#------------------------------------------------------------------------------
#$Date: 2019-11-23 06:30:05 +0200 (Sat, 23 Nov 2019) $
#$Revision: 232331 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/74/4347462.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4347462
loop_
_publ_author_name
'Xu, Hang'
'Fang, Ming'
'Cao, Chun-Shuai'
'Qiao, Wan-Zhen'
'Zhao, Bin'
_publ_section_title
;
 Unique (3,4,10)-Connected Lanthanide-Organic Framework as a Recyclable
 Chemical Sensor for Detecting Al(3.).
;
_journal_issue                   10
_journal_name_full               'Inorganic chemistry'
_journal_page_first              4790
_journal_page_last               4794
_journal_paper_doi               10.1021/acs.inorgchem.6b00190
_journal_volume                  55
_journal_year                    2016
_chemical_formula_moiety         '0.25(C656 H420 Eu20 O176), 0.5(O2)'
_chemical_formula_sum            'C164 H105 Eu5 O45'
_chemical_formula_weight         3555.28
_space_group_crystal_system      orthorhombic
_space_group_IT_number           57
_space_group_name_Hall           '-P 2c 2b'
_space_group_name_H-M_alt        'P b c m'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2016-03-08
_audit_creation_method
;
Olex2 1.2
(compiled 2015.09.30 svn.r3233 for OlexSys, GUI svn.r5155)
;
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   24.0875(9)
_cell_length_b                   27.8262(8)
_cell_length_c                   30.3154(13)
_cell_measurement_reflns_used    5765
_cell_measurement_temperature    133(2)
_cell_measurement_theta_max      21.6410
_cell_measurement_theta_min      3.0120
_cell_volume                     20319.3(13)
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      133(2)
_diffrn_measured_fraction_theta_full 0.978
_diffrn_measured_fraction_theta_max 0.978
_diffrn_measurement_device_type  multi-scan
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1147
_diffrn_reflns_av_unetI/netI     0.1471
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       33
_diffrn_reflns_limit_k_min       -30
_diffrn_reflns_limit_l_max       36
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            61930
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         2.85
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    1.583
_exptl_crystal_density_diffrn    1.162
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             7056
_platon_squeeze_details
;
;
_refine_diff_density_max         1.877
_refine_diff_density_min         -0.951
_refine_diff_density_rms         0.151
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.021
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1016
_refine_ls_number_reflns         17884
_refine_ls_number_restraints     71
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.1726
_refine_ls_R_factor_gt           0.0945
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1184P)²+5.3037P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2173
_refine_ls_wR_factor_ref         0.2751
_reflns_number_gt                9121
_reflns_number_total             17884
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic6b00190_si_002.cif
_cod_data_source_block           Eu
_cod_database_code               4347462
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups, All O(H,H) groups
2. Restrained distances
 C3A-C8A
 1.36 with sigma of 0.02
 C3A-C78
 1.36 with sigma of 0.02
 C77-C78
 1.36 with sigma of 0.02
 C76-C77
 1.36 with sigma of 0.02
 C76-C73
 1.36 with sigma of 0.02
 C78-C75
 1.36 with sigma of 0.02
 C78-C9B
 1.36 with sigma of 0.02
 C73-C74
 1.36 with sigma of 0.02
 C73-C13B
 1.36 with sigma of 0.02
 C13B-C9B
 1.36 with sigma of 0.02
 C75-C74
 1.36 with sigma of 0.02
 C8A-C76
 2.41 with sigma of 0.02
 C74-C13B
 2.41 with sigma of 0.02
 C3A-C77
 2.41 with sigma of 0.02
 C75-C9B
 2.41 with sigma of 0.02
 C73-C3A
 2.41 with sigma of 0.02
 C77-C73
 2.41 with sigma of 0.02
 C74-C78
 2.41 with sigma of 0.02
 C78-C76
 2.41 with sigma of 0.02
 C27B-C24
 0.001 with sigma of 1.5
 O6A-Eu2 \\sim Eu2-O6B
 with sigma of 0.02
 O5A-Eu1 \\sim Eu1-O5B
 with sigma of 0.02
 O5A-C27A \\sim C27A-O6A
 with sigma of 0.02
 O1A-Eu1 \\sim Eu1-O1B
 with sigma of 0.02
 O1B-C1 \\sim C1-O1A
 with sigma of 0.02
 O12B-Eu1 \\sim Eu1-O12A
 with sigma of 0.02
 O12B-C80 \\sim C80-O12A
 with sigma of 0.02
 O6B-C27B \\sim C27B-O5B
 with sigma of 0.02
 C27B-O5B \\sim O5A-C27A
 with sigma of 0.02
 C27A-O6A \\sim O6B-C27B
 with sigma of 0.02
 C27A-C24_$1 \\sim C24_$1-C27B
 with sigma of 0.02
3. Rigid bond restraints
 C73, C76
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
 C73, C13B
 with sigma for 1-2 distances of 0.001 and sigma for 1-3 distances of 0.001
4. Uiso/Uaniso restraints and constraints
Uanis(C27B) \\sim Ueq, Uanis(C27A) \\sim Ueq, Uanis(O6A) \\sim Ueq, Uanis(O6B)
\\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.005
Uanis(O5A) \\sim Ueq, Uanis(O5B) \\sim Ueq: with sigma of 0.005 and sigma for
terminal atoms of 0.005
Uanis(O4AA) = Uanis(O6BA)
Uanis(O1A) = Uanis(O1B)
Uanis(O6A) = Uanis(O6B)
Uanis(O5A) = Uanis(O5B)
Uanis(O12A) = Uanis(O12B)
Uanis(C74) = Uanis(C8A)
Uanis(C75) = Uanis(C3A)
Uanis(C13B) = Uanis(C76)
Uanis(C9B) = Uanis(C77)
Uanis(C27A) = Uanis(C27B)
5. Others
 Sof(C75)=Sof(H75)=Sof(C74)=Sof(H74)=Sof(C9B)=Sof(H9B)=Sof(C13B)=Sof(H13B)=1-
 FVAR(1)
 Sof(C8A)=Sof(H8A)=Sof(C3A)=Sof(H3A)=Sof(C77)=Sof(H77)=Sof(C76)=Sof(H76)=FVAR(1)
 Sof(O5B)=Sof(O6B)=Sof(C27B)=1-FVAR(2)
 Sof(O6A)=Sof(C27A)=Sof(O5A)=FVAR(2)
 Sof(O1B)=1-FVAR(3)
 Sof(O1A)=FVAR(3)
 Sof(O12B)=1-FVAR(4)
 Sof(O12A)=FVAR(4)
 Fixed Sof: H24A(0.5) H24B(0.5) H23A(0.5) H23B(0.5) H22A(0.5) H22B(0.5)
 H81A(0.5) H81B(0.5) H81C(0.5) H20A(0.5) H20B(0.5) H21A(0.5) H21B(0.5)
 H25A(0.5) H25B(0.5) O4AA(0.25) O6BA(0.25)
6.a Riding coordinates:
 O24(H24A,H24B), O23(H23A,H23B), O22(H22A,H22B), O20(H20A,H20B), O21(H21A,
 H21B), O25(H25A,H25B)
6.b Aromatic/amide H refined with riding coordinates:
 C49(H49), C45(H45), C0AA(H0AA), C20(H20), C119(H119), C17(H17), C31(H31),
 C12(H12), C6(H6), C5(H5), C47(H47), C43(H43), C16(H16), C52(H52), C13(H13),
 C18(H18), C66(H66), C62(H62), C9(H9), C57(H57), C71(H71), C4(H4), C36(H36),
 C32(H32), C59(H59), C50(H50), C58(H58), C3(H3), C39(H39), C26(H26), C30(H30),
 C40(H40), C56(H56), C33(H33), C22(H22), C25(H25), C70(H70), C23(H23), C65(H65),
  C69(H69), C44(H44), C75(H75), C74(H74), C9B(H9B), C13B(H13B), C8A(H8A),
 C3A(H3A), C77(H77), C76(H76)
6.c Idealised Me refined as rotating group:
 C81(H81A,H81B,H81C)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, -y, z+1/2'
3 'x, -y+1/2, -z'
4 '-x, y+1/2, -z+1/2'
5 '-x, -y, -z'
6 'x, y, -z-1/2'
7 '-x, y-1/2, z'
8 'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_site_symmetry_order
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Eu1 Eu 0.75636(3) 0.76293(2) 0.36313(2) 0.0471(2) Uani 1 d . . 1 D . .
Eu3 Eu 0.87839(4) 0.27268(3) 0.7500 0.0497(3) Uani 1 d . . 2 S T P
Eu2 Eu 0.77383(4) 0.85184(3) 0.2500 0.0533(3) Uani 1 d . . 2 DS T P
Eu4 Eu 0.61793(4) 0.29552(3) 1.2500 0.0584(3) Uani 1 d . . 2 S T P
O24 O 0.7125(5) 0.3314(5) 1.2500 0.070(4) Uani 1 d . . 2 S T P
H24A H 0.7322 0.3176 1.2305 0.106 Uiso 0.50 d . . 1 R . .
H24B H 0.7273 0.3275 1.2752 0.106 Uiso 0.50 d . . 1 R . .
O4 O 0.8901(4) 0.3300(3) 0.6940(3) 0.063(2) Uani 1 d . . 1 . . .
O23 O 0.7855(5) 0.3122(5) 0.7500 0.072(4) Uani 1 d . . 2 S T P
H23A H 0.7655 0.2996 0.7699 0.107 Uiso 0.50 d . . 1 R . .
H23B H 0.7702 0.3082 0.7250 0.107 Uiso 0.50 d . . 1 R . .
O19 O 0.7597(3) 0.7710(3) 0.2854(3) 0.0443(19) Uani 1 d . . 1 . . .
O9 O 0.6822(4) 0.2532(4) 1.2021(4) 0.078(3) Uani 1 d . . 1 . . .
C60 C 0.5960(5) 0.9666(4) 0.4095(5) 0.049(3) Uani 1 d . . 1 . . .
O13 O 0.6845(4) 0.8179(3) 0.3490(3) 0.072(3) Uani 1 d . . 1 . . .
C37 C 0.7182(6) 0.1085(4) 1.0382(5) 0.058(3) Uani 1 d . . 1 . . .
C49 C 0.7598(5) -0.0397(4) 1.0577(5) 0.056(3) Uani 1 d . . 1 . . .
H49 H 0.7649 -0.0190 1.0815 0.067 Uiso 1 calc . . 1 R . .
O15 O 0.6881(5) 1.1081(4) 0.6853(5) 0.113(4) Uani 1 d . . 1 . . .
C45 C 0.7189(5) 0.0588(4) 1.0418(4) 0.054(3) Uani 1 d . . 1 . . .
H45 H 0.7013 0.0441 1.0655 0.065 Uiso 1 calc . . 1 R . .
C61 C 0.5692(5) 1.0052(4) 0.4375(5) 0.059(4) Uani 1 d . . 1 . . .
C72 C 0.5020(6) 1.0708(4) 0.4421(5) 0.063(4) Uani 1 d A . 1 . . .
C35 C 0.7690(6) 0.1026(4) 0.9686(5) 0.057(3) Uani 1 d . . 1 . . .
C0AA C 0.7395(6) -0.0528(5) 0.9829(5) 0.067(4) Uani 1 d . . 1 . . .
H0AA H 0.7314 -0.0410 0.9550 0.081 Uiso 1 calc . . 1 R . .
C20 C 0.9610(5) 0.4834(4) 0.4297(5) 0.056(3) Uani 1 d . . 1 . . .
H20 H 0.9696 0.4947 0.4016 0.068 Uiso 1 calc . . 1 R . .
C119 C 0.5277(5) 1.0332(4) 0.4175(5) 0.060(4) Uani 1 d . . 1 . . .
H119 H 0.5171 1.0273 0.3885 0.072 Uiso 1 calc . . 1 R . .
C17 C 0.9555(6) 0.4031(4) 0.5837(4) 0.059(3) Uani 1 d . . 1 . . .
H17 H 0.9927 0.4007 0.5760 0.071 Uiso 1 calc . . 1 R . .
C7 C 0.8972(5) 0.5541(4) 0.4377(4) 0.048(3) Uani 1 d . . 1 . . .
C31 C 0.8430(7) 0.1187(5) 0.9143(5) 0.078(5) Uani 1 d . . 1 . . .
H31 H 0.8659 0.0965 0.9283 0.093 Uiso 1 calc . . 1 R . .
C14 C 0.8803(5) 0.3838(4) 0.6343(4) 0.054(3) Uani 1 d . . 1 . . .
C12 C 0.8644(6) 0.4341(5) 0.5721(5) 0.066(4) Uani 1 d . . 1 . . .
H12 H 0.8396 0.4524 0.5556 0.079 Uiso 1 calc . . 1 R . .
C6 C 0.8864(5) 0.5909(4) 0.4656(5) 0.061(4) Uani 1 d . . 1 . . .
H6 H 0.8936 0.5875 0.4956 0.073 Uiso 1 calc . . 1 R . .
C5 C 0.8643(6) 0.6344(5) 0.4492(5) 0.067(4) Uani 1 d . . 1 . . .
H5 H 0.8587 0.6603 0.4680 0.080 Uiso 1 calc . . 1 R . .
O11 O 0.6816(4) 0.7052(3) 0.3437(3) 0.076(3) Uani 1 d . . 1 . . .
C47 C 0.7705(5) 0.0532(4) 0.9743(4) 0.054(3) Uani 1 d . . 1 . . .
H47 H 0.7888 0.0344 0.9535 0.064 Uiso 1 calc . . 1 R . .
C43 C 0.6279(7) 0.1638(6) 1.1260(7) 0.100(6) Uani 1 d . . 1 . . .
