#------------------------------------------------------------------------------
#$Date: 2019-11-24 06:43:57 +0200 (Sun, 24 Nov 2019) $
#$Revision: 236997 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/34/99/4349979.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4349979
loop_
_publ_author_name
'Ji, Xiao-Qin'
'Ma, Fang'
'Xiong, Jin'
'Yang, Jing'
'Sun, Hao-Ling'
'Zhang, Yi-Quan'
'Gao, Song'
_publ_section_title
;
 A rare chloride-bridged dysprosium chain with slow magnetic relaxation: a
 thermally activated mechanism via a second-excited state promoted by
 magnetic interactions
;
_journal_issue                   3
_journal_name_full               'Inorganic Chemistry Frontiers'
_journal_page_first              786
_journal_paper_doi               10.1039/C8QI01331D
_journal_volume                  6
_journal_year                    2019
_chemical_formula_moiety         'C13 H12 Br Cl Dy N4 O4'
_chemical_formula_sum            'C13 H12 Br Cl Dy N4 O4'
_chemical_formula_weight         566.13
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     iterative
_atom_sites_solution_secondary   difmap
_audit_creation_date             2018-09-25
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2018-09-25 deposited with the CCDC.
2019-01-29 downloaded from the CCDC.
;
_cell_angle_alpha                99.133(6)
_cell_angle_beta                 92.117(6)
_cell_angle_gamma                104.301(7)
_cell_formula_units_Z            2
_cell_length_a                   6.9739(6)
_cell_length_b                   9.0675(7)
_cell_length_c                   13.0622(9)
_cell_measurement_reflns_used    1394
_cell_measurement_temperature    100.01(10)
_cell_measurement_theta_max      24.8440
_cell_measurement_theta_min      3.5180
_cell_volume                     787.75(11)
_computing_cell_refinement       'CrysAlisPro 1.171.39.32a (Rigaku OD, 2017)'
_computing_data_collection       'CrysAlisPro 1.171.39.32a (Rigaku OD, 2017)'
_computing_data_reduction        'CrysAlisPro 1.171.39.32a (Rigaku OD, 2017)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    'olex2.solve (Bourhis et al., 2015)'
_diffrn_ambient_temperature      100.01(10)
_diffrn_detector_area_resol_mean 5.3127
_diffrn_detector_type            AtlasS2
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.953
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
#--------------------------------------------------------------------------
  1  ω    -18.00  94.00   1.00    1.50    --   23.13  57.00   0.00  112
  2  ω     99.00 125.00   1.00    1.50    --   23.13 178.00   0.00   26
  3  ω    -14.00 107.00   1.00    1.50    --   23.13  57.00 120.00  121
  4  ω    -13.00 103.00   1.00    1.50    --   23.13  77.00-150.00  116
;
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type  'SuperNova, Dual, Cu at home/near, AtlasS2'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0575
_diffrn_reflns_av_unetI/netI     0.1211
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            5233
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         3.30
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    7.475
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.89858
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.39.32a (Rigaku Oxford Diffraction, 2017)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'clear light yellow'
_exptl_crystal_density_diffrn    2.387
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             536
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.06
_exptl_crystal_size_min          0.05
_refine_diff_density_max         2.226
_refine_diff_density_min         -1.753
_refine_diff_density_rms         0.313
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.971
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     221
_refine_ls_number_reflns         3429
_refine_ls_number_restraints     72
_refine_ls_restrained_S_all      0.961
_refine_ls_R_factor_all          0.0745
_refine_ls_R_factor_gt           0.0527
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0134P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0887
_refine_ls_wR_factor_ref         0.0978
_reflns_number_gt                2654
_reflns_number_total             3429
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c8qi01331d2.cif
_cod_data_source_block           20161116l
_cod_database_code               4349979
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, H4 of O4, All N(H) groups
 At 1.5 times of:
  All C(H,H,H) groups, H11 of O4
2. Uiso/Uaniso restraints and constraints
Uanis(C4) \\sim Ueq, Uanis(C6) \\sim Ueq, Uanis(C9) \\sim Ueq: with sigma of
0.001 and sigma for terminal atoms of 0.002
Uanis(N1) \\sim Ueq, Uanis(N4) \\sim Ueq: with sigma of 0.001 and sigma for
terminal atoms of 0.002
Uanis(O4) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uanis(N2) \\sim Ueq, Uanis(N3) \\sim Ueq: with sigma of 0.001 and sigma for
terminal atoms of 0.002
Uanis(C8) \\sim Ueq, Uanis(C2) \\sim Ueq, Uanis(C5) \\sim Ueq: with sigma of
0.001 and sigma for terminal atoms of 0.002
Uanis(C12) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
3.a Aromatic/amide H refined with riding coordinates:
 N2(H2), C12(H12), C7(H7), C3(H3), C2(H2A), C10(H10), C5(H5), O4(H4)
3.b Idealised Me refined as rotating group:
 C13(H13A,H13B,H13C)
;
_olex2_submission_special_instructions 'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Dy1 Dy 0.25201(6) 0.07472(5) 0.59165(3) 0.00766(12) Uani 1 d . .
