#------------------------------------------------------------------------------
#$Date: 2019-11-23 08:32:36 +0200 (Sat, 23 Nov 2019) $
#$Revision: 232567 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/78/4347888.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4347888
loop_
_publ_author_name
'Li, Lei-Lei'
'Cao, Gao-Juan'
'Zhao, Jun-Wei'
'He, Huan'
'Yang, Bai-Feng'
'Yang, Guo-Yu'
_publ_section_title
;
 Lanthanide Germanate Cluster Organic Frameworks Based on {Ln8Ge12}
 Clusters: From One-Dimensional Chains to Two-Dimensional Layers and
 Three-Dimensional Frameworks.
;
_journal_issue                   11
_journal_name_full               'Inorganic chemistry'
_journal_page_first              5671
_journal_page_last               5683
_journal_paper_doi               10.1021/acs.inorgchem.6b00754
_journal_volume                  55
_journal_year                    2016
_chemical_formula_moiety         '0.5(C120 H168 Ge24 N12 Nd20 O144), 12(O)'
_chemical_formula_sum            'C60 H108 Ge12 N6 Nd10 O84'
_chemical_formula_weight         4571.00
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2016-05-04
_audit_creation_method
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_cell_angle_alpha                90.00
_cell_angle_beta                 106.542(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   16.425(6)
_cell_length_b                   18.842(6)
_cell_length_c                   19.184(7)
_cell_measurement_reflns_used    14001
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.4820
_cell_measurement_theta_min      2.1616
_cell_volume                     5691(3)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean none
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0387
_diffrn_reflns_av_unetI/netI     0.0436
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            41959
_diffrn_reflns_theta_full        27.49
_diffrn_reflns_theta_max         27.49
_diffrn_reflns_theta_min         2.21
_diffrn_source                   'fine-focus sealed tube'
_diffrn_standards_decay_%        none
_diffrn_standards_interval_count none
_diffrn_standards_interval_time  none
_diffrn_standards_number         none
_exptl_absorpt_coefficient_mu    7.701
_exptl_absorpt_correction_T_max  0.3378
_exptl_absorpt_correction_T_min  0.2136
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            PINK
_exptl_crystal_density_diffrn    2.667
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       BLOCK
_exptl_crystal_F_000             4332
_exptl_crystal_size_max          0.29
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.18
_refine_diff_density_max         2.579
_refine_diff_density_min         -1.327
_refine_diff_density_rms         0.212
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.078
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     775
_refine_ls_number_reflns         12980
_refine_ls_number_restraints     3162
_refine_ls_restrained_S_all      1.013
_refine_ls_R_factor_all          0.0494
_refine_ls_R_factor_gt           0.0373
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0498P)²+3.7023P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0879
_refine_ls_wR_factor_ref         0.0979
_reflns_number_gt                10630
_reflns_number_total             12980
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic6b00754_si_013.cif
_cod_data_source_block           12
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_exptl_absorpt_correction_type' value 'MULTI-SCAN' was
changed to 'multi-scan' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/ACS/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_cell_volume        5692(3)
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               4347888
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups, All O(H,H) groups
2. Uiso/Uaniso restraints and constraints
All non-hydrogen atoms have similar U: within 3.8A with sigma of 0.02 and sigma
for terminal atoms of 0.04
: with sigma of 0.01 and sigma for terminal atoms of 0.02
3.a Riding coordinates:
 O1W(H1A,H1B), O2W(H2A,H2B), O3W(H3A,H3B), O4W(H4A,H4B), O5W(H5A,H5B), O6W(H6A,
 H6B)
3.b Secondary CH2 refined with riding coordinates:
 C1(H1C,H1D), C2(H2C,H2D), C4(H4C,H4D), C5(H5C,H5D), C7(H7A,H7B), C8(H8A,H8B),
 C10(H10A,H10B), C11(H11A,H11B), C13(H13A,H13B), C14(H14A,H14B), C16(H16A,H16B),
  C17(H17A,H17B)
3.c Aromatic/amide H refined with riding coordinates:
 C21(H21), C22(H22), C23(H23), C26(H26), C27(H27), C28(H28)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x+1/2, y+1/2, -z+1/2'
3 '-x, -y, -z'
4 'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Nd1 Nd 0.30384(2) 0.407546(18) 0.802740(17) 0.02044(8) Uani 1 1 d U
Nd2 Nd 0.74477(2) 0.649214(17) 0.747211(16) 0.01965(8) Uani 1 1 d U
Nd3 Nd 0.548577(18) 0.307768(16) 1.078817(15) 0.01613(7) Uani 1 1 d U
Nd4 Nd 0.618786(17) 0.571248(16) 0.881088(15) 0.01340(7) Uani 1 1 d U
Nd5 Nd 0.676160(18) 0.383694(16) 0.950828(15) 0.01533(7) Uani 1 1 d U
Ge1 Ge 0.26151(4) 0.59137(3) 0.84831(3) 0.01771(13) Uani 1 1 d U
Ge2 Ge 0.22262(4) 0.46542(3) 0.94871(3) 0.01701(13) Uani 1 1 d U
Ge3 Ge 0.32156(4) 0.31691(3) 0.96627(3) 0.01763(13) Uani 1 1 d U
Ge4 Ge 0.47025(4) 0.28847(3) 0.88838(3) 0.01816(13) Uani 1 1 d U
Ge5 Ge 0.50966(4) 0.41240(3) 0.78672(3) 0.01835(13) Uani 1 1 d U
Ge6 Ge 0.40752(4) 0.56225(3) 0.76850(3) 0.01854(13) Uani 1 1 d U
O1 O 0.2134(3) 0.5107(2) 0.8661(2) 0.0247(9) Uani 1 1 d U
O2 O 0.2528(2) 0.3843(2) 0.9136(2) 0.0197(8) Uani 1 1 d U
O3 O 0.3638(3) 0.3004(2) 0.8910(2) 0.0240(9) Uani 1 1 d U
O4 O 0.4456(2) 0.3441(2) 0.8086(2) 0.0201(8) Uani 1 1 d U
O5 O 0.4157(2) 0.4682(2) 0.7584(2) 0.0220(9) Uani 1 1 d U
O6 O 0.3067(3) 0.5492(2) 0.7851(2) 0.0245(9) Uani 1 1 d U
O7 O 0.3335(2) 0.6215(2) 0.9279(2) 0.0208(8) Uani 1 1 d U
O8 O 0.3110(2) 0.4948(2) 1.0165(2) 0.0184(8) Uani 1 1 d U
O9 O 0.4084(2) 0.3526(2) 1.0322(2) 0.0213(8) Uani 1 1 d U
O10 O 0.5476(2) 0.3303(2) 0.9571(2) 0.0196(8) Uani 1 1 d U
O11 O 0.5748(2) 0.4536(2) 0.8637(2) 0.0205(8) Uani 1 1 d U
O12 O 0.4731(2) 0.5952(2) 0.8500(2) 0.0210(8) Uani 1 1 d U
O13 O 0.3437(3) 0.7091(2) 0.8048(2) 0.0323(10) Uani 1 1 d U
O14 O 0.2874(3) 0.8050(3) 0.7427(3) 0.0404(12) Uani 1 1 d U
O15 O 0.1726(3) 0.6083(3) 0.9771(3) 0.0335(11) Uani 1 1 d U
O16 O 0.0458(3) 0.6495(3) 0.9148(3) 0.0412(12) Uani 1 1 d U
O17 O 0.2532(3) 0.3583(2) 1.0565(2) 0.0230(9) Uani 1 1 d U
O18 O 0.1933(3) 0.3000(3) 1.1302(2) 0.0335(11) Uani 1 1 d U
O19 O 0.4706(3) 0.2100(2) 1.0031(3) 0.0342(11) Uani 1 1 d U
O20 O 0.4382(5) 0.0970(3) 1.0113(3) 0.0649(19) Uani 1 1 d U
O21 O 0.6193(3) 0.3210(2) 0.8314(2) 0.0261(9) Uani 1 1 d U
O22 O 0.6982(3) 0.2566(2) 0.7787(2) 0.0327(10) Uani 1 1 d U
O23 O 0.5487(3) 0.5544(2) 0.7469(2) 0.0244(9) Uani 1 1 d U
O24 O 0.6074(3) 0.5997(3) 0.6660(2) 0.0324(10) Uani 1 1 d U
O25 O 0.6295(3) 0.6790(2) 0.8091(2) 0.0233(9) Uani 1 1 d U
O26 O 0.5283(3) 0.7466(2) 0.8330(2) 0.0294(10) Uani 1 1 d U
O27 O 0.7328(3) 0.5445(2) 0.8242(2) 0.0242(9) Uani 1 1 d U
O28 O 0.7540(3) 0.4302(2) 0.8557(2) 0.0285(10) Uani 1 1 d U
O29 O 0.7713(3) 0.6426(3) 0.6280(2) 0.0333(10) Uani 1 1 d U
O30 O 0.8049(5) 0.5860(3) 0.5388(3) 0.0648(18) Uani 1 1 d U
O1W O 0.4111(3) 0.4600(2) 0.9129(2) 0.0255(9) Uani 1 1 d U
H1A H 0.4637 0.4651 0.9172 0.031 Uiso 1 1 d R
H1B H 0.4021 0.4743 0.9520 0.031 Uiso 1 1 d R
O2W O 0.3039(5) 0.3687(5) 0.6682(4) 0.094(2) Uani 1 1 d U
H2A H 0.2596 0.3470 0.6438 0.113 Uiso 1 1 d R
H2B H 0.3179 0.3983 0.6401 0.113 Uiso 1 1 d R
O3W O 0.1742(4) 0.4486(3) 0.7101(3) 0.0645(18) Uani 1 1 d U
H3A H 0.1256 0.4293 0.7010 0.077 Uiso 1 1 d R
H3B H 0.1798 0.4653 0.6705 0.077 Uiso 1 1 d R
O4W O 0.7318(3) 0.2572(3) 0.9663(2) 0.0344(11) Uani 1 1 d U
H4A H 0.7257 0.2244 0.9348 0.041 Uiso 1 1 d R
H4B H 0.7778 0.2498 0.9995 0.041 Uiso 1 1 d R
O5W O 0.6489(3) 0.1985(3) 1.0689(3) 0.0450(13) Uani 1 1 d U
H5A H 0.6987 0.2095 1.0679 0.054 Uiso 1 1 d R
H5B H 0.6452 0.1535 1.0691 0.054 Uiso 1 1 d R
O6W O 0.9016(3) 0.6201(3) 0.7929(3) 0.0459(13) Uani 1 1 d U
H6A H 0.9389 0.6336 0.8311 0.055 Uiso 1 1 d R
H6B H 0.9240 0.5888 0.7722 0.055 Uiso 1 1 d R
O7W O 0.5678(6) 0.6057(5) 0.5086(5) 0.112(3) Uani 1 1 d U
O8W O 0.5131(4) 0.1065(3) 0.1555(3) 0.0569(16) Uani 1 1 d U
O9W O 1.0038(5) 0.5165(4) 0.7418(4) 0.0765(19) Uani 1 1 d U
O10W O 0.1183(4) 0.7796(4) 0.9357(4) 0.0702(18) Uani 1 1 d U
O11W O 0.1652(10) 0.9593(9) 0.9337(8) 0.213(5) Uani 1 1 d U
O12W O 0.3357(8) 0.9943(6) 0.9307(4) 0.148(4) Uani 1 1 d U
N1 N 0.6228(4) 0.7501(3) 0.6899(3) 0.0318(12) Uani 1 1 d U
N2 N 0.4822(5) 0.8343(4) 0.6249(4) 0.0600(18) Uani 1 1 d U
N3 N 0.7745(3) 0.5246(3) 0.7034(3) 0.0253(11) Uani 1 1 d U
C1 C 0.1757(4) 0.6577(4) 0.8012(4) 0.0382(15) Uani 1 1 d U
H1C H 0.1261 0.6314 0.7740 0.046 Uiso 1 1 calc R
H1D H 0.1596 0.6846 0.8383 0.046 Uiso 1 1 calc R
C2 C 0.1994(6) 0.7096(6) 0.7500(6) 0.071(2) Uani 1 1 d U
H2C H 0.1953 0.6845 0.7050 0.085 Uiso 1 1 calc R
H2D H 0.1562 0.7463 0.7389 0.085 Uiso 1 1 calc R
C3 C 0.2814(5) 0.7451(4) 0.7711(4) 0.0409(17) Uani 1 1 d U
C4 C 0.1180(4) 0.4670(3) 0.9748(3) 0.0262(13) Uani 1 1 d U
H4C H 0.0902 0.4213 0.9636 0.031 Uiso 1 1 calc R
H4D H 0.1303 0.4747 1.0267 0.031 Uiso 1 1 calc R
C5 C 0.0588(4) 0.5244(4) 0.9348(4) 0.0328(15) Uani 1 1 d U
H5C H 0.0086 0.5244 0.9518 0.039 Uiso 1 1 calc R
H5D H 0.0408 0.5124 0.8835 0.039 Uiso 1 1 calc R
C6 C 0.0957(4) 0.6005(4) 0.9428(3) 0.0270(13) Uani 1 1 d U
C7 C 0.2622(4) 0.2330(3) 0.9834(4) 0.0294(13) Uani 1 1 d U
H7A H 0.2403 0.2078 0.9378 0.035 Uiso 1 1 calc R
H7B H 0.3024 0.2019 1.0164 0.035 Uiso 1 1 calc R
C8 C 0.1890(4) 0.2482(4) 1.0153(4) 0.0324(14) Uani 1 1 d U
H8A H 0.1396 0.2631 0.9769 0.039 Uiso 1 1 calc R
H8B H 0.1743 0.2053 1.0370 0.039 Uiso 1 1 calc R
C9 C 0.2136(4) 0.3056(3) 1.0722(3) 0.0252(13) Uani 1 1 d U
C10 C 0.4996(4) 0.1935(3) 0.8673(4) 0.0317(14) Uani 1 1 d U
H10A H 0.4835 0.1872 0.8150 0.038 Uiso 1 1 calc R
H10B H 0.5608 0.1881 0.8851 0.038 Uiso 1 1 calc R
C11 C 0.4576(5) 0.1349(4) 0.9007(4) 0.0440(18) Uani 1 1 d U
H11A H 0.3997 0.1289 0.8705 0.053 Uiso 1 1 calc R
H11B H 0.4874 0.0907 0.8993 0.053 Uiso 1 1 calc R
C12 C 0.4561(5) 0.1479(4) 0.9774(4) 0.0364(15) Uani 1 1 d U
C13 C 0.5435(4) 0.3903(3) 0.7005(3) 0.0268(13) Uani 1 1 d U
H13A H 0.4957 0.3976 0.6578 0.032 Uiso 1 1 calc R
H13B H 0.5887 0.4221 0.6974 0.032 Uiso 1 1 calc R
C14 C 0.5743(5) 0.3129(4) 0.7021(4) 0.0373(16) Uani 1 1 d U
H14A H 0.5259 0.2811 0.6921 0.045 Uiso 1 1 calc R
H14B H 0.6026 0.3062 0.6646 0.045 Uiso 1 1 calc R
C15 C 0.6354(4) 0.2951(3) 0.7759(3) 0.0259(13) Uani 1 1 d U
C16 C 0.3917(4) 0.6132(4) 0.6782(3) 0.0286(13) Uani 1 1 d U
H16A H 0.3345 0.6043 0.6475 0.034 Uiso 1 1 calc R
H16B H 0.3965 0.6636 0.6886 0.034 Uiso 1 1 calc R
C17 C 0.4542(5) 0.5937(4) 0.6360(4) 0.0400(16) Uani 1 1 d U
H17A H 0.4556 0.6314 0.6019 0.048 Uiso 1 1 calc R
H17B H 0.4352 0.5507 0.6083 0.048 Uiso 1 1 calc R
C18 C 0.5443(4) 0.5822(4) 0.6871(3) 0.0273(13) Uani 1 1 d U
C19 C 0.5743(4) 0.7277(3) 0.7943(3) 0.0241(12) Uani 1 1 d U
C20 C 0.5634(4) 0.7635(4) 0.7228(3) 0.0271(13) Uani 1 1 d U
C21 C 0.4930(5) 0.8054(4) 0.6905(4) 0.0420(16) Uani 1 1 d U
H21 H 0.4525 0.8134 0.7151 0.050 Uiso 1 1 calc R
C22 C 0.5429(6) 0.8219(5) 0.5938(5) 0.058(2) Uani 1 1 d U
H22 H 0.5376 0.8412 0.5481 0.069 Uiso 1 1 calc R
C23 C 0.6130(5) 0.7822(4) 0.6255(4) 0.0442(17) Uani 1 1 d U
H23 H 0.6550 0.7773 0.6020 0.053 Uiso 1 1 calc R
C24 C 0.7523(4) 0.4807(3) 0.8137(3) 0.0241(12) Uani 1 1 d U
C25 C 0.7733(4) 0.4673(3) 0.7436(3) 0.0251(12) Uani 1 1 d U
C26 C 0.7869(5) 0.4005(4) 0.7202(4) 0.0348(14) Uani 1 1 d U
H26 H 0.7861 0.3610 0.7490 0.042 Uiso 1 1 calc R
C27 C 0.8017(5) 0.3928(4) 0.6533(4) 0.0390(16) Uani 1 1 d U
H27 H 0.8100 0.3479 0.6364 0.047 Uiso 1 1 calc R
C28 C 0.8042(5) 0.4523(4) 0.6115(4) 0.0402(16) Uani 1 1 d U
H28 H 0.8161 0.4483 0.5671 0.048 Uiso 1 1 calc R
C29 C 0.7883(5) 0.5183(4) 0.6379(3) 0.0315(14) Uani 1 1 d U
C30 C 0.7883(5) 0.5871(4) 0.5976(4) 0.0367(15) Uani 1 1 d U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Nd Nd -0.1943 3.0179 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Ge5 Nd1 Ge3 104.840(17) . .
