#------------------------------------------------------------------------------
#$Date: 2019-11-25 00:34:17 +0200 (Mon, 25 Nov 2019) $
#$Revision: 239771 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/35/01/4350186.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4350186
loop_
_publ_author_name
'Dong, Yu-Bin'
'Xu, Hong-Xia'
'Ma, Jian-Ping'
'Huang, Ru-Qi'
_publ_section_title
;
 Silver(I) coordination polymers based on a nano-sized bent
 bis(3-acetylenylphenyl-(4-cyanophenyl))oxadiazole ligand: the role of
 ligand isomerism and the templating effect of polyatomic anions and
 solvent intermediates.
;
_journal_issue                   8
_journal_name_full               'Inorganic chemistry'
_journal_page_first              3325
_journal_page_last               3343
_journal_paper_doi               10.1021/ic052158w
_journal_volume                  45
_journal_year                    2006
_chemical_formula_sum            'C40 H22 Ag2 F6 N4 O7 S2'
_chemical_formula_weight         1064.48
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                104.084(2)
_cell_angle_beta                 94.263(2)
_cell_angle_gamma                104.432(2)
_cell_formula_units_Z            2
_cell_length_a                   10.8840(16)
_cell_length_b                   13.0047(19)
_cell_length_c                   16.524(3)
_cell_measurement_temperature    293(2)
_cell_volume                     2174.2(6)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0212
_diffrn_reflns_av_sigmaI/netI    0.0480
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            11835
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         1.68
_exptl_absorpt_coefficient_mu    1.074
_exptl_absorpt_correction_T_max  0.8730
_exptl_absorpt_correction_T_min  0.4842
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    1.626
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       bar
_exptl_crystal_F_000             1052
_exptl_crystal_size_max          0.79
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.13
_refine_diff_density_max         0.898
_refine_diff_density_min         -0.496
_refine_diff_density_rms         '0.084 End ===='
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.018
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     550
_refine_ls_number_reflns         7908
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.018
_refine_ls_R_factor_all          0.0754
_refine_ls_R_factor_gt           0.0511
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0832P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1330
_refine_ls_wR_factor_ref         0.1443
_reflns_number_gt                5376
_reflns_number_total             7908
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic052158wsi20051219_053724.cif
_cod_data_source_block           2
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Triclinic' was changed to
'triclinic' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/ACS/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4350186
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.35134(4) 0.23314(3) 0.15453(3) 0.06764(17) Uani 1 1 d .
Ag2 Ag 0.59586(4) 0.14904(3) 0.25236(3) 0.06614(17) Uani 1 1 d .
N1 N 0.4691(3) 0.0275(3) 0.1322(2) 0.0420(8) Uani 1 1 d .
N2 N 0.3736(3) 0.0613(3) 0.0930(2) 0.0419(8) Uani 1 1 d .
N3 N -0.2448(5) 0.6576(4) -0.1300(3) 0.0818(15) Uani 1 1 d .
N4 N 1.2622(4) -0.1463(4) 0.6519(3) 0.0723(13) Uani 1 1 d .
C1 C 0.4586(4) -0.0724(3) 0.0895(2) 0.0357(9) Uani 1 1 d .
C2 C 0.5335(4) -0.1486(3) 0.1013(2) 0.0357(9) Uani 1 1 d .
C3 C 0.5100(4) -0.2486(3) 0.0411(3) 0.0479(11) Uani 1 1 d .
H3 H 0.4484 -0.2667 -0.0060 0.058 Uiso 1 1 calc R
C4 C 0.5797(5) -0.3216(4) 0.0521(3) 0.0614(14) Uani 1 1 d .
H4 H 0.5652 -0.3888 0.0119 0.074 Uiso 1 1 calc R
C5 C 0.6693(4) -0.2952(4) 0.1217(3) 0.0502(11) Uani 1 1 d .
H5 H 0.7137 -0.3456 0.1290 0.060 Uiso 1 1 calc R
C6 C 0.6952(4) -0.1943(4) 0.1818(3) 0.0404(10) Uani 1 1 d .
C7 C 0.6258(4) -0.1209(3) 0.1707(3) 0.0409(10) Uani 1 1 d .
H7 H 0.6418 -0.0529 0.2102 0.049 Uiso 1 1 calc R
C8 C 0.7892(4) -0.1684(4) 0.2552(3) 0.0447(10) Uani 1 1 d .