Br1 Br 0.79707(13) 0.84218(10) 0.96854(7) 0.0170(2) Uani 1 d . .
Cl1 Cl 0.5222(3) 0.1448(2) 0.44126(17) 0.0162(5) Uani 1 d . .
O1 O 0.4499(8) 0.2026(6) 0.7247(4) 0.0133(14) Uani 1 d . .
O2 O 0.0358(8) 0.1251(6) 0.4669(4) 0.0123(14) Uani 1 d . .
O3 O -0.0967(8) 0.5461(6) 0.1848(5) 0.0131(14) Uani 1 d . .
N3 N -0.1506(9) 0.1389(8) 0.2942(5) 0.0069(15) Uani 1 d . U
N1 N 0.2978(10) 0.3505(8) 0.5796(5) 0.0087(16) Uani 1 d . U
N2 N 0.2017(9) 0.3833(8) 0.4906(5) 0.0083(15) Uani 1 d . U
H2 H 0.2273 0.4746 0.4715 0.010 Uiso 1 calc R .
C8 C 0.0737(11) 0.2634(9) 0.4419(6) 0.0062(17) Uani 1 d . U
N4 N -0.1073(10) 0.4179(8) 0.2186(5) 0.0097(16) Uani 1 d . U
C13 C -0.1310(13) 0.0834(11) 0.7559(7) 0.019(2) Uani 1 d . .
H13A H -0.1789 -0.0244 0.7210 0.028 Uiso 1 calc GR .
H13B H -0.2413 0.1327 0.7588 0.028 Uiso 1 calc GR .
H13C H -0.0767 0.0866 0.8267 0.028 Uiso 1 calc GR .
C4 C 0.6947(12) 0.6400(10) 0.8889(6) 0.0082(18) Uani 1 d . U
C9 C -0.0343(12) 0.2754(9) 0.3438(6) 0.0075(18) Uani 1 d . U
C12 C -0.2400(12) 0.1477(10) 0.2034(6) 0.0094(19) Uani 1 d . U
H12 H -0.3232 0.0552 0.1644 0.011 Uiso 1 calc R .
C7 C 0.4178(11) 0.4746(9) 0.6339(6) 0.0075(18) Uani 1 d . .
H7 H 0.4365 0.5686 0.6077 0.009 Uiso 1 calc R .
C3 C 0.7016(12) 0.5135(10) 0.9337(7) 0.012(2) Uani 1 d . .
H3 H 0.7603 0.5259 1.0023 0.014 Uiso 1 calc R .
C1 C 0.5272(12) 0.3444(10) 0.7754(7) 0.0116(19) Uani 1 d . .
C2 C 0.6202(12) 0.3665(10) 0.8755(7) 0.013(2) Uani 1 d . U
H2A H 0.6281 0.2786 0.9048 0.015 Uiso 1 calc R .
C11 C -0.2196(13) 0.2820(11) 0.1628(7) 0.013(2) Uani 1 d . .
C6 C 0.5233(11) 0.4769(9) 0.7313(6) 0.0066(18) Uani 1 d . U
C10 C -0.0133(12) 0.4130(10) 0.3111(7) 0.0106(19) Uani 1 d . .
H10 H 0.0662 0.5052 0.3523 0.013 Uiso 1 calc R .
C5 C 0.6099(12) 0.6244(10) 0.7903(7) 0.014(2) Uani 1 d . U
H5 H 0.6094 0.7139 0.7612 0.016 Uiso 1 calc R .
O4 O 0.0190(8) 0.1630(7) 0.7000(4) 0.0160(14) Uani 1 d . U
H4 H 0.0291 0.2706 0.7065 0.019 Uiso 1 calc R .
