#------------------------------------------------------------------------------
#$Date: 2019-11-23 05:46:39 +0200 (Sat, 23 Nov 2019) $
#$Revision: 232261 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/73/4347313.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4347313
loop_
_publ_author_name
'Zhu, Mei'
'Li, Cun'
'Wang, Xiufeng'
'Li, Licun'
'Sutter, Jean-Pascal'
_publ_section_title
;
 Thermal Magnetic Hysteresis in a Copper-Gadolinium-Radical Chain
 Compound.
;
_journal_issue                   6
_journal_name_full               'Inorganic chemistry'
_journal_page_first              2676
_journal_page_last               2678
_journal_paper_doi               10.1021/acs.inorgchem.6b00004
_journal_volume                  55
_journal_year                    2016
_chemical_formula_moiety         'C47 H35 Cu Dy F30 N8 O14'
_chemical_formula_sum            'C47 H35 Cu Dy F30 N8 O14'
_chemical_formula_weight         1731.88
_space_group_IT_number           13
_space_group_name_Hall           '-P 2yc'
_space_group_name_H-M_alt        'P 1 2/c 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yc'
_symmetry_space_group_name_H-M   'P 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 108.21(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   14.588(3)
_cell_length_b                   11.141(2)
_cell_length_c                   20.125(4)
_cell_measurement_reflns_used    11536
_cell_measurement_temperature    113(2)
_cell_measurement_theta_max      27.9
_cell_measurement_theta_min      1.6
_cell_volume                     3107.0(12)
_computing_cell_refinement       'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_data_collection       'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_data_reduction        'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      113(2)
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'profile data from ω-scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0423
_diffrn_reflns_av_sigmaI/netI    0.0362
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            24378
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.47
_exptl_absorpt_coefficient_mu    1.693
_exptl_absorpt_correction_T_max  0.816
_exptl_absorpt_correction_T_min  0.752
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   CrystalClear
_exptl_crystal_colour            purple
_exptl_crystal_density_diffrn    1.851
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             1700
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.12
_refine_diff_density_max         3.402
_refine_diff_density_min         -1.860
_refine_diff_density_rms         0.196
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.068
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     461
_refine_ls_number_reflns         5376
_refine_ls_number_restraints     66
_refine_ls_restrained_S_all      1.130
_refine_ls_R_factor_all          0.0892
_refine_ls_R_factor_gt           0.0815
_refine_ls_shift/su_max          0.032
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1000P)²+36.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2022
_refine_ls_wR_factor_ref         0.2106
_reflns_number_gt                4757
_reflns_number_total             5487
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic6b00004_si_005.cif
_cod_data_source_block           Dy113K
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'Multi-scan' was
changed to 'multi-scan' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/ACS/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_sg_symbol_H-M      P2/c
_cod_database_code               4347313
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Dy1 Dy 0.5000 0.40805(5) 0.2500 0.0290(2) Uani 1 2 d S
Cu1 Cu 0.0000 0.09564(13) 0.2500 0.0354(4) Uani 1 2 d SU
F4 F 0.6890(12) -0.0175(14) 0.2959(7) 0.168(5) Uani 1 1 d U
F5 F 0.7555(6) 0.1000(8) 0.3741(5) 0.090(3) Uani 1 1 d U
F6 F 0.6301(12) 0.0148(18) 0.3663(9) 0.188(5) Uani 1 1 d U
F7 F 0.6333(9) 0.7129(8) 0.1320(7) 0.137(5) Uani 1 1 d .
F8 F 0.4921(9) 0.7736(14) 0.0945(5) 0.163(7) Uani 1 1 d .
F9 F 0.5917(9) 0.8685(8) 0.1690(5) 0.104(3) Uani 1 1 d .
F10 F 0.2169(8) -0.2318(10) 0.2088(10) 0.163(7) Uani 1 1 d .
F11 F 0.1231(13) -0.2897(10) 0.2602(6) 0.164(7) Uani 1 1 d .
F12 F 0.0939(8) -0.3173(8) 0.1551(5) 0.111(4) Uani 1 1 d .
