#------------------------------------------------------------------------------
#$Date: 2019-11-23 11:55:27 +0200 (Sat, 23 Nov 2019) $
#$Revision: 233187 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/86/4348614.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4348614
loop_
_publ_author_name
'Ooi, Shota'
'Tanaka, Takayuki'
'Osuka, Atsuhiro'
_publ_section_title
;
 Metal Complexes of meso-meso Linked Corrole Dimers.
;
_journal_issue                   17
_journal_name_full               'Inorganic chemistry'
_journal_page_first              8920
_journal_page_last               8927
_journal_paper_doi               10.1021/acs.inorgchem.6b01422
_journal_volume                  55
_journal_year                    2016
_chemical_formula_moiety
'2(C62 H16 Ag2 F20 N8), 1.5(C7 H16), 5(C4 H8 O2)'
_chemical_formula_sum            'C154.5 H96 Ag4 F40 N16 O10'
_chemical_formula_weight         3527.95
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_cell_angle_alpha                90
_cell_angle_beta                 106.1114(19)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   16.9309(14)
_cell_length_b                   31.154(4)
_cell_length_c                   27.599(2)
_cell_measurement_reflns_used    13208
_cell_measurement_temperature    93(2)
_cell_measurement_theta_max      68.2
_cell_measurement_theta_min      25.2
_cell_volume                     13986(2)
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      93(2)
_diffrn_detector_area_resol_mean 5.8140
_diffrn_measured_fraction_theta_full 0.982
_diffrn_measured_fraction_theta_max 0.982
_diffrn_measurement_device_type  'Rigaku XtaLAB P200'
_diffrn_measurement_method       ω
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54187
_diffrn_reflns_av_R_equivalents  0.0380
_diffrn_reflns_av_unetI/netI     0.0322
_diffrn_reflns_Laue_measured_fraction_full 0.982
_diffrn_reflns_Laue_measured_fraction_max 0.982
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       37
_diffrn_reflns_limit_k_min       -35
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            84655
_diffrn_reflns_point_group_measured_fraction_full 0.982
_diffrn_reflns_point_group_measured_fraction_max 0.982
_diffrn_reflns_theta_full        67.000
_diffrn_reflns_theta_max         67.000
_diffrn_reflns_theta_min         6.577
_exptl_absorpt_coefficient_mu    5.505
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'REQAB (Rigaku, 1998)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.676
_exptl_crystal_description       prism
_exptl_crystal_F_000             7052
_exptl_crystal_size_max          0.050
_exptl_crystal_size_mid          0.040
_exptl_crystal_size_min          0.040
_exptl_transmission_factor_max   0.802
_exptl_transmission_factor_min   0.768
_refine_diff_density_max         3.109
_refine_diff_density_min         -1.103
_refine_diff_density_rms         0.136
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.130
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     2142
_refine_ls_number_reflns         24480
_refine_ls_number_restraints     260
_refine_ls_restrained_S_all      1.130
_refine_ls_R_factor_all          0.0759
_refine_ls_R_factor_gt           0.0659
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0727P)²+105.9286P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1750
_refine_ls_wR_factor_ref         0.1857
_reflns_Friedel_coverage         0.000
_reflns_number_gt                21229
_reflns_number_total             24480
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            revised-10Ag.cif
_cod_data_source_block           151124oi
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_original_formula_sum        'C154.50 H96 Ag4 F40 N16 O10'
_cod_database_code               4348614
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.770
_shelx_estimated_absorpt_t_max   0.810
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
F2 F -0.1761(4) 0.40776(17) 0.6488(2) 0.0711(15) Uani 1 1 d . . . . .
F3 F -0.3078(3) 0.37000(19) 0.5837(2) 0.0733(16) Uani 1 1 d . . . . .
F5 F -0.1449(3) 0.25337(16) 0.56567(19) 0.0569(12) Uani 1 1 d . . . . .
F7 F 0.5847(4) 0.1025(3) 0.8177(3) 0.094(2) Uani 1 1 d . . . . .
F9 F 0.3689(5) 0.0029(2) 0.7698(4) 0.114(3) Uani 1 1 d . . . . .
F11 F 0.5610(3) 0.24428(15) 0.42355(18) 0.0516(11) Uani 1 1 d . . . . .
F12 F 0.6810(3) 0.30227(18) 0.4366(2) 0.0607(13) Uani 1 1 d . . . . .
F15 F 0.3703(3) 0.35559(13) 0.41975(15) 0.0402(9) Uani 1 1 d . . . . .
F16 F -0.0764(3) 0.16215(14) 0.2971(2) 0.0527(12) Uani 1 1 d . . . . .
F21 F -0.2919(3) 0.28978(16) 0.34044(18) 0.0521(11) Uani 1 1 d . . . . .
F23 F -0.4304(3) 0.17579(18) 0.2434(2) 0.0694(16) Uani 1 1 d . . . . .
F24 F -0.3249(3) 0.17839(16) 0.18540(19) 0.0586(13) Uani 1 1 d . . . . .
F25 F -0.2020(3) 0.23662(15) 0.20564(17) 0.0490(11) Uani 1 1 d . . . . .
F27 F 0.2462(4) 0.56018(18) 0.4743(2) 0.0737(16) Uani 1 1 d . . . . .
F28 F 0.3889(3) 0.55223(16) 0.4487(2) 0.0713(16) Uani 1 1 d . . . . .
F30 F 0.2776(3) 0.43808(15) 0.3412(2) 0.0595(13) Uani 1 1 d . . . . .
F31 F -0.3560(3) 0.45125(14) -0.01112(16) 0.0467(10) Uani 1 1 d . . . . .
F36 F -0.3191(3) 0.64423(17) 0.31829(18) 0.0537(12) Uani 1 1 d . . . . .
F37 F -0.3852(3) 0.66059(18) 0.39420(18) 0.0619(13) Uani 1 1 d . . . . .
F38 F -0.5342(3) 0.62861(16) 0.39253(18) 0.0573(12) Uani 1 1 d . . . . .
F39 F -0.6175(3) 0.57937(16) 0.3141(2) 0.0629(14) Uani 1 1 d . . . . .
F40 F -0.5508(3) 0.56139(16) 0.2382(2) 0.0613(14) Uani 1 1 d . . . . .
Ag1 Ag 0.23804(3) 0.19408(2) 0.39268(2) 0.02753(12) Uani 1 1 d . . . . .
Ag2 Ag 0.16825(3) 0.22390(2) 0.66894(2) 0.02850(12) Uani 1 1 d . . . . .
Ag3 Ag -0.03188(3) 0.37348(2) 0.31672(2) 0.02694(12) Uani 1 1 d . . . . .
Ag4 Ag -0.31049(3) 0.55819(2) 0.14413(2) 0.03043(12) Uani 1 1 d . . . . .
N1 N 0.2166(4) 0.20182(18) 0.7362(2) 0.0325(12) Uani 1 1 d . . . . .
N2 N 0.2458(4) 0.19060(18) 0.6425(2) 0.0318(12) Uani 1 1 d . . . . .
N3 N 0.1069(4) 0.24910(18) 0.6044(2) 0.0337(13) Uani 1 1 d . . . . .
N4 N 0.1005(4) 0.25422(18) 0.7041(2) 0.0317(12) Uani 1 1 d . . . . .
N5 N 0.1959(3) 0.16070(17) 0.33249(19) 0.0273(11) Uani 1 1 d . . . . .
N6 N 0.1540(4) 0.17146(17) 0.4224(2) 0.0309(12) Uani 1 1 d . . . . .
N7 N 0.2902(4) 0.23218(18) 0.4490(2) 0.0321(12) Uani 1 1 d . . . . .
N8 N 0.3125(3) 0.21241(18) 0.3550(2) 0.0292(12) Uani 1 1 d . . . . .
N9 N 0.0735(3) 0.36772(17) 0.3661(2) 0.0288(11) Uani 1 1 d . . . . .
N10 N -0.0117(4) 0.43394(18) 0.3049(2) 0.0332(12) Uani 1 1 d . . . . .
N11 N -0.1425(4) 0.37155(18) 0.2703(2) 0.0329(12) Uani 1 1 d . . . . .
N12 N -0.0384(3) 0.31422(17) 0.3362(2) 0.0287(11) Uani 1 1 d . . . . .
N13 N -0.3845(4) 0.60308(18) 0.1509(2) 0.0340(13) Uani 1 1 d . . . . .
C1 C 0.0466(4) 0.2615(2) 0.7687(3) 0.0354(15) Uani 1 1 d . . . . .
H1 H 0.0388 0.2606 0.8015 0.042 Uiso 1 1 calc R U . . .
C2 C 0.0888(4) 0.3297(2) 0.3923(2) 0.0278(13) Uani 1 1 d . . . . .
C3 C 0.1648(4) 0.3351(2) 0.4294(2) 0.0319(14) Uani 1 1 d . . . . .
H3 H 0.1925 0.3142 0.4531 0.038 Uiso 1 1 calc R U . . .
C4 C -0.1020(4) 0.2864(2) 0.3232(2) 0.0286(13) Uani 1 1 d . . . . .
C5 C -0.4178(5) 0.6178(2) 0.0119(3) 0.0383(16) Uani 1 1 d . . . . .
H5 H -0.4549 0.6385 -0.0071 0.046 Uiso 1 1 calc R U . . .
C6 C 0.3728(5) 0.2801(2) 0.4988(3) 0.0356(15) Uani 1 1 d . . . . .
H6 H 0.4145 0.3010 0.5109 0.043 Uiso 1 1 calc R U . . .
C7 C 0.3548(4) 0.2593(2) 0.4508(2) 0.0335(15) Uani 1 1 d . . . . .
C8 C -0.3245(4) 0.5640(2) 0.0331(3) 0.0323(14) Uani 1 1 d . . . . .
C9 C -0.0687(5) 0.4598(2) 0.2722(3) 0.0342(15) Uani 1 1 d . . . . .
C10 C 0.0248(4) 0.2992(2) 0.3749(2) 0.0266(13) Uani 1 1 d . . . . .
C11 C -0.4242(5) 0.6245(2) 0.1076(3) 0.0364(16) Uani 1 1 d . . . . .
C12 C 0.1512(4) 0.1809(2) 0.4702(2) 0.0320(14) Uani 1 1 d . . . . .
C13 C 0.0775(4) 0.1268(2) 0.3504(2) 0.0299(14) Uani 1 1 d . . . . .
C14 C 0.3737(5) 0.1174(2) 0.7441(3) 0.0414(18) Uani 1 1 d . . . . .
C15 C -0.3746(4) 0.5885(2) -0.0069(3) 0.0343(15) Uani 1 1 d . . . . .
H15 H -0.3777 0.5851 -0.0415 0.041 Uiso 1 1 calc R U . . .
C16 C -0.0044(5) 0.2813(2) 0.7273(3) 0.0340(15) Uani 1 1 d . . . . .
H16 H -0.0538 0.2961 0.7265 0.041 Uiso 1 1 calc R U . . .
C17 C -0.3689(5) 0.2044(3) 0.2531(3) 0.0479(19) Uani 1 1 d . . . . .
C18 C -0.2254(5) 0.3117(3) 0.5743(3) 0.0488(19) Uani 1 1 d . . . . .
C19 C 0.0007(5) 0.2869(2) 0.6342(3) 0.0351(15) Uani 1 1 d . . . . .
C20 C -0.0922(5) 0.3496(3) 0.6384(3) 0.0466(19) Uani 1 1 d . . . . .
C21 C -0.3610(5) 0.2328(3) 0.2928(3) 0.0465(19) Uani 1 1 d . . . . .
C22 C -0.2622(6) 0.4802(3) -0.1090(3) 0.056(2) Uani 1 1 d . . . . .
C23 C -0.2525(4) 0.2356(2) 0.2348(3) 0.0373(16) Uani 1 1 d . . . . .
C24 C 0.4552(6) 0.1249(3) 0.7689(3) 0.052(2) Uani 1 1 d . . . . .
C25 C 0.1899(5) 0.5022(3) 0.4213(3) 0.0480(19) Uani 1 1 d . . . . .
C26 C 0.3258(5) 0.5261(3) 0.4281(4) 0.051(2) Uani 1 1 d . . . . .
C27 C -0.1986(5) 0.4808(2) 0.2119(3) 0.0370(16) Uani 1 1 d . . . . .
C28 C -0.2348(5) 0.3509(3) 0.5950(4) 0.052(2) Uani 1 1 d . . . . .
C29 C 0.2537(6) 0.5301(3) 0.4411(3) 0.052(2) Uani 1 1 d . . . . .
C30 C -0.2702(5) 0.5103(2) -0.0142(3) 0.0362(16) Uani 1 1 d . . . . .
C31 C -0.2765(4) 0.5267(2) 0.0354(3) 0.0330(15) Uani 1 1 d . . . . .
C32 C 0.3974(8) 0.0431(3) 0.7693(5) 0.070(3) Uani 1 1 d . . . . .
C33 C -0.1667(5) 0.4530(2) 0.1328(3) 0.0382(16) Uani 1 1 d . . . . .
H33 H -0.1322 0.4294 0.1464 0.046 Uiso 1 1 calc R U . . .
C34 C 0.1201(5) 0.1249(2) 0.2662(3) 0.0334(15) Uani 1 1 d . . . . .
H34 H 0.0792 0.1069 0.2455 0.040 Uiso 1 1 calc R U . . .
C35 C -0.2224(6) 0.5177(3) -0.0891(3) 0.058(2) Uani 1 1 d . . . . .
C36 C -0.1909(5) 0.4651(2) 0.0835(3) 0.0386(16) Uani 1 1 d . . . . .
H36 H -0.1778 0.4505 0.0565 0.046 Uiso 1 1 calc R U . . .
C37 C -0.0308(5) 0.5012(2) 0.2752(3) 0.0419(18) Uani 1 1 d . . . . .
H37 H -0.0544 0.5260 0.2566 0.050 Uiso 1 1 calc R U . . .
C38 C 0.3457(7) 0.0741(3) 0.7445(4) 0.058(2) Uani 1 1 d . . . . .
C39 C 0.5078(7) 0.0935(4) 0.7938(4) 0.068(3) Uani 1 1 d . . . . .
C40 C 0.3379(5) 0.1419(2) 0.6339(3) 0.0435(18) Uani 1 1 d . . . . .
H40 H 0.3782 0.1199 0.6412 0.052 Uiso 1 1 calc R U . . .
C41 C -0.4844(5) 0.6407(2) 0.1684(3) 0.0402(17) Uani 1 1 d . . . . .
H41 H -0.5202 0.6528 0.1858 0.048 Uiso 1 1 calc R U . . .
C42 C 0.6040(5) 0.3151(3) 0.4320(3) 0.0459(19) Uani 1 1 d . . . . .
C43 C -0.3065(6) 0.5326(3) 0.2919(3) 0.053(2) Uani 1 1 d D . . . .
H43 H -0.327(5) 0.535(3) 0.315(2) 0.04(2) Uiso 1 1 d D . . . .
C44 C 0.0705(5) 0.2676(2) 0.5227(3) 0.0410(17) Uani 1 1 d . . . . .