H43 H 0.5905 0.1631 1.1336 0.120 Uiso 1 calc . . 1 R . .
C8 C 0.9226(5) 0.5069(4) 0.4544(5) 0.049(3) Uani 1 d . . 1 . . .
C16 C 0.9359(7) 0.3810(5) 0.6223(6) 0.081(5) Uani 1 d . . 1 . . .
H16 H 0.9606 0.3643 0.6402 0.097 Uiso 1 calc . . 1 R . .
C48 C 0.7492(5) -0.0213(4) 1.0175(4) 0.045(3) Uani 1 d . . 1 . . .
C52 C 0.7420(6) -0.1018(4) 0.9900(5) 0.072(4) Uani 1 d . . 1 . . .
H52 H 0.7357 -0.1226 0.9665 0.086 Uiso 1 calc . . 1 R . .
C13 C 0.8461(6) 0.4135(5) 0.6103(5) 0.062(4) Uani 1 d . . 1 . . .
H13 H 0.8102 0.4195 0.6202 0.075 Uiso 1 calc . . 1 R . .
C55 C 0.6482(5) 0.8954(4) 0.3591(5) 0.053(3) Uani 1 d . . 1 . . .
C10 C 0.9346(5) 0.4502(4) 0.5136(4) 0.047(3) Uani 1 d . . 1 . . .
C18 C 0.9743(5) 0.4261(4) 0.4883(4) 0.048(3) Uani 1 d . . 1 . . .
H18 H 0.9916 0.3991 0.5000 0.057 Uiso 1 calc . . 1 R . .
C63 C 0.5612(5) 1.0495(4) 0.5045(5) 0.056(3) Uani 1 d . . 1 . . .
C51 C 0.7536(5) -0.1207(5) 1.0309(4) 0.057(4) Uani 1 d . . 1 . . .
C66 C 0.6540(7) 1.0697(6) 0.6041(6) 0.085(5) Uani 1 d . . 1 . . .
H66 H 0.6912 1.0647 0.6110 0.101 Uiso 1 calc . . 1 R . .
C62 C 0.5842(6) 1.0130(5) 0.4792(5) 0.059(3) Uani 1 d . . 1 . . .
H62 H 0.6111 0.9933 0.4918 0.071 Uiso 1 calc . . 1 R . .
C46 C 0.7453(5) 0.0309(4) 1.0105(4) 0.053(3) Uani 1 d . . 1 . . .
C64 C 0.5807(6) 1.0633(5) 0.5509(5) 0.064(4) Uani 1 d . . 1 . . .
O22 O 0.9735(6) 0.2769(5) 0.7500 0.087(4) Uani 1 d . . 2 S T P
H22A H 0.9938 0.2776 0.7729 0.130 Uiso 0.50 d . . 1 R . .
H22B H 0.9938 0.2776 0.7271 0.130 Uiso 0.50 d . . 1 R . .
O26 O 0.6118(4) 0.3528(4) 1.1948(4) 0.080(3) Uani 1 d . . 1 . . .
O10 O 0.5976(5) 0.2293(4) 1.1958(4) 0.088(3) Uani 1 d . . 1 . . .
O2 O 0.8047(4) 0.6850(3) 0.3500(3) 0.067(3) Uani 1 d . . 1 . . .
O8 O 0.8130(5) 0.2296(3) 0.7966(4) 0.086(3) Uani 1 d . . 1 . . .
O7 O 0.8965(5) 0.2071(4) 0.8066(4) 0.085(3) Uani 1 d . . 1 . . .
C9 C 0.9095(5) 0.4915(4) 0.4966(5) 0.051(3) Uani 1 d . . 1 . . .
H9 H 0.8839 0.5085 0.5135 0.062 Uiso 1 calc . . 1 R . .
O1B O 0.800(3) 0.7101(19) 0.4185(7) 0.076(12) Uani 0.36(10) d . 2 1 D . .
C67 C 0.6184(6) 1.0974(5) 0.6331(5) 0.071(4) Uani 1 d . . 1 . . .
O18 O 0.7655(5) 0.8135(3) 0.4229(4) 0.092(4) Uani 1 d . . 1 . . .
C57 C 0.6099(6) 0.9748(5) 0.3660(5) 0.067(4) Uani 1 d . . 1 . . .
H57 H 0.6024 1.0046 0.3534 0.081 Uiso 1 calc . . 1 R . .
O3 O 0.8091(5) 0.3688(4) 0.6859(4) 0.094(3) Uani 1 d . . 1 . . .
C71 C 0.5203(5) 1.0781(4) 0.4848(4) 0.054(3) Uani 1 d . . 1 . . .
H71 H 0.5049 1.1031 0.5010 0.065 Uiso 1 calc . . 1 R . .
C4 C 0.8829(6) 0.5572(4) 0.3934(5) 0.064(4) Uani 1 d . . 1 . . .
H4 H 0.8888 0.5313 0.3746 0.077 Uiso 1 calc . . 1 R . .
C36 C 0.7434(6) 0.1286(5) 1.0012(5) 0.066(4) Uani 1 d . . 1 . . .
H36 H 0.7427 0.1619 0.9983 0.079 Uiso 1 calc . . 1 R . .
C32 C 0.7755(7) 0.1815(5) 0.8688(5) 0.074(4) Uani 1 d . . 1 . . .
H32 H 0.7516 0.2014 0.8531 0.089 Uiso 1 calc . . 1 R . .
O14 O 0.6985(4) 0.8714(3) 0.2953(3) 0.061(2) Uani 1 d . . 1 . . .
C81 C 0.7492(6) 0.6993(5) 0.2500 0.039(4) Uani 1 d . . 2 S T P
H81A H 0.7168 0.6921 0.2327 0.058 Uiso 0.50 calc . -1 1 GR . .
H81B H 0.7436 0.6884 0.2797 0.058 Uiso 0.50 calc . -1 1 GR . .
H81C H 0.7808 0.6833 0.2375 0.058 Uiso 0.50 calc . -1 1 GR . .
C19 C 0.9884(5) 0.4414(5) 0.4464(5) 0.059(3) Uani 1 d . . 1 . . .
C73 C 0.4594(6) 1.1019(5) 0.4238(5) 0.073(4) Uani 1 d . . 1 D U .
C59 C 0.6092(5) 0.9227(5) 0.4270(5) 0.067(4) Uani 1 d . . 1 . . .
H59 H 0.6016 0.9168 0.4566 0.081 Uiso 1 calc . . 1 R . .
C34 C 0.7902(6) 0.1261(4) 0.9298(5) 0.060(4) Uani 1 d . . 1 . . .
C21 C 1.0302(5) 0.4171(5) 0.4205(4) 0.054(3) Uani 1 d . . 1 . . .
C50 C 0.7635(6) -0.0894(4) 1.0645(5) 0.059(3) Uani 1 d . . 1 . . .
H50 H 0.7727 -0.1011 1.0923 0.071 Uiso 1 calc . . 1 R . .
C82 C 0.7580(6) 0.7473(6) 0.2500 0.048(4) Uani 1 d . . 2 S T P
O20 O 0.8667(7) 0.8263(8) 0.2500 0.138(7) Uani 1 d . . 2 S T P
H20A H 0.8816 0.8341 0.2744 0.206 Uiso 0.50 d . . 1 R . .
H20B H 0.8836 0.8401 0.2289 0.206 Uiso 0.50 d . . 1 R . .
C11 C 0.9183(5) 0.4291(4) 0.5567(4) 0.051(3) Uani 1 d . . 1 . . .
C38 C 0.6963(6) 0.1388(5) 1.0751(5) 0.065(4) Uani 1 d . . 1 . . .
C28 C 0.8486(7) 0.2069(4) 0.8170(5) 0.057(3) Uani 1 d . . 1 . . .
C15 C 0.8579(7) 0.3582(5) 0.6744(5) 0.067(4) Uani 1 d . . 1 . . .
O17 O 0.7496(7) 0.7981(4) 0.4910(4) 0.146(7) Uani 1 d . . 1 . . .
C42 C 0.6452(6) 0.2283(5) 1.1828(5) 0.070(4) Uani 1 d . . 1 . . .
O12B O 0.6785(11) 0.7359(9) 0.4081(8) 0.061(5) Uani 0.46(3) d . 2 1 D . .
C54 C 0.6804(6) 0.8595(5) 0.3327(5) 0.061(4) Uani 1 d . . 1 . . .
C58 C 0.6333(6) 0.8874(5) 0.4021(5) 0.068(4) Uani 1 d . . 1 . . .
H58 H 0.6397 0.8573 0.4145 0.082 Uiso 1 calc . . 1 R . .
C2 C 0.8512(6) 0.6384(4) 0.4050(5) 0.063(4) Uani 1 d . . 1 . . .
C29 C 0.8293(7) 0.1765(5) 0.8555(5) 0.069(4) Uani 1 d . . 1 . . .
C3 C 0.8597(6) 0.6000(5) 0.3775(5) 0.067(4) Uani 1 d . . 1 . . .
H3 H 0.8499 0.6024 0.3479 0.080 Uiso 1 calc . . 1 R . .
C1 C 0.8208(6) 0.6818(5) 0.3891(4) 0.069(4) Uani 1 d . . 1 D . .
C41 C 0.6623(6) 0.1950(6) 1.1476(6) 0.079(5) Uani 1 d . . 1 . . .
C39 C 0.7337(7) 0.1686(6) 1.0974(6) 0.085(5) Uani 1 d . . 1 . . .
H39 H 0.7712 0.1679 1.0903 0.102 Uiso 1 calc . . 1 R . .
C26 C 1.0659(6) 0.4427(6) 0.3903(5) 0.079(4) Uani 1 d . . 1 . . .
H26 H 1.0624 0.4756 0.3861 0.095 Uiso 1 calc . . 1 R . .
C30 C 0.8626(7) 0.1438(5) 0.8779(6) 0.075(4) Uani 1 d . . 1 . . .
H30 H 0.8988 0.1386 0.8684 0.090 Uiso 1 calc . . 1 R . .
C40 C 0.7142(7) 0.2002(6) 1.1312(6) 0.086(5) Uani 1 d . . 1 . . .
H40 H 0.7372 0.2244 1.1418 0.103 Uiso 1 calc . . 1 R . .
C56 C 0.6350(6) 0.9393(5) 0.3408(5) 0.076(4) Uani 1 d . . 1 . . .
H56 H 0.6430 0.9451 0.3113 0.092 Uiso 1 calc . . 1 R . .
C80 C 0.6669(7) 0.7019(5) 0.3819(6) 0.071(4) Uani 1 d . . 1 D . .
C33 C 0.7564(6) 0.1575(5) 0.9052(6) 0.072(4) Uani 1 d . . 1 . . .
H33 H 0.7198 0.1621 0.9140 0.087 Uiso 1 calc . . 1 R . .
O5B O 0.8273(13) 0.8187(11) 0.3537(12) 0.071(4) Uani 0.310(15) d . 2 1 D U .
C22 C 1.0408(6) 0.3684(5) 0.4262(5) 0.081(5) Uani 1 d . . 1 . . .
H22 H 1.0229 0.3520 0.4489 0.097 Uiso 1 calc . . 1 R . .
C53 C 0.7561(8) 0.8259(5) 0.4605(5) 0.080(5) Uani 1 d . . 1 . . .
C25 C 1.1060(6) 0.4163(7) 0.3675(5) 0.078(5) Uani 1 d . . 1 . . .
H25 H 1.1306 0.4329 0.3494 0.094 Uiso 1 calc . . 1 R . .
C70 C 0.5450(7) 1.0850(6) 0.5813(6) 0.099(6) Uani 1 d . . 1 . . .
H70 H 0.5076 1.0880 0.5744 0.119 Uiso 1 calc . . 1 R . .
C23 C 1.0773(7) 0.3432(6) 0.3991(6) 0.094(6) Uani 1 d . . 1 . . .
H23 H 1.0790 0.3098 0.4005 0.113 Uiso 1 calc . . 1 R . .
C65 C 0.6309(8) 1.0510(7) 0.5657(6) 0.118(8) Uani 1 d . . 1 . . .
H65 H 0.6515 1.0288 0.5496 0.141 Uiso 1 calc . . 1 R . .
C69 C 0.5635(7) 1.1016(6) 0.6207(6) 0.088(5) Uani 1 d . . 1 . . .
H69 H 0.5385 1.1162 0.6399 0.105 Uiso 1 calc . . 1 R . .
C44 C 0.6466(6) 0.1333(5) 1.0932(6) 0.088(6) Uani 1 d . . 1 . . .
H44 H 0.6238 0.1083 1.0837 0.106 Uiso 1 calc . . 1 R . .
C68 C 0.6421(6) 1.1174(6) 0.6738(6) 0.081(5) Uani 1 d . . 1 . . .
O21 O 0.7885(11) 0.9327(5) 0.2500 0.149(9) Uani 1 d . . 2 S T P
H21A H 0.7918 0.9501 0.2729 0.223 Uiso 0.50 d . . 1 R . .
H21B H 0.7918 0.9501 0.2271 0.223 Uiso 0.50 d . . 1 R . .
C78 C 0.3777(5) 1.1658(4) 0.3950(4) 0.061(4) Uani 1 d . . 1 D . .
C75 C 0.4160(8) 1.1491(8) 0.3650(5) 0.075(6) Uani 0.664(11) d A 2 1 D . .
H75 H 0.4154 1.1598 0.3359 0.090 Uiso 0.664(11) calc A 2 1 R . .
C74 C 0.4562(8) 1.1158(7) 0.3790(5) 0.070(6) Uani 0.664(11) d A 2 1 D . .
H74 H 0.4808 1.1027 0.3587 0.084 Uiso 0.664(11) calc A 2 1 R . .
C9B C 0.3770(10) 1.1486(10) 0.4379(6) 0.095(9) Uani 0.664(11) d A 2 1 D . .