C9 C 0.8644(4) -0.1554(4) 0.3149(3) 0.0490(11) Uani 1 1 d .
C10 C 0.9504(4) -0.1468(4) 0.3871(3) 0.0464(11) Uani 1 1 d .
C11 C 1.0792(5) -0.1365(6) 0.3842(4) 0.0838(19) Uani 1 1 d .
H11 H 1.1117 -0.1313 0.3344 0.101 Uiso 1 1 calc R
C12 C 1.1593(5) -0.1338(6) 0.4518(4) 0.087(2) Uani 1 1 d .
H12 H 1.2455 -0.1275 0.4478 0.105 Uiso 1 1 calc R
C13 C 1.1142(5) -0.1402(4) 0.5257(3) 0.0533(12) Uani 1 1 d .
C14 C 1.1985(5) -0.1435(5) 0.5963(4) 0.0627(14) Uani 1 1 d .
C15 C 0.9874(5) -0.1474(5) 0.5326(3) 0.0643(14) Uani 1 1 d .
H15 H 0.9568 -0.1499 0.5833 0.077 Uiso 1 1 calc R
C16 C 0.9058(5) -0.1507(5) 0.4627(3) 0.0645(15) Uani 1 1 d .
H16 H 0.8199 -0.1557 0.4669 0.077 Uiso 1 1 calc R
C17 C 0.3128(4) -0.0197(3) 0.0298(3) 0.0377(9) Uani 1 1 d .
C18 C 0.2083(4) -0.0275(3) -0.0340(3) 0.0392(10) Uani 1 1 d .
C19 C 0.1611(4) -0.1233(3) -0.0994(3) 0.0478(11) Uani 1 1 d .
H19 H 0.1937 -0.1834 -0.1014 0.057 Uiso 1 1 calc R
C20 C 0.0662(5) -0.1290(4) -0.1612(3) 0.0624(14) Uani 1 1 d .
H20 H 0.0359 -0.1925 -0.2058 0.075 Uiso 1 1 calc R
C21 C 0.0155(5) -0.0407(4) -0.1576(3) 0.0558(13) Uani 1 1 d .
H21 H -0.0499 -0.0456 -0.1991 0.067 Uiso 1 1 calc R
C22 C 0.0617(4) 0.0547(4) -0.0923(3) 0.0419(10) Uani 1 1 d .
C23 C 0.1575(4) 0.0608(3) -0.0310(3) 0.0416(10) Uani 1 1 d .
H23 H 0.1887 0.1248 0.0130 0.050 Uiso 1 1 calc R
C24 C 0.0145(4) 0.1490(4) -0.0911(3) 0.0475(11) Uani 1 1 d .
C25 C -0.0222(4) 0.2268(4) -0.0922(3) 0.0492(11) Uani 1 1 d .
C26 C -0.0632(4) 0.3230(4) -0.0968(3) 0.0455(11) Uani 1 1 d .
C27 C -0.0290(5) 0.3731(4) -0.1592(3) 0.0546(12) Uani 1 1 d .
H27 H 0.0243 0.3475 -0.1959 0.066 Uiso 1 1 calc R
C28 C -0.0738(5) 0.4620(4) -0.1677(3) 0.0561(13) Uani 1 1 d .
H28 H -0.0518 0.4952 -0.2105 0.067 Uiso 1 1 calc R
C29 C -0.1503(5) 0.4997(4) -0.1125(3) 0.0535(12) Uani 1 1 d .
C30 C -0.2002(5) 0.5891(4) -0.1221(3) 0.0617(13) Uani 1 1 d .
C31 C -0.1826(5) 0.4527(4) -0.0472(3) 0.0562(12) Uani 1 1 d .
H31 H -0.2328 0.4803 -0.0090 0.067 Uiso 1 1 calc R
C32 C -0.1381(5) 0.3635(4) -0.0403(3) 0.0544(12) Uani 1 1 d .
H32 H -0.1590 0.3308 0.0029 0.065 Uiso 1 1 calc R
C33 C 0.3759(11) 0.3468(10) 0.4185(7) 0.139(4) Uani 1 1 d .
C34 C 0.6960(10) 0.4867(6) 0.2817(5) 0.108(3) Uani 1 1 d .