H44 H 0.0702 0.2705 0.4884 0.049 Uiso 1 1 calc R U . . .
C45 C -0.4324(5) 0.6013(2) 0.2764(3) 0.0382(16) Uani 1 1 d . . . . .
C46 C -0.3933(5) 0.5901(2) 0.2356(3) 0.0379(16) Uani 1 1 d . . . . .
C47 C 0.0171(5) 0.2864(2) 0.5447(3) 0.0413(17) Uani 1 1 d . . . . .
H47 H -0.0277 0.3043 0.5281 0.050 Uiso 1 1 calc R U . . .
C48 C -0.5009(5) 0.6197(3) 0.3548(3) 0.0437(18) Uani 1 1 d . . . . .
C49 C -0.3921(5) 0.6271(3) 0.3167(3) 0.0444(18) Uani 1 1 d . . . . .
C50 C -0.5080(5) 0.5856(2) 0.2766(3) 0.0466(19) Uani 1 1 d . . . . .
C51 C -0.2519(6) 0.5031(3) 0.2863(3) 0.053(2) Uani 1 1 d . . . . .
H51 H -0.2237 0.4831 0.3110 0.064 Uiso 1 1 calc R U . . .
C52 C -0.5432(5) 0.5943(3) 0.3157(3) 0.049(2) Uani 1 1 d . . . . .
C53 C -0.4258(5) 0.6359(3) 0.3559(3) 0.0449(18) Uani 1 1 d . . . . .
C54 C 0.0645(5) 0.1139(2) 0.7099(3) 0.0393(16) Uani 1 1 d . . . . .
H54A H 0.0814 0.0858 0.7262 0.047 Uiso 1 1 calc R U . . .
H54B H 0.0969 0.1365 0.7320 0.047 Uiso 1 1 calc R U . . .
C55 C 0.0825(5) 0.1150(2) 0.6597(3) 0.0463(19) Uani 1 1 d . . . . .
H55A H 0.1422 0.1110 0.6645 0.056 Uiso 1 1 calc R U . . .
H55B H 0.0531 0.0913 0.6384 0.056 Uiso 1 1 calc R U . . .
C56 C -0.0456(5) 0.1606(2) 0.6800(3) 0.0448(18) Uani 1 1 d . . . . .
H56A H -0.0163 0.1843 0.7014 0.054 Uiso 1 1 calc R U . . .
H56B H -0.1053 0.1646 0.6753 0.054 Uiso 1 1 calc R U . . .
C57 C -0.0279(5) 0.1621(3) 0.6296(3) 0.0485(19) Uani 1 1 d . . . . .
H57A H -0.0609 0.1400 0.6071 0.058 Uiso 1 1 calc R U . . .
H57B H -0.0439 0.1905 0.6138 0.058 Uiso 1 1 calc R U . . .
C58 C 0.4904(6) 0.0058(3) 0.6500(3) 0.053(2) Uani 1 1 d . . . . .
H58A H 0.4338 0.0154 0.6330 0.063 Uiso 1 1 calc R U . . .
H58B H 0.4887 -0.0153 0.6765 0.063 Uiso 1 1 calc R U . . .
C59 C 0.5230(6) 0.0157(3) 0.5742(3) 0.056(2) Uani 1 1 d . . . . .
H59A H 0.4648 0.0244 0.5606 0.067 Uiso 1 1 calc R U . . .
H59B H 0.5417 0.0026 0.5467 0.067 Uiso 1 1 calc R U . . .
C60 C 0.5741(6) 0.0529(4) 0.5951(4) 0.064(3) Uani 1 1 d . . . . .
H60A H 0.5788 0.0721 0.5674 0.077 Uiso 1 1 calc R U . . .
H60B H 0.6300 0.0433 0.6137 0.077 Uiso 1 1 calc R U . . .
C61 C 0.5441(7) 0.0430(4) 0.6716(3) 0.070(3) Uani 1 1 d . . . . .
H61A H 0.6020 0.0334 0.6844 0.084 Uiso 1 1 calc R U . . .
H61B H 0.5269 0.0555 0.7000 0.084 Uiso 1 1 calc R U . . .
C62 C -0.2497(7) 0.1590(4) 0.3890(5) 0.082(3) Uani 1 1 d . . . . .
H62A H -0.2708 0.1505 0.3532 0.098 Uiso 1 1 calc R U . . .
H62B H -0.2926 0.1526 0.4061 0.098 Uiso 1 1 calc R U . . .
C63 C -0.2000(7) 0.2157(3) 0.4435(4) 0.067(3) Uani 1 1 d . . . . .
H63A H -0.2417 0.2105 0.4619 0.081 Uiso 1 1 calc R U . . .
H63B H -0.1868 0.2467 0.4456 0.081 Uiso 1 1 calc R U . . .
C64 C -0.1237(7) 0.1904(3) 0.4678(4) 0.066(3) Uani 1 1 d . . . . .
H64A H -0.0807 0.1968 0.4508 0.079 Uiso 1 1 calc R U . . .
H64B H -0.1025 0.1988 0.5037 0.079 Uiso 1 1 calc R U . . .
C65 C -0.1734(7) 0.1338(3) 0.4134(5) 0.072(3) Uani 1 1 d . . . . .
H65A H -0.1864 0.1028 0.4106 0.087 Uiso 1 1 calc R U . . .
H65B H -0.1314 0.1395 0.3954 0.087 Uiso 1 1 calc R U . . .
C66 C 0.4553(7) 0.2438(4) 0.6762(5) 0.077(3) Uani 1 1 d . . . . .
H66A H 0.4009 0.2388 0.6528 0.116 Uiso 1 1 calc R U . . .
H66B H 0.4716 0.2737 0.6736 0.116 Uiso 1 1 calc R U . . .
H66C H 0.4534 0.2381 0.7108 0.116 Uiso 1 1 calc R U . . .
C67 C 0.5263(7) 0.2203(4) 0.6105(4) 0.070(3) Uani 1 1 d . . . . .
H67A H 0.5464 0.2498 0.6080 0.084 Uiso 1 1 calc R U . . .
H67B H 0.4710 0.2179 0.5863 0.084 Uiso 1 1 calc R U . . .
C68 C 0.5838(8) 0.1889(4) 0.5948(4) 0.073(3) Uani 1 1 d . . . . .
H68A H 0.6385 0.1902 0.6197 0.087 Uiso 1 1 calc R U . . .
H68B H 0.5623 0.1594 0.5954 0.087 Uiso 1 1 calc R U . . .
C69 C 0.5931(7) 0.1979(4) 0.5433(5) 0.079(3) Uani 1 1 d . . . . .
H69A H 0.6193 0.2263 0.5436 0.094 Uiso 1 1 calc R U . . .
H69B H 0.5378 0.1992 0.5190 0.094 Uiso 1 1 calc R U . . .
C70 C 0.7305(7) 0.1562(5) 0.5582(5) 0.091(4) Uani 1 1 d . . . . .
H70A H 0.7282 0.1409 0.5888 0.137 Uiso 1 1 calc R U . . .
H70B H 0.7585 0.1838 0.5675 0.137 Uiso 1 1 calc R U . . .
H70C H 0.7607 0.1389 0.5396 0.137 Uiso 1 1 calc R U . . .
C71 C 0.5178(7) 0.2140(4) 0.6631(4) 0.068(3) Uani 1 1 d . . . . .
H71A H 0.5721 0.2186 0.6877 0.082 Uiso 1 1 calc R U . . .
H71B H 0.5014 0.1839 0.6666 0.082 Uiso 1 1 calc R U . . .
C72 C 0.6444(8) 0.1640(4) 0.5254(5) 0.084(3) Uani 1 1 d . . . . .
H72A H 0.6142 0.1365 0.5216 0.101 Uiso 1 1 calc R U . . .
H72B H 0.6479 0.1725 0.4915 0.101 Uiso 1 1 calc R U . . .
C73 C -0.1865(8) 0.3894(4) 0.3896(5) 0.041(3) Uani 0.5 1 d D U P A 2
H73A H -0.2180 0.3755 0.3579 0.049 Uiso 0.5 1 calc R U P A 2
H73B H -0.2245 0.4075 0.4024 0.049 Uiso 0.5 1 calc R U P A 2
C74 C -0.0644(10) 0.4277(5) 0.4308(6) 0.057(3) Uani 0.5 1 d D U P A 2
H74A H -0.0172 0.4430 0.4243 0.069 Uiso 0.5 1 calc R U P A 2
H74B H -0.0934 0.4483 0.4473 0.069 Uiso 0.5 1 calc R U P A 2
C75 C -0.1467(8) 0.3566(5) 0.4276(5) 0.041(3) Uani 0.5 1 d D U P A 2
H75A H -0.1901 0.3377 0.4335 0.049 Uiso 0.5 1 calc R U P A 2
H75B H -0.1108 0.3386 0.4130 0.049 Uiso 0.5 1 calc R U P A 2
C82 C -0.0329(11) 0.3931(6) 0.4658(7) 0.068(4) Uani 0.5 1 d D U P A 2
H82A H 0.0002 0.3731 0.4515 0.082 Uiso 0.5 1 calc R U P A 2
H82B H 0.0024 0.4047 0.4980 0.082 Uiso 0.5 1 calc R U P A 2
C85 C 0.0155(6) -0.0075(3) 0.4543(4) 0.059(2) Uani 1 1 d . . . . .
H85A H 0.0681 0.0080 0.4588 0.070 Uiso 1 1 calc R U . . .
H85B H 0.0010 -0.0212 0.4206 0.070 Uiso 1 1 calc R U . . .
C86 C -0.0263(7) 0.0416(3) 0.5059(4) 0.060(2) Uani 1 1 d . . . . .
H86A H -0.0705 0.0615 0.5084 0.072 Uiso 1 1 calc R U . . .
H86B H 0.0252 0.0582 0.5114 0.072 Uiso 1 1 calc R U . . .
O1 O -0.0204(3) 0.12057(16) 0.7048(2) 0.0431(12) Uani 1 1 d . . . . .
O2 O 0.0574(3) 0.15486(16) 0.6352(2) 0.0458(13) Uani 1 1 d . . . . .
O3 O -0.2326(4) 0.2036(2) 0.3921(3) 0.0653(17) Uani 1 1 d . . . . .
O4 O -0.1416(5) 0.1448(2) 0.4643(3) 0.0709(19) Uani 1 1 d . . . . .
O5 O 0.5362(5) 0.0766(3) 0.6298(3) 0.081(2) Uani 1 1 d . . . . .
O6 O 0.5310(5) -0.0129(3) 0.6129(3) 0.086(2) Uani 1 1 d . . . . .
O7 O -0.1218(6) 0.4147(3) 0.3813(4) 0.050(2) Uani 0.5 1 d D U P A 2
O8 O -0.0998(7) 0.3720(4) 0.4740(4) 0.057(3) Uani 0.5 1 d D U P A 2
O13 O -0.0471(4) 0.0225(2) 0.4566(2) 0.0596(16) Uani 1 1 d . . . . .
N14 N -0.2446(4) 0.51231(18) 0.1267(2) 0.0349(13) Uani 1 1 d . . . . .
N15 N -0.2933(4) 0.54049(18) 0.2142(2) 0.0372(13) Uani 1 1 d . . . . .
F4 F -0.2911(3) 0.29300(18) 0.5425(2) 0.0691(15) Uani 1 1 d . . . . .
F6 F 0.4849(3) 0.16594(19) 0.7709(2) 0.0719(15) Uani 1 1 d . . . . .
F8 F 0.5278(5) 0.0210(2) 0.8174(3) 0.100(3) Uani 1 1 d . . . . .
F10 F 0.2690(4) 0.06534(17) 0.7219(3) 0.0839(19) Uani 1 1 d . . . . .
F13 F 0.6476(3) 0.38724(19) 0.4408(2) 0.0659(15) Uani 1 1 d . . . . .
F17 F -0.2082(3) 0.11461(19) 0.2527(2) 0.0689(15) Uani 1 1 d . . . . .
F18 F -0.2006(3) 0.02680(18) 0.26024(19) 0.0645(15) Uani 1 1 d . . . . .
F22 F -0.4142(3) 0.2313(2) 0.3207(2) 0.0688(15) Uani 1 1 d . . . . .
F32 F -0.3500(4) 0.42331(16) -0.10204(19) 0.0623(14) Uani 1 1 d . . . . .
F33 F -0.2601(4) 0.4656(2) -0.15317(19) 0.0792(18) Uani 1 1 d . . . . .
F34 F -0.1783(4) 0.5386(2) -0.1146(2) 0.0793(18) Uani 1 1 d . . . . .
N16 N -0.3379(4) 0.58079(17) 0.0761(2) 0.0329(12) Uani 1 1 d . . . . .
F1 F -0.0296(3) 0.36995(15) 0.6707(2) 0.0586(13) Uani 1 1 d . . . . .
F14 F 0.4913(3) 0.41344(15) 0.4322(2) 0.0612(13) Uani 1 1 d . . . . .
F19 F -0.0622(4) -0.01085(14) 0.3181(2) 0.0726(16) Uani 1 1 d . . . . .
F20 F 0.0703(3) 0.03706(14) 0.3620(2) 0.0594(13) Uani 1 1 d . . . . .
F26 F 0.1210(3) 0.50634(18) 0.4357(2) 0.0640(14) Uani 1 1 d . . . . .
F29 F 0.4028(3) 0.49139(17) 0.3813(3) 0.0739(17) Uani 1 1 d . . . . .
F35 F -0.1864(3) 0.56828(16) -0.02430(19) 0.0565(12) Uani 1 1 d . . . . .
C87 C 0.1324(4) 0.3973(2) 0.3848(2) 0.0308(14) Uani 1 1 d . . . . .
C88 C -0.2392(5) 0.5032(2) 0.0789(3) 0.0366(16) Uani 1 1 d . . . . .
C89 C -0.3976(4) 0.6120(2) 0.0653(3) 0.0337(15) Uani 1 1 d . . . . .
C90 C 0.2442(5) 0.1904(2) 0.5927(2) 0.0324(15) Uani 1 1 d . . . . .
C91 C 0.2961(4) 0.1977(2) 0.3068(2) 0.0312(14) Uani 1 1 d . . . . .
C92 C 0.1127(4) 0.2428(2) 0.7543(2) 0.0313(14) Uani 1 1 d . . . . .
C93 C 0.1279(5) 0.2426(2) 0.5602(2) 0.0335(15) Uani 1 1 d . . . . .
C94 C 0.3512(4) 0.2206(2) 0.2843(3) 0.0333(15) Uani 1 1 d . . . . .
H94 H 0.3554 0.2173 0.2509 0.040 Uiso 1 1 calc R U . . .
C95 C 0.0002(4) 0.2573(2) 0.3867(2) 0.0309(14) Uani 1 1 d . . . . .
H95 H 0.0313 0.2383 0.4117 0.037 Uiso 1 1 calc R U . . .
C96 C 0.2671(4) 0.2342(2) 0.4931(2) 0.0325(14) Uani 1 1 d . . . . .