H9B H 0.3488 1.1574 0.4573 0.114 Uiso 0.664(11) calc A 2 1 R . .
C13B C 0.4191(9) 1.1179(8) 0.4514(6) 0.085(7) Uani 0.664(11) d A 2 1 D U .
H13B H 0.4198 1.1079 0.4806 0.102 Uiso 0.664(11) calc A 2 1 R . .
C8A C 0.4139(15) 1.0862(10) 0.3974(12) 0.070(6) Uani 0.336(11) d A 1 1 D . .
H8A H 0.4088 1.0535 0.3923 0.084 Uiso 0.336(11) calc A 1 1 R . .
C3A C 0.3780(13) 1.1186(8) 0.3798(11) 0.075(6) Uani 0.336(11) d A 1 1 D . .
H3A H 0.3537 1.1092 0.3576 0.090 Uiso 0.336(11) calc A 1 1 R . .
C77 C 0.4151(15) 1.1791(9) 0.4276(13) 0.095(9) Uani 0.336(11) d A 1 1 D . .
H77 H 0.4124 1.2094 0.4404 0.114 Uiso 0.336(11) calc A 1 1 R . .
C76 C 0.4563(14) 1.1478(9) 0.4413(12) 0.085(7) Uani 0.336(11) d A 1 1 D U .
H76 H 0.4820 1.1576 0.4624 0.102 Uiso 0.336(11) calc A 1 1 R . .
C24 C 1.1111(7) 0.3682(8) 0.3702(5) 0.090(6) Uani 1 d . . 1 D . .
O6B O 0.8182(14) 0.8850(11) 0.3142(9) 0.078(4) Uani 0.310(15) d . 2 1 D U .
C27B C 0.8325(14) 0.8619(12) 0.3469(15) 0.083(7) Uani 0.310(15) d . 2 1 D U .
O25 O 0.5231(7) 0.3014(5) 1.2500 0.090(5) Uani 1 d . . 2 S T P
H25A H 0.5028 0.3027 1.2729 0.136 Uiso 0.50 d . . 1 R . .
H25B H 0.5028 0.3027 1.2271 0.136 Uiso 0.50 d . . 1 R . .
O4AA O 0.5635(11) 0.7810(13) 0.2500 0.106(8) Uani 0.50 d . . 2 S T P
O6BA O 0.6233(11) 0.7687(13) 0.2500 0.106(8) Uani 0.50 d . . 2 S T P
O6A O 0.8090(6) 0.8578(6) 0.3255(5) 0.078(4) Uani 0.690(15) d . 1 1 D U .
C27A C 0.8477(10) 0.8361(6) 0.3441(8) 0.083(7) Uani 0.690(15) d . 1 1 D U .
O5A O 0.8469(6) 0.7912(5) 0.3484(5) 0.071(4) Uani 0.690(15) d . 1 1 D U .
O1A O 0.822(3) 0.7206(11) 0.4123(12) 0.076(12) Uani 0.64(10) d . 1 1 D . .
O12A O 0.6974(9) 0.7169(9) 0.4134(5) 0.061(5) Uani 0.54(3) d . 1 1 D . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O19 Eu1 O11 81.4(3) . .
O19 Eu1 O2 84.7(3) . .
O19 Eu1 O1B 135.9(6) . .
O19 Eu1 O12B 127.7(7) . .
O19 Eu1 C80 106.6(4) . .
O19 Eu1 O1A 128.5(13) . .
O19 Eu1 O12A 133.6(4) . .
O13 Eu1 O19 77.4(3) . .
O13 Eu1 O11 81.0(4) . .
O13 Eu1 O2 151.8(3) . .
O13 Eu1 O1B 145.8(10) . .
O13 Eu1 O12B 74.6(9) . .
O13 Eu1 C80 82.2(4) . .
O13 Eu1 O5A 115.4(5) . .
O13 Eu1 O1A 153.1(9) . .
O13 Eu1 O12A 91.5(7) . .
O11 Eu1 O2 74.8(4) . .
O11 Eu1 C80 25.7(4) . .
O2 Eu1 C80 82.2(4) . .
O1B Eu1 O11 95(2) . .
O1B Eu1 O2 52.5(6) . .
O1B Eu1 C80 80(2) . .
O1B Eu1 O1A 14.7(17) . .
O18 Eu1 O19 136.1(3) . .
O18 Eu1 O13 79.4(4) . .
O18 Eu1 O11 130.6(4) . .
O18 Eu1 O2 127.7(3) . .
O18 Eu1 O1B 77.8(10) . .
O18 Eu1 O12B 79.7(5) . .
O18 Eu1 C80 106.5(5) . .
O18 Eu1 O5B 67.6(10) . .
O18 Eu1 O5A 81.8(5) . .
O18 Eu1 O1A 75.9(4) . .
O18 Eu1 O12A 83.4(5) . .
O12B Eu1 O11 51.3(5) . .
O12B Eu1 O2 100.4(7) . .
O12B Eu1 O1B 76(2) . .
O12B Eu1 C80 26.8(5) . .
O12B Eu1 O1A 90.6(19) . .
O12B Eu1 O12A 16.9(6) . .
O5B Eu1 O19 77.8(9) . .
O5B Eu1 O13 94.9(10) . .
O5B Eu1 O11 159.2(9) . .
O5B Eu1 O2 102.6(10) . .
O5B Eu1 O1B 100(2) . .
O5B Eu1 O12B 147.1(10) . .
O5B Eu1 C80 173.9(10) . .
O5B Eu1 O5A 22.5(8) . .
O5B Eu1 O1A 85.4(18) . .
O5B Eu1 O12A 148.5(9) . .
O5A Eu1 O19 75.4(4) . .
O5A Eu1 O11 147.1(4) . .
O5A Eu1 O2 80.1(5) . .
O5A Eu1 O1B 86(2) . .
O5A Eu1 O12B 156.9(7) . .
O5A Eu1 C80 162.0(5) . .
O5A Eu1 O1A 71.4(18) . .
O5A Eu1 O12A 146.0(6) . .
O1A Eu1 O11 107.5(13) . .
O1A Eu1 O2 51.9(4) . .
O1A Eu1 C80 94.8(17) . .
O12A Eu1 O11 52.3(4) . .
O12A Eu1 O2 85.1(7) . .
O12A Eu1 O1B 61(2) . .
O12A Eu1 C80 27.0(4) . .
O12A Eu1 O1A 75.4(18) . .
O4 Eu3 O4 92.7(4) 6_557 .
O4 Eu3 O23 78.9(3) 6_557 .
O4 Eu3 O23 78.9(3) . .
O4 Eu3 O8 89.6(4) . 6_557
O4 Eu3 O8 89.6(4) 6_557 .
O4 Eu3 O8 146.4(3) 6_557 6_557
O4 Eu3 O8 146.4(3) . .
O4 Eu3 O7 88.8(4) 6_557 .
O4 Eu3 O7 162.9(4) 6_557 6_557
O4 Eu3 O7 162.9(4) . .
O4 Eu3 O7 88.8(4) . 6_557
O4 Eu3 C28 172.1(4) . .
O4 Eu3 C28 172.1(4) 6_557 6_557
O4 Eu3 C28 87.2(4) . 6_557
O4 Eu3 C28 87.2(4) 6_557 .
O23 Eu3 O7 118.1(3) . .
O23 Eu3 O7 118.1(3) . 6_557
O23 Eu3 C28 93.3(4) . .
O23 Eu3 C28 93.3(4) . 6_557
O22 Eu3 O4 81.1(3) . .
O22 Eu3 O4 81.1(3) . 6_557
O22 Eu3 O23 150.9(5) . .
O22 Eu3 O8 132.2(3) . .
O22 Eu3 O8 132.2(3) . 6_557
O22 Eu3 O7 82.3(4) . 6_557
O22 Eu3 O7 82.3(4) . .
O22 Eu3 C28 106.7(4) . 6_557
O22 Eu3 C28 106.7(4) . .
O8 Eu3 O23 68.7(3) 6_557 .
O8 Eu3 O23 68.7(3) . .
O8 Eu3 O8 71.0(6) 6_557 .
O8 Eu3 O7 98.6(4) 6_557 .
O8 Eu3 O7 50.6(3) . .
O8 Eu3 O7 50.6(3) 6_557 6_557
O8 Eu3 O7 98.6(4) . 6_557
O8 Eu3 C28 86.2(4) . 6_557
O8 Eu3 C28 25.7(4) . .
O8 Eu3 C28 25.7(4) 6_557 6_557
O8 Eu3 C28 86.2(4) 6_557 .
O7 Eu3 O7 84.9(5) . 6_557
O7 Eu3 C28 93.6(4) . 6_557
O7 Eu3 C28 25.0(3) . .
O7 Eu3 C28 93.6(4) 6_557 .
O7 Eu3 C28 25.0(3) 6_557 6_557
C28 Eu3 C28 91.8(6) 6_557 .
Eu1 Eu2 H20A 101.9 6_556 .
Eu1 Eu2 H20B 80.7 6_556 .
O19 Eu2 Eu1 79.06(18) . 6_556
O19 Eu2 Eu1 28.56(17) 6_556 6_556
O19 Eu2 O19 50.5(3) . 6_556
O19 Eu2 C82 25.28(18) . .
O19 Eu2 C82 25.28(18) 6_556 .
O19 Eu2 H20A 81.5 . .
O19 Eu2 H20A 94.7 6_556 .
O19 Eu2 H20B 97.1 . .
O19 Eu2 H20B 85.7 6_556 .
O14 Eu2 Eu1 122.2(2) . 6_556
O14 Eu2 Eu1 65.5(2) 6_556 6_556
O14 Eu2 O19 81.5(3) . .
O14 Eu2 O19 110.7(3) 6_556 .
O14 Eu2 O19 110.7(3) . 6_556
O14 Eu2 O19 81.5(3) 6_556 6_556
O14 Eu2 O14 71.9(5) 6_556 .
O14 Eu2 C82 97.5(3) . .
O14 Eu2 C82 97.5(3) 6_556 .
O14 Eu2 O20 144.0(2) . .
O14 Eu2 O20 144.0(2) 6_556 .
O14 Eu2 H20A 159.0 6_556 .
O14 Eu2 H20A 128.1 . .
O14 Eu2 H20B 129.7 6_556 .
O14 Eu2 H20B 155.9 . .
O14 Eu2 O6B 136.9(8) . 6_556
O14 Eu2 O6B 77.3(9) 6_556 6_556
O14 Eu2 O6B 77.3(9) . .
O14 Eu2 O6B 136.9(8) 6_556 .
O14 Eu2 O6A 143.3(4) 6_556 .
O14 Eu2 O6A 72.7(4) 6_556 6_556
O14 Eu2 O6A 143.3(4) . 6_556
O14 Eu2 O6A 72.7(4) . .
C82 Eu2 Eu1 53.833(15) . 6_556
C82 Eu2 H20A 86.9 . .
C82 Eu2 H20B 90.4 . .
O20 Eu2 Eu1 85.3(3) . 6_556
O20 Eu2 O19 81.8(5) . .
O20 Eu2 O19 81.8(5) . 6_556
O20 Eu2 C82 79.8(6) . .
O20 Eu2 H20A 17.1 . .
O20 Eu2 H20B 17.1 . .
O20 Eu2 O6B 72.1(9) . .
O20 Eu2 O6B 72.1(9) . 6_556
O20 Eu2 O6A 72.0(4) . 6_556
O20 Eu2 O6A 72.0(4) . .
H20A Eu2 H20B 29.3 . .
O21 Eu2 Eu1 126.193(14) . 6_556
O21 Eu2 O19 154.74(17) . .
O21 Eu2 O19 154.74(17) . 6_556
O21 Eu2 O14 83.7(6) . .
O21 Eu2 O14 83.7(6) . 6_556
O21 Eu2 C82 178.5(7) . .
O21 Eu2 O20 98.7(8) . .
O21 Eu2 H20A 91.7 . .
O21 Eu2 H20B 88.1 . .
O21 Eu2 O6B 63.4(8) . .
O21 Eu2 O6B 63.4(8) . 6_556
O21 Eu2 O6A 83.1(5) . .
O21 Eu2 O6A 83.1(5) . 6_556
O6B Eu2 Eu1 157.0(8) . 6_556
O6B Eu2 Eu1 67.3(9) 6_556 6_556
O6B Eu2 O19 138.5(8) . 6_556
O6B Eu2 O19 93.3(9) . .
O6B Eu2 O19 93.3(9) 6_556 6_556
O6B Eu2 O19 138.5(8) 6_556 .
O6B Eu2 C82 116.0(8) 6_556 .
O6B Eu2 C82 116.0(8) . .
O6B Eu2 H20A 82.3 6_556 .
O6B Eu2 H20A 55.3 . .
O6B Eu2 H20B 55.1 6_556 .
O6B Eu2 H20B 78.8 . .
O6B Eu2 O6B 108.0(18) . 6_556
O6B Eu2 O6A 20.4(7) 6_556 6_556
O6B Eu2 O6A 125.2(10) 6_556 .
O6B Eu2 O6A 20.4(7) . .
O6B Eu2 O6A 125.2(10) . 6_556
O6A Eu2 Eu1 47.0(4) 6_556 6_556
O6A Eu2 Eu1 146.0(4) . 6_556
O6A Eu2 O19 120.4(4) . 6_556
O6A Eu2 O19 73.0(5) 6_556 6_556
O6A Eu2 O19 73.0(5) . .
O6A Eu2 O19 120.4(4) 6_556 .
O6A Eu2 C82 96.4(4) . .
O6A Eu2 C82 96.4(4) 6_556 .
O6A Eu2 H20A 86.4 6_556 .
O6A Eu2 H20A 55.4 . .
O6A Eu2 H20B 57.0 6_556 .
