#------------------------------------------------------------------------------
#$Date: 2019-11-23 08:01:50 +0200 (Sat, 23 Nov 2019) $
#$Revision: 232500 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/77/4347785.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4347785
loop_
_publ_author_name
'Axthammer, Quirin J.'
'Klapötke, Thomas M'
'Krumm, Burkhard'
'Reith, Thomas'
_publ_section_title
;
 Energetic Sila-Nitrocarbamates: Silicon Analogues of Neo-Pentane
 Derivatives.
;
_journal_issue                   9
_journal_name_full               'Inorganic chemistry'
_journal_page_first              4683
_journal_page_last               4692
_journal_paper_doi               10.1021/acs.inorgchem.6b00602
_journal_volume                  55
_journal_year                    2016
_chemical_formula_moiety         'C6 H12 N4 O8 Si'
_chemical_formula_sum            'C6 H12 N4 O8 Si'
_chemical_formula_weight         296.267
_chemical_name_common
'(dimethylsilanediyl)bis(methylene) bis(nitrocarbamate)'
_chemical_name_systematic
'(dimethylsilanediyl)bis(methylene) bis(nitrocarbamate)'
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date
;
'Thu Mar 19 05:50:08 2015'
;
_audit_creation_method           SHELXL-97
_cell_angle_alpha                83.530(4)
_cell_angle_beta                 87.158(5)
_cell_angle_gamma                81.859(5)
_cell_formula_units_Z            2
_cell_length_a                   7.2240(5)
_cell_length_b                   7.4110(4)
_cell_length_c                   12.2810(6)
_cell_measurement_reflns_used    1697
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      28.9820
_cell_measurement_theta_min      4.4870
_cell_volume                     646.34(7)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
;
_computing_molecular_graphics
;
'ORTEP (M. N. Burnett, C. K. Johnson, ORTEP-III: Oak Ridge Thermal Ellipsoid
# Plot Program for Crystal Structure Illustrations, Oak Ridge National
# Laboratory Report ORNL-6895, 1996). Windows version (L. J. Farrugia, Univ.
# Glasgow) used --- SCHAKAL (E. Keller, University of  Freiburg (Breisgau),
# Germany, 1995)'
;
_computing_publication_material
;PLATON (A. L. Spek, Acta Crystallogr, Sect. A, 1990, 46, C34, 1995 version).
# --- T.B.Cohen, Pure Appl. Chem. 1996,68,2339-2359 (atomic masses).
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    SIR-97
_diffrn_ambient_temperature      173(2)
_diffrn_detector_area_resol_mean 15.9809
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_details
;
#__ type_ start__ end____ width___ exp.time_
  1 omega  -47.00   47.00   0.5000   15.0000
omega____ theta____ kappa____ phi______ frames
    -      -23.2957   57.0000  150.0000 188

#__ type_ start__ end____ width___ exp.time_
  2 omega  -25.00   22.00   0.5000   15.0000
omega____ theta____ kappa____ phi______ frames
    -      -23.2957  -99.0000  -90.0000 94

#__ type_ start__ end____ width___ exp.time_
  3 omega  -47.00   47.00   0.5000   15.0000
omega____ theta____ kappa____ phi______ frames
    -      -23.2957   57.0000  -90.0000 188

#__ type_ start__ end____ width___ exp.time_
  4 omega  -20.00    7.00   0.5000   15.0000
omega____ theta____ kappa____ phi______ frames
    -      -23.2957  -99.0000  150.0000 54

#__ type_ start__ end____ width___ exp.time_
  5 omega  -54.00  -24.00   0.5000   15.0000
omega____ theta____ kappa____ phi______ frames
    -      -23.2957   77.0000    0.0000 60

#__ type_ start__ end____ width___ exp.time_
  6 omega  -45.00   41.00   0.5000   15.0000
omega____ theta____ kappa____ phi______ frames
    -      -23.2957   38.0000  -90.0000 172

#__ type_ start__ end____ width___ exp.time_
  7 omega   -5.00   22.00   0.5000   15.0000
omega____ theta____ kappa____ phi______ frames
    -      -23.2957  -99.0000 -150.0000 54