C35 C 0.4184(10) 0.7158(9) 0.2917(8) 0.128(3) Uani 1 1 d .
H35 H 0.4032 0.6414 0.2642 0.154 Uiso 1 1 calc R
C36 C 0.3598(8) 0.7797(12) 0.2613(5) 0.128(4) Uani 1 1 d .
H36 H 0.2998 0.7486 0.2128 0.154 Uiso 1 1 calc R
C37 C 0.3864(8) 0.8929(9) 0.3007(7) 0.108(3) Uani 1 1 d .
H37 H 0.3459 0.9372 0.2787 0.130 Uiso 1 1 calc R
C38 C 0.4744(10) 0.9363(8) 0.3732(7) 0.116(3) Uani 1 1 d .
H38 H 0.4962 1.0112 0.4006 0.139 Uiso 1 1 calc R
C39 C 0.5258(9) 0.8711(13) 0.4022(6) 0.133(4) Uani 1 1 d .
H39 H 0.5831 0.8996 0.4520 0.159 Uiso 1 1 calc R
C40 C 0.4991(11) 0.7624(11) 0.3624(9) 0.136(3) Uani 1 1 d .
H40 H 0.5391 0.7189 0.3858 0.163 Uiso 1 1 calc R
O1 O 0.3623(3) -0.1069(2) 0.02389(17) 0.0389(7) Uani 1 1 d .
O2 O 0.5961(4) 0.2923(3) 0.1795(3) 0.0886(13) Uani 1 1 d .
O3 O 0.6845(7) 0.4438(4) 0.1235(3) 0.136(2) Uani 1 1 d .
O4 O 0.8179(6) 0.3722(5) 0.2007(6) 0.173(3) Uani 1 1 d .
O5 O 0.4042(5) 0.2047(5) 0.2911(3) 0.1133(17) Uani 1 1 d .
O6 O 0.3098(7) 0.1389(5) 0.4030(4) 0.133(2) Uani 1 1 d .
O7 O 0.1960(5) 0.2096(6) 0.3142(4) 0.141(2) Uani 1 1 d .
F1 F 0.5869(10) 0.5163(8) 0.2788(6) 0.258(5) Uani 1 1 d .
F2 F 0.7815(7) 0.5756(4) 0.2933(3) 0.186(3) Uani 1 1 d .
F3 F 0.6891(7) 0.4464(5) 0.3445(3) 0.161(2) Uani 1 1 d .
F4 F 0.3855(8) 0.4175(4) 0.3776(5) 0.202(4) Uani 1 1 d .
F5 F 0.3122(8) 0.3597(5) 0.4795(4) 0.209(4) Uani 1 1 d .
F6 F 0.5019(8) 0.3508(7) 0.4514(5) 0.237(4) Uani 1 1 d .
S1 S 0.68709(17) 0.39061(11) 0.18448(9) 0.0713(4) Uani 1 1 d .
S2 S 0.31795(15) 0.20915(14) 0.34979(10) 0.0734(4) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N3 Ag1 N2 139.35(17) 2_565 .
N3 Ag1 O5 125.72(19) 2_565 .
N2 Ag1 O5 88.42(16) . .
N3 Ag1 O2 121.33(17) 2_565 .
N2 Ag1 O2 84.60(13) . .
O5 Ag1 O2 76.33(16) . .
N4 Ag2 N1 137.47(16) 2_756 .
N4 Ag2 O2 128.59(16) 2_756 .
N1 Ag2 O2 85.96(12) . .
N4 Ag2 O5 120.10(18) 2_756 .
N1 Ag2 O5 87.55(16) . .
O2 Ag2 O5 77.77(17) . .
C1 N1 N2 106.4(3) . .
C1 N1 Ag2 135.7(3) . .
N2 N1 Ag2 117.9(2) . .
C17 N2 N1 107.3(3) . .
C17 N2 Ag1 135.0(3) . .
N1 N2 Ag1 117.6(2) . .
C30 N3 Ag1 171.8(5) . 2_565
C14 N4 Ag2 172.2(5) . 2_756
N1 C1 O1 111.2(3) . .
N1 C1 C2 130.4(4) . .
O1 C1 C2 118.4(3) . .
C7 C2 C3 120.6(4) . .
