
C15 C16 H16 121.0 . .
C11 C16 H16 121.0 . .
C22 C21 C26 117.9(13) . .
C22 C21 P1 117.9(10) . .
C26 C21 P1 123.6(11) . .
C21 C22 C23 123.1(14) . .
C21 C22 H22 118.5 . .
C23 C22 H22 118.5 . .
C22 C23 C24 117.8(13) . .
C22 C23 H23 121.1 . .
C24 C23 H23 121.1 . .
C25 C24 C23 119.4(13) . .
C25 C24 H24 120.3 . .
C23 C24 H24 120.3 . .
C26 C25 C24 119.6(14) . .
C26 C25 H25 120.2 . .
C24 C25 H25 120.2 . .
C25 C26 C21 122.0(13) . .
C25 C26 H26 119.0 . .
C21 C26 H26 119.0 . .
C32 C31 C36 119.6(14) . .
C32 C31 P2 123.1(11) . .
C36 C31 P2 117.2(13) . .
C31 C32 C33 120.4(16) . .
C31 C32 H32 119.8 . .
C33 C32 H32 119.8 . .
C34 C33 C32 118.5(19) . .
C34 C33 H33 120.7 . .
C32 C33 H33 120.7 . .
C35 C34 C33 122.4(17) . .
C35 C34 H34 118.8 . .
C33 C34 H34 118.8 . .
C34 C35 C36 121.5(17) . .
C34 C35 H35 119.2 . .
C36 C35 H35 119.2 . .
C35 C36 C31 117.6(18) . .
C35 C36 H36 121.2 . .
C31 C36 H36 121.2 . .
C46 C41 C42 119.6(15) . .
C46 C41 P2 116.6(12) . .
C42 C41 P2 123.1(12) . .
C41 C42 C43 120.9(14) . .
C41 C42 H42 119.6 . .
C43 C42 H42 119.5 . .
C44 C43 C42 117.6(16) . .
C44 C43 H43 121.2 . .
C42 C43 H43 121.2 . .
C45 C44 C43 121.0(16) . .
C45 C44 H44 119.5 . .
C43 C44 H44 119.5 . .
C44 C45 C46 120.3(16) . .
C44 C45 H45 119.9 . .
C46 C45 H45 119.9 . .
C41 C46 C45 120.2(16) . .
C41 C46 H46 119.9 . .
C45 C46 H46 119.9 . .
C52 C51 C56 114.7(15) . .
C52 C51 P3 124.8(13) . .
C56 C51 P3 120.4(12) . .
C51 C52 C53 120(2) . .
C51 C52 H52 120.0 . .
C53 C52 H52 119.9 . .
C54 C53 C52 127(3) . .
C54 C53 H53 116.6 . .
C52 C53 H53 116.7 . .
C55 C54 C53 113(2) . .
C55 C54 H54 123.4 . .
C53 C54 H54 123.4 . .
C54 C55 C56 125(3) . .
C54 C55 H55 117.5 . .
C56 C55 H55 117.5 . .
C55 C56 C51 120(2) . .
C55 C56 H56 119.8 . .
C51 C56 H56 119.8 . .
C66 C61 C62 118.8(12) . .
C66 C61 P3 119.2(10) . .
C62 C61 P3 121.9(10) . .
C63 C62 C61 118.8(15) . .
C63 C62 H62 120.6 . .
C61 C62 H62 120.6 . .
C64 C63 C62 120.7(16) . .
C64 C63 H63 119.6 . .
C62 C63 H63 119.6 . .
C65 C64 C63 120.9(16) . .
C65 C64 H64 119.6 . .
C63 C64 H64 119.6 . .
C64 C65 C66 121.1(17) . .
C64 C65 H65 119.5 . .
C66 C65 H65 119.4 . .
C61 C66 C65 119.7(14) . .
C61 C66 H66 120.2 . .
C65 C66 H66 120.2 . .
C76 C71 C72 118.9(12) . .
C76 C71 P4 122.6(11) . .
C72 C71 P4 118.0(9) . .
C73 C72 C71 118.9(12) . .
C73 C72 H72 120.6 . .
C71 C72 H72 120.6 . .
C72 C73 C74 121.4(14) . .
