#------------------------------------------------------------------------------
#$Date: 2019-11-23 01:36:19 +0200 (Sat, 23 Nov 2019) $
#$Revision: 231779 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/64/4346443.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4346443
loop_
_publ_author_name
'Warzecha, Evan'
'Berto, Timothy C.'
'Berry, John F.'
_publ_section_title
;
 Axial Ligand Coordination to the C-H Amination Catalyst Rh2(esp)2: A
 Structural and Spectroscopic Study.
;
_journal_issue                   17
_journal_name_full               'Inorganic chemistry'
_journal_page_first              8817
_journal_page_last               8824
_journal_paper_doi               10.1021/acs.inorgchem.5b01532
_journal_volume                  54
_journal_year                    2015
_chemical_formula_moiety         'C44 H54 N2 O8 Rh2'
_chemical_formula_sum            'C44 H54 N2 O8 Rh2'
_chemical_formula_weight         944.71
_chemical_name_common            'Compound 3'
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_cell_angle_alpha                90
_cell_angle_beta                 114.0958(13)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   10.2303(3)
_cell_length_b                   20.4927(7)
_cell_length_c                   11.1999(4)
_cell_measurement_reflns_used    9917
_cell_measurement_temperature    100.0
_cell_measurement_theta_max      71.93
_cell_measurement_theta_min      4.31
_cell_volume                     2143.42(13)
_computing_cell_refinement       'SAINT+ Ver. 8.34A (Bruker-AXS, 2014)'
_computing_data_collection       'APEX2 Ver. 2014.1-1 (Bruker-AXS, 2014)'
_computing_data_reduction        'SAINT+ Ver. 8.34A (Bruker-AXS, 2014)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008-2013)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008-2013)'
_computing_structure_refinement  'SHELXTL (Sheldrick, 2008-2013)'
_computing_structure_solution    'SHELXTL (Sheldrick, 2008-2013)'
_diffrn_ambient_temperature      100.0
_diffrn_detector_area_resol_mean 7.9
_diffrn_detector_type            'CCD area detector'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker SMART APEX2 area detector'
_diffrn_measurement_method       '0.60\ ω and 0.6\ φ scans'
_diffrn_radiation_collimation    '0.5 mm double-pinhole'
_diffrn_radiation_monochromator  'equatorially mounted graphite'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54178
_diffrn_reflns_av_R_equivalents  0.0363
_diffrn_reflns_av_unetI/netI     0.0192
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.993
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            34986
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_theta_full        67.679
_diffrn_reflns_theta_max         72.083
_diffrn_reflns_theta_min         4.315
_diffrn_source                   'sealed X-ray tube'
_diffrn_source_type              'Siemens, K FFCU 2K 90'
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    6.659
_exptl_absorpt_correction_T_max  0.8346
_exptl_absorpt_correction_T_min  0.2232
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
SADABS-2012/1 (Bruker,2012) was used for absorption correction.
wR2(int) was 0.0800 before and 0.0550 after correction.
The Ratio of minimum to maximum transmission is 0.2674.
The λ/2 correction factor is 0.0015.
;
_exptl_crystal_colour            red
_exptl_crystal_colour_primary    red
_exptl_crystal_density_diffrn    1.464
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             972
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.187
_exptl_crystal_size_min          0.049
_refine_diff_density_max         0.702
_refine_diff_density_min         -0.559
_refine_diff_density_rms         0.075
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.042
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     258
_refine_ls_number_reflns         4193
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.042
_refine_ls_R_factor_all          0.0239
_refine_ls_R_factor_gt           0.0227
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0310P)²+2.2850P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0609
_refine_ls_wR_factor_ref         0.0618
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4009
_reflns_number_total             4193
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic5b01532_si_002.cif
_cod_data_source_block           berry514
_cod_database_code               4346443
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.736
_shelx_estimated_absorpt_t_min   0.176
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C5(H5A,H5B), C12(H12A,H12B)
2.b Aromatic/amide H refined with riding coordinates:
 C7(H7), C8(H8), C9(H9), C11(H11), C17(H17), C18(H18), C19(H19), C21(H21)
2.c Idealised Me refined as rotating group:
 C3(H3A,H3B,H3C), C4(H4A,H4B,H4C), C14(H14A,H14B,H14C), C15(H15A,H15B,H15C),
 C22(H22A,H22B,H22C)
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
Rh1 Rh 0.99215(2) 0.51797(2) 0.09911(2) 0.01456(6) Uani 1 1 d .