C7 C2 C1 120.7(4) . .
C3 C2 C1 118.7(4) . .
C2 C3 C4 119.0(4) . .
C2 C3 H3 120.5 . .
C4 C3 H3 120.5 . .
C5 C4 C3 120.5(4) . .
C5 C4 H4 119.8 . .
C3 C4 H4 119.8 . .
C4 C5 C6 121.0(4) . .
C4 C5 H5 119.5 . .
C6 C5 H5 119.5 . .
C5 C6 C7 118.6(4) . .
C5 C6 C8 120.1(4) . .
C7 C6 C8 121.2(4) . .
C2 C7 C6 120.3(4) . .
C2 C7 H7 119.9 . .
C6 C7 H7 119.9 . .
C9 C8 C6 175.1(5) . .
C8 C9 C10 176.3(5) . .
C11 C10 C16 117.7(4) . .
C11 C10 C9 122.0(4) . .
C16 C10 C9 120.3(4) . .
C12 C11 C10 121.8(5) . .
C12 C11 H11 119.1 . .
C10 C11 H11 119.1 . .
C11 C12 C13 120.2(5) . .
C11 C12 H12 119.9 . .
C13 C12 H12 119.9 . .
C12 C13 C15 120.2(4) . .
C12 C13 C14 120.1(5) . .
C15 C13 C14 119.7(5) . .
N4 C14 C13 178.8(6) . .
C13 C15 C16 119.1(5) . .
C13 C15 H15 120.5 . .
C16 C15 H15 120.5 . .
C10 C16 C15 120.9(5) . .
C10 C16 H16 119.5 . .
C15 C16 H16 119.5 . .
N2 C17 O1 110.7(3) . .
N2 C17 C18 130.2(4) . .
O1 C17 C18 119.0(4) . .
C23 C18 C19 119.6(4) . .
C23 C18 C17 120.6(4) . .
C19 C18 C17 119.8(4) . .
C20 C19 C18 119.7(4) . .
C20 C19 H19 120.1 . .
C18 C19 H19 120.1 . .
C19 C20 C21 120.3(4) . .
C19 C20 H20 119.8 . .
C21 C20 H20 119.8 . .
C22 C21 C20 120.2(4) . .
C22 C21 H21 119.9 . .
C20 C21 H21 119.9 . .
C23 C22 C21 119.5(4) . .
C23 C22 C24 120.2(4) . .
C21 C22 C24 120.3(4) . .
C22 C23 C18 120.7(4) . .
C22 C23 H23 119.7 . .
C18 C23 H23 119.7 . .
C25 C24 C22 177.8(5) . .
C24 C25 C26 177.1(5) . .
C27 C26 C32 120.0(4) . .
C27 C26 C25 119.5(4) . .
C32 C26 C25 120.6(4) . .
C26 C27 C28 120.3(5) . .
C26 C27 H27 119.9 . .
C28 C27 H27 119.9 . .
C29 C28 C27 119.2(4) . .
C29 C28 H28 120.4 . .
C27 C28 H28 120.4 . .
C28 C29 C31 121.4(4) . .
C28 C29 C30 119.8(5) . .
C31 C29 C30 118.8(5) . .
N3 C30 C29 177.2(6) . .
C32 C31 C29 118.5(5) . .
C32 C31 H31 120.7 . .
C29 C31 H31 120.7 . .
C26 C32 C31 120.6(5) . .
C26 C32 H32 119.7 . .
C31 C32 H32 119.7 . .
F4 C33 F5 115.5(13) . .
F4 C33 F6 107.7(9) . .
F5 C33 F6 107.9(10) . .
F4 C33 S2 111.2(8) . .
F5 C33 S2 111.0(8) . .
F6 C33 S2 102.7(9) . .
F2 C34 F3 115.0(8) . .
F2 C34 F1 103.9(8) . .
F3 C34 F1 101.0(8) . .
F2 C34 S1 114.1(6) . .
F3 C34 S1 114.6(6) . .
F1 C34 S1 106.2(7) . .
C40 C35 C36 117.2(11) . .
C40 C35 H35 121.4 . .
C36 C35 H35 121.4 . .
C35 C36 C37 121.5(9) . .
C35 C36 H36 119.2 . .
C37 C36 H36 119.2 . .
C38 C37 C36 117.9(9) . .