C97 C 0.2727(4) 0.1709(2) 0.7525(2) 0.0328(15) Uani 1 1 d . . . . .
C98 C -0.1935(4) 0.3367(2) 0.2620(2) 0.0313(14) Uani 1 1 d . . . . .
C99 C -0.0767(4) 0.2499(2) 0.3550(2) 0.0307(14) Uani 1 1 d . . . . .
H99 H -0.1082 0.2245 0.3544 0.037 Uiso 1 1 calc R U . . .
C100 C 0.5872(5) 0.3581(3) 0.4341(3) 0.049(2) Uani 1 1 d . . . . .
C101 C 0.0856(5) 0.1563(2) 0.4793(3) 0.0373(16) Uani 1 1 d . . . . .
H101 H 0.0692 0.1560 0.5096 0.045 Uiso 1 1 calc R U . . .
C102 C 0.3718(4) 0.2434(2) 0.3651(3) 0.0332(15) Uani 1 1 d . . . . .
C103 C 0.1266(4) 0.1359(2) 0.3181(2) 0.0302(14) Uani 1 1 d . . . . .
C104 C -0.2274(5) 0.5322(3) -0.0425(3) 0.0476(19) Uani 1 1 d . . . . .
C105 C -0.3150(5) 0.2055(2) 0.2239(3) 0.0433(18) Uani 1 1 d . . . . .
C106 C 0.0935(4) 0.1430(2) 0.3998(2) 0.0308(14) Uani 1 1 d . . . . .
C107 C 0.0030(4) 0.1008(2) 0.3293(2) 0.0311(14) Uani 1 1 d . . . . .
C108 C -0.1358(6) 0.0507(3) 0.2840(3) 0.047(2) Uani 1 1 d . . . . .
C109 C -0.2423(4) 0.2646(2) 0.2743(3) 0.0320(14) Uani 1 1 d . . . . .
C110 C -0.2028(5) 0.4825(2) 0.1602(3) 0.0361(16) Uani 1 1 d . . . . .
C111 C -0.1799(4) 0.4061(2) 0.2424(3) 0.0340(15) Uani 1 1 d . . . . .
C112 C 0.1916(4) 0.3765(2) 0.4249(3) 0.0353(15) Uani 1 1 d . . . . .
H112 H 0.2410 0.3889 0.4450 0.042 Uiso 1 1 calc R U . . .
C113 C 0.0389(5) 0.2749(2) 0.5972(3) 0.0351(15) Uani 1 1 d . . . . .
C114 C -0.1758(4) 0.2967(2) 0.2862(2) 0.0297(14) Uani 1 1 d . . . . .
C115 C 0.0575(5) 0.4563(2) 0.3291(3) 0.0344(15) Uani 1 1 d . . . . .
C116 C 0.1911(5) 0.2156(2) 0.5551(2) 0.0337(15) Uani 1 1 d . . . . .
C117 C 0.1792(4) 0.2139(2) 0.7723(3) 0.0338(15) Uani 1 1 d . . . . .
C118 C 0.2303(4) 0.1681(2) 0.2932(3) 0.0324(14) Uani 1 1 d . . . . .
C119 C 0.3048(5) 0.1605(2) 0.5878(3) 0.0422(18) Uani 1 1 d . . . . .
H119 H 0.3198 0.1545 0.5578 0.051 Uiso 1 1 calc R U . . .
C120 C 0.0020(5) 0.0565(2) 0.3350(3) 0.0409(17) Uani 1 1 d . . . . .
C121 C -0.4204(5) 0.6113(2) 0.1890(3) 0.0357(15) Uani 1 1 d . . . . .
C122 C 0.3933(4) 0.2651(2) 0.4122(3) 0.0336(15) Uani 1 1 d . . . . .
C123 C -0.2602(5) 0.3914(2) 0.2142(3) 0.0389(16) Uani 1 1 d . . . . .
H123 H -0.3005 0.4081 0.1910 0.047 Uiso 1 1 calc R U . . .
C124 C 0.1819(4) 0.1445(2) 0.2517(3) 0.0329(15) Uani 1 1 d . . . . .
H124 H 0.1909 0.1427 0.2193 0.039 Uiso 1 1 calc R U . . .
C125 C 0.1943(5) 0.4702(2) 0.3875(3) 0.0395(16) Uani 1 1 d . . . . .
C126 C 0.4465(4) 0.3411(2) 0.4234(3) 0.0347(15) Uani 1 1 d . . . . .
C127 C 0.2734(5) 0.1631(2) 0.8041(2) 0.0345(15) Uani 1 1 d . . . . .
H127 H 0.3076 0.1431 0.8264 0.041 Uiso 1 1 calc R U . . .
C128 C 0.2026(4) 0.2104(2) 0.5030(2) 0.0325(15) Uani 1 1 d . . . . .
C129 C -0.1388(5) 0.0951(3) 0.2790(3) 0.0433(18) Uani 1 1 d . . . . .
C130 C -0.3344(5) 0.5570(2) 0.2471(3) 0.0427(18) Uani 1 1 d . . . . .
C131 C -0.1459(5) 0.4472(2) 0.2431(3) 0.0358(15) Uani 1 1 d . . . . .
C132 C -0.1494(5) 0.2920(2) 0.5856(3) 0.0412(17) Uani 1 1 d . . . . .
C133 C -0.2436(5) 0.5073(2) 0.2363(3) 0.0419(17) Uani 1 1 d . . . . .
C134 C 0.4606(4) 0.2977(2) 0.4203(2) 0.0343(15) Uani 1 1 d . . . . .
C135 C -0.2984(5) 0.2626(2) 0.3021(3) 0.0388(16) Uani 1 1 d . . . . .
C136 C 0.0292(4) 0.2757(2) 0.6855(3) 0.0320(14) Uani 1 1 d . . . . .
C137 C 0.4758(7) 0.0514(3) 0.7930(4) 0.063(3) Uani 1 1 d . . . . .
C138 C 0.3154(5) 0.1515(2) 0.7211(3) 0.0364(16) Uani 1 1 d . . . . .
C139 C 0.2170(4) 0.1890(2) 0.8155(2) 0.0342(15) Uani 1 1 d . . . . .
H139 H 0.2048 0.1904 0.8470 0.041 Uiso 1 1 calc R U . . .
C140 C -0.0661(6) 0.0321(2) 0.3125(3) 0.0455(19) Uani 1 1 d . . . . .
C141 C 0.3198(5) 0.2650(2) 0.5243(2) 0.0367(16) Uani 1 1 d . . . . .
H141 H 0.3185 0.2735 0.5571 0.044 Uiso 1 1 calc R U . . .
C142 C -0.3075(6) 0.4579(3) -0.0816(3) 0.049(2) Uani 1 1 d . . . . .
C143 C -0.1673(5) 0.3695(3) 0.6277(3) 0.051(2) Uani 1 1 d . . . . .
C144 C 0.3014(5) 0.1615(2) 0.6694(3) 0.0357(16) Uani 1 1 d . . . . .
C145 C 0.3961(4) 0.2479(2) 0.3201(3) 0.0350(15) Uani 1 1 d . . . . .
H145 H 0.4373 0.2670 0.3157 0.042 Uiso 1 1 calc R U . . .
C146 C -0.0705(5) 0.1185(2) 0.3018(3) 0.0381(16) Uani 1 1 d . . . . .
C147 C -0.2683(4) 0.3500(2) 0.2262(3) 0.0382(16) Uani 1 1 d . . . . .
H147 H -0.3155 0.3326 0.2133 0.046 Uiso 1 1 calc R U . . .
C148 C 0.0443(5) 0.4992(2) 0.3089(3) 0.0414(18) Uani 1 1 d . . . . .
H148 H 0.0822 0.5223 0.3179 0.050 Uiso 1 1 calc R U . . .
C149 C 0.5416(5) 0.2859(2) 0.4249(3) 0.0386(16) Uani 1 1 d . . . . .
C150 C 0.0506(5) 0.1333(2) 0.4363(3) 0.0332(15) Uani 1 1 d . . . . .
H150 H 0.0055 0.1142 0.4316 0.040 Uiso 1 1 calc R U . . .
C151 C -0.3105(5) 0.4731(2) -0.0352(3) 0.0394(17) Uani 1 1 d . . . . .
C152 C -0.0793(5) 0.3101(2) 0.6184(3) 0.0382(16) Uani 1 1 d . . . . .
C153 C 0.3328(5) 0.4953(3) 0.3944(4) 0.052(2) Uani 1 1 d . . . . .
C154 C 0.5083(5) 0.3712(3) 0.4301(3) 0.0459(18) Uani 1 1 d . . . . .
C155 C 0.1251(5) 0.4404(2) 0.3655(3) 0.0341(15) Uani 1 1 d . . . . .
C156 C 0.2680(5) 0.4679(2) 0.3749(3) 0.0448(18) Uani 1 1 d . . . . .
C157 C -0.4867(5) 0.6493(2) 0.1189(3) 0.0405(17) Uani 1 1 d . . . . .
H157 H -0.5234 0.6682 0.0967 0.049 Uiso 1 1 calc R U . . .
C158 C 0.4164(12) 0.4728(7) 0.5712(7) 0.066(4) Uani 0.5 1 d D U P B 1
H15D H 0.4742 0.4695 0.5917 0.080 Uiso 0.5 1 calc R U P B 1
H15E H 0.4089 0.5024 0.5577 0.080 Uiso 0.5 1 calc R U P B 1
O9 O 0.3186(7) 0.4493(4) 0.4980(4) 0.059(3) Uani 0.5 1 d D U P B 1
O10 O 0.3617(8) 0.4651(5) 0.6021(5) 0.067(3) Uani 0.5 1 d D U P B 1
C76 C 0.3968(9) 0.4398(6) 0.5271(6) 0.053(3) Uani 0.5 1 d D U P B 1
H76A H 0.4368 0.4425 0.5071 0.063 Uiso 0.5 1 calc R U P B 1
H76B H 0.3991 0.4101 0.5403 0.063 Uiso 0.5 1 calc R U P B 1
C78 C 0.2810(10) 0.4735(6) 0.5696(6) 0.063(3) Uani 0.5 1 d D U P B 1
H78A H 0.2780 0.5030 0.5560 0.075 Uiso 0.5 1 calc R U P B 1
H78B H 0.2395 0.4705 0.5886 0.075 Uiso 0.5 1 calc R U P B 1
C166 C 0.2651(12) 0.4421(6) 0.5283(7) 0.063(3) Uani 0.5 1 d D U P B 1
H16N H 0.2734 0.4127 0.5424 0.076 Uiso 0.5 1 calc R U P B 1
H16O H 0.2073 0.4446 0.5075 0.076 Uiso 0.5 1 calc R U P B 1
C77 C 0.1116(13) 0.4159(6) 0.6383(7) 0.059(5) Uani 0.5 1 d . . P C 1
H77A H 0.0851 0.4199 0.6657 0.071 Uiso 0.5 1 calc R U P C 1
H77B H 0.1663 0.4298 0.6489 0.071 Uiso 0.5 1 calc R U P C 1
C79 C 0.1568(12) 0.3670(8) 0.5902(7) 0.064(5) Uani 0.5 1 d . . P C 1
H79A H 0.2108 0.3816 0.5979 0.077 Uiso 0.5 1 calc R U P C 1
H79B H 0.1652 0.3363 0.5836 0.077 Uiso 0.5 1 calc R U P C 1
C80 C 0.067(2) 0.4356(11) 0.5972(11) 0.094(10) Uani 0.5 1 d . . P C 1
H80A H 0.0657 0.4668 0.6038 0.112 Uiso 0.5 1 calc R U P C 1
H80B H 0.0093 0.4249 0.5891 0.112 Uiso 0.5 1 calc R U P C 1
C84 C 0.1042(16) 0.3851(7) 0.5486(10) 0.082(7) Uani 0.5 1 d . . P C 1
H84A H 0.1223 0.3775 0.5185 0.099 Uiso 0.5 1 calc R U P C 1
H84B H 0.0485 0.3730 0.5440 0.099 Uiso 0.5 1 calc R U P C 1
O11 O 0.1231(11) 0.3708(5) 0.6322(6) 0.090(5) Uani 0.5 1 d . . P C 1
O12 O 0.1004(12) 0.4280(5) 0.5519(7) 0.104(7) Uani 0.5 1 d . . P C 1
C160 C 0.127(3) 0.4590(11) 0.5807(19) 0.172(10) Uani 0.5 1 d D U P D 2
H16A H 0.1640 0.4816 0.5994 0.207 Uiso 0.5 1 calc R U P D 2
H16B H 0.1030 0.4685 0.5455 0.207 Uiso 0.5 1 calc R U P D 2
C165 C 0.409(2) 0.4825(15) 0.5331(17) 0.163(11) Uani 0.5 1 d D U P D 2
H16C H 0.4199 0.5108 0.5207 0.245 Uiso 0.5 1 calc R U P D 2
H16D H 0.4598 0.4718 0.5570 0.245 Uiso 0.5 1 calc R U P D 2
H16E H 0.3922 0.4625 0.5047 0.245 Uiso 0.5 1 calc R U P D 2
C164 C 0.336(3) 0.4864(11) 0.5618(18) 0.183(9) Uani 0.5 1 d D U P D 2
H16F H 0.3523 0.5063 0.5908 0.219 Uiso 0.5 1 calc R U P D 2
H16G H 0.2843 0.4970 0.5382 0.219 Uiso 0.5 1 calc R U P D 2
C162 C 0.236(2) 0.4201(13) 0.5447(15) 0.185(9) Uani 0.5 1 d D U P D 2
H16H H 0.2429 0.3928 0.5282 0.222 Uiso 0.5 1 calc R U P D 2
H16I H 0.2110 0.4415 0.5183 0.222 Uiso 0.5 1 calc R U P D 2
C161 C 0.176(2) 0.4130(11) 0.5826(18) 0.182(9) Uani 0.5 1 d D U P D 2
H16J H 0.2097 0.4066 0.6174 0.218 Uiso 0.5 1 calc R U P D 2
H16K H 0.1372 0.3891 0.5706 0.218 Uiso 0.5 1 calc R U P D 2
C159 C 0.053(3) 0.4488(16) 0.608(2) 0.169(14) Uani 0.5 1 d D U P D 2
H15A H 0.0007 0.4597 0.5865 0.254 Uiso 0.5 1 calc R U P D 2
H15B H 0.0661 0.4630 0.6408 0.254 Uiso 0.5 1 calc R U P D 2
H15C H 0.0493 0.4178 0.6123 0.254 Uiso 0.5 1 calc R U P D 2
C163 C 0.3239(17) 0.4374(13) 0.5809(15) 0.181(9) Uani 0.5 1 d D U P D 2
H16L H 0.3693 0.4186 0.5776 0.218 Uiso 0.5 1 calc R U P D 2
H16M H 0.3234 0.4376 0.6167 0.218 Uiso 0.5 1 calc R U P D 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag 0.1306 4.2820 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N5 Ag1 N8 80.5(2) . .
N5 Ag1 N6 91.6(2) . .
N8 Ag1 N6 172.1(2) . .
N5 Ag1 N7 172.2(2) . .