C72 C73 H73 119.3 . .
C74 C73 H73 119.3 . .
C75 C74 C73 119.5(14) . .
C75 C74 H74 120.3 . .
C73 C74 H74 120.3 . .
C74 C75 C76 120.2(14) . .
C74 C75 H75 119.9 . .
C76 C75 H75 119.9 . .
C71 C76 C75 121.0(15) . .
C71 C76 H76 119.5 . .
C75 C76 H76 119.5 . .
C86 C81 C82 119.2(12) . .
C86 C81 P4 124.2(10) . .
C82 C81 P4 116.4(10) . .
C83 C82 C81 119.4(15) . .
C83 C82 H82 120.3 . .
C81 C82 H82 120.3 . .
C82 C83 C84 119.9(17) . .
C82 C83 H83 120.0 . .
C84 C83 H83 120.0 . .
C85 C84 C83 120.9(14) . .
C85 C84 H84 119.6 . .
C83 C84 H84 119.6 . .
C84 C85 C86 117.7(15) . .
C84 C85 H85 121.2 . .
C86 C85 H85 121.2 . .
C81 C86 C85 122.9(14) . .
C81 C86 H86 118.6 . .
C85 C86 H86 118.6 . .
C2A C1A N1 123.1(17) . .
C2A C1A H1A 118.5 . .
N1 C1A H1A 118.5 . .
C1A C2A C3A 115(2) . .
C1A C2A H2A 122.7 . .
C3A C2A H2A 122.5 . .
C4A C3A C2A 109(2) . .
C4A C3A H3A 125.1 . .
C2A C3A H3A 125.6 . .
C5A C4A C3A 142(3) . .
C5A C4A H4A 108.8 . .
C3A C4A H4A 108.9 . .
C4A C5A C5B 135(2) . .
C4A C5A N1 95(3) . .
C5B C5A N1 131(2) . .
N2 C1B C2B 122(2) . .
N2 C1B H1B 119.0 . .
C2B C1B H1B 119.3 . .
C3B C2B C1B 116(3) . .
C3B C2B H2B 122.4 . .
C1B C2B H2B 122.1 . .
C4B C3B C2B 118(3) . .
C4B C3B H3B 120.0 . .
C2B C3B H3B 122.0 . .
C5B C4B C3B 115(4) . .
C5B C4B H4B 122.5 . .
C3B C4B H4B 122.8 . .
N2 C5B C4B 134(3) . .
N2 C5B C5A 103(2) . .
C4B C5B C5A 118(4) . .
C2C C1C N3 123.9(18) . .
C2C C1C H1C 118.0 . .
N3 C1C H1C 118.0 . .
C1C C2C C3C 118(2) . .
C1C C2C H2C 121.0 . .
C3C C2C H2C 121.0 . .
C4C C3C C2C 118(2) . .
C4C C3C H3C 121.2 . .
C2C C3C H3C 121.2 . .
C3C C4C C5C 125(2) . .
C3C C4C H4C 117.4 . .
C5C C4C H4C 117.4 . .
C4C C5C N3 117.5(15) . .
C4C C5C C5D 127.2(16) . .
N3 C5C C5D 114.7(13) . .
N4 C1D C2D 128.3(17) . .
N4 C1D H1D 115.9 . .
C2D C1D H1D 115.9 . .
C1D C2D C3D 114(2) . .
C1D C2D H2D 123.2 . .
C3D C2D H2D 123.2 . .
C4D C3D C2D 119(2) . .
C4D C3D H3D 120.3 . .
C2D C3D H3D 120.3 . .
C3D C4D C5D 120(2) . .
C3D C4D H4D 119.8 . .
C5D C4D H4D 119.8 . .
C5C C5D C4D 123.1(19) . .
C5C C5D N4 115.4(15) . .
C4D C5D N4 121(2) . .
F1 Sb1 F3 92.5(10) . .
F1 Sb1 F5 91.6(11) . .
F3 Sb1 F5 93.4(9) . .
F1 Sb1 F4 93.5(12) . .
F3 Sb1 F4 173.5(9) . .
F5 Sb1 F4 88.8(11) . .
F1 Sb1 F6 177.4(9) . .