C38 C37 H37 121.1 . .
C36 C37 H37 121.1 . .
C39 C38 C37 118.7(10) . .
C39 C38 H38 120.7 . .
C37 C38 H38 120.7 . .
C38 C39 C40 122.1(10) . .
C38 C39 H39 119.0 . .
C40 C39 H39 119.0 . .
C35 C40 C39 122.5(11) . .
C35 C40 H40 118.7 . .
C39 C40 H40 118.7 . .
C1 O1 C17 104.4(3) . .
S1 O2 Ag2 131.4(3) . .
S1 O2 Ag1 133.2(3) . .
Ag2 O2 Ag1 90.14(13) . .
S2 O5 Ag1 120.1(3) . .
S2 O5 Ag2 145.7(3) . .
Ag1 O5 Ag2 93.23(15) . .
O3 S1 O2 121.6(3) . .
O3 S1 O4 110.4(5) . .
O2 S1 O4 107.3(3) . .
O3 S1 C34 107.5(3) . .
O2 S1 C34 110.2(4) . .
O4 S1 C34 97.1(5) . .
O5 S2 O6 118.5(4) . .
O5 S2 O7 112.6(4) . .
O6 S2 O7 112.4(4) . .
O5 S2 C33 104.2(4) . .
O6 S2 C33 105.5(5) . .
O7 S2 C33 101.5(5) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N3 2.136(4) 2_565
Ag1 N2 2.299(3) .
Ag1 O5 2.425(5) .
Ag1 O2 2.554(5) .
Ag2 N4 2.141(4) 2_756
Ag2 N1 2.307(3) .
Ag2 O2 2.452(4) .
Ag2 O5 2.452(5) .
N1 C1 1.290(5) .
N1 N2 1.399(4) .
N2 C17 1.286(5) .
N3 C30 1.144(6) .
N3 Ag1 2.136(4) 2_565
N4 C14 1.122(6) .
N4 Ag2 2.141(4) 2_756
C1 O1 1.355(5) .
C1 C2 1.470(5) .
C2 C7 1.379(6) .
C2 C3 1.382(6) .
C3 C4 1.389(6) .
C3 H3 0.9300 .
C4 C5 1.367(6) .
C4 H4 0.9300 .
C5 C6 1.388(6) .
C5 H5 0.9300 .
C6 C7 1.391(5) .
C6 C8 1.441(6) .
C7 H7 0.9300 .
C8 C9 1.184(6) .
C9 C10 1.424(6) .
C10 C11 1.380(7) .
C10 C16 1.381(7) .
C11 C12 1.353(7) .
C11 H11 0.9300 .
C12 C13 1.363(8) .
C12 H12 0.9300 .
C13 C15 1.375(7) .
C13 C14 1.446(7) .
C15 C16 1.389(7) .
C15 H15 0.9300 .
C16 H16 0.9300 .
C17 O1 1.358(5) .
C17 C18 1.458(6) .
C18 C23 1.386(6) .
C18 C19 1.389(6) .
C19 C20 1.372(6) .
C19 H19 0.9300 .
C20 C21 1.383(6) .
C20 H20 0.9300 .
C21 C22 1.383(6) .
C21 H21 0.9300 .
C22 C23 1.372(6) .
C22 C24 1.440(6) .
C23 H23 0.9300 .
C24 C25 1.180(6) .
C25 C26 1.446(6) .
C26 C27 1.373(6) .
C26 C32 1.379(7) .
C27 C28 1.394(6) .
C27 H27 0.9300 .
C28 C29 1.366(7) .
C28 H28 0.9300 .
C29 C31 1.391(7) .
C29 C30 1.435(6) .
C31 C32 1.389(6) .
C31 H31 0.9300 .
C32 H32 0.9300 .
C33 F4 1.256(13) .
C33 F5 1.268(10) .
C33 F6 1.421(13) .
C33 S2 1.798(11) .
C34 F2 1.252(9) .
C34 F3 1.269(8) .
C34 F1 1.336(12) .
C34 S1 1.759(7) .
C35 C40 1.320(14) .
C35 C36 1.329(14) .
C35 H35 0.9300 .
C36 C37 1.403(13) .
C36 H36 0.9300 .
C37 C38 1.379(12) .
C37 H37 0.9300 .
C38 C39 1.286(13) .