N8 Ag1 N7 91.8(2) . .
N6 Ag1 N7 96.0(2) . .
N1 Ag2 N4 81.1(2) . .
N1 Ag2 N3 172.1(2) . .
N4 Ag2 N3 91.3(2) . .
N1 Ag2 N2 91.1(2) . .
N4 Ag2 N2 172.2(2) . .
N3 Ag2 N2 96.5(2) . .
N9 Ag3 N12 80.1(2) . .
N9 Ag3 N11 171.9(2) . .
N12 Ag3 N11 92.0(2) . .
N9 Ag3 N10 92.1(2) . .
N12 Ag3 N10 172.1(2) . .
N11 Ag3 N10 95.7(2) . .
N13 Ag4 N16 80.9(2) . .
N13 Ag4 N14 171.5(2) . .
N16 Ag4 N14 91.6(2) . .
N13 Ag4 N15 91.8(2) . .
N16 Ag4 N15 172.7(2) . .
N14 Ag4 N15 95.6(2) . .
C97 N1 C117 112.3(6) . .
C97 N1 Ag2 130.6(5) . .
C117 N1 Ag2 116.1(5) . .
C90 N2 C144 111.2(6) . .
C90 N2 Ag2 123.1(5) . .
C144 N2 Ag2 125.3(4) . .
C93 N3 C113 111.7(6) . .
C93 N3 Ag2 123.0(5) . .
C113 N3 Ag2 125.3(4) . .
C136 N4 C92 112.1(6) . .
C136 N4 Ag2 129.9(4) . .
C92 N4 Ag2 115.4(5) . .
C103 N5 C118 112.3(5) . .
C103 N5 Ag1 129.8(4) . .
C118 N5 Ag1 116.8(4) . .
C106 N6 C12 111.0(5) . .
C106 N6 Ag1 125.5(4) . .
C12 N6 Ag1 123.4(5) . .
C7 N7 C96 111.0(6) . .
C7 N7 Ag1 125.5(4) . .
C96 N7 Ag1 123.5(5) . .
C91 N8 C102 112.1(5) . .
C91 N8 Ag1 116.2(4) . .
C102 N8 Ag1 130.7(5) . .
C87 N9 C2 112.0(6) . .
C87 N9 Ag3 130.3(5) . .
C2 N9 Ag3 117.0(4) . .
C115 N10 C9 111.7(6) . .
C115 N10 Ag3 125.1(5) . .
C9 N10 Ag3 123.2(5) . .
C98 N11 C111 111.0(6) . .
C98 N11 Ag3 125.4(4) . .
C111 N11 Ag3 123.6(5) . .
C4 N12 C10 112.4(5) . .
C4 N12 Ag3 129.9(4) . .
C10 N12 Ag3 116.8(4) . .
C11 N13 C121 111.3(6) . .
C11 N13 Ag4 116.4(5) . .
C121 N13 Ag4 130.4(5) . .
C16 C1 C92 108.4(6) . .
C16 C1 H1 125.8 . .
C92 C1 H1 125.8 . .
N9 C2 C3 106.2(6) . .
N9 C2 C10 112.6(6) . .
C3 C2 C10 141.3(6) . .
C112 C3 C2 107.5(6) . .
C112 C3 H3 126.2 . .
C2 C3 H3 126.2 . .
N12 C4 C114 121.7(6) . .
N12 C4 C99 105.5(6) . .
C114 C4 C99 132.8(6) . .
C15 C5 C89 108.0(6) . .
C15 C5 H5 126.0 . .
C89 C5 H5 126.0 . .
C141 C6 C7 108.6(6) . .
C141 C6 H6 125.7 . .
C7 C6 H6 125.7 . .
N7 C7 C122 125.7(6) . .
N7 C7 C6 106.0(6) . .
C122 C7 C6 128.3(7) . .
N16 C8 C31 120.4(6) . .
N16 C8 C15 105.2(6) . .
C31 C8 C15 133.9(6) . .
N10 C9 C131 125.9(6) . .
N10 C9 C37 105.5(6) . .
C131 C9 C37 128.6(7) . .
N12 C10 C2 113.1(5) . .
N12 C10 C95 106.0(6) . .
C2 C10 C95 140.7(6) . .
N13 C11 C157 106.8(6) . .
N13 C11 C89 113.2(6) . .
C157 C11 C89 139.5(7) . .
N6 C12 C128 125.4(6) . .
N6 C12 C101 107.0(6) . .
C128 C12 C101 127.5(6) . .
C103 C13 C106 123.7(6) . .
C103 C13 C107 116.9(6) . .
C106 C13 C107 119.4(6) . .
C24 C14 C38 116.3(8) . .
C24 C14 C138 123.4(7) . .
C38 C14 C138 120.2(8) . .
C5 C15 C8 109.6(6) . .
C5 C15 H15 125.2 . .
C8 C15 H15 125.2 . .
C1 C16 C136 108.5(6) . .
C1 C16 H16 125.7 . .
C136 C16 H16 125.7 . .
F23 C17 C105 120.2(7) . .
F23 C17 C21 119.0(7) . .
C105 C17 C21 120.9(7) . .
F4 C18 C28 119.1(8) . .
F4 C18 C132 120.3(8) . .
C28 C18 C132 120.6(8) . .
C113 C19 C136 124.6(7) . .
C113 C19 C152 118.9(6) . .
C136 C19 C152 116.3(6) . .
F1 C20 C143 116.5(7) . .
F1 C20 C152 120.0(7) . .
C143 C20 C152 123.5(8) . .
F22 C21 C135 121.5(7) . .
F22 C21 C17 119.9(7) . .
C135 C21 C17 118.6(7) . .
F33 C22 C35 121.7(9) . .
F33 C22 C142 119.4(9) . .
C35 C22 C142 118.8(7) . .
F25 C23 C105 117.8(7) . .
F25 C23 C109 120.0(6) . .
C105 C23 C109 122.2(7) . .
F6 C24 C39 117.7(9) . .
F6 C24 C14 118.9(7) . .
C39 C24 C14 123.3(9) . .
F26 C25 C29 118.3(7) . .
F26 C25 C125 118.9(7) . .
C29 C25 C125 122.7(8) . .
F28 C26 C153 120.5(8) . .
F28 C26 C29 119.8(8) . .
C153 C26 C29 119.7(7) . .
C110 C27 C133 125.4(7) . .
C110 C27 C131 117.7(6) . .
C133 C27 C131 116.9(6) . .
F3 C28 C143 121.0(8) . .
F3 C28 C18 120.5(8) . .
C143 C28 C18 118.4(8) . .
F27 C29 C26 120.3(8) . .
F27 C29 C25 119.9(8) . .
C26 C29 C25 119.8(8) . .
C104 C30 C151 116.7(7) . .
C104 C30 C31 122.0(7) . .
C151 C30 C31 121.2(6) . .
C88 C31 C8 126.0(6) . .
C88 C31 C30 118.5(6) . .
C8 C31 C30 115.4(6) . .
C137 C32 F9 119.2(9) . .
C137 C32 C38 121.7(10) . .
F9 C32 C38 119.1(12) . .
C36 C33 C110 107.2(6) . .
C36 C33 H33 126.4 . .
C110 C33 H33 126.4 . .
C124 C34 C103 109.4(6) . .
C124 C34 H34 125.3 . .
C103 C34 H34 125.3 . .
F34 C35 C22 119.1(8) . .
F34 C35 C104 121.3(9) . .
C22 C35 C104 119.6(8) . .
C33 C36 C88 109.1(6) . .
C33 C36 H36 125.5 . .
C88 C36 H36 125.5 . .
C148 C37 C9 108.6(6) . .
C148 C37 H37 125.7 . .
C9 C37 H37 125.7 . .
F10 C38 C32 120.7(10) . .
F10 C38 C14 118.7(8) . .
C32 C38 C14 120.5(10) . .
F7 C39 C24 120.9(11) . .
F7 C39 C137 121.8(9) . .
C24 C39 C137 117.3(10) . .
C119 C40 C144 108.2(7) . .
C119 C40 H40 125.9 . .
C144 C40 H40 125.9 . .
C157 C41 C121 109.3(7) . .
C157 C41 H41 125.3 . .
C121 C41 H41 125.3 . .
F12 C42 C149 120.6(8) . .
F12 C42 C100 119.7(7) . .
C149 C42 C100 119.7(7) . .
C51 C43 C130 109.8(7) . .
C51 C43 H43 127(6) . .
C130 C43 H43 122(6) . .
C47 C44 C93 108.2(6) . .
C47 C44 H44 125.9 . .
C93 C44 H44 125.9 . .
C50 C45 C49 117.1(7) . .
C50 C45 C46 121.8(7) . .
C49 C45 C46 121.1(7) . .
C121 C46 C130 125.4(7) . .
C121 C46 C45 118.6(6) . .
C130 C46 C45 115.8(7) . .
C44 C47 C113 109.1(7) . .
C44 C47 H47 125.4 . .
C113 C47 H47 125.4 . .
F38 C48 C53 119.7(7) . .
F38 C48 C52 119.4(8) . .
C53 C48 C52 120.9(7) . .
F36 C49 C53 118.3(7) . .
F36 C49 C45 120.2(7) . .
C53 C49 C45 121.6(8) . .
F40 C50 C45 120.0(7) . .
F40 C50 C52 117.8(7) . .
C45 C50 C52 122.1(8) . .
C43 C51 C133 107.7(7) . .
C43 C51 H51 126.2 . .
C133 C51 H51 126.2 . .
F39 C52 C48 120.7(7) . .
F39 C52 C50 120.6(8) . .
C48 C52 C50 118.7(8) . .
F37 C53 C48 120.4(7) . .
F37 C53 C49 120.0(8) . .
C48 C53 C49 119.6(8) . .
O1 C54 C55 111.4(7) . .
O1 C54 H54A 109.4 . .
C55 C54 H54A 109.4 . .
O1 C54 H54B 109.4 . .
C55 C54 H54B 109.4 . .
H54A C54 H54B 108.0 . .
O2 C55 C54 110.4(6) . .
O2 C55 H55A 109.6 . .
C54 C55 H55A 109.6 . .
O2 C55 H55B 109.6 . .
C54 C55 H55B 109.6 . .
H55A C55 H55B 108.1 . .
O1 C56 C57 111.2(6) . .
O1 C56 H56A 109.4 . .
C57 C56 H56A 109.4 . .
O1 C56 H56B 109.4 . .
C57 C56 H56B 109.4 . .
H56A C56 H56B 108.0 . .
O2 C57 C56 110.4(7) . .
O2 C57 H57A 109.6 . .
C56 C57 H57A 109.6 . .
O2 C57 H57B 109.6 . .
C56 C57 H57B 109.6 . .
H57A C57 H57B 108.1 . .
C61 C58 O6 103.3(7) . .
C61 C58 H58A 111.1 . .
O6 C58 H58A 111.1 . .
C61 C58 H58B 111.1 . .
O6 C58 H58B 111.1 . .
H58A C58 H58B 109.1 . .
O6 C59 C60 106.7(8) . .
O6 C59 H59A 110.4 . .
C60 C59 H59A 110.4 . .
O6 C59 H59B 110.4 . .
C60 C59 H59B 110.4 . .
H59A C59 H59B 108.6 . .
C59 C60 O5 109.3(8) . .
C59 C60 H60A 109.8 . .
O5 C60 H60A 109.8 . .
C59 C60 H60B 109.8 . .
O5 C60 H60B 109.8 . .
H60A C60 H60B 108.3 . .
C58 C61 O5 108.2(7) . .
C58 C61 H61A 110.1 . .
O5 C61 H61A 110.1 . .
C58 C61 H61B 110.1 . .
O5 C61 H61B 110.1 . .
H61A C61 H61B 108.4 . .
O3 C62 C65 110.5(9) . .
O3 C62 H62A 109.5 . .
C65 C62 H62A 109.5 . .
O3 C62 H62B 109.5 . .
C65 C62 H62B 109.5 . .
H62A C62 H62B 108.1 . .
O3 C63 C64 110.8(8) . .
O3 C63 H63A 109.5 . .
C64 C63 H63A 109.5 . .
O3 C63 H63B 109.5 . .
C64 C63 H63B 109.5 . .
H63A C63 H63B 108.1 . .
O4 C64 C63 110.2(9) . .
O4 C64 H64A 109.6 . .
C63 C64 H64A 109.6 . .
O4 C64 H64B 109.6 . .
C63 C64 H64B 109.6 . .
H64A C64 H64B 108.1 . .
O4 C65 C62 111.4(9) . .
O4 C65 H65A 109.3 . .
C62 C65 H65A 109.3 . .
O4 C65 H65B 109.3 . .
C62 C65 H65B 109.3 . .
H65A C65 H65B 108.0 . .
C71 C66 H66A 109.5 . .
C71 C66 H66B 109.5 . .
H66A C66 H66B 109.5 . .
C71 C66 H66C 109.5 . .
H66A C66 H66C 109.5 . .
H66B C66 H66C 109.5 . .
C71 C67 C68 115.3(9) . .
C71 C67 H67A 108.4 . .
C68 C67 H67A 108.4 . .
C71 C67 H67B 108.4 . .
C68 C67 H67B 108.4 . .
H67A C67 H67B 107.5 . .
C69 C68 C67 113.1(10) . .
C69 C68 H68A 109.0 . .
C67 C68 H68A 109.0 . .
C69 C68 H68B 109.0 . .
C67 C68 H68B 109.0 . .
H68A C68 H68B 107.8 . .
C68 C69 C72 113.3(10) . .
C68 C69 H69A 108.9 . .
C72 C69 H69A 108.9 . .
C68 C69 H69B 108.9 . .
C72 C69 H69B 108.9 . .
H69A C69 H69B 107.7 . .
C72 C70 H70A 109.5 . .
C72 C70 H70B 109.5 . .
H70A C70 H70B 109.5 . .
C72 C70 H70C 109.5 . .
H70A C70 H70C 109.5 . .
H70B C70 H70C 109.5 . .
C67 C71 C66 114.0(9) . .
C67 C71 H71A 108.8 . .
C66 C71 H71A 108.8 . .
C67 C71 H71B 108.8 . .
C66 C71 H71B 108.8 . .
H71A C71 H71B 107.7 . .
C70 C72 C69 117.2(11) . .
C70 C72 H72A 108.0 . .
C69 C72 H72A 108.0 . .
C70 C72 H72B 108.0 . .
C69 C72 H72B 108.0 . .
H72A C72 H72B 107.2 . .
O7 C73 C75 106.0(12) . .
O7 C73 H73A 110.5 . .
C75 C73 H73A 110.5 . .
O7 C73 H73B 110.5 . .
C75 C73 H73B 110.5 . .
H73A C73 H73B 108.7 . .
C82 C74 O7 115.7(14) . .
C82 C74 H74A 108.4 . .
O7 C74 H74A 108.4 . .
C82 C74 H74B 108.4 . .
O7 C74 H74B 108.4 . .
H74A C74 H74B 107.4 . .
O8 C75 C73 116.4(13) . .
O8 C75 H75A 108.2 . .
