#------------------------------------------------------------------------------
#$Date: 2019-11-23 11:34:12 +0200 (Sat, 23 Nov 2019) $
#$Revision: 233103 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/85/4348567.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4348567
loop_
_publ_author_name
'Lamming, Glenn'
'El-Zubir, Osama'
'Kolokotroni, James'
'McGurk, Christopher'
'Waddell, Paul G.'
'Probert, Michael R.'
'Houlton, Andrew'
_publ_section_title
;
 Two-Dimensional Frameworks Based on Ag(I)-N Bond Formation: Single
 Crystal to Single Molecular Sheet Transformation.
;
_journal_issue                   19
_journal_name_full               'Inorganic chemistry'
_journal_page_first              9644
_journal_page_last               9652
_journal_paper_doi               10.1021/acs.inorgchem.6b01365
_journal_volume                  55
_journal_year                    2016
_chemical_formula_moiety         'C18 H20 Ag F2 N4 O2 P, H2 O'
_chemical_formula_sum            'C18 H22 Ag F2 N4 O3 P'
_chemical_formula_weight         519.23
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_audit_creation_date             2015-06-09
_audit_creation_method
;
Olex2 1.2
(compiled 2015.01.26 svn.r3151 for OlexSys, GUI svn.r4998)
;
_cell_angle_alpha                106.187(4)
_cell_angle_beta                 101.424(3)
_cell_angle_gamma                102.635(3)
_cell_formula_units_Z            2
_cell_length_a                   8.1169(3)
_cell_length_b                   11.0480(5)
_cell_length_c                   12.3782(5)
_cell_measurement_reflns_used    6441
_cell_measurement_temperature    150.0(2)
_cell_measurement_theta_max      66.6530
_cell_measurement_theta_min      3.8440
_cell_volume                     999.67(8)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    'XT (Sheldrick, 2015)'
_diffrn_ambient_environment      N~2~
_diffrn_ambient_temperature      150.0(2)
_diffrn_detector                 'CCD plate'
_diffrn_detector_area_resol_mean 10.3968
_diffrn_detector_type            Atlas
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_details
;
#__ type_ start__ end____ width___ exp.time_
  1 omega  -26.00   68.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       41.5905  -57.0000   60.0000 94

#__ type_ start__ end____ width___ exp.time_
  2 omega   19.00  115.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       41.5905   57.0000 -150.0000 96

#__ type_ start__ end____ width___ exp.time_
  3 omega    4.00   81.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       41.5905 -125.0000  -30.0000 77

#__ type_ start__ end____ width___ exp.time_
  4 omega   35.00  128.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000  -91.0000   70.4149 93

#__ type_ start__ end____ width___ exp.time_
  5 omega   89.00  115.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000  -86.0000  142.2347 26

#__ type_ start__ end____ width___ exp.time_
  6 omega   23.00   50.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000  -61.0000  -30.0000 27

#__ type_ start__ end____ width___ exp.time_
  7 omega   13.00   55.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000  -86.0000  142.2347 42

#__ type_ start__ end____ width___ exp.time_
  8 omega   20.00  154.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000  -15.0000 -150.0000 134

#__ type_ start__ end____ width___ exp.time_
  9 omega   20.00   82.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000  -94.0000 -150.0000 62

#__ type_ start__ end____ width___ exp.time_
 10 omega   34.00  110.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000   15.0000  150.0000 76

#__ type_ start__ end____ width___ exp.time_
 11 omega   22.00   48.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000  -30.0000  120.0000 26

#__ type_ start__ end____ width___ exp.time_
 12 omega  118.00  163.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000   77.0000    0.0000 45

#__ type_ start__ end____ width___ exp.time_
 13 omega   29.00   65.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000  -30.0000  -30.0000 36

#__ type_ start__ end____ width___ exp.time_
 14 omega   26.00   71.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000  -45.0000 -150.0000 45

#__ type_ start__ end____ width___ exp.time_
 15 omega   49.00   82.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000 -125.0000  150.0000 33

#__ type_ start__ end____ width___ exp.time_
 16 omega   24.00   62.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000  -45.0000  120.0000 38

#__ type_ start__ end____ width___ exp.time_
 17 omega   84.00  109.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000  125.0000  150.0000 25

