#------------------------------------------------------------------------------
#$Date: 2019-11-23 01:10:26 +0200 (Sat, 23 Nov 2019) $
#$Revision: 231734 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/63/4346347.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4346347
loop_
_publ_author_name
'Guo, Peng-Hu'
'Liu, Jiang'
'Wu, Zi-Hao'
'Yan, Hua'
'Chen, Yan-Cong'
'Jia, Jian-Hua'
'Tong, Ming-Liang'
_publ_section_title
;
 Single-Molecule-Magnet Behavior in a [2 × 2] Grid Dy(III)4 Cluster
 and a Dysprosium-Doped Y(III)4 Cluster.
;
_journal_issue                   16
_journal_name_full               'Inorganic chemistry'
_journal_page_first              8087
_journal_page_last               8092
_journal_paper_doi               10.1021/acs.inorgchem.5b01322
_journal_volume                  54
_journal_year                    2015
_chemical_formula_sum            'C52 H40 Dy4 N24 O18'
_chemical_formula_weight         1939.08
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 92.784(1)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   11.9694(4)
_cell_length_b                   17.0199(4)
_cell_length_c                   15.5030(5)
_cell_measurement_temperature    298(2)
_cell_volume                     3154.51(16)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.985
_diffrn_measured_fraction_theta_max 0.985
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0498
_diffrn_reflns_av_sigmaI/netI    0.0506
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            23090
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         3.19
_exptl_absorpt_coefficient_mu    4.773
_exptl_absorpt_correction_T_max  0.6733
_exptl_absorpt_correction_T_min  0.5156
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.041
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1856
_exptl_crystal_size_max          0.16
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.09
_refine_diff_density_max         1.877
_refine_diff_density_min         -2.724
_refine_diff_density_rms         0.164
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.108
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     443
_refine_ls_number_reflns         7121
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.110
_refine_ls_R_factor_all          0.0617
_refine_ls_R_factor_gt           0.0428
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0477P)²+5.6798P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0966
_refine_ls_wR_factor_ref         0.1133
_reflns_number_gt                5419
_reflns_number_total             7121
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic5b01322_si_002.cif
_cod_data_source_block           dym
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               4346347
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Dy1 Dy 0.92211(3) 0.067415(15) 0.306792(18) 0.03867(10) Uani 1 1 d .
Dy2 Dy 0.81344(3) -0.137399(17) 0.524152(18) 0.04243(11) Uani 1 1 d .
O1 O 1.0491(5) 0.0661(3) 0.4152(3) 0.0646(14) Uani 1 1 d .
H1O H 1.0194 0.0290 0.4437 0.077 Uiso 1 1 d R
O2 O 1.0345(5) 0.1647(3) 0.2592(3) 0.0606(13) Uani 1 1 d .
O3 O 1.1804(5) 0.1987(3) 0.3436(3) 0.0670(14) Uani 1 1 d .
O4 O 0.8302(5) 0.1097(3) 0.1603(3) 0.0641(14) Uani 1 1 d .
O5 O 0.7656(4) 0.0102(3) 0.2261(3) 0.0549(12) Uani 1 1 d .
O6 O 0.6868(6) 0.0463(4) 0.1028(4) 0.091(2) Uani 1 1 d .
O7 O 0.6682(5) -0.1671(3) 0.4133(3) 0.0626(13) Uani 1 1 d .
O8 O 0.6769(6) -0.2455(3) 0.5201(4) 0.0725(16) Uani 1 1 d .
O9 O 0.5395(6) -0.2562(4) 0.4257(5) 0.094(2) Uani 1 1 d .
N1 N 1.0325(5) 0.0026(3) 0.1931(3) 0.0485(14) Uani 1 1 d .
N2 N 0.9501(5) -0.0763(3) 0.3310(3) 0.0396(11) Uani 1 1 d .
N3 N 0.9310(5) -0.1299(3) 0.3952(3) 0.0406(12) Uani 1 1 d .
N4 N 1.0526(6) -0.1844(3) 0.3067(4) 0.0541(15) Uani 1 1 d .
N5 N 0.9320(5) -0.2601(3) 0.5013(3) 0.0514(14) Uani 1 1 d .
N6 N 0.8122(5) 0.1901(3) 0.3307(3) 0.0492(14) Uani 1 1 d .
N7 N 0.7887(5) 0.0542(3) 0.4234(3) 0.0404(12) Uani 1 1 d .
N8 N 0.7541(5) -0.0032(3) 0.4785(3) 0.0408(12) Uani 1 1 d .
N9 N 0.6567(5) 0.1073(3) 0.5036(4) 0.0524(15) Uani 1 1 d .
N10 N 0.6473(5) -0.0855(3) 0.6033(4) 0.0543(15) Uani 1 1 d .
N11 N 0.7577(6) 0.0558(4) 0.1604(4) 0.0534(15) Uani 1 1 d .
N12 N 0.6252(6) -0.2239(4) 0.4517(5) 0.0618(17) Uani 1 1 d .
C1 C 1.0670(7) 0.0413(4) 0.1229(5) 0.060(2) Uani 1 1 d .
