#------------------------------------------------------------------------------
#$Date: 2019-11-23 07:19:09 +0200 (Sat, 23 Nov 2019) $
#$Revision: 232410 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/76/4347636.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4347636
loop_
_publ_author_name
'Lim, Kwang Soo'
'Baldoví, José J'
'Lee, Woo Ram'
'Song, Jeong Hwa'
'Yoon, Sung Won'
'Suh, Byoung Jin'
'Coronado, Eugenio'
'Gaita-Ariño, Alejandro'
'Hong, Chang Seop'
_publ_section_title
;
 Switching of Slow Magnetic Relaxation Dynamics in Mononuclear
 Dysprosium(III) Compounds with Charge Density.
;
_journal_issue                   11
_journal_name_full               'Inorganic chemistry'
_journal_page_first              5398
_journal_page_last               5404
_journal_paper_doi               10.1021/acs.inorgchem.6b00410
_journal_volume                  55
_journal_year                    2016
_chemical_formula_sum            'C22 H46 Co2 Dy0.04 N O21 P6 Y0.96'
_chemical_formula_weight         1056.13
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 102.938(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.2922(5)
_cell_length_b                   19.4442(8)
_cell_length_c                   16.7632(7)
_cell_measurement_reflns_used    48301
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      21.609
_cell_measurement_theta_min      2.438
_cell_volume                     3904.9(3)
_computing_cell_refinement       'Bruker SMART APEXll'
_computing_data_collection       'Bruker SMART APEXll'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    WingX
_computing_publication_material  WingX
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    SHELXTL
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'omega scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1233
_diffrn_reflns_av_sigmaI/netI    0.1385
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            47009
_diffrn_reflns_theta_full        28.48
_diffrn_reflns_theta_max         28.48
_diffrn_reflns_theta_min         1.63
_exptl_absorpt_coefficient_mu    2.656
_exptl_absorpt_correction_T_max  0.7771
_exptl_absorpt_correction_T_min  0.5341
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.796
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2148
_exptl_crystal_size_max          0.27
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.601
_refine_diff_density_min         -0.957
_refine_diff_density_rms         0.145
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.942
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     491
_refine_ls_number_reflns         9796
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.942
_refine_ls_R_factor_all          0.1625
_refine_ls_R_factor_gt           0.0608
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0631P)²+0.5000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1246
_refine_ls_wR_factor_ref         0.1630
_reflns_number_gt                4451
_reflns_number_total             9796
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic6b00410_si_002.cif
_cod_data_source_block           diluted-2
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'MULTI-SCAN' was
changed to 'multi-scan' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/ACS/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               4347636
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Y1 Y 0.29513(4) 0.21647(3) 0.76050(3) 0.03207(16) Uani 0.96 1 d P
Dy1 Dy 0.29513(4) 0.21647(3) 0.76050(3) 0.03207(16) Uani 0.04 1 d P
O1 O 0.4747(3) 0.2595(2) 0.7718(2) 0.0393(10) Uani 1 1 d .
P1 P 0.59110(12) 0.23906(8) 0.81170(9) 0.0343(4) Uani 1 1 d .
O7 O 0.6505(3) 0.3028(2) 0.8648(3) 0.0503(12) Uani 1 1 d .
C6 C 0.5958(6) 0.3659(4) 0.8688(5) 0.069(2) Uani 1 1 d .
H6A H 0.5886 0.3900 0.8179 0.103 Uiso 1 1 calc R
H6B H 0.6385 0.3932 0.9125 0.103 Uiso 1 1 calc R
H6C H 0.5231 0.3575 0.8788 0.103 Uiso 1 1 calc R
O8 O 0.6634(3) 0.2342(2) 0.7442(2) 0.0442(11) Uani 1 1 d .
C7 C 0.6589(6) 0.2898(4) 0.6875(4) 0.061(2) Uani 1 1 d .