O6A Eu2 H20B 83.8 . .
O6A Eu2 O6A 138.7(8) . 6_556
O24 Eu4 O10 118.2(3) . 6_558
O24 Eu4 O10 118.2(3) . .
O24 Eu4 C42 93.0(4) . .
O24 Eu4 C42 93.0(4) . 6_558
O9 Eu4 O24 67.1(3) . .
O9 Eu4 O24 67.1(3) 6_558 .
O9 Eu4 O9 73.5(5) . 6_558
O9 Eu4 O10 51.6(3) . .
O9 Eu4 O10 51.6(3) 6_558 6_558
O9 Eu4 O10 99.2(4) 6_558 .
O9 Eu4 O10 99.2(4) . 6_558
O9 Eu4 C42 87.8(4) . 6_558
O9 Eu4 C42 26.4(4) . .
O9 Eu4 C42 87.8(4) 6_558 .
O9 Eu4 C42 26.4(4) 6_558 6_558
O26 Eu4 O24 77.4(3) 6_558 .
O26 Eu4 O24 77.4(3) . .
O26 Eu4 O9 86.7(4) . .
O26 Eu4 O9 143.8(4) . 6_558
O26 Eu4 O9 86.7(4) 6_558 6_558
O26 Eu4 O9 143.8(4) 6_558 .
O26 Eu4 O26 92.6(6) 6_558 .
O26 Eu4 O10 91.1(4) 6_558 6_558
O26 Eu4 O10 164.4(4) 6_558 .
O26 Eu4 O10 91.1(4) . .
O26 Eu4 O10 164.4(4) . 6_558
O26 Eu4 C42 87.1(4) 6_558 6_558
O26 Eu4 C42 170.3(4) 6_558 .
O26 Eu4 C42 170.3(4) . 6_558
O26 Eu4 C42 87.1(4) . .
O10 Eu4 O10 81.5(6) . 6_558
O10 Eu4 C42 91.8(4) 6_558 .
O10 Eu4 C42 25.3(4) 6_558 6_558
O10 Eu4 C42 25.3(4) . .
O10 Eu4 C42 91.8(4) . 6_558
C42 Eu4 C42 91.6(7) . 6_558
O25 Eu4 O24 152.2(5) . .
O25 Eu4 O9 132.1(3) . .
O25 Eu4 O9 132.1(3) . 6_558
O25 Eu4 O26 83.5(4) . .
O25 Eu4 O26 83.5(4) . 6_558
O25 Eu4 O10 81.8(4) . 6_558
O25 Eu4 O10 81.8(4) . .
O25 Eu4 C42 106.1(4) . .
O25 Eu4 C42 106.1(4) . 6_558
Eu4 O24 H24A 109.4 . .
Eu4 O24 H24B 109.4 . .
H24A O24 H24B 109.5 . .
C15 O4 Eu3 134.0(9) . .
Eu3 O23 H23A 109.0 . .
Eu3 O23 H23B 109.3 . .
H23A O23 H23B 109.5 . .
Eu1 O19 Eu2 121.0(3) . .
C82 O19 Eu1 142.7(9) . .
C82 O19 Eu2 96.3(9) . .
C42 O9 Eu4 95.3(9) . .
C57 C60 C61 121.5(11) . .
C59 C60 C61 121.0(13) . .
C59 C60 C57 117.5(12) . .
C54 O13 Eu1 136.5(9) . .
C45 C37 C36 117.2(12) . .
C45 C37 C38 120.5(12) . .
C36 C37 C38 122.0(11) . .
C48 C49 H49 119.3 . .
C48 C49 C50 121.3(13) . .
C50 C49 H49 119.3 . .
C37 C45 H45 119.6 . .
C46 C45 C37 120.8(12) . .
C46 C45 H45 119.6 . .
C119 C61 C60 117.1(13) . .
C62 C61 C60 122.1(12) . .
C62 C61 C119 120.8(13) . .
C119 C72 C73 123.0(13) . .
C71 C72 C119 117.4(12) . .
C71 C72 C73 119.6(12) . .
C47 C35 C34 122.9(13) . .
C36 C35 C47 116.4(12) . .
C36 C35 C34 120.6(11) . .
C48 C0AA H0AA 120.0 . .
C52 C0AA H0AA 120.0 . .
C52 C0AA C48 120.0(13) . .
C8 C20 H20 119.6 . .
C8 C20 C19 120.8(13) . .
C19 C20 H20 119.6 . .
C61 C119 C72 119.3(13) . .
C61 C119 H119 120.3 . .
C72 C119 H119 120.3 . .
C16 C17 H17 120.2 . .
C16 C17 C11 119.6(13) . .
C11 C17 H17 120.2 . .
C6 C7 C8 121.2(12) . .
C6 C7 C4 120.6(11) . .
C4 C7 C8 118.1(11) . .
C34 C31 H31 119.6 . .
C34 C31 C30 120.8(14) . .
C30 C31 H31 119.6 . .
C16 C14 C15 121.9(12) . .
C13 C14 C16 118.3(12) . .
C13 C14 C15 119.6(12) . .
C13 C12 H12 118.5 . .
C13 C12 C11 122.9(13) . .
C11 C12 H12 118.5 . .
C7 C6 H6 120.0 . .
C7 C6 C5 120.0(13) . .
C5 C6 H6 120.0 . .
C6 C5 H5 120.1 . .
C2 C5 C6 119.8(13) . .
C2 C5 H5 120.1 . .
C80 O11 Eu1 91.9(9) . .
C35 C47 H47 119.1 . .
C35 C47 C46 121.8(12) . .
C46 C47 H47 119.1 . .
C41 C43 H43 118.8 . .
C41 C43 C44 122.4(15) . .
C44 C43 H43 118.8 . .
C20 C8 C7 120.2(12) . .
C20 C8 C9 121.0(10) . .
C9 C8 C7 118.6(11) . .
C17 C16 H16 119.4 . .
C14 C16 C17 121.1(14) . .
C14 C16 H16 119.4 . .
C49 C48 C0AA 118.4(11) . .
C49 C48 C46 121.2(12) . .
C0AA C48 C46 120.3(12) . .
C0AA C52 H52 119.2 . .
C51 C52 C0AA 121.7(14) . .
C51 C52 H52 119.2 . .
C14 C13 H13 119.7 . .
C12 C13 C14 120.5(13) . .
C12 C13 H13 119.7 . .
C58 C55 C54 122.4(12) . .
C58 C55 C56 117.9(12) . .
C56 C55 C54 119.6(13) . .
C18 C10 C9 119.3(11) . .
C18 C10 C11 118.2(10) . .
C9 C10 C11 122.4(11) . .
C10 C18 H18 119.2 . .
C19 C18 C10 121.6(11) . .
C19 C18 H18 119.2 . .
C62 C63 C64 124.6(12) . .
C62 C63 C71 117.4(13) . .
C71 C63 C64 117.8(11) . .
C52 C51 C53 122.6(14) . 6_547
C50 C51 C52 117.8(12) . .
C50 C51 C53 119.6(12) . 6_547
C67 C66 H66 121.0 . .
C65 C66 H66 121.0 . .
C65 C66 C67 118.0(15) . .
C61 C62 C63 122.3(13) . .
C61 C62 H62 118.8 . .
C63 C62 H62 118.8 . .
C45 C46 C47 119.2(11) . .
C45 C46 C48 119.1(12) . .
C47 C46 C48 121.6(12) . .
C70 C64 C63 121.6(12) . .
C65 C64 C63 121.6(13) . .
C65 C64 C70 116.4(14) . .
Eu3 O22 H22A 125.3 . .
Eu3 O22 H22B 125.3 . .
H22A O22 H22B 109.5 . .
C68 O26 Eu4 140.4(10) 8_576 .
C42 O10 Eu4 92.5(9) . .
C1 O2 Eu1 93.2(8) . .
C28 O8 Eu3 95.4(9) . .
C28 O7 Eu3 90.9(8) . .
C8 C9 C10 119.8(11) . .
C8 C9 H9 120.1 . .
C10 C9 H9 120.1 . .
C1 O1B Eu1 93.3(12) . .
C66 C67 C68 118.7(14) . .
C69 C67 C66 116.7(14) . .
C69 C67 C68 124.6(14) . .
C53 O18 Eu1 153.6(12) . .
C60 C57 H57 119.6 . .
C60 C57 C56 120.9(13) . .
C56 C57 H57 119.6 . .
C72 C71 C63 122.7(12) . .
C72 C71 H71 118.6 . .
C63 C71 H71 118.6 . .
C7 C4 H4 120.5 . .
C7 C4 C3 119.1(12) . .
C3 C4 H4 120.5 . .
C37 C36 H36 117.8 . .
C35 C36 C37 124.4(12) . .
C35 C36 H36 117.8 . .
C29 C32 H32 119.8 . .
C29 C32 C33 120.5(14) . .
C33 C32 H32 119.8 . .
C54 O14 Eu2 137.4(9) . .
C82 C81 H81A 109.5 . .
C82 C81 H81B 109.5 . .
C82 C81 H81C 109.5 . .
C20 C19 C21 120.8(12) . .
C18 C19 C20 117.5(12) . .
C18 C19 C21 121.7(12) . .
C74 C73 C72 124.5(12) . .
C74 C73 C8A 60.2(19) . .
C13B C73 C72 117.9(13) . .
C13B C73 C74 117.6(12) . .
C13B C73 C8A 84.1(19) . .
C13B C73 C76 55(2) . .
C8A C73 C72 125.0(15) . .
C76 C73 C72 116.3(14) . .
C76 C73 C74 96.6(19) . .
C76 C73 C8A 117.2(13) . .
C60 C59 H59 119.2 . .
C60 C59 C58 121.6(15) . .
C58 C59 H59 119.2 . .
C31 C34 C35 122.7(13) . .
C31 C34 C33 116.7(13) . .
C33 C34 C35 120.6(13) . .
C19 C21 C26 121.8(12) . .
C22 C21 C19 121.3(13) . .
C22 C21 C26 116.7(12) . .
C49 C50 H50 119.7 . .
C51 C50 C49 120.7(12) . .
C51 C50 H50 119.7 . .
O19 C82 Eu2 58.4(8) 6_556 .
O19 C82 Eu2 58.4(8) . .
O19 C82 O19 116.6(16) 6_556 .
O19 C82 C81 121.5(8) . .
O19 C82 C81 121.5(8) 6_556 .
C81 C82 Eu2 178.5(11) . .
Eu2 O20 H20A 108.9 . .
Eu2 O20 H20B 108.6 . .
H20A O20 H20B 109.5 . .
C17 C11 C10 123.0(11) . .
C12 C11 C17 116.8(12) . .
C12 C11 C10 120.2(11) . .
C39 C38 C37 117.9(13) . .
C44 C38 C37 124.3(13) . .
C44 C38 C39 116.7(14) . .
O8 C28 Eu3 58.9(7) . .
O8 C28 C29 117.5(14) . .
O7 C28 Eu3 64.1(8) . .
O7 C28 O8 122.4(13) . .
O7 C28 C29 120.1(13) . .
C29 C28 Eu3 173.4(10) . .
O4 C15 C14 117.1(13) . .
O4 C15 O3 126.4(14) . .
O3 C15 C14 116.4(13) . .
O9 C42 Eu4 58.3(7) . .
O9 C42 C41 118.7(13) . .
O10 C42 Eu4 62.2(8) . .
O10 C42 O9 120.1(14) . .
O10 C42 C41 120.9(14) . .
C41 C42 Eu4 176.8(11) . .
C80 O12B Eu1 92.9(11) . .
O13 C54 C55 116.2(14) . .
O14 C54 O13 124.6(14) . .
O14 C54 C55 119.0(12) . .
C55 C58 C59 121.3(14) . .
C55 C58 H58 119.4 . .
C59 C58 H58 119.4 . .
C5 C2 C1 119.4(12) . .
C3 C2 C5 119.6(12) . .
C3 C2 C1 120.5(13) . .
C32 C29 C28 117.5(13) . .
C32 C29 C30 118.0(13) . .
C30 C29 C28 124.5(14) . .
C4 C3 H3 119.6 . .
C2 C3 C4 120.8(14) . .
C2 C3 H3 119.6 . .
O2 C1 Eu1 60.8(7) . .
O2 C1 O1B 119.6(17) . .
O2 C1 C2 121.1(12) . .
O2 C1 O1A 117.8(16) . .
O1B C1 Eu1 59.9(10) . .
O1B C1 C2 117.3(14) . .
O1B C1 O1A 28(3) . .
C2 C1 Eu1 175.8(10) . .
O1A C1 Eu1 60.1(8) . .
O1A C1 C2 119.2(13) . .
C43 C41 C42 125.3(14) . .
C40 C41 C43 116.8(16) . .
C40 C41 C42 117.2(15) . .
C38 C39 H39 120.0 . .
C38 C39 C40 120.0(14) . .
C40 C39 H39 120.0 . .
C21 C26 H26 121.1 . .
C25 C26 C21 117.8(14) . .
C25 C26 H26 121.1 . .
C31 C30 C29 121.5(15) . .
C31 C30 H30 119.2 . .
C29 C30 H30 119.2 . .
C41 C40 C39 120.1(16) . .
C41 C40 H40 119.9 . .
C39 C40 H40 119.9 . .
C55 C56 C57 120.6(15) . .
C55 C56 H56 119.7 . .
C57 C56 H56 119.7 . .
O11 C80 Eu1 62.4(8) . .
O11 C80 O12B 118.5(15) . .
O11 C80 C78 120.2(13) . 7_655
O11 C80 O12A 121.5(15) . .
O12B C80 Eu1 60.3(9) . .
O12B C80 C78 119.1(15) . 7_655
O12B C80 O12A 32.8(12) . .
