#------------------------------------------------------------------------------
#$Date: 2019-11-25 00:34:17 +0200 (Mon, 25 Nov 2019) $
#$Revision: 239771 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/35/01/4350192.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4350192
loop_
_publ_author_name
'Dong, Yu-Bin'
'Xu, Hong-Xia'
'Ma, Jian-Ping'
'Huang, Ru-Qi'
_publ_section_title
;
 Silver(I) coordination polymers based on a nano-sized bent
 bis(3-acetylenylphenyl-(4-cyanophenyl))oxadiazole ligand: the role of
 ligand isomerism and the templating effect of polyatomic anions and
 solvent intermediates.
;
_journal_issue                   8
_journal_name_full               'Inorganic chemistry'
_journal_page_first              3325
_journal_page_last               3343
_journal_paper_doi               10.1021/ic052158w
_journal_volume                  45
_journal_year                    2006
_chemical_formula_sum            'C39 H24 Ag Cl N4 O5'
_chemical_formula_weight         771.94
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 118.073(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   19.328(4)
_cell_length_b                   23.253(5)
_cell_length_c                   19.734(4)
_cell_measurement_reflns_used    1265
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      18.241
_cell_measurement_theta_min      2.208
_cell_volume                     7826(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1033
_diffrn_reflns_av_sigmaI/netI    0.1566
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            16183
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.24
_exptl_absorpt_coefficient_mu    0.628
_exptl_absorpt_correction_T_max  0.9633
_exptl_absorpt_correction_T_min  0.9172
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            clourless
_exptl_crystal_density_diffrn    1.310
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             3120
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.09
_exptl_crystal_size_min          0.06
_refine_diff_density_max         1.508
_refine_diff_density_min         -0.606
_refine_diff_density_rms         0.118
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.055
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     453
_refine_ls_number_reflns         6839
_refine_ls_number_restraints     39
_refine_ls_restrained_S_all      1.062
_refine_ls_R_factor_all          0.1835
_refine_ls_R_factor_gt           0.0993
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0940P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2138
_refine_ls_wR_factor_ref         0.2466
_reflns_number_gt                3182
_reflns_number_total             6839
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ic052158wsi20051219_053724.cif
_cod_data_source_block           8
_cod_depositor_comments
;
The following automatic conversions were performed:

data item '_symmetry_cell_setting' value 'Monoclinic' was changed to
'monoclinic' in accordance with the
/home/saulius/struct/COD-crude-data/automatic-downloads/DataCite-retrospective/ACS/depositions/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 last updated on
2011-04-26.

Automatic conversion script
Id: cif_fix_values 6909 2019-04-08 15:41:33Z antanas 
;
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               4350192
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.55305(4) 0.12011(4) 0.35257(4) 0.0586(3) Uani 1 1 d .
N1 N 0.4184(4) 0.1183(3) 0.2949(4) 0.051(2) Uani 1 1 d .
N2 N 0.3760(5) 0.1257(3) 0.2138(5) 0.051(2) Uani 1 1 d .
N3 N -0.3687(6) -0.0592(4) -0.0396(6) 0.077(3) Uani 1 1 d .
N4 N -0.0707(6) 0.3036(4) 0.5562(5) 0.070(3) Uani 1 1 d .
C1 C 0.3051(5) 0.1308(4) 0.1977(6) 0.040(2) Uani 1 1 d .
C2 C 0.2347(5) 0.1361(4) 0.1200(6) 0.045(3) Uani 1 1 d .
C3 C 0.2419(6) 0.1619(4) 0.0615(6) 0.052(3) Uani 1 1 d .
H3 H 0.2903 0.1760 0.0698 0.063 Uiso 1 1 calc R
C4 C 0.1772(7) 0.1669(5) -0.0101(6) 0.070(3) Uani 1 1 d .
H4 H 0.1814 0.1853 -0.0498 0.084 Uiso 1 1 calc R
C5 C 0.1050(6) 0.1440(5) -0.0221(6) 0.058(3) Uani 1 1 d .
H5 H 0.0610 0.1475 -0.0699 0.070 Uiso 1 1 calc R
C6 C 0.0993(6) 0.1161(4) 0.0369(6) 0.050(3) Uani 1 1 d .
C7 C 0.1644(6) 0.1133(4) 0.1092(6) 0.049(3) Uani 1 1 d .
H7 H 0.1606 0.0961 0.1499 0.059 Uiso 1 1 calc R
C8 C 0.0269(6) 0.0931(5) 0.0246(6) 0.055(3) Uani 1 1 d .