H7A H 0.5824 0.3008 0.6638 0.091 Uiso 1 1 calc R
H7B H 0.6957 0.2765 0.6451 0.091 Uiso 1 1 calc R
H7C H 0.6955 0.3293 0.7157 0.091 Uiso 1 1 calc R
O2 O 0.4038(3) 0.1242(2) 0.7403(2) 0.0394(10) Uani 1 1 d .
P2 P 0.51123(12) 0.09178(8) 0.78244(9) 0.0350(4) Uani 1 1 d .
O9 O 0.5851(3) 0.0747(2) 0.7176(2) 0.0423(10) Uani 1 1 d .
C8 C 0.5390(6) 0.0365(3) 0.6459(4) 0.0564(19) Uani 1 1 d .
H8A H 0.5405 -0.0116 0.6590 0.085 Uiso 1 1 calc R
H8B H 0.5820 0.0444 0.6055 0.085 Uiso 1 1 calc R
H8C H 0.4633 0.0507 0.6246 0.085 Uiso 1 1 calc R
O10 O 0.4850(3) 0.0148(2) 0.8068(2) 0.0454(11) Uani 1 1 d .
C9 C 0.4046(5) 0.0048(3) 0.8552(4) 0.059(2) Uani 1 1 d .
H9A H 0.4417 0.0026 0.9120 0.089 Uiso 1 1 calc R
H9B H 0.3651 -0.0375 0.8395 0.089 Uiso 1 1 calc R
H9C H 0.3527 0.0424 0.8467 0.089 Uiso 1 1 calc R
O3 O 0.3731(3) 0.1919(2) 0.8936(2) 0.0372(10) Uani 1 1 d .
P3 P 0.48807(13) 0.17585(9) 0.94215(9) 0.0366(4) Uani 1 1 d .
O11 O 0.4793(3) 0.1192(2) 1.0088(2) 0.0517(12) Uani 1 1 d .
C10 C 0.3900(5) 0.1204(4) 1.0511(4) 0.060(2) Uani 1 1 d .
H10A H 0.3838 0.1658 1.0724 0.091 Uiso 1 1 calc R
H10B H 0.4052 0.0880 1.0954 0.091 Uiso 1 1 calc R
H10C H 0.3213 0.1085 1.0139 0.091 Uiso 1 1 calc R
O12 O 0.5328(3) 0.2415(2) 0.9965(2) 0.0548(13) Uani 1 1 d .
C11 C 0.4629(6) 0.2918(4) 1.0215(4) 0.066(2) Uani 1 1 d .
H11A H 0.4324 0.3214 0.9762 0.099 Uiso 1 1 calc R
H11B H 0.5059 0.3185 1.0656 0.099 Uiso 1 1 calc R
H11C H 0.4032 0.2692 1.0396 0.099 Uiso 1 1 calc R
Co1 Co 0.61974(6) 0.14554(4) 0.88241(4) 0.0337(2) Uani 1 1 d .
C1 C 0.7301(5) 0.1354(4) 0.9959(4) 0.058(2) Uani 1 1 d .
H1 H 0.7182 0.1521 1.0452 0.070 Uiso 1 1 calc R
C2 C 0.7819(5) 0.1698(4) 0.9424(4) 0.0523(18) Uani 1 1 d .
H2 H 0.8106 0.2142 0.9498 0.063 Uiso 1 1 calc R
C3 C 0.7845(5) 0.1274(4) 0.8757(4) 0.0489(18) Uani 1 1 d .
H3 H 0.8145 0.1384 0.8311 0.059 Uiso 1 1 calc R
C4 C 0.7337(5) 0.0658(4) 0.8884(4) 0.0474(17) Uani 1 1 d .
H4 H 0.7246 0.0279 0.8537 0.057 Uiso 1 1 calc R
C5 C 0.6989(5) 0.0704(4) 0.9615(4) 0.0518(19) Uani 1 1 d .
