#------------------------------------------------------------------------------
#$Date: 2019-11-23 04:47:51 +0200 (Sat, 23 Nov 2019) $
#$Revision: 232160 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/70/4347084.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4347084
loop_
_publ_author_name
'Sivchik, Vasily V.'
'Grachova, Elena V.'
'Melnikov, Alexei S.'
'Smirnov, Sergey N.'
'Ivanov, Alexander Yu'
'Hirva, Pipsa'
'Tunik, Sergey P.'
'Koshevoy, Igor O.'
_publ_section_title
;
 Solid-State and Solution Metallophilic Aggregation of a Cationic
 [Pt(NCN)L](+) Cyclometalated Complex.
;
_journal_issue                   7
_journal_name_full               'Inorganic chemistry'
_journal_page_first              3351
_journal_page_last               3363
_journal_paper_doi               10.1021/acs.inorgchem.5b02713
_journal_volume                  55
_journal_year                    2016
_chemical_formula_moiety         '4(C18 H14 N3 Pt), 4(F6 P), C2 H3 N'
_chemical_formula_sum            'C74 H59 F24 N13 P4 Pt4'
_chemical_formula_weight         2490.58
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/6
_cell_angle_alpha                90
_cell_angle_beta                 93.827(4)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   6.7128(6)
_cell_length_b                   22.339(2)
_cell_length_c                   25.698(3)
_cell_measurement_reflns_used    9969
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      29.48
_cell_measurement_theta_min      2.42
_cell_volume                     3845.0(7)
_computing_cell_refinement       'SAINT (Bruker AXS, 2009)'
_computing_data_collection       'APEX2 (Bruker AXS, 2010)'
_computing_data_reduction        'SAINT (Bruker AXS, 2009)'
_computing_molecular_graphics    'Diamond v.4.01 (Brandenburg, 2014)'
_computing_publication_material  'SHELXL-2014/6 (Sheldrick, 2014)'
_computing_structure_refinement  'SHELXL-2014/6 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-2013 (Sheldrick, 2013)'
_diffrn_ambient_temperature      200(2)
_diffrn_detector_area_resol_mean 16
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device       '62mm x 62mm CCD camera on κ-goniostat'
_diffrn_measurement_device_type  'Bruker KAPPA APEX II DUO CCD'
_diffrn_measurement_method       'φ scans and ω scans with κ offset'
_diffrn_radiation_monochromator  'curved graphite crystal'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0315
_diffrn_reflns_av_unetI/netI     0.0282
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.999
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -6
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            38562
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.999
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.000
_diffrn_reflns_theta_min         1.823
_exptl_absorpt_coefficient_mu    7.449
_exptl_absorpt_correction_T_max  0.694
_exptl_absorpt_correction_T_min  0.175
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'SADABS (Sheldrick, 2008)'
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    2.151
_exptl_crystal_description       needle
_exptl_crystal_F_000             2364
_exptl_crystal_size_max          0.360
_exptl_crystal_size_mid          0.074
_exptl_crystal_size_min          0.053
_refine_diff_density_max         1.609
_refine_diff_density_min         -1.271
_refine_diff_density_rms         0.102
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.025
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     553
_refine_ls_number_reflns         8408
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.025
_refine_ls_R_factor_all          0.0388
_refine_ls_R_factor_gt           0.0257
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0198P)²+6.4160P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0512
_refine_ls_wR_factor_ref         0.0556
_reflns_Friedel_coverage         0.000
_reflns_number_gt                6893
_reflns_number_total             8408
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic5b02713_si_002.cif
_cod_data_source_block           2PF6200
_cod_original_cell_volume        3845.1(6)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               4347084
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.175
_shelx_estimated_absorpt_t_max   0.694
_shelxl_version_number           2014/6
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
C1 C 0.4392(5) 0.65397(18) 0.59365(16) 0.0301(9) Uani 1 1 d . . .
C2 C 0.4364(5) 0.60636(17) 0.62845(15) 0.0302(9) Uani 1 1 d . . .
C3 C 0.4159(6) 0.54890(18) 0.60850(18) 0.0372(10) Uani 1 1 d . . .
H3 H 0.4140 0.5154 0.6312 0.045 Uiso 1 1 calc R U .