#__ type_ start__ end____ width___ exp.time_
 18 omega  138.00  167.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000  125.0000  150.0000 29

#__ type_ start__ end____ width___ exp.time_
 19 omega   62.00   88.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000  -61.0000  -30.0000 26

#__ type_ start__ end____ width___ exp.time_
 20 omega   34.00   77.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000  -94.0000  -60.0000 43

#__ type_ start__ end____ width___ exp.time_
 21 omega   69.00  128.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000  -93.0000 -129.4046 59

#__ type_ start__ end____ width___ exp.time_
 22 omega  115.00  141.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000   15.0000  150.0000 26

#__ type_ start__ end____ width___ exp.time_
 23 omega   42.00   85.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000  -61.0000   60.0000 43

#__ type_ start__ end____ width___ exp.time_
 24 omega   61.00   90.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000   77.0000    0.0000 29

#__ type_ start__ end____ width___ exp.time_
 25 omega   88.00  114.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000  -92.0000  -49.8974 26

#__ type_ start__ end____ width___ exp.time_
 26 omega   35.00   68.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000  -92.0000  -49.8974 33

#__ type_ start__ end____ width___ exp.time_
 27 omega  -34.00   68.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       41.5905  -38.0000  150.0000 102

#__ type_ start__ end____ width___ exp.time_
 28 omega   12.00  116.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       41.5905   57.0000  120.0000 104

#__ type_ start__ end____ width___ exp.time_
 29 omega   12.00  116.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       41.5905   57.0000   30.0000 104

#__ type_ start__ end____ width___ exp.time_
 30 omega   12.00  116.00   1.0000    4.0000
omega____ theta____ kappa____ phi______ frames
    -       41.5905   57.0000  -60.0000 104

#__ type_ start__ end____ width___ exp.time_
 31 omega   63.00  171.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000   30.0000    0.0000 108

#__ type_ start__ end____ width___ exp.time_
 32 omega   60.00  172.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000   77.0000 -180.0000 112

#__ type_ start__ end____ width___ exp.time_
 33 omega   63.00  171.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000   30.0000  -90.0000 108

#__ type_ start__ end____ width___ exp.time_
 34 omega   60.00  172.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000   77.0000  120.0000 112