C9 C -0.0315(7) 0.0716(5) 0.0167(6) 0.064(3) Uani 1 1 d .
C10 C -0.1051(6) 0.0444(5) 0.0051(7) 0.055(3) Uani 1 1 d .
C11 C -0.1705(6) 0.0455(4) -0.0661(6) 0.058(3) Uani 1 1 d .
H11 H -0.1679 0.0636 -0.1068 0.069 Uiso 1 1 calc R
C12 C -0.2390(6) 0.0202(5) -0.0776(7) 0.064(3) Uani 1 1 d .
H12 H -0.2828 0.0204 -0.1259 0.077 Uiso 1 1 calc R
C13 C -0.2421(6) -0.0058(4) -0.0160(7) 0.052(3) Uani 1 1 d .
C14 C -0.3130(7) -0.0358(5) -0.0294(6) 0.057(3) Uani 1 1 d .
C15 C -0.1777(7) -0.0077(6) 0.0549(7) 0.080(4) Uani 1 1 d .
H15 H -0.1801 -0.0255 0.0959 0.096 Uiso 1 1 calc R
C16 C -0.1096(7) 0.0171(5) 0.0644(7) 0.075(4) Uani 1 1 d .
H16 H -0.0653 0.0154 0.1122 0.090 Uiso 1 1 calc R
C17 C 0.3669(5) 0.1189(4) 0.3177(6) 0.042(2) Uani 1 1 d .
C18 C 0.3753(5) 0.1134(4) 0.3945(6) 0.043(2) Uani 1 1 d .
C19 C 0.4411(6) 0.0856(5) 0.4514(6) 0.060(3) Uani 1 1 d .
H19 H 0.4790 0.0701 0.4403 0.072 Uiso 1 1 calc R
C20 C 0.4486(6) 0.0816(5) 0.5239(6) 0.063(3) Uani 1 1 d .
H20 H 0.4926 0.0632 0.5617 0.075 Uiso 1 1 calc R
C21 C 0.3942(6) 0.1035(5) 0.5432(6) 0.061(3) Uani 1 1 d .
H21 H 0.4013 0.1008 0.5931 0.073 Uiso 1 1 calc R
C22 C 0.3277(6) 0.1302(4) 0.4854(6) 0.049(3) Uani 1 1 d .
C23 C 0.3198(5) 0.1345(4) 0.4119(6) 0.044(2) Uani 1 1 d .
H23 H 0.2754 0.1521 0.3735 0.053 Uiso 1 1 calc R
C24 C 0.2691(6) 0.1557(4) 0.5011(6) 0.052(3) Uani 1 1 d .
C25 C 0.2206(6) 0.1758(5) 0.5112(6) 0.058(3) Uani 1 1 d .
C26 C 0.1577(7) 0.2016(4) 0.5224(6) 0.058(3) Uani 1 1 d .
C27 C 0.0934(7) 0.2280(5) 0.4593(6) 0.066(3) Uani 1 1 d .
H27 H 0.0922 0.2293 0.4116 0.080 Uiso 1 1 calc R
C28 C 0.0331(6) 0.2515(5) 0.4682(6) 0.061(3) Uani 1 1 d .
H28 H -0.0099 0.2672 0.4261 0.073 Uiso 1 1 calc R
C29 C 0.0361(6) 0.2520(4) 0.5392(6) 0.049(3) Uani 1 1 d .
C30 C -0.0239(6) 0.2810(4) 0.5492(7) 0.056(3) Uani 1 1 d .
C31 C 0.0969(7) 0.2266(5) 0.6016(7) 0.067(3) Uani 1 1 d .
H31 H 0.0973 0.2261 0.6490 0.081 Uiso 1 1 calc R
C32 C 0.1585(7) 0.2014(4) 0.5931(6) 0.061(3) Uani 1 1 d .