H5 H 0.6616 0.0364 0.9839 0.062 Uiso 1 1 calc R
O4 O 0.2172(3) 0.1906(2) 0.6279(2) 0.0377(10) Uani 1 1 d .
P4 P 0.10702(13) 0.16484(9) 0.58026(9) 0.0388(4) Uani 1 1 d .
O13 O 0.0597(4) 0.2199(3) 0.5115(3) 0.0702(16) Uani 1 1 d .
C17 C 0.1244(8) 0.2711(5) 0.4864(5) 0.110(4) Uani 1 1 d .
H17A H 0.1708 0.2925 0.5336 0.165 Uiso 1 1 calc R
H17B H 0.0763 0.3051 0.4550 0.165 Uiso 1 1 calc R
H17C H 0.1704 0.2510 0.4533 0.165 Uiso 1 1 calc R
O14 O 0.1282(4) 0.0999(2) 0.5284(3) 0.0662(15) Uani 1 1 d .
C18 C 0.2255(7) 0.0959(5) 0.4956(6) 0.133(5) Uani 1 1 d .
H18A H 0.2109 0.1173 0.4427 0.199 Uiso 1 1 calc R
H18B H 0.2450 0.0486 0.4905 0.199 Uiso 1 1 calc R
H18C H 0.2861 0.1192 0.5315 0.199 Uiso 1 1 calc R
O5 O 0.1922(3) 0.1209(2) 0.7790(2) 0.0420(10) Uani 1 1 d .
P5 P 0.08167(13) 0.08949(8) 0.74336(10) 0.0366(4) Uani 1 1 d .
O15 O 0.1005(4) 0.0100(2) 0.7262(3) 0.0569(12) Uani 1 1 d .
C19 C 0.1802(6) -0.0092(4) 0.6798(5) 0.077(2) Uani 1 1 d .
H19A H 0.1447 -0.0100 0.6226 0.116 Uiso 1 1 calc R
H19B H 0.2093 -0.0540 0.6965 0.116 Uiso 1 1 calc R
H19C H 0.2402 0.0236 0.6890 0.116 Uiso 1 1 calc R
O16 O 0.0124(3) 0.0801(2) 0.8116(2) 0.0484(12) Uani 1 1 d .
C20 C 0.0633(6) 0.0515(4) 0.8889(4) 0.068(2) Uani 1 1 d .
H20A H 0.0810 0.0041 0.8821 0.102 Uiso 1 1 calc R
H20B H 0.0129 0.0548 0.9250 0.102 Uiso 1 1 calc R
H20C H 0.1306 0.0763 0.9119 0.102 Uiso 1 1 calc R
O6 O 0.1134(3) 0.2555(2) 0.7493(2) 0.0381(10) Uani 1 1 d .
P6 P -0.00133(12) 0.23573(9) 0.70435(10) 0.0363(4) Uani 1 1 d .
O17 O -0.0813(3) 0.2388(2) 0.7670(3) 0.0576(13) Uani 1 1 d .
C21 C -0.0769(6) 0.2958(4) 0.8194(4) 0.068(2) Uani 1 1 d .
H21A H -0.0011 0.3034 0.8484 0.103 Uiso 1 1 calc R
H21B H -0.1225 0.2871 0.8579 0.103 Uiso 1 1 calc R
H21C H -0.1040 0.3359 0.7877 0.103 Uiso 1 1 calc R
O18 O -0.0512(4) 0.2948(2) 0.6422(3) 0.0626(14) Uani 1 1 d .
C22 C -0.0048(7) 0.3600(4) 0.6398(5) 0.098(3) Uani 1 1 d .
H22A H 0.0012 0.3823 0.6917 0.147 Uiso 1 1 calc R
H22B H -0.0517 0.3868 0.5976 0.147 Uiso 1 1 calc R
H22C H 0.0680 0.3557 0.6284 0.147 Uiso 1 1 calc R
Co2 Co -0.02682(6) 0.13892(4) 0.64018(4) 0.0347(2) Uani 1 1 d .