C4 C 0.3981(6) 0.5411(2) 0.55474(18) 0.0425(11) Uani 1 1 d . . .
H4 H 0.3822 0.5018 0.5411 0.051 Uiso 1 1 calc R U .
C5 C 0.4026(6) 0.5886(2) 0.52054(18) 0.0402(10) Uani 1 1 d . . .
H5 H 0.3918 0.5819 0.4840 0.048 Uiso 1 1 calc R U .
C6 C 0.4230(6) 0.64652(19) 0.54001(16) 0.0335(9) Uani 1 1 d . . .
C7 C 0.4910(6) 0.70923(18) 0.73702(16) 0.0333(9) Uani 1 1 d . . .
H7 H 0.5039 0.7514 0.7410 0.040 Uiso 1 1 calc R U .
C8 C 0.4935(7) 0.6743(2) 0.78066(17) 0.0415(10) Uani 1 1 d . . .
H8 H 0.5067 0.6920 0.8143 0.050 Uiso 1 1 calc R U .
C9 C 0.4768(7) 0.6132(2) 0.77524(17) 0.0425(11) Uani 1 1 d . . .
H9 H 0.4796 0.5881 0.8051 0.051 Uiso 1 1 calc R U .
C10 C 0.4559(6) 0.58887(19) 0.72602(17) 0.0382(10) Uani 1 1 d . . .
H10 H 0.4417 0.5468 0.7217 0.046 Uiso 1 1 calc R U .
C11 C 0.4557(6) 0.62570(17) 0.68305(15) 0.0306(9) Uani 1 1 d . . .
C12 C 0.4530(7) 0.8067(2) 0.52245(18) 0.0433(11) Uani 1 1 d . . .
H12 H 0.4660 0.8407 0.5446 0.052 Uiso 1 1 calc R U .
C13 C 0.4405(8) 0.8147(3) 0.46934(19) 0.0549(13) Uani 1 1 d . . .
H13 H 0.4438 0.8538 0.4549 0.066 Uiso 1 1 calc R U .
C14 C 0.4233(8) 0.7657(3) 0.43767(19) 0.0574(14) Uani 1 1 d . . .
H14 H 0.4141 0.7707 0.4009 0.069 Uiso 1 1 calc R U .
C15 C 0.4191(7) 0.7097(2) 0.45850(17) 0.0484(12) Uani 1 1 d . . .
H15 H 0.4090 0.6756 0.4364 0.058 Uiso 1 1 calc R U .
C16 C 0.4296(6) 0.7029(2) 0.51218(16) 0.0357(10) Uani 1 1 d . . .
C17 C 0.4987(7) 0.8702(2) 0.66018(17) 0.0413(10) Uani 1 1 d . . .
C18 C 0.5100(9) 0.9328(2) 0.6738(2) 0.0649(16) Uani 1 1 d . . .
H18A H 0.4973 0.9571 0.6420 0.097 Uiso 1 1 calc R U .
H18B H 0.6388 0.9411 0.6927 0.097 Uiso 1 1 calc R U .
H18C H 0.4017 0.9428 0.6960 0.097 Uiso 1 1 calc R U .
C19 C -0.0618(6) 0.69933(19) 0.55656(16) 0.0354(9) Uani 1 1 d . . .
C20 C -0.0780(6) 0.6405(2) 0.54159(18) 0.0383(10) Uani 1 1 d . . .
C21 C -0.0933(6) 0.6283(2) 0.48804(19) 0.0482(12) Uani 1 1 d . . .
H21 H -0.1057 0.5882 0.4760 0.058 Uiso 1 1 calc R U .
C22 C -0.0903(7) 0.6749(3) 0.4529(2) 0.0542(13) Uani 1 1 d . . .
H22 H -0.0996 0.6662 0.4166 0.065 Uiso 1 1 calc R U .
C23 C -0.0745(7) 0.7333(3) 0.46854(19) 0.0528(13) Uani 1 1 d . . .
H23 H -0.0728 0.7645 0.4435 0.063 Uiso 1 1 calc R U .
C24 C -0.0608(6) 0.7465(2) 0.52132(18) 0.0415(10) Uani 1 1 d . . .