C73 C75 H75A 108.2 . .
O8 C75 H75B 108.2 . .
C73 C75 H75B 108.2 . .
H75A C75 H75B 107.3 . .
O8 C82 C74 107.3(15) . .
O8 C82 H82A 110.3 . .
C74 C82 H82A 110.3 . .
O8 C82 H82B 110.3 . .
C74 C82 H82B 110.3 . .
H82A C82 H82B 108.5 . .
O13 C85 C86 111.8(7) . 3_556
O13 C85 H85A 109.3 . .
C86 C85 H85A 109.3 3_556 .
O13 C85 H85B 109.3 . .
C86 C85 H85B 109.3 3_556 .
H85A C85 H85B 107.9 . .
O13 C86 C85 110.4(8) . 3_556
O13 C86 H86A 109.6 . .
C85 C86 H86A 109.6 3_556 .
O13 C86 H86B 109.6 . .
C85 C86 H86B 109.6 3_556 .
H86A C86 H86B 108.1 . .
C54 O1 C56 109.6(6) . .
C55 O2 C57 110.5(6) . .
C62 O3 C63 109.5(8) . .
C65 O4 C64 108.7(7) . .
C60 O5 C61 100.5(8) . .
C59 O6 C58 108.4(7) . .
C73 O7 C74 109.7(11) . .
C82 O8 C75 107.3(12) . .
C85 O13 C86 108.9(7) . .
C110 N14 C88 110.5(6) . .
C110 N14 Ag4 123.9(5) . .
C88 N14 Ag4 125.5(5) . .
C133 N15 C130 110.3(6) . .
C133 N15 Ag4 124.1(5) . .
C130 N15 Ag4 125.4(5) . .
C8 N16 C89 111.7(6) . .
C8 N16 Ag4 130.4(5) . .
C89 N16 Ag4 115.6(5) . .
N9 C87 C112 105.8(6) . .
N9 C87 C155 121.1(6) . .
C112 C87 C155 133.0(7) . .
N14 C88 C31 125.5(6) . .
N14 C88 C36 105.9(6) . .
C31 C88 C36 128.6(7) . .
N16 C89 C11 113.4(6) . .
N16 C89 C5 105.4(6) . .
C11 C89 C5 140.8(7) . .
N2 C90 C116 124.7(6) . .
N2 C90 C119 106.6(6) . .
C116 C90 C119 128.7(6) . .
N8 C91 C118 114.2(6) . .
N8 C91 C94 105.9(6) . .
C118 C91 C94 139.8(6) . .
N4 C92 C1 105.4(6) . .
N4 C92 C117 113.3(6) . .
C1 C92 C117 140.9(6) . .
N3 C93 C116 124.8(6) . .
N3 C93 C44 105.7(6) . .
C116 C93 C44 129.5(6) . .
C145 C94 C91 107.1(6) . .
C145 C94 H94 126.5 . .
C91 C94 H94 126.5 . .
C99 C95 C10 107.0(6) . .
C99 C95 H95 126.5 . .
C10 C95 H95 126.5 . .
N7 C96 C128 124.9(6) . .
N7 C96 C141 106.3(6) . .
C128 C96 C141 128.8(6) . .
N1 C97 C138 122.6(6) . .
N1 C97 C127 105.3(6) . .
C138 C97 C127 132.0(7) . .
N11 C98 C114 125.7(6) . .
N11 C98 C147 106.4(6) . .
C114 C98 C147 127.8(6) . .
C95 C99 C4 109.1(6) . .
C95 C99 H99 125.4 . .
C4 C99 H99 125.4 . .
F13 C100 C154 119.9(8) . .
F13 C100 C42 120.5(8) . .
C154 C100 C42 119.6(7) . .
C150 C101 C12 107.3(6) . .
C150 C101 H101 126.3 . .
C12 C101 H101 126.3 . .
N8 C102 C145 105.5(6) . .
N8 C102 C122 120.8(6) . .
C145 C102 C122 133.6(7) . .
N5 C103 C13 122.6(6) . .
N5 C103 C34 104.1(6) . .
C13 C103 C34 133.2(7) . .
F35 C104 C30 120.0(7) . .
F35 C104 C35 117.3(7) . .
C30 C104 C35 122.7(8) . .
F24 C105 C17 119.7(7) . .
F24 C105 C23 121.6(7) . .
C17 C105 C23 118.7(7) . .
N6 C106 C13 126.3(6) . .
N6 C106 C150 106.1(6) . .
C13 C106 C150 127.6(6) . .
C146 C107 C120 115.0(7) . .
C146 C107 C13 122.5(6) . .
C120 C107 C13 122.4(7) . .
F18 C108 C140 120.8(8) . .
F18 C108 C129 120.1(8) . .
C140 C108 C129 119.1(7) . .
C135 C109 C23 116.9(6) . .
C135 C109 C114 120.7(6) . .
C23 C109 C114 122.5(6) . .
N14 C110 C27 125.6(6) . .
N14 C110 C33 107.3(6) . .
C27 C110 C33 127.1(6) . .
N11 C111 C131 125.7(7) . .
N11 C111 C123 105.9(6) . .
C131 C111 C123 128.4(6) . .
C3 C112 C87 108.5(6) . .
C3 C112 H112 125.8 . .
C87 C112 H112 125.8 . .
N3 C113 C19 126.0(6) . .
N3 C113 C47 105.2(6) . .
C19 C113 C47 128.7(7) . .
C98 C114 C4 124.9(6) . .
C98 C114 C109 116.5(6) . .
C4 C114 C109 118.4(6) . .
N10 C115 C155 126.5(6) . .
N10 C115 C148 105.3(6) . .
C155 C115 C148 128.2(7) . .
C93 C116 C90 127.6(6) . .
C93 C116 C128 117.7(6) . .
C90 C116 C128 114.6(6) . .
N1 C117 C139 105.6(6) . .
N1 C117 C92 113.7(6) . .
C139 C117 C92 140.4(6) . .
N5 C118 C91 111.9(6) . .
N5 C118 C124 105.8(6) . .
C91 C118 C124 142.1(6) . .
C40 C119 C90 107.9(6) . .
C40 C119 H119 126.0 . .
C90 C119 H119 126.0 . .
F20 C120 C140 119.3(7) . .
F20 C120 C107 118.6(7) . .
C140 C120 C107 122.1(8) . .
N13 C121 C46 120.8(6) . .
N13 C121 C41 105.3(6) . .
C46 C121 C41 133.9(7) . .
C7 C122 C102 125.3(7) . .
C7 C122 C134 117.8(6) . .
C102 C122 C134 116.9(6) . .
C147 C123 C111 108.4(6) . .
C147 C123 H123 125.8 . .
C111 C123 H123 125.8 . .
C34 C124 C118 108.3(6) . .
C34 C124 H124 125.9 . .
C118 C124 H124 125.9 . .
C25 C125 C156 115.3(7) . .
C25 C125 C155 122.9(7) . .
C156 C125 C155 121.8(7) . .
F15 C126 C154 117.3(7) . .
F15 C126 C134 120.2(6) . .
C154 C126 C134 122.4(7) . .
C139 C127 C97 108.4(6) . .
C139 C127 H127 125.8 . .
C97 C127 H127 125.8 . .
C96 C128 C12 126.4(6) . .
C96 C128 C116 116.1(6) . .
C12 C128 C116 117.4(6) . .
F17 C129 C146 120.6(7) . .
F17 C129 C108 120.5(7) . .
C146 C129 C108 118.9(8) . .
N15 C130 C46 125.3(7) . .
N15 C130 C43 105.5(6) . .
C46 C130 C43 129.2(7) . .
C9 C131 C111 125.8(6) . .
C9 C131 C27 116.9(6) . .
C111 C131 C27 117.2(7) . .
F5 C132 C18 117.7(7) . .
F5 C132 C152 119.8(7) . .
C18 C132 C152 122.5(7) . .
N15 C133 C27 125.1(7) . .
N15 C133 C51 106.7(7) . .
C27 C133 C51 128.0(7) . .
C126 C134 C149 116.0(7) . .
C126 C134 C122 122.4(6) . .
C149 C134 C122 121.6(7) . .
F21 C135 C21 117.7(7) . .
F21 C135 C109 119.6(6) . .
C21 C135 C109 122.7(7) . .
N4 C136 C19 121.7(6) . .
N4 C136 C16 105.5(6) . .
C19 C136 C16 132.8(7) . .
C32 C137 F8 122.4(10) . .
C32 C137 C39 120.8(8) . .
F8 C137 C39 116.8(11) . .
C97 C138 C144 123.6(7) . .
C97 C138 C14 116.3(6) . .
C144 C138 C14 119.9(6) . .
C127 C139 C117 108.4(6) . .
C127 C139 H139 125.8 . .
C117 C139 H139 125.8 . .
F19 C140 C108 119.9(8) . .
F19 C140 C120 119.2(8) . .
C108 C140 C120 120.8(7) . .
C6 C141 C96 108.1(6) . .
C6 C141 H141 126.0 . .
C96 C141 H141 126.0 . .
F32 C142 C151 121.2(8) . .
F32 C142 C22 118.9(7) . .
C151 C142 C22 119.9(8) . .
F2 C143 C20 120.7(8) . .
F2 C143 C28 118.9(7) . .
C20 C143 C28 120.3(8) . .
N2 C144 C138 126.2(6) . .
N2 C144 C40 105.9(6) . .
C138 C144 C40 127.8(7) . .
C94 C145 C102 109.4(6) . .
C94 C145 H145 125.3 . .
C102 C145 H145 125.3 . .
F16 C146 C129 117.2(7) . .
F16 C146 C107 118.8(6) . .
C129 C146 C107 123.9(7) . .
C123 C147 C98 108.3(7) . .
C123 C147 H147 125.8 . .
C98 C147 H147 125.8 . .
C37 C148 C115 108.9(7) . .
C37 C148 H148 125.6 . .
C115 C148 H148 125.6 . .
F11 C149 C42 117.6(7) . .
F11 C149 C134 119.8(7) . .
C42 C149 C134 122.6(7) . .
C101 C150 C106 108.5(6) . .
C101 C150 H150 125.7 . .
C106 C150 H150 125.7 . .
F31 C151 C142 117.5(7) . .
F31 C151 C30 120.2(6) . .
C142 C151 C30 122.3(7) . .
C20 C152 C132 114.6(7) . .
C20 C152 C19 122.9(7) . .
C132 C152 C19 122.2(7) . .
F29 C153 C26 120.0(8) . .
F29 C153 C156 120.4(8) . .
C26 C153 C156 119.6(8) . .
F14 C154 C100 120.0(7) . .
F14 C154 C126 120.4(7) . .
C100 C154 C126 119.6(8) . .
C115 C155 C87 124.8(6) . .
C115 C155 C125 118.2(6) . .
C87 C155 C125 117.0(7) . .
F30 C156 C153 117.5(7) . .
F30 C156 C125 119.6(7) . .
C153 C156 C125 122.9(7) . .
C41 C157 C11 107.3(7) . .
C41 C157 H157 126.4 . .
C11 C157 H157 126.4 . .
O10 C158 C76 108.6(14) . .
O10 C158 H15D 110.0 . .
C76 C158 H15D 110.0 . .
O10 C158 H15E 110.0 . .
C76 C158 H15E 110.0 . .
H15D C158 H15E 108.4 . .
C76 O9 C166 106.8(14) . .
C78 O10 C158 104.9(14) . .
O9 C76 C158 106.1(14) . .
O9 C76 H76A 110.5 . .
C158 C76 H76A 110.5 . .
O9 C76 H76B 110.5 . .
C158 C76 H76B 110.5 . .
H76A C76 H76B 108.7 . .
O10 C78 C166 107.5(15) . .
O10 C78 H78A 110.2 . .
C166 C78 H78A 110.2 . .
O10 C78 H78B 110.2 . .
C166 C78 H78B 110.2 . .
H78A C78 H78B 108.5 . .
O9 C166 C78 110.1(15) . .
O9 C166 H16N 109.6 . .
C78 C166 H16N 109.6 . .
O9 C166 H16O 109.6 . .
C78 C166 H16O 109.6 . .
H16N C166 H16O 108.1 . .
C80 C77 O11 115(2) . .
C80 C77 H77A 108.6 . .
O11 C77 H77A 108.6 . .
C80 C77 H77B 108.6 . .
O11 C77 H77B 108.6 . .
H77A C77 H77B 107.6 . .
C84 C79 O11 109(2) . .
C84 C79 H79A 109.8 . .
O11 C79 H79A 109.8 . .
C84 C79 H79B 109.8 . .
O11 C79 H79B 109.8 . .
H79A C79 H79B 108.2 . .
C77 C80 O12 112(2) . .
C77 C80 H80A 109.3 . .
O12 C80 H80A 109.3 . .
C77 C80 H80B 109.3 . .
O12 C80 H80B 109.3 . .
H80A C80 H80B 107.9 . .
O12 C84 C79 113(2) . .
O12 C84 H84A 109.0 . .
C79 C84 H84A 109.0 . .
O12 C84 H84B 109.0 . .
C79 C84 H84B 109.0 . .
H84A C84 H84B 107.8 . .
C79 O11 C77 105.9(15) . .
C84 O12 C80 104.2(19) . .
C159 C160 C161 105.0(19) . .
C159 C160 H16A 110.7 . .
C161 C160 H16A 110.7 . .
C159 C160 H16B 110.7 . .
C161 C160 H16B 110.7 . .
H16A C160 H16B 108.8 . .
C164 C165 H16C 109.5 . .
C164 C165 H16D 109.5 . .
H16C C165 H16D 109.5 . .
C164 C165 H16E 109.5 . .
H16C C165 H16E 109.5 . .
H16D C165 H16E 109.5 . .
C163 C164 C165 105.1(19) . .
C163 C164 H16F 110.7 . .
C165 C164 H16F 110.7 . .
C163 C164 H16G 110.7 . .
C165 C164 H16G 110.7 . .
H16F C164 H16G 108.8 . .
C163 C162 C161 105.7(19) . .
C163 C162 H16H 110.6 . .
C161 C162 H16H 110.6 . .
C163 C162 H16I 110.6 . .
C161 C162 H16I 110.6 . .
H16H C162 H16I 108.7 . .
C162 C161 C160 104.8(19) . .
C162 C161 H16J 110.8 . .
C160 C161 H16J 110.8 . .
C162 C161 H16K 110.8 . .
C160 C161 H16K 110.8 . .
H16J C161 H16K 108.9 . .
C160 C159 H15A 109.5 . .
C160 C159 H15B 109.5 . .
H15A C159 H15B 109.5 . .
C160 C159 H15C 109.5 . .
H15A C159 H15C 109.5 . .
H15B C159 H15C 109.5 . .
C162 C163 C164 106(2) . .
C162 C163 H16L 110.5 . .
C164 C163 H16L 110.5 . .
C162 C163 H16M 110.5 . .
C164 C163 H16M 110.5 . .
H16L C163 H16M 108.6 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
F2 C143 1.353(10) .
F3 C28 1.328(10) .
F5 C132 1.333(9) .
F7 C39 1.315(13) .