O1 O 1.07986(15) 0.60422(7) 0.07720(14) 0.0194(3) Uani 1 1 d .
O2 O 1.09272(15) 0.57096(7) -0.10990(14) 0.0198(3) Uani 1 1 d .
O3 O 0.78978(14) 0.54985(7) -0.01400(13) 0.0181(3) Uani 1 1 d .
O4 O 0.80582(15) 0.51677(6) -0.19995(14) 0.0194(3) Uani 1 1 d .
N1 N 0.97762(18) 0.55348(8) 0.28342(17) 0.0190(3) Uani 1 1 d .
C1 C 1.1118(2) 0.61181(10) -0.0204(2) 0.0194(4) Uani 1 1 d .
C2 C 1.1806(2) 0.67783(10) -0.0272(2) 0.0258(5) Uani 1 1 d .
C3 C 1.2178(3) 0.68103(11) -0.1462(3) 0.0315(5) Uani 1 1 d .
H3A H 1.2820 0.6449 -0.1427 0.047 Uiso 1 1 calc GR
H3B H 1.2653 0.7226 -0.1459 0.047 Uiso 1 1 calc GR
H3C H 1.1298 0.6777 -0.2264 0.047 Uiso 1 1 calc GR
C4 C 1.3168(3) 0.68484(13) 0.0991(3) 0.0389(6) Uani 1 1 d .
H4A H 1.2926 0.6798 0.1748 0.058 Uiso 1 1 calc GR
H4B H 1.3588 0.7280 0.1015 0.058 Uiso 1 1 calc GR
H4C H 1.3858 0.6511 0.1017 0.058 Uiso 1 1 calc GR
C5 C 1.0749(3) 0.73352(10) -0.0323(3) 0.0285(5) Uani 1 1 d .
H5A H 1.0660 0.7347 0.0524 0.034 Uiso 1 1 calc R
H5B H 1.1166 0.7757 -0.0425 0.034 Uiso 1 1 calc R
C6 C 0.9275(3) 0.72727(10) -0.1403(2) 0.0264(5) Uani 1 1 d .
C7 C 0.8881(3) 0.75800(11) -0.2618(3) 0.0330(6) Uani 1 1 d .
H7 H 0.9555 0.7844 -0.2778 0.040 Uiso 1 1 calc R
C8 C 0.7514(3) 0.75006(13) -0.3588(3) 0.0373(6) Uani 1 1 d .
H8 H 0.7260 0.7711 -0.4407 0.045 Uiso 1 1 calc R
C9 C 0.6510(3) 0.71173(12) -0.3376(2) 0.0309(5) Uani 1 1 d .
H9 H 0.5581 0.7062 -0.4052 0.037 Uiso 1 1 calc R
C10 C 0.6870(2) 0.68115(10) -0.2165(2) 0.0242(5) Uani 1 1 d .
C11 C 0.8248(2) 0.68951(10) -0.1202(2) 0.0229(4) Uani 1 1 d .
H11 H 0.8498 0.6688 -0.0379 0.027 Uiso 1 1 calc R
C12 C 0.5795(2) 0.63988(10) -0.1894(2) 0.0224(4) Uani 1 1 d .
H12A H 0.4820 0.6558 -0.2447 0.027 Uiso 1 1 calc R
H12B H 0.5949 0.6461 -0.0970 0.027 Uiso 1 1 calc R
C13 C 0.5866(2) 0.56584(10) -0.2148(2) 0.0204(4) Uani 1 1 d .
C14 C 0.5385(2) 0.55172(12) -0.3604(2) 0.0286(5) Uani 1 1 d .