C38 H38 0.9300 .
C39 C40 1.352(14) .
C39 H39 0.9300 .
C40 H40 0.9300 .
O2 S1 1.388(4) .
O3 S1 1.356(5) .
O4 S1 1.516(6) .
O5 S2 1.400(5) .
O6 S2 1.406(5) .
O7 S2 1.413(6) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
N4 Ag2 N1 C1 -5.5(5) 2_756
O2 Ag2 N1 C1 142.5(4) .
O5 Ag2 N1 C1 -139.6(4) .
N4 Ag2 N1 N2 171.3(3) 2_756
O2 Ag2 N1 N2 -40.7(3) .
O5 Ag2 N1 N2 37.2(3) .
C1 N1 N2 C17 -0.2(5) .
Ag2 N1 N2 C17 -177.8(3) .
C1 N1 N2 Ag1 176.5(3) .
Ag2 N1 N2 Ag1 -1.1(4) .
N3 Ag1 N2 C17 -10.2(5) 2_565
O5 Ag1 N2 C17 139.6(4) .
O2 Ag1 N2 C17 -144.0(4) .
N3 Ag1 N2 N1 174.2(3) 2_565
O5 Ag1 N2 N1 -36.0(3) .
O2 Ag1 N2 N1 40.5(3) .
N2 N1 C1 O1 0.4(5) .
Ag2 N1 C1 O1 177.5(3) .
N2 N1 C1 C2 179.7(4) .
Ag2 N1 C1 C2 -3.3(7) .
N1 C1 C2 C7 5.9(7) .
O1 C1 C2 C7 -174.9(4) .
N1 C1 C2 C3 -173.8(4) .
O1 C1 C2 C3 5.4(6) .
C7 C2 C3 C4 0.8(7) .
C1 C2 C3 C4 -179.5(4) .
C2 C3 C4 C5 0.5(8) .
C3 C4 C5 C6 -1.6(8) .
C4 C5 C6 C7 1.3(7) .
C4 C5 C6 C8 179.4(5) .
C3 C2 C7 C6 -1.1(6) .
C1 C2 C7 C6 179.2(4) .
C5 C6 C7 C2 0.0(6) .
C8 C6 C7 C2 -178.0(4) .
C5 C6 C8 C9 -29(6) .
C7 C6 C8 C9 149(6) .
C6 C8 C9 C10 -19(13) .
C8 C9 C10 C11 117(8) .
C8 C9 C10 C16 -62(8) .
C16 C10 C11 C12 2.1(10) .
C9 C10 C11 C12 -176.7(6) .
C10 C11 C12 C13 -0.6(12) .
C11 C12 C13 C15 -1.3(10) .
C11 C12 C13 C14 176.5(6) .
Ag2 N4 C14 C13 180(100) 2_756
C12 C13 C14 N4 -177(100) .
C15 C13 C14 N4 1(29) .
C12 C13 C15 C16 1.6(9) .
C14 C13 C15 C16 -176.2(5) .
C11 C10 C16 C15 -1.7(8) .
C9 C10 C16 C15 177.1(5) .
C13 C15 C16 C10 -0.1(9) .
N1 N2 C17 O1 -0.1(5) .
Ag1 N2 C17 O1 -176.0(3) .
N1 N2 C17 C18 -177.3(4) .
Ag1 N2 C17 C18 6.8(7) .
N2 C17 C18 C23 -1.5(7) .
O1 C17 C18 C23 -178.4(4) .
N2 C17 C18 C19 177.0(4) .
O1 C17 C18 C19 0.0(6) .
C23 C18 C19 C20 1.0(7) .
C17 C18 C19 C20 -177.5(4) .
C18 C19 C20 C21 -1.4(8) .
C19 C20 C21 C22 1.2(8) .
C20 C21 C22 C23 -0.5(7) .
C20 C21 C22 C24 176.3(5) .
C21 C22 C23 C18 0.1(7) .
C24 C22 C23 C18 -176.7(4) .
C19 C18 C23 C22 -0.4(6) .
C17 C18 C23 C22 178.1(4) .
C23 C22 C24 C25 106(14) .
C21 C22 C24 C25 -71(14) .
C22 C24 C25 C26 -3(22) .
C24 C25 C26 C27 7(11) .
C24 C25 C26 C32 -174(10) .