F9 C32 1.342(13) .
F11 C149 1.340(9) .
F12 C42 1.337(9) .
F15 C126 1.343(8) .
F16 C146 1.366(8) .
F21 C135 1.335(9) .
F23 C17 1.339(9) .
F24 C105 1.331(9) .
F25 C23 1.328(8) .
F27 C29 1.342(10) .
F28 C26 1.340(9) .
F30 C156 1.354(9) .
F31 C151 1.335(9) .
F36 C49 1.336(10) .
F37 C53 1.334(9) .
F38 C48 1.344(8) .
F39 C52 1.331(10) .
F40 C50 1.339(9) .
Ag1 N5 1.921(5) .
Ag1 N8 1.930(5) .
Ag1 N6 1.960(5) .
Ag1 N7 1.961(6) .
Ag2 N1 1.935(5) .
Ag2 N4 1.941(5) .
Ag2 N3 1.960(6) .
Ag2 N2 1.966(5) .
Ag3 N9 1.929(6) .
Ag3 N12 1.935(5) .
Ag3 N11 1.955(6) .
Ag3 N10 1.957(6) .
Ag4 N13 1.921(6) .
Ag4 N16 1.936(6) .
Ag4 N14 1.954(6) .
Ag4 N15 1.953(6) .
N1 C97 1.339(9) .
N1 C117 1.374(9) .
N2 C90 1.367(8) .
N2 C144 1.368(9) .
N3 C93 1.375(8) .
N3 C113 1.374(9) .
N4 C136 1.351(9) .
N4 C92 1.389(8) .
N5 C103 1.369(9) .
N5 C118 1.384(8) .
N6 C106 1.367(9) .
N6 C12 1.366(8) .
N7 C7 1.373(9) .
N7 C96 1.378(8) .
N8 C91 1.360(8) .
N8 C102 1.365(9) .
N9 C87 1.351(9) .
N9 C2 1.377(8) .
N10 C115 1.368(9) .
N10 C9 1.383(9) .
N11 C98 1.365(9) .
N11 C111 1.372(9) .
N12 C4 1.351(8) .
N12 C10 1.369(8) .
N13 C11 1.371(9) .
N13 C121 1.376(9) .
C1 C16 1.372(10) .
C1 C92 1.415(10) .
C1 H1 0.9500 .
C2 C3 1.415(10) .
C2 C10 1.420(9) .
C3 C112 1.383(10) .
C3 H3 0.9500 .
C4 C114 1.413(10) .
C4 C99 1.428(9) .
C5 C15 1.357(11) .
C5 C89 1.429(10) .
C5 H5 0.9500 .
C6 C141 1.369(10) .
C6 C7 1.428(10) .
C6 H6 0.9500 .
C7 C122 1.408(10) .
C8 N16 1.373(9) .
C8 C31 1.410(10) .
C8 C15 1.414(10) .
C9 C131 1.387(11) .
C9 C37 1.434(10) .
C10 C95 1.433(9) .
C11 C157 1.413(11) .
C11 C89 1.418(10) .
C12 C128 1.409(10) .
C12 C101 1.427(10) .
C13 C103 1.404(9) .
C13 C106 1.408(9) .
C13 C107 1.477(10) .
C14 C24 1.380(13) .
C14 C38 1.430(13) .
C14 C138 1.469(10) .
C15 H15 0.9500 .
C16 C136 1.433(9) .
C16 H16 0.9500 .
C17 C105 1.376(12) .
C17 C21 1.386(12) .
C18 F4 1.344(10) .
C18 C28 1.376(13) .
C18 C132 1.382(11) .
C19 C113 1.401(10) .
C19 C136 1.408(10) .
C19 C152 1.489(10) .
C20 F1 1.339(9) .
C20 C143 1.370(12) .
C20 C152 1.393(11) .
C21 F22 1.339(9) .
C21 C135 1.378(10) .
C22 F33 1.311(10) .
C22 C35 1.384(14) .
C22 C142 1.402(13) .
C23 C105 1.383(10) .
C23 C109 1.390(10) .
C24 F6 1.371(11) .
C24 C39 1.372(13) .
C25 F26 1.339(9) .
C25 C29 1.376(12) .
C25 C125 1.382(11) .
C26 C153 1.362(13) .
C26 C29 1.369(13) .
C27 C110 1.411(10) .
C27 C133 1.414(10) .
C27 C131 1.488(10) .
C28 C143 1.373(13) .
C30 C104 1.383(11) .
C30 C151 1.385(11) .
C30 C31 1.492(10) .
C31 C88 1.399(10) .
C32 C137 1.332(16) .
C32 C38 1.354(13) .
C33 C36 1.360(10) .
C33 C110 1.431(10) .
C33 H33 0.9500 .
C34 C124 1.364(10) .
C34 C103 1.445(9) .
C34 H34 0.9500 .
C35 F34 1.330(10) .
C35 C104 1.388(12) .
C36 C88 1.427(10) .
C36 H36 0.9500 .
C37 C148 1.352(12) .
C37 H37 0.9500 .
C38 F10 1.305(12) .
C39 C137 1.417(16) .
C40 C119 1.370(10) .
C40 C144 1.431(10) .
C40 H40 0.9500 .
C41 C157 1.380(11) .
C41 C121 1.414(10) .
C41 H41 0.9500 .
C42 C149 1.367(11) .
C42 C100 1.375(13) .
C43 C51 1.342(12) .
C43 C130 1.416(12) .
C43 H43 0.802(10) .
C44 C47 1.355(11) .
C44 C93 1.437(10) .
C44 H44 0.9500 .
C45 C50 1.371(11) .
C45 C49 1.386(11) .
C45 C46 1.498(10) .
C46 C121 1.404(11) .
C46 C130 1.408(10) .
C47 C113 1.436(10) .
C47 H47 0.9500 .
C48 C53 1.360(12) .
C48 C52 1.369(12) .
C49 C53 1.384(11) .
C50 C52 1.396(11) .
C51 C133 1.429(11) .
C51 H51 0.9500 .
C54 O1 1.419(9) .
C54 C55 1.500(11) .
C54 H54A 0.9900 .
C54 H54B 0.9900 .
C55 O2 1.421(10) .
C55 H55A 0.9900 .
C55 H55B 0.9900 .
C56 O1 1.428(9) .
C56 C57 1.503(12) .
C56 H56A 0.9900 .
C56 H56B 0.9900 .
C57 O2 1.428(10) .
C57 H57A 0.9900 .
C57 H57B 0.9900 .
C58 C61 1.490(13) .
C58 O6 1.500(12) .
C58 H58A 0.9900 .
C58 H58B 0.9900 .
C59 O6 1.367(11) .
C59 C60 1.467(13) .
C59 H59A 0.9900 .
C59 H59B 0.9900 .
C60 O5 1.486(12) .
C60 H60A 0.9900 .
C60 H60B 0.9900 .
C61 O5 1.536(13) .
C61 H61A 0.9900 .
C61 H61B 0.9900 .
C62 O3 1.416(13) .
C62 C65 1.501(15) .
C62 H62A 0.9900 .
C62 H62B 0.9900 .
C63 O3 1.423(12) .
C63 C64 1.504(14) .
C63 H63A 0.9900 .
C63 H63B 0.9900 .
C64 O4 1.450(12) .
C64 H64A 0.9900 .
C64 H64B 0.9900 .
C65 O4 1.401(13) .
C65 H65A 0.9900 .
C65 H65B 0.9900 .
C66 C71 1.526(15) .
C66 H66A 0.9800 .
C66 H66B 0.9800 .
C66 H66C 0.9800 .
C67 C71 1.509(15) .
C67 C68 1.526(15) .
C67 H67A 0.9900 .
C67 H67B 0.9900 .
C68 C69 1.498(16) .
C68 H68A 0.9900 .
C68 H68B 0.9900 .
C69 C72 1.533(17) .
C69 H69A 0.9900 .
C69 H69B 0.9900 .
C70 C72 1.507(17) .
C70 H70A 0.9800 .
C70 H70B 0.9800 .
C70 H70C 0.9800 .
C71 H71A 0.9900 .
C71 H71B 0.9900 .
C72 H72A 0.9900 .
C72 H72B 0.9900 .
C73 O7 1.419(13) .
C73 C75 1.486(15) .
C73 H73A 0.9900 .
C73 H73B 0.9900 .
C74 C82 1.447(17) .
C74 O7 1.497(15) .
C74 H74A 0.9900 .
C74 H74B 0.9900 .
C75 O8 1.391(14) .
C75 H75A 0.9900 .
C75 H75B 0.9900 .
C82 O8 1.381(16) .
C82 H82A 0.9900 .
C82 H82B 0.9900 .
C85 O13 1.426(11) .
C85 C86 1.502(13) 3_556
C85 H85A 0.9900 .
C85 H85B 0.9900 .
C86 O13 1.438(11) .
C86 C85 1.502(13) 3_556
C86 H86A 0.9900 .
C86 H86B 0.9900 .
N14 C110 1.362(9) .
N14 C88 1.378(9) .
N15 C133 1.365(9) .
N15 C130 1.386(9) .
F8 C137 1.341(10) .
F13 C100 1.340(9) .
F17 C129 1.342(10) .
F18 C108 1.337(9) .
F32 C142 1.333(10) .
N16 C89 1.374(9) .
F14 C154 1.351(10) .
F19 C140 1.346(9) .
F20 C120 1.333(9) .
F29 C153 1.339(10) .
F35 C104 1.344(10) .
C87 C112 1.425(10) .
C87 C155 1.438(10) .
C90 C116 1.409(10) .
C90 C119 1.419(10) .
C91 C118 1.416(10) .
C91 C94 1.443(9) .
C92 C117 1.418(10) .
C93 C116 1.400(10) .
C94 C145 1.365(10) .
C94 H94 0.9500 .
C95 C99 1.373(10) .
C95 H95 0.9500 .
C96 C128 1.408(10) .
C96 C141 1.426(10) .
C97 C138 1.409(10) .
C97 C127 1.443(9) .
C98 C114 1.408(9) .
C98 C147 1.434(10) .
C99 H99 0.9500 .
C100 C154 1.372(12) .
C101 C150 1.373(10) .
C101 H101 0.9500 .
C102 C145 1.420(10) .
C102 C122 1.419(10) .
C106 C150 1.429(9) .
C107 C146 1.380(11) .
C107 C120 1.391(9) .
C108 C140 1.353(13) .
C108 C129 1.390(12) .
C109 C135 1.379(10) .
C109 C114 1.472(9) .
C111 C131 1.401(10) .
C111 C123 1.440(11) .
C112 H112 0.9500 .
C115 C155 1.388(11) .
C115 C148 1.442(10) .
C116 C128 1.512(9) .
C117 C139 1.417(10) .
C118 C124 1.415(10) .
C119 H119 0.9500 .
C120 C140 1.377(12) .
C122 C134 1.496(10) .
C123 C147 1.350(11) .
C123 H123 0.9500 .
C124 H124 0.9500 .
C125 C156 1.388(11) .
C125 C155 1.485(10) .
C126 C154 1.379(11) .
C126 C134 1.381(10) .
C127 C139 1.352(10) .
C127 H127 0.9500 .
C129 C146 1.366(11) .
C132 C152 1.397(11) .
C134 C149 1.391(10) .
C138 C144 1.415(9) .
C139 H139 0.9500 .
C141 H141 0.9500 .
C142 C151 1.379(11) .
C145 H145 0.9500 .
C147 H147 0.9500 .
C148 H148 0.9500 .
C150 H150 0.9500 .
C153 C156 1.376(11) .
C157 H157 0.9500 .
C158 O10 1.442(16) .
C158 C76 1.557(17) .
C158 H15D 0.9900 .
C158 H15E 0.9900 .
O9 C76 1.377(15) .
O9 C166 1.413(15) .
O10 C78 1.435(16) .
C76 H76A 0.9900 .
C76 H76B 0.9900 .
C78 C166 1.469(17) .
C78 H78A 0.9900 .
C78 H78B 0.9900 .
C166 H16N 0.9900 .
C166 H16O 0.9900 .
C77 C80 1.33(4) .
C77 O11 1.43(3) .
C77 H77A 0.9900 .
C77 H77B 0.9900 .
C79 C84 1.37(3) .
C79 O11 1.43(2) .
C79 H79A 0.9900 .
C79 H79B 0.9900 .
C80 O12 1.53(3) .
C80 H80A 0.9900 .
C80 H80B 0.9900 .
C84 O12 1.34(3) .
C84 H84A 0.9900 .
C84 H84B 0.9900 .
C160 C159 1.65(3) .
C160 C161 1.65(2) .
C160 H16A 0.9900 .
C160 H16B 0.9900 .
C165 C164 1.66(2) .
C165 H16C 0.9800 .
C165 H16D 0.9800 .
C165 H16E 0.9800 .
C164 C163 1.65(2) .
C164 H16F 0.9900 .
C164 H16G 0.9900 .
C162 C163 1.64(2) .
C162 C161 1.65(2) .
C162 H16H 0.9900 .
C162 H16I 0.9900 .
C161 H16J 0.9900 .
C161 H16K 0.9900 .
C159 H15A 0.9800 .
C159 H15B 0.9800 .
C159 H15C 0.9800 .
C163 H16L 0.9900 .
C163 H16M 0.9900 .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C16 H16 F16 0.95 2.46 3.100(8) 124.6 4_566
C16 H16 F25 0.95 2.62 3.278(9) 126.8 4_566
C33 H33 O1 0.95 2.63 3.551(9) 163.9 4_565
C34 H34 F1 0.95 2.46 3.113(9) 125.7 4_565
C41 H41 F23 0.95 2.44 3.341(9) 158.7 2_455
C43 H43 O10 0.802(10) 2.52(3) 3.310(15) 167(8) 3_566
C54 H54A F19 0.99 2.61 3.301(9) 126.6 3_556
C58 H58B F40 0.99 2.46 3.426(9) 165.8 4_666
C60 H60B N14 0.99 2.69 3.582(12) 150.7 4_666
C62 H62B F32 0.99 2.54 3.124(12) 117.3 4_566
C64 H64B F5 0.99 2.65 3.437(11) 136.7 .
C75 H75A F12 0.99 2.47 3.441(15) 167.4 1_455
C112 H112 O9 0.95 2.52 3.382(14) 151.4 .
C124 H124 O11 0.95 2.40 3.205(19) 142.9 4_565
C127 H127 F15 0.95 2.50 3.211(8) 131.6 4_566
C127 H127 F30 0.95 2.63 3.309(8) 128.4 4_566
C141 H141 F37 0.95 2.54 3.206(9) 127.2 3_566
C157 H157 F11 0.95 2.48 3.302(9) 145.3 2
C158 H15D F29 0.99 2.35 3.179(19) 141.0 3_666
C76 H76A F14 0.99 2.65 3.526(17) 148.1 .
C77 H77A F1 0.99 2.52 3.123(18) 118.9 .
C166 H16O O12 0.99 2.50 3.06(3) 115.6 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
C87 N9 C2 C3 -2.2(7) .
Ag3 N9 C2 C3 -173.7(4) .