H11 H -0.264(12) 0.299(10) 0.099(7) 0.024 Uiso 1 d R .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Cl1 Dy1 Dy1 109.60(5) 2_656 2_556
Cl1 Dy1 Dy1 99.59(5) . 2_556
Cl1 Dy1 Cl1 69.37(7) . 2_656
O1 Dy1 Dy1 157.38(15) . 2_556
O1 Dy1 Cl1 96.32(16) . .
O1 Dy1 Cl1 90.99(16) . 2_656
O1 Dy1 O2 137.6(2) . .
O1 Dy1 O2 145.7(2) . 2_556
O1 Dy1 N3 85.3(2) . 2_556
O1 Dy1 N1 74.2(2) . .
O1 Dy1 O4 80.1(2) . .
O2 Dy1 Dy1 32.02(14) 2_556 2_556
O2 Dy1 Dy1 32.08(14) . 2_556
O2 Dy1 Cl1 115.53(15) 2_556 .
O2 Dy1 Cl1 81.43(15) . .
O2 Dy1 Cl1 126.19(14) . 2_656
O2 Dy1 Cl1 88.78(14) 2_556 2_656
O2 Dy1 O2 64.1(2) . 2_556
O2 Dy1 N3 62.9(2) 2_556 2_556
O2 Dy1 N3 124.3(2) . 2_556
O2 Dy1 N1 64.7(2) . .
O2 Dy1 N1 125.9(2) 2_556 .
O2 Dy1 O4 79.0(2) . .
O2 Dy1 O4 80.20(19) 2_556 .
N3 Dy1 Dy1 93.65(14) 2_556 2_556
N3 Dy1 Cl1 68.04(15) 2_556 2_656
N3 Dy1 Cl1 137.40(15) 2_556 .
N1 Dy1 Dy1 95.43(15) . 2_556
N1 Dy1 Cl1 136.84(16) . 2_656
N1 Dy1 Cl1 72.26(16) . .
N1 Dy1 N3 146.6(2) . 2_556
O4 Dy1 Dy1 77.68(14) . 2_556
O4 Dy1 Cl1 145.71(15) . .
O4 Dy1 Cl1 144.19(16) . 2_656
O4 Dy1 N3 76.7(2) . 2_556
O4 Dy1 N1 74.0(2) . .
Dy1 Cl1 Dy1 110.63(7) . 2_656
C1 O1 Dy1 142.1(6) . .
Dy1 O2 Dy1 115.9(2) . 2_556
C8 O2 Dy1 125.0(5) . 2_556
C8 O2 Dy1 118.9(5) . .
C9 N3 Dy1 115.7(5) . 2_556
C12 N3 Dy1 127.8(5) . 2_556
C12 N3 C9 113.6(7) . .
N2 N1 Dy1 116.6(4) . .
C7 N1 Dy1 130.7(6) . .
C7 N1 N2 112.0(7) . .
N1 N2 H2 124.2 . .
C8 N2 N1 111.6(7) . .
C8 N2 H2 124.2 . .
O2 C8 C9 115.6(7) . .
N2 C8 O2 125.6(8) . .
N2 C8 C9 118.7(8) . .
O3 N4 C11 120.0(7) . .
O3 N4 C10 122.3(7) . .
C11 N4 C10 117.7(8) . .
H13A C13 H13B 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
O4 C13 H13A 109.5 . .
O4 C13 H13B 109.5 . .
O4 C13 H13C 109.5 . .
C3 C4 Br1 119.1(6) . .
C5 C4 Br1 119.2(7) . .
C5 C4 C3 121.7(8) . .
N3 C9 C8 113.4(7) . .
N3 C9 C10 125.2(8) . .
C10 C9 C8 121.4(7) . .
N3 C12 H12 117.7 . .
N3 C12 C11 124.6(8) . .
C11 C12 H12 117.7 . .
N1 C7 H7 118.1 . .
N1 C7 C6 123.7(8) . .
C6 C7 H7 118.1 . .
C4 C3 H3 120.9 . .
C4 C3 C2 118.3(8) . .
C2 C3 H3 120.9 . .
O1 C1 C2 119.5(8) . .
O1 C1 C6 122.3(8) . .
C2 C1 C6 118.2(8) . .
C3 C2 C1 122.2(9) . .