H14A H 0.6018 0.5744 -0.3929 0.043 Uiso 1 1 calc GR
H14B H 0.4400 0.5671 -0.4082 0.043 Uiso 1 1 calc GR
H14C H 0.5428 0.5046 -0.3737 0.043 Uiso 1 1 calc GR
C15 C 0.4892(2) 0.52989(12) -0.1626(2) 0.0257(5) Uani 1 1 d .
H15A H 0.4997 0.4827 -0.1697 0.039 Uiso 1 1 calc GR
H15B H 0.3894 0.5424 -0.2140 0.039 Uiso 1 1 calc GR
H15C H 0.5163 0.5416 -0.0707 0.039 Uiso 1 1 calc GR
C16 C 0.7402(2) 0.54216(9) -0.1370(2) 0.0176(4) Uani 1 1 d .
C17 C 1.0916(2) 0.55475(11) 0.3980(2) 0.0252(5) Uani 1 1 d .
H17 H 1.1810 0.5397 0.4018 0.030 Uiso 1 1 calc R
C18 C 1.0838(3) 0.57725(12) 0.5110(2) 0.0298(5) Uani 1 1 d .
H18 H 1.1668 0.5777 0.5910 0.036 Uiso 1 1 calc R
C19 C 0.9536(3) 0.59928(11) 0.5069(2) 0.0285(5) Uani 1 1 d .
H19 H 0.9459 0.6139 0.5843 0.034 Uiso 1 1 calc R
C20 C 0.8355(2) 0.59965(11) 0.3884(2) 0.0267(5) Uani 1 1 d .
C21 C 0.8532(2) 0.57552(10) 0.2799(2) 0.0227(4) Uani 1 1 d .
H21 H 0.7721 0.5747 0.1985 0.027 Uiso 1 1 calc R
C22 C 0.6937(3) 0.62726(14) 0.3754(3) 0.0396(6) Uani 1 1 d .
H22A H 0.6784 0.6698 0.3318 0.059 Uiso 1 1 calc GR
H22B H 0.6940 0.6325 0.4625 0.059 Uiso 1 1 calc GR
H22C H 0.6165 0.5974 0.3235 0.059 Uiso 1 1 calc GR
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh 0.0927 3.6045 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Rh1 Rh1 87.47(4) . 3_765
O1 Rh1 O2 175.81(6) . 3_765
O1 Rh1 O3 91.86(6) . .
O1 Rh1 N1 91.55(6) . .
O2 Rh1 Rh1 88.38(4) 3_765 3_765
O2 Rh1 O3 88.53(6) 3_765 .
O2 Rh1 N1 92.60(6) 3_765 .
O3 Rh1 Rh1 87.61(4) . 3_765
O3 Rh1 N1 92.04(6) . .
O4 Rh1 Rh1 88.27(4) 3_765 3_765
O4 Rh1 O1 88.45(6) 3_765 .
O4 Rh1 O2 90.86(6) 3_765 3_765
O4 Rh1 O3 175.85(6) 3_765 .
O4 Rh1 N1 92.09(6) 3_765 .
N1 Rh1 Rh1 178.95(4) . 3_765
C1 O1 Rh1 119.27(13) . .
C1 O2 Rh1 118.54(13) . 3_765
C16 O3 Rh1 119.22(13) . .
C16 O4 Rh1 118.88(13) . 3_765
C17 N1 Rh1 121.92(14) . .
C21 N1 Rh1 120.08(14) . .
C21 N1 C17 117.98(19) . .
O1 C1 C2 115.63(18) . .
O2 C1 O1 126.32(18) . .
O2 C1 C2 118.05(18) . .
C1 C2 C5 108.70(17) . .
C3 C2 C1 111.20(18) . .
C3 C2 C4 110.2(2) . .
C3 C2 C5 110.64(19) . .
C4 C2 C1 107.33(19) . .
C4 C2 C5 108.7(2) . .
C2 C3 H3A 109.5 . .
C2 C3 H3B 109.5 . .