F3 Sb1 F6 87.0(7) . .
F5 Sb1 F6 91.0(8) . .
F4 Sb1 F6 86.8(9) . .
F1 Sb1 F2 92.4(9) . .
F3 Sb1 F2 86.3(9) . .
F5 Sb1 F2 176.0(8) . .
F4 Sb1 F2 91.0(10) . .
F6 Sb1 F2 85.0(6) . .
F11 Sb2 F8 125.8(16) . .
F11 Sb2 F9 88.2(9) . .
F8 Sb2 F9 89.5(9) . .
F11 Sb2 F10 77.7(15) . .
F8 Sb2 F10 156.3(10) . .
F9 Sb2 F10 88.2(12) . .
F11 Sb2 F7 95.7(8) . .
F8 Sb2 F7 90.8(7) . .
F9 Sb2 F7 175.0(13) . .
F10 Sb2 F7 89.5(9) . .
F11 Sb2 F12 155.0(16) . .
F8 Sb2 F12 79.2(10) . .
F9 Sb2 F12 91.2(13) . .
F10 Sb2 F12 77.2(10) . .
F7 Sb2 F12 84.0(10) . .
Cl3A C5 Cl3 124(4) . .
Cl3A C5 Cl4 104(3) . .
Cl3 C5 Cl4 111(4) . .
Cl6 C6 Cl5 103(3) . .
Cl7 C7 Cl8 99(2) . .
Cl7 C7 H7A 112.0 . .
Cl8 C7 H7A 112.0 . .
Cl7 C7 H7B 112.0 . .
Cl8 C7 H7B 112.0 . .
H7A C7 H7B 109.7 . .
Cl10 C8 Cl9 106.9(19) . .
Cl10 C8 H8A 110.3 . .
Cl9 C8 H8A 110.3 . .
Cl10 C8 H8B 110.3 . .
Cl9 C8 H8B 110.3 . .
H8A C8 H8B 108.6 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Os1 N2 2.036(9) .
Os1 N4 2.073(16) .
Os1 N1 2.120(14) .
Os1 N3 2.126(11) .
Os1 P1 2.306(4) .
Os1 P2 2.323(4) .
Pd1 P4 2.234(3) .
Pd1 P3 2.236(3) .
Pd1 Cl1 2.338(4) .
Pd1 Cl2 2.344(4) .
P1 C21 1.855(14) .
P1 C11 1.861(16) .
P1 C1 1.884(11) .
P2 C31 1.840(14) .
P2 C41 1.857(16) .
P2 C2 1.876(11) .
P3 C51 1.801(12) .
P3 C61 1.814(12) .
P3 C3 1.846(10) .
P4 C71 1.812(12) .
P4 C81 1.818(11) .
P4 C4 1.831(11) .
N1 C1A 1.38(2) .
N1 C5A 1.420(18) .
N2 C5B 1.32(3) .
N2 C1B 1.352(17) .
N3 C1C 1.36(2) .
N3 C5C 1.368(17) .
N4 C1D 1.32(2) .
N4 C5D 1.51(4) .
C1 C4 1.548(13) .
C1 C2 1.557(17) .
C1 H1 0.9900 .
C2 C3 1.564(13) .
C2 H2 0.9900 .
C3 C4 1.564(16) .
C3 H3 0.9900 .
C4 H4 0.9900 .
C11 C12 1.353(19) .
C11 C16 1.40(3) .
C12 C13 1.42(3) .
C12 H12 0.9400 .
C13 C14 1.31(3) .
C13 H13 0.9400 .
C14 C15 1.35(3) .
C14 H14 0.9400 .
C15 C16 1.31(3) .
C15 H15 0.9400 .
C16 H16 0.9400 .
C21 C22 1.346(19) .
C21 C26 1.386(17) .
C22 C23 1.37(2) .
C22 H22 0.9400 .
C23 C24 1.41(2) .
C23 H23 0.9400 .
C24 C25 1.38(2) .
C24 H24 0.9400 .
C25 C26 1.348(19) .
C25 H25 0.9400 .
C26 H26 0.9400 .
C31 C32 1.38(2) .
C31 C36 1.41(2) .