F13 F -0.0967(4) -0.0507(5) -0.0107(3) 0.0435(13) Uani 1 1 d .
F14 F -0.2044(4) 0.0154(7) 0.0326(4) 0.067(2) Uani 1 1 d .
F15 F -0.1012(5) 0.1379(6) 0.0122(3) 0.0526(16) Uani 1 1 d .
O1 O 0.5567(4) 0.3252(6) 0.1636(3) 0.0370(14) Uani 1 1 d D
O2 O 0.6010(5) 0.2469(6) 0.3015(3) 0.0370(14) Uani 1 1 d D
O3 O 0.5439(5) 0.5745(6) 0.1959(3) 0.0355(14) Uani 1 1 d .
O4 O 0.3551(4) 0.4884(6) 0.1740(3) 0.0348(14) Uani 1 1 d .
O5 O 0.0621(5) 0.3291(7) 0.0421(4) 0.0490(18) Uani 1 1 d .
O6 O 0.0925(8) -0.0493(7) 0.2439(4) 0.071(3) Uani 1 1 d DU
O7 O -0.0499(5) 0.0950(5) 0.1487(3) 0.0408(16) Uani 1 1 d D
N1 N 0.2831(5) 0.4531(7) 0.1205(4) 0.0305(16) Uani 1 1 d .
N2 N 0.1444(5) 0.3794(8) 0.0580(4) 0.0371(18) Uani 1 1 d .
N3 N 0.2006(6) 0.3998(7) 0.3089(4) 0.0383(18) Uani 1 1 d .
N4 N 0.1031(5) 0.2380(7) 0.2477(4) 0.0298(15) Uani 1 1 d .
C1 C 0.6743(7) 0.0611(9) 0.3333(6) 0.044(2) Uani 1 1 d D
C2 C 0.6297(9) 0.1620(12) 0.2781(7) 0.067(3) Uani 1 1 d D
C3 C 0.6288(10) 0.1428(13) 0.2073(7) 0.070(3) Uani 1 1 d DU
H3 H 0.6550 0.0728 0.1957 0.084 Uiso 1 1 calc R
C4 C 0.5875(8) 0.2308(11) 0.1542(7) 0.070(4) Uani 1 1 d DU
C5 C 0.5965(10) 0.1938(10) 0.0875(7) 0.060(3) Uani 1 1 d DU
C6 C 0.5647(8) 0.7611(9) 0.1490(5) 0.045(2) Uani 1 1 d .
C7 C 0.5348(6) 0.6854(8) 0.2026(5) 0.036(2) Uani 1 1 d .
C8 C 0.5000 0.7484(13) 0.2500 0.035(3) Uani 1 2 d S
H8 H 0.5000 0.8319 0.2500 0.042 Uiso 1 2 calc SR
C9 C 0.2207(7) 0.4293(8) 0.2502(5) 0.035(2) Uani 1 1 d .
H9 H 0.2608 0.4944 0.2508 0.042 Uiso 1 1 calc R
C10 C 0.1829(6) 0.3644(8) 0.1883(4) 0.0308(18) Uani 1 1 d .
C11 C 0.1238(6) 0.2691(8) 0.1894(5) 0.0320(19) Uani 1 1 d .
H11 H 0.0974 0.2248 0.1488 0.038 Uiso 1 1 calc R
C12 C 0.1428(7) 0.3066(8) 0.3042(5) 0.037(2) Uani 1 1 d .
H12 H 0.1281 0.2863 0.3445 0.044 Uiso 1 1 calc R
C13 C 0.2045(6) 0.3988(8) 0.1236(4) 0.0293(18) Uani 1 1 d .
C14 C 0.2484(9) 0.6264(10) 0.0443(6) 0.052(3) Uani 1 1 d .
H14A H 0.1871 0.6357 0.0520 0.078 Uiso 1 1 calc R
H14B H 0.2447 0.6584 -0.0008 0.078 Uiso 1 1 calc R
H14C H 0.2970 0.6688 0.0799 0.078 Uiso 1 1 calc R
C15 C 0.3707(7) 0.4751(10) 0.0342(5) 0.042(2) Uani 1 1 d .