#__ type_ start__ end____ width___ exp.time_
 35 omega   63.00  168.00   1.0000   16.0000
omega____ theta____ kappa____ phi______ frames
    -       93.5000   61.0000   60.0000 105
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'Xcalibur, Atlas, Gemini ultra'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      -0.0587425000
_diffrn_orient_matrix_UB_12      -0.1226428000
_diffrn_orient_matrix_UB_13      0.0348161000
_diffrn_orient_matrix_UB_21      0.0312193000
_diffrn_orient_matrix_UB_22      0.0892286000
_diffrn_orient_matrix_UB_23      0.1269071000
_diffrn_orient_matrix_UB_31      -0.1911486000
_diffrn_orient_matrix_UB_32      0.0054973000
_diffrn_orient_matrix_UB_33      -0.0294408000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0425
_diffrn_reflns_av_unetI/netI     0.0362
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.991
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            14167
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.991
_diffrn_reflns_theta_full        66.500
_diffrn_reflns_theta_max         66.934
_diffrn_reflns_theta_min         3.869
_diffrn_source                   'sealed X-ray tube'
_diffrn_source_type              'Enhance Ultra (Cu) X-ray Source'
_exptl_absorpt_coefficient_mu    9.266
_exptl_absorpt_correction_T_max  0.884
_exptl_absorpt_correction_T_min  0.420
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.37.33 (release 27-03-2014 CrysAlis171 .NET)
(compiled Mar 27 2014,17:12:48)
Analytical numeric absorption correction using a multifaceted crystal
			model based on expressions derived by R.C. Clark & J.S. Reid.
(Clark, R. C. & Reid, J. S. (1995). Acta Cryst. A51, 887-897)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    1.725
_exptl_crystal_description       plate
_exptl_crystal_F_000             524
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.07
_exptl_crystal_size_min          0.01
_refine_diff_density_max         0.365
_refine_diff_density_min         -0.496
_refine_diff_density_rms         0.070
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.019
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     268
_refine_ls_number_reflns         3527
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.019
_refine_ls_R_factor_all          0.0299
_refine_ls_R_factor_gt           0.0239
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0264P)²+0.1101P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0530
_refine_ls_wR_factor_ref         0.0555
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3166
_reflns_number_total             3527
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic6b01365_si_001.cif
_cod_data_source_block           3
_cod_original_cell_volume        999.68(7)
_cod_database_code               4348567
_shelxl_version_number           2014/6
_chemical_oxdiff_formula         'C18 H22 N4 S1 O5 Ag1'
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_reflns_odcompleteness_completeness 98.88