C2 C3 H3C 109.5 . .
H3A C3 H3B 109.5 . .
H3A C3 H3C 109.5 . .
H3B C3 H3C 109.5 . .
C2 C4 H4A 109.5 . .
C2 C4 H4B 109.5 . .
C2 C4 H4C 109.5 . .
H4A C4 H4B 109.5 . .
H4A C4 H4C 109.5 . .
H4B C4 H4C 109.5 . .
C2 C5 H5A 108.6 . .
C2 C5 H5B 108.6 . .
H5A C5 H5B 107.5 . .
C6 C5 C2 114.84(19) . .
C6 C5 H5A 108.6 . .
C6 C5 H5B 108.6 . .
C7 C6 C5 122.6(2) . .
C11 C6 C5 119.4(2) . .
C11 C6 C7 118.0(2) . .
C6 C7 H7 119.8 . .
C8 C7 C6 120.4(2) . .
C8 C7 H7 119.8 . .
C7 C8 H8 119.6 . .
C7 C8 C9 120.9(2) . .
C9 C8 H8 119.6 . .
C8 C9 H9 120.0 . .
C8 C9 C10 119.9(2) . .
C10 C9 H9 120.0 . .
C9 C10 C12 121.3(2) . .
C11 C10 C9 118.5(2) . .
C11 C10 C12 120.20(19) . .
C6 C11 H11 118.9 . .
C10 C11 C6 122.3(2) . .
C10 C11 H11 118.9 . .
C10 C12 H12A 108.6 . .
C10 C12 H12B 108.6 . .
C10 C12 C13 114.71(17) . .
H12A C12 H12B 107.6 . .
C13 C12 H12A 108.6 . .
C13 C12 H12B 108.6 . .
C14 C13 C12 111.25(18) . .
C14 C13 C15 109.91(19) . .
C14 C13 C16 110.85(17) . .
C15 C13 C12 108.29(17) . .
C16 C13 C12 108.62(17) . .
C16 C13 C15 107.81(17) . .
C13 C14 H14A 109.5 . .
C13 C14 H14B 109.5 . .
C13 C14 H14C 109.5 . .
H14A C14 H14B 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C13 C15 H15A 109.5 . .
C13 C15 H15B 109.5 . .
C13 C15 H15C 109.5 . .
H15A C15 H15B 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
O3 C16 C13 116.17(17) . .
O4 C16 O3 126.01(18) . .
O4 C16 C13 117.82(18) . .
N1 C17 H17 118.9 . .
N1 C17 C18 122.2(2) . .
C18 C17 H17 118.9 . .
C17 C18 H18 120.3 . .
C17 C18 C19 119.5(2) . .
C19 C18 H18 120.3 . .
C18 C19 H19 120.5 . .
C20 C19 C18 118.9(2) . .
C20 C19 H19 120.5 . .
C19 C20 C21 117.5(2) . .
C19 C20 C22 121.6(2) . .
C21 C20 C22 120.9(2) . .
N1 C21 C20 123.9(2) . .
N1 C21 H21 118.1 . .
C20 C21 H21 118.1 . .
C20 C22 H22A 109.5 . .
C20 C22 H22B 109.5 . .
C20 C22 H22C 109.5 . .
H22A C22 H22B 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Rh1 Rh1 2.4057(3) 3_765
Rh1 O1 2.0419(14) .
Rh1 O2 2.0433(14) 3_765
Rh1 O3 2.0437(13) .
Rh1 O4 2.0367(14) 3_765
Rh1 N1 2.2502(17) .
O1 C1 1.272(3) .
O2 Rh1 2.0433(14) 3_765
O2 C1 1.258(3) .
O3 C16 1.268(2) .
O4 Rh1 2.0367(14) 3_765
O4 C16 1.267(3) .
N1 C17 1.337(3) .
N1 C21 1.335(3) .
C1 C2 1.541(3) .
C2 C3 1.530(3) .
C2 C4 1.534(4) .
C2 C5 1.557(3) .
C3 H3A 0.9800 .
C3 H3B 0.9800 .