C25 C -0.0515(7) 0.5937(2) 0.6766(2) 0.0475(12) Uani 1 1 d . . .
H25 H -0.0383 0.6129 0.7096 0.057 Uiso 1 1 calc R U .
C26 C -0.0637(7) 0.5323(2) 0.6748(2) 0.0608(15) Uani 1 1 d . . .
H26 H -0.0583 0.5094 0.7060 0.073 Uiso 1 1 calc R U .
C27 C -0.0837(7) 0.5046(2) 0.6271(3) 0.0600(15) Uani 1 1 d . . .
H27 H -0.0929 0.4622 0.6252 0.072 Uiso 1 1 calc R U .
C28 C -0.0906(7) 0.5377(2) 0.5827(2) 0.0517(13) Uani 1 1 d . . .
H28 H -0.1047 0.5184 0.5497 0.062 Uiso 1 1 calc R U .
C29 C -0.0769(6) 0.59946(19) 0.58536(19) 0.0387(10) Uani 1 1 d . . .
C30 C -0.0133(7) 0.8525(2) 0.6271(2) 0.0566(14) Uani 1 1 d . . .
H30 H -0.0035 0.8502 0.6641 0.068 Uiso 1 1 calc R U .
C31 C -0.0085(9) 0.9075(2) 0.6040(3) 0.0716(18) Uani 1 1 d . . .
H31 H 0.0030 0.9428 0.6245 0.086 Uiso 1 1 calc R U .
C32 C -0.0206(9) 0.9104(3) 0.5514(3) 0.0773(19) Uani 1 1 d . . .
H32 H -0.0167 0.9483 0.5348 0.093 Uiso 1 1 calc R U .
C33 C -0.0382(8) 0.8597(2) 0.5219(2) 0.0609(15) Uani 1 1 d . . .
H33 H -0.0479 0.8621 0.4849 0.073 Uiso 1 1 calc R U .
C34 C -0.0417(6) 0.8044(2) 0.5469(2) 0.0436(11) Uani 1 1 d . . .
C35 C -0.0093(7) 0.7468(2) 0.75263(19) 0.0423(10) Uani 1 1 d . . .
C36 C 0.0019(8) 0.7590(2) 0.80797(18) 0.0514(12) Uani 1 1 d . . .
H36A H 0.0146 0.8022 0.8138 0.077 Uiso 1 1 calc R U .
H36B H 0.1184 0.7385 0.8247 0.077 Uiso 1 1 calc R U .
H36C H -0.1196 0.7444 0.8229 0.077 Uiso 1 1 calc R U .
C37 C 0.4912(19) 0.9752(6) 0.5048(6) 0.070(3) Uani 0.5 1 d . . P
C38 C 0.482(2) 1.0059(9) 0.5486(6) 0.102(5) Uani 0.5 1 d . . P
H38C H 0.5321 0.9650 0.5537 0.153 Uiso 0.5 1 calc R U P
H38B H 0.3393 1.0070 0.5549 0.153 Uiso 0.5 1 calc R U P
H38A H 0.5552 1.0329 0.5730 0.153 Uiso 0.5 1 calc R U P
N1 N 0.4710(5) 0.68629(14) 0.68901(12) 0.0287(7) Uani 1 1 d . . .
N2 N 0.4472(5) 0.75199(16) 0.54380(13) 0.0347(8) Uani 1 1 d . . .
N3 N 0.4877(5) 0.82116(16) 0.64877(14) 0.0373(8) Uani 1 1 d . . .
N4 N -0.0575(5) 0.62702(16) 0.63375(14) 0.0383(8) Uani 1 1 d . . .
N5 N -0.0313(5) 0.80190(16) 0.59995(16) 0.0435(9) Uani 1 1 d . . .
N6 N -0.0189(6) 0.73723(17) 0.70931(16) 0.0460(9) Uani 1 1 d . . .
N7 N 0.463(2) 0.9529(7) 0.5411(5) 0.107(5) Uani 0.5 1 d . . P
F1 F 0.4572(7) 0.94131(13) 0.79780(13) 0.0942(13) Uani 1 1 d . . .
F2 F 0.6328(11) 0.89742(19) 0.8629(2) 0.181(3) Uani 1 1 d . . .