C78 C80 Eu1 174.1(11) 7_655 .
O12A C80 Eu1 60.7(9) . .
O12A C80 C78 115.2(14) . 7_655
C32 C33 C34 122.3(14) . .
C32 C33 H33 118.8 . .
C34 C33 H33 118.8 . .
C27B O5B Eu1 139(3) . .
C21 C22 H22 118.8 . .
C21 C22 C23 122.3(14) . .
C23 C22 H22 118.8 . .
O18 C53 C51 116.6(14) . 6_567
O18 C53 O17 123.9(13) . .
O17 C53 C51 119.4(13) . 6_567
C26 C25 H25 118.2 . .
C24 C25 C26 123.7(15) . .
C24 C25 H25 118.2 . .
C64 C70 H70 119.1 . .
C69 C70 C64 121.8(15) . .
C69 C70 H70 119.1 . .
C22 C23 H23 120.3 . .
C24 C23 C22 119.4(15) . .
C24 C23 H23 120.3 . .
C66 C65 H65 118.4 . .
C64 C65 C66 123.2(14) . .
C64 C65 H65 118.4 . .
C67 C69 H69 119.2 . .
C70 C69 C67 121.6(16) . .
C70 C69 H69 119.2 . .
C43 C44 H44 119.3 . .
C38 C44 C43 121.4(14) . .
C38 C44 H44 119.3 . .
O15 C68 O26 122.0(16) . 8_575
O15 C68 C67 121.7(16) . .
O26 C68 C67 116.2(13) 8_575 .
Eu2 O21 H21A 125.3 . .
Eu2 O21 H21B 125.3 . .
H21A O21 H21B 109.5 . .
C75 C78 C80 121.5(13) . 7_665
C75 C78 C9B 120.8(12) . .
C75 C78 C3A 57.3(19) . .
C75 C78 C77 97(2) . .
C9B C78 C80 117.6(13) . 7_665
C9B C78 C3A 89.1(19) . .
C9B C78 C77 55(2) . .
C3A C78 C80 122.7(13) . 7_665
C77 C78 C80 117.8(12) . 7_665
C77 C78 C3A 119.0(12) . .
C78 C75 H75 120.5 . .
C78 C75 C74 118.9(13) . .
C74 C75 H75 120.5 . .
C73 C74 H74 119.8 . .
C75 C74 C73 120.5(12) . .
C75 C74 H74 119.8 . .
C78 C9B H9B 120.7 . .
C13B C9B C78 118.6(15) . .
C13B C9B H9B 120.7 . .
C73 C13B C9B 123.0(15) . .
C73 C13B H13B 118.5 . .
C9B C13B H13B 118.5 . .
C73 C8A H8A 119.8 . .
C3A C8A C73 120(2) . .
C3A C8A H8A 119.8 . .
C78 C3A H3A 120.0 . .
C8A C3A C78 119.9(17) . .
C8A C3A H3A 120.0 . .
C78 C77 H77 119.6 . .
C76 C77 C78 120.7(14) . .
C76 C77 H77 119.6 . .
C73 C76 C77 120.3(15) . .
C73 C76 H76 119.9 . .
C77 C76 H76 119.9 . .
C25 C24 C23 119.1(14) . .
C25 C24 C27B 99.5(19) . 7_755
C25 C24 C27A 126.7(16) . 7_755
C23 C24 C27B 138.7(19) . 7_755
C23 C24 C27A 114.1(17) . 7_755
C27B C24 C27A 30.4(17) 7_755 7_755
C27B O6B Eu2 125(3) . .
O5B C27B C24 97(2) . 7_765
O5B C27B O6B 128(4) . .
O6B C27B C24 124(3) . 7_765
Eu4 O25 H25A 125.3 . .
Eu4 O25 H25B 125.3 . .
H25A O25 H25B 109.5 . .
Eu2 O6A Eu1 98.2(5) . .
C27A O6A Eu1 74.4(14) . .
C27A O6A Eu2 130.4(15) . .
C24 C27A Eu1 138.4(15) 7_765 .
O6A C27A Eu1 82.5(15) . .
O6A C27A C24 115.4(16) . 7_765
O6A C27A O5A 121(2) . .
O5A C27A Eu1 46.1(10) . .
O5A C27A C24 121.9(17) . 7_765
C27A O5A Eu1 111.4(14) . .
C1 O1A Eu1 93.0(10) . .
C80 O12A Eu1 92.2(10) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O19 2.369(8) .
Eu1 O13 2.350(9) .
Eu1 O11 2.485(9) .
Eu1 O2 2.493(8) .
Eu1 O1B 2.470(18) .
Eu1 O18 2.304(10) .
Eu1 O12B 2.437(16) .
Eu1 C80 2.802(15) .
Eu1 O5B 2.325(19) .
Eu1 O5A 2.362(13) .
Eu1 O1A 2.476(13) .
Eu1 O12A 2.446(14) .
Eu3 O4 2.346(9) 6_557
Eu3 O4 2.346(9) .
Eu3 O23 2.493(12) .
Eu3 O22 2.293(15) .
Eu3 O8 2.430(10) 6_557
Eu3 O8 2.430(10) .
Eu3 O7 2.542(10) 6_557
Eu3 O7 2.542(10) .
Eu3 C28 2.827(13) 6_557
Eu3 C28 2.827(13) .
Eu2 Eu1 4.2499(8) 6_556
Eu2 O19 2.514(8) 6_556
Eu2 O19 2.514(8) .
Eu2 O14 2.340(9) 6_556
Eu2 O14 2.340(9) .
Eu2 C82 2.934(18) .
Eu2 O20 2.347(17) .
Eu2 H20A 2.7429 .
Eu2 H20B 2.7389 .
Eu2 O21 2.278(15) .
Eu2 O6B 2.404(19) 6_556
Eu2 O6B 2.404(19) .
Eu2 O6A 2.447(14) .
Eu2 O6A 2.447(14) 6_556
Eu4 O24 2.487(13) .
Eu4 O9 2.428(10) 6_558
Eu4 O9 2.428(10) .
Eu4 O26 2.316(10) 6_558
Eu4 O26 2.316(10) .
Eu4 O10 2.516(10) 6_558
Eu4 O10 2.516(10) .
Eu4 C42 2.841(15) 6_558
Eu4 C42 2.841(15) .
Eu4 O25 2.291(16) .
O24 H24A 0.8501 .
O24 H24B 0.8500 .
O4 C15 1.252(15) .
O23 H23A 0.8499 .
O23 H23B 0.8501 .
O19 C82 1.261(11) .
O9 C42 1.269(16) .
C60 C61 1.513(17) .
C60 C57 1.380(18) .
C60 C59 1.370(17) .
O13 C54 1.263(15) .
C37 C45 1.388(16) .
C37 C36 1.394(19) .
C37 C38 1.496(19) .
C49 H49 0.9300 .
C49 C48 1.347(17) .
C49 C50 1.401(17) .
O15 C68 1.188(17) .
C45 H45 0.9300 .
C45 C46 1.380(17) .
C61 C119 1.405(18) .
C61 C62 1.334(18) .
C72 C119 1.425(18) .
C72 C71 1.381(18) .
C72 C73 1.455(17) .
C35 C47 1.385(16) .
C35 C36 1.370(19) .
C35 C34 1.439(19) .
C0AA H0AA 0.9300 .
C0AA C48 1.387(19) .
C0AA C52 1.380(17) .
C20 H20 0.9300 .
C20 C8 1.358(17) .
C20 C19 1.435(17) .
C119 H119 0.9300 .
C17 H17 0.9300 .
C17 C16 1.404(19) .
C17 C11 1.412(17) .
C7 C6 1.352(17) .
C7 C8 1.534(15) .
C7 C4 1.389(18) .
C31 H31 0.9300 .
C31 C34 1.37(2) .
C31 C30 1.39(2) .
C14 C16 1.389(19) .
C14 C13 1.375(17) .
C14 C15 1.511(19) .
C12 H12 0.9300 .
C12 C13 1.367(18) .
C12 C11 1.387(18) .
C6 H6 0.9300 .
C6 C5 1.414(17) .
C5 H5 0.9300 .
C5 C2 1.381(19) .
O11 C80 1.215(17) .
C47 H47 0.9300 .
C47 C46 1.401(18) .
C43 H43 0.9300 .
C43 C41 1.37(2) .
C43 C44 1.38(2) .
C8 C9 1.385(17) .
C16 H16 0.9300 .
C48 C46 1.471(16) .
C52 H52 0.9300 .
C52 C51 1.377(19) .
C13 H13 0.9300 .
C55 C54 1.498(19) .
C55 C58 1.369(19) .
C55 C56 1.378(18) .
C10 C18 1.396(16) .
C10 C9 1.397(16) .
C10 C11 1.487(17) .
C18 H18 0.9300 .
C18 C19 1.385(17) .
C63 C62 1.388(18) .
C63 C64 1.531(19) .
C63 C71 1.400(17) .
C51 C50 1.361(18) .
C51 C53 1.511(18) 6_547
C66 H66 0.9300 .
C66 C67 1.45(2) .
C66 C65 1.39(2) .
C62 H62 0.9300 .
C64 C70 1.40(2) .
C64 C65 1.33(2) .
O22 H22A 0.8499 .
O22 H22B 0.8499 .
O26 C68 1.275(17) 8_576
O10 C42 1.213(17) .
O2 C1 1.248(15) .
O8 C28 1.231(16) .
O7 C28 1.196(16) .
C9 H9 0.9300 .
O1B C1 1.29(2) .
C67 C69 1.38(2) .
C67 C68 1.47(2) .
O18 C53 1.214(17) .
C57 H57 0.9300 .
C57 C56 1.389(18) .
O3 C15 1.262(17) .
C71 H71 0.9300 .
C4 H4 0.9300 .
C4 C3 1.402(17) .
C36 H36 0.9300 .
C32 H32 0.9300 .
C32 C29 1.37(2) .
C32 C33 1.37(2) .
O14 C54 1.257(16) .
C81 H81A 0.9600 .
C81 H81B 0.9600 .
C81 H81C 0.9600 .
C81 C82 1.35(2) .
C19 C21 1.444(17) .
C73 C74 1.414(14) .
C73 C13B 1.354(15) .
C73 C8A 1.42(3) .
C73 C76 1.383(18) .
C59 H59 0.9300 .
C59 C58 1.371(18) .
C34 C33 1.408(19) .
C21 C26 1.447(19) .
C21 C22 1.390(18) .
C50 H50 0.9300 .
C82 O19 1.261(11) 6_556
O20 H20A 0.8502 .
O20 H20B 0.8499 .
C38 C39 1.40(2) .
C38 C44 1.328(19) .
C28 C29 1.515(19) .
O17 C53 1.215(18) .
C42 C41 1.47(2) .
O12B C80 1.27(2) .
C58 H58 0.9300 .
C2 C3 1.369(17) .
C2 C1 1.492(18) .
C29 C30 1.391(19) .
C3 H3 0.9300 .
C1 O1A 1.291(19) .
C41 C40 1.35(2) .
C39 H39 0.9300 .
C39 C40 1.43(2) .
C26 H26 0.9300 .
C26 C25 1.40(2) .
C30 H30 0.9300 .
C40 H40 0.9300 .
C56 H56 0.9300 .
C80 C78 1.524(18) 7_655
C80 O12A 1.275(19) .
C33 H33 0.9300 .
O5B C27B 1.227(19) .
C22 H22 0.9300 .
C22 C23 1.39(2) .
C53 C51 1.511(18) 6_567
C25 H25 0.9300 .
C25 C24 1.35(2) .
C70 H70 0.9300 .
C70 C69 1.36(2) .
C23 H23 0.9300 .
C23 C24 1.38(2) .
C65 H65 0.9300 .
C69 H69 0.9300 .
C44 H44 0.9300 .
C68 O26 1.275(17) 8_575
O21 H21A 0.8499 .
O21 H21B 0.8499 .
C78 C80 1.524(18) 7_665
C78 C75 1.376(14) .
C78 C9B 1.387(15) .
C78 C3A 1.391(17) .
C78 C77 1.388(16) .
C75 H75 0.9300 .
C75 C74 1.407(16) .
C74 H74 0.9300 .
C9B H9B 0.9300 .
C9B C13B 1.387(17) .
C13B H13B 0.9300 .
C8A H8A 0.9300 .
C8A C3A 1.359(19) .
C3A H3A 0.9300 .
C77 H77 0.9300 .
C77 C76 1.384(16) .
C76 H76 0.9300 .
C24 C27B 1.54(3) 7_755
C24 C27A 1.55(3) 7_755
O6B C27B 1.231(19) .
C27B C24 1.54(3) 7_765
O25 H25A 0.8499 .
O25 H25B 0.8499 .
O4AA O6BA 1.48(4) .
O6A C27A 1.245(15) .
C27A C24 1.55(3) 7_765
C27A O5A 1.256(16) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Eu1 Eu2 O19 Eu1 -178.0(4) 6_556 .
Eu1 Eu2 O19 C82 3.2(8) 6_556 .
Eu1 Eu2 O14 C54 104.8(13) 6_556 .
Eu1 Eu2 C82 O19 -176.1(10) 6_556 .
Eu1 Eu2 C82 O19 -0.7(6) 6_556 6_556
Eu1 Eu2 C82 C81 -88.4(2) 6_556 .
Eu1 Eu2 O6B C27B -61(5) 6_556 .
Eu1 Eu2 O6A Eu1 -50.2(8) 6_556 .
Eu1 Eu2 O6A C27A 26(3) 6_556 .
Eu1 O19 C82 Eu2 -178.3(15) . .
Eu1 O19 C82 O19 177.3(3) . 6_556
Eu1 O19 C82 C81 4(2) . .
Eu1 O13 C54 C55 -130.2(11) . .
Eu1 O13 C54 O14 54(2) . .