O1 Nd1 Ge3 82.76(8) . .
O1 Nd1 Ge5 129.98(8) . .
O2 Nd1 Ge3 29.51(9) . .
O2 Nd1 Ge5 129.75(9) . .
O2 Nd1 O1 55.65(12) . .
O2 Nd1 O3 58.80(13) . .
O2 Nd1 O4 113.04(12) . .
O2 Nd1 O6 107.37(13) . .
O2 Nd1 O2W 148.27(19) . .
O3 Nd1 Ge3 29.95(9) . .
O3 Nd1 Ge5 83.24(9) . .
O3 Nd1 O1 112.59(12) . .
O3 Nd1 O6 145.33(12) . .
O3 Nd1 O2W 107.8(2) . .
O4 Nd1 Ge3 83.80(9) . .
O4 Nd1 Ge5 29.88(9) . .
O4 Nd1 O1 148.03(12) . .
O4 Nd1 O3 56.80(13) . .
O4 Nd1 O6 114.52(12) . .
O4 Nd1 O2W 70.68(19) . .
O5 Nd1 Ge3 129.95(9) . .
O5 Nd1 Ge5 30.12(9) . .
O5 Nd1 O1 110.31(13) . .
O5 Nd1 O2 144.24(13) . .
O5 Nd1 O3 112.98(13) . .
O5 Nd1 O4 59.29(13) . .
O5 Nd1 O6 57.64(13) . .
O5 Nd1 O1W 72.70(13) . .
O5 Nd1 O2W 66.24(18) . .
O6 Nd1 Ge3 126.50(9) . .
O6 Nd1 Ge5 84.86(9) . .
O6 Nd1 O1 54.60(12) . .
O14 Nd1 Ge3 79.70(12) 2_546 .
O14 Nd1 Ge5 120.03(13) 2_546 .
O14 Nd1 O1 109.99(15) 2_546 .
O14 Nd1 O2 81.25(16) 2_546 .
O14 Nd1 O3 72.78(15) 2_546 .
O14 Nd1 O4 95.88(15) 2_546 .
O14 Nd1 O5 132.20(16) 2_546 .
O14 Nd1 O6 140.19(14) 2_546 .
O14 Nd1 O1W 144.51(15) 2_546 .
O14 Nd1 O2W 67.1(2) 2_546 .
O14 Nd1 O3W 71.15(18) 2_546 .
O1W Nd1 Ge3 65.39(10) . .
O1W Nd1 Ge5 66.51(10) . .
O1W Nd1 O1 73.03(13) . .
O1W Nd1 O2 71.66(13) . .
O1W Nd1 O3 73.70(13) . .
O1W Nd1 O4 74.99(13) . .
O1W Nd1 O6 71.68(13) . .
O1W Nd1 O2W 135.84(18) . .
O2W Nd1 Ge3 134.79(19) . .
O2W Nd1 Ge5 69.86(15) . .
O2W Nd1 O1 136.3(2) . .
O2W Nd1 O6 98.3(2) . .
O3W Nd1 Ge3 128.97(17) . .
O3W Nd1 Ge5 125.89(17) . .
O3W Nd1 O1 69.82(18) . .
O3W Nd1 O2 103.54(19) . .
O3W Nd1 O3 141.91(17) . .
O3W Nd1 O4 138.87(19) . .
O3W Nd1 O5 100.21(19) . .
O3W Nd1 O6 69.05(16) . .
O3W Nd1 O1W 136.71(18) . .
O3W Nd1 O2W 68.3(2) . .
O18 Nd2 Nd4 71.34(11) 3_667 .
O18 Nd2 O24 141.46(15) 3_667 .
O18 Nd2 O25 68.51(14) 3_667 .
O18 Nd2 O27 79.86(14) 3_667 .
O18 Nd2 O6W 69.66(16) 3_667 .
O18 Nd2 N1 99.70(17) 3_667 .
O18 Nd2 N3 126.53(16) 3_667 .
O22 Nd2 Nd4 139.76(12) 2_656 .
O22 Nd2 O18 77.69(15) 2_656 3_667
O22 Nd2 O24 121.93(15) 2_656 .
O22 Nd2 O25 107.54(15) 2_656 .
O22 Nd2 O27 155.34(15) 2_656 .
O22 Nd2 O29 70.00(16) 2_656 .
O22 Nd2 O6W 80.34(18) 2_656 .
O22 Nd2 N1 66.91(17) 2_656 .
O22 Nd2 N3 126.26(17) 2_656 .
O24 Nd2 Nd4 74.12(11) . .
O24 Nd2 O25 73.68(14) . .
O24 Nd2 N1 65.69(16) . .
O24 Nd2 N3 71.49(16) . .
O25 Nd2 Nd4 36.91(9) . .
O25 Nd2 N1 59.02(15) . .
O25 Nd2 N3 125.52(15) . .
O27 Nd2 Nd4 36.11(10) . .
O27 Nd2 O24 82.33(14) . .
O27 Nd2 O25 73.00(13) . .
O27 Nd2 O6W 82.42(16) . .
O27 Nd2 N1 127.51(15) . .
O27 Nd2 N3 62.01(15) . .
O29 Nd2 Nd4 147.23(12) . .
O29 Nd2 O18 140.62(16) . 3_667
O29 Nd2 O24 76.74(16) . .
O29 Nd2 O25 142.50(14) . .
O29 Nd2 O27 125.08(15) . .
O29 Nd2 O6W 83.02(17) . .
O29 Nd2 N1 87.98(16) . .
O29 Nd2 N3 63.26(16) . .
O6W Nd2 Nd4 111.00(13) . .
O6W Nd2 O24 140.77(16) . .
O6W Nd2 O25 134.31(15) . .
O6W Nd2 N1 147.16(18) . .
O6W Nd2 N3 69.41(17) . .
N1 Nd2 Nd4 93.41(12) . .
N3 Nd2 Nd4 93.17(12) . .
N3 Nd2 N1 132.84(17) . .
Nd4 Nd3 Nd5 116.89(2) 3_667 .
Ge4 Nd3 Nd4 101.480(18) . 3_667
Ge4 Nd3 Nd5 59.48(2) . .
O7 Nd3 Nd4 108.66(10) 3_667 3_667
O7 Nd3 Nd5 34.48(9) 3_667 .
O7 Nd3 Ge4 93.66(9) 3_667 .
O7 Nd3 O13 74.59(15) 3_667 3_667
O7 Nd3 O19 132.79(15) 3_667 .
O7 Nd3 O26 144.11(14) 3_667 3_667
O7 Nd3 O5W 84.28(16) 3_667 .
O9 Nd3 Nd4 35.57(9) . 3_667
O9 Nd3 Nd5 105.53(10) . .
O9 Nd3 Ge4 67.54(9) . .
O9 Nd3 O7 119.74(14) . 3_667
O9 Nd3 O13 139.72(15) . 3_667
O9 Nd3 O19 76.02(15) . .
O9 Nd3 O26 77.66(14) . 3_667
O9 Nd3 O5W 142.82(15) . .
O10 Nd3 Nd4 106.78(10) . 3_667
O10 Nd3 Nd5 34.18(9) . .
O10 Nd3 Ge4 25.85(9) . .
O10 Nd3 O7 67.91(13) . 3_667
O10 Nd3 O9 80.29(13) . .
O10 Nd3 O13 136.39(15) . 3_667
O10 Nd3 O19 72.37(15) . .
O10 Nd3 O26 147.80(14) . 3_667
O10 Nd3 O5W 84.23(15) . .
O12 Nd3 Nd4 35.64(10) 3_667 3_667
O12 Nd3 Nd5 105.90(10) 3_667 .
O12 Nd3 Ge4 127.30(9) 3_667 .
O12 Nd3 O7 81.80(14) 3_667 3_667
O12 Nd3 O9 69.78(13) 3_667 .
O12 Nd3 O10 118.04(14) 3_667 .
O12 Nd3 O13 76.25(14) 3_667 3_667
O12 Nd3 O19 141.06(15) 3_667 .
O12 Nd3 O26 75.40(14) 3_667 3_667
O12 Nd3 O5W 146.19(14) 3_667 .
O13 Nd3 Nd4 105.65(11) 3_667 3_667
O13 Nd3 Nd5 104.04(12) 3_667 .
O13 Nd3 Ge4 152.66(11) 3_667 .
O13 Nd3 O19 124.07(16) 3_667 .
O13 Nd3 O26 73.30(15) 3_667 3_667
O13 Nd3 O5W 70.38(15) 3_667 .
O19 Nd3 Nd4 106.37(12) . 3_667
O19 Nd3 Nd5 100.62(12) . .
O19 Nd3 Ge4 48.59(11) . .
O19 Nd3 O26 79.70(15) . 3_667
O19 Nd3 O5W 67.10(16) . .
O26 Nd3 Nd4 65.91(10) 3_667 3_667
O26 Nd3 Nd5 176.78(10) 3_667 .
O26 Nd3 Ge4 122.20(10) 3_667 .
O26 Nd3 O5W 99.57(16) 3_667 .
O5W Nd3 Nd4 165.31(13) . 3_667
O5W Nd3 Nd5 77.69(13) . .
O5W Nd3 Ge4 84.13(11) . .
Nd3 Nd4 Nd2 116.32(2) 3_667 .
Nd5 Nd4 Nd2 116.412(15) . .
Nd5 Nd4 Nd3 127.251(15) . 3_667
Ge3 Nd4 Nd2 104.00(3) 3_667 .
Ge3 Nd4 Nd3 61.276(19) 3_667 3_667
Ge3 Nd4 Nd5 106.38(2) 3_667 .
O8 Nd4 Nd2 120.86(10) 3_667 .
O8 Nd4 Nd3 111.15(10) 3_667 3_667
O8 Nd4 Nd5 36.35(9) 3_667 .
O8 Nd4 Ge3 70.40(10) 3_667 3_667
O8 Nd4 O9 82.93(14) 3_667 3_667
O8 Nd4 O12 122.83(14) 3_667 .
O8 Nd4 O17 74.43(13) 3_667 3_667
O8 Nd4 O23 139.84(14) 3_667 .
O8 Nd4 O25 143.66(13) 3_667 .
O8 Nd4 O27 90.45(14) 3_667 .
O9 Nd4 Nd2 118.02(11) 3_667 .
O9 Nd4 Nd3 36.28(9) 3_667 3_667
O9 Nd4 Nd5 113.53(10) 3_667 .
O9 Nd4 Ge3 26.07(9) 3_667 3_667
O9 Nd4 O12 70.96(13) 3_667 .
O9 Nd4 O17 68.66(14) 3_667 3_667
O9 Nd4 O23 132.87(14) 3_667 .
O9 Nd4 O25 87.27(14) 3_667 .
O9 Nd4 O27 139.65(14) 3_667 .
O11 Nd4 Nd2 116.96(10) . .
O11 Nd4 Nd3 112.71(10) . 3_667
O11 Nd4 Nd5 36.90(9) . .
O11 Nd4 Ge3 133.86(10) . 3_667
O11 Nd4 O8 70.84(13) . 3_667
O11 Nd4 O9 125.00(15) . 3_667
O11 Nd4 O12 83.90(14) . .
O11 Nd4 O17 139.76(14) . 3_667
O11 Nd4 O23 72.59(13) . .
O11 Nd4 O25 139.94(14) . .
O11 Nd4 O27 89.21(14) . .