H32 H 0.2002 0.1844 0.6352 0.074 Uiso 1 1 calc R
C33 C 0.1677(15) 0.9365(10) 0.2574(13) 0.190(9) Uani 1 1 d DU
C34 C 0.2364(13) 0.9718(10) 0.2784(12) 0.202(9) Uani 1 1 d DU
H34 H 0.2300 1.0110 0.2678 0.243 Uiso 1 1 calc R
C35 C 0.3147(15) 0.9482(11) 0.3155(18) 0.249(13) Uani 1 1 d DU
H35 H 0.3584 0.9710 0.3270 0.299 Uiso 1 1 calc R
C36 C 0.3223(15) 0.8880(10) 0.334(2) 0.295(18) Uani 1 1 d DU
H36 H 0.3723 0.8722 0.3550 0.354 Uiso 1 1 calc R
C37 C 0.2590(12) 0.8503(11) 0.3217(12) 0.211(9) Uani 1 1 d DU
H37 H 0.2657 0.8119 0.3368 0.253 Uiso 1 1 calc R
C38 C 0.1828(13) 0.8787(10) 0.2834(12) 0.183(8) Uani 1 1 d DU
H38 H 0.1395 0.8565 0.2752 0.220 Uiso 1 1 calc R
C39 C 0.0938(13) 0.9603(11) 0.2224(13) 0.207(9) Uani 1 1 d U
H39A H 0.0759 0.9634 0.1681 0.311 Uiso 1 1 calc R
H39B H 0.0954 0.9979 0.2432 0.311 Uiso 1 1 calc R
H39C H 0.0585 0.9363 0.2313 0.311 Uiso 1 1 calc R
O1 O 0.2928(4) 0.1264(3) 0.2592(4) 0.0489(17) Uani 1 1 d .
O2 O 0.4515(11) 0.0696(6) 0.7410(13) 0.297(12) Uani 1 1 d D
O3 O 0.4756(14) -0.0029(6) 0.6855(7) 0.312(14) Uani 1 1 d D
O4 O 0.4845(7) 0.3084(5) 0.1882(5) 0.142(4) Uani 1 1 d .
O5 O 0.5615(12) 0.2430(7) 0.2586(11) 0.278(11) Uani 1 1 d .
Cl1 Cl 0.5000 0.0258(2) 0.7500 0.102(2) Uani 1 2 d SD
Cl2 Cl 0.5000 0.2758(2) 0.2500 0.0877(16) Uani 1 2 d S
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ag1 N2 123.9(3) . 2_655
N1 Ag1 N3 121.4(3) . 6_656
N2 Ag1 N3 104.0(3) 2_655 6_656
N1 Ag1 N4 96.4(3) . 7_556
N2 Ag1 N4 117.8(3) 2_655 7_556
N3 Ag1 N4 88.0(3) 6_656 7_556
C17 N1 N2 105.3(7) . .
C17 N1 Ag1 135.8(7) . .
N2 N1 Ag1 118.3(5) . .
C1 N2 N1 106.1(8) . .
C1 N2 Ag1 137.0(7) . 2_655
N1 N2 Ag1 116.7(5) . 2_655
C14 N3 Ag1 125.9(9) . 6_455
C30 N4 Ag1 126.8(9) . 7_556
N2 C1 O1 113.5(9) . .
N2 C1 C2 128.4(9) . .
O1 C1 C2 117.9(8) . .
C3 C2 C7 121.6(10) . .
C3 C2 C1 119.7(8) . .
C7 C2 C1 118.7(8) . .
C2 C3 C4 119.9(9) . .
C3 C4 C5 119.3(10) . .
C6 C5 C4 120.2(10) . .
C5 C6 C7 119.6(9) . .
C5 C6 C8 120.0(10) . .
C7 C6 C8 120.4(9) . .
C2 C7 C6 119.4(9) . .
C9 C8 C6 176.7(12) . .
C8 C9 C10 178.7(13) . .
C16 C10 C11 118.8(10) . .
C16 C10 C9 120.8(10) . .
C11 C10 C9 120.4(11) . .
C12 C11 C10 120.9(10) . .
C11 C12 C13 118.7(10) . .
C15 C13 C12 121.1(10) . .
C15 C13 C14 120.1(10) . .
C12 C13 C14 118.6(10) . .
N3 C14 C13 179.6(14) . .
C16 C15 C13 118.9(11) . .
C15 C16 C10 121.5(11) . .
N1 C17 O1 112.8(8) . .
N1 C17 C18 130.3(9) . .
O1 C17 C18 116.9(7) . .
C23 C18 C19 119.5(9) . .
C23 C18 C17 121.1(9) . .
C19 C18 C17 119.4(8) . .
C20 C19 C18 118.6(9) . .
C19 C20 C21 123.0(10) . .
C20 C21 C22 117.8(9) . .
C23 C22 C21 119.5(9) . .
C23 C22 C24 119.0(9) . .
C21 C22 C24 121.4(9) . .
C18 C23 C22 121.6(9) . .
C25 C24 C22 177.7(12) . .
C24 C25 C26 178.8(12) . .
C32 C26 C27 118.3(10) . .
C32 C26 C25 122.2(11) . .
C27 C26 C25 119.5(9) . .
C28 C27 C26 120.4(10) . .
C27 C28 C29 120.2(10) . .