Eu1 O11 C80 O12B 23(2) . .
Eu1 O11 C80 C78 -174.0(12) . 7_655
Eu1 O11 C80 O12A -15(2) . .
Eu1 O2 C1 O1B 12(5) . .
Eu1 O2 C1 C2 175.6(13) . .
Eu1 O2 C1 O1A -20(4) . .
Eu1 O1B C1 O2 -12(5) . .
Eu1 O1B C1 C2 -176.4(12) . .
Eu1 O1B C1 O1A 82.1(19) . .
Eu1 O18 C53 C51 -146.1(18) . 6_567
Eu1 O18 C53 O17 35(4) . .
Eu1 O12B C80 O11 -24(2) . .
Eu1 O12B C80 C78 173.3(12) . 7_655
Eu1 O12B C80 O12A 81.1(16) . .
Eu1 O5B C27B C24 151(3) . 7_765
Eu1 O5B C27B O6B -65(8) . .
Eu1 O6A C27A C24 -141(2) . 7_765
Eu1 O6A C27A O5A 26(2) . .
Eu3 O4 C15 C14 -169.7(8) . .
Eu3 O4 C15 O3 13(2) . .
Eu3 O8 C28 O7 -8.4(16) . .
Eu3 O8 C28 C29 173.6(11) . .
Eu3 O7 C28 O8 8.0(15) . .
Eu3 O7 C28 C29 -174.1(12) . .
Eu3 C28 C29 C32 46(10) . .
Eu3 C28 C29 C30 -134(9) . .
Eu2 O19 C82 O19 -4.4(15) . 6_556
Eu2 O19 C82 C81 -178.2(13) . .
Eu2 O14 C54 O13 -34(2) . .
Eu2 O14 C54 C55 150.3(9) . .
Eu2 O6B C27B O5B 0(7) . .
Eu2 O6B C27B C24 136(3) . 7_765
Eu2 O6A C27A Eu1 -87.5(17) . .
Eu2 O6A C27A C24 131.9(16) . 7_765
Eu2 O6A C27A O5A -61(3) . .
Eu4 O9 C42 O10 -7.3(17) . .
Eu4 O9 C42 C41 178.7(13) . .
Eu4 O10 C42 O9 7.1(16) . .
Eu4 O10 C42 C41 -179.1(15) . .
Eu4 C42 C41 C43 -164(21) . .
Eu4 C42 C41 C40 6(23) . .
O24 Eu4 O9 C42 -167.9(10) . .
O24 Eu4 O26 C68 5.8(17) . 8_576
O24 Eu4 O10 C42 4.5(11) . .
O24 Eu4 C42 O9 11.2(9) . .
O24 Eu4 C42 O10 -176.0(10) . .
O24 Eu4 C42 C41 -9(22) . .
O4 Eu3 O4 C15 -86.6(13) 6_557 .
O4 Eu3 O8 C28 -178.7(8) . .
O4 Eu3 O8 C28 -84.4(9) 6_557 .
O4 Eu3 O7 C28 86.0(9) 6_557 .
O4 Eu3 O7 C28 -178.7(10) . .
O4 Eu3 C28 O8 5(3) . .
O4 Eu3 C28 O8 94.9(9) 6_557 .
O4 Eu3 C28 O7 177(2) . .
O4 Eu3 C28 O7 -93.1(9) 6_557 .
O4 Eu3 C28 C29 37(10) 6_557 .
O4 Eu3 C28 C29 -53(11) . .
O23 Eu3 O4 C15 -8.5(13) . .
O23 Eu3 O8 C28 -162.7(10) . .
O23 Eu3 O7 C28 9.3(10) . .
O23 Eu3 C28 O8 16.2(9) . .
O23 Eu3 C28 O7 -171.8(9) . .
O23 Eu3 C28 C29 -42(10) . .
O19 Eu1 O13 C54 -61.9(13) . .
O19 Eu1 O11 C80 -169.3(10) . .
O19 Eu1 O2 C1 161.7(9) . .
O19 Eu1 O1B C1 -10(7) . .
O19 Eu1 O18 C53 151(2) . .
O19 Eu1 O12B C80 43(2) . .
O19 Eu1 C1 O2 -19.3(10) . .
O19 Eu1 C1 O1B 173(5) . .
O19 Eu1 C1 C2 -137(14) . .
O19 Eu1 C1 O1A 140(4) . .
O19 Eu1 C80 O11 11.1(10) . .
O19 Eu1 C80 O12B -146(2) . .
O19 Eu1 C80 C78 129(11) . 7_655
O19 Eu1 C80 O12A 176.6(16) . .
O19 Eu1 O5B C27B 81(5) . .
O19 Eu1 O6A Eu2 15.9(3) . .
O19 Eu1 O6A C27A -113.8(14) . .
O19 Eu1 C27A C24 178(2) . 7_765
O19 Eu1 C27A O6A 58.0(13) . .
O19 Eu1 C27A O5A -90.5(15) . .
O19 Eu1 O5A C27A 83.2(15) . .
O19 Eu1 O1A C1 -51(4) . .
O19 Eu1 O12A C80 -4(2) . .
O19 Eu2 O19 Eu1 -178.7(2) 6_556 .
O19 Eu2 O19 C82 2.6(9) 6_556 .
O19 Eu2 O14 C54 75.4(13) 6_556 .
O19 Eu2 O14 C54 33.5(13) . .
O19 Eu2 C82 O19 -175.4(15) 6_556 .
O19 Eu2 C82 O19 175.4(15) . 6_556
O19 Eu2 C82 C81 -87.7(8) 6_556 .
O19 Eu2 C82 C81 87.7(8) . .
O19 Eu2 O6B C27B -18(4) 6_556 .
O19 Eu2 O6B C27B 9(4) . .
O19 Eu2 O6A Eu1 -13.9(3) . .
O19 Eu2 O6A Eu1 -32.0(6) 6_556 .
O19 Eu2 O6A C27A 44(2) 6_556 .
O19 Eu2 O6A C27A 63(2) . .
O9 Eu4 O9 C42 120.5(9) 6_558 .
O9 Eu4 O26 C68 -61.5(18) . 8_576
O9 Eu4 O26 C68 -6(2) 6_558 8_576
O9 Eu4 O10 C42 -64.4(11) 6_558 .
O9 Eu4 O10 C42 -4.1(10) . .
O9 Eu4 C42 O9 -55.8(9) 6_558 .
O9 Eu4 C42 O10 172.8(17) . .
O9 Eu4 C42 O10 117.0(10) 6_558 .
O9 Eu4 C42 C41 -21(22) . .
O9 Eu4 C42 C41 -76(22) 6_558 .
O9 C42 C41 C43 175.6(17) . .
O9 C42 C41 C40 -14(2) . .
C60 C61 C119 C72 -178.6(11) . .
C60 C61 C62 C63 177.7(11) . .
C60 C57 C56 C55 -2(2) . .
C60 C59 C58 C55 4(2) . .
O13 Eu1 O19 Eu2 57.6(4) . .
O13 Eu1 O19 C82 -124.4(15) . .
O13 Eu1 O11 C80 -90.7(10) . .
O13 Eu1 O2 C1 -147.6(9) . .
O13 Eu1 O1B C1 154.6(16) . .
O13 Eu1 O18 C53 92(3) . .
O13 Eu1 O12B C80 103.4(19) . .
O13 Eu1 C1 O2 95.9(16) . .
O13 Eu1 C1 O1B -72(5) . .
O13 Eu1 C1 C2 -22(15) . .
O13 Eu1 C1 O1A -105(4) . .
O13 Eu1 C80 O11 85.4(10) . .
O13 Eu1 C80 O12B -71(2) . .
O13 Eu1 C80 C78 -157(11) . 7_655
O13 Eu1 C80 O12A -109.1(17) . .
O13 Eu1 O5B C27B 5(5) . .
O13 Eu1 O6A Eu2 -69.0(5) . .
O13 Eu1 O6A C27A 161.2(14) . .
O13 Eu1 C27A C24 102.4(19) . 7_765
O13 Eu1 C27A O6A -17.8(13) . .
O13 Eu1 C27A O5A -166.3(14) . .
O13 Eu1 O5A C27A 15.1(16) . .
O13 Eu1 O1A C1 147.1(10) . .
O13 Eu1 O12A C80 69.5(16) . .
C37 C45 C46 C47 -1.5(19) . .
C37 C45 C46 C48 174.7(12) . .
C37 C38 C39 C40 176.5(14) . .
C37 C38 C44 C43 -177.3(16) . .
C49 C48 C46 C45 -40.1(18) . .
C49 C48 C46 C47 136.0(14) . .
C45 C37 C36 C35 -1(2) . .
C45 C37 C38 C39 113.9(16) . .
C45 C37 C38 C44 -53(2) . .
C61 C60 C57 C56 179.4(13) . .
C61 C60 C59 C58 179.8(12) . .
C72 C73 C74 C75 -174.9(19) . .
C72 C73 C13B C9B 179(2) . .
C72 C73 C8A C3A -176(3) . .
C72 C73 C76 C77 -177(4) . .
C35 C47 C46 C45 -1(2) . .
C35 C47 C46 C48 -177.1(12) . .
C35 C34 C33 C32 178.2(14) . .
C0AA C48 C46 C45 137.1(13) . .
C0AA C48 C46 C47 -46.8(18) . .
C0AA C52 C51 C50 -1(2) . .
C0AA C52 C51 C53 179.5(13) . 6_547
C20 C8 C9 C10 -2.0(19) . .
C20 C19 C21 C26 31.7(19) . .
C20 C19 C21 C22 -153.5(13) . .
C119 C61 C62 C63 -2(2) . .
C119 C72 C71 C63 -2(2) . .
C119 C72 C73 C74 -32(3) . .
C119 C72 C73 C13B 146.7(19) . .
C119 C72 C73 C8A 44(3) . .
C119 C72 C73 C76 -151(2) . .
C7 C6 C5 C2 3(2) . .
C7 C8 C9 C10 -176.1(11) . .
C7 C4 C3 C2 0(2) . .
C31 C34 C33 C32 -3(2) . .
C6 C7 C8 C20 -141.6(13) . .
C6 C7 C8 C9 32.6(17) . .
C6 C7 C4 C3 3(2) . .
C6 C5 C2 C3 0(2) . .
C6 C5 C2 C1 171.6(13) . .
C5 C2 C3 C4 -2(2) . .
C5 C2 C1 Eu1 -59(15) . .
C5 C2 C1 O2 -174.7(15) . .
C5 C2 C1 O1B -11(5) . .
C5 C2 C1 O1A 21(4) . .
O11 Eu1 O19 Eu2 140.2(4) . .
O11 Eu1 O19 C82 -41.8(15) . .
O11 Eu1 O13 C54 -145.0(14) . .
O11 Eu1 O2 C1 -115.8(10) . .
O11 Eu1 O1B C1 73(4) . .
O11 Eu1 O18 C53 24(3) . .
O11 Eu1 O12B C80 12.7(13) . .
O11 Eu1 C1 O2 60.5(9) . .
O11 Eu1 C1 O1B -107(5) . .
O11 Eu1 C1 C2 -58(14) . .
O11 Eu1 C1 O1A -140(4) . .
O11 Eu1 C80 O12B -157(2) . .
O11 Eu1 C80 C78 118(11) . 7_655
O11 Eu1 C80 O12A 166(2) . .
O11 Eu1 O5B C27B 82(6) . .
O11 Eu1 O6A Eu2 -17.8(8) . .
O11 Eu1 O6A C27A -147.6(13) . .
O11 Eu1 C27A C24 178.5(15) . 7_765
O11 Eu1 C27A O6A 58.3(19) . .
O11 Eu1 C27A O5A -90.2(16) . .
O11 Eu1 O5A C27A 129.7(15) . .
O11 Eu1 O1A C1 42(4) . .
O11 Eu1 O12A C80 -7.9(11) . .
O11 C80 O12A Eu1 15(2) . .
C47 C35 C36 C37 -1(2) . .
C47 C35 C34 C31 -53(2) . .
C47 C35 C34 C33 125.5(15) . .
C43 C41 C40 C39 -10(3) . .
C8 C20 C19 C18 -0.1(19) . .
C8 C20 C19 C21 -178.5(12) . .
C8 C7 C6 C5 178.3(12) . .
C8 C7 C4 C3 -180.0(12) . .
C16 C17 C11 C12 4.7(19) . .
C16 C17 C11 C10 -175.1(12) . .
C16 C14 C13 C12 9(2) . .
C16 C14 C15 O4 -8(2) . .
C16 C14 C15 O3 169.8(14) . .
C48 C49 C50 C51 -3(2) . .
C48 C0AA C52 C51 0(2) . .
C52 C0AA C48 C49 -1(2) . .
C52 C0AA C48 C46 -178.5(12) . .
C52 C51 C50 C49 2(2) . .
C13 C14 C16 C17 -8(2) . .
C13 C14 C15 O4 177.0(13) . .
C13 C14 C15 O3 -5(2) . .
C13 C12 C11 C17 -3(2) . .
C13 C12 C11 C10 176.6(13) . .
C10 C18 C19 C20 0.4(18) . .
C10 C18 C19 C21 178.8(11) . .
C18 C10 C9 C8 2.2(18) . .
C18 C10 C11 C17 33.1(18) . .
C18 C10 C11 C12 -146.6(12) . .
C18 C19 C21 C26 -146.7(13) . .
C18 C19 C21 C22 28(2) . .
C63 C64 C70 C69 -173.3(16) . .
C63 C64 C65 C66 168.4(17) . .
C66 C67 C69 C70 -7(3) . .
C66 C67 C68 O15 -7(3) . .
C66 C67 C68 O26 169.9(15) . 8_575
C62 C61 C119 C72 1(2) . .