H1 H 1.0483 0.0940 0.1157 0.072 Uiso 1 1 calc R
C2 C 1.1284(8) 0.0053(5) 0.0623(5) 0.065(2) Uani 1 1 d .
H2 H 1.1499 0.0334 0.0144 0.078 Uiso 1 1 calc R
C3 C 1.1584(8) -0.0715(5) 0.0718(5) 0.072(3) Uani 1 1 d .
H3 H 1.2001 -0.0963 0.0307 0.087 Uiso 1 1 calc R
C4 C 1.1252(8) -0.1122(5) 0.1443(5) 0.067(2) Uani 1 1 d .
H4 H 1.1441 -0.1648 0.1525 0.081 Uiso 1 1 calc R
C5 C 1.0635(6) -0.0728(4) 0.2040(4) 0.0450(15) Uani 1 1 d .
C6 C 1.0236(6) -0.1120(4) 0.2811(4) 0.0465(16) Uani 1 1 d .
C7 C 0.9939(6) -0.1927(4) 0.3775(4) 0.0484(16) Uani 1 1 d .
C8 C 1.0001(6) -0.2616(4) 0.4349(4) 0.0483(16) Uani 1 1 d .
C9 C 1.0730(7) -0.3230(4) 0.4216(5) 0.063(2) Uani 1 1 d .
H9 H 1.1199 -0.3222 0.3756 0.076 Uiso 1 1 calc R
C10 C 1.0742(8) -0.3856(5) 0.4784(6) 0.072(2) Uani 1 1 d .
H10 H 1.1223 -0.4277 0.4709 0.086 Uiso 1 1 calc R
C11 C 1.0052(8) -0.3855(5) 0.5452(5) 0.070(2) Uani 1 1 d .
H11 H 1.0053 -0.4273 0.5840 0.084 Uiso 1 1 calc R
C12 C 0.9353(7) -0.3227(4) 0.5544(5) 0.062(2) Uani 1 1 d .
H12 H 0.8874 -0.3233 0.5999 0.075 Uiso 1 1 calc R
C13 C 0.8207(7) 0.2554(4) 0.2811(5) 0.059(2) Uani 1 1 d .
H13 H 0.8694 0.2546 0.2362 0.070 Uiso 1 1 calc R
C14 C 0.7602(7) 0.3225(4) 0.2947(5) 0.059(2) Uani 1 1 d .
H14 H 0.7685 0.3664 0.2599 0.071 Uiso 1 1 calc R
C15 C 0.6869(7) 0.3237(4) 0.3609(5) 0.061(2) Uani 1 1 d .
H15 H 0.6459 0.3688 0.3716 0.073 Uiso 1 1 calc R
C16 C 0.6754(7) 0.2577(4) 0.4106(5) 0.058(2) Uani 1 1 d .
H16 H 0.6261 0.2571 0.4552 0.070 Uiso 1 1 calc R
C17 C 0.7390(6) 0.1916(3) 0.3931(4) 0.0454(15) Uani 1 1 d .
C18 C 0.7274(6) 0.1177(4) 0.4413(4) 0.0448(15) Uani 1 1 d .
C19 C 0.6757(6) 0.0327(4) 0.5242(4) 0.0469(16) Uani 1 1 d .
C20 C 0.6165(6) -0.0108(4) 0.5901(4) 0.0501(17) Uani 1 1 d .
C21 C 0.5322(7) 0.0256(5) 0.6340(5) 0.063(2) Uani 1 1 d .
H21 H 0.5137 0.0780 0.6238 0.076 Uiso 1 1 calc R
C22 C 0.4769(8) -0.0183(6) 0.6934(6) 0.079(3) Uani 1 1 d .
H22 H 0.4206 0.0043 0.7244 0.094 Uiso 1 1 calc R
C23 C 0.5059(8) -0.0961(6) 0.7063(5) 0.078(3) Uani 1 1 d .
H23 H 0.4681 -0.1267 0.7451 0.093 Uiso 1 1 calc R
C24 C 0.5906(8) -0.1275(5) 0.6615(5) 0.071(2) Uani 1 1 d .
H24 H 0.6102 -0.1797 0.6713 0.085 Uiso 1 1 calc R
C25 C 1.1233(6) 0.2017(4) 0.2738(5) 0.0531(17) Uani 1 1 d .
C26 C 1.1649(11) 0.2585(7) 0.2068(7) 0.108(4) Uani 1 1 d U
H26A H 1.1612 0.2337 0.1511 0.162 Uiso 1 1 calc R
H26B H 1.2409 0.2729 0.2218 0.162 Uiso 1 1 calc R
H26C H 1.1188 0.3047 0.2051 0.162 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Dy1 O2 81.90(19) . .
O1 Dy1 O5 151.63(17) . .
O2 Dy1 O5 125.60(17) . .
O1 Dy1 N7 83.6(2) . .
O2 Dy1 N7 135.49(18) . .
O5 Dy1 N7 80.20(17) . .
O1 Dy1 N2 78.07(18) . .
O2 Dy1 N2 133.17(19) . .
O5 Dy1 N2 77.11(17) . .
N7 Dy1 N2 83.58(15) . .
O1 Dy1 N6 104.0(2) . .
O2 Dy1 N6 76.39(19) . .