H15A H 0.4183 0.5266 0.0648 0.063 Uiso 1 1 calc R
H15B H 0.3644 0.4942 -0.0135 0.063 Uiso 1 1 calc R
H15C H 0.3904 0.3930 0.0434 0.063 Uiso 1 1 calc R
C16 C 0.2744(7) 0.4935(9) 0.0469(5) 0.037(2) Uani 1 1 d .
C17 C 0.1918(7) 0.4108(9) 0.0034(5) 0.040(2) Uani 1 1 d .
C18 C 0.2254(9) 0.2940(10) -0.0187(6) 0.055(3) Uani 1 1 d .
H18A H 0.2703 0.2561 0.0211 0.082 Uiso 1 1 calc R
H18B H 0.2563 0.3092 -0.0536 0.082 Uiso 1 1 calc R
H18C H 0.1709 0.2421 -0.0378 0.082 Uiso 1 1 calc R
C19 C 0.1174(8) 0.4708(13) -0.0580(6) 0.061(3) Uani 1 1 d .
H19A H 0.0690 0.4133 -0.0814 0.092 Uiso 1 1 calc R
H19B H 0.1485 0.5010 -0.0901 0.092 Uiso 1 1 calc R
H19C H 0.0876 0.5359 -0.0412 0.092 Uiso 1 1 calc R
C20 C -0.1097(7) 0.0278(9) 0.0372(4) 0.041(2) Uani 1 1 d D
C21 C -0.0466(5) 0.0098(7) 0.1080(4) 0.036(2) Uani 1 1 d D
C22 C 0.0087(7) -0.0948(8) 0.1255(5) 0.037(2) Uani 1 1 d D
H22 H 0.0020 -0.1526 0.0910 0.044 Uiso 1 1 calc R
C23 C 0.0728(9) -0.1174(9) 0.1915(5) 0.049(3) Uani 1 1 d D
C24 C 0.1272(9) -0.2373(11) 0.2049(6) 0.056(3) Uani 1 1 d D
F3 F 0.4986(12) 0.1646(17) 0.0460(8) 0.173(6) Uani 1 1 d U
F2 F 0.6188(12) 0.1002(12) 0.0680(8) 0.157(5) Uani 1 1 d U
F1 F 0.6199(10) 0.2811(9) 0.0550(5) 0.122(4) Uani 1 1 d U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1653 3.9035 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Dy1 O1 133.5(3) 2_655 .
O1 Dy1 O3 75.8(2) 2_655 2_655
O1 Dy1 O3 150.7(2) . 2_655
O1 Dy1 O3 150.7(2) 2_655 .
O1 Dy1 O3 75.8(2) . .
O3 Dy1 O3 75.1(3) 2_655 .
O1 Dy1 O2 73.0(2) 2_655 2_655
O1 Dy1 O2 71.9(2) . 2_655
O3 Dy1 O2 125.9(2) 2_655 2_655
O3 Dy1 O2 128.8(2) . 2_655
O1 Dy1 O2 71.9(2) 2_655 .
O1 Dy1 O2 73.0(2) . .
O3 Dy1 O2 128.8(2) 2_655 .
O3 Dy1 O2 125.9(2) . .
O2 Dy1 O2 80.2(3) 2_655 .
O1 Dy1 O4 97.0(2) 2_655 2_655
O1 Dy1 O4 100.3(2) . 2_655
O3 Dy1 O4 73.6(2) 2_655 2_655
O3 Dy1 O4 71.4(2) . 2_655
O2 Dy1 O4 152.4(2) 2_655 2_655
O2 Dy1 O4 72.1(2) . 2_655
O1 Dy1 O4 100.3(2) 2_655 .
O1 Dy1 O4 97.0(2) . .
O3 Dy1 O4 71.4(2) 2_655 .
O3 Dy1 O4 73.6(2) . .
O2 Dy1 O4 72.1(2) 2_655 .
O2 Dy1 O4 152.4(2) . .
O4 Dy1 O4 135.5(3) 2_655 .
O7 Cu1 O7 179.6(3) 2 .
O7 Cu1 O6 88.4(3) 2 2
O7 Cu1 O6 91.3(3) . 2
O7 Cu1 O6 91.3(3) 2 .
