#------------------------------------------------------------------------------
#$Date: 2019-11-28 19:44:29 +0200 (Thu, 28 Nov 2019) $
#$Revision: 244427 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/35/07/4350765.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4350765
loop_
_publ_author_name
'Shu, Yu-Bo'
'Tang, Xiao-Liang'
'Liu, Wei-Sheng'
_publ_section_title
;
 Sm and Eu(iii) lanthanide triple helicate cages based on
 N,N′-methylene-bis(pyridin-4-one)
;
_journal_issue                   3
_journal_name_full               'Inorg. Chem. Front.'
_journal_page_first              226
_journal_paper_doi               10.1039/C3QI00089C
_journal_volume                  1
_journal_year                    2014
_chemical_absolute_configuration ad
_chemical_formula_moiety         'C33 H31.98 Eu2 N12 O25'
_chemical_formula_sum            'C33 H31.98 Eu2 N12 O25'
_chemical_formula_weight         1300.63
_space_group_crystal_system      trigonal
_space_group_IT_number           146
_space_group_name_Hall           'R 3'
_space_group_name_H-M_alt        'R 3 :H'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     heavy
_atom_sites_solution_secondary   difmap
_audit_creation_date             2013-10-12
_audit_creation_method
;
Olex2 1.2
(compiled 2013.09.17 svn.r2790 for OlexSys, GUI svn.r4601)
;
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            3
_cell_length_a                   14.359(2)
_cell_length_b                   14.359(2)
_cell_length_c                   19.115(4)
_cell_measurement_reflns_used    805
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      16.00
_cell_measurement_theta_min      2.69
_cell_volume                     3413.1(10)
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'SAINT v7.60A (Bruker, 2009)'
_computing_molecular_graphics
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_publication_material
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_structure_refinement
;
SHELX, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
;
_computing_structure_solution
;
SHELX, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
;
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0670
_diffrn_reflns_av_unetI/netI     0.0895
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            5775
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.95
_diffrn_source                   'fine-focus sealed tube'
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.834
_exptl_absorpt_correction_T_max  0.797
_exptl_absorpt_correction_T_min  0.672
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2008/1 (Bruker,2008) was used for absorption correction.
wR2(int) was 0.0576 before and 0.0476 after correction.
The Ratio of minimum to maximum transmission is 0.8486.
The λ/2 correction factor is 0.0015.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.898
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       polyhedral
_exptl_crystal_F_000             1919.9
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.08
_refine_diff_density_max         1.091
_refine_diff_density_min         -1.098
_refine_diff_density_rms         0.190
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.10(5)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.096
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     218
_refine_ls_number_reflns         2690
_refine_ls_number_restraints     78
_refine_ls_restrained_S_all      1.116
_refine_ls_R_factor_all          0.0822
_refine_ls_R_factor_gt           0.0661
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0185P)²+162.9368P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1345
_refine_ls_wR_factor_ref         0.1430
_reflns_number_gt                2014
_reflns_number_total             2690
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3qi00089c.txt
_cod_data_source_block           syb121208a_0m
_cod_original_cell_volume        3413.1(14)
_cod_original_sg_symbol_H-M      'R 3'
_cod_database_code               4350765
_olex2_refinement_description
;
1. Others
 Fixed Sof: H3A(0.33) H3(0.33)
 Fixed U13: Eu2(0) Eu1(0) O3(0)
 Fixed U23: Eu2(0) Eu1(0) O3(0)
 Fixed Uiso: H1(0.07) H2(0.099) H4(0.136) H5(0.098) H6A(0.061) H6B(0.061)
 H7(0.083) H8(0.115) H10(0.112) H11(0.07) H3A(0.116) H3(0.116)
 Fixed X: H1(0.503) H2(0.5225) H4(0.2302) H5(0.2159) H6A(0.2679) H6B(0.393)
 H7(0.4718) H8(0.4626) H10(0.1904) H11(0.1786) Eu2(0.3333) Eu1(0.3333)
 O3(0.3333) H3A(0.3874) H3(0.3407)
 Fixed Y: H1(0.9676) H2(0.895) H4(0.8213) H5(0.9029) H6A(0.9854) H6B(1.0578)
 H7(1.0307) H8(0.9423) H10(0.6973) H11(0.803) Eu2(0.6667) Eu1(0.6667)
 O3(0.6667) H3A(0.6593) H3(0.7281)
 Fixed Z: H1(0.4615) H2(0.3588) H4(0.2946) H5(0.3925) H6A(0.4919) H6B(0.5005)
 H7(0.5996) H8(0.7016) H10(0.6349) H11(0.5464) H3A(0.0304) H3(0.0304)
;
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 'x, y, z'
2 '-y, x-y, z'
3 '-x+y, -x, z'
4 'x+2/3, y+1/3, z+1/3'
5 '-y+2/3, x-y+1/3, z+1/3'
6 '-x+y+2/3, -x+1/3, z+1/3'
7 'x+1/3, y+2/3, z+2/3'
8 '-y+1/3, x-y+2/3, z+2/3'
9 '-x+y+1/3, -x+2/3, z+2/3'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.448(2) 0.9366(19) 0.4288(11) 0.059(7) Uani 1 1 d DU
H1 H 0.5030 0.9676 0.4615 0.070 Uiso 1 1 calc R
C2 C 0.457(2) 0.891(2) 0.3679(12) 0.083(10) Uani 1 1 d DU
H2 H 0.5225 0.8950 0.3588 0.099 Uiso 1 1 calc R
C3 C 0.376(2) 0.8414(17) 0.3196(10) 0.102(12) Uani 1 1 d DU
C4 C 0.284(2) 0.848(2) 0.3281(14) 0.113(12) Uani 1 1 d DU
H4 H 0.2302 0.8213 0.2946 0.136 Uiso 1 1 calc R
C5 C 0.276(2) 0.8956(15) 0.3871(11) 0.081(9) Uani 1 1 d DU
H5 H 0.2159 0.9029 0.3925 0.098 Uiso 1 1 calc R
C6 C 0.3344(19) 0.9841(14) 0.4975(10) 0.051(6) Uani 1 1 d .