C12 C -0.1936(5) 0.1257(4) 0.6414(4) 0.0501(19) Uani 1 1 d .
H12 H -0.2271 0.1425 0.6820 0.060 Uiso 1 1 calc R
C13 C -0.1845(5) 0.1608(4) 0.5700(4) 0.0544(19) Uani 1 1 d .
H13 H -0.2103 0.2049 0.5550 0.065 Uiso 1 1 calc R
C14 C -0.1307(6) 0.1181(4) 0.5264(4) 0.057(2) Uani 1 1 d .
H14 H -0.1149 0.1283 0.4760 0.069 Uiso 1 1 calc R
C15 C -0.1037(5) 0.0575(4) 0.5693(4) 0.0526(19) Uani 1 1 d .
H15 H -0.0657 0.0203 0.5538 0.063 Uiso 1 1 calc R
C16 C -0.1446(6) 0.0627(4) 0.6406(4) 0.0533(19) Uani 1 1 d .
H16 H -0.1392 0.0290 0.6806 0.064 Uiso 1 1 calc R
O19 O 0.2990(3) 0.3324(2) 0.8251(3) 0.0437(11) Uani 1 1 d .
O20 O 0.2779(3) 0.3312(2) 0.6943(3) 0.0457(11) Uani 1 1 d .
N1 N 0.2811(4) 0.3647(3) 0.7590(4) 0.0493(15) Uani 1 1 d .
O21 O 0.2656(5) 0.4266(3) 0.7576(3) 0.0867(18) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Y Y -2.7962 3.5667 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
O4 Y1 O3 155.04(15)
O4 Y1 O2 79.32(13)
O3 Y1 O2 81.38(13)
O4 Y1 O5 80.17(13)
O3 Y1 O5 79.73(13)
O2 Y1 O5 75.29(14)
O4 Y1 O6 78.84(13)
O3 Y1 O6 109.51(13)
O2 Y1 O6 144.98(13)
O5 Y1 O6 74.25(13)
O4 Y1 O1 110.09(13)
O3 Y1 O1 79.19(13)
O2 Y1 O1 73.84(13)
O5 Y1 O1 144.73(13)
O6 Y1 O1 139.91(14)
O4 Y1 O20 77.68(14)
O3 Y1 O20 127.12(14)
O2 Y1 O20 128.93(14)
O5 Y1 O20 142.22(13)
O6 Y1 O20 71.70(13)
O1 Y1 O20 72.40(13)
O4 Y1 O19 125.99(14)
O3 Y1 O19 78.54(14)
O2 Y1 O19 144.17(13)
O5 Y1 O19 128.80(14)
O6 Y1 O19 70.43(13)
O1 Y1 O19 73.44(13)
O20 Y1 O19 51.18(14)
O4 Y1 N1 101.63(16)
O3 Y1 N1 103.29(16)
O2 Y1 N1 144.15(14)
O5 Y1 N1 140.52(14)
O6 Y1 N1 67.62(13)
O1 Y1 N1 72.29(13)
O20 Y1 N1 25.69(13)
O19 Y1 N1 25.55(14)
P1 O1 Y1 137.5(2)
O1 P1 O8 109.2(2)
O1 P1 O7 108.4(2)
O8 P1 O7 100.5(2)
O1 P1 Co1 119.57(17)
O8 P1 Co1 107.02(17)
O7 P1 Co1 110.42(17)
C6 O7 P1 122.5(4)
C7 O8 P1 118.8(4)
P2 O2 Y1 137.7(2)
O2 P2 O9 110.0(2)
O2 P2 O10 107.9(2)
O9 P2 O10 99.0(2)
O2 P2 Co1 119.36(17)