C31 C29 C28 121.2(10) . .
C31 C29 C30 119.0(10) . .
C28 C29 C30 119.7(11) . .
N4 C30 C29 179.3(13) . .
C29 C31 C32 119.1(10) . .
C26 C32 C31 120.6(11) . .
C39 C33 C38 123(2) . .
C39 C33 C34 121(2) . .
C38 C33 C34 115(2) . .
C35 C34 C33 122(2) . .
C36 C35 C34 117(3) . .
C37 C36 C35 125(3) . .
C36 C37 C38 113(2) . .
C33 C38 C37 127(2) . .
C1 O1 C17 102.3(7) . .
Cl1 O2 O2 49.6(9) . 2_656
O3 Cl1 O3 118.9(14) 2_656 .
O3 Cl1 O2 110.4(11) 2_656 2_656
O3 Cl1 O2 115.1(13) . 2_656
O3 Cl1 O2 115.1(13) 2_656 .
O3 Cl1 O2 110.4(11) . .
O2 Cl1 O2 80.9(18) 2_656 .
O4 Cl2 O4 111.3(10) . 2_655
O4 Cl2 O5 103.8(8) . .
O4 Cl2 O5 113.3(11) 2_655 .
O4 Cl2 O5 113.3(11) . 2_655
O4 Cl2 O5 103.8(8) 2_655 2_655
O5 Cl2 O5 111.6(19) . 2_655
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.298(7) .
Ag1 N2 2.303(8) 2_655
Ag1 N3 2.408(10) 6_656
Ag1 N4 2.434(10) 7_556
N1 C17 1.273(10) .
N1 N2 1.424(10) .
N2 C1 1.258(11) .
N2 Ag1 2.303(8) 2_655
N3 C14 1.135(12) .
N3 Ag1 2.408(10) 6_455
N4 C30 1.110(12) .
N4 Ag1 2.434(10) 7_556
C1 O1 1.346(10) .
C1 C2 1.501(13) .
C2 C3 1.366(13) .
C2 C7 1.378(12) .
C3 C4 1.382(13) .
C4 C5 1.405(14) .
C5 C6 1.383(14) .
C6 C7 1.391(13) .
C6 C8 1.407(14) .
C8 C9 1.176(14) .
C9 C10 1.473(15) .
C10 C16 1.370(15) .
C10 C11 1.378(13) .
C11 C12 1.368(13) .
C12 C13 1.384(14) .
C13 C15 1.367(14) .
C13 C14 1.446(14) .
C15 C16 1.366(15) .
C17 O1 1.363(10) .
C17 C18 1.452(13) .
C18 C23 1.361(12) .
C18 C19 1.398(13) .
C19 C20 1.372(13) .
C20 C21 1.376(14) .
C21 C22 1.399(14) .
C22 C23 1.388(13) .
C22 C24 1.437(13) .
C24 C25 1.145(12) .
C25 C26 1.462(14) .
C26 C32 1.389(13) .
C26 C27 1.419(14) .
C27 C28 1.372(14) .
C28 C29 1.375(13) .
C29 C31 1.373(14) .
C29 C30 1.433(14) .
C31 C32 1.407(14) .
C33 C39 1.38(3) .
C33 C38 1.421(14) .
C33 C34 1.446(14) .
C34 C35 1.444(15) .
C35 C36 1.436(15) .
C36 C37 1.431(15) .
C37 C38 1.458(15) .
O2 Cl1 1.338(9) .
O2 O2 1.74(3) 2_656
O3 Cl1 1.312(8) .
O4 Cl2 1.345(9) .
O5 Cl2 1.353(13) .
Cl1 O3 1.312(8) 2_656
Cl1 O2 1.338(9) 2_656
Cl2 O4 1.345(9) 2_655
Cl2 O5 1.353(13) 2_655
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N2 Ag1 N1 C17 -174.7(9) 2_655 .
N3 Ag1 N1 C17 46.6(11) 6_656 .
N4 Ag1 N1 C17 -44.9(10) 7_556 .
N2 Ag1 N1 N2 -5.3(6) 2_655 .
N3 Ag1 N1 N2 -144.0(6) 6_656 .
N4 Ag1 N1 N2 124.5(6) 7_556 .
C17 N1 N2 C1 1.1(10) . .
Ag1 N1 N2 C1 -171.3(6) . .
C17 N1 N2 Ag1 -175.4(6) . 2_655
Ag1 N1 N2 Ag1 12.2(8) . 2_655
N1 N2 C1 O1 -1.6(10) . .