O5 Dy1 N6 90.75(19) . .
N7 Dy1 N6 66.80(16) . .
N2 Dy1 N6 149.62(17) . .
O1 Dy1 N1 99.4(2) . .
O2 Dy1 N1 75.70(18) . .
O5 Dy1 N1 83.11(19) . .
N7 Dy1 N1 148.42(16) . .
N2 Dy1 N1 66.59(16) . .
N6 Dy1 N1 140.25(17) . .
O1 Dy1 O4 157.08(18) . .
O2 Dy1 O4 75.23(18) . .
O5 Dy1 O4 50.72(16) . .
N7 Dy1 O4 113.90(18) . .
N2 Dy1 O4 117.04(17) . .
N6 Dy1 O4 72.11(17) . .
N1 Dy1 O4 73.79(18) . .
O1 Dy1 N11 175.37(18) . .
O2 Dy1 N11 100.51(18) . .
O5 Dy1 N11 25.31(15) . .
N7 Dy1 N11 97.25(17) . .
N2 Dy1 N11 97.48(17) . .
N6 Dy1 N11 80.42(18) . .
N1 Dy1 N11 77.49(19) . .
O4 Dy1 N11 25.41(16) . .
O1 Dy1 H1O 20.2 . .
O2 Dy1 H1O 102.1 . .
O5 Dy1 H1O 131.7 . .
N7 Dy1 H1O 69.0 . .
N2 Dy1 H1O 63.6 . .
N6 Dy1 H1O 108.9 . .
N1 Dy1 H1O 104.2 . .
O4 Dy1 H1O 177.0 . .
N11 Dy1 H1O 157.0 . .
O1 Dy2 O3 83.07(19) 3_756 3_756
O1 Dy2 O7 154.40(18) 3_756 .
O3 Dy2 O7 121.71(19) 3_756 .
O1 Dy2 O8 154.0(2) 3_756 .
O3 Dy2 O8 71.1(2) 3_756 .
O7 Dy2 O8 51.42(19) . .
O1 Dy2 N8 79.24(19) 3_756 .
O3 Dy2 N8 131.87(18) 3_756 .
O7 Dy2 N8 78.79(17) . .
O8 Dy2 N8 120.0(2) . .
O1 Dy2 N3 82.88(19) 3_756 .
O3 Dy2 N3 137.80(19) 3_756 .
O7 Dy2 N3 81.77(18) . .
O8 Dy2 N3 114.60(18) . .
N8 Dy2 N3 83.66(15) . .
O1 Dy2 N10 100.8(2) 3_756 .
O3 Dy2 N10 73.7(2) 3_756 .
O7 Dy2 N10 82.2(2) . .
O8 Dy2 N10 74.8(2) . .
N8 Dy2 N10 66.37(17) . .
N3 Dy2 N10 148.23(17) . .
O1 Dy2 N5 95.8(2) 3_756 .
O3 Dy2 N5 76.06(19) 3_756 .
O7 Dy2 N5 96.57(19) . .
O8 Dy2 N5 76.0(2) . .
N8 Dy2 N5 149.73(16) . .
N3 Dy2 N5 66.07(16) . .
N10 Dy2 N5 143.24(18) . .
O1 Dy2 N12 176.27(19) 3_756 .
O3 Dy2 N12 96.1(2) 3_756 .
O7 Dy2 N12 25.78(17) . .
O8 Dy2 N12 25.75(18) . .
N8 Dy2 N12 98.73(19) . .
N3 Dy2 N12 100.06(18) . .
N10 Dy2 N12 75.53(19) . .
N5 Dy2 N12 87.55(19) . .
Dy1 O1 Dy2 141.8(2) . 3_756
Dy1 O1 H1O 96.4 . .
Dy2 O1 H1O 120.2 3_756 .
C25 O2 Dy1 145.0(5) . .
C25 O3 Dy2 141.4(5) . 3_756
N11 O4 Dy1 93.5(4) . .
N11 O5 Dy1 101.2(4) . .
N12 O7 Dy2 96.9(5) . .
N12 O8 Dy2 95.9(4) . .
C5 N1 C1 118.2(6) . .
C5 N1 Dy1 118.9(4) . .
C1 N1 Dy1 122.8(4) . .
C6 N2 N3 104.7(5) . .
C6 N2 Dy1 116.3(4) . .
N3 N2 Dy1 137.0(4) . .
C7 N3 N2 105.3(5) . .
C7 N3 Dy2 117.7(4) . .
N2 N3 Dy2 137.0(4) . .
C6 N4 C7 101.7(5) . .
C8 N5 C12 116.9(6) . .
C8 N5 Dy2 118.9(4) . .
C12 N5 Dy2 124.2(5) . .
C17 N6 C13 117.6(6) . .
C17 N6 Dy1 119.4(4) . .
C13 N6 Dy1 123.0(4) . .
C18 N7 N8 105.1(5) . .
C18 N7 Dy1 117.1(4) . .
N8 N7 Dy1 137.8(4) . .
C19 N8 N7 104.0(5) . .
C19 N8 Dy2 117.6(4) . .
N7 N8 Dy2 137.7(4) . .
C19 N9 C18 101.3(5) . .
C20 N10 C24 117.3(6) . .