O12 Nd4 Nd2 116.31(10) . .
O12 Nd4 Nd3 36.15(10) . 3_667
O12 Nd4 Nd5 113.71(10) . .
O12 Nd4 Ge3 96.84(10) . 3_667
O12 Nd4 O17 133.11(14) . 3_667
O12 Nd4 O23 68.15(14) . .
O12 Nd4 O25 85.99(14) . .
O12 Nd4 O27 140.80(14) . .
O17 Nd4 Nd2 65.96(10) 3_667 .
O17 Nd4 Nd3 98.25(10) 3_667 3_667
O17 Nd4 Nd5 103.63(10) 3_667 .
O17 Nd4 Ge3 44.09(10) 3_667 3_667
O17 Nd4 O23 129.49(13) 3_667 .
O17 Nd4 O25 69.41(13) 3_667 .
O23 Nd4 Nd2 63.96(10) . .
O23 Nd4 Nd3 97.78(10) . 3_667
O23 Nd4 Nd5 103.74(10) . .
O23 Nd4 Ge3 149.76(10) . 3_667
O25 Nd4 Nd2 38.23(10) . .
O25 Nd4 Nd3 78.09(10) . 3_667
O25 Nd4 Nd5 154.64(10) . .
O25 Nd4 Ge3 85.79(10) . 3_667
O25 Nd4 O23 67.67(14) . .
O27 Nd4 Nd2 36.65(10) . .
O27 Nd4 Nd3 152.93(10) . 3_667
O27 Nd4 Nd5 79.81(10) . .
O27 Nd4 Ge3 115.05(10) . 3_667
O27 Nd4 O17 71.21(14) . 3_667
O27 Nd4 O23 72.95(14) . .
O27 Nd4 O25 74.86(14) . .
Nd4 Nd5 Nd3 115.858(15) . .
O7 Nd5 Nd3 34.57(9) 3_667 .
O7 Nd5 Nd4 107.67(10) 3_667 .
O7 Nd5 O11 118.64(14) 3_667 .
O7 Nd5 O15 78.06(15) 3_667 3_667
O7 Nd5 O21 139.68(14) 3_667 .
O7 Nd5 O28 149.82(14) 3_667 .
O7 Nd5 O4W 88.23(14) 3_667 .
O8 Nd5 Nd3 102.15(10) 3_667 .
O8 Nd5 Nd4 35.75(9) 3_667 .
O8 Nd5 O7 78.87(13) 3_667 3_667
O8 Nd5 O10 114.24(14) 3_667 .
O8 Nd5 O11 69.16(13) 3_667 .
O8 Nd5 O15 78.12(14) 3_667 3_667
O8 Nd5 O21 132.73(13) 3_667 .
O8 Nd5 O28 80.69(14) 3_667 .
O8 Nd5 O4W 151.02(14) 3_667 .
O10 Nd5 Nd3 34.12(9) . .
O10 Nd5 Nd4 106.08(10) . .
O10 Nd5 O7 67.95(13) . 3_667
O10 Nd5 O11 79.41(14) . .
O10 Nd5 O15 139.68(15) . 3_667
O10 Nd5 O21 75.03(14) . .
O10 Nd5 O28 141.61(13) . .
O10 Nd5 O4W 83.79(15) . .
O11 Nd5 Nd3 104.39(10) . .
O11 Nd5 Nd4 35.74(9) . .
O11 Nd5 O15 138.07(15) . 3_667
O11 Nd5 O21 67.46(14) . .
O11 Nd5 O28 73.36(14) . .
O11 Nd5 O4W 138.97(14) . .
O15 Nd5 Nd3 107.60(12) 3_667 .
O15 Nd5 Nd4 104.38(11) 3_667 .
O15 Nd5 O21 126.19(15) 3_667 .
O15 Nd5 O28 76.17(15) 3_667 .
O15 Nd5 O4W 73.85(15) 3_667 .
O21 Nd5 Nd3 105.88(10) . .
O21 Nd5 Nd4 97.21(10) . .
O21 Nd5 O28 69.82(14) . .
O21 Nd5 O4W 72.12(14) . .
O28 Nd5 Nd3 175.61(10) . .
O28 Nd5 Nd4 64.60(10) . .
O4W Nd5 Nd3 79.81(11) . .
O4W Nd5 Nd4 163.45(11) . .
O4W Nd5 O28 99.36(15) . .
O1 Ge1 C1 109.9(3) . .
O6 Ge1 O1 92.5(2) . .
O6 Ge1 C1 111.4(3) . .
O7 Ge1 O1 109.67(19) . .
O7 Ge1 O6 115.63(19) . .
O7 Ge1 C1 115.3(3) . .
O1 Ge2 O2 92.11(19) . .
O1 Ge2 C4 111.8(2) . .
O2 Ge2 C4 118.3(2) . .
O8 Ge2 O1 110.92(18) . .
O8 Ge2 O2 106.86(18) . .
O8 Ge2 C4 114.7(2) . .
Nd1 Ge3 Nd4 112.68(3) . 3_667
O2 Ge3 Nd1 43.81(13) . .
O2 Ge3 Nd4 91.47(13) . 3_667
O2 Ge3 C7 113.9(2) . .
O3 Ge3 Nd1 47.12(14) . .
O3 Ge3 Nd4 133.88(13) . 3_667
O3 Ge3 O2 89.77(18) . .
O3 Ge3 C7 108.9(2) . .
O9 Ge3 Nd1 107.59(14) . .
O9 Ge3 Nd4 35.94(13) . 3_667
O9 Ge3 O2 112.69(19) . .
O9 Ge3 O3 103.00(19) . .
O9 Ge3 C7 122.5(2) . .
C7 Ge3 Nd1 129.2(2) . .
C7 Ge3 Nd4 112.5(2) . 3_667
O3 Ge4 Nd3 91.67(13) . .
O3 Ge4 O4 88.05(18) . .
O3 Ge4 C10 115.5(3) . .
O4 Ge4 Nd3 138.28(13) . .
O4 Ge4 C10 111.7(2) . .
O10 Ge4 Nd3 36.47(13) . .
O10 Ge4 O3 115.72(19) . .
O10 Ge4 O4 108.63(18) . .
O10 Ge4 C10 114.1(2) . .
C10 Ge4 Nd3 105.9(2) . .
O4 Ge5 Nd1 46.27(13) . .
O4 Ge5 O5 88.90(19) . .
O4 Ge5 C13 112.2(2) . .
O5 Ge5 Nd1 43.86(13) . .
O5 Ge5 C13 107.2(2) . .
O11 Ge5 Nd1 108.33(14) . .
O11 Ge5 O4 112.53(18) . .
O11 Ge5 O5 105.05(18) . .
O11 Ge5 C13 124.4(2) . .
C13 Ge5 Nd1 126.3(2) . .
O5 Ge6 C16 112.9(2) . .
O6 Ge6 O5 89.15(19) . .
O6 Ge6 C16 109.4(2) . .
O12 Ge6 O5 113.80(18) . .
O12 Ge6 O6 104.87(19) . .
O12 Ge6 C16 121.3(2) . .
Ge1 O1 Nd1 100.48(17) . .
Ge2 O1 Nd1 97.39(18) . .
Ge2 O1 Ge1 130.6(2) . .
Ge2 O2 Nd1 111.09(18) . .
Ge2 O2 Ge3 125.8(2) . .
Ge3 O2 Nd1 106.68(18) . .
Ge3 O3 Nd1 102.93(18) . .
Ge4 O3 Nd1 105.59(18) . .
Ge4 O3 Ge3 130.7(2) . .
Ge4 O4 Nd1 106.65(17) . .
Ge5 O4 Nd1 103.84(18) . .
Ge5 O4 Ge4 127.8(2) . .
Ge5 O5 Nd1 106.02(18) . .
Ge6 O5 Nd1 109.19(19) . .
Ge6 O5 Ge5 128.6(2) . .
Ge1 O6 Nd1 109.34(19) . .
Ge1 O6 Ge6 130.3(2) . .
Ge6 O6 Nd1 102.08(18) . .
Nd5 O7 Nd3 110.95(15) 3_667 3_667
Ge1 O7 Nd3 119.7(2) . 3_667
Ge1 O7 Nd5 128.8(2) . 3_667
Nd4 O8 Nd5 107.91(15) 3_667 3_667
Ge2 O8 Nd4 124.53(19) . 3_667
Ge2 O8 Nd5 119.86(19) . 3_667
Nd4 O9 Nd3 108.15(15) 3_667 .
Ge3 O9 Nd3 129.8(2) . .
Ge3 O9 Nd4 117.99(19) . 3_667
Nd3 O10 Nd5 111.70(15) . .
Ge4 O10 Nd3 117.68(19) . .
Ge4 O10 Nd5 128.5(2) . .
Nd4 O11 Nd5 107.35(15) . .
Ge5 O11 Nd4 129.6(2) . .
Ge5 O11 Nd5 119.0(2) . .
Nd4 O12 Nd3 108.22(15) . 3_667
Ge6 O12 Nd3 129.6(2) . 3_667
Ge6 O12 Nd4 119.1(2) . .
C3 O13 Nd3 145.2(5) . 3_667
C3 O14 Nd1 137.8(5) . 2_556
C6 O15 Nd5 176.3(5) . 3_667
C9 O17 Nd4 136.3(4) . 3_667
C9 O18 Nd2 132.0(4) . 3_667
C12 O19 Nd3 158.2(5) . .
C15 O21 Nd5 146.8(4) . .
C15 O22 Nd2 150.1(4) . 2_646
C18 O23 Nd4 141.1(4) . .
C18 O24 Nd2 124.8(4) . .
Nd4 O25 Nd2 104.86(15) . .
C19 O25 Nd2 129.2(4) . .
C19 O25 Nd4 123.8(4) . .
C19 O26 Nd3 139.7(4) . 3_667
Nd4 O27 Nd2 107.23(15) . .
C24 O27 Nd2 125.8(4) . .
C24 O27 Nd4 121.1(4) . .
C24 O28 Nd5 140.5(4) . .
C30 O29 Nd2 126.4(4) . .
C20 N1 Nd2 119.4(4) . .
C20 N1 C23 116.0(6) . .
C23 N1 Nd2 124.2(5) . .
C22 N2 C21 116.1(7) . .
C25 N3 Nd2 120.9(4) . .
C25 N3 C29 120.3(6) . .
C29 N3 Nd2 118.7(4) . .
C2 C1 Ge1 116.1(6) . .
C3 C2 C1 120.4(8) . .
O13 C3 O14 123.7(7) . .
O13 C3 C2 117.0(7) . .
O14 C3 C2 117.9(7) . .
C5 C4 Ge2 111.9(4) . .
C4 C5 C6 115.9(5) . .
O15 C6 C5 117.8(6) . .
O16 C6 O15 125.3(6) . .
O16 C6 C5 116.8(6) . .
C8 C7 Ge3 114.1(5) . .
C9 C8 C7 110.2(5) . .
O17 C9 C8 116.1(5) . .
O18 C9 O17 124.1(6) . .
O18 C9 C8 119.8(6) . .
C11 C10 Ge4 114.3(5) . .
C12 C11 C10 115.3(6) . .
O19 C12 C11 118.6(7) . .
O20 C12 O19 123.9(7) . .
O20 C12 C11 117.4(7) . .
C14 C13 Ge5 111.1(4) . .
C15 C14 C13 110.6(5) . .
O21 C15 C14 117.3(6) . .
O22 C15 O21 123.7(6) . .
O22 C15 C14 119.0(6) . .
C17 C16 Ge6 114.8(5) . .
C16 C17 C18 111.5(6) . .
O23 C18 O24 124.7(6) . .
O23 C18 C17 116.2(6) . .
O24 C18 C17 119.1(6) . .
O25 C19 C20 115.1(5) . .
O26 C19 O25 126.1(6) . .
O26 C19 C20 118.8(6) . .
N1 C20 C19 116.0(6) . .
N1 C20 C21 121.7(6) . .
C21 C20 C19 122.2(6) . .
N2 C21 C20 121.4(7) . .
N2 C22 C23 123.1(8) . .
N1 C23 C22 121.5(7) . .
O27 C24 C25 115.5(5) . .
O28 C24 O27 125.5(6) . .
O28 C24 C25 118.9(6) . .
N3 C25 C24 115.3(5) . .
N3 C25 C26 121.5(6) . .
C26 C25 C24 123.1(6) . .
C25 C26 C27 119.2(7) . .
C26 C27 C28 119.7(7) . .
C29 C28 C27 118.2(7) . .
N3 C29 C28 121.0(6) . .
N3 C29 C30 115.3(6) . .
C28 C29 C30 123.6(6) . .
O29 C30 C29 116.2(6) . .
O30 C30 O29 124.8(7) . .
O30 C30 C29 119.0(7) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Nd1 Ge3 3.5104(12) .
Nd1 Ge5 3.4818(14) .
Nd1 O1 2.913(5) .
Nd1 O2 2.537(4) .
Nd1 O3 2.639(4) .
Nd1 O4 2.591(4) .
Nd1 O5 2.510(4) .
Nd1 O6 2.692(5) .
Nd1 O14 2.448(5) 2_546
Nd1 O1W 2.535(4) .
Nd1 O2W 2.683(7) .
Nd1 O3W 2.477(5) .
Nd2 Nd4 4.0079(10) .
Nd2 O18 2.474(5) 3_667
Nd2 O22 2.342(4) 2_656
Nd2 O24 2.528(5) .
Nd2 O25 2.566(4) .
Nd2 O27 2.505(4) .
Nd2 O29 2.451(4) .
Nd2 O6W 2.534(5) .
Nd2 N1 2.753(6) .
Nd2 N3 2.587(5) .
Nd3 Nd4 3.8144(10) 3_667
Nd3 Nd5 3.9239(10) .
Nd3 Ge4 3.5296(13) .
Nd3 O7 2.384(4) 3_667
Nd3 O9 2.375(4) .
Nd3 O10 2.369(4) .
Nd3 O12 2.369(4) 3_667
Nd3 O13 2.443(4) 3_667
Nd3 O19 2.467(4) .
Nd3 O26 2.594(4) 3_667
Nd3 O5W 2.676(5) .
Nd4 Nd3 3.8143(10) 3_667
Nd4 Nd5 3.8011(11) .
Nd4 Ge3 3.5132(11) 3_667
Nd4 O8 2.334(4) 3_667
Nd4 O9 2.335(4) 3_667
Nd4 O11 2.326(4) .
Nd4 O12 2.340(4) .
Nd4 O17 2.486(4) 3_667
Nd4 O23 2.523(4) .
Nd4 O25 2.490(4) .
Nd4 O27 2.473(4) .