Ag1 N2 C1 O1 173.8(6) 2_655 .
N1 N2 C1 C2 -176.0(8) . .
Ag1 N2 C1 C2 -0.5(15) 2_655 .
N2 C1 C2 C3 -30.7(14) . .
O1 C1 C2 C3 155.1(9) . .
N2 C1 C2 C7 147.7(10) . .
O1 C1 C2 C7 -26.5(12) . .
C7 C2 C3 C4 1.8(15) . .
C1 C2 C3 C4 -179.8(9) . .
C2 C3 C4 C5 -1.7(16) . .
C3 C4 C5 C6 -0.7(17) . .
C4 C5 C6 C7 2.9(16) . .
C4 C5 C6 C8 -179.8(10) . .
C3 C2 C7 C6 0.4(15) . .
C1 C2 C7 C6 -177.9(8) . .
C5 C6 C7 C2 -2.8(15) . .
C8 C6 C7 C2 180.0(9) . .
C5 C6 C8 C9 146(22) . .
C7 C6 C8 C9 -37(23) . .
C6 C8 C9 C10 -111(56) . .
C8 C9 C10 C16 146(56) . .
C8 C9 C10 C11 -33(56) . .
C16 C10 C11 C12 0.5(16) . .
C9 C10 C11 C12 179.8(10) . .
C10 C11 C12 C13 1.1(16) . .
C11 C12 C13 C15 -1.6(17) . .
C11 C12 C13 C14 -176.0(10) . .
Ag1 N3 C14 C13 -175(100) 6_455 .
C15 C13 C14 N3 42(100) . .
C12 C13 C14 N3 -144(100) . .
C12 C13 C15 C16 0.5(18) . .
C14 C13 C15 C16 174.9(11) . .
C13 C15 C16 C10 1.1(19) . .
C11 C10 C16 C15 -1.6(18) . .
C9 C10 C16 C15 179.1(11) . .
N2 N1 C17 O1 -0.2(10) . .
Ag1 N1 C17 O1 170.2(6) . .
N2 N1 C17 C18 -179.8(9) . .
Ag1 N1 C17 C18 -9.4(17) . .
N1 C17 C18 C23 156.9(10) . .
O1 C17 C18 C23 -22.7(13) . .
N1 C17 C18 C19 -23.8(16) . .
O1 C17 C18 C19 156.6(9) . .
C23 C18 C19 C20 -1.7(16) . .
C17 C18 C19 C20 179.0(10) . .
C18 C19 C20 C21 0.3(18) . .
C19 C20 C21 C22 1.1(17) . .
C20 C21 C22 C23 -1.2(15) . .
C20 C21 C22 C24 -178.2(10) . .
C19 C18 C23 C22 1.6(14) . .
C17 C18 C23 C22 -179.1(9) . .
C21 C22 C23 C18 -0.1(15) . .
C24 C22 C23 C18 176.9(9) . .
C23 C22 C24 C25 29(29) . .
C21 C22 C24 C25 -154(29) . .
C22 C24 C25 C26 -16(82) . .
C24 C25 C26 C32 169(100) . .
C24 C25 C26 C27 -11(58) . .
C32 C26 C27 C28 -1.3(17) . .
C25 C26 C27 C28 178.9(10) . .
C26 C27 C28 C29 2.9(17) . .
C27 C28 C29 C31 -3.3(17) . .
C27 C28 C29 C30 174.8(10) . .
Ag1 N4 C30 C29 -116(100) 7_556 .
C31 C29 C30 N4 170(100) . .
C28 C29 C30 N4 -8(100) . .
C28 C29 C31 C32 2.2(16) . .
C30 C29 C31 C32 -175.9(9) . .
C27 C26 C32 C31 0.2(16) . .
C25 C26 C32 C31 180.0(10) . .
C29 C31 C32 C26 -0.6(17) . .
C39 C33 C34 C35 180(3) . .
C38 C33 C34 C35 7(4) . .
C33 C34 C35 C36 -2(5) . .
C34 C35 C36 C37 -3(6) . .
C35 C36 C37 C38 4(5) . .
C39 C33 C38 C37 -179(2) . .
C34 C33 C38 C37 -7(4) . .
C36 C37 C38 C33 1(4) . .
N2 C1 O1 C17 1.4(10) . .
C2 C1 O1 C17 176.4(7) . .
N1 C17 O1 C1 -0.7(10) . .
C18 C17 O1 C1 179.0(8) . .
O2 O2 Cl1 O3 108.4(13) 2_656 2_656
O2 O2 Cl1 O3 -113.5(14) 2_656 .