O9 P2 Co1 106.34(16)
O10 P2 Co1 112.20(17)
C8 O9 P2 120.3(4)
C9 O10 P2 118.5(4)
P3 O3 Y1 135.8(2)
O3 P3 O11 108.8(2)
O3 P3 O12 107.9(2)
O11 P3 O12 102.9(2)
O3 P3 Co1 121.15(16)
O11 P3 Co1 108.13(17)
O12 P3 Co1 106.51(17)
C10 O11 P3 121.0(4)
C11 O12 P3 124.3(4)
C5 Co1 C2 65.6(3)
C5 Co1 C4 39.2(2)
C2 Co1 C4 65.3(3)
C5 Co1 C3 65.8(3)
C2 Co1 C3 39.2(2)
C4 Co1 C3 39.0(2)
C5 Co1 C1 39.6(3)
C2 Co1 C1 38.8(2)
C4 Co1 C1 65.9(3)
C3 Co1 C1 65.9(3)
C5 Co1 P1 161.0(2)
C2 Co1 P1 95.5(2)
C4 Co1 P1 132.9(2)
C3 Co1 P1 98.9(2)
C1 Co1 P1 125.0(2)
C5 Co1 P2 106.0(2)
C2 Co1 P2 147.6(2)
C4 Co1 P2 88.22(19)
C3 Co1 P2 108.3(2)
C1 Co1 P2 145.5(2)
P1 Co1 P2 89.15(7)
C5 Co1 P3 100.91(18)
C2 Co1 P3 116.7(2)
C4 Co1 P3 138.3(2)
C3 Co1 P3 155.05(19)
C1 Co1 P3 90.29(19)
P1 Co1 P3 88.72(6)
P2 Co1 P3 95.43(6)
C2 C1 C5 107.1(6)
C2 C1 Co1 70.3(4)
C5 C1 Co1 69.5(3)
C1 C2 C3 109.2(7)
C1 C2 Co1 70.9(4)
C3 C2 Co1 70.6(4)
C4 C3 C2 107.2(6)
C4 C3 Co1 70.3(4)
C2 C3 Co1 70.1(3)
C3 C4 C5 108.5(6)
C3 C4 Co1 70.7(4)
C5 C4 Co1 69.9(4)
C4 C5 C1 108.0(7)
C4 C5 Co1 70.9(4)
C1 C5 Co1 70.9(4)
P4 O4 Y1 136.9(2)
O4 P4 O13 107.6(2)
O4 P4 O14 108.6(2)
O13 P4 O14 102.6(3)
O4 P4 Co2 121.32(16)
O13 P4 Co2 107.51(19)
O14 P4 Co2 107.62(18)
C17 O13 P4 124.1(5)
C18 O14 P4 120.5(4)
P5 O5 Y1 139.0(2)
O5 P5 O16 110.3(2)
O5 P5 O15 108.3(2)
O16 P5 O15 98.1(2)
O5 P5 Co2 118.96(17)
O16 P5 Co2 107.15(16)
O15 P5 Co2 112.00(18)
C19 O15 P5 119.6(4)
C20 O16 P5 120.4(4)
P6 O6 Y1 137.6(2)
O6 P6 O18 109.2(2)
O6 P6 O17 108.1(2)
O18 P6 O17 101.7(3)
O6 P6 Co2 119.48(17)
O18 P6 Co2 108.31(18)
O17 P6 Co2 108.62(18)
C21 O17 P6 119.8(4)
C22 O18 P6 125.4(4)
C12 Co2 C16 38.5(3)
C12 Co2 C13 39.6(2)
C16 Co2 C13 65.4(3)
C12 Co2 C15 65.6(3)
C16 Co2 C15 39.4(2)
C13 Co2 C15 65.4(3)
C12 Co2 C14 65.1(3)
C16 Co2 C14 65.1(3)
C13 Co2 C14 38.4(3)
C15 Co2 C14 38.8(3)
C12 Co2 P6 97.9(2)
C16 Co2 P6 130.3(2)
C13 Co2 P6 96.7(2)
C15 Co2 P6 161.5(2)