C20 N10 Dy2 118.2(4) . .
C24 N10 Dy2 124.4(5) . .
O6 N11 O4 123.6(6) . .
O6 N11 O5 121.8(7) . .
O4 N11 O5 114.6(6) . .
O6 N11 Dy1 175.3(5) . .
O4 N11 Dy1 61.1(4) . .
O5 N11 Dy1 53.5(3) . .
O9 N12 O8 121.5(7) . .
O9 N12 O7 123.2(8) . .
O8 N12 O7 115.3(7) . .
O9 N12 Dy2 174.0(5) . .
O8 N12 Dy2 58.4(4) . .
O7 N12 Dy2 57.3(4) . .
N1 C1 C2 122.0(7) . .
N1 C1 H1 119.0 . .
C2 C1 H1 119.0 . .
C3 C2 C1 120.3(7) . .
C3 C2 H2 119.9 . .
C1 C2 H2 119.9 . .
C2 C3 C4 118.7(7) . .
C2 C3 H3 120.7 . .
C4 C3 H3 120.7 . .
C5 C4 C3 118.7(7) . .
C5 C4 H4 120.7 . .
C3 C4 H4 120.7 . .
N1 C5 C4 122.1(6) . .
N1 C5 C6 116.0(5) . .
C4 C5 C6 121.9(6) . .
N4 C6 N2 114.4(5) . .
N4 C6 C5 124.9(6) . .
N2 C6 C5 120.6(5) . .
N4 C7 N3 114.0(5) . .
N4 C7 C8 124.5(6) . .
N3 C7 C8 121.5(6) . .
N5 C8 C9 122.6(6) . .
N5 C8 C7 115.6(6) . .
C9 C8 C7 121.8(6) . .
C10 C9 C8 118.4(7) . .
C10 C9 H9 120.8 . .
C8 C9 H9 120.8 . .
C11 C10 C9 119.9(8) . .
C11 C10 H10 120.1 . .
C9 C10 H10 120.1 . .
C10 C11 C12 118.6(7) . .
C10 C11 H11 120.7 . .
C12 C11 H11 120.7 . .
N5 C12 C11 123.7(7) . .
N5 C12 H12 118.2 . .
C11 C12 H12 118.2 . .
N6 C13 C14 122.6(7) . .
N6 C13 H13 118.7 . .
C14 C13 H13 118.7 . .
C13 C14 C15 119.0(6) . .
C13 C14 H14 120.5 . .
C15 C14 H14 120.5 . .
C16 C15 C14 119.3(6) . .
C16 C15 H15 120.4 . .
C14 C15 H15 120.4 . .
C15 C16 C17 118.7(7) . .
C15 C16 H16 120.6 . .
C17 C16 H16 120.6 . .
N6 C17 C16 122.8(6) . .
N6 C17 C18 115.5(5) . .
C16 C17 C18 121.6(6) . .
N9 C18 N7 114.7(5) . .
N9 C18 C17 124.3(6) . .
N7 C18 C17 121.1(6) . .
N9 C19 N8 115.0(5) . .
N9 C19 C20 124.6(6) . .
N8 C19 C20 120.4(6) . .
N10 C20 C21 123.4(6) . .
N10 C20 C19 116.6(6) . .
C21 C20 C19 120.0(6) . .
C22 C21 C20 117.9(7) . .
C22 C21 H21 121.0 . .
C20 C21 H21 121.0 . .
C21 C22 C23 119.4(8) . .
C21 C22 H22 120.3 . .
C23 C22 H22 120.3 . .
C24 C23 C22 119.3(7) . .
C24 C23 H23 120.3 . .
C22 C23 H23 120.3 . .
N10 C24 C23 122.6(8) . .
N10 C24 H24 118.7 . .
C23 C24 H24 118.7 . .
O2 C25 O3 124.2(6) . .
O2 C25 C26 120.0(7) . .
O3 C25 C26 115.7(7) . .
C25 C26 H26A 109.5 . .
C25 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
C25 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 O1 2.211(5) .
Dy1 O2 2.279(5) .
Dy1 O5 2.408(5) .
Dy1 N7 2.480(5) .
Dy1 N2 2.495(5) .
Dy1 N6 2.505(5) .
Dy1 N1 2.510(5) .
Dy1 O4 2.577(5) .
Dy1 N11 2.938(7) .
Dy1 H1O 2.4595 .
Dy2 O1 2.216(5) 3_756
Dy2 O3 2.298(5) 3_756
Dy2 O7 2.437(5) .
Dy2 O8 2.460(5) .
Dy2 N8 2.484(5) .
Dy2 N3 2.503(5) .
Dy2 N10 2.545(6) .
Dy2 N5 2.559(6) .
Dy2 N12 2.874(7) .
O1 Dy2 2.216(5) 3_756
O1 H1O 0.8567 .
O2 C25 1.247(9) .
O3 C25 1.252(8) .
O3 Dy2 2.298(5) 3_756
O4 N11 1.263(8) .
O5 N11 1.280(7) .
O6 N11 1.212(8) .
O7 N12 1.259(8) .
O8 N12 1.255(9) .
O9 N12 1.215(9) .
N1 C5 1.343(8) .