O7 Cu1 O6 88.4(3) . .
O6 Cu1 O6 81.5(5) 2 .
O7 Cu1 N4 89.4(3) 2 .
O7 Cu1 N4 90.8(3) . .
O6 Cu1 N4 176.3(3) 2 .
O6 Cu1 N4 95.5(3) . .
O7 Cu1 N4 90.8(3) 2 2
O7 Cu1 N4 89.4(3) . 2
O6 Cu1 N4 95.5(3) 2 2
O6 Cu1 N4 176.3(3) . 2
N4 Cu1 N4 87.5(4) . 2
C4 O1 Dy1 135.4(8) . .
C2 O2 Dy1 133.1(8) . .
C7 O3 Dy1 132.6(6) . .
N1 O4 Dy1 138.1(5) . .
C23 O6 Cu1 121.5(8) . .
C21 O7 Cu1 127.3(6) . .
O4 N1 C13 125.9(7) . .
O4 N1 C16 121.1(7) . .
C13 N1 C16 112.0(7) . .
O5 N2 C13 126.0(7) . .
O5 N2 C17 121.9(7) . .
C13 N2 C17 111.6(7) . .
C12 N3 C9 116.0(8) . .
C12 N4 C11 115.9(8) . .
C12 N4 Cu1 120.7(6) . .
C11 N4 Cu1 123.1(6) . .
F6 C1 F4 105.5(15) . .
F6 C1 F5 110.1(13) . .
F4 C1 F5 109.4(12) . .
F6 C1 C2 122.2(13) . .
F4 C1 C2 101.1(12) . .
F5 C1 C2 107.7(9) . .
O2 C2 C3 128.0(13) . .
O2 C2 C1 114.1(12) . .
C3 C2 C1 117.9(12) . .
C2 C3 C4 120.5(13) . .
C2 C3 H3 119.7 . .
C4 C3 H3 119.7 . .
O1 C4 C3 125.4(12) . .
O1 C4 C5 123.4(12) . .
C3 C4 C5 110.9(12) . .
F2 C5 F1 110.7(12) . .
F2 C5 C4 131.6(14) . .
F1 C5 C4 112.0(10) . .
F2 C5 F3 86.3(13) . .
F1 C5 F3 104.5(13) . .
C4 C5 F3 103.8(10) . .
F8 C6 F7 109.0(13) . .
F8 C6 F9 105.0(12) . .
F7 C6 F9 106.6(11) . .
F8 C6 C7 108.9(9) . .
F7 C6 C7 112.1(9) . .
F9 C6 C7 114.8(9) . .
O3 C7 C8 129.8(9) . .
O3 C7 C6 113.7(9) . .
C8 C7 C6 116.5(9) . .
C7 C8 C7 119.8(12) 2_655 .
C7 C8 H8 120.1 2_655 .
C7 C8 H8 120.1 . .
N3 C9 C10 121.6(8) . .
N3 C9 H9 119.2 . .
C10 C9 H9 119.2 . .
C11 C10 C9 117.5(8) . .
C11 C10 C13 121.4(8) . .
C9 C10 C13 121.1(8) . .
N4 C11 C10 121.8(8) . .
N4 C11 H11 119.1 . .
C10 C11 H11 119.1 . .
N3 C12 N4 127.2(8) . .
N3 C12 H12 116.4 . .
N4 C12 H12 116.4 . .
N1 C13 N2 109.6(7) . .
N1 C13 C10 126.0(8) . .
N2 C13 C10 124.4(8) . .
C16 C14 H14A 109.5 . .
C16 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C16 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C16 C15 H15A 109.5 . .
C16 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
C16 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
N1 C16 C15 109.0(7) . .
N1 C16 C14 105.5(8) . .
C15 C16 C14 111.0(8) . .
N1 C16 C17 100.9(7) . .
C15 C16 C17 114.9(8) . .
C14 C16 C17 114.6(9) . .
C18 C17 N2 106.3(8) . .
C18 C17 C19 110.8(10) . .
N2 C17 C19 108.6(8) . .
C18 C17 C16 114.4(8) . .