C32 C26 C27 C28 -2.5(7) .
C25 C26 C27 C28 176.3(4) .
C26 C27 C28 C29 1.0(8) .
C27 C28 C29 C31 1.2(8) .
C27 C28 C29 C30 -178.2(5) .
Ag1 N3 C30 C29 -28(16) 2_565
C28 C29 C30 N3 123(13) .
C31 C29 C30 N3 -57(13) .
C28 C29 C31 C32 -1.8(8) .
C30 C29 C31 C32 177.5(5) .
C27 C26 C32 C31 1.9(7) .
C25 C26 C32 C31 -176.9(4) .
C29 C31 C32 C26 0.3(7) .
C40 C35 C36 C37 2.6(15) .
C35 C36 C37 C38 -0.9(13) .
C36 C37 C38 C39 -1.4(12) .
C37 C38 C39 C40 2.1(15) .
C36 C35 C40 C39 -2.0(16) .
C38 C39 C40 C35 -0.3(17) .
N1 C1 O1 C17 -0.5(4) .
C2 C1 O1 C17 -179.8(4) .
N2 C17 O1 C1 0.4(4) .
C18 C17 O1 C1 177.9(4) .
N4 Ag2 O2 S1 3.2(5) 2_756
N1 Ag2 O2 S1 -149.5(4) .
O5 Ag2 O2 S1 122.1(4) .
N4 Ag2 O2 Ag1 -152.98(19) 2_756
N1 Ag2 O2 Ag1 54.31(13) .
O5 Ag2 O2 Ag1 -34.06(17) .
N3 Ag1 O2 S1 3.0(4) 2_565
N2 Ag1 O2 S1 149.6(4) .
O5 Ag1 O2 S1 -120.7(4) .
N3 Ag1 O2 Ag2 158.45(18) 2_565
N2 Ag1 O2 Ag2 -54.97(13) .
O5 Ag1 O2 Ag2 34.71(17) .
N3 Ag1 O5 S2 34.6(5) 2_565
N2 Ag1 O5 S2 -121.6(4) .
O2 Ag1 O5 S2 153.5(4) .
N3 Ag1 O5 Ag2 -153.7(2) 2_565
N2 Ag1 O5 Ag2 50.05(18) .
O2 Ag1 O5 Ag2 -34.77(16) .
N4 Ag2 O5 S2 -28.9(8) 2_756
N1 Ag2 O5 S2 117.0(7) .
O2 Ag2 O5 S2 -156.6(7) .
N4 Ag2 O5 Ag1 163.94(17) 2_756
N1 Ag2 O5 Ag1 -50.19(17) .
O2 Ag2 O5 Ag1 36.20(17) .
Ag2 O2 S1 O3 162.0(4) .
Ag1 O2 S1 O3 -51.7(6) .
Ag2 O2 S1 O4 33.6(5) .
Ag1 O2 S1 O4 180.0(4) .
Ag2 O2 S1 C34 -71.0(5) .
Ag1 O2 S1 C34 75.4(5) .
F2 C34 S1 O3 -49.5(9) .
F3 C34 S1 O3 174.8(8) .
F1 C34 S1 O3 64.3(8) .
F2 C34 S1 O2 175.9(7) .
F3 C34 S1 O2 40.3(9) .
F1 C34 S1 O2 -70.3(7) .
F2 C34 S1 O4 64.6(8) .
F3 C34 S1 O4 -71.1(9) .
F1 C34 S1 O4 178.4(7) .
Ag1 O5 S2 O6 145.4(4) .
Ag2 O5 S2 O6 -19.7(8) .
Ag1 O5 S2 O7 11.4(5) .
Ag2 O5 S2 O7 -153.7(6) .
Ag1 O5 S2 C33 -97.7(6) .
Ag2 O5 S2 C33 97.1(8) .
F4 C33 S2 O5 55.3(10) .
F5 C33 S2 O5 -174.6(10) .
F6 C33 S2 O5 -59.6(8) .
F4 C33 S2 O6 -179.1(9) .
F5 C33 S2 O6 -49.1(11) .
F6 C33 S2 O6 66.0(8) .
F4 C33 S2 O7 -61.7(10) .
F5 C33 S2 O7 68.3(11) .
F6 C33 S2 O7 -176.6(7) .