N1 C1 1.354(8) .
N2 C6 1.345(8) .
N2 N3 1.377(6) .
N3 C7 1.343(8) .
N4 C6 1.335(8) .
N4 C7 1.338(8) .
N5 C8 1.345(9) .
N5 C12 1.346(8) .
N6 C17 1.337(8) .
N6 C13 1.358(8) .
N7 C18 1.343(8) .
N7 N8 1.375(6) .
N8 C19 1.350(8) .
N9 C19 1.325(8) .
N9 C18 1.326(9) .
N10 C20 1.337(9) .
N10 C24 1.358(9) .
C1 C2 1.365(10) .
C1 H1 0.9300 .
C2 C3 1.362(11) .
C2 H2 0.9300 .
C3 C4 1.395(10) .
C3 H3 0.9300 .
C4 C5 1.385(9) .
C4 H4 0.9300 .
C5 C6 1.469(8) .
C7 C8 1.473(8) .
C8 C9 1.383(10) .
C9 C10 1.382(10) .
C9 H9 0.9300 .
C10 C11 1.356(12) .
C10 H10 0.9300 .
C11 C12 1.370(11) .
C11 H11 0.9300 .
C12 H12 0.9300 .
C13 C14 1.375(10) .
C13 H13 0.9300 .
C14 C15 1.381(10) .
C14 H14 0.9300 .
C15 C16 1.374(10) .
C15 H15 0.9300 .
C16 C17 1.391(9) .
C16 H16 0.9300 .
C17 C18 1.474(8) .
C19 C20 1.471(9) .
C20 C21 1.391(10) .
C21 C22 1.380(11) .
C21 H21 0.9300 .
C22 C23 1.380(13) .
C22 H22 0.9300 .
C23 C24 1.365(12) .
C23 H23 0.9300 .
C24 H24 0.9300 .
C25 C26 1.521(11) .
C26 H26A 0.9600 .
C26 H26B 0.9600 .
C26 H26C 0.9600 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O2 Dy1 O1 Dy2 16.5(4) . 3_756
O5 Dy1 O1 Dy2 -176.6(3) . 3_756
N7 Dy1 O1 Dy2 -121.3(5) . 3_756
N2 Dy1 O1 Dy2 153.9(5) . 3_756
N6 Dy1 O1 Dy2 -57.2(5) . 3_756
N1 Dy1 O1 Dy2 90.5(5) . 3_756
O4 Dy1 O1 Dy2 20.0(8) . 3_756
N11 Dy1 O1 Dy2 138(2) . 3_756
O1 Dy1 O2 C25 3.8(9) . .
O5 Dy1 O2 C25 -168.5(8) . .
N7 Dy1 O2 C25 76.0(10) . .
N2 Dy1 O2 C25 -61.3(10) . .
N6 Dy1 O2 C25 110.5(9) . .
N1 Dy1 O2 C25 -98.1(9) . .
O4 Dy1 O2 C25 -174.8(9) . .
N11 Dy1 O2 C25 -172.2(9) . .
O1 Dy1 O4 N11 170.4(5) . .
O2 Dy1 O4 N11 174.0(4) . .
O5 Dy1 O4 N11 0.6(4) . .
N7 Dy1 O4 N11 -52.3(4) . .
N2 Dy1 O4 N11 42.8(4) . .
N6 Dy1 O4 N11 -105.8(4) . .
N1 Dy1 O4 N11 95.0(4) . .
O1 Dy1 O5 N11 -172.3(4) . .
O2 Dy1 O5 N11 -8.4(5) . .
N7 Dy1 O5 N11 131.7(4) . .
N2 Dy1 O5 N11 -142.7(4) . .
N6 Dy1 O5 N11 65.4(4) . .
N1 Dy1 O5 N11 -75.3(4) . .
O4 Dy1 O5 N11 -0.6(4) . .
O1 Dy2 O7 N12 -171.4(5) 3_756 .
O3 Dy2 O7 N12 -7.4(5) 3_756 .
O8 Dy2 O7 N12 4.1(4) . .
N8 Dy2 O7 N12 -140.0(4) . .
N3 Dy2 O7 N12 134.9(4) . .
N10 Dy2 O7 N12 -72.7(4) . .
N5 Dy2 O7 N12 70.3(4) . .
O1 Dy2 O8 N12 171.4(4) 3_756 .
O3 Dy2 O8 N12 165.7(5) 3_756 .
O7 Dy2 O8 N12 -4.1(4) . .
N8 Dy2 O8 N12 37.6(5) . .
N3 Dy2 O8 N12 -59.6(5) . .
N10 Dy2 O8 N12 88.1(4) . .
N5 Dy2 O8 N12 -114.5(4) . .
O1 Dy1 N1 C5 65.4(5) . .
O2 Dy1 N1 C5 144.4(6) . .
O5 Dy1 N1 C5 -86.1(5) . .
N7 Dy1 N1 C5 -27.7(7) . .
N2 Dy1 N1 C5 -7.2(5) . .
N6 Dy1 N1 C5 -168.9(5) . .
O4 Dy1 N1 C5 -137.1(6) . .
N11 Dy1 N1 C5 -111.1(5) . .