C3 C2 H2A 118.9 . .
C1 C2 H2A 118.9 . .
N4 C11 C12 119.3(8) . .
N4 C11 H11 109(6) . .
C12 C11 H11 131(6) . .
C1 C6 C7 124.9(7) . .
C5 C6 C7 115.8(8) . .
C5 C6 C1 118.9(8) . .
N4 C10 H10 120.2 . .
C9 C10 N4 119.5(7) . .
C9 C10 H10 120.2 . .
C4 C5 C6 120.7(8) . .
C4 C5 H5 119.6 . .
C6 C5 H5 119.6 . .
Dy1 O4 H4 114.3 . .
C13 O4 Dy1 131.4(5) . .
C13 O4 H4 114.3 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 Dy1 3.9899(9) 2_556
Dy1 Cl1 2.809(2) .
Dy1 Cl1 2.821(2) 2_656
Dy1 O1 2.159(5) .
Dy1 O2 2.352(6) .
Dy1 O2 2.355(5) 2_556
Dy1 N3 2.606(7) 2_556
Dy1 N1 2.473(7) .
Dy1 O4 2.395(6) .
Br1 C4 1.909(8) .
Cl1 Dy1 2.821(2) 2_656
O1 C1 1.320(9) .
O2 Dy1 2.355(5) 2_556
O2 C8 1.312(10) .
O3 N4 1.294(9) .
N3 Dy1 2.606(7) 2_556
N3 C9 1.348(9) .
N3 C12 1.342(10) .
N1 N2 1.429(9) .
N1 C7 1.307(9) .
N2 H2 0.8800 .
N2 C8 1.282(9) .
C8 C9 1.495(11) .
N4 C11 1.364(10) .
N4 C10 1.365(10) .
C13 H13A 0.9800 .
C13 H13B 0.9800 .
C13 H13C 0.9800 .
C13 O4 1.414(10) .
C4 C3 1.378(12) .
C4 C5 1.369(11) .
C9 C10 1.358(12) .
C12 H12 0.9500 .
C12 C11 1.382(12) .
C7 H7 0.9500 .
C7 C6 1.440(11) .
C3 H3 0.9500 .
C3 C2 1.396(11) .
C1 C2 1.400(11) .
C1 C6 1.418(12) .
C2 H2A 0.9500 .
C11 H11 0.93(9) .
C6 C5 1.409(11) .
C10 H10 0.9500 .
C5 H5 0.9500 .
O4 H4 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Dy1 Dy1 Cl1 Dy1 -107.46(7) 2_556 2_656
Dy1 Dy1 O1 C1 -57.2(11) 2_556 .
Dy1 Dy1 O2 C8 174.4(7) 2_556 .
Dy1 Dy1 N1 N2 -23.1(5) 2_556 .
Dy1 Dy1 N1 C7 167.4(7) 2_556 .
Dy1 Dy1 O4 C13 75.8(7) 2_556 .
Dy1 O1 C1 C2 165.6(6) . .
Dy1 O1 C1 C6 -15.7(14) . .
Dy1 O2 C8 N2 162.3(6) 2_556 .
Dy1 O2 C8 N2 -11.6(11) . .
Dy1 O2 C8 C9 -22.1(10) 2_556 .
Dy1 O2 C8 C9 164.0(5) . .
Dy1 N3 C9 C8 20.8(8) 2_556 .
Dy1 N3 C9 C10 -158.9(7) 2_556 .
Dy1 N3 C12 C11 159.2(6) 2_556 .
Dy1 N1 N2 C8 13.3(8) . .
Dy1 N1 C7 C6 -14.6(11) . .
Br1 C4 C3 C2 177.9(6) . .
Br1 C4 C5 C6 -176.6(6) . .
Cl1 Dy1 Cl1 Dy1 0.0 2_656 2_656
Cl1 Dy1 O1 C1 146.7(9) 2_656 .
Cl1 Dy1 O1 C1 77.3(9) . .
Cl1 Dy1 O2 Dy1 67.4(3) 2_656 2_556
Cl1 Dy1 O2 Dy1 123.9(2) . 2_556
Cl1 Dy1 O2 C8 -118.2(5) 2_656 .
Cl1 Dy1 O2 C8 -61.7(6) . .
Cl1 Dy1 N1 N2 75.2(5) . .
Cl1 Dy1 N1 N2 103.3(5) 2_656 .