#__ type_ start__ end____ width___ exp.time_
  8 omega  -94.00    0.00   0.5000   15.0000
omega____ theta____ kappa____ phi______ frames
    -      -23.2957  -57.0000    0.0000 188

;
_diffrn_measurement_device       'CCD camera on κ-goniostat'
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       omega-scan
_diffrn_orient_matrix_UB_11      -0.0009465000
_diffrn_orient_matrix_UB_12      0.0051255000
_diffrn_orient_matrix_UB_13      -0.0579981000
_diffrn_orient_matrix_UB_21      0.0119120000
_diffrn_orient_matrix_UB_22      -0.0970948000
_diffrn_orient_matrix_UB_23      0.0032130000
_diffrn_orient_matrix_UB_31      -0.0985165000
_diffrn_orient_matrix_UB_32      0.0016360000
_diffrn_orient_matrix_UB_33      0.0029482000
_diffrn_radiation_collimation    0.5
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0252
_diffrn_reflns_av_sigmaI/netI    0.0357
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            5515
_diffrn_reflns_theta_full        26.37
_diffrn_reflns_theta_max         26.37
_diffrn_reflns_theta_min         4.12
_diffrn_source_current           40
_diffrn_source_type              'Spellman generator'
_diffrn_source_voltage           50
_exptl_absorpt_coefficient_mu    0.224
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.87757
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.522
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             308
_exptl_crystal_size_max          0.39
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.01
_refine_diff_density_max         0.303
_refine_diff_density_min         -0.242
_refine_diff_density_rms         0.048
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     220
_refine_ls_number_reflns         2622
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.036
_refine_ls_R_factor_all          0.0499
_refine_ls_R_factor_gt           0.0387
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0512P)²+0.1133P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0939
_refine_ls_wR_factor_ref         0.1035
_reflns_number_gt                2141
_reflns_number_total             2622
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            ic6b00602_si_002.cif
_cod_data_source_block           2b
_cod_original_cell_volume        646.34(6)
_cod_database_code               4347785
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
Si1 Si 0.78595(7) 0.24820(7) 0.16184(4) 0.03034(16) Uani 1 1 d
O5 O 1.10508(17) -0.00521(16) 0.14692(10) 0.0310(3) Uani 1 1 d
O1 O 0.59239(17) 0.2191(2) 0.35456(10) 0.0383(4) Uani 1 1 d
O6 O 1.22116(18) 0.06265(18) 0.30113(12) 0.0386(3) Uani 1 1 d
O2 O 0.64479(18) 0.3126(2) 0.51573(11) 0.0399(4) Uani 1 1 d
O3 O 0.3377(2) 0.2984(2) 0.64712(12) 0.0502(4) Uani 1 1 d
N3 N 1.2489(2) -0.2293(2) 0.26756(14) 0.0308(4) Uani 1 1 d
N1 N 0.3673(2) 0.2167(2) 0.47755(14) 0.0350(4) Uani 1 1 d
O4 O 0.1004(2) 0.2321(3) 0.56721(15) 0.0691(6) Uani 1 1 d
N2 N 0.2629(2) 0.2539(2) 0.57070(14) 0.0387(4) Uani 1 1 d
C2 C 0.5474(2) 0.2571(2) 0.45563(14) 0.0277(4) Uani 1 1 d
C4 C 1.1890(2) -0.0441(2) 0.24029(15) 0.0274(4) Uani 1 1 d
C1 C 0.7849(3) 0.2339(3) 0.31593(17) 0.0363(5) Uani 1 1 d
C3 C 1.0375(3) 0.1906(2) 0.11491(17) 0.0315(4) Uani 1 1 d
C5 C 0.6964(4) 0.4861(3) 0.1075(2) 0.0474(6) Uani 1 1 d
C6 C 0.6467(4) 0.0792(4) 0.1191(2) 0.0505(6) Uani 1 1 d