O1 Dy1 N1 C1 -111.4(6) . .
O2 Dy1 N1 C1 -32.3(6) . .
O5 Dy1 N1 C1 97.1(6) . .
N7 Dy1 N1 C1 155.6(6) . .
N2 Dy1 N1 C1 176.1(7) . .
N6 Dy1 N1 C1 14.3(8) . .
O4 Dy1 N1 C1 46.1(6) . .
N11 Dy1 N1 C1 72.1(6) . .
O1 Dy1 N2 C6 -95.2(5) . .
O2 Dy1 N2 C6 -28.5(6) . .
O5 Dy1 N2 C6 98.6(5) . .
N7 Dy1 N2 C6 -180.0(5) . .
N6 Dy1 N2 C6 167.3(5) . .
N1 Dy1 N2 C6 10.6(5) . .
O4 Dy1 N2 C6 66.4(5) . .
N11 Dy1 N2 C6 83.5(5) . .
O1 Dy1 N2 N3 65.8(6) . .
O2 Dy1 N2 N3 132.5(6) . .
O5 Dy1 N2 N3 -100.3(6) . .
N7 Dy1 N2 N3 -18.9(6) . .
N6 Dy1 N2 N3 -31.6(8) . .
N1 Dy1 N2 N3 171.7(7) . .
O4 Dy1 N2 N3 -132.5(6) . .
N11 Dy1 N2 N3 -115.4(6) . .
C6 N2 N3 C7 -0.5(7) . .
Dy1 N2 N3 C7 -163.0(5) . .
C6 N2 N3 Dy2 -179.0(5) . .
Dy1 N2 N3 Dy2 18.5(10) . .
O1 Dy2 N3 C7 101.0(5) 3_756 .
O3 Dy2 N3 C7 29.6(6) 3_756 .
O7 Dy2 N3 C7 -99.5(5) . .
O8 Dy2 N3 C7 -58.9(6) . .
N8 Dy2 N3 C7 -179.1(5) . .
N10 Dy2 N3 C7 -160.0(5) . .
N5 Dy2 N3 C7 1.5(5) . .
N12 Dy2 N3 C7 -81.3(5) . .
O1 Dy2 N3 N2 -80.5(6) 3_756 .
O3 Dy2 N3 N2 -151.9(5) 3_756 .
O7 Dy2 N3 N2 78.9(6) . .
O8 Dy2 N3 N2 119.5(6) . .
N8 Dy2 N3 N2 -0.6(6) . .
N10 Dy2 N3 N2 18.4(8) . .
N5 Dy2 N3 N2 179.9(6) . .
N12 Dy2 N3 N2 97.2(6) . .
O1 Dy2 N5 C8 -78.2(5) 3_756 .
O3 Dy2 N5 C8 -159.5(6) 3_756 .
O7 Dy2 N5 C8 79.4(5) . .
O8 Dy2 N5 C8 126.9(6) . .
N8 Dy2 N5 C8 0.4(8) . .
N3 Dy2 N5 C8 1.4(5) . .
N10 Dy2 N5 C8 165.2(5) . .
N12 Dy2 N5 C8 103.6(5) . .
O1 Dy2 N5 C12 98.3(6) 3_756 .
O3 Dy2 N5 C12 16.9(6) 3_756 .
O7 Dy2 N5 C12 -104.2(6) . .
O8 Dy2 N5 C12 -56.7(6) . .
N8 Dy2 N5 C12 176.8(5) . .
N3 Dy2 N5 C12 177.8(7) . .
N10 Dy2 N5 C12 -18.4(8) . .
N12 Dy2 N5 C12 -80.0(6) . .
O1 Dy1 N6 C17 -75.0(5) . .
O2 Dy1 N6 C17 -152.9(6) . .
O5 Dy1 N6 C17 80.5(5) . .
N7 Dy1 N6 C17 1.5(5) . .
N2 Dy1 N6 C17 15.3(7) . .
N1 Dy1 N6 C17 160.6(5) . .
O4 Dy1 N6 C17 128.5(6) . .
N11 Dy1 N6 C17 103.8(5) . .
O1 Dy1 N6 C13 107.1(6) . .
O2 Dy1 N6 C13 29.2(6) . .
O5 Dy1 N6 C13 -97.4(6) . .
N7 Dy1 N6 C13 -176.4(6) . .
N2 Dy1 N6 C13 -162.6(5) . .
N1 Dy1 N6 C13 -17.3(7) . .
O4 Dy1 N6 C13 -49.4(6) . .
N11 Dy1 N6 C13 -74.2(6) . .
O1 Dy1 N7 C18 107.4(5) . .
O2 Dy1 N7 C18 35.9(6) . .
O5 Dy1 N7 C18 -96.0(5) . .
N2 Dy1 N7 C18 -174.0(5) . .
N6 Dy1 N7 C18 -0.9(5) . .
N1 Dy1 N7 C18 -155.1(5) . .
O4 Dy1 N7 C18 -57.2(5) . .
N11 Dy1 N7 C18 -77.2(5) . .
O1 Dy1 N7 N8 -74.3(6) . .
O2 Dy1 N7 N8 -145.8(5) . .
O5 Dy1 N7 N8 82.3(6) . .