C32 C33 1.39(2) .
C32 H32 0.9400 .
C33 C34 1.37(3) .
C33 H33 0.9400 .
C34 C35 1.30(2) .
C34 H34 0.9400 .
C35 C36 1.40(2) .
C35 H35 0.9400 .
C36 H36 0.9400 .
C41 C46 1.355(19) .
C41 C42 1.372(19) .
C42 C43 1.40(2) .
C42 H42 0.9400 .
C43 C44 1.38(2) .
C43 H43 0.9400 .
C44 C45 1.35(3) .
C44 H44 0.9400 .
C45 C46 1.38(2) .
C45 H45 0.9400 .
C46 H46 0.9400 .
C51 C52 1.35(2) .
C51 C56 1.38(2) .
C52 C53 1.36(3) .
C52 H52 0.9400 .
C53 C54 1.33(5) .
C53 H53 0.9400 .
C54 C55 1.30(5) .
C54 H54 0.9400 .
C55 C56 1.38(3) .
C55 H55 0.9400 .
C56 H56 0.9400 .
C61 C66 1.355(19) .
C61 C62 1.404(18) .
C62 C63 1.38(2) .
C62 H62 0.9400 .
C63 C64 1.35(3) .
C63 H63 0.9400 .
C64 C65 1.31(2) .
C64 H64 0.9400 .
C65 C66 1.39(2) .
C65 H65 0.9400 .
C66 H66 0.9400 .
C71 C76 1.368(16) .
C71 C72 1.403(17) .
C72 C73 1.38(2) .
C72 H72 0.9400 .
C73 C74 1.378(19) .
C73 H73 0.9400 .
C74 C75 1.35(2) .
C74 H74 0.9400 .
C75 C76 1.39(2) .
C75 H75 0.9400 .
C76 H76 0.9400 .
C81 C86 1.365(18) .
C81 C82 1.405(19) .
C82 C83 1.39(2) .
C82 H82 0.9400 .
C83 C84 1.40(3) .
C83 H83 0.9400 .
C84 C85 1.39(2) .
C84 H84 0.9400 .
C85 C86 1.395(17) .
C85 H85 0.9400 .
C86 H86 0.9400 .
C1A C2A 1.35(2) .
C1A H1A 0.9400 .
C2A C3A 1.49(4) .
C2A H2A 0.9400 .
C3A C4A 1.48(4) .
C3A H3A 0.9400 .
C4A C5A 1.40(5) .
C4A H4A 0.9400 .
C5A C5B 1.44(5) .
C1B C2B 1.46(3) .
C1B H1B 0.9400 .
C2B C3B 1.39(6) .
C2B H2B 0.9400 .
C3B C4B 1.27(6) .
C3B H3B 0.9400 .
C4B C5B 1.30(3) .
C4B H4B 0.9400 .
C1C C2C 1.35(3) .
C1C H1C 0.9400 .
C2C C3C 1.38(3) .
C2C H2C 0.9400 .
C3C C4C 1.32(3) .
C3C H3C 0.9400 .
C4C C5C 1.36(2) .
C4C H4C 0.9400 .
C5C C5D 1.40(2) .
C1D C2D 1.36(2) .
C1D H1D 0.9400 .
C2D C3D 1.57(4) .
C2D H2D 0.9400 .
C3D C4D 1.35(3) .
C3D H3D 0.9400 .
C4D C5D 1.41(3) .
C4D H4D 0.9400 .
Sb1 F1 1.728(17) .
Sb1 F3 1.784(18) .
Sb1 F5 1.805(15) .
Sb1 F4 1.864(18) .
Sb1 F6 1.898(13) .
Sb1 F2 1.925(14) .
Sb2 F11 1.618(19) .
Sb2 F8 1.789(17) .
Sb2 F9 1.80(3) .
Sb2 F10 1.820(19) .
Sb2 F7 1.831(12) .
Sb2 F12 2.02(2) .
C5 Cl3A 1.58(8) .
C5 Cl3 1.70(5) .
C5 Cl4 1.82(5) .
C6 Cl6 1.40(4) .
C6 Cl5 2.03(6) .
C7 Cl7 1.70(5) .
C7 Cl8 1.73(5) .