C14 Co2 P6 128.1(3)
C12 Co2 P5 111.9(2)
C16 Co2 P5 89.2(2)
C13 Co2 P5 151.3(2)
C15 Co2 P5 103.8(2)
C14 Co2 P5 142.1(3)
P6 Co2 P5 89.67(7)
C12 Co2 P4 152.63(19)
C16 Co2 P4 140.3(2)
C13 Co2 P4 113.5(2)
C15 Co2 P4 102.0(2)
C14 Co2 P4 89.67(19)
P6 Co2 P4 89.29(7)
P5 Co2 P4 94.47(7)
C16 C12 C13 107.9(6)
C16 C12 Co2 70.8(4)
C13 C12 Co2 70.3(3)
C14 C13 C12 107.6(7)
C14 C13 Co2 71.2(4)
C12 C13 Co2 70.1(3)
C13 C14 C15 109.1(6)
C13 C14 Co2 70.4(4)
C15 C14 Co2 70.3(4)
C14 C15 C16 107.0(7)
C14 C15 Co2 70.9(4)
C16 C15 Co2 70.1(4)
C12 C16 C15 108.5(6)
C12 C16 Co2 70.7(4)
C15 C16 Co2 70.4(4)
N1 O19 Y1 95.0(4)
N1 O20 Y1 95.6(4)
O21 N1 O19 120.6(7)
O21 N1 O20 121.4(6)
O19 N1 O20 117.9(6)
O21 N1 Y1 174.5(4)
O19 N1 Y1 59.4(3)
O20 N1 Y1 58.7(3)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Y1 O4 2.271(3)
Y1 O3 2.273(4)
Y1 O2 2.307(4)
Y1 O5 2.308(4)
Y1 O6 2.326(4)
Y1 O1 2.328(4)
Y1 O20 2.479(4)
Y1 O19 2.496(4)
Y1 N1 2.888(6)
O1 P1 1.491(4)
P1 O8 1.591(4)
P1 O7 1.602(4)
P1 Co1 2.1561(18)
O7 C6 1.408(7)
O8 C7 1.431(7)
O2 P2 1.491(4)
P2 O9 1.600(4)
P2 O10 1.603(4)
P2 Co1 2.1630(17)
O9 C8 1.419(6)
O10 C9 1.425(6)
O3 P3 1.498(4)
P3 O11 1.590(4)
P3 O12 1.593(4)
P3 Co1 2.1669(17)
O11 C10 1.435(7)
O12 C11 1.426(7)
Co1 C5 2.065(6)
Co1 C2 2.077(6)
Co1 C4 2.077(6)
Co1 C3 2.083(6)
Co1 C1 2.084(6)
C1 C2 1.382(9)
C1 C5 1.407(9)
C2 C3 1.396(8)
C3 C4 1.389(9)
C4 C5 1.389(8)
O4 P4 1.496(4)
P4 O13 1.586(5)
P4 O14 1.588(4)
P4 Co2 2.1702(17)
O13 C17 1.396(8)
O14 C18 1.426(8)
O5 P5 1.488(4)
P5 O16 1.582(4)
P5 O15 1.598(5)
P5 Co2 2.1590(17)
O15 C19 1.431(7)
O16 C20 1.421(7)
O6 P6 1.493(4)
P6 O18 1.578(4)
P6 O17 1.592(4)
P6 Co2 2.1558(18)
O17 C21 1.409(7)
O18 C22 1.394(8)
Co2 C12 2.071(6)
Co2 C16 2.073(6)
Co2 C13 2.074(6)
Co2 C15 2.076(6)
Co2 C14 2.084(6)
C12 C16 1.368(9)
C12 C13 1.403(9)
C13 C14 1.369(9)
C14 C15 1.383(9)
C15 C16 1.399(9)
O19 N1 1.250(6)
O20 N1 1.258(6)
N1 O21 1.217(6)