C62 C63 C64 C70 -153.7(15) . .
C62 C63 C64 C65 19(2) . .
C62 C63 C71 C72 1(2) . .
C64 C63 C62 C61 -173.6(13) . .
C64 C63 C71 C72 175.9(13) . .
C64 C70 C69 C67 -1(3) . .
O22 Eu3 O4 C15 -167.2(13) . .
O22 Eu3 O8 C28 -6.8(11) . .
O22 Eu3 O7 C28 167.2(10) . .
O22 Eu3 C28 O8 174.7(9) . .
O22 Eu3 C28 O7 -13.2(10) . .
O22 Eu3 C28 C29 116(10) . .
O26 Eu4 O9 C42 -90.1(10) . .
O26 Eu4 O9 C42 180.0(9) 6_558 .
O26 Eu4 O26 C68 82.3(18) 6_558 8_576
O26 Eu4 O10 C42 80.8(10) . .
O26 Eu4 O10 C42 -175.5(13) 6_558 .
O26 Eu4 C42 O9 0(3) 6_558 .
O26 Eu4 C42 O9 88.4(10) . .
O26 Eu4 C42 O10 173(2) 6_558 .
O26 Eu4 C42 O10 -98.8(10) . .
O26 Eu4 C42 C41 -21(24) 6_558 .
O26 Eu4 C42 C41 68(22) . .
O10 Eu4 O9 C42 3.9(9) . .
O10 Eu4 O9 C42 75.3(10) 6_558 .
O10 Eu4 O26 C68 -174.2(17) 6_558 8_576
O10 Eu4 O26 C68 -112.9(18) . 8_576
O10 Eu4 O10 C42 -113.0(10) 6_558 .
O10 Eu4 C42 O9 -172.8(17) . .
O10 Eu4 C42 O9 -107.2(10) 6_558 .
O10 Eu4 C42 O10 65.6(10) 6_558 .
O10 Eu4 C42 C41 -128(22) 6_558 .
O10 Eu4 C42 C41 167(23) . .
O10 C42 C41 C43 2(3) . .
O10 C42 C41 C40 171.9(16) . .
O2 Eu1 O19 Eu2 -144.4(4) . .
O2 Eu1 O19 C82 33.6(15) . .
O2 Eu1 O13 C54 -113.9(14) . .
O2 Eu1 O11 C80 103.9(10) . .
O2 Eu1 O1B C1 7(3) . .
O2 Eu1 O18 C53 -80(3) . .
O2 Eu1 O12B C80 -48(2) . .
O2 Eu1 C1 O1B -168(5) . .
O2 Eu1 C1 C2 -118(15) . .
O2 Eu1 C1 O1A 159(4) . .
O2 Eu1 C80 O11 -71.0(9) . .
O2 Eu1 C80 O12B 132(2) . .
O2 Eu1 C80 C78 47(11) . 7_655
O2 Eu1 C80 O12A 94.5(17) . .
O2 Eu1 O5B C27B 162(5) . .
O2 Eu1 O6A Eu2 82.3(5) . .
O2 Eu1 O6A C27A -47.5(14) . .
O2 Eu1 C27A C24 -101.0(19) . 7_765
O2 Eu1 C27A O6A 138.7(12) . .
O2 Eu1 C27A O5A -9.8(15) . .
O2 Eu1 O5A C27A 170.3(15) . .
O2 Eu1 O1A C1 -11(2) . .
O2 Eu1 O12A C80 -82.4(15) . .
O2 C1 O1A Eu1 20(4) . .
O8 Eu3 O4 C15 6.7(16) . .
O8 Eu3 O4 C15 59.8(13) 6_557 .
O8 Eu3 O8 C28 123.5(8) 6_557 .
O8 Eu3 O7 C28 -4.4(9) . .
O8 Eu3 O7 C28 -61.1(10) 6_557 .
O8 Eu3 C28 O8 -52.2(9) 6_557 .
O8 Eu3 C28 O7 119.9(9) 6_557 .
O8 Eu3 C28 O7 172.1(15) . .
O8 Eu3 C28 C29 -58(9) . .
O8 Eu3 C28 C29 -111(10) 6_557 .
O8 C28 C29 C32 -9(2) . .
O8 C28 C29 C30 170.8(15) . .
O7 Eu3 O4 C15 110.4(13) 6_557 .
O7 Eu3 O4 C15 178.7(14) . .
O7 Eu3 O8 C28 4.3(8) . .
O7 Eu3 O8 C28 80.5(9) 6_557 .
O7 Eu3 O7 C28 -109.9(9) 6_557 .
O7 Eu3 C28 O8 -172.1(15) . .
O7 Eu3 C28 O8 -102.3(9) 6_557 .
O7 Eu3 C28 O7 69.8(9) 6_557 .
O7 Eu3 C28 C29 -161(10) 6_557 .
O7 Eu3 C28 C29 130(10) . .
O7 C28 C29 C32 173.0(15) . .
O7 C28 C29 C30 -7(2) . .
C9 C10 C18 C19 -1.5(18) . .
C9 C10 C11 C17 -150.8(12) . .
C9 C10 C11 C12 29.5(18) . .
O1B Eu1 O19 Eu2 -131(3) . .
O1B Eu1 O19 C82 46(3) . .
O1B Eu1 O13 C54 129(4) . .
O1B Eu1 O11 C80 55.0(12) . .
O1B Eu1 O2 C1 -7(3) . .
O1B Eu1 O18 C53 -63(3) . .
O1B Eu1 O12B C80 -95(2) . .
O1B Eu1 C1 O2 168(5) . .
O1B Eu1 C1 C2 50(15) . .
O1B Eu1 C1 O1A -33(4) . .
O1B Eu1 C80 O11 -124.1(11) . .
O1B Eu1 C80 O12B 79(2) . .
O1B Eu1 C80 C78 -6(11) . 7_655
O1B Eu1 C80 O12A 41.4(17) . .
O1B Eu1 O5B C27B -144(5) . .
O1B Eu1 O6A Eu2 144.8(7) . .
O1B Eu1 O6A C27A 15.0(15) . .
O1B Eu1 C27A C24 -47(2) . 7_765
O1B Eu1 C27A O6A -167.5(13) . .
O1B Eu1 C27A O5A 44.1(16) . .
O1B Eu1 O5A C27A -137.1(17) . .
O1B Eu1 O1A C1 75(2) . .
O1B Eu1 O12A C80 -132(2) . .
O1B C1 O1A Eu1 -81(2) . .
C67 C66 C65 C64 11(3) . .
O18 Eu1 O19 Eu2 -2.1(7) . .
O18 Eu1 O19 C82 175.9(14) . .
O18 Eu1 O13 C54 80.6(14) . .
O18 Eu1 O11 C80 -23.2(11) . .
O18 Eu1 O2 C1 14.2(11) . .
O18 Eu1 O1B C1 -156(5) . .
O18 Eu1 O12B C80 -175(2) . .
O18 Eu1 C1 O2 -168.6(9) . .
O18 Eu1 C1 O1B 24(5) . .
O18 Eu1 C1 C2 73(14) . .
O18 Eu1 C1 O1A -9(4) . .
O18 Eu1 C80 O11 161.9(9) . .
O18 Eu1 C80 O12B 5(2) . .
O18 Eu1 C80 C78 -80(11) . 7_655
O18 Eu1 C80 O12A -32.6(17) . .
O18 Eu1 O5B C27B -72(5) . .
O18 Eu1 O6A Eu2 -152.7(6) . .
O18 Eu1 O6A C27A 77.5(14) . .
O18 Eu1 C27A C24 24.9(18) . 7_765
O18 Eu1 C27A O6A -95.3(13) . .
O18 Eu1 C27A O5A 116.2(15) . .
O18 Eu1 O5A C27A -59.0(15) . .
O18 Eu1 O1A C1 171(4) . .
O18 Eu1 O12A C80 148.6(16) . .
C57 C60 C61 C119 41.4(18) . .
C57 C60 C61 C62 -138.0(15) . .
C57 C60 C59 C58 -2(2) . .
C71 C72 C119 C61 1.0(19) . .
C71 C72 C73 C74 146.4(18) . .
C71 C72 C73 C13B -35(2) . .
C71 C72 C73 C8A -138(2) . .
C71 C72 C73 C76 27(3) . .
C71 C63 C62 C61 1(2) . .
C71 C63 C64 C70 32(2) . .
C71 C63 C64 C65 -154.9(17) . .
C4 C7 C6 C5 -5(2) . .
C4 C7 C8 C20 41.4(17) . .
C4 C7 C8 C9 -144.4(13) . .
C36 C37 C45 C46 2(2) . .
C36 C37 C38 C39 -60(2) . .
C36 C37 C38 C44 132.6(18) . .
C36 C35 C47 C46 2(2) . .
C36 C35 C34 C31 130.5(16) . .
C36 C35 C34 C33 -51(2) . .
C32 C29 C30 C31 -3(2) . .
O14 Eu2 O19 Eu1 -119.7(4) 6_556 .
O14 Eu2 O19 Eu1 -52.8(4) . .
O14 Eu2 O19 C82 61.5(9) 6_556 .
O14 Eu2 O19 C82 128.5(9) . .
O14 Eu2 O14 C54 148.6(12) 6_556 .
O14 Eu2 C82 O19 124.0(8) . 6_556
O14 Eu2 C82 O19 51.4(8) 6_556 6_556
O14 Eu2 C82 O19 -51.4(8) . .
O14 Eu2 C82 O19 -124.0(8) 6_556 .
O14 Eu2 C82 C81 -36.3(2) 6_556 .
O14 Eu2 C82 C81 36.3(2) . .
O14 Eu2 O6B C27B 134(3) 6_556 .
O14 Eu2 O6B C27B 89(4) . .
O14 Eu2 O6A Eu1 72.3(4) . .
O14 Eu2 O6A Eu1 88.2(8) 6_556 .
O14 Eu2 O6A C27A 164.7(18) 6_556 .
O14 Eu2 O6A C27A 149(2) . .
C19 C20 C8 C7 174.9(11) . .
C19 C20 C8 C9 0.9(19) . .
C19 C21 C26 C25 178.5(14) . .
C19 C21 C22 C23 174.3(15) . .
C73 C72 C119 C61 179.0(13) . .
C73 C72 C71 C63 179.9(12) . .
C73 C8A C3A C78 -14(6) . .
C59 C60 C61 C119 -140.9(13) . .
C59 C60 C61 C62 39.6(19) . .
C59 C60 C57 C56 2(2) . .
C34 C35 C47 C46 -174.2(13) . .
C34 C35 C36 C37 175.2(14) . .
C34 C31 C30 C29 -1(2) . .
C21 C26 C25 C24 4(2) . .
C21 C22 C23 C24 11(3) . .
C50 C49 C48 C0AA 2.6(19) . .
C50 C49 C48 C46 179.9(11) . .
C82 Eu2 O19 Eu1 178.8(10) . .
C82 Eu2 O14 C54 53.2(13) . .
C82 Eu2 O6B C27B -3(4) . .
C82 Eu2 O6A Eu1 -23.6(5) . .
C82 Eu2 O6A C27A 53(2) . .
O20 Eu2 O19 Eu1 95.2(4) . .
O20 Eu2 O19 C82 -83.5(8) . .
O20 Eu2 O14 C54 -29.8(17) . .
O20 Eu2 C82 O19 -92.3(8) . 6_556
O20 Eu2 C82 O19 92.3(8) . .
O20 Eu2 C82 C81 180.0 . .
O20 Eu2 O6B C27B -71(4) . .
O20 Eu2 O6A Eu1 -100.6(7) . .
O20 Eu2 O6A C27A -24(2) . .
C11 C17 C16 C14 1(2) . .
C11 C12 C13 C14 -4(2) . .
C11 C10 C18 C19 174.8(12) . .
C11 C10 C9 C8 -173.8(12) . .
C38 C37 C45 C46 -171.8(13) . .
C38 C37 C36 C35 173.2(14) . .
C38 C39 C40 C41 13(3) . .
C28 Eu3 O4 C15 3(3) . .
C28 Eu3 O4 C15 85.4(13) 6_557 .
C28 Eu3 O8 C28 102.3(10) 6_557 .
C28 Eu3 O7 C28 -86.4(11) 6_557 .
C28 Eu3 C28 O8 -77.3(10) 6_557 .
C28 Eu3 C28 O7 94.8(10) 6_557 .
C28 Eu3 C28 C29 -136(10) 6_557 .
C28 C29 C30 C31 177.0(14) . .
C15 C14 C16 C17 176.8(13) . .
C15 C14 C13 C12 -175.1(13) . .
C42 Eu4 O9 C42 97.9(11) 6_558 .
C42 Eu4 O26 C68 -6(4) 6_558 8_576
C42 Eu4 O26 C68 -88.0(18) . 8_576
C42 Eu4 O10 C42 -89.9(12) 6_558 .
C42 Eu4 C42 O9 -81.9(10) 6_558 .
C42 Eu4 C42 O10 90.9(11) 6_558 .
C42 Eu4 C42 C41 -103(22) 6_558 .
C42 C41 C40 C39 179.1(16) . .
O12B Eu1 O19 Eu2 116.6(9) . .
O12B Eu1 O19 C82 -65.5(17) . .
O12B Eu1 O13 C54 162.8(15) . .
O12B Eu1 O11 C80 -13.2(13) . .
O12B Eu1 O2 C1 -70.8(11) . .
O12B Eu1 O1B C1 122(5) . .
O12B Eu1 O18 C53 16(3) . .
O12B Eu1 C1 O2 111.7(10) . .
O12B Eu1 C1 O1B -56(5) . .
O12B Eu1 C1 C2 -6(14) . .
O12B Eu1 C1 O1A -89(4) . .
O12B Eu1 C80 O11 157(2) . .