C7 H7A 0.9800 .
C7 H7B 0.9800 .
C8 Cl10 1.64(5) .
C8 Cl9 1.87(7) .
C8 H8A 0.9800 .
C8 H8B 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
N2 Os1 P1 C21 121.7(6) . . . .
N4 Os1 P1 C21 -40.4(11) . . . .
N3 Os1 P1 C21 36.6(6) . . . .
P2 Os1 P1 C21 -138.8(5) . . . .
N2 Os1 P1 C11 1.5(6) . . . .
N4 Os1 P1 C11 -160.7(11) . . . .
N3 Os1 P1 C11 -83.7(6) . . . .
P2 Os1 P1 C11 101.0(5) . . . .
N2 Os1 P1 C1 -120.0(5) . . . .
N4 Os1 P1 C1 77.8(10) . . . .
N3 Os1 P1 C1 154.8(5) . . . .
P2 Os1 P1 C1 -20.5(4) . . . .
N2 Os1 P2 C31 2.4(6) . . . .
N4 Os1 P2 C31 175.1(10) . . . .
N1 Os1 P2 C31 83.0(6) . . . .
P1 Os1 P2 C31 -100.7(5) . . . .
N2 Os1 P2 C41 -118.8(6) . . . .
N4 Os1 P2 C41 53.8(10) . . . .
N1 Os1 P2 C41 -38.3(6) . . . .
P1 Os1 P2 C41 138.0(5) . . . .
N2 Os1 P2 C2 122.4(5) . . . .
N4 Os1 P2 C2 -65.0(9) . . . .
N1 Os1 P2 C2 -157.1(5) . . . .
P1 Os1 P2 C2 19.3(4) . . . .
P4 Pd1 P3 C51 -149.8(5) . . . .
Cl1 Pd1 P3 C51 42.3(5) . . . .
P4 Pd1 P3 C61 88.3(5) . . . .
Cl1 Pd1 P3 C61 -79.6(5) . . . .
P4 Pd1 P3 C3 -29.0(3) . . . .
Cl1 Pd1 P3 C3 163.0(3) . . . .
P3 Pd1 P4 C71 151.8(4) . . . .
Cl1 Pd1 P4 C71 -141.9(7) . . . .
Cl2 Pd1 P4 C71 -28.6(4) . . . .
P3 Pd1 P4 C81 -87.2(4) . . . .
Cl1 Pd1 P4 C81 -20.9(8) . . . .
Cl2 Pd1 P4 C81 92.4(5) . . . .
P3 Pd1 P4 C4 26.2(4) . . . .
Cl1 Pd1 P4 C4 92.5(7) . . . .
Cl2 Pd1 P4 C4 -154.2(4) . . . .
N2 Os1 N1 C1A -174.1(13) . . . .
N4 Os1 N1 C1A -12.1(15) . . . .
N3 Os1 N1 C1A -89.6(13) . . . .
P2 Os1 N1 C1A 85.9(12) . . . .
N2 Os1 N1 C5A 8.2(13) . . . .
N4 Os1 N1 C5A 170.2(16) . . . .
N3 Os1 N1 C5A 92.7(13) . . . .
P2 Os1 N1 C5A -91.8(13) . . . .
N4 Os1 N2 C5B -86(4) . . . .
N1 Os1 N2 C5B -18(2) . . . .
N3 Os1 N2 C5B -105(2) . . . .
P1 Os1 N2 C5B 161(2) . . . .
P2 Os1 N2 C5B 72(2) . . . .
N4 Os1 N2 C1B 104(4) . . . .
N1 Os1 N2 C1B 171.9(14) . . . .
N3 Os1 N2 C1B 84.9(14) . . . .
P1 Os1 N2 C1B -9.5(14) . . . .
P2 Os1 N2 C1B -98.3(14) . . . .
N2 Os1 N3 C1C -12.7(12) . . . .
N4 Os1 N3 C1C 173.8(15) . . . .
N1 Os1 N3 C1C -93.4(12) . . . .
P1 Os1 N3 C1C 90.4(12) . . . .
N2 Os1 N3 C5C 169.2(11) . . . .
N4 Os1 N3 C5C -4.4(13) . . . .