Nd5 O7 2.379(4) 3_667
Nd5 O8 2.367(4) 3_667
Nd5 O10 2.372(4) .
Nd5 O11 2.391(4) .
Nd5 O15 2.480(4) 3_667
Nd5 O21 2.510(4) .
Nd5 O28 2.658(4) .
Nd5 O4W 2.539(5) .
Ge1 O1 1.790(4) .
Ge1 O6 1.780(4) .
Ge1 O7 1.739(4) .
Ge1 C1 1.908(7) .
Ge2 O1 1.768(4) .
Ge2 O2 1.796(4) .
Ge2 O8 1.741(4) .
Ge2 C4 1.922(6) .
Ge3 Nd4 3.5131(11) 3_667
Ge3 O2 1.805(4) .
Ge3 O3 1.798(4) .
Ge3 O9 1.748(4) .
Ge3 C7 1.935(6) .
Ge4 O3 1.777(4) .
Ge4 O4 1.803(4) .
Ge4 O10 1.738(4) .
Ge4 C10 1.926(6) .
Ge5 O4 1.787(4) .
Ge5 O5 1.818(4) .
Ge5 O11 1.740(4) .
Ge5 C13 1.933(6) .
Ge6 O5 1.791(4) .
Ge6 O6 1.789(4) .
Ge6 O12 1.741(4) .
Ge6 C16 1.932(6) .
O7 Nd3 2.384(4) 3_667
O7 Nd5 2.379(4) 3_667
O8 Nd4 2.334(4) 3_667
O8 Nd5 2.367(4) 3_667
O9 Nd4 2.335(4) 3_667
O12 Nd3 2.369(4) 3_667
O13 Nd3 2.443(4) 3_667
O13 C3 1.243(8) .
O14 Nd1 2.448(5) 2_556
O14 C3 1.269(9) .
O15 Nd5 2.480(4) 3_667
O15 C6 1.255(7) .
O16 C6 1.249(8) .
O17 Nd4 2.486(4) 3_667
O17 C9 1.269(7) .
O18 Nd2 2.474(5) 3_667
O18 C9 1.253(7) .
O19 C12 1.266(8) .
O20 C12 1.239(9) .
O21 C15 1.264(7) .
O22 Nd2 2.342(4) 2_646
O22 C15 1.251(7) .
O23 C18 1.243(7) .
O24 C18 1.260(8) .
O25 C19 1.265(7) .
O26 Nd3 2.594(4) 3_667
O26 C19 1.252(7) .
O27 C24 1.276(7) .
O28 C24 1.240(7) .
O29 C30 1.266(9) .
O30 C30 1.234(8) .
N1 C20 1.330(8) .
N1 C23 1.344(9) .
N2 C21 1.335(10) .
N2 C22 1.321(11) .
N3 C25 1.331(8) .
N3 C29 1.345(8) .
C1 C2 1.513(12) .
C2 C3 1.455(12) .
C4 C5 1.511(9) .
C5 C6 1.547(9) .
C7 C8 1.523(9) .
C8 C9 1.509(9) .
C10 C11 1.536(10) .
C11 C12 1.501(10) .
C13 C14 1.541(9) .
C14 C15 1.521(9) .
C16 C17 1.522(10) .
C17 C18 1.540(9) .
C19 C20 1.492(8) .
C20 C21 1.392(9) .
C22 C23 1.362(11) .
C24 C25 1.502(8) .
C25 C26 1.376(9) .
C26 C27 1.379(10) .
C27 C28 1.386(10) .
C28 C29 1.396(10) .
C29 C30 1.508(10) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Nd1 Ge3 O2 Ge2 -132.8(3) . .
Nd1 Ge3 O3 Ge4 124.2(4) . .
Nd1 Ge3 O9 Nd3 -101.1(2) . .
Nd1 Ge3 O9 Nd4 104.58(18) . 3_667
Nd1 Ge3 C7 C8 -101.0(5) . .
Nd1 Ge5 O4 Ge4 -124.4(3) . .
Nd1 Ge5 O5 Ge6 131.8(4) . .
Nd1 Ge5 O11 Nd4 -96.4(2) . .
Nd1 Ge5 O11 Nd5 109.11(18) . .
Nd1 Ge5 C13 C14 -96.3(5) . .
Nd1 O14 C3 O13 -162.6(5) 2_556 .
Nd1 O14 C3 C2 31.2(12) 2_556 .
Nd2 Nd4 Nd5 Nd3 -178.894(9) . .
Nd2 Nd4 Nd5 O7 144.81(10) . 3_667
Nd2 Nd4 Nd5 O8 106.94(17) . 3_667
Nd2 Nd4 Nd5 O10 -143.75(9) . .
Nd2 Nd4 Nd5 O11 -100.46(17) . .
Nd2 Nd4 Nd5 O15 63.00(12) . 3_667
Nd2 Nd4 Nd5 O21 -67.31(10) . .
Nd2 Nd4 Nd5 O28 -3.74(11) . .
Nd2 Nd4 Nd5 O4W -18.6(4) . .
Nd2 Nd4 O11 Nd5 98.85(14) . .
Nd2 Nd4 O11 Ge5 -57.9(3) . .
Nd2 Nd4 O12 Nd3 -99.31(14) . 3_667
Nd2 Nd4 O12 Ge6 62.6(2) . .
Nd2 Nd4 O23 C18 -28.1(6) . .
Nd2 Nd4 O25 C19 164.6(5) . .
Nd2 Nd4 O27 C24 -154.5(5) . .
Nd2 O18 C9 O17 -26.2(10) 3_667 .
Nd2 O18 C9 C8 155.3(5) 3_667 .
Nd2 O22 C15 O21 122.5(8) 2_646 .
Nd2 O22 C15 C14 -58.0(12) 2_646 .
Nd2 O24 C18 O23 -36.1(9) . .
Nd2 O24 C18 C17 145.3(5) . .
Nd2 O25 C19 O26 -168.2(5) . .
Nd2 O25 C19 C20 13.4(8) . .
Nd2 O27 C24 O28 172.7(4) . .
Nd2 O27 C24 C25 -8.2(7) . .
Nd2 O29 C30 O30 -176.8(6) . .
Nd2 O29 C30 C29 2.9(9) . .
Nd2 N1 C20 C19 6.9(8) . .
Nd2 N1 C20 C21 -169.7(5) . .
Nd2 N1 C23 C22 168.0(7) . .
Nd2 N3 C25 C24 1.1(7) . .
Nd2 N3 C25 C26 178.3(5) . .
Nd2 N3 C29 C28 -179.6(5) . .
Nd2 N3 C29 C30 2.4(8) . .
Nd3 Nd4 Nd5 Nd3 -0.259(18) 3_667 .
Nd3 Nd4 Nd5 O7 -36.55(10) 3_667 3_667
Nd3 Nd4 Nd5 O8 -74.42(17) 3_667 3_667
Nd3 Nd4 Nd5 O10 34.89(10) 3_667 .
Nd3 Nd4 Nd5 O11 78.17(17) 3_667 .
Nd3 Nd4 Nd5 O15 -118.37(12) 3_667 3_667
Nd3 Nd4 Nd5 O21 111.33(10) 3_667 .
Nd3 Nd4 Nd5 O28 174.89(11) 3_667 .
Nd3 Nd4 Nd5 O4W 160.0(4) 3_667 .
Nd3 Nd4 O11 Nd5 -122.37(12) 3_667 .
Nd3 Nd4 O11 Ge5 80.9(3) 3_667 .
Nd3 Nd4 O12 Ge6 161.9(3) 3_667 .
Nd3 Nd4 O23 C18 87.5(7) 3_667 .
Nd3 Nd4 O25 Nd2 -179.45(14) 3_667 .
Nd3 Nd4 O25 C19 -14.8(4) 3_667 .
Nd3 Nd4 O27 Nd2 -4.1(3) 3_667 .
Nd3 Nd4 O27 C24 -158.6(3) 3_667 .
Nd3 Nd5 O10 Ge4 -163.0(4) . .
Nd3 Nd5 O11 Nd4 114.47(13) . .
Nd3 Nd5 O11 Ge5 -85.9(2) . .
Nd3 Nd5 O21 C15 -145.5(7) . .
Nd3 Nd5 O28 C24 87.8(14) . .
Nd3 Ge4 O3 Nd1 123.90(13) . .
Nd3 Ge4 O3 Ge3 0.8(3) . .
Nd3 Ge4 O4 Nd1 -75.6(2) . .
Nd3 Ge4 O4 Ge5 47.6(4) . .
Nd3 Ge4 O10 Nd5 162.1(4) . .
Nd3 Ge4 C10 C11 63.2(5) . .
Nd3 O13 C3 O14 81.2(12) 3_667 .
Nd3 O13 C3 C2 -112.4(9) 3_667 .
Nd3 O19 C12 O20 73.6(16) . .
Nd3 O19 C12 C11 -108.6(12) . .
Nd3 O26 C19 O25 -34.6(10) 3_667 .
Nd3 O26 C19 C20 143.8(5) 3_667 .
Nd4 Nd2 O24 C18 13.4(5) . .
Nd4 Nd2 O25 C19 -163.5(6) . .
Nd4 Nd2 O27 C24 152.9(5) . .
Nd4 Nd2 O29 C30 -49.3(7) . .
Nd4 Nd2 N1 C20 13.2(5) . .
Nd4 Nd2 N1 C23 -159.3(6) . .
Nd4 Nd2 N3 C25 -22.3(5) . .
Nd4 Nd2 N3 C29 155.4(5) . .
Nd4 Nd3 Nd5 Nd4 0.232(16) 3_667 .
Nd4 Nd3 Nd5 O7 83.99(17) 3_667 3_667
Nd4 Nd3 Nd5 O8 35.33(9) 3_667 3_667
Nd4 Nd3 Nd5 O10 -80.19(18) 3_667 .
Nd4 Nd3 Nd5 O11 -35.98(10) 3_667 .
Nd4 Nd3 Nd5 O15 116.55(12) 3_667 3_667
Nd4 Nd3 Nd5 O21 -106.21(10) 3_667 .
Nd4 Nd3 Nd5 O28 -94.6(12) 3_667 .
Nd4 Nd3 Nd5 O4W -174.16(10) 3_667 .
Nd4 Nd3 Ge4 O3 -28.83(14) 3_667 .
Nd4 Nd3 Ge4 O4 60.10(19) 3_667 .
Nd4 Nd3 Ge4 O10 104.9(2) 3_667 .
Nd4 Nd3 Ge4 C10 -146.0(2) 3_667 .
Nd4 Nd3 O9 Ge3 -156.2(4) 3_667 .
Nd4 Nd3 O10 Nd5 113.37(14) 3_667 .
Nd4 Nd3 O10 Ge4 -81.6(2) 3_667 .
Nd4 Nd3 O19 C12 -148.1(13) 3_667 .
Nd4 Nd5 O10 Nd3 -112.56(14) . .
Nd4 Nd5 O10 Ge4 84.5(3) . .
Nd4 Nd5 O11 Ge5 159.7(3) . .
Nd4 Nd5 O21 C15 95.0(7) . .
Nd4 Nd5 O28 C24 -9.1(6) . .
Nd4 Ge3 O2 Nd1 122.03(13) 3_667 .
Nd4 Ge3 O2 Ge2 -10.8(3) 3_667 .
Nd4 Ge3 O3 Nd1 -80.62(18) 3_667 .
Nd4 Ge3 O3 Ge4 43.5(4) 3_667 .
Nd4 Ge3 O9 Nd3 154.3(4) 3_667 .
Nd4 Ge3 C7 C8 50.3(5) 3_667 .
Nd4 O17 C9 O18 47.7(9) 3_667 .
Nd4 O17 C9 C8 -133.8(5) 3_667 .
Nd4 O23 C18 O24 50.9(11) . .
Nd4 O23 C18 C17 -130.4(6) . .
Nd4 O25 C19 O26 31.1(9) . .
Nd4 O25 C19 C20 -147.3(4) . .
Nd4 O27 C24 O28 -37.8(8) . .
Nd4 O27 C24 C25 141.3(4) . .
Nd5 Nd3 Ge4 O3 -143.41(14) . .
Nd5 Nd3 Ge4 O4 -54.48(19) . .
Nd5 Nd3 Ge4 O10 -9.7(2) . .
Nd5 Nd3 Ge4 C10 99.4(2) . .
Nd5 Nd3 O9 Nd4 -114.73(13) . 3_667
Nd5 Nd3 O9 Ge3 89.0(3) . .
Nd5 Nd3 O10 Ge4 165.0(3) . .
Nd5 Nd3 O19 C12 89.5(13) . .
Nd5 Nd4 O11 Ge5 -156.8(4) . .
Nd5 Nd4 O12 Nd3 121.30(12) . 3_667
Nd5 Nd4 O12 Ge6 -76.8(2) . .
Nd5 Nd4 O23 C18 -141.0(7) . .
Nd5 Nd4 O25 Nd2 -1.3(3) . .
Nd5 Nd4 O25 C19 163.4(4) . .
Nd5 Nd4 O27 Nd2 176.98(14) . .
Nd5 Nd4 O27 C24 22.5(4) . .
Nd5 O15 C6 O16 156(7) 3_667 .
Nd5 O15 C6 C5 -23(8) 3_667 .
Nd5 O21 C15 O22 45.5(11) . .
Nd5 O21 C15 C14 -134.0(6) . .
Nd5 O28 C24 O27 32.5(10) . .
Nd5 O28 C24 C25 -146.5(5) . .
Ge1 C1 C2 C3 -44.4(12) . .
Ge2 C4 C5 C6 -55.1(7) . .
Ge3 Nd1 Ge5 O4 46.73(17) . .
Ge3 Nd1 Ge5 O5 -150.12(18) . .
Ge3 Nd1 Ge5 O11 -57.25(14) . .
Ge3 Nd1 Ge5 C13 133.6(2) . .
Ge3 Nd1 O1 Ge1 134.00(15) . .
Ge3 Nd1 O1 Ge2 0.25(13) . .
Ge3 Nd1 O2 Ge2 140.3(3) . .
Ge3 Nd1 O3 Ge4 -139.4(3) . .
Ge3 Nd1 O4 Ge4 2.18(15) . .
Ge3 Nd1 O4 Ge5 -134.92(15) . .
Ge3 Nd1 O5 Ge5 38.9(2) . .
Ge3 Nd1 O5 Ge6 -103.00(16) . .
Ge3 Nd1 O6 Ge1 -31.9(2) . .
Ge3 Nd1 O6 Ge6 108.98(15) . .
Ge3 Nd4 Nd5 Nd3 65.80(3) 3_667 .