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     66.97
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups, All C(H,H,H) groups
2. Restrained distances
 O3-H3B = O3-H3A
 0.9 with sigma of 0.02
3.a Ternary CH refined with riding coordinates:
 C8(H8), C17(H17)
3.b Secondary CH2 refined with riding coordinates:
 C9(H9A,H9B), C10(H10A,H10B), C18(H18A,H18B), C19(H19A,H19B)
3.c Aromatic/amide H refined with riding coordinates:
 C2(H2), C4(H4), C5(H5), C6(H6), C7(H7), C11(H11), C13(H13), C14(H14),
 C15(H15), C16(H16)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
Ag1 Ag 0.42444(3) 0.24001(2) 0.15927(2) 0.02140(7) Uani 1 1 d .
P1 P 0.26639(9) -0.09376(6) 0.22129(6) 0.02159(15) Uani 1 1 d .
F1 F 0.3632(3) -0.1926(2) 0.16950(19) 0.0527(5) Uani 1 1 d .
F2 F 0.3660(2) -0.06057(17) 0.35213(15) 0.0364(4) Uani 1 1 d .
O1 O 0.3187(3) 0.02316(19) 0.18913(19) 0.0321(5) Uani 1 1 d .
O2 O 0.0830(3) -0.1660(2) 0.20106(19) 0.0357(5) Uani 1 1 d .
O3 O -0.0594(3) -0.3985(2) 0.2456(2) 0.0366(5) Uani 1 1 d D
N1 N 0.5641(3) 0.3383(2) 0.3616(2) 0.0253(5) Uani 1 1 d .
N2 N 0.8600(3) 0.7348(2) 0.4808(2) 0.0283(5) Uani 1 1 d .
N3 N -0.3277(3) 0.1808(2) 0.1223(2) 0.0232(5) Uani 1 1 d .
N4 N 0.2485(3) 0.33903(19) 0.07318(18) 0.0171(4) Uani 1 1 d .
C2 C 0.6488(4) 0.4665(3) 0.4017(2) 0.0259(6) Uani 1 1 d .
H2 H 0.6440 0.5131 0.3477 0.031 Uiso 1 1 calc R
H3A H -0.008(4) -0.329(2) 0.229(3) 0.031 Uiso 1 1 d DR
H3B H -0.082(4) -0.372(3) 0.314(2) 0.031 Uiso 1 1 d DR
C3 C 0.7436(4) 0.5364(3) 0.5173(2) 0.0253(6) Uani 1 1 d .
C4 C 0.7495(4) 0.4683(3) 0.5960(3) 0.0306(7) Uani 1 1 d .
H4 H 0.8116 0.5127 0.6762 0.037 Uiso 1 1 calc R
C5 C 0.6638(4) 0.3354(3) 0.5560(3) 0.0333(7) Uani 1 1 d .
H5 H 0.6670 0.2865 0.6082 0.040 Uiso 1 1 calc R
C6 C 0.5734(4) 0.2742(3) 0.4392(2) 0.0279(6) Uani 1 1 d .
H6 H 0.5149 0.1825 0.4125 0.033 Uiso 1 1 calc R
C7 C 0.8230(4) 0.6796(3) 0.5537(2) 0.0274(6) Uani 1 1 d .
H7 H 0.8472 0.7319 0.6335 0.033 Uiso 1 1 calc R
C8 C 0.9216(4) 0.8784(3) 0.5217(2) 0.0269(6) Uani 1 1 d .
H8 H 0.8998 0.9141 0.5994 0.032 Uiso 1 1 calc R
C9 C 0.8180(4) 0.9256(3) 0.4330(3) 0.0293(6) Uani 1 1 d .
H9A H 0.6919 0.8987 0.4295 0.035 Uiso 1 1 calc R
H9B H 0.8305 0.8835 0.3544 0.035 Uiso 1 1 calc R
C10 C 1.1169(4) 0.9244(3) 0.5338(3) 0.0298(6) Uani 1 1 d .
H10A H 1.1402 0.8822 0.4589 0.036 Uiso 1 1 calc R
H10B H 1.1823 0.8971 0.5948 0.036 Uiso 1 1 calc R
C11 C -0.1963(4) 0.2628(3) 0.1037(2) 0.0217(6) Uani 1 1 d .
H11 H -0.2129 0.3424 0.0949 0.026 Uiso 1 1 calc R
C12 C -0.0371(3) 0.2381(2) 0.0966(2) 0.0193(5) Uani 1 1 d .
C13 C -0.0121(4) 0.1231(3) 0.1123(2) 0.0219(6) Uani 1 1 d .
H13 H 0.0952 0.1031 0.1092 0.026 Uiso 1 1 calc R
C14 C -0.1457(4) 0.0384(3) 0.1325(2) 0.0231(6) Uani 1 1 d .
H14 H -0.1310 -0.0404 0.1443 0.028 Uiso 1 1 calc R
C15 C -0.3009(4) 0.0696(3) 0.1353(2) 0.0249(6) Uani 1 1 d .
H15 H -0.3931 0.0094 0.1470 0.030 Uiso 1 1 calc R
C16 C 0.0880(3) 0.3320(2) 0.0658(2) 0.0200(5) Uani 1 1 d .