C87 N9 C2 C10 176.4(5) .
Ag3 N9 C2 C10 5.0(7) .
N9 C2 C3 C112 1.3(7) .
C10 C2 C3 C112 -176.7(8) .
C10 N12 C4 C114 175.9(6) .
Ag3 N12 C4 C114 7.3(9) .
C10 N12 C4 C99 -1.8(7) .
Ag3 N12 C4 C99 -170.5(4) .
C96 N7 C7 C122 180.0(7) .
Ag1 N7 C7 C122 1.5(10) .
C96 N7 C7 C6 -0.8(8) .
Ag1 N7 C7 C6 -179.2(5) .
C141 C6 C7 N7 0.4(8) .
C141 C6 C7 C122 179.6(7) .
C115 N10 C9 C131 -178.3(7) .
Ag3 N10 C9 C131 -1.0(10) .
C115 N10 C9 C37 1.8(8) .
Ag3 N10 C9 C37 179.1(5) .
C4 N12 C10 C2 -174.4(5) .
Ag3 N12 C10 C2 -4.1(7) .
C4 N12 C10 C95 1.8(7) .
Ag3 N12 C10 C95 172.1(4) .
N9 C2 C10 N12 -0.5(7) .
C3 C2 C10 N12 177.4(7) .
N9 C2 C10 C95 -174.7(8) .
C3 C2 C10 C95 3.3(15) .
C121 N13 C11 C157 2.6(8) .
Ag4 N13 C11 C157 168.2(5) .
C121 N13 C11 C89 -170.9(6) .
Ag4 N13 C11 C89 -5.3(8) .
C106 N6 C12 C128 -177.2(6) .
Ag1 N6 C12 C128 5.8(10) .
C106 N6 C12 C101 1.1(8) .
Ag1 N6 C12 C101 -176.0(5) .
C89 C5 C15 C8 -1.4(8) .
N16 C8 C15 C5 -1.7(8) .
C31 C8 C15 C5 170.3(7) .
C92 C1 C16 C136 -0.6(8) .
F23 C17 C21 F22 0.2(13) .
C105 C17 C21 F22 179.9(8) .
F23 C17 C21 C135 -179.0(8) .
C105 C17 C21 C135 0.7(13) .
C38 C14 C24 F6 -178.4(7) .
C138 C14 C24 F6 -2.6(12) .
C38 C14 C24 C39 -1.3(12) .
C138 C14 C24 C39 174.5(8) .
F4 C18 C28 F3 0.0(13) .
C132 C18 C28 F3 179.4(8) .
F4 C18 C28 C143 179.6(8) .
C132 C18 C28 C143 -1.0(13) .
F28 C26 C29 F27 0.0(14) .
C153 C26 C29 F27 179.7(8) .
F28 C26 C29 C25 -177.6(8) .
C153 C26 C29 C25 2.1(14) .
F26 C25 C29 F27 0.7(13) .
C125 C25 C29 F27 -178.8(8) .
F26 C25 C29 C26 178.3(8) .
C125 C25 C29 C26 -1.2(14) .
N16 C8 C31 C88 0.5(11) .
C15 C8 C31 C88 -170.5(8) .
N16 C8 C31 C30 176.7(6) .
C15 C8 C31 C30 5.7(11) .
C104 C30 C31 C88 -114.4(8) .
C151 C30 C31 C88 68.7(10) .
C104 C30 C31 C8 69.1(10) .
C151 C30 C31 C8 -107.8(8) .
F33 C22 C35 F34 -2.7(14) .
C142 C22 C35 F34 178.9(8) .
F33 C22 C35 C104 179.1(8) .
C142 C22 C35 C104 0.7(14) .
C110 C33 C36 C88 2.7(9) .
N10 C9 C37 C148 -0.9(8) .
C131 C9 C37 C148 179.1(7) .
C137 C32 C38 F10 -179.4(9) .
F9 C32 C38 F10 1.0(15) .
C137 C32 C38 C14 -1.8(15) .
F9 C32 C38 C14 178.7(9) .
C24 C14 C38 F10 179.4(8) .
C138 C14 C38 F10 3.4(12) .
C24 C14 C38 C32 1.7(12) .
C138 C14 C38 C32 -174.3(8) .
F6 C24 C39 F7 -1.6(13) .
C14 C24 C39 F7 -178.8(8) .
F6 C24 C39 C137 178.0(8) .
C14 C24 C39 C137 0.8(13) .
C50 C45 C46 C121 78.4(10) .
C49 C45 C46 C121 -103.6(9) .
C50 C45 C46 C130 -98.5(9) .
C49 C45 C46 C130 79.5(9) .
C93 C44 C47 C113 1.1(9) .
C50 C45 C49 F36 -178.5(7) .
C46 C45 C49 F36 3.4(11) .
C50 C45 C49 C53 1.5(12) .
C46 C45 C49 C53 -176.6(7) .
C49 C45 C50 F40 178.4(7) .
C46 C45 C50 F40 -3.5(12) .
C49 C45 C50 C52 -1.1(12) .
C46 C45 C50 C52 177.0(7) .
C130 C43 C51 C133 -0.9(12) .
F38 C48 C52 F39 1.8(12) .
C53 C48 C52 F39 -178.5(8) .
F38 C48 C52 C50 179.6(7) .
C53 C48 C52 C50 -0.6(12) .
F40 C50 C52 F39 -1.0(12) .
C45 C50 C52 F39 178.6(7) .
F40 C50 C52 C48 -178.8(7) .
C45 C50 C52 C48 0.7(13) .
F38 C48 C53 F37 -0.2(12) .
C52 C48 C53 F37 -180.0(8) .
F38 C48 C53 C49 -179.3(7) .
C52 C48 C53 C49 1.0(12) .
F36 C49 C53 F37 -0.5(11) .
C45 C49 C53 F37 179.5(7) .
F36 C49 C53 C48 178.6(7) .
C45 C49 C53 C48 -1.4(12) .
O1 C54 C55 O2 58.0(8) .
O1 C56 C57 O2 -57.0(8) .
O6 C59 C60 O5 -70.1(10) .
O6 C58 C61 O5 67.1(9) .
O3 C63 C64 O4 -58.1(11) .
O3 C62 C65 O4 59.6(13) .
C71 C67 C68 C69 -177.3(10) .
C67 C68 C69 C72 -174.8(10) .
C68 C67 C71 C66 -175.9(10) .
C68 C69 C72 C70 -57.2(14) .
O7 C73 C75 O8 59.8(14) .
O7 C74 C82 O8 -57.5(18) .
C55 C54 O1 C56 -57.4(8) .
C57 C56 O1 C54 56.9(8) .
C54 C55 O2 C57 -57.1(8) .
C56 C57 O2 C55 56.8(8) .
C65 C62 O3 C63 -57.6(12) .
C64 C63 O3 C62 57.7(11) .
C62 C65 O4 C64 -58.5(11) .
C63 C64 O4 C65 57.8(10) .
C59 C60 O5 C61 65.5(9) .
C58 C61 O5 C60 -66.4(9) .
C60 C59 O6 C58 68.5(10) .
C61 C58 O6 C59 -67.9(10) .
C75 C73 O7 C74 -48.1(14) .
C82 C74 O7 C73 53.1(17) .
C74 C82 O8 C75 59.9(17) .
C73 C75 O8 C82 -66.3(16) .
C86 C85 O13 C86 57.8(11) 3_556
C85 C86 O13 C85 -57.0(11) 3_556
C31 C8 N16 C89 -168.9(6) .
C15 C8 N16 C89 4.4(7) .
C31 C8 N16 Ag4 -7.4(10) .
C15 C8 N16 Ag4 165.8(5) .
C2 N9 C87 C112 2.2(7) .
Ag3 N9 C87 C112 172.2(4) .
C2 N9 C87 C155 -175.0(6) .
Ag3 N9 C87 C155 -5.0(9) .
C110 N14 C88 C31 178.5(7) .
Ag4 N14 C88 C31 3.7(11) .
C110 N14 C88 C36 0.1(8) .
Ag4 N14 C88 C36 -174.7(5) .
C8 C31 C88 N14 1.2(12) .
C30 C31 C88 N14 -174.9(7) .
C8 C31 C88 C36 179.2(7) .
C30 C31 C88 C36 3.1(12) .
C33 C36 C88 N14 -1.8(9) .
C33 C36 C88 C31 179.9(8) .
C8 N16 C89 C11 169.0(6) .
Ag4 N16 C89 C11 4.6(8) .
C8 N16 C89 C5 -5.3(8) .
Ag4 N16 C89 C5 -169.7(5) .
N13 C11 C89 N16 0.4(9) .
C157 C11 C89 N16 -170.0(9) .
N13 C11 C89 C5 171.6(9) .
C157 C11 C89 C5 1.2(17) .
C15 C5 C89 N16 4.0(8) .
C15 C5 C89 C11 -167.6(9) .
C144 N2 C90 C116 177.4(7) .
Ag2 N2 C90 C116 4.0(10) .
C144 N2 C90 C119 -2.4(8) .
Ag2 N2 C90 C119 -175.8(5) .
C102 N8 C91 C118 -175.1(6) .
Ag1 N8 C91 C118 -5.1(7) .
C102 N8 C91 C94 1.5(8) .
Ag1 N8 C91 C94 171.4(4) .
C136 N4 C92 C1 -4.5(7) .
Ag2 N4 C92 C1 -167.9(4) .
C136 N4 C92 C117 169.6(6) .
Ag2 N4 C92 C117 6.2(7) .
C16 C1 C92 N4 3.0(7) .
C16 C1 C92 C117 -168.5(8) .
C113 N3 C93 C116 -175.7(7) .
Ag2 N3 C93 C116 4.2(10) .
C113 N3 C93 C44 2.4(8) .
Ag2 N3 C93 C44 -177.7(5) .
C47 C44 C93 N3 -2.1(9) .
C47 C44 C93 C116 175.8(7) .
N8 C91 C94 C145 -0.8(8) .
C118 C91 C94 C145 174.3(8) .
N12 C10 C95 C99 -0.9(7) .
C2 C10 C95 C99 173.5(8) .
C7 N7 C96 C128 179.7(6) .
Ag1 N7 C96 C128 -1.8(10) .
C7 N7 C96 C141 0.8(8) .
Ag1 N7 C96 C141 179.3(5) .
C117 N1 C97 C138 176.0(6) .
Ag2 N1 C97 C138 8.1(10) .
C117 N1 C97 C127 -1.6(8) .
Ag2 N1 C97 C127 -169.6(5) .
C111 N11 C98 C114 -177.0(6) .
Ag3 N11 C98 C114 1.3(10) .
C111 N11 C98 C147 0.3(8) .
Ag3 N11 C98 C147 178.7(5) .
C10 C95 C99 C4 -0.1(7) .
N12 C4 C99 C95 1.2(7) .
C114 C4 C99 C95 -176.3(7) .
F12 C42 C100 F13 -0.1(12) .
C149 C42 C100 F13 -179.6(7) .
F12 C42 C100 C154 -179.1(7) .
C149 C42 C100 C154 1.4(12) .
N6 C12 C101 C150 -0.6(8) .
C128 C12 C101 C150 177.6(7) .
C91 N8 C102 C145 -1.5(8) .
Ag1 N8 C102 C145 -169.6(5) .
C91 N8 C102 C122 175.2(6) .
Ag1 N8 C102 C122 7.1(10) .
C118 N5 C103 C13 -175.0(6) .
Ag1 N5 C103 C13 -7.8(9) .
C118 N5 C103 C34 3.4(7) .
Ag1 N5 C103 C34 170.5(5) .
C106 C13 C103 N5 1.5(10) .
C107 C13 C103 N5 178.0(6) .
C106 C13 C103 C34 -176.3(7) .
C107 C13 C103 C34 0.2(11) .
C124 C34 C103 N5 -2.4(7) .
C124 C34 C103 C13 175.7(7) .
C151 C30 C104 F35 -179.6(7) .
C31 C30 C104 F35 3.4(12) .
C151 C30 C104 C35 -1.6(12) .
C31 C30 C104 C35 -178.6(8) .
F34 C35 C104 F35 0.6(13) .
C22 C35 C104 F35 178.7(8) .
F34 C35 C104 C30 -177.5(8) .
C22 C35 C104 C30 0.7(14) .
F23 C17 C105 F24 1.0(13) .
C21 C17 C105 F24 -178.7(8) .
F23 C17 C105 C23 179.7(8) .
C21 C17 C105 C23 -0.1(13) .
F25 C23 C105 F24 -0.2(11) .
C109 C23 C105 F24 178.8(7) .
F25 C23 C105 C17 -178.8(7) .
C109 C23 C105 C17 0.2(12) .
C12 N6 C106 C13 179.0(6) .
Ag1 N6 C106 C13 -3.9(10) .
C12 N6 C106 C150 -1.1(7) .
Ag1 N6 C106 C150 175.9(4) .
C103 C13 C106 N6 4.5(11) .
C107 C13 C106 N6 -171.9(6) .
C103 C13 C106 C150 -175.4(7) .
C107 C13 C106 C150 8.2(10) .
C103 C13 C107 C146 -84.5(8) .
C106 C13 C107 C146 92.1(8) .
C103 C13 C107 C120 94.3(8) .
C106 C13 C107 C120 -89.1(8) .
F25 C23 C109 C135 178.1(7) .
C105 C23 C109 C135 -0.9(11) .
F25 C23 C109 C114 -1.2(11) .
C105 C23 C109 C114 179.9(7) .
C88 N14 C110 C27 -176.9(7) .
Ag4 N14 C110 C27 -2.0(11) .
C88 N14 C110 C33 1.5(8) .
Ag4 N14 C110 C33 176.4(5) .
C133 C27 C110 N14 6.6(13) .
C131 C27 C110 N14 -176.6(7) .
C133 C27 C110 C33 -171.5(8) .
C131 C27 C110 C33 5.3(12) .
C36 C33 C110 N14 -2.6(9) .
C36 C33 C110 C27 175.8(8) .
C98 N11 C111 C131 177.9(7) .
Ag3 N11 C111 C131 -0.5(10) .
C98 N11 C111 C123 -0.7(8) .
Ag3 N11 C111 C123 -179.1(4) .
C2 C3 C112 C87 0.0(7) .
N9 C87 C112 C3 -1.3(7) .
C155 C87 C112 C3 175.4(7) .
C93 N3 C113 C19 178.4(7) .
Ag2 N3 C113 C19 -1.5(10) .
C93 N3 C113 C47 -1.7(8) .
Ag2 N3 C113 C47 178.4(5) .
C136 C19 C113 N3 3.4(12) .
C152 C19 C113 N3 -171.6(7) .
C136 C19 C113 C47 -176.6(7) .
C152 C19 C113 C47 8.5(12) .
C44 C47 C113 N3 0.3(9) .
C44 C47 C113 C19 -179.8(8) .
N11 C98 C114 C4 0.2(11) .
C147 C98 C114 C4 -176.6(7) .
N11 C98 C114 C109 175.5(6) .
C147 C98 C114 C109 -1.3(10) .
N12 C4 C114 C98 -4.6(10) .