Ge3 Nd4 Nd5 O7 29.50(10) 3_667 3_667
Ge3 Nd4 Nd5 O8 -8.37(16) 3_667 3_667
Ge3 Nd4 Nd5 O10 100.95(10) 3_667 .
Ge3 Nd4 Nd5 O11 144.23(17) 3_667 .
Ge3 Nd4 Nd5 O15 -52.31(12) 3_667 3_667
Ge3 Nd4 Nd5 O21 177.38(10) 3_667 .
Ge3 Nd4 Nd5 O28 -119.05(11) 3_667 .
Ge3 Nd4 Nd5 O4W -134.0(4) 3_667 .
Ge3 Nd4 O11 Nd5 -51.1(2) 3_667 .
Ge3 Nd4 O11 Ge5 152.19(18) 3_667 .
Ge3 Nd4 O12 Nd3 10.03(15) 3_667 3_667
Ge3 Nd4 O12 Ge6 172.0(2) 3_667 .
Ge3 Nd4 O23 C18 44.3(8) 3_667 .
Ge3 Nd4 O25 Nd2 119.04(12) 3_667 .
Ge3 Nd4 O25 C19 -76.3(4) 3_667 .
Ge3 Nd4 O27 Nd2 -79.59(14) 3_667 .
Ge3 Nd4 O27 C24 125.9(4) 3_667 .
Ge3 C7 C8 C9 -40.8(7) . .
Ge4 Nd3 Nd5 Nd4 87.94(2) . .
Ge4 Nd3 Nd5 O7 171.70(17) . 3_667
Ge4 Nd3 Nd5 O8 123.04(9) . 3_667
Ge4 Nd3 Nd5 O10 7.52(18) . .
Ge4 Nd3 Nd5 O11 51.73(10) . .
Ge4 Nd3 Nd5 O15 -155.74(12) . 3_667
Ge4 Nd3 Nd5 O21 -18.50(10) . .
Ge4 Nd3 Nd5 O28 -6.9(12) . .
Ge4 Nd3 Nd5 O4W -86.45(10) . .
Ge4 Nd3 O9 Nd4 -161.47(18) . 3_667
Ge4 Nd3 O9 Ge3 42.3(2) . .
Ge4 Nd3 O10 Nd5 -165.0(3) . .
Ge4 Nd3 O19 C12 120.9(13) . .
Ge4 C10 C11 C12 -42.4(8) . .
Ge5 Nd1 Ge3 Nd4 84.32(2) . 3_667
Ge5 Nd1 Ge3 O2 151.03(18) . .
Ge5 Nd1 Ge3 O3 -45.26(18) . .
Ge5 Nd1 Ge3 O9 46.32(14) . .
Ge5 Nd1 Ge3 C7 -124.4(3) . .
Ge5 Nd1 O1 Ge1 30.7(2) . .
Ge5 Nd1 O1 Ge2 -103.07(15) . .
Ge5 Nd1 O2 Ge2 102.84(17) . .
Ge5 Nd1 O2 Ge3 -37.5(2) . .
Ge5 Nd1 O3 Ge3 136.25(16) . .
Ge5 Nd1 O3 Ge4 -3.13(15) . .
Ge5 Nd1 O4 Ge4 137.1(3) . .
Ge5 Nd1 O5 Ge6 -141.9(3) . .
Ge5 Nd1 O6 Ge1 -136.53(17) . .
Ge5 Nd1 O6 Ge6 4.31(14) . .
Ge5 C13 C14 C15 -46.4(7) . .
Ge6 C16 C17 C18 -39.3(8) . .
O1 Nd1 Ge3 Nd4 -45.20(8) . 3_667
O1 Nd1 Ge3 O2 21.52(19) . .
O1 Nd1 Ge3 O3 -174.78(19) . .
O1 Nd1 Ge3 O9 -83.20(16) . .
O1 Nd1 Ge3 C7 106.0(3) . .
O1 Nd1 Ge5 O4 139.7(2) . .
O1 Nd1 Ge5 O5 -57.1(2) . .
O1 Nd1 Ge5 O11 35.74(17) . .
O1 Nd1 Ge5 C13 -133.4(3) . .
O1 Nd1 O2 Ge2 -13.50(14) . .
O1 Nd1 O2 Ge3 -153.9(2) . .
O1 Nd1 O3 Ge3 5.6(2) . .
O1 Nd1 O3 Ge4 -133.77(16) . .
O1 Nd1 O4 Ge4 67.8(3) . .
O1 Nd1 O4 Ge5 -69.3(3) . .
O1 Nd1 O5 Ge5 136.66(16) . .
O1 Nd1 O5 Ge6 -5.3(2) . .
O1 Nd1 O6 Ge1 12.25(14) . .
O1 Nd1 O6 Ge6 153.1(2) . .
O1 Ge1 O6 Nd1 -16.35(18) . .
O1 Ge1 O6 Ge6 -142.4(3) . .
O1 Ge1 O7 Nd3 152.8(2) . 3_667
O1 Ge1 O7 Nd5 -36.7(3) . 3_667
O1 Ge1 C1 C2 -150.0(6) . .
O1 Ge2 O2 Nd1 18.54(19) . .
O1 Ge2 O2 Ge3 149.6(3) . .
O1 Ge2 O8 Nd4 -156.3(2) . 3_667
O1 Ge2 O8 Nd5 58.0(3) . 3_667
O1 Ge2 C4 C5 -18.3(5) . .
O2 Nd1 Ge3 Nd4 -66.71(18) . 3_667
O2 Nd1 Ge3 O3 163.7(3) . .
O2 Nd1 Ge3 O9 -104.7(2) . .
O2 Nd1 Ge3 C7 84.5(3) . .
O2 Nd1 Ge5 O4 64.8(2) . .
O2 Nd1 Ge5 O5 -132.0(2) . .
O2 Nd1 Ge5 O11 -39.17(18) . .
O2 Nd1 Ge5 C13 151.7(3) . .
O2 Nd1 O1 Ge1 146.6(2) . .
O2 Nd1 O1 Ge2 12.89(14) . .
O2 Nd1 O3 Ge3 -9.30(14) . .
O2 Nd1 O3 Ge4 -148.7(2) . .
O2 Nd1 O4 Ge4 6.2(2) . .
O2 Nd1 O4 Ge5 -130.88(16) . .
O2 Nd1 O5 Ge5 77.7(3) . .
O2 Nd1 O5 Ge6 -64.2(3) . .
O2 Nd1 O6 Ge1 -6.4(2) . .
O2 Nd1 O6 Ge6 134.44(16) . .
O2 Ge2 O1 Nd1 -15.10(16) . .
O2 Ge2 O1 Ge1 -125.8(3) . .
O2 Ge2 O8 Nd4 -57.3(3) . 3_667
O2 Ge2 O8 Nd5 157.1(2) . 3_667
O2 Ge2 C4 C5 -123.4(4) . .
O2 Ge3 O3 Nd1 11.20(17) . .
O2 Ge3 O3 Ge4 135.4(3) . .
O2 Ge3 O9 Nd3 -147.6(2) . .
O2 Ge3 O9 Nd4 58.1(3) . 3_667
O2 Ge3 C7 C8 -52.1(5) . .
O3 Nd1 Ge3 Nd4 129.58(18) . 3_667
O3 Nd1 Ge3 O2 -163.7(3) . .
O3 Nd1 Ge3 O9 91.6(2) . .
O3 Nd1 Ge3 C7 -79.2(3) . .
O3 Nd1 Ge5 O4 25.81(19) . .
O3 Nd1 Ge5 O5 -171.0(2) . .
O3 Nd1 Ge5 O11 -78.17(17) . .
O3 Nd1 Ge5 C13 112.7(3) . .
O3 Nd1 O1 Ge1 131.18(15) . .
O3 Nd1 O1 Ge2 -2.6(2) . .
O3 Nd1 O2 Ge2 149.8(2) . .
O3 Nd1 O2 Ge3 9.43(15) . .
O3 Nd1 O4 Ge4 -11.78(15) . .
O3 Nd1 O4 Ge5 -148.9(2) . .
O3 Nd1 O5 Ge5 9.7(2) . .
O3 Nd1 O5 Ge6 -132.25(17) . .
O3 Nd1 O6 Ge1 -66.3(3) . .
O3 Nd1 O6 Ge6 74.6(3) . .
O3 Ge3 O2 Nd1 -11.87(18) . .
O3 Ge3 O2 Ge2 -144.6(3) . .
O3 Ge3 O9 Nd3 -52.4(3) . .
O3 Ge3 O9 Nd4 153.3(2) . 3_667
O3 Ge3 C7 C8 -150.5(4) . .
O3 Ge4 O4 Nd1 14.71(18) . .
O3 Ge4 O4 Ge5 137.9(3) . .
O3 Ge4 O10 Nd3 53.3(3) . .
O3 Ge4 O10 Nd5 -144.6(2) . .
O3 Ge4 C10 C11 -36.6(6) . .
O4 Nd1 Ge3 Nd4 105.72(9) . 3_667
O4 Nd1 Ge3 O2 172.4(2) . .
O4 Nd1 Ge3 O3 -23.9(2) . .
O4 Nd1 Ge3 O9 67.72(16) . .
O4 Nd1 Ge3 C7 -103.0(3) . .
O4 Nd1 Ge5 O5 163.1(2) . .
O4 Nd1 Ge5 O11 -104.0(2) . .
O4 Nd1 Ge5 C13 86.8(3) . .
O4 Nd1 O1 Ge1 68.1(3) . .
O4 Nd1 O1 Ge2 -65.6(3) . .
O4 Nd1 O2 Ge2 132.17(17) . .
O4 Nd1 O2 Ge3 -8.2(2) . .
O4 Nd1 O3 Ge3 151.3(2) . .
O4 Nd1 O3 Ge4 11.89(15) . .
O4 Nd1 O5 Ge5 -9.67(14) . .
O4 Nd1 O5 Ge6 -151.6(2) . .
O4 Nd1 O6 Ge1 -132.81(17) . .
O4 Nd1 O6 Ge6 8.0(2) . .
O4 Ge4 O3 Nd1 -14.36(18) . .
O4 Ge4 O3 Ge3 -137.5(3) . .
O4 Ge4 O10 Nd3 150.4(2) . .
O4 Ge4 O10 Nd5 -47.5(3) . .
O4 Ge4 C10 C11 -135.2(5) . .
O4 Ge5 O5 Nd1 12.10(18) . .
O4 Ge5 O5 Ge6 143.9(3) . .
O4 Ge5 O11 Nd4 -145.8(2) . .
O4 Ge5 O11 Nd5 59.7(3) . .
O4 Ge5 C13 C14 -45.1(5) . .
O5 Nd1 Ge3 Nd4 65.29(12) . 3_667
O5 Nd1 Ge3 O2 132.0(2) . .
O5 Nd1 Ge3 O3 -64.3(2) . .
O5 Nd1 Ge3 O9 27.29(18) . .
O5 Nd1 Ge3 C7 -143.5(3) . .
O5 Nd1 Ge5 O4 -163.1(2) . .
O5 Nd1 Ge5 O11 92.9(2) . .
O5 Nd1 Ge5 C13 -76.3(3) . .
O5 Nd1 O1 Ge1 3.97(19) . .
O5 Nd1 O1 Ge2 -129.77(16) . .
O5 Nd1 O2 Ge2 63.2(3) . .
O5 Nd1 O2 Ge3 -77.1(3) . .
O5 Nd1 O3 Ge3 131.38(16) . .
O5 Nd1 O3 Ge4 -8.0(2) . .
O5 Nd1 O4 Ge4 146.9(2) . .
O5 Nd1 O4 Ge5 9.74(14) . .
O5 Nd1 O6 Ge1 -150.3(2) . .
O5 Nd1 O6 Ge6 -9.49(14) . .
O5 Ge5 O4 Nd1 -11.59(17) . .
O5 Ge5 O4 Ge4 -136.0(3) . .
O5 Ge5 O11 Nd4 -50.6(3) . .
O5 Ge5 O11 Nd5 154.9(2) . .
O5 Ge5 C13 C14 -141.1(4) . .
O5 Ge6 O6 Nd1 11.26(17) . .
O5 Ge6 O6 Ge1 139.9(3) . .
O5 Ge6 O12 Nd3 -147.8(2) . 3_667
O5 Ge6 O12 Nd4 54.6(3) . .
O5 Ge6 C16 C17 -49.7(6) . .
O6 Nd1 Ge3 Nd4 -10.32(11) . 3_667
O6 Nd1 Ge3 O2 56.4(2) . .
O6 Nd1 Ge3 O3 -139.9(2) . .
O6 Nd1 Ge3 O9 -48.32(18) . .
O6 Nd1 Ge3 C7 140.9(3) . .
O6 Nd1 Ge5 O4 173.18(19) . .
O6 Nd1 Ge5 O5 -23.7(2) . .
O6 Nd1 Ge5 O11 69.20(16) . .
O6 Nd1 Ge5 C13 -100.0(3) . .
O6 Nd1 O1 Ge1 -11.68(13) . .
O6 Nd1 O1 Ge2 -145.4(2) . .
O6 Nd1 O2 Ge2 4.9(2) . .
O6 Nd1 O2 Ge3 -135.45(16) . .
O6 Nd1 O3 Ge3 65.5(3) . .
O6 Nd1 O3 Ge4 -73.9(3) . .
O6 Nd1 O4 Ge4 129.64(16) . .
O6 Nd1 O4 Ge5 -7.5(2) . .
O6 Nd1 O5 Ge5 151.7(2) . .
O6 Nd1 O5 Ge6 9.82(15) . .
O6 Ge1 O1 Nd1 14.46(16) . .
O6 Ge1 O1 Ge2 123.8(3) . .
O6 Ge1 O7 Nd3 49.9(3) . 3_667
O6 Ge1 O7 Nd5 -139.5(2) . 3_667
O6 Ge1 C1 C2 -49.0(7) . .
O6 Ge6 O5 Nd1 -12.52(19) . .
O6 Ge6 O5 Ge5 -143.2(3) . .
O6 Ge6 O12 Nd3 -52.1(3) . 3_667
O6 Ge6 O12 Nd4 150.4(2) . .
O6 Ge6 C16 C17 -147.2(5) . .
O7 Nd3 Nd5 Nd4 -83.75(17) 3_667 .
O7 Nd3 Nd5 O8 -48.66(19) 3_667 3_667
O7 Nd3 Nd5 O10 -164.2(2) 3_667 .
O7 Nd3 Nd5 O11 -120.0(2) 3_667 .
O7 Nd3 Nd5 O15 32.6(2) 3_667 3_667
O7 Nd3 Nd5 O21 169.8(2) 3_667 .
O7 Nd3 Nd5 O28 -179(24) 3_667 .