F3 F 0.3147(8) 0.87834(19) 0.85238(16) 0.1264(19) Uani 1 1 d . . .
F4 F 0.6664(6) 0.86739(19) 0.77872(18) 0.1137(16) Uani 1 1 d . . .
F5 F 0.3493(6) 0.85234(16) 0.77077(14) 0.0880(11) Uani 1 1 d . . .
F6 F 0.5353(6) 0.80833(13) 0.83627(13) 0.0799(10) Uani 1 1 d . . .
F7 F 0.1700(6) 0.63056(15) 0.87647(15) 0.0971(13) Uani 1 1 d . . .
F8 F -0.1603(6) 0.63206(15) 0.88170(14) 0.0912(12) Uani 1 1 d . . .
F9 F 0.0196(6) 0.55670(15) 0.91887(13) 0.0868(11) Uani 1 1 d . . .
F10 F -0.0311(5) 0.61340(14) 0.80601(11) 0.0699(9) Uani 1 1 d . . .
F11 F 0.1492(5) 0.53825(14) 0.84332(14) 0.0772(10) Uani 1 1 d . . .
F12 F -0.1797(5) 0.53966(14) 0.84781(15) 0.0809(10) Uani 1 1 d . . .
P1 P 0.4978(3) 0.87499(6) 0.81733(5) 0.0610(4) Uani 1 1 d . . .
P2 P -0.0051(2) 0.58530(5) 0.86241(5) 0.0478(3) Uani 1 1 d . . .
Pt1 Pt 0.46457(2) 0.73296(2) 0.62119(2) 0.02850(5) Uani 1 1 d . . .
Pt2 Pt -0.04111(2) 0.71729(2) 0.62955(2) 0.03489(5) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C6 C1 C2 123.0(4) . .
C6 C1 Pt1 118.7(3) . .
C2 C1 Pt1 118.3(3) . .
C3 C2 C1 118.4(4) . .
C3 C2 C11 128.9(4) . .
C1 C2 C11 112.7(3) . .
C2 C3 C4 118.9(4) . .
C2 C3 H3 120.5 . .
C4 C3 H3 120.5 . .
C5 C4 C3 122.2(4) . .
C5 C4 H4 118.9 . .
C3 C4 H4 118.9 . .
C4 C5 C6 119.5(4) . .
C4 C5 H5 120.3 . .
C6 C5 H5 120.3 . .
C1 C6 C5 118.0(4) . .
C1 C6 C16 112.5(4) . .
C5 C6 C16 129.5(4) . .
N1 C7 C8 122.3(4) . .
N1 C7 H7 118.8 . .
C8 C7 H7 118.8 . .
C7 C8 C9 119.2(4) . .
C7 C8 H8 120.4 . .
C9 C8 H8 120.4 . .
C10 C9 C8 119.2(4) . .
C10 C9 H9 120.4 . .
C8 C9 H9 120.4 . .
C9 C10 C11 119.8(4) . .
C9 C10 H10 120.1 . .
C11 C10 H10 120.1 . .
N1 C11 C10 120.4(4) . .
N1 C11 C2 113.6(3) . .
C10 C11 C2 125.9(4) . .
N2 C12 C13 121.6(5) . .
N2 C12 H12 119.2 . .
C13 C12 H12 119.2 . .
C14 C13 C12 119.1(5) . .
C14 C13 H13 120.5 . .
C12 C13 H13 120.5 . .
C15 C14 C13 120.3(5) . .
C15 C14 H14 119.8 . .
C13 C14 H14 119.8 . .
C14 C15 C16 119.4(5) . .
C14 C15 H15 120.3 . .
C16 C15 H15 120.3 . .
N2 C16 C15 120.1(4) . .
N2 C16 C6 114.1(4) . .
C15 C16 C6 125.8(4) . .
N3 C17 C18 178.9(5) . .
C17 C18 H18A 109.5 . .
C17 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C17 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
C20 C19 C24 123.2(4) . .
C20 C19 Pt2 118.3(3) . .
C24 C19 Pt2 118.5(3) . .
C19 C20 C21 117.5(4) . .
C19 C20 C29 113.1(4) . .
C21 C20 C29 129.5(4) . .