N2 C17 C16 100.2(7) . .
C19 C17 C16 115.4(9) . .
C17 C18 H18A 109.5 . .
C17 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C17 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
C17 C19 H19A 109.5 . .
C17 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
C17 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
F15 C20 F13 105.8(7) . .
F15 C20 F14 106.0(8) . .
F13 C20 F14 104.5(7) . .
F15 C20 C21 112.9(7) . .
F13 C20 C21 115.0(7) . .
F14 C20 C21 111.8(7) . .
O7 C21 C22 126.7(8) . .
O7 C21 C20 113.1(8) . .
C22 C21 C20 120.1(7) . .
C23 C22 C21 123.7(9) . .
C23 C22 H22 118.1 . .
C21 C22 H22 118.1 . .
O6 C23 C22 127.0(11) . .
O6 C23 C24 114.1(10) . .
C22 C23 C24 118.9(9) . .
F11 C24 F10 107.1(13) . .
F11 C24 F12 104.3(12) . .
F10 C24 F12 101.9(13) . .
F11 C24 C23 112.9(12) . .
F10 C24 C23 115.5(11) . .
F12 C24 C23 114.1(9) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 O1 2.337(6) 2_655
Dy1 O1 2.337(6) .
Dy1 O3 2.339(6) 2_655
Dy1 O3 2.339(6) .
Dy1 O2 2.348(6) 2_655
Dy1 O2 2.348(6) .
Dy1 O4 2.364(6) 2_655
Dy1 O4 2.364(6) .
Cu1 O7 1.938(6) 2
Cu1 O7 1.938(6) .
Cu1 O6 2.132(10) 2
Cu1 O6 2.132(10) .
Cu1 N4 2.196(7) .
Cu1 N4 2.196(7) 2
F4 C1 1.216(15) .
F5 C1 1.287(12) .
F6 C1 1.180(16) .
F7 C6 1.273(14) .
F8 C6 1.272(14) .
F9 C6 1.284(13) .
F10 C24 1.287(16) .
F11 C24 1.274(15) .
F12 C24 1.316(14) .
F13 C20 1.357(10) .
F14 C20 1.362(11) .
F15 C20 1.346(12) .
O1 C4 1.182(14) .
O2 C2 1.189(15) .
O3 C7 1.254(11) .
O4 N1 1.308(10) .
O5 N2 1.273(10) .
O6 C23 1.257(13) .
O7 C21 1.265(8) .
N1 C13 1.315(11) .
N1 C16 1.514(11) .
N2 C13 1.354(12) .
N2 C17 1.511(11) .
N3 C12 1.322(12) .
N3 C9 1.344(12) .
N4 C12 1.342(12) .
N4 C11 1.344(11) .
C1 C2 1.572(17) .
C2 C3 1.437(19) .
C3 C4 1.437(19) .
C3 H3 0.9300 .
C4 C5 1.449(17) .
C5 F2 1.194(15) .
C5 F1 1.276(14) .
C5 F3 1.449(19) .
C6 C7 1.536(13) .
C7 C8 1.401(12) .
C8 C7 1.401(12) 2_655
C8 H8 0.9300 .
C9 C10 1.395(13) .
C9 H9 0.9300 .
C10 C11 1.373(13) .
C10 C13 1.483(11) .
C11 H11 0.9300 .
C12 H12 0.9300 .
C14 C16 1.525(14) .
C14 H14A 0.9600 .
C14 H14B 0.9600 .
C14 H14C 0.9600 .
C15 C16 1.518(13) .
C15 H15A 0.9600 .
C15 H15B 0.9600 .
C15 H15C 0.9600 .
C16 C17 1.552(14) .
C17 C18 1.507(15) .
C17 C19 1.521(14) .
C18 H18A 0.9600 .
C18 H18B 0.9600 .
C18 H18C 0.9600 .
C19 H19A 0.9600 .
C19 H19B 0.9600 .
C19 H19C 0.9600 .
C20 C21 1.449(9) .
C21 C22 1.399(13) .
C22 C23 1.388(14) .
C22 H22 0.9300 .