N4 N 1.1870(2) -0.3745(2) 0.22624(14) 0.0403(4) Uani 1 1 d
O8 O 1.1105(3) -0.3508(2) 0.14070(15) 0.0687(6) Uani 1 1 d
O7 O 1.2222(3) -0.5190(2) 0.28107(16) 0.0823(7) Uani 1 1 d
H3A H 1.047(3) 0.200(3) 0.0364(18) 0.033(5) Uiso 1 1 d
H3B H 1.118(3) 0.260(3) 0.1449(17) 0.033(5) Uiso 1 1 d
H1B H 0.824(3) 0.339(3) 0.3411(17) 0.035(5) Uiso 1 1 d
H1A H 0.855(3) 0.130(3) 0.3482(17) 0.032(5) Uiso 1 1 d
H6B H 0.519(4) 0.106(4) 0.142(2) 0.067(8) Uiso 1 1 d
H6A H 0.689(4) -0.033(4) 0.150(2) 0.073(9) Uiso 1 1 d
H6C H 0.648(4) 0.087(4) 0.043(3) 0.076(9) Uiso 1 1 d
H5C H 0.766(4) 0.569(4) 0.128(3) 0.081(10) Uiso 1 1 d
H5B H 0.704(4) 0.498(4) 0.033(3) 0.075(9) Uiso 1 1 d
H5A H 0.570(4) 0.517(4) 0.129(2) 0.077(9) Uiso 1 1 d
H2 H 1.293(3) -0.262(3) 0.325(2) 0.041(6) Uiso 1 1 d
H1 H 0.312(3) 0.192(3) 0.431(2) 0.045(7) Uiso 1 1 d
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C6 Si1 C5 112.41(14)
C6 Si1 C1 110.04(12)
C5 Si1 C1 108.64(11)
C6 Si1 C3 109.53(10)
C5 Si1 C3 109.68(10)
C1 Si1 C3 106.36(9)
C4 O5 C3 116.38(14)
C2 O1 C1 116.71(14)
N4 N3 C4 127.11(16)
N4 N3 H2 109.8(17)
C4 N3 H2 119.2(16)
N2 N1 C2 124.49(16)
N2 N1 H1 114.8(18)
C2 N1 H1 119.3(18)
O3 N2 O4 126.58(17)
O3 N2 N1 119.35(16)
O4 N2 N1 114.03(17)
O2 C2 O1 126.20(17)
O2 C2 N1 127.32(16)
O1 C2 N1 106.47(15)
O6 C4 O5 126.87(17)
O6 C4 N3 118.60(17)
O5 C4 N3 114.51(15)
O1 C1 Si1 106.48(12)
O1 C1 H1B 109.6(12)
Si1 C1 H1B 112.4(13)
O1 C1 H1A 105.2(13)
Si1 C1 H1A 113.9(12)
H1B C1 H1A 108.9(18)
O5 C3 Si1 110.46(12)
O5 C3 H3A 103.0(12)
Si1 C3 H3A 110.1(11)
O5 C3 H3B 107.5(12)
Si1 C3 H3B 112.8(11)
H3A C3 H3B 112.5(17)
Si1 C5 H5C 112.1(19)
Si1 C5 H5B 110.1(18)
H5C C5 H5B 106(3)
Si1 C5 H5A 111.0(18)
H5C C5 H5A 110(2)
H5B C5 H5A 108(2)
Si1 C6 H6B 110.9(16)
Si1 C6 H6A 110.4(19)
H6B C6 H6A 107(2)
Si1 C6 H6C 109.5(19)
H6B C6 H6C 106(2)
H6A C6 H6C 113(3)
O8 N4 O7 125.67(18)
O8 N4 N3 119.86(17)
O7 N4 N3 114.42(17)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Si1 C6 1.848(2)
Si1 C5 1.851(2)
Si1 C1 1.883(2)
Si1 C3 1.8836(19)
O5 C4 1.308(2)
O5 C3 1.479(2)
O1 C2 1.318(2)
O1 C1 1.462(2)
O6 C4 1.200(2)
O2 C2 1.188(2)
O3 N2 1.205(2)
N3 N4 1.378(2)
N3 C4 1.388(2)
N3 H2 0.78(2)
N1 N2 1.371(2)
N1 C2 1.383(2)
N1 H1 0.77(2)
O4 N2 1.211(2)
C1 H1B 0.95(2)
C1 H1A 0.92(2)
C3 H3A 0.96(2)
C3 H3B 0.94(2)
C5 H5C 0.91(3)
C5 H5B 0.91(3)
C5 H5A 0.94(3)
C6 H6B 0.95(3)
C6 H6A 0.89(3)
C6 H6C 0.93(3)
N4 O8 1.195(2)
N4 O7 1.201(2)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C2 N1 N2 O3 -12.1(3)
C2 N1 N2 O4 169.95(19)
C1 O1 C2 O2 4.9(3)
C1 O1 C2 N1 -174.18(16)
N2 N1 C2 O2 7.5(3)
N2 N1 C2 O1 -173.44(17)
C3 O5 C4 O6 -2.1(3)
C3 O5 C4 N3 179.55(14)
N4 N3 C4 O6 161.94(18)
N4 N3 C4 O5 -19.6(3)
C2 O1 C1 Si1 -162.10(14)
C6 Si1 C1 O1 -43.57(18)
C5 Si1 C1 O1 79.89(17)
C3 Si1 C1 O1 -162.11(13)
C4 O5 C3 Si1 -93.32(16)
C6 Si1 C3 O5 -49.81(18)
C5 Si1 C3 O5 -173.62(14)
C1 Si1 C3 O5 69.07(15)
C4 N3 N4 O8 20.5(3)
C4 N3 N4 O7 -161.7(2)
loop_
_iucr_refine_instructions_details
;
TITL kx148_P-1 in P-1
CELL  0.71073   7.2240   7.4110  12.2810   83.530   87.158   81.859
ZERR     2.00   0.0005   0.0004   0.0006    0.004    0.005    0.005
LATT   1
SFAC  C    H    N    O    SI
UNIT  12   24   8    16   2
MERG   2
SHEL 1000 0.8
FMAP   2
ACTA
CONF
HTAB
BOND $H
PLAN   20
L.S.  10
TEMP  -100.00
WGHT    0.051200    0.113300
FVAR      10.35115