C22 C21 C20 119.5(5) . .
C22 C21 H21 120.2 . .
C20 C21 H21 120.2 . .
C23 C22 C21 122.2(5) . .
C23 C22 H22 118.9 . .
C21 C22 H22 118.9 . .
C22 C23 C24 119.3(5) . .
C22 C23 H23 120.3 . .
C24 C23 H23 120.3 . .
C23 C24 C19 118.3(5) . .
C23 C24 C34 129.1(5) . .
C19 C24 C34 112.5(4) . .
N4 C25 C26 122.2(5) . .
N4 C25 H25 118.9 . .
C26 C25 H25 118.9 . .
C27 C26 C25 118.8(5) . .
C27 C26 H26 120.6 . .
C25 C26 H26 120.6 . .
C28 C27 C26 120.1(5) . .
C28 C27 H27 119.9 . .
C26 C27 H27 119.9 . .
C27 C28 C29 120.1(5) . .
C27 C28 H28 119.9 . .
C29 C28 H28 119.9 . .
C28 C29 N4 119.3(5) . .
C28 C29 C20 126.4(4) . .
N4 C29 C20 114.2(4) . .
N5 C30 C31 122.8(6) . .
N5 C30 H30 118.6 . .
C31 C30 H30 118.6 . .
C32 C31 C30 118.4(6) . .
C32 C31 H31 120.8 . .
C30 C31 H31 120.8 . .
C31 C32 C33 121.0(6) . .
C31 C32 H32 119.5 . .
C33 C32 H32 119.5 . .
C32 C33 C34 118.8(6) . .
C32 C33 H33 120.6 . .
C34 C33 H33 120.6 . .
N5 C34 C33 119.8(5) . .
N5 C34 C24 114.5(4) . .
C33 C34 C24 125.6(5) . .
N6 C35 C36 179.7(6) . .
C35 C36 H36A 109.5 . .
C35 C36 H36B 109.5 . .
H36A C36 H36B 109.5 . .
C35 C36 H36C 109.5 . .
H36A C36 H36C 109.5 . .
H36B C36 H36C 109.5 . .
N7 C37 C38 169.0(18) . 3_676
C37 C38 H38C 109.5 3_676 .
C37 C38 H38B 109.5 3_676 .
H38C C38 H38B 109.5 . .
C37 C38 H38A 109.5 3_676 .
H38C C38 H38A 109.5 . .
H38B C38 H38A 109.5 . .
C7 N1 C11 119.1(3) . .
C7 N1 Pt1 126.3(3) . .
C11 N1 Pt1 114.6(2) . .
C12 N2 C16 119.5(4) . .
C12 N2 Pt1 126.2(3) . .
C16 N2 Pt1 114.3(3) . .
C17 N3 Pt1 175.2(4) . .
C25 N4 C29 119.4(4) . .
C25 N4 Pt2 127.2(3) . .
C29 N4 Pt2 113.4(3) . .
C30 N5 C34 119.2(4) . .
C30 N5 Pt2 126.6(4) . .
C34 N5 Pt2 114.2(3) . .
C35 N6 Pt2 178.4(4) . .
F2 P1 F4 96.0(4) . .
F2 P1 F3 89.5(4) . .
F4 P1 F3 174.2(3) . .
F2 P1 F6 89.9(2) . .
F4 P1 F6 89.2(2) . .
F3 P1 F6 89.0(2) . .
F2 P1 F1 91.0(2) . .
F4 P1 F1 91.0(2) . .
F3 P1 F1 90.7(2) . .
F6 P1 F1 179.1(2) . .
F2 P1 F5 177.8(4) . .
F4 P1 F5 86.1(2) . .
F3 P1 F5 88.4(3) . .
F6 P1 F5 90.6(2) . .
F1 P1 F5 88.5(2) . .
F7 P2 F11 90.2(2) . .
F7 P2 F8 90.1(2) . .
F11 P2 F8 179.6(2) . .
F7 P2 F10 89.44(19) . .
F11 P2 F10 90.80(19) . .
F8 P2 F10 89.45(19) . .
F7 P2 F12 179.4(3) . .
F11 P2 F12 89.3(2) . .
F8 P2 F12 90.4(2) . .