C23 C24 1.534(16) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 Dy1 O1 C4 -19.4(8) 2_655 .
O3 Dy1 O1 C4 165.3(8) 2_655 .
O3 Dy1 O1 C4 158.2(9) . .
O2 Dy1 O1 C4 -62.1(8) 2_655 .
O2 Dy1 O1 C4 22.9(9) . .
O4 Dy1 O1 C4 90.5(9) 2_655 .
O4 Dy1 O1 C4 -130.7(8) . .
O1 Dy1 O2 C2 129.7(11) 2_655 .
O1 Dy1 O2 C2 -19.3(10) . .
O3 Dy1 O2 C2 -176.7(10) 2_655 .
O3 Dy1 O2 C2 -76.7(11) . .
O2 Dy1 O2 C2 54.6(10) 2_655 .
O4 Dy1 O2 C2 -126.4(10) 2_655 .
O4 Dy1 O2 C2 52.5(12) . .
O1 Dy1 O3 C7 -9.5(11) 2_655 .
O1 Dy1 O3 C7 174.0(9) . .
O3 Dy1 O3 C7 -2.4(7) 2_655 .
O2 Dy1 O3 C7 121.9(8) 2_655 .
O2 Dy1 O3 C7 -129.8(8) . .
O4 Dy1 O3 C7 -79.8(8) 2_655 .
O4 Dy1 O3 C7 72.2(8) . .
O1 Dy1 O4 N1 -88.4(7) 2_655 .
O1 Dy1 O4 N1 48.2(7) . .
O3 Dy1 O4 N1 -159.5(8) 2_655 .
O3 Dy1 O4 N1 121.1(8) . .
O2 Dy1 O4 N1 -20.2(7) 2_655 .
O2 Dy1 O4 N1 -18.0(10) . .
O4 Dy1 O4 N1 160.5(8) 2_655 .
O7 Cu1 O6 C23 156.3(9) 2 .
O7 Cu1 O6 C23 -23.4(9) . .
O6 Cu1 O6 C23 68.1(9) 2 .
N4 Cu1 O6 C23 -114.1(9) . .
N4 Cu1 O6 C23 31(5) 2 .
O7 Cu1 O7 C21 -19.8(7) 2 .
O6 Cu1 O7 C21 -60.5(7) 2 .
O6 Cu1 O7 C21 21.0(7) . .
N4 Cu1 O7 C21 116.5(7) . .
N4 Cu1 O7 C21 -156.0(7) 2 .
Dy1 O4 N1 C13 87.3(10) . .
Dy1 O4 N1 C16 -104.7(9) . .
O7 Cu1 N4 C12 -20.6(7) 2 .
O7 Cu1 N4 C12 159.7(7) . .
O6 Cu1 N4 C12 -75(5) 2 .
O6 Cu1 N4 C12 -111.8(7) . .
N4 Cu1 N4 C12 70.3(7) 2 .
O7 Cu1 N4 C11 165.4(7) 2 .
O7 Cu1 N4 C11 -14.3(7) . .
O6 Cu1 N4 C11 111(4) 2 .
O6 Cu1 N4 C11 74.2(7) . .
N4 Cu1 N4 C11 -103.7(7) 2 .
Dy1 O2 C2 C3 15(2) . .
Dy1 O2 C2 C1 -165.1(6) . .
F6 C1 C2 O2 57.4(18) . .
F4 C1 C2 O2 173.9(13) . .
F5 C1 C2 O2 -71.4(14) . .
F6 C1 C2 C3 -123.0(16) . .
F4 C1 C2 C3 -6.6(16) . .
F5 C1 C2 C3 108.2(13) . .
O2 C2 C3 C4 -2(2) . .
C1 C2 C3 C4 179.0(10) . .
Dy1 O1 C4 C3 -21.3(14) . .
Dy1 O1 C4 C5 164.7(7) . .
C2 C3 C4 O1 4.0(17) . .
C2 C3 C4 C5 178.7(11) . .
O1 C4 C5 F2 -173.5(17) . .
C3 C4 C5 F2 12(2) . .
O1 C4 C5 F1 36.1(16) . .
C3 C4 C5 F1 -138.7(13) . .