N2 Dy1 N7 N8 4.3(6) . .
N6 Dy1 N7 N8 177.4(6) . .
N1 Dy1 N7 N8 23.2(8) . .
O4 Dy1 N7 N8 121.1(6) . .
N11 Dy1 N7 N8 101.1(6) . .
C18 N7 N8 C19 -0.4(7) . .
Dy1 N7 N8 C19 -178.8(5) . .
C18 N7 N8 Dy2 -170.3(5) . .
Dy1 N7 N8 Dy2 11.3(10) . .
O1 Dy2 N8 C19 -99.0(5) 3_756 .
O3 Dy2 N8 C19 -28.6(6) 3_756 .
O7 Dy2 N8 C19 94.2(5) . .
O8 Dy2 N8 C19 62.2(5) . .
N3 Dy2 N8 C19 177.1(5) . .
N10 Dy2 N8 C19 7.9(5) . .
N5 Dy2 N8 C19 178.0(5) . .
N12 Dy2 N8 C19 77.8(5) . .
O1 Dy2 N8 N7 69.9(6) 3_756 .
O3 Dy2 N8 N7 140.3(5) 3_756 .
O7 Dy2 N8 N7 -96.9(6) . .
O8 Dy2 N8 N7 -128.8(6) . .
N3 Dy2 N8 N7 -14.0(6) . .
N10 Dy2 N8 N7 176.8(6) . .
N5 Dy2 N8 N7 -13.1(8) . .
N12 Dy2 N8 N7 -113.3(6) . .
O1 Dy2 N10 C20 66.1(6) 3_756 .
O3 Dy2 N10 C20 145.6(6) 3_756 .
O7 Dy2 N10 C20 -88.1(6) . .
O8 Dy2 N10 C20 -140.1(6) . .
N8 Dy2 N10 C20 -7.0(5) . .
N3 Dy2 N10 C20 -27.7(8) . .
N5 Dy2 N10 C20 -178.7(5) . .
N12 Dy2 N10 C20 -113.5(6) . .
O1 Dy2 N10 C24 -110.7(7) 3_756 .
O3 Dy2 N10 C24 -31.2(7) 3_756 .
O7 Dy2 N10 C24 95.1(7) . .
O8 Dy2 N10 C24 43.1(7) . .
N8 Dy2 N10 C24 176.2(7) . .
N3 Dy2 N10 C24 155.5(6) . .
N5 Dy2 N10 C24 4.5(9) . .
N12 Dy2 N10 C24 69.7(7) . .
Dy1 O4 N11 O6 -179.9(7) . .
Dy1 O4 N11 O5 -0.9(6) . .
Dy1 O5 N11 O6 180.0(6) . .
Dy1 O5 N11 O4 1.0(6) . .
O1 Dy1 N11 O6 52(8) . .
O2 Dy1 N11 O6 173(7) . .
O5 Dy1 N11 O6 0(7) . .
N7 Dy1 N11 O6 -48(7) . .
N2 Dy1 N11 O6 36(7) . .
N6 Dy1 N11 O6 -113(7) . .
N1 Dy1 N11 O6 100(7) . .
O4 Dy1 N11 O6 179(100) . .
O1 Dy1 N11 O4 -127(2) . .
O2 Dy1 N11 O4 -5.9(4) . .
O5 Dy1 N11 O4 -178.9(6) . .
N7 Dy1 N11 O4 133.1(4) . .
N2 Dy1 N11 O4 -142.4(4) . .
N6 Dy1 N11 O4 68.2(4) . .
N1 Dy1 N11 O4 -78.5(4) . .
O1 Dy1 N11 O5 52(2) . .
O2 Dy1 N11 O5 173.1(4) . .
N7 Dy1 N11 O5 -47.9(4) . .
N2 Dy1 N11 O5 36.5(4) . .
N6 Dy1 N11 O5 -112.8(4) . .
N1 Dy1 N11 O5 100.5(4) . .
O4 Dy1 N11 O5 178.9(6) . .
Dy2 O8 N12 O9 -173.0(6) . .
Dy2 O8 N12 O7 6.8(6) . .
Dy2 O7 N12 O9 172.9(6) . .
Dy2 O7 N12 O8 -6.9(6) . .
O1 Dy2 N12 O9 -1(8) 3_756 .
O3 Dy2 N12 O9 77(6) 3_756 .
O7 Dy2 N12 O9 -97(6) . .
O8 Dy2 N12 O9 90(6) . .
N8 Dy2 N12 O9 -58(6) . .
N3 Dy2 N12 O9 -143(6) . .
N10 Dy2 N12 O9 5(6) . .
N5 Dy2 N12 O9 152(6) . .
O1 Dy2 N12 O8 -91(3) 3_756 .
O3 Dy2 N12 O8 -13.6(4) 3_756 .
O7 Dy2 N12 O8 172.7(7) . .
N8 Dy2 N12 O8 -147.7(4) . .
N3 Dy2 N12 O8 127.2(4) . .
N10 Dy2 N12 O8 -85.0(4) . .
N5 Dy2 N12 O8 62.1(4) . .
O1 Dy2 N12 O7 97(3) 3_756 .
O3 Dy2 N12 O7 173.7(4) 3_756 .