C99 C4 C114 C98 172.5(7) .
N12 C4 C114 C109 -179.7(6) .
C99 C4 C114 C109 -2.6(11) .
C135 C109 C114 C98 -89.1(8) .
C23 C109 C114 C98 90.1(8) .
C135 C109 C114 C4 86.4(8) .
C23 C109 C114 C4 -94.3(8) .
C9 N10 C115 C155 177.6(7) .
Ag3 N10 C115 C155 0.4(10) .
C9 N10 C115 C148 -1.9(8) .
Ag3 N10 C115 C148 -179.1(5) .
N3 C93 C116 C90 0.0(12) .
C44 C93 C116 C90 -177.6(8) .
N3 C93 C116 C128 176.7(6) .
C44 C93 C116 C128 -0.9(11) .
N2 C90 C116 C93 -4.6(12) .
C119 C90 C116 C93 175.2(8) .
N2 C90 C116 C128 178.6(6) .
C119 C90 C116 C128 -1.7(11) .
C97 N1 C117 C139 1.6(8) .
Ag2 N1 C117 C139 171.4(4) .
C97 N1 C117 C92 -172.8(6) .
Ag2 N1 C117 C92 -3.0(7) .
N4 C92 C117 N1 -2.1(8) .
C1 C92 C117 N1 169.0(8) .
N4 C92 C117 C139 -173.6(8) .
C1 C92 C117 C139 -2.6(16) .
C103 N5 C118 C91 173.2(5) .
Ag1 N5 C118 C91 4.2(7) .
C103 N5 C118 C124 -3.1(7) .
Ag1 N5 C118 C124 -172.1(4) .
N8 C91 C118 N5 0.6(8) .
C94 C91 C118 N5 -174.2(8) .
N8 C91 C118 C124 174.8(8) .
C94 C91 C118 C124 -0.1(16) .
C144 C40 C119 C90 -2.9(10) .
N2 C90 C119 C40 3.3(9) .
C116 C90 C119 C40 -176.5(8) .
C146 C107 C120 F20 -178.7(6) .
C13 C107 C120 F20 2.4(10) .
C146 C107 C120 C140 3.3(10) .
C13 C107 C120 C140 -175.6(6) .
C11 N13 C121 C46 175.2(7) .
Ag4 N13 C121 C46 12.3(10) .
C11 N13 C121 C41 -2.1(8) .
Ag4 N13 C121 C41 -165.0(5) .
C130 C46 C121 N13 -5.6(12) .
C45 C46 C121 N13 177.9(6) .
C130 C46 C121 C41 170.8(8) .
C45 C46 C121 C41 -5.7(12) .
C157 C41 C121 N13 0.7(8) .
C157 C41 C121 C46 -176.1(8) .
N7 C7 C122 C102 -0.6(11) .
C6 C7 C122 C102 -179.7(7) .
N7 C7 C122 C134 177.4(6) .
C6 C7 C122 C134 -1.7(11) .
N8 C102 C122 C7 -3.7(11) .
C145 C102 C122 C7 171.9(7) .
N8 C102 C122 C134 178.3(6) .
C145 C102 C122 C134 -6.1(12) .
N11 C111 C123 C147 0.8(8) .
C131 C111 C123 C147 -177.8(7) .
C103 C34 C124 C118 0.6(8) .
N5 C118 C124 C34 1.4(8) .
C91 C118 C124 C34 -173.0(9) .
F26 C25 C125 C156 -179.5(8) .
C29 C25 C125 C156 0.0(13) .
F26 C25 C125 C155 1.4(13) .
C29 C25 C125 C155 -179.1(8) .
N1 C97 C127 C139 1.0(8) .
C138 C97 C127 C139 -176.3(8) .
N7 C96 C128 C12 0.0(11) .
C141 C96 C128 C12 178.7(7) .
N7 C96 C128 C116 176.5(6) .
C141 C96 C128 C116 -4.8(11) .
N6 C12 C128 C96 -2.3(11) .
C101 C12 C128 C96 179.9(7) .
N6 C12 C128 C116 -178.7(6) .
C101 C12 C128 C116 3.4(11) .
C93 C116 C128 C96 101.2(8) .
C90 C116 C128 C96 -81.7(8) .
C93 C116 C128 C12 -82.0(8) .
C90 C116 C128 C12 95.2(8) .
F18 C108 C129 F17 3.9(11) .
C140 C108 C129 F17 -177.1(7) .
F18 C108 C129 C146 -177.0(7) .
C140 C108 C129 C146 1.9(11) .
C133 N15 C130 C46 -176.9(8) .
Ag4 N15 C130 C46 -2.0(12) .
C133 N15 C130 C43 0.9(9) .
Ag4 N15 C130 C43 175.8(6) .
C121 C46 C130 N15 0.7(13) .
C45 C46 C130 N15 177.3(7) .
C121 C46 C130 C43 -176.6(9) .
C45 C46 C130 C43 0.0(13) .
C51 C43 C130 N15 0.0(11) .
C51 C43 C130 C46 177.8(9) .
N10 C9 C131 C111 1.0(12) .
C37 C9 C131 C111 -179.1(7) .
N10 C9 C131 C27 177.7(6) .
C37 C9 C131 C27 -2.4(11) .
N11 C111 C131 C9 -0.2(12) .
C123 C111 C131 C9 178.2(7) .
N11 C111 C131 C27 -176.8(6) .
C123 C111 C131 C27 1.5(11) .
C110 C27 C131 C9 100.2(8) .
C133 C27 C131 C9 -82.7(9) .
C110 C27 C131 C111 -82.8(9) .
C133 C27 C131 C111 94.3(9) .
F4 C18 C132 F5 -2.9(12) .
C28 C18 C132 F5 177.8(8) .
F4 C18 C132 C152 -180.0(7) .
C28 C18 C132 C152 0.7(13) .
C130 N15 C133 C27 174.1(8) .
Ag4 N15 C133 C27 -0.9(12) .
C130 N15 C133 C51 -1.4(9) .
Ag4 N15 C133 C51 -176.4(6) .
C110 C27 C133 N15 -5.0(13) .
C131 C27 C133 N15 178.2(7) .
C110 C27 C133 C51 169.6(9) .
C131 C27 C133 C51 -7.2(13) .
C43 C51 C133 N15 1.4(11) .
C43 C51 C133 C27 -174.0(9) .
F15 C126 C134 C149 -179.5(6) .
C154 C126 C134 C149 0.8(10) .
F15 C126 C134 C122 0.8(10) .
C154 C126 C134 C122 -178.9(7) .
C7 C122 C134 C126 -66.6(9) .
C102 C122 C134 C126 111.6(8) .
C7 C122 C134 C149 113.8(8) .
C102 C122 C134 C149 -68.1(9) .
F22 C21 C135 F21 0.7(12) .
C17 C21 C135 F21 179.8(8) .
F22 C21 C135 C109 179.3(8) .
C17 C21 C135 C109 -1.5(13) .
C23 C109 C135 F21 -179.8(7) .
C114 C109 C135 F21 -0.5(11) .
C23 C109 C135 C21 1.6(11) .
C114 C109 C135 C21 -179.2(7) .
C92 N4 C136 C19 -173.9(6) .
Ag2 N4 C136 C19 -13.6(10) .
C92 N4 C136 C16 4.2(7) .
Ag2 N4 C136 C16 164.5(5) .
C113 C19 C136 N4 4.2(11) .
C152 C19 C136 N4 179.3(6) .
C113 C19 C136 C16 -173.3(7) .
C152 C19 C136 C16 1.8(11) .
C1 C16 C136 N4 -2.1(7) .
C1 C16 C136 C19 175.7(7) .
F9 C32 C137 F8 0.1(16) .
C38 C32 C137 F8 -179.5(9) .
F9 C32 C137 C39 -179.2(9) .
C38 C32 C137 C39 1.2(16) .
F7 C39 C137 C32 178.8(9) .
C24 C39 C137 C32 -0.7(14) .
F7 C39 C137 F8 -0.5(13) .
C24 C39 C137 F8 180.0(8) .
N1 C97 C138 C144 -2.4(11) .
C127 C97 C138 C144 174.6(7) .
N1 C97 C138 C14 -178.6(7) .
C127 C97 C138 C14 -1.7(12) .
C24 C14 C138 C97 -89.3(9) .
C38 C14 C138 C97 86.4(9) .
C24 C14 C138 C144 94.3(9) .
C38 C14 C138 C144 -90.0(9) .
C97 C127 C139 C117 -0.1(8) .
N1 C117 C139 C127 -0.9(8) .
C92 C117 C139 C127 171.1(8) .
F18 C108 C140 F19 -1.6(11) .
C129 C108 C140 F19 179.5(7) .
F18 C108 C140 C120 176.9(7) .
C129 C108 C140 C120 -2.1(11) .
F20 C120 C140 F19 -0.2(11) .
C107 C120 C140 F19 177.8(7) .
F20 C120 C140 C108 -178.6(7) .
C107 C120 C140 C108 -0.7(11) .
C7 C6 C141 C96 0.1(8) .
N7 C96 C141 C6 -0.5(8) .
C128 C96 C141 C6 -179.4(7) .
F33 C22 C142 F32 -2.6(12) .
C35 C22 C142 F32 175.9(8) .
F33 C22 C142 C151 -179.7(8) .
C35 C22 C142 C151 -1.2(13) .
F1 C20 C143 F2 0.5(13) .
C152 C20 C143 F2 179.3(8) .
F1 C20 C143 C28 -179.9(8) .
C152 C20 C143 C28 -1.1(14) .
F3 C28 C143 F2 0.4(14) .
C18 C28 C143 F2 -179.1(8) .
F3 C28 C143 C20 -179.2(8) .
C18 C28 C143 C20 1.3(14) .
C90 N2 C144 C138 -176.1(7) .
Ag2 N2 C144 C138 -2.9(11) .
C90 N2 C144 C40 0.7(8) .
Ag2 N2 C144 C40 173.9(5) .
C97 C138 C144 N2 0.0(12) .
C14 C138 C144 N2 176.0(7) .
C97 C138 C144 C40 -176.1(8) .
C14 C138 C144 C40 0.0(13) .
C119 C40 C144 N2 1.4(9) .
C119 C40 C144 C138 178.1(8) .
C91 C94 C145 C102 0.0(8) .
N8 C102 C145 C94 0.9(8) .
C122 C102 C145 C94 -175.2(8) .
F17 C129 C146 F16 0.8(11) .
C108 C129 C146 F16 -178.3(7) .
F17 C129 C146 C107 -180.0(7) .
C108 C129 C146 C107 0.9(12) .
C120 C107 C146 F16 175.7(6) .
C13 C107 C146 F16 -5.4(10) .
C120 C107 C146 C129 -3.5(10) .
C13 C107 C146 C129 175.4(7) .
C111 C123 C147 C98 -0.6(8) .
N11 C98 C147 C123 0.2(8) .
C114 C98 C147 C123 177.5(7) .
C9 C37 C148 C115 -0.2(8) .
N10 C115 C148 C37 1.3(8) .
C155 C115 C148 C37 -178.3(7) .
F12 C42 C149 F11 1.0(10) .
C100 C42 C149 F11 -179.5(7) .
F12 C42 C149 C134 179.6(7) .
C100 C42 C149 C134 -0.9(11) .
C126 C134 C149 F11 178.4(6) .
C122 C134 C149 F11 -1.9(10) .
C126 C134 C149 C42 -0.2(10) .
C122 C134 C149 C42 179.5(7) .
C12 C101 C150 C106 0.0(8) .
N6 C106 C150 C101 0.6(8) .
C13 C106 C150 C101 -179.5(7) .
F32 C142 C151 F31 1.5(11) .
C22 C142 C151 F31 178.5(7) .
F32 C142 C151 C30 -176.7(7) .
C22 C142 C151 C30 0.3(12) .
C104 C30 C151 F31 -177.1(7) .
C31 C30 C151 F31 -0.1(11) .
C104 C30 C151 C142 1.1(12) .
C31 C30 C151 C142 178.2(7) .
F1 C20 C152 C132 179.5(7) .
C143 C20 C152 C132 0.7(12) .
F1 C20 C152 C19 4.8(12) .
C143 C20 C152 C19 -173.9(8) .
F5 C132 C152 C20 -177.5(7) .
C18 C132 C152 C20 -0.5(11) .
F5 C132 C152 C19 -2.8(11) .
C18 C132 C152 C19 174.2(7) .
C113 C19 C152 C20 -124.5(8) .
C136 C19 C152 C20 60.2(10) .
C113 C19 C152 C132 61.3(10) .
C136 C19 C152 C132 -114.1(8) .
F28 C26 C153 F29 -0.9(14) .
C29 C26 C153 F29 179.4(8) .
F28 C26 C153 C156 178.0(8) .
C29 C26 C153 C156 -1.7(14) .
F13 C100 C154 F14 0.9(12) .
C42 C100 C154 F14 179.9(7) .
F13 C100 C154 C126 -179.8(7) .
C42 C100 C154 C126 -0.8(12) .
F15 C126 C154 F14 -0.7(11) .
C134 C126 C154 F14 179.0(7) .
F15 C126 C154 C100 180.0(7) .
C134 C126 C154 C100 -0.3(12) .
N10 C115 C155 C87 -1.5(11) .
C148 C115 C155 C87 177.9(7) .
N10 C115 C155 C125 -179.6(6) .
C148 C115 C155 C125 -0.2(11) .
N9 C87 C155 C115 3.7(10) .
C112 C87 C155 C115 -172.6(7) .
N9 C87 C155 C125 -178.2(6) .
C112 C87 C155 C125 5.5(11) .
C25 C125 C155 C115 73.1(10) .
C156 C125 C155 C115 -105.9(9) .
C25 C125 C155 C87 -105.1(9) .
C156 C125 C155 C87 75.9(9) .
F29 C153 C156 F30 -1.8(13) .
C26 C153 C156 F30 179.4(8) .
F29 C153 C156 C125 179.4(8) .
C26 C153 C156 C125 0.5(14) .
C25 C125 C156 F30 -178.5(8) .
C155 C125 C156 F30 0.6(12) .
C25 C125 C156 C153 0.3(13) .
C155 C125 C156 C153 179.4(8) .
C121 C41 C157 C11 0.8(9) .
N13 C11 C157 C41 -2.1(8) .
C89 C11 C157 C41 168.7(9) .
C76 C158 O10 C78 -63.4(19) .
C166 O9 C76 C158 -63.9(17) .
O10 C158 C76 O9 65.5(19) .
C158 O10 C78 C166 63.2(18) .
C76 O9 C166 C78 67.2(19) .
O10 C78 C166 O9 -66(2) .
O11 C77 C80 O12 -54(3) .
O11 C79 C84 O12 69(3) .
C84 C79 O11 C77 -58(2) .
C80 C77 O11 C79 55(2) .
C79 C84 O12 C80 -62(3) .
C77 C80 O12 C84 55(3) .
C163 C162 C161 C160 92(4) .
C159 C160 C161 C162 168(3) .
C161 C162 C163 C164 -116(2) .
C165 C164 C163 C162 -108(3) .