C3 H3C 0.9800 .
C4 H4A 0.9800 .
C4 H4B 0.9800 .
C4 H4C 0.9800 .
C5 H5A 0.9900 .
C5 H5B 0.9900 .
C5 C6 1.505(4) .
C6 C7 1.401(3) .
C6 C11 1.395(3) .
C7 H7 0.9500 .
C7 C8 1.387(4) .
C8 H8 0.9500 .
C8 C9 1.388(4) .
C9 H9 0.9500 .
C9 C10 1.400(3) .
C10 C11 1.392(3) .
C10 C12 1.513(3) .
C11 H11 0.9500 .
C12 H12A 0.9900 .
C12 H12B 0.9900 .
C12 C13 1.551(3) .
C13 C14 1.527(3) .
C13 C15 1.534(3) .
C13 C16 1.532(3) .
C14 H14A 0.9800 .
C14 H14B 0.9800 .
C14 H14C 0.9800 .
C15 H15A 0.9800 .
C15 H15B 0.9800 .
C15 H15C 0.9800 .
C17 H17 0.9500 .
C17 C18 1.379(3) .
C18 H18 0.9500 .
C18 C19 1.389(3) .
C19 H19 0.9500 .
C19 C20 1.383(3) .
C20 C21 1.391(3) .
C20 C22 1.508(3) .
C21 H21 0.9500 .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
Rh1 O1 C1 O2 1.3(3) .
Rh1 O1 C1 C2 -178.64(13) .
Rh1 O2 C1 O1 -1.9(3) 3_765
Rh1 O2 C1 C2 177.96(14) 3_765
Rh1 O3 C16 O4 -1.2(3) .
Rh1 O3 C16 C13 178.60(13) .
Rh1 O4 C16 O3 1.8(3) 3_765
Rh1 O4 C16 C13 -178.01(13) 3_765
Rh1 N1 C17 C18 179.15(17) .
Rh1 N1 C21 C20 -178.55(16) .
O1 C1 C2 C3 178.66(18) .
O1 C1 C2 C4 58.1(2) .
O1 C1 C2 C5 -59.3(2) .
O2 C1 C2 C3 -1.2(3) .
O2 C1 C2 C4 -121.8(2) .
O2 C1 C2 C5 120.8(2) .
N1 C17 C18 C19 0.2(4) .
C1 C2 C5 C6 -54.6(3) .
C2 C5 C6 C7 -94.4(2) .
C2 C5 C6 C11 85.6(3) .
C3 C2 C5 C6 67.8(2) .
C4 C2 C5 C6 -171.2(2) .
C5 C6 C7 C8 179.2(2) .
C5 C6 C11 C10 -179.32(19) .
C6 C7 C8 C9 0.0(4) .
C7 C6 C11 C10 0.7(3) .
C7 C8 C9 C10 0.8(4) .
C8 C9 C10 C11 -0.9(3) .
C8 C9 C10 C12 179.0(2) .
C9 C10 C11 C6 0.2(3) .
C9 C10 C12 C13 94.2(2) .
C10 C12 C13 C14 -68.1(2) .
C10 C12 C13 C15 171.05(18) .
C10 C12 C13 C16 54.2(2) .
C11 C6 C7 C8 -0.8(3) .
C11 C10 C12 C13 -85.9(3) .
C12 C10 C11 C6 -179.77(19) .
C12 C13 C16 O3 59.3(2) .
C12 C13 C16 O4 -120.84(19) .
C14 C13 C16 O3 -178.14(18) .
C14 C13 C16 O4 1.7(3) .
C15 C13 C16 O3 -57.8(2) .
C15 C13 C16 O4 122.0(2) .
C17 N1 C21 C20 0.0(3) .
C17 C18 C19 C20 -1.7(3) .
C18 C19 C20 C21 2.2(3) .
C18 C19 C20 C22 -175.7(2) .
C19 C20 C21 N1 -1.4(3) .
C21 N1 C17 C18 0.7(3) .
C22 C20 C21 N1 176.5(2) .