O7 Nd3 Nd5 O4W 101.9(2) 3_667 .
O7 Nd3 Ge4 O3 -138.72(17) 3_667 .
O7 Nd3 Ge4 O4 -49.8(2) 3_667 .
O7 Nd3 Ge4 O10 -5.0(2) 3_667 .
O7 Nd3 Ge4 C10 104.1(2) 3_667 .
O7 Nd3 O9 Nd4 -80.47(19) 3_667 3_667
O7 Nd3 O9 Ge3 123.3(3) 3_667 .
O7 Nd3 O10 Nd5 9.59(15) 3_667 .
O7 Nd3 O10 Ge4 174.6(3) 3_667 .
O7 Nd3 O19 C12 75.3(13) 3_667 .
O7 Nd5 O10 Nd3 -9.61(15) 3_667 .
O7 Nd5 O10 Ge4 -172.6(3) 3_667 .
O7 Nd5 O11 Nd4 80.42(19) 3_667 .
O7 Nd5 O11 Ge5 -119.9(2) 3_667 .
O7 Nd5 O21 C15 -136.5(7) 3_667 .
O7 Nd5 O28 C24 -90.6(7) 3_667 .
O7 Ge1 O1 Nd1 -103.92(18) . .
O7 Ge1 O1 Ge2 5.4(4) . .
O7 Ge1 O6 Nd1 96.9(2) . .
O7 Ge1 O6 Ge6 -29.1(4) . .
O7 Ge1 C1 C2 85.4(7) . .
O8 Nd4 Nd5 Nd3 74.17(17) 3_667 .
O8 Nd4 Nd5 O7 37.87(19) 3_667 3_667
O8 Nd4 Nd5 O10 109.31(19) 3_667 .
O8 Nd4 Nd5 O11 152.6(2) 3_667 .
O8 Nd4 Nd5 O15 -43.9(2) 3_667 3_667
O8 Nd4 Nd5 O21 -174.25(19) 3_667 .
O8 Nd4 Nd5 O28 -110.7(2) 3_667 .
O8 Nd4 Nd5 O4W -125.6(4) 3_667 .
O8 Nd4 O11 Nd5 -16.78(15) 3_667 .
O8 Nd4 O11 Ge5 -173.5(3) 3_667 .
O8 Nd4 O12 Nd3 81.1(2) 3_667 3_667
O8 Nd4 O12 Ge6 -117.0(2) 3_667 .
O8 Nd4 O23 C18 -135.9(6) 3_667 .
O8 Nd4 O25 Nd2 70.9(3) 3_667 .
O8 Nd4 O25 C19 -124.4(4) 3_667 .
O8 Nd4 O27 Nd2 -148.08(16) 3_667 .
O8 Nd4 O27 C24 57.5(4) 3_667 .
O8 Nd5 O10 Nd3 -75.36(19) 3_667 .
O8 Nd5 O10 Ge4 121.7(2) 3_667 .
O8 Nd5 O11 Nd4 16.72(14) 3_667 .
O8 Nd5 O11 Ge5 176.4(3) 3_667 .
O8 Nd5 O21 C15 90.4(8) 3_667 .
O8 Nd5 O28 C24 -42.8(6) 3_667 .
O8 Ge2 O1 Nd1 93.86(18) . .
O8 Ge2 O1 Ge1 -16.8(4) . .
O8 Ge2 O2 Nd1 -94.07(19) . .
O8 Ge2 O2 Ge3 37.0(3) . .
O8 Ge2 C4 C5 109.1(4) . .
O9 Nd3 Nd5 Nd4 36.56(10) . .
O9 Nd3 Nd5 O7 120.3(2) . 3_667
O9 Nd3 Nd5 O8 71.66(13) . 3_667
O9 Nd3 Nd5 O10 -43.9(2) . .
O9 Nd3 Nd5 O11 0.35(14) . .
O9 Nd3 Nd5 O15 152.88(15) . 3_667
O9 Nd3 Nd5 O21 -69.88(14) . .
O9 Nd3 Nd5 O28 -58.3(12) . .
O9 Nd3 Nd5 O4W -137.83(14) . .
O9 Nd3 Ge4 O3 -17.96(18) . .
O9 Nd3 Ge4 O4 71.0(2) . .
O9 Nd3 Ge4 O10 115.7(2) . .
O9 Nd3 Ge4 C10 -135.1(2) . .
O9 Nd3 O10 Nd5 137.37(19) . .
O9 Nd3 O10 Ge4 -57.6(2) . .
O9 Nd3 O19 C12 -166.9(13) . .
O9 Nd4 Nd5 Nd3 39.07(10) 3_667 .
O9 Nd4 Nd5 O7 2.78(14) 3_667 3_667
O9 Nd4 Nd5 O8 -35.1(2) 3_667 3_667
O9 Nd4 Nd5 O10 74.22(14) 3_667 .
O9 Nd4 Nd5 O11 117.5(2) 3_667 .
O9 Nd4 Nd5 O15 -79.04(16) 3_667 3_667
O9 Nd4 Nd5 O21 150.66(14) 3_667 .
O9 Nd4 Nd5 O28 -145.77(15) 3_667 .
O9 Nd4 Nd5 O4W -160.7(4) 3_667 .
O9 Nd4 O11 Nd5 -83.1(2) 3_667 .
O9 Nd4 O11 Ge5 120.2(3) 3_667 .
O9 Nd4 O12 Nd3 13.26(15) 3_667 3_667
O9 Nd4 O12 Ge6 175.2(3) 3_667 .
O9 Nd4 O23 C18 77.0(7) 3_667 .
O9 Nd4 O25 Nd2 145.12(15) 3_667 .
O9 Nd4 O25 C19 -50.2(4) 3_667 .
O9 Nd4 O27 Nd2 -68.5(3) 3_667 .
O9 Nd4 O27 C24 137.0(4) 3_667 .
O9 Ge3 O2 Nd1 92.1(2) . .
O9 Ge3 O2 Ge2 -40.6(3) . .
O9 Ge3 O3 Nd1 -102.06(18) . .
O9 Ge3 O3 Ge4 22.1(4) . .
O9 Ge3 C7 C8 89.5(5) . .
O10 Nd3 Nd5 Nd4 80.42(18) . .
O10 Nd3 Nd5 O7 164.2(2) . 3_667
O10 Nd3 Nd5 O8 115.5(2) . 3_667
O10 Nd3 Nd5 O11 44.2(2) . .
O10 Nd3 Nd5 O15 -163.3(2) . 3_667
O10 Nd3 Nd5 O21 -26.0(2) . .
O10 Nd3 Nd5 O28 -14.5(13) . .
O10 Nd3 Nd5 O4W -94.0(2) . .
O10 Nd3 Ge4 O3 -133.7(3) . .
O10 Nd3 Ge4 O4 -44.8(3) . .
O10 Nd3 Ge4 C10 109.1(3) . .
O10 Nd3 O9 Nd4 -137.99(18) . 3_667
O10 Nd3 O9 Ge3 65.8(3) . .
O10 Nd3 O19 C12 109.0(13) . .
O10 Nd5 O11 Nd4 137.92(18) . .
O10 Nd5 O11 Ge5 -62.4(2) . .
O10 Nd5 O21 C15 -160.2(8) . .
O10 Nd5 O28 C24 74.8(7) . .
O10 Ge4 O3 Nd1 95.4(2) . .
O10 Ge4 O3 Ge3 -27.7(4) . .
O10 Ge4 O4 Nd1 -101.82(18) . .
O10 Ge4 O4 Ge5 21.4(3) . .
O10 Ge4 C10 C11 101.1(5) . .
O11 Nd4 Nd5 Nd3 -78.43(17) . .
O11 Nd4 Nd5 O7 -114.7(2) . 3_667
O11 Nd4 Nd5 O8 -152.6(2) . 3_667
O11 Nd4 Nd5 O10 -43.28(19) . .
O11 Nd4 Nd5 O15 163.5(2) . 3_667
O11 Nd4 Nd5 O21 33.2(2) . .
O11 Nd4 Nd5 O28 96.7(2) . .
O11 Nd4 Nd5 O4W 81.8(4) . .
O11 Nd4 O12 Nd3 143.58(17) . 3_667
O11 Nd4 O12 Ge6 -54.5(2) . .
O11 Nd4 O23 C18 -161.1(7) . .
O11 Nd4 O25 Nd2 -68.2(2) . .
O11 Nd4 O25 C19 96.4(5) . .
O11 Nd4 O27 Nd2 141.09(16) . .
O11 Nd4 O27 C24 -13.4(4) . .
O11 Nd5 O10 Nd3 -136.60(19) . .
O11 Nd5 O10 Ge4 60.4(3) . .
O11 Nd5 O21 C15 115.2(8) . .
O11 Nd5 O28 C24 28.1(6) . .
O11 Ge5 O4 Nd1 94.27(19) . .
O11 Ge5 O4 Ge4 -30.1(3) . .
O11 Ge5 O5 Nd1 -100.96(19) . .
O11 Ge5 O5 Ge6 30.9(3) . .
O11 Ge5 C13 C14 96.2(5) . .
O12 Nd3 Nd5 Nd4 -36.35(10) 3_667 .
O12 Nd3 Nd5 O7 47.4(2) 3_667 3_667
O12 Nd3 Nd5 O8 -1.25(13) 3_667 3_667
O12 Nd3 Nd5 O10 -116.8(2) 3_667 .
O12 Nd3 Nd5 O11 -72.57(14) 3_667 .
O12 Nd3 Nd5 O15 79.96(15) 3_667 3_667
O12 Nd3 Nd5 O21 -142.79(14) 3_667 .
O12 Nd3 Nd5 O28 -131.2(12) 3_667 .
O12 Nd3 Nd5 O4W 149.26(14) 3_667 .
O12 Nd3 Ge4 O3 -56.24(19) 3_667 .
O12 Nd3 Ge4 O4 32.7(2) 3_667 .
O12 Nd3 Ge4 O10 77.5(3) 3_667 .
O12 Nd3 Ge4 C10 -173.4(3) 3_667 .
O12 Nd3 O9 Nd4 -13.15(15) 3_667 3_667
O12 Nd3 O9 Ge3 -169.4(3) 3_667 .
O12 Nd3 O10 Nd5 76.6(2) 3_667 .
O12 Nd3 O10 Ge4 -118.4(2) 3_667 .
O12 Nd3 O19 C12 -137.9(12) 3_667 .
O12 Nd4 Nd5 Nd3 -39.54(11) . .
O12 Nd4 Nd5 O7 -75.84(14) . 3_667
O12 Nd4 Nd5 O8 -113.71(19) . 3_667
O12 Nd4 Nd5 O10 -4.40(14) . .
O12 Nd4 Nd5 O11 38.9(2) . .
O12 Nd4 Nd5 O15 -157.65(16) . 3_667
O12 Nd4 Nd5 O21 72.04(14) . .
O12 Nd4 Nd5 O28 135.61(15) . .
O12 Nd4 Nd5 O4W 120.7(4) . .
O12 Nd4 O11 Nd5 -144.69(17) . .
O12 Nd4 O11 Ge5 58.6(3) . .
O12 Nd4 O23 C18 108.6(7) . .
O12 Nd4 O25 Nd2 -143.79(16) . .
O12 Nd4 O25 C19 20.8(4) . .
O12 Nd4 O27 Nd2 61.8(3) . .
O12 Nd4 O27 C24 -92.7(5) . .
O12 Ge6 O5 Nd1 93.4(2) . .
O12 Ge6 O5 Ge5 -37.3(4) . .
O12 Ge6 O6 Nd1 -103.17(18) . .
O12 Ge6 O6 Ge1 25.5(4) . .
O12 Ge6 C16 C17 90.6(5) . .
O13 Nd3 Nd5 Nd4 -115.78(11) 3_667 .
O13 Nd3 Nd5 O7 -32.0(2) 3_667 3_667
O13 Nd3 Nd5 O8 -80.68(14) 3_667 3_667
O13 Nd3 Nd5 O10 163.8(2) 3_667 .
O13 Nd3 Nd5 O11 -151.99(15) 3_667 .
O13 Nd3 Nd5 O15 0.54(16) 3_667 3_667
O13 Nd3 Nd5 O21 137.79(15) 3_667 .
O13 Nd3 Nd5 O28 149.3(12) 3_667 .
O13 Nd3 Nd5 O4W 69.84(15) 3_667 .
O13 Nd3 Ge4 O3 158.4(3) 3_667 .
O13 Nd3 Ge4 O4 -112.7(3) 3_667 .
O13 Nd3 Ge4 O10 -67.9(3) 3_667 .
O13 Nd3 Ge4 C10 41.3(3) 3_667 .
O13 Nd3 O9 Nd4 21.1(3) 3_667 3_667
O13 Nd3 O9 Ge3 -135.1(3) 3_667 .
O13 Nd3 O10 Nd5 -23.1(3) 3_667 .
O13 Nd3 O10 Ge4 141.9(2) 3_667 .
O13 Nd3 O19 C12 -25.6(13) 3_667 .
O14 Nd1 Ge3 Nd4 -157.12(13) 2_546 3_667
O14 Nd1 Ge3 O2 -90.4(2) 2_546 .
O14 Nd1 Ge3 O3 73.3(2) 2_546 .
O14 Nd1 Ge3 O9 164.88(19) 2_546 .
O14 Nd1 Ge3 C7 -5.9(3) 2_546 .
O14 Nd1 Ge5 O4 -39.8(2) 2_546 .
O14 Nd1 Ge5 O5 123.3(2) 2_546 .
O14 Nd1 Ge5 O11 -143.78(19) 2_546 .
O14 Nd1 Ge5 C13 47.0(3) 2_546 .
O14 Nd1 O1 Ge1 -149.77(17) 2_546 .
O14 Nd1 O1 Ge2 76.49(19) 2_546 .
O14 Nd1 O2 Ge2 -135.1(2) 2_546 .
O14 Nd1 O2 Ge3 84.5(2) 2_546 .
O14 Nd1 O3 Ge3 -99.4(2) 2_546 .
O14 Nd1 O3 Ge4 121.2(2) 2_546 .
O14 Nd1 O4 Ge4 -76.7(2) 2_546 .
O14 Nd1 O4 Ge5 146.15(19) 2_546 .
O14 Nd1 O5 Ge5 -77.5(2) 2_546 .
O14 Nd1 O5 Ge6 140.60(19) 2_546 .
O14 Nd1 O6 Ge1 90.9(3) 2_546 .
O14 Nd1 O6 Ge6 -128.3(2) 2_546 .
O15 Nd5 O10 Nd3 25.1(3) 3_667 .
O15 Nd5 O10 Ge4 -137.9(2) 3_667 .