O8 Dy2 N12 O7 -172.7(7) . .
N8 Dy2 N12 O7 39.6(4) . .
N3 Dy2 N12 O7 -45.4(4) . .
N10 Dy2 N12 O7 102.3(4) . .
N5 Dy2 N12 O7 -110.6(4) . .
C5 N1 C1 C2 2.2(12) . .
Dy1 N1 C1 C2 179.0(7) . .
N1 C1 C2 C3 -0.9(14) . .
C1 C2 C3 C4 -0.1(15) . .
C2 C3 C4 C5 -0.3(15) . .
C1 N1 C5 C4 -2.6(12) . .
Dy1 N1 C5 C4 -179.5(6) . .
C1 N1 C5 C6 -179.8(7) . .
Dy1 N1 C5 C6 3.2(8) . .
C3 C4 C5 N1 1.7(13) . .
C3 C4 C5 C6 178.7(8) . .
C7 N4 C6 N2 -0.8(9) . .
C7 N4 C6 C5 -179.1(7) . .
N3 N2 C6 N4 0.8(8) . .
Dy1 N2 C6 N4 167.6(5) . .
N3 N2 C6 C5 179.2(6) . .
Dy1 N2 C6 C5 -14.0(9) . .
N1 C5 C6 N4 -174.4(7) . .
C4 C5 C6 N4 8.4(12) . .
N1 C5 C6 N2 7.4(10) . .
C4 C5 C6 N2 -169.9(8) . .
C6 N4 C7 N3 0.5(9) . .
C6 N4 C7 C8 -176.3(7) . .
N2 N3 C7 N4 0.0(8) . .
Dy2 N3 C7 N4 178.9(5) . .
N2 N3 C7 C8 176.9(6) . .
Dy2 N3 C7 C8 -4.2(9) . .
C12 N5 C8 C9 -1.5(11) . .
Dy2 N5 C8 C9 175.1(6) . .
C12 N5 C8 C7 179.5(7) . .
Dy2 N5 C8 C7 -3.8(8) . .
N4 C7 C8 N5 -178.0(7) . .
N3 C7 C8 N5 5.4(10) . .
N4 C7 C8 C9 3.0(12) . .
N3 C7 C8 C9 -173.6(7) . .
N5 C8 C9 C10 0.9(12) . .
C7 C8 C9 C10 179.8(8) . .
C8 C9 C10 C11 -0.1(14) . .
C9 C10 C11 C12 0.1(14) . .
C8 N5 C12 C11 1.5(12) . .
Dy2 N5 C12 C11 -175.0(7) . .
C10 C11 C12 N5 -0.8(14) . .
C17 N6 C13 C14 2.1(12) . .
Dy1 N6 C13 C14 -179.9(6) . .
N6 C13 C14 C15 -0.6(13) . .
C13 C14 C15 C16 -0.8(13) . .
C14 C15 C16 C17 0.5(12) . .
C13 N6 C17 C16 -2.4(11) . .
Dy1 N6 C17 C16 179.6(6) . .
C13 N6 C17 C18 176.1(7) . .
Dy1 N6 C17 C18 -1.9(8) . .
C15 C16 C17 N6 1.1(12) . .
C15 C16 C17 C18 -177.3(7) . .
C19 N9 C18 N7 -0.5(9) . .
C19 N9 C18 C17 178.5(7) . .
N8 N7 C18 N9 0.6(8) . .
Dy1 N7 C18 N9 179.4(5) . .
N8 N7 C18 C17 -178.5(6) . .
Dy1 N7 C18 C17 0.4(8) . .
N6 C17 C18 N9 -178.0(7) . .
C16 C17 C18 N9 0.6(12) . .
N6 C17 C18 N7 1.0(10) . .
C16 C17 C18 N7 179.6(7) . .
C18 N9 C19 N8 0.2(9) . .
C18 N9 C19 C20 -178.5(7) . .
N7 N8 C19 N9 0.1(8) . .
Dy2 N8 C19 N9 172.4(5) . .
N7 N8 C19 C20 178.9(6) . .
Dy2 N8 C19 C20 -8.7(9) . .
C24 N10 C20 C21 1.6(12) . .
Dy2 N10 C20 C21 -175.4(6) . .
C24 N10 C20 C19 -177.5(7) . .
Dy2 N10 C20 C19 5.5(9) . .
N9 C19 C20 N10 -179.2(7) . .
N8 C19 C20 N10 2.1(10) . .
N9 C19 C20 C21 1.7(12) . .
N8 C19 C20 C21 -177.0(7) . .
N10 C20 C21 C22 -0.9(13) . .
C19 C20 C21 C22 178.1(8) . .
C20 C21 C22 C23 -0.7(14) . .
C21 C22 C23 C24 1.5(15) . .
C20 N10 C24 C23 -0.6(14) . .
Dy2 N10 C24 C23 176.2(7) . .
C22 C23 C24 N10 -0.9(16) . .
Dy1 O2 C25 O3 -12.4(15) . .
Dy1 O2 C25 C26 171.6(7) . .
Dy2 O3 C25 O2 3.0(14) 3_756 .
Dy2 O3 C25 C26 179.3(7) 3_756 .