O1 C4 C5 F3 -76.1(13) . .
C3 C4 C5 F3 109.2(13) . .
Dy1 O3 C7 C8 5.1(14) . .
Dy1 O3 C7 C6 -173.2(6) . .
F8 C6 C7 O3 88.1(13) . .
F7 C6 C7 O3 -32.6(14) . .
F9 C6 C7 O3 -154.5(11) . .
F8 C6 C7 C8 -90.5(13) . .
F7 C6 C7 C8 148.8(10) . .
F9 C6 C7 C8 26.9(13) . .
O3 C7 C8 C7 -2.7(8) . 2_655
C6 C7 C8 C7 175.6(9) . 2_655
C12 N3 C9 C10 -0.3(13) . .
N3 C9 C10 C11 0.2(13) . .
N3 C9 C10 C13 179.1(8) . .
C12 N4 C11 C10 0.7(12) . .
Cu1 N4 C11 C10 175.0(6) . .
C9 C10 C11 N4 -0.4(13) . .
C13 C10 C11 N4 -179.3(8) . .
C9 N3 C12 N4 0.6(15) . .
C11 N4 C12 N3 -0.9(14) . .
Cu1 N4 C12 N3 -175.3(8) . .
O4 N1 C13 N2 177.9(8) . .
C16 N1 C13 N2 9.1(10) . .
O4 N1 C13 C10 -1.5(14) . .
C16 N1 C13 C10 -170.3(8) . .
O5 N2 C13 N1 -179.8(9) . .
C17 N2 C13 N1 7.5(10) . .
O5 N2 C13 C10 -0.4(15) . .
C17 N2 C13 C10 -173.1(8) . .
C11 C10 C13 N1 -152.4(9) . .
C9 C10 C13 N1 28.7(13) . .
C11 C10 C13 N2 28.3(13) . .
C9 C10 C13 N2 -150.6(9) . .
O4 N1 C16 C15 48.6(11) . .
C13 N1 C16 C15 -142.0(8) . .
O4 N1 C16 C14 -70.6(10) . .
C13 N1 C16 C14 98.8(9) . .
O4 N1 C16 C17 169.9(7) . .
C13 N1 C16 C17 -20.7(9) . .
O5 N2 C17 C18 -73.2(11) . .
C13 N2 C17 C18 99.8(10) . .
O5 N2 C17 C19 46.0(13) . .
C13 N2 C17 C19 -140.9(9) . .
O5 N2 C17 C16 167.4(8) . .
C13 N2 C17 C16 -19.5(10) . .
N1 C16 C17 C18 -91.2(9) . .
C15 C16 C17 C18 25.8(11) . .
C14 C16 C17 C18 156.1(8) . .
N1 C16 C17 N2 22.0(8) . .
C15 C16 C17 N2 139.0(8) . .
C14 C16 C17 N2 -90.7(9) . .
N1 C16 C17 C19 138.5(8) . .
C15 C16 C17 C19 -104.5(10) . .
C14 C16 C17 C19 25.8(12) . .
Cu1 O7 C21 C22 -12.6(11) . .
Cu1 O7 C21 C20 166.2(6) . .
F15 C20 C21 O7 47.8(8) . .
F13 C20 C21 O7 169.4(8) . .
F14 C20 C21 O7 -71.6(9) . .
F15 C20 C21 C22 -133.2(8) . .
F13 C20 C21 C22 -11.6(10) . .
F14 C20 C21 C22 107.3(9) . .
O7 C21 C22 C23 -3.1(14) . .
C20 C21 C22 C23 178.1(9) . .
Cu1 O6 C23 C22 18.3(17) . .
Cu1 O6 C23 C24 -161.5(8) . .
C21 C22 C23 O6 -1.5(18) . .
C21 C22 C23 C24 178.2(9) . .
O6 C23 C24 F11 48.9(17) . .
C22 C23 C24 F11 -130.9(14) . .
O6 C23 C24 F10 -74.7(17) . .
C22 C23 C24 F10 105.4(15) . .
O6 C23 C24 F12 167.7(12) . .
C22 C23 C24 F12 -12.1(17) . .