Cl1 Dy1 N1 C7 -94.3(7) . .
Cl1 Dy1 N1 C7 -66.2(8) 2_656 .
Cl1 Dy1 O4 C13 164.7(6) . .
Cl1 Dy1 O4 C13 -30.7(8) 2_656 .
O1 Dy1 Cl1 Dy1 88.68(17) . 2_656
O1 Dy1 O2 Dy1 -146.1(3) . 2_556
O1 Dy1 O2 C8 28.3(7) . .
O1 Dy1 N1 N2 177.4(5) . .
O1 Dy1 N1 C7 7.9(7) . .
O1 Dy1 O4 C13 -108.5(7) . .
O1 C1 C2 C3 -178.9(7) . .
O1 C1 C6 C7 7.5(13) . .
O1 C1 C6 C5 -179.7(7) . .
O2 Dy1 Cl1 Dy1 -78.17(17) 2_556 2_656
O2 Dy1 Cl1 Dy1 -134.01(15) . 2_656
O2 Dy1 O1 C1 -124.0(8) 2_556 .
O2 Dy1 O1 C1 -6.9(10) . .
O2 Dy1 O2 Dy1 0.0 2_556 2_556
O2 Dy1 O2 C8 174.4(7) 2_556 .
O2 Dy1 N1 N2 -13.5(4) . .
O2 Dy1 N1 N2 -33.9(6) 2_556 .
O2 Dy1 N1 C7 156.7(6) 2_556 .
O2 Dy1 N1 C7 177.0(8) . .
O2 Dy1 O4 C13 108.5(7) . .
O2 Dy1 O4 C13 43.2(7) 2_556 .
O2 C8 C9 N3 -2.0(10) . .
O2 C8 C9 C10 177.7(8) . .
O3 N4 C11 C12 -175.6(8) . .
O3 N4 C10 C9 178.2(8) . .
N3 Dy1 Cl1 Dy1 -1.3(2) 2_556 2_656
N3 Dy1 O1 C1 -145.5(9) 2_556 .
N3 Dy1 O2 Dy1 -19.1(4) 2_556 2_556
N3 Dy1 O2 C8 155.3(5) 2_556 .
N3 Dy1 N1 N2 -128.2(5) 2_556 .
N3 Dy1 N1 C7 62.3(8) 2_556 .
N3 Dy1 O4 C13 -21.1(7) 2_556 .
N3 C9 C10 N4 -3.4(13) . .
N3 C12 C11 N4 -2.4(13) . .
N1 Dy1 Cl1 Dy1 159.87(18) . 2_656
N1 Dy1 O1 C1 7.8(9) . .
N1 Dy1 O2 Dy1 -161.7(3) . 2_556
N1 Dy1 O2 C8 12.7(5) . .
N1 Dy1 O4 C13 175.2(7) . .
N1 N2 C8 O2 -1.7(11) . .
N1 N2 C8 C9 -177.2(6) . .
N1 C7 C6 C1 6.7(13) . .
N1 C7 C6 C5 -166.3(8) . .
N2 N1 C7 C6 175.6(7) . .
N2 C8 C9 N3 174.0(7) . .
N2 C8 C9 C10 -6.3(12) . .
C8 C9 C10 N4 177.0(7) . .
C4 C3 C2 C1 -2.0(12) . .
C9 N3 C12 C11 -0.6(12) . .
C12 N3 C9 C8 -176.8(7) . .
C12 N3 C9 C10 3.5(12) . .
C7 N1 N2 C8 -175.3(7) . .
C7 C6 C5 C4 172.8(7) . .
C3 C4 C5 C6 1.0(13) . .
C1 C6 C5 C4 -0.7(12) . .
C2 C1 C6 C7 -173.8(7) . .
C2 C1 C6 C5 -1.0(12) . .
C11 N4 C10 C9 0.1(12) . .
C6 C1 C2 C3 2.3(12) . .
C10 N4 C11 C12 2.6(12) . .
C5 C4 C3 C2 0.3(12) . .
O4 Dy1 Cl1 Dy1 170.4(2) . 2_656
O4 Dy1 O1 C1 -68.2(9) . .
O4 Dy1 O2 Dy1 -84.4(3) . 2_556
O4 Dy1 O2 C8 90.0(6) . .
O4 Dy1 N1 N2 -98.7(5) . .
O4 Dy1 N1 C7 91.9(7) . .