H16 H 0.0443 0.3937 0.0375 0.024 Uiso 1 1 calc R
C17 C 0.3422(3) 0.4352(2) 0.0268(2) 0.0177(5) Uani 1 1 d .
H17 H 0.2577 0.4788 -0.0049 0.021 Uiso 1 1 calc R
C18 C 0.4948(4) 0.5407(2) 0.1224(2) 0.0198(5) Uani 1 1 d .
H18A H 0.5763 0.4985 0.1578 0.024 Uiso 1 1 calc R
H18B H 0.4498 0.5892 0.1846 0.024 Uiso 1 1 calc R
C19 C 0.5947(4) 0.6379(2) 0.0730(2) 0.0205(5) Uani 1 1 d .
H19A H 0.5165 0.6863 0.0443 0.025 Uiso 1 1 calc R
H19B H 0.6968 0.7029 0.1359 0.025 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
_exptl_oxdiff_crystal_face_indexfrac_h
_exptl_oxdiff_crystal_face_indexfrac_k
_exptl_oxdiff_crystal_face_indexfrac_l
_exptl_oxdiff_crystal_face_x
_exptl_oxdiff_crystal_face_y
_exptl_oxdiff_crystal_face_z
0 1 -1 0.0010 0.0000 1.0000 -1.0000 -0.1575 -0.0377 0.0349
0 1 1 0.0375 -0.0000 0.9999 1.0001 -0.0878 0.2161 -0.0239
0 0 -1 0.0231 0.0000 0.0000 -1.0001 -0.0348 -0.1269 0.0294
0 -1 -1 0.0285 0.0000 -0.9999 -1.0001 0.0878 -0.2161 0.0239
0 0 1 0.0371 -0.0000 -0.0000 1.0001 0.0348 0.1269 -0.0294
-2 1 0 0.0509 -2.0000 1.0000 -0.0000 -0.0052 0.0268 0.3878
2 -1 0 0.0769 2.0000 -1.0000 0.0000 0.0052 -0.0268 -0.3878
0 -1 1 0.0122 -0.0000 -1.0000 1.0000 0.1575 0.0377 -0.0349
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ag1 O1 89.49(7) . .
N3 Ag1 O1 88.64(7) 1_655 .
N3 Ag1 N1 91.99(8) 1_655 .
N4 Ag1 O1 124.66(7) . .
N4 Ag1 N1 118.32(8) . .
N4 Ag1 N3 132.22(7) . 1_655
F1 P1 F2 96.28(11) . .
O1 P1 F1 108.50(12) . .
O1 P1 F2 108.10(11) . .
O1 P1 O2 123.11(12) . .
O2 P1 F1 108.66(13) . .
O2 P1 F2 108.88(11) . .
P1 O1 Ag1 173.16(14) . .
H3A O3 H3B 109(3) . .
C2 N1 Ag1 117.62(18) . .
C2 N1 C6 116.9(2) . .
C6 N1 Ag1 125.36(18) . .
C7 N2 C8 117.7(2) . .
C11 N3 Ag1 122.24(17) . 1_455
C15 N3 Ag1 120.04(17) . 1_455
C15 N3 C11 117.1(2) . .
C16 N4 Ag1 130.50(17) . .
C16 N4 C17 115.9(2) . .
C17 N4 Ag1 113.35(15) . .
N1 C2 H2 117.9 . .
N1 C2 C3 124.2(2) . .
C3 C2 H2 117.9 . .
C2 C3 C7 119.6(2) . .
C4 C3 C2 117.8(3) . .
C4 C3 C7 122.4(3) . .
C3 C4 H4 120.5 . .
C5 C4 C3 119.0(3) . .
C5 C4 H4 120.5 . .
C4 C5 H5 120.5 . .
C4 C5 C6 119.1(3) . .
C6 C5 H5 120.5 . .
N1 C6 C5 123.1(3) . .
N1 C6 H6 118.4 . .
C5 C6 H6 118.4 . .
N2 C7 C3 121.3(3) . .
N2 C7 H7 119.3 . .
C3 C7 H7 119.3 . .
N2 C8 H8 109.4 . .
N2 C8 C9 108.1(2) . .
N2 C8 C10 110.0(2) . .
C9 C8 H8 109.4 . .
C10 C8 H8 109.4 . .
C10 C8 C9 110.7(2) . .
C8 C9 H9A 109.4 . .
C8 C9 H9B 109.4 . .
C8 C9 C10 111.2(2) . 2_776
H9A C9 H9B 108.0 . .
C10 C9 H9A 109.4 2_776 .
C10 C9 H9B 109.4 2_776 .
C8 C10 C9 111.1(2) . 2_776
C8 C10 H10A 109.4 . .
C8 C10 H10B 109.4 . .
C9 C10 H10A 109.4 2_776 .
C9 C10 H10B 109.4 2_776 .
H10A C10 H10B 108.0 . .
N3 C11 H11 118.1 . .
N3 C11 C12 123.8(2) . .
C12 C11 H11 118.1 . .
C11 C12 C16 117.4(2) . .
C13 C12 C11 117.8(2) . .
C13 C12 C16 124.8(2) . .
C12 C13 H13 120.5 . .
C14 C13 C12 119.0(3) . .
C14 C13 H13 120.5 . .
C13 C14 H14 120.4 . .
C13 C14 C15 119.1(2) . .
C15 C14 H14 120.4 . .
N3 C15 C14 123.2(2) . .