O15 Nd5 O11 Nd4 -24.4(3) 3_667 .
O15 Nd5 O11 Ge5 135.3(2) 3_667 .
O15 Nd5 O21 C15 -18.8(8) 3_667 .
O15 Nd5 O28 C24 -122.7(7) 3_667 .
O17 Nd4 Nd5 Nd3 111.45(10) 3_667 .
O17 Nd4 Nd5 O7 75.15(14) 3_667 3_667
O17 Nd4 Nd5 O8 37.28(19) 3_667 3_667
O17 Nd4 Nd5 O10 146.59(14) 3_667 .
O17 Nd4 Nd5 O11 -170.1(2) 3_667 .
O17 Nd4 Nd5 O15 -6.66(16) 3_667 3_667
O17 Nd4 Nd5 O21 -136.97(14) 3_667 .
O17 Nd4 Nd5 O28 -73.40(15) 3_667 .
O17 Nd4 Nd5 O4W -88.3(4) 3_667 .
O17 Nd4 O11 Nd5 15.0(3) 3_667 .
O17 Nd4 O11 Ge5 -141.8(2) 3_667 .
O17 Nd4 O12 Nd3 -18.5(3) 3_667 3_667
O17 Nd4 O12 Ge6 143.44(19) 3_667 .
O17 Nd4 O23 C18 -20.0(7) 3_667 .
O17 Nd4 O25 Nd2 76.91(16) 3_667 .
O17 Nd4 O25 C19 -118.4(5) 3_667 .
O17 Nd4 O27 Nd2 -74.71(16) 3_667 .
O17 Nd4 O27 C24 130.8(4) 3_667 .
O18 Nd2 Nd4 Nd3 79.41(13) 3_667 3_667
O18 Nd2 Nd4 Nd5 -101.80(13) 3_667 .
O18 Nd2 Nd4 Ge3 14.83(12) 3_667 3_667
O18 Nd2 Nd4 O8 -60.46(17) 3_667 3_667
O18 Nd2 Nd4 O9 38.49(16) 3_667 3_667
O18 Nd2 Nd4 O11 -143.29(16) 3_667 .
O18 Nd2 Nd4 O12 119.91(16) 3_667 .
O18 Nd2 Nd4 O17 -7.98(16) 3_667 3_667
O18 Nd2 Nd4 O23 165.19(17) 3_667 .
O18 Nd2 Nd4 O25 78.8(2) 3_667 .
O18 Nd2 Nd4 O27 -98.5(2) 3_667 .
O18 Nd2 O24 C18 -13.6(6) 3_667 .
O18 Nd2 O25 Nd4 -87.22(17) 3_667 .
O18 Nd2 O25 C19 109.3(5) 3_667 .
O18 Nd2 O27 Nd4 72.16(17) 3_667 .
O18 Nd2 O27 C24 -134.9(5) 3_667 .
O18 Nd2 O29 C30 114.7(6) 3_667 .
O18 Nd2 N1 C20 -58.5(5) 3_667 .
O18 Nd2 N1 C23 129.1(6) 3_667 .
O18 Nd2 N3 C25 46.7(5) 3_667 .
O18 Nd2 N3 C29 -135.6(5) 3_667 .
O19 Nd3 Nd5 Nd4 114.85(11) . .
O19 Nd3 Nd5 O7 -161.4(2) . 3_667
O19 Nd3 Nd5 O8 149.94(15) . 3_667
O19 Nd3 Nd5 O10 34.4(2) . .
O19 Nd3 Nd5 O11 78.63(15) . .
O19 Nd3 Nd5 O15 -128.84(16) . 3_667
O19 Nd3 Nd5 O21 8.41(15) . .
O19 Nd3 Nd5 O28 20.0(13) . .
O19 Nd3 Nd5 O4W -59.54(15) . .
O19 Nd3 Ge4 O3 73.0(2) . .
O19 Nd3 Ge4 O4 161.9(2) . .
O19 Nd3 Ge4 O10 -153.3(3) . .
O19 Nd3 Ge4 C10 -44.2(3) . .
O19 Nd3 O9 Nd4 147.9(2) . 3_667
O19 Nd3 O9 Ge3 -8.3(3) . .
O19 Nd3 O10 Nd5 -144.3(2) . .
O19 Nd3 O10 Ge4 20.7(2) . .
O21 Nd5 O10 Nd3 154.1(2) . .
O21 Nd5 O10 Ge4 -8.9(2) . .
O21 Nd5 O11 Nd4 -144.0(2) . .
O21 Nd5 O11 Ge5 15.6(2) . .
O21 Nd5 O28 C24 99.7(6) . .
O22 Nd2 Nd4 Nd3 37.79(17) 2_656 3_667
O22 Nd2 Nd4 Nd5 -143.42(17) 2_656 .
O22 Nd2 Nd4 Ge3 -26.79(17) 2_656 3_667
O22 Nd2 Nd4 O8 -102.1(2) 2_656 3_667
O22 Nd2 Nd4 O9 -3.1(2) 2_656 3_667
O22 Nd2 Nd4 O11 175.1(2) 2_656 .
O22 Nd2 Nd4 O12 78.3(2) 2_656 .
O22 Nd2 Nd4 O17 -49.6(2) 2_656 3_667
O22 Nd2 Nd4 O23 123.6(2) 2_656 .
O22 Nd2 Nd4 O25 37.2(2) 2_656 .
O22 Nd2 Nd4 O27 -140.1(2) 2_656 .
O22 Nd2 O24 C18 -125.8(5) 2_656 .
O22 Nd2 O25 Nd4 -155.83(15) 2_656 .
O22 Nd2 O25 C19 40.7(5) 2_656 .
O22 Nd2 O27 Nd4 96.8(4) 2_656 .
O22 Nd2 O27 C24 -110.2(5) 2_656 .
O22 Nd2 O29 C30 151.4(6) 2_656 .
O22 Nd2 N1 C20 -130.5(5) 2_656 .
O22 Nd2 N1 C23 57.0(6) 2_656 .
O22 Nd2 N3 C25 149.1(4) 2_656 .
O22 Nd2 N3 C29 -33.2(5) 2_656 .
O23 Nd4 Nd5 Nd3 -111.43(10) . .
O23 Nd4 Nd5 O7 -147.72(14) . 3_667
O23 Nd4 Nd5 O8 174.41(19) . 3_667
O23 Nd4 Nd5 O10 -76.28(14) . .
O23 Nd4 Nd5 O11 -33.0(2) . .
O23 Nd4 Nd5 O15 130.46(16) . 3_667
O23 Nd4 Nd5 O21 0.16(14) . .
O23 Nd4 Nd5 O28 63.73(15) . .
O23 Nd4 Nd5 O4W 48.8(4) . .
O23 Nd4 O11 Nd5 146.33(19) . .
O23 Nd4 O11 Ge5 -10.4(3) . .
O23 Nd4 O12 Nd3 -142.8(2) . 3_667
O23 Nd4 O12 Ge6 19.2(2) . .
O23 Nd4 O25 Nd2 -75.78(16) . .
O23 Nd4 O25 C19 88.9(5) . .
O23 Nd4 O27 Nd2 69.07(16) . .
O23 Nd4 O27 C24 -85.4(4) . .
O24 Nd2 Nd4 Nd3 -83.21(12) . 3_667
O24 Nd2 Nd4 Nd5 95.58(11) . .
O24 Nd2 Nd4 Ge3 -147.79(11) . 3_667
O24 Nd2 Nd4 O8 136.91(16) . 3_667
O24 Nd2 Nd4 O9 -124.14(15) . 3_667
O24 Nd2 Nd4 O11 54.09(15) . .
O24 Nd2 Nd4 O12 -42.71(16) . .
O24 Nd2 Nd4 O17 -170.61(16) . 3_667
O24 Nd2 Nd4 O23 2.57(16) . .
O24 Nd2 Nd4 O25 -83.82(19) . .
O24 Nd2 Nd4 O27 98.9(2) . .
O24 Nd2 O25 Nd4 85.13(17) . .
O24 Nd2 O25 C19 -78.4(5) . .
O24 Nd2 O27 Nd4 -73.51(17) . .
O24 Nd2 O27 C24 79.4(5) . .
O24 Nd2 O29 C30 -77.0(6) . .
O24 Nd2 N1 C20 84.1(5) . .
O24 Nd2 N1 C23 -88.4(6) . .
O24 Nd2 N3 C25 -94.4(5) . .
O24 Nd2 N3 C29 83.3(5) . .
O25 Nd2 Nd4 Nd3 0.60(15) . 3_667
O25 Nd2 Nd4 Nd5 179.39(15) . .
O25 Nd2 Nd4 Ge3 -63.97(15) . 3_667
O25 Nd2 Nd4 O8 -139.27(19) . 3_667
O25 Nd2 Nd4 O9 -40.32(18) . 3_667
O25 Nd2 Nd4 O11 137.90(19) . .
O25 Nd2 Nd4 O12 41.10(19) . .
O25 Nd2 Nd4 O17 -86.79(19) . 3_667
O25 Nd2 Nd4 O23 86.38(19) . .
O25 Nd2 Nd4 O27 -177.3(2) . .
O25 Nd2 O24 C18 -25.0(5) . .
O25 Nd2 O27 Nd4 1.70(14) . .
O25 Nd2 O27 C24 154.6(5) . .
O25 Nd2 O29 C30 -115.6(6) . .
O25 Nd2 N1 C20 -0.9(5) . .
O25 Nd2 N1 C23 -173.3(6) . .
O25 Nd2 N3 C25 -41.5(5) . .
O25 Nd2 N3 C29 136.2(5) . .
O25 Nd4 Nd5 Nd3 -178.0(2) . .
O25 Nd4 Nd5 O7 145.7(2) . 3_667
O25 Nd4 Nd5 O8 107.8(3) . 3_667
O25 Nd4 Nd5 O10 -142.9(2) . .
O25 Nd4 Nd5 O11 -99.6(3) . .
O25 Nd4 Nd5 O15 63.9(3) . 3_667
O25 Nd4 Nd5 O21 -66.4(2) . .
O25 Nd4 Nd5 O28 -2.9(2) . .
O25 Nd4 Nd5 O4W -17.8(4) . .
O25 Nd4 O11 Nd5 138.99(17) . .
O25 Nd4 O11 Ge5 -17.8(4) . .
O25 Nd4 O12 Nd3 -75.24(17) . 3_667
O25 Nd4 O12 Ge6 86.7(2) . .
O25 Nd4 O23 C18 13.8(7) . .
O25 Nd4 O27 Nd2 -1.74(14) . .
O25 Nd4 O27 C24 -156.2(4) . .
O25 C19 C20 N1 -12.4(9) . .
O25 C19 C20 C21 164.2(7) . .
O26 Nd3 Nd5 Nd4 -149.8(18) 3_667 .
O26 Nd3 Nd5 O7 -66.0(18) 3_667 3_667
O26 Nd3 Nd5 O8 -114.7(18) 3_667 3_667
O26 Nd3 Nd5 O10 129.8(18) 3_667 .
O26 Nd3 Nd5 O11 174.0(18) 3_667 .
O26 Nd3 Nd5 O15 -33.5(18) 3_667 3_667
O26 Nd3 Nd5 O21 103.8(18) 3_667 .
O26 Nd3 Nd5 O28 115(2) 3_667 .
O26 Nd3 Nd5 O4W 35.8(18) 3_667 .
O26 Nd3 Ge4 O3 39.80(18) 3_667 .
O26 Nd3 Ge4 O4 128.7(2) 3_667 .
O26 Nd3 Ge4 O10 173.5(3) 3_667 .
O26 Nd3 Ge4 C10 -77.4(3) 3_667 .
O26 Nd3 O9 Nd4 65.64(17) 3_667 3_667
O26 Nd3 O9 Ge3 -90.6(3) 3_667 .
O26 Nd3 O10 Nd5 -175.36(19) 3_667 .
O26 Nd3 O10 Ge4 -10.4(4) 3_667 .
O26 Nd3 O19 C12 -87.2(13) 3_667 .
O26 C19 C20 N1 169.0(6) . .
O26 C19 C20 C21 -14.3(10) . .
O27 Nd2 Nd4 Nd3 177.90(16) . 3_667
O27 Nd2 Nd4 Nd5 -3.32(16) . .
O27 Nd2 Nd4 Ge3 113.32(16) . 3_667
O27 Nd2 Nd4 O8 38.02(19) . 3_667
O27 Nd2 Nd4 O9 136.97(19) . 3_667
O27 Nd2 Nd4 O11 -44.80(19) . .
O27 Nd2 Nd4 O12 -141.61(19) . .
O27 Nd2 Nd4 O17 90.50(19) . 3_667
O27 Nd2 Nd4 O23 -96.32(19) . .
O27 Nd2 Nd4 O25 177.3(2) . .
O27 Nd2 O24 C18 49.4(5) . .
O27 Nd2 O25 Nd4 -1.67(13) . .
O27 Nd2 O25 C19 -165.2(5) . .
O27 Nd2 O29 C30 -6.4(6) . .
O27 Nd2 N1 C20 26.1(6) . .
O27 Nd2 N1 C23 -146.3(6) . .
O27 Nd2 N3 C25 -3.4(4) . .
O27 Nd2 N3 C29 174.3(5) . .
O27 Nd4 Nd5 Nd3 179.10(10) . .
O27 Nd4 Nd5 O7 142.80(14) . 3_667
O27 Nd4 Nd5 O8 104.93(19) . 3_667
O27 Nd4 Nd5 O10 -145.76(14) . .
O27 Nd4 Nd5 O11 -102.5(2) . .
O27 Nd4 Nd5 O15 60.99(16) . 3_667
O27 Nd4 Nd5 O21 -69.32(14) . .
O27 Nd4 Nd5 O28 -5.75(14) . .
O27 Nd4 Nd5 O4W -20.7(4) . .
O27 Nd4 O11 Nd5 73.96(17) . .
O27 Nd4 O11 Ge5 -82.8(3) . .
O27 Nd4 O12 Nd3 -135.23(18) . 3_667
O27 Nd4 O12 Ge6 26.7(4) . .
O27 Nd4 O23 C18 -66.4(7) . .
O27 Nd4 O25 Nd2 1.67(13) . .
O27 Nd4 O25 C19 166.3(5) . .
O27 C24 C25 N3 4.2(8) . .
O27 C24 C25 C26 -172.9(6) . .
O28 Nd5 O10 Nd3 178.23(16) . .
O28 Nd5 O10 Ge4 15.3(4) . .
O28 Nd5 O11 Nd4 -69.44(17) . .
O28 Nd5 O11 Ge5 90.2(2) . .
O28 Nd5 O21 C15 35.5(7) . .
O28 C24 C25 N3 -176.6(6) . .