N1 Os1 N3 C5C 88.4(11) . . . .
P1 Os1 N3 C5C -87.8(10) . . . .
N2 Os1 N4 C1D 175.0(14) . . . .
N1 Os1 N4 C1D 109(3) . . . .
N3 Os1 N4 C1D -166(3) . . . .
P1 Os1 N4 C1D -68(3) . . . .
P2 Os1 N4 C1D 17(3) . . . .
N2 Os1 N4 C5D -22(5) . . . .
N1 Os1 N4 C5D -88.0(19) . . . .
N3 Os1 N4 C5D -2.4(17) . . . .
P1 Os1 N4 C5D 94.6(19) . . . .
P2 Os1 N4 C5D -179.7(18) . . . .
C21 P1 C1 C4 -114.6(10) . . . .
C11 P1 C1 C4 -10.4(11) . . . .
Os1 P1 C1 C4 124.3(8) . . . .
C21 P1 C1 C2 139.2(8) . . . .
C11 P1 C1 C2 -116.6(9) . . . .
Os1 P1 C1 C2 18.1(8) . . . .
C4 C1 C2 C3 -3.8(8) . . . .
P1 C1 C2 C3 120.1(7) . . . .
C4 C1 C2 P2 -126.6(7) . . . .
P1 C1 C2 P2 -2.7(10) . . . .
C31 P2 C2 C1 119.0(9) . . . .
C41 P2 C2 C1 -136.4(9) . . . .
Os1 P2 C2 C1 -13.7(8) . . . .
C31 P2 C2 C3 13.5(10) . . . .
C41 P2 C2 C3 118.1(10) . . . .
Os1 P2 C2 C3 -119.2(8) . . . .
C1 C2 C3 C4 3.8(8) . . . .
P2 C2 C3 C4 123.3(8) . . . .
C1 C2 C3 P3 119.2(8) . . . .
P2 C2 C3 P3 -121.3(7) . . . .
C51 P3 C3 C2 52.1(10) . . . .
C61 P3 C3 C2 164.1(9) . . . .
Pd1 P3 C3 C2 -75.5(8) . . . .
C51 P3 C3 C4 154.3(8) . . . .
C61 P3 C3 C4 -93.7(8) . . . .
Pd1 P3 C3 C4 26.8(7) . . . .
C2 C1 C4 C3 3.8(8) . . . .
P1 C1 C4 C3 -116.0(8) . . . .
C2 C1 C4 P4 -112.3(9) . . . .
P1 C1 C4 P4 128.0(8) . . . .
C2 C3 C4 C1 -3.8(8) . . . .
P3 C3 C4 C1 -124.7(7) . . . .
C2 C3 C4 P4 114.8(7) . . . .
P3 C3 C4 P4 -6.1(9) . . . .
C71 P4 C4 C1 -49.8(10) . . . .
C81 P4 C4 C1 -161.3(8) . . . .
Pd1 P4 C4 C1 85.3(8) . . . .
C71 P4 C4 C3 -152.1(7) . . . .
C81 P4 C4 C3 96.3(8) . . . .
Pd1 P4 C4 C3 -17.1(8) . . . .
C21 P1 C11 C12 -172.9(16) . . . .
C1 P1 C11 C12 76.8(17) . . . .
Os1 P1 C11 C12 -47.3(17) . . . .
C21 P1 C11 C16 11.3(16) . . . .
C1 P1 C11 C16 -99.0(15) . . . .
Os1 P1 C11 C16 136.8(15) . . . .
C16 C11 C12 C13 -3(3) . . . .
P1 C11 C12 C13 -179(2) . . . .
C11 C12 C13 C14 3(4) . . . .
C12 C13 C14 C15 1(4) . . . .
C13 C14 C15 C16 -7(4) . . . .
C14 C15 C16 C11 8(4) . . . .
C12 C11 C16 C15 -3(3) . . . .
P1 C11 C16 C15 173.3(17) . . . .
C11 P1 C21 C22 62.5(12) . . . .
C1 P1 C21 C22 168.9(11) . . . .
Os1 P1 C21 C22 -72.0(12) . . . .
C11 P1 C21 C26 -126.2(13) . . . .