O12B Eu1 C80 C78 -86(11) . 7_655
O12B Eu1 C80 O12A -37.8(14) . .
O12B Eu1 O5B C27B -64(6) . .
O12B Eu1 O6A Eu2 -101.5(12) . .
O12B Eu1 O6A C27A 128.7(17) . .
O12B Eu1 C27A C24 37(3) . 7_765
O12B Eu1 C27A O6A -83(2) . .
O12B Eu1 C27A O5A 129(2) . .
O12B Eu1 O5A C27A -96(2) . .
O12B Eu1 O1A C1 91(3) . .
O12B Eu1 O12A C80 72.3(17) . .
O12B C80 O12A Eu1 -79.7(16) . .
C54 C55 C58 C59 172.8(12) . .
C54 C55 C56 C57 -173.8(13) . .
C58 C55 C54 O13 12.7(19) . .
C58 C55 C54 O14 -171.4(13) . .
C58 C55 C56 C57 3(2) . .
C2 C1 O1A Eu1 -175.2(12) . .
C29 C32 C33 C34 -1(2) . .
C3 C2 C1 Eu1 113(14) . .
C3 C2 C1 O2 -3(2) . .
C3 C2 C1 O1B 161(5) . .
C3 C2 C1 O1A -167(4) . .
C1 C2 C3 C4 -173.3(14) . .
C41 C43 C44 C38 -13(3) . .
C39 C38 C44 C43 15(3) . .
C26 C21 C22 C23 -11(2) . .
C26 C25 C24 C23 -4(3) . .
C26 C25 C24 C27B -169(2) . 7_755
C26 C25 C24 C27A 176.4(19) . 7_755
C30 C31 C34 C35 -177.0(14) . .
C30 C31 C34 C33 4(2) . .
C56 C55 C54 O13 -170.6(13) . .
C56 C55 C54 O14 5.3(19) . .
C56 C55 C58 C59 -4(2) . .
C80 Eu1 O19 Eu2 135.4(4) . .
C80 Eu1 O19 C82 -46.6(15) . .
C80 Eu1 O13 C54 -170.9(14) . .
C80 Eu1 O2 C1 -90.7(10) . .
C80 Eu1 O1B C1 94(4) . .
C80 Eu1 O18 C53 13(3) . .
C80 Eu1 C1 O2 86.0(10) . .
C80 Eu1 C1 O1B -82(5) . .
C80 Eu1 C1 C2 -32(14) . .
C80 Eu1 C1 O1A -115(4) . .
C80 Eu1 O5B C27B -56(12) . .
C80 Eu1 O6A Eu2 -56.7(11) . .
C80 Eu1 O6A C27A 173.5(14) . .
C80 Eu1 C27A C24 81(7) . 7_765
C80 Eu1 C27A O6A -40(8) . .
C80 Eu1 C27A O5A 172(6) . .
C80 Eu1 O5A C27A -177.9(17) . .
C80 Eu1 O1A C1 65(4) . .
C80 C78 C75 C74 180.0(18) 7_665 .
C80 C78 C9B C13B -176(2) 7_665 .
C80 C78 C3A C8A -171(3) 7_665 .
C80 C78 C77 C76 179(4) 7_665 .
C33 C32 C29 C28 -175.7(14) . .
C33 C32 C29 C30 5(2) . .
O5B Eu1 O19 Eu2 -40.3(10) . .
O5B Eu1 O19 C82 137.7(18) . .
O5B Eu1 O13 C54 14.5(17) . .
O5B Eu1 O11 C80 -171(3) . .
O5B Eu1 O2 C1 85.5(13) . .
O5B Eu1 O1B C1 -92(4) . .
O5B Eu1 O18 C53 -168(3) . .
O5B Eu1 O12B C80 178.1(19) . .
O5B Eu1 C1 O2 -99.6(13) . .
O5B Eu1 C1 O1B 93(5) . .
O5B Eu1 C1 C2 142(14) . .
O5B Eu1 C1 O1A 60(4) . .
O5B Eu1 C80 O11 147(9) . .
O5B Eu1 C80 O12B -10(9) . .
O5B Eu1 C80 C78 -95(13) . 7_655
O5B Eu1 C80 O12A -47(9) . .
O5B Eu1 O6A Eu2 137(2) . .
O5B Eu1 O6A C27A 7(3) . .
O5B Eu1 C27A C24 -7(15) . 7_765
O5B Eu1 C27A O6A -127(15) . .
O5B Eu1 C27A O5A 84(14) . .
O5B Eu1 O5A C27A -10(3) . .
O5B Eu1 O1A C1 -121(4) . .
O5B Eu1 O12A C80 171(2) . .
C22 C21 C26 C25 3(2) . .
C22 C23 C24 C25 -3(3) . .
C22 C23 C24 C27B 154(3) . 7_755
C22 C23 C24 C27A 176.4(18) . 7_755
C53 C51 C50 C49 -178.1(12) 6_547 .
C70 C64 C65 C66 -18(3) . .
C65 C66 C67 C69 2(2) . .
C65 C66 C67 C68 180.0(17) . .
C65 C64 C70 C69 13(3) . .
C69 C67 C68 O15 171.3(18) . .
C69 C67 C68 O26 -12(3) . 8_575
C44 C43 C41 C42 -179.9(18) . .
C44 C43 C41 C40 10(3) . .
C44 C38 C39 C40 -15(2) . .
C68 C67 C69 C70 175.7(18) . .
O21 Eu2 O19 Eu1 2.2(17) . .
O21 Eu2 O19 C82 -176.6(17) . .
O21 Eu2 O14 C54 -126.0(14) . .
O21 Eu2 C82 O19 92.3(8) . .
O21 Eu2 C82 O19 -92.3(8) . 6_556
O21 Eu2 C82 C81 180.0 . .
O21 Eu2 O6B C27B 179(4) . .
O21 Eu2 O6A Eu1 157.8(7) . .
O21 Eu2 O6A C27A -126(2) . .
C78 C80 O12A Eu1 175.2(11) 7_655 .
C78 C75 C74 C73 -4(3) . .
C78 C9B C13B C73 -4(4) . .
C78 C77 C76 C73 -3(7) . .
C75 C78 C9B C13B 6(4) . .
C75 C78 C3A C8A 80(4) . .
C75 C78 C77 C76 -49(5) . .
C74 C73 C13B C9B -3(4) . .
C74 C73 C8A C3A -63(3) . .
C74 C73 C76 C77 50(5) . .
C9B C78 C75 C74 -3(3) . .
C9B C78 C3A C8A -48(4) . .
C9B C78 C77 C76 74(4) . .
C13B C73 C74 C75 7(3) . .
C13B C73 C8A C3A 64(4) . .
C13B C73 C76 C77 -70(4) . .
C8A C73 C74 C75 71(2) . .
C8A C73 C13B C9B -55(3) . .
C8A C73 C76 C77 -10(6) . .
C3A C78 C75 C74 -69(2) . .
C3A C78 C9B C13B 57(3) . .
C3A C78 C77 C76 7(6) . .
C77 C78 C75 C74 51(3) . .
C77 C78 C9B C13B -70(2) . .
C77 C78 C3A C8A 1(5) . .
C76 C73 C74 C75 -47(3) . .
C76 C73 C13B C9B 75(3) . .
C76 C73 C8A C3A 19(5) . .
C24 C27A O5A Eu1 128.5(19) 7_765 .
O6B Eu2 O19 Eu1 23.9(9) . .
O6B Eu2 O19 Eu1 146.1(14) 6_556 .
O6B Eu2 O19 C82 -154.9(12) . .
O6B Eu2 O19 C82 -32.7(16) 6_556 .
O6B Eu2 O14 C54 -164.8(17) 6_556 .
O6B Eu2 O14 C54 -61.9(15) . .
O6B Eu2 C82 O19 -156.5(12) . 6_556
O6B Eu2 C82 O19 28.1(13) . .
O6B Eu2 C82 O19 156.5(12) 6_556 .
O6B Eu2 C82 O19 -28.1(13) 6_556 6_556
O6B Eu2 C82 C81 -115.8(10) 6_556 .
O6B Eu2 C82 C81 115.8(10) . .
O6B Eu2 O6B C27B -135(3) 6_556 .
O6B Eu2 O6A Eu1 172(3) . .
O6B Eu2 O6A Eu1 -151.9(10) 6_556 .
O6B Eu2 O6A C27A -111(4) . .
O6B Eu2 O6A C27A -75(3) 6_556 .
O25 Eu4 O9 C42 -12.0(12) . .
O25 Eu4 O26 C68 165.4(18) . 8_576
O25 Eu4 O10 C42 164.1(11) . .
O25 Eu4 C42 O9 170.8(9) . .
O25 Eu4 C42 O10 -16.4(11) . .
O25 Eu4 C42 C41 150(22) . .
O6A Eu2 O19 Eu1 158.7(5) 6_556 .
O6A Eu2 O19 Eu1 21.6(5) . .
O6A Eu2 O19 C82 -157.1(9) . .
O6A Eu2 O19 C82 -20.1(10) 6_556 .
O6A Eu2 O14 C54 -41.3(13) . .
O6A Eu2 O14 C54 164.6(13) 6_556 .
O6A Eu2 C82 O19 -22.0(9) 6_556 6_556
O6A Eu2 C82 O19 22.0(9) . .
O6A Eu2 C82 O19 -162.7(8) . 6_556
O6A Eu2 C82 O19 162.7(8) 6_556 .
O6A Eu2 C82 C81 109.7(4) . .
O6A Eu2 C82 C81 -109.7(4) 6_556 .
O6A Eu2 O6B C27B -123(4) 6_556 .
O6A Eu2 O6B C27B 15(3) . .
O6A Eu2 O6A Eu1 -131.0(9) 6_556 .
O6A Eu2 O6A C27A -55(3) 6_556 .
O6A C27A O5A Eu1 -37(3) . .
O5A Eu1 O19 Eu2 -63.2(5) . .
O5A Eu1 O19 C82 114.7(15) . .
O5A Eu1 O13 C54 5.0(15) . .
O5A Eu1 O11 C80 145.5(10) . .
O5A Eu1 O2 C1 85.7(10) . .
O5A Eu1 O1B C1 -74(4) . .
O5A Eu1 O18 C53 -150(3) . .
O5A Eu1 O12B C80 -137.3(14) . .
O5A Eu1 C1 O2 -89.5(10) . .
O5A Eu1 C1 O1B 103(5) . .
O5A Eu1 C1 C2 152(14) . .
O5A Eu1 C1 O1A 70(4) . .
O5A Eu1 C80 O11 -82.7(19) . .
O5A Eu1 C80 O12B 121(2) . .
O5A Eu1 C80 C78 35(12) . 7_655
O5A Eu1 C80 O12A 83(2) . .
O5A Eu1 O5B C27B 162(7) . .
O5A Eu1 O6A Eu2 113.0(8) . .
O5A Eu1 O6A C27A -16.8(13) . .
O5A Eu1 C27A C24 -91(2) . 7_765
O5A Eu1 C27A O6A 148(2) . .
O5A Eu1 O1A C1 -103(4) . .
O5A Eu1 O12A C80 -146.7(11) . .
O1A Eu1 O19 Eu2 -114.2(16) . .
O1A Eu1 O19 C82 64(2) . .
O1A Eu1 O13 C54 104(4) . .
O1A Eu1 O11 C80 63.0(16) . .
O1A Eu1 O2 C1 12(2) . .
O1A Eu1 O1B C1 -75(2) . .
O1A Eu1 O18 C53 -78(3) . .
O1A Eu1 O12B C80 -99.4(19) . .
O1A Eu1 C1 O2 -159(4) . .
O1A Eu1 C1 O1B 33(4) . .
O1A Eu1 C1 C2 83(15) . .
O1A Eu1 C80 O11 -121.5(11) . .
O1A Eu1 C80 O12B 82(2) . .
O1A Eu1 C80 C78 -4(11) . 7_655
O1A Eu1 C80 O12A 44.0(18) . .
O1A Eu1 O5B C27B -148(5) . .
O1A Eu1 O6A Eu2 139.5(9) . .
O1A Eu1 O6A C27A 9.7(16) . .
O1A Eu1 C27A C24 -51(2) . 7_765
O1A Eu1 C27A O6A -171.0(15) . .
O1A Eu1 C27A O5A 40.5(16) . .
O1A Eu1 O5A C27A -136.7(16) . .
O1A Eu1 O12A C80 -134.3(17) . .
O12A Eu1 O19 Eu2 137.5(10) . .
O12A Eu1 O19 C82 -44.5(18) . .
O12A Eu1 O13 C54 163.6(14) . .
O12A Eu1 O11 C80 8.3(12) . .
O12A Eu1 O2 C1 -63.6(10) . .
O12A Eu1 O1B C1 115(5) . .
O12A Eu1 O18 C53 -1(3) . .
O12A Eu1 O12B C80 -73.7(16) . .
O12A Eu1 C1 O2 112.0(10) . .
O12A Eu1 C1 O1B -56(5) . .
O12A Eu1 C1 C2 -6(14) . .
O12A Eu1 C1 O1A -89(4) . .
O12A Eu1 C80 O11 -166(2) . .
O12A Eu1 C80 O12B 37.8(14) . .
O12A Eu1 C80 C78 -48(10) . 7_655
O12A Eu1 O5B C27B -96(5) . .
O12A Eu1 O6A Eu2 -120.4(12) . .
O12A Eu1 O6A C27A 109.8(18) . .
O12A Eu1 C27A C24 2(3) . 7_765
O12A Eu1 C27A O6A -118.0(19) . .
O12A Eu1 C27A O5A 93(2) . .
O12A Eu1 O5A C27A -124.1(17) . .
O12A Eu1 O1A C1 84(3) . .
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.198 0.015 0.164 8468 2072 ' '