N3 C15 H15 118.4 . .
C14 C15 H15 118.4 . .
N4 C16 C12 126.7(2) . .
N4 C16 H16 116.7 . .
C12 C16 H16 116.7 . .
N4 C17 H17 108.5 . .
N4 C17 C18 111.2(2) . .
N4 C17 C19 109.1(2) . 2_665
C18 C17 H17 108.5 . .
C18 C17 C19 111.0(2) . 2_665
C19 C17 H17 108.5 2_665 .
C17 C18 H18A 109.4 . .
C17 C18 H18B 109.4 . .
C17 C18 C19 111.0(2) . .
H18A C18 H18B 108.0 . .
C19 C18 H18A 109.4 . .
C19 C18 H18B 109.4 . .
C17 C19 C18 110.5(2) 2_665 .
C17 C19 H19A 109.6 2_665 .
C17 C19 H19B 109.6 2_665 .
C18 C19 H19A 109.6 . .
C18 C19 H19B 109.6 . .
H19A C19 H19B 108.1 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 O1 2.5166(18) .
Ag1 N1 2.357(2) .
Ag1 N3 2.337(2) 1_655
Ag1 N4 2.259(2) .
P1 F1 1.5504(19) .
P1 F2 1.5593(18) .
P1 O1 1.4564(19) .
P1 O2 1.462(2) .
O3 H3A 0.885(18) .
O3 H3B 0.884(18) .
N1 C2 1.332(4) .
N1 C6 1.343(4) .
N2 C7 1.269(4) .
N2 C8 1.459(3) .
N3 Ag1 2.337(2) 1_455
N3 C11 1.343(3) .
N3 C15 1.339(4) .
N4 C16 1.271(3) .
N4 C17 1.482(3) .
C2 H2 0.9500 .
C2 C3 1.387(4) .
C3 C4 1.387(4) .
C3 C7 1.471(4) .
C4 H4 0.9500 .
C4 C5 1.377(4) .
C5 H5 0.9500 .
C5 C6 1.380(4) .
C6 H6 0.9500 .
C7 H7 0.9500 .
C8 H8 1.0000 .
C8 C9 1.526(4) .
C8 C10 1.518(4) .
C9 H9A 0.9900 .
C9 H9B 0.9900 .
C9 C10 1.532(4) 2_776
C10 C9 1.532(4) 2_776
C10 H10A 0.9900 .
C10 H10B 0.9900 .
C11 H11 0.9500 .
C11 C12 1.392(4) .
C12 C13 1.388(4) .
C12 C16 1.472(4) .
C13 H13 0.9500 .
C13 C14 1.381(4) .
C14 H14 0.9500 .
C14 C15 1.382(4) .
C15 H15 0.9500 .
C16 H16 0.9500 .
C17 H17 1.0000 .
C17 C18 1.521(4) .
C17 C19 1.522(3) 2_665
C18 H18A 0.9900 .
C18 H18B 0.9900 .
C18 C19 1.538(3) .
C19 C17 1.522(4) 2_665
C19 H19A 0.9900 .
C19 H19B 0.9900 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O3 H3A O2 0.885(18) 1.944(19) 2.825(3) 173(3) .
O3 H3B N2 0.884(18) 2.269(19) 3.139(3) 168(3) 1_445
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Ag1 N1 C2 C3 -176.9(2) . .
Ag1 N1 C6 C5 176.9(2) . .
Ag1 N3 C11 C12 171.27(19) 1_455 .
Ag1 N3 C15 C14 -169.8(2) 1_455 .
Ag1 N4 C16 C12 -10.7(4) . .
Ag1 N4 C17 C18 -57.0(2) . .
Ag1 N4 C17 C19 65.8(2) . 2_665
N1 C2 C3 C4 -0.4(5) . .
N1 C2 C3 C7 -176.2(3) . .
N2 C8 C9 C10 -176.6(2) . 2_776
N2 C8 C10 C9 175.3(2) . 2_776
N3 C11 C12 C13 -1.5(4) . .
N3 C11 C12 C16 174.8(2) . .
N4 C17 C18 C19 178.4(2) . .
C2 N1 C6 C5 0.6(4) . .
C2 C3 C4 C5 0.9(4) . .
C2 C3 C7 N2 -24.1(4) . .
C3 C4 C5 C6 -0.6(5) . .
C4 C3 C7 N2 160.2(3) . .
C4 C5 C6 N1 -0.1(5) . .
C6 N1 C2 C3 -0.3(4) . .
C7 N2 C8 C9 -131.8(3) . .
C7 N2 C8 C10 107.3(3) . .
C7 C3 C4 C5 176.6(3) . .
C8 N2 C7 C3 173.8(3) . .
C9 C8 C10 C9 56.0(3) . 2_776
C10 C8 C9 C10 -56.1(3) . 2_776
C11 N3 C15 C14 1.2(4) . .
C11 C12 C13 C14 0.8(4) . .
C11 C12 C16 N4 167.9(3) . .
C12 C13 C14 C15 0.7(4) . .
C13 C12 C16 N4 -16.1(4) . .
C13 C14 C15 N3 -1.8(4) . .
C15 N3 C11 C12 0.5(4) . .
C16 N4 C17 C18 118.4(2) . .
C16 N4 C17 C19 -118.8(2) . 2_665
C16 C12 C13 C14 -175.2(2) . .
C17 N4 C16 C12 174.9(2) . .
C17 C18 C19 C17 -56.4(3) . 2_665
C19 C17 C18 C19 56.7(3) 2_665 .