C1 P1 C21 C26 -19.8(14) . . . .
Os1 P1 C21 C26 99.3(12) . . . .
C26 C21 C22 C23 3(2) . . . .
P1 C21 C22 C23 174.9(11) . . . .
C21 C22 C23 C24 -5(2) . . . .
C22 C23 C24 C25 4(2) . . . .
C23 C24 C25 C26 -2(2) . . . .
C24 C25 C26 C21 0(3) . . . .
C22 C21 C26 C25 0(2) . . . .
P1 C21 C26 C25 -171.5(13) . . . .
C41 P2 C31 C32 -22.6(13) . . . .
C2 P2 C31 C32 87.3(12) . . . .
Os1 P2 C31 C32 -149.7(10) . . . .
C41 P2 C31 C36 161.4(12) . . . .
C2 P2 C31 C36 -88.7(12) . . . .
Os1 P2 C31 C36 34.3(13) . . . .
C36 C31 C32 C33 2(2) . . . .
P2 C31 C32 C33 -173.5(12) . . . .
C31 C32 C33 C34 -1(2) . . . .
C32 C33 C34 C35 -1(3) . . . .
C33 C34 C35 C36 2(3) . . . .
C34 C35 C36 C31 -1(3) . . . .
C32 C31 C36 C35 -1(2) . . . .
P2 C31 C36 C35 175.0(13) . . . .
C31 P2 C41 C46 -59.2(14) . . . .
C2 P2 C41 C46 -165.4(13) . . . .
Os1 P2 C41 C46 74.8(14) . . . .
C31 P2 C41 C42 130.3(15) . . . .
C2 P2 C41 C42 24.1(16) . . . .
Os1 P2 C41 C42 -95.7(14) . . . .
C46 C41 C42 C43 3(3) . . . .
P2 C41 C42 C43 172.8(14) . . . .
C41 C42 C43 C44 -1(3) . . . .
C42 C43 C44 C45 3(3) . . . .
C43 C44 C45 C46 -6(4) . . . .
C42 C41 C46 C45 -6(3) . . . .
P2 C41 C46 C45 -176.6(15) . . . .
C44 C45 C46 C41 7(3) . . . .
C61 P3 C51 C52 -18.4(14) . . . .
C3 P3 C51 C52 94.3(14) . . . .
Pd1 P3 C51 C52 -143.3(12) . . . .
C61 P3 C51 C56 164.2(11) . . . .
C3 P3 C51 C56 -83.1(12) . . . .
Pd1 P3 C51 C56 39.3(13) . . . .
C56 C51 C52 C53 -1(2) . . . .
P3 C51 C52 C53 -178.1(15) . . . .
C51 C52 C53 C54 0(4) . . . .
C52 C53 C54 C55 0(5) . . . .
C53 C54 C55 C56 1(4) . . . .
C54 C55 C56 C51 -2(4) . . . .
C52 C51 C56 C55 2(2) . . . .
P3 C51 C56 C55 179.3(14) . . . .
C51 P3 C61 C66 -97.2(14) . . . .
C3 P3 C61 C66 150.4(13) . . . .
Pd1 P3 C61 C66 31.5(14) . . . .
C51 P3 C61 C62 83.6(13) . . . .
C3 P3 C61 C62 -28.8(14) . . . .
Pd1 P3 C61 C62 -147.8(11) . . . .
C66 C61 C62 C63 1(2) . . . .
P3 C61 C62 C63 -179.3(14) . . . .
C61 C62 C63 C64 0(3) . . . .
C62 C63 C64 C65 -2(4) . . . .
C63 C64 C65 C66 3(5) . . . .
C62 C61 C66 C65 -1(3) . . . .
P3 C61 C66 C65 179.7(18) . . . .
C64 C65 C66 C61 -1(4) . . . .
C81 P4 C71 C76 -145.6(11) . . . .
C4 P4 C71 C76 103.0(12) . . . .
Pd1 P4 C71 C76 -24.8(12) . . . .
C81 P4 C71 C72 42.0(10) . . . .
C4 P4 C71 C72 -69.3(10) . . . .
Pd1 P4 C71 C72 162.8(8) . . . .