O28 C24 C25 C26 6.2(10) . .
O29 Nd2 Nd4 Nd3 -111.3(2) . 3_667
O29 Nd2 Nd4 Nd5 67.5(2) . .
O29 Nd2 Nd4 Ge3 -175.8(2) . 3_667
O29 Nd2 Nd4 O8 108.9(2) . 3_667
O29 Nd2 Nd4 O9 -152.2(2) . 3_667
O29 Nd2 Nd4 O11 26.0(2) . .
O29 Nd2 Nd4 O12 -70.8(2) . .
O29 Nd2 Nd4 O17 161.4(2) . 3_667
O29 Nd2 Nd4 O23 -25.5(2) . .
O29 Nd2 Nd4 O25 -111.9(3) . .
O29 Nd2 Nd4 O27 70.8(3) . .
O29 Nd2 O24 C18 178.3(5) . .
O29 Nd2 O25 Nd4 124.4(2) . .
O29 Nd2 O25 C19 -39.1(6) . .
O29 Nd2 O27 Nd4 -141.34(16) . .
O29 Nd2 O27 C24 11.6(5) . .
O29 Nd2 N1 C20 160.4(5) . .
O29 Nd2 N1 C23 -12.0(6) . .
O29 Nd2 N3 C25 -178.6(5) . .
O29 Nd2 N3 C29 -0.9(5) . .
O1W Nd1 Ge3 Nd4 29.41(11) . 3_667
O1W Nd1 Ge3 O2 96.1(2) . .
O1W Nd1 Ge3 O3 -100.2(2) . .
O1W Nd1 Ge3 O9 -8.58(17) . .
O1W Nd1 Ge3 C7 -179.3(3) . .
O1W Nd1 Ge5 O4 100.9(2) . .
O1W Nd1 Ge5 O5 -95.9(2) . .
O1W Nd1 Ge5 O11 -3.05(17) . .
O1W Nd1 Ge5 C13 -172.2(3) . .
O1W Nd1 O1 Ge1 67.59(17) . .
O1W Nd1 O1 Ge2 -66.16(16) . .
O1W Nd1 O2 Ge2 68.11(19) . .
O1W Nd1 O2 Ge3 -72.24(18) . .
O1W Nd1 O3 Ge3 68.81(18) . .
O1W Nd1 O3 Ge4 -70.58(19) . .
O1W Nd1 O4 Ge4 68.32(18) . .
O1W Nd1 O4 Ge5 -68.79(17) . .
O1W Nd1 O5 Ge5 72.83(18) . .
O1W Nd1 O5 Ge6 -69.09(18) . .
O1W Nd1 O6 Ge1 -69.60(19) . .
O1W Nd1 O6 Ge6 71.24(17) . .
O2W Nd1 Ge3 Nd4 160.5(2) . 3_667
O2W Nd1 Ge3 O2 -132.8(3) . .
O2W Nd1 Ge3 O3 30.9(3) . .
O2W Nd1 Ge3 O9 122.5(3) . .
O2W Nd1 Ge3 C7 -48.3(3) . .
O2W Nd1 Ge5 O4 -86.0(3) . .
O2W Nd1 Ge5 O5 77.1(3) . .
O2W Nd1 Ge5 O11 170.0(2) . .
O2W Nd1 Ge5 C13 0.8(3) . .
O2W Nd1 O1 Ge1 -72.5(3) . .
O2W Nd1 O1 Ge2 153.8(2) . .
O2W Nd1 O2 Ge2 -137.6(4) . .
O2W Nd1 O2 Ge3 82.1(4) . .
O2W Nd1 O3 Ge3 -157.5(2) . .
O2W Nd1 O3 Ge4 63.1(2) . .
O2W Nd1 O4 Ge4 -139.9(3) . .
O2W Nd1 O4 Ge5 83.0(2) . .
O2W Nd1 O5 Ge5 -90.5(3) . .
O2W Nd1 O5 Ge6 127.6(3) . .
O2W Nd1 O6 Ge1 154.7(2) . .
O2W Nd1 O6 Ge6 -64.4(2) . .
O3W Nd1 Ge3 Nd4 -101.83(19) . 3_667
O3W Nd1 Ge3 O2 -35.1(3) . .
O3W Nd1 Ge3 O3 128.6(3) . .
O3W Nd1 Ge3 O9 -139.8(2) . .
O3W Nd1 Ge3 C7 49.4(3) . .
O3W Nd1 Ge5 O4 -127.4(2) . .
O3W Nd1 Ge5 O5 35.8(3) . .
O3W Nd1 Ge5 O11 128.7(2) . .
O3W Nd1 Ge5 C13 -40.5(3) . .
O3W Nd1 O1 Ge1 -89.8(2) . .
O3W Nd1 O1 Ge2 136.5(2) . .
O3W Nd1 O2 Ge2 -67.0(2) . .
O3W Nd1 O2 Ge3 152.6(2) . .
O3W Nd1 O3 Ge3 -80.1(3) . .
O3W Nd1 O3 Ge4 140.5(3) . .
O3W Nd1 O4 Ge4 -144.7(2) . .
O3W Nd1 O4 Ge5 78.2(3) . .
O3W Nd1 O5 Ge5 -151.2(2) . .
O3W Nd1 O5 Ge6 66.9(2) . .
O3W Nd1 O6 Ge1 91.8(2) . .
O3W Nd1 O6 Ge6 -127.3(2) . .
O4W Nd5 O10 Nd3 80.99(18) . .
O4W Nd5 O10 Ge4 -82.0(3) . .
O4W Nd5 O11 Nd4 -154.57(18) . .
O4W Nd5 O11 Ge5 5.1(4) . .
O4W Nd5 O21 C15 -72.0(8) . .
O4W Nd5 O28 C24 166.6(6) . .
O5W Nd3 Nd5 Nd4 178.36(11) . .
O5W Nd3 Nd5 O7 -97.9(2) . 3_667
O5W Nd3 Nd5 O8 -146.55(14) . 3_667
O5W Nd3 Nd5 O10 97.9(2) . .
O5W Nd3 Nd5 O11 142.14(15) . .
O5W Nd3 Nd5 O15 -65.33(16) . 3_667
O5W Nd3 Nd5 O21 71.92(15) . .
O5W Nd3 Nd5 O28 83.5(12) . .
O5W Nd3 Nd5 O4W 3.97(15) . .
O5W Nd3 Ge4 O3 137.43(19) . .
O5W Nd3 Ge4 O4 -133.6(2) . .
O5W Nd3 Ge4 O10 -88.9(3) . .
O5W Nd3 Ge4 C10 20.3(3) . .
O5W Nd3 O9 Nd4 155.2(2) . 3_667
O5W Nd3 O9 Ge3 -1.0(4) . .
O5W Nd3 O10 Nd5 -76.56(19) . .
O5W Nd3 O10 Ge4 88.5(2) . .
O5W Nd3 O19 C12 17.9(13) . .
O6W Nd2 Nd4 Nd3 137.90(13) . 3_667
O6W Nd2 Nd4 Nd5 -43.31(13) . .
O6W Nd2 Nd4 Ge3 73.32(13) . 3_667
O6W Nd2 Nd4 O8 -1.98(17) . 3_667
O6W Nd2 Nd4 O9 96.98(17) . 3_667
O6W Nd2 Nd4 O11 -84.80(17) . .
O6W Nd2 Nd4 O12 178.40(17) . .
O6W Nd2 Nd4 O17 50.51(17) . 3_667
O6W Nd2 Nd4 O23 -136.32(17) . .
O6W Nd2 Nd4 O25 137.3(2) . .
O6W Nd2 Nd4 O27 -40.0(2) . .
O6W Nd2 O24 C18 117.4(5) . .
O6W Nd2 O25 Nd4 -62.2(3) . .
O6W Nd2 O25 C19 134.3(5) . .
O6W Nd2 O27 Nd4 142.75(18) . .
O6W Nd2 O27 C24 -64.3(5) . .
O6W Nd2 O29 C30 69.2(6) . .
O6W Nd2 N1 C20 -125.8(5) . .
O6W Nd2 N1 C23 61.8(7) . .
O6W Nd2 N3 C25 88.9(5) . .
O6W Nd2 N3 C29 -93.4(5) . .
N1 Nd2 Nd4 Nd3 -19.68(12) . 3_667
N1 Nd2 Nd4 Nd5 159.11(12) . .
N1 Nd2 Nd4 Ge3 -84.26(12) . 3_667
N1 Nd2 Nd4 O8 -159.56(16) . 3_667
N1 Nd2 Nd4 O9 -60.61(16) . 3_667
N1 Nd2 Nd4 O11 117.62(16) . .
N1 Nd2 Nd4 O12 20.82(16) . .
N1 Nd2 Nd4 O17 -107.08(16) . 3_667
N1 Nd2 Nd4 O23 66.10(16) . .
N1 Nd2 Nd4 O25 -20.29(19) . .
N1 Nd2 Nd4 O27 162.4(2) . .
N1 Nd2 O24 C18 -87.9(5) . .
N1 Nd2 O25 Nd4 156.2(2) . .
N1 Nd2 O25 C19 -7.3(5) . .
N1 Nd2 O27 Nd4 -22.3(2) . .
N1 Nd2 O27 C24 130.6(4) . .
N1 Nd2 O29 C30 -142.4(6) . .
N1 Nd2 N3 C25 -120.0(5) . .
N1 Nd2 N3 C29 57.8(5) . .
N1 C20 C21 N2 -0.3(12) . .
N2 C22 C23 N1 3.2(15) . .
N3 Nd2 Nd4 Nd3 -152.95(11) . 3_667
N3 Nd2 Nd4 Nd5 25.84(11) . .
N3 Nd2 Nd4 Ge3 142.47(11) . 3_667
N3 Nd2 Nd4 O8 67.17(16) . 3_667
N3 Nd2 Nd4 O9 166.12(15) . 3_667
N3 Nd2 Nd4 O11 -15.65(15) . .
N3 Nd2 Nd4 O12 -112.45(16) . .
N3 Nd2 Nd4 O17 119.65(16) . 3_667
N3 Nd2 Nd4 O23 -67.17(16) . .
N3 Nd2 Nd4 O25 -153.56(19) . .
N3 Nd2 Nd4 O27 29.15(19) . .
N3 Nd2 O24 C18 112.4(5) . .
N3 Nd2 O25 Nd4 33.1(2) . .
N3 Nd2 O25 C19 -130.4(5) . .
N3 Nd2 O27 Nd4 -146.6(2) . .
N3 Nd2 O27 C24 6.4(4) . .
N3 Nd2 O29 C30 -1.2(6) . .
N3 Nd2 N1 C20 110.7(5) . .
N3 Nd2 N1 C23 -61.8(7) . .
N3 C25 C26 C27 -0.2(11) . .
N3 C29 C30 O29 -3.4(10) . .
N3 C29 C30 O30 176.3(7) . .
C1 Ge1 O1 Nd1 128.3(3) . .
C1 Ge1 O1 Ge2 -122.4(4) . .
C1 Ge1 O6 Nd1 -128.9(3) . .
C1 Ge1 O6 Ge6 105.1(4) . .
C1 Ge1 O7 Nd3 -82.5(3) . 3_667
C1 Ge1 O7 Nd5 88.0(3) . 3_667
C1 C2 C3 O13 39.4(14) . .
C1 C2 C3 O14 -153.4(8) . .
C4 Ge2 O1 Nd1 -136.8(2) . .
C4 Ge2 O1 Ge1 112.6(4) . .
C4 Ge2 O2 Nd1 134.8(2) . .
C4 Ge2 O2 Ge3 -94.1(3) . .
C4 Ge2 O8 Nd4 75.8(3) . 3_667
C4 Ge2 O8 Nd5 -69.8(3) . 3_667
C4 C5 C6 O15 4.7(9) . .
C4 C5 C6 O16 -174.6(6) . .
C7 Ge3 O2 Nd1 -122.5(2) . .
C7 Ge3 O2 Ge2 104.7(3) . .
C7 Ge3 O3 Nd1 126.5(2) . .
C7 Ge3 O3 Ge4 -109.4(4) . .
C7 Ge3 O9 Nd3 70.4(4) . .
C7 Ge3 O9 Nd4 -83.9(3) . 3_667
C7 C8 C9 O17 43.0(8) . .
C7 C8 C9 O18 -138.4(6) . .
C10 Ge4 O3 Nd1 -127.6(3) . .
C10 Ge4 O3 Ge3 109.3(4) . .
C10 Ge4 O4 Nd1 131.5(2) . .
C10 Ge4 O4 Ge5 -105.3(3) . .
C10 Ge4 O10 Nd3 -84.3(3) . .
C10 Ge4 O10 Nd5 77.8(3) . .
C10 C11 C12 O19 15.6(11) . .
C10 C11 C12 O20 -166.4(7) . .
C13 Ge5 O4 Nd1 -119.7(2) . .
C13 Ge5 O4 Ge4 115.9(3) . .
C13 Ge5 O5 Nd1 125.0(2) . .
C13 Ge5 O5 Ge6 -103.2(3) . .
C13 Ge5 O11 Nd4 73.0(4) . .
C13 Ge5 O11 Nd5 -81.5(3) . .
C13 C14 C15 O21 37.9(9) . .
C13 C14 C15 O22 -141.6(6) . .
C16 Ge6 O5 Nd1 -123.3(2) . .
C16 Ge6 O5 Ge5 106.0(3) . .
C16 Ge6 O6 Nd1 125.3(2) . .
C16 Ge6 O6 Ge1 -106.0(4) . .
C16 Ge6 O12 Nd3 72.3(4) . 3_667
C16 Ge6 O12 Nd4 -85.3(3) . .
C16 C17 C18 O23 35.6(9) . .
C16 C17 C18 O24 -145.7(6) . .
C19 C20 C21 N2 -176.8(7) . .
C20 N1 C23 C22 -4.7(12) . .
C21 N2 C22 C23 0.0(15) . .
C22 N2 C21 C20 -1.4(13) . .
C23 N1 C20 C19 180.0(6) . .
C23 N1 C20 C21 3.3(10) . .
C24 C25 C26 C27 176.8(6) . .
C25 N3 C29 C28 -1.9(10) . .
C25 N3 C29 C30 -179.8(6) . .
C25 C26 C27 C28 1.1(11) . .
C26 C27 C28 C29 -2.3(12) . .
C27 C28 C29 N3 2.7(11) . .
C27 C28 C29 C30 -179.5(7) . .
C28 C29 C30 O29 178.7(7) . .
C28 C29 C30 O30 -1.5(12) . .
C29 N3 C25 C24 -176.6(6) . .
C29 N3 C25 C26 0.7(10) . .