SI1    5    0.785951    0.248205    0.161842    11.00000    0.03141    0.03414 =
         0.02587   -0.00568    0.00090   -0.00462
O5    4    1.105081   -0.005207    0.146922    11.00000    0.03807    0.02749 =
         0.02713   -0.00478   -0.00461   -0.00108
O1    4    0.592395    0.219139    0.354562    11.00000    0.03144    0.06160 =
         0.02639   -0.01721    0.00361   -0.01324
O6    4    1.221162    0.062646    0.301133    11.00000    0.04594    0.03517 =
         0.03928   -0.01245   -0.00770   -0.01204
O2    4    0.644791    0.312605    0.515727    11.00000    0.03873    0.05827 =
         0.02595   -0.00876   -0.00471   -0.01372
O3    4    0.337718    0.298372    0.647116    11.00000    0.05506    0.07014 =
         0.02808   -0.01684    0.00456   -0.01098
N3    3    1.248928   -0.229274    0.267562    11.00000    0.03813    0.02948 =
         0.02588   -0.00502   -0.01070   -0.00299
N1    3    0.367316    0.216670    0.477551    11.00000    0.03101    0.05248 =
         0.02432   -0.01281    0.00048   -0.00871
O4    4    0.100407    0.232131    0.567209    11.00000    0.03530    0.11965 =
         0.05696   -0.02393    0.01192   -0.01932
N2    3    0.262892    0.253921    0.570696    11.00000    0.03889    0.04464 =
         0.03185   -0.00639    0.00536   -0.00410
C2    1    0.547428    0.257070    0.455628    11.00000    0.03164    0.02925 =
         0.02151   -0.00272   -0.00314   -0.00076
C4    1    1.189001   -0.044088    0.240293    11.00000    0.02527    0.03089 =
         0.02725   -0.00606    0.00157   -0.00655
C1    1    0.784918    0.233874    0.315932    11.00000    0.02944    0.04868 =
         0.03125   -0.00734    0.00213   -0.00552
C3    1    1.037482    0.190602    0.114913    11.00000    0.03666    0.02617 =
         0.03032    0.00022    0.00167   -0.00325
C5    1    0.696441    0.486128    0.107484    11.00000    0.04626    0.04707 =
         0.04454   -0.00069    0.00035    0.00450
C6    1    0.646744    0.079174    0.119069    11.00000    0.05220    0.06259 =
         0.04326   -0.01830    0.00457   -0.02262
N4    3    1.186953   -0.374450    0.226240    11.00000    0.05661    0.02865 =
         0.03729   -0.00943   -0.01475   -0.00195
O8    4    1.110549   -0.350835    0.140697    11.00000    0.11897    0.03676 =
         0.05565   -0.00772   -0.05101   -0.00954
O7    4    1.222222   -0.519010    0.281069    11.00000    0.15401    0.02667 =
         0.06892    0.00331   -0.05292   -0.01133
H3A   2    1.047356    0.200169    0.036403    11.00000    0.03261
H3B   2    1.118195    0.260186    0.144920    11.00000    0.03277
H1B   2    0.824221    0.338919    0.341142    11.00000    0.03537
H1A   2    0.855112    0.130360    0.348193    11.00000    0.03184
H6B   2    0.519100    0.105988    0.141873    11.00000    0.06680
H6A   2    0.688770   -0.033355    0.149846    11.00000    0.07259
H6C   2    0.648099    0.087115    0.043020    11.00000    0.07559
H5C   2    0.766122    0.568775    0.128213    11.00000    0.08091
H5B   2    0.704164    0.498326    0.032655    11.00000    0.07536
H5A   2    0.570146    0.516549    0.128670    11.00000    0.07658
H2    2    1.293084   -0.261948    0.324741    11.00000    0.04053
H1    2    0.311681    0.192045    0.430935    11.00000    0.04543
HKLF    4
 