F10 P2 F12 90.22(19) . .
F7 P2 F9 91.0(2) . .
F11 P2 F9 89.15(19) . .
F8 P2 F9 90.60(19) . .
F10 P2 F9 179.5(2) . .
F12 P2 F9 89.3(2) . .
C1 Pt1 N1 80.76(15) . .
C1 Pt1 N2 80.33(16) . .
N1 Pt1 N2 161.08(13) . .
C1 Pt1 N3 177.81(16) . .
N1 Pt1 N3 101.28(13) . .
N2 Pt1 N3 97.62(14) . .
C19 Pt2 N4 80.95(17) . .
C19 Pt2 N5 80.26(17) . .
N4 Pt2 N5 161.21(15) . .
C19 Pt2 N6 179.79(18) . .
N4 Pt2 N6 99.24(15) . .
N5 Pt2 N6 99.55(16) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C6 1.385(5) .
C1 C2 1.391(6) .
C1 Pt1 1.905(4) .
C2 C3 1.386(5) .
C2 C11 1.466(5) .
C3 C4 1.390(6) .
C3 H3 0.9500 .
C4 C5 1.380(7) .
C4 H4 0.9500 .
C5 C6 1.390(6) .
C5 H5 0.9500 .
C6 C16 1.451(6) .
C7 N1 1.335(5) .
C7 C8 1.365(6) .
C7 H7 0.9500 .
C8 C9 1.377(6) .
C8 H8 0.9500 .
C9 C10 1.375(6) .
C9 H9 0.9500 .
C10 C11 1.377(6) .
C10 H10 0.9500 .
C11 N1 1.365(5) .
C12 N2 1.341(6) .
C12 C13 1.374(6) .
C12 H12 0.9500 .
C13 C14 1.363(7) .
C13 H13 0.9500 .
C14 C15 1.363(7) .
C14 H14 0.9500 .
C15 C16 1.385(6) .
C15 H15 0.9500 .
C16 N2 1.365(5) .
C17 N3 1.135(5) .
C17 C18 1.443(6) .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
C19 C20 1.372(6) .
C19 C24 1.389(6) .
C19 Pt2 1.914(4) .
C20 C21 1.400(6) .
C20 C29 1.450(6) .
C21 C22 1.380(7) .
C21 H21 0.9500 .
C22 C23 1.367(7) .
C22 H22 0.9500 .
C23 C24 1.385(7) .
C23 H23 0.9500 .
C24 C34 1.453(7) .
C25 N4 1.328(6) .
C25 C26 1.375(7) .
C25 H25 0.9500 .
C26 C27 1.370(8) .
C26 H26 0.9500 .
C27 C28 1.359(7) .
C27 H27 0.9500 .
C28 C29 1.384(6) .
C28 H28 0.9500 .
C29 N4 1.386(5) .
C30 N5 1.328(6) .
C30 C31 1.365(8) .
C30 H30 0.9500 .
C31 C32 1.350(9) .
C31 H31 0.9500 .
C32 C33 1.364(8) .
C32 H32 0.9500 .
C33 C34 1.395(7) .
C33 H33 0.9500 .
C34 N5 1.360(6) .
C35 N6 1.131(6) .
C35 C36 1.445(6) .
C36 H36A 0.9800 .
C36 H36B 0.9800 .
C36 H36C 0.9800 .
C37 N7 1.085(17) .
C37 C38 1.46(2) 3_676
C38 C37 1.46(2) 3_676
C38 H38C 0.9800 .
C38 H38B 0.9800 .
C38 H38A 0.9800 .
N1 Pt1 2.029(3) .
N2 Pt1 2.030(3) .
N3 Pt1 2.096(4) .
N4 Pt2 2.023(4) .
N5 Pt2 2.040(4) .
N6 Pt2 2.093(4) .
F1 P1 1.582(3) .
F2 P1 1.517(4) .
F3 P1 1.573(4) .
F4 P1 1.564(4) .
F5 P1 1.588(4) .
F6 P1 1.582(3) .
F7 P2 1.574(3) .
F8 P2 1.578(3) .
F9 P2 1.584(3) .
F10 P2 1.578(3) .
F11 P2 1.577(3) .
F12 P2 1.579(3) .