C76 C71 C72 C73 2.8(19) . . . .
P4 C71 C72 C73 175.4(11) . . . .
C71 C72 C73 C74 0(2) . . . .
C72 C73 C74 C75 -3(2) . . . .
C73 C74 C75 C76 3(2) . . . .
C72 C71 C76 C75 -3(2) . . . .
P4 C71 C76 C75 -175.5(12) . . . .
C74 C75 C76 C71 1(3) . . . .
C71 P4 C81 C86 -120.0(11) . . . .
C4 P4 C81 C86 -8.7(13) . . . .
Pd1 P4 C81 C86 108.2(11) . . . .
C71 P4 C81 C82 64.3(13) . . . .
C4 P4 C81 C82 175.6(12) . . . .
Pd1 P4 C81 C82 -67.5(12) . . . .
C86 C81 C82 C83 1(2) . . . .
P4 C81 C82 C83 177.4(15) . . . .
C81 C82 C83 C84 -2(3) . . . .
C82 C83 C84 C85 1(3) . . . .
C83 C84 C85 C86 0(3) . . . .
C82 C81 C86 C85 0(2) . . . .
P4 C81 C86 C85 -175.6(10) . . . .
C84 C85 C86 C81 -1(2) . . . .
C5A N1 C1A C2A -3(3) . . . .
Os1 N1 C1A C2A -179.3(14) . . . .
N1 C1A C2A C3A 6(3) . . . .
C1A C2A C3A C4A -5(3) . . . .
C2A C3A C4A C5A 1(5) . . . .
C3A C4A C5A C5B 178(3) . . . .
C3A C4A C5A N1 3(5) . . . .
C1A N1 C5A C4A -2(3) . . . .
Os1 N1 C5A C4A 175.6(15) . . . .
C1A N1 C5A C5B -178(3) . . . .
Os1 N1 C5A C5B 0(4) . . . .
C5B N2 C1B C2B 8(3) . . . .
Os1 N2 C1B C2B 179.1(18) . . . .
N2 C1B C2B C3B -16(5) . . . .
C1B C2B C3B C4B 27(8) . . . .
C2B C3B C4B C5B -29(8) . . . .
C1B N2 C5B C4B -13(6) . . . .
Os1 N2 C5B C4B 175(4) . . . .
C1B N2 C5B C5A -168(2) . . . .
Os1 N2 C5B C5A 20(3) . . . .
C3B C4B C5B N2 24(7) . . . .
C3B C4B C5B C5A 177(4) . . . .
C4A C5A C5B N2 174(3) . . . .
N1 C5A C5B N2 -12(5) . . . .
C4A C5A C5B C4B 13(6) . . . .
N1 C5A C5B C4B -172(2) . . . .
C5C N3 C1C C2C 2(2) . . . .
Os1 N3 C1C C2C -176.6(13) . . . .
N3 C1C C2C C3C -4(3) . . . .
C1C C2C C3C C4C 0(3) . . . .
C2C C3C C4C C5C 6(3) . . . .
C3C C4C C5C N3 -9(3) . . . .
C3C C4C C5C C5D 162.4(19) . . . .
C1C N3 C5C C4C 5(2) . . . .
Os1 N3 C5C C4C -177.1(11) . . . .
C1C N3 C5C C5D -167.6(14) . . . .
Os1 N3 C5C C5D 10.7(18) . . . .
C5D N4 C1D C2D 22(4) . . . .
Os1 N4 C1D C2D -175(2) . . . .
N4 C1D C2D C3D -19(4) . . . .
C1D C2D C3D C4D 10(4) . . . .
C2D C3D C4D C5D -5(4) . . . .
C4C C5C C5D C4D 6(3) . . . .
N3 C5C C5D C4D 177.1(18) . . . .
C4C C5C C5D N4 176(2) . . . .
N3 C5C C5D N4 -13(3) . . . .
C3D C4D C5D C5C 178(2) . . . .
C3D C4D C5D N4 8(3) . . . .
C1D N4 C5D C5C 175(2) . . . .
Os1 N4 C5D C5C 9(3) . . . .
C1D N4 C5D C4D -15(4) . . . .
Os1 N4 C5D C4D 179.4(16) . . . .