REM  kx148_P-1 in P-1
REM R1 =  0.0387 for   2141 Fo > 4sig(Fo)  and  0.0499 for all   2622 data
REM    220 parameters refined using      0 restraints
 
END
 
WGHT      0.0512      0.1133
REM Highest difference peak  0.303,  deepest hole -0.242,  1-sigma level  0.048
Q1    1   0.9117  0.2425  0.1140  11.00000  0.05    0.30
Q2    1   0.9236  0.2094  0.1466  11.00000  0.05    0.28
Q3    1   0.7336  0.1565  0.1270  11.00000  0.05    0.23
Q4    1   0.7328  0.2332  0.2468  11.00000  0.05    0.22
Q5    1   0.7840  0.1960  0.2449  11.00000  0.05    0.21
Q6    1   1.1218 -0.4766  0.2881  11.00000  0.05    0.20
Q7    1   1.0592 -0.3617  0.2005  11.00000  0.05    0.20
Q8    1   0.1177  0.3371  0.5671  11.00000  0.05    0.18
Q9    1   1.2222 -0.2742  0.2518  11.00000  0.05    0.18
Q10   1   0.6345  0.2168  0.5010  11.00000  0.05    0.17
Q11   1   1.2096 -0.5036  0.3545  11.00000  0.05    0.17
Q12   1   1.0962 -0.0535  0.1962  11.00000  0.05    0.17
Q13   1   1.2746 -0.4945  0.2473  11.00000  0.05    0.16
Q14   1   0.6819  0.2076  0.3439  11.00000  0.05    0.16
Q15   1   0.3353  0.1968  0.5341  11.00000  0.05    0.16
Q16   1   0.6226  0.3266  0.3620  11.00000  0.05    0.16
Q17   1   0.2857  0.2577  0.7214  11.00000  0.05    0.16
Q18   1   0.6735  0.3463  0.5227  11.00000  0.05    0.15
Q19   1   1.2285 -0.1391  0.2417  11.00000  0.05    0.15
Q20   1   0.8701  0.0154  0.3593  11.00000  0.05    0.15
;