H6A H 0.2679 0.9854 0.4919 0.061 Uiso 1 1 calc R
H6B H 0.3930 1.0578 0.5005 0.061 Uiso 1 1 calc R
C7 C 0.411(2) 0.965(2) 0.6096(11) 0.069(8) Uani 1 1 d .
H7 H 0.4718 1.0307 0.5996 0.083 Uiso 1 1 calc R
C8 C 0.407(2) 0.914(2) 0.6693(16) 0.096(9) Uani 1 1 d DU
H8 H 0.4626 0.9423 0.7016 0.115 Uiso 1 1 calc R
C9 C 0.318(2) 0.820(2) 0.6796(13) 0.093(8) Uani 1 1 d DU
C10 C 0.241(2) 0.770(2) 0.6307(15) 0.093(11) Uani 1 1 d DU
H10 H 0.1904 0.6973 0.6349 0.112 Uiso 1 1 calc R
C11 C 0.238(2) 0.8275(16) 0.5753(12) 0.058(6) Uani 1 1 d DU
H11 H 0.1786 0.8030 0.5464 0.070 Uiso 1 1 calc R
Eu2 Eu 0.3333 0.6667 0.17874(6) 0.0291(7) Uani 1 3 d S
Eu1 Eu 0.3333 0.6667 0.82123(6) 0.0248(6) Uani 1 3 d S
N1 N 0.3503(17) 0.9329(13) 0.4385(8) 0.058(5) Uani 1 1 d .
N2 N 0.3296(17) 0.9237(14) 0.5649(9) 0.066(6) Uani 1 1 d D
N3 N 0.5296(17) 0.8511(17) 0.1260(17) 0.111(11) Uani 1 1 d DU
N4 N 0.1445(17) 0.6346(16) 0.9038(14) 0.107(10) Uani 1 1 d DU
O1 O 0.3871(18) 0.7952(16) 0.2623(10) 0.096(8) Uani 1 1 d D
O2 O 0.315(2) 0.777(2) 0.7424(12) 0.107(8) Uani 1 1 d U
O3 O 0.3333 0.6667 0.0476(15) 0.077(8) Uani 1 3 d S
H3A H 0.3874 0.6593 0.0304 0.116 Uiso 0.33 1 d PR
H3B H 0.3407 0.7281 0.0304 0.116 Uiso 0.33 1 d PR
O4 O 0.4460(19) 0.8527(15) 0.1279(11) 0.091(8) Uani 1 1 d D
O5 O 0.5320(9) 0.7691(10) 0.1487(8) 0.053(4) Uani 1 1 d D
O6 O 0.6121(19) 0.9385(18) 0.1130(16) 0.149(9) Uani 1 1 d DU
O7 O 0.184(2) 0.709(3) 0.8586(10) 0.130(12) Uani 1 1 d D
O8 O 0.1899(13) 0.5810(19) 0.9155(9) 0.085(6) Uani 1 1 d DU
O9 O 0.067(2) 0.629(2) 0.9365(16) 0.174(11) Uani 1 1 d DU
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C2 C1 H1 122.2 . .
C2 C1 N1 116(2) . .
N1 C1 H1 122.2 . .
C1 C2 H2 118.0 . .
C3 C2 C1 124(3) . .
C3 C2 H2 118.0 . .
C2 C3 C4 118(2) . .
O1 C3 C2 122(2) . .
O1 C3 C4 119.2(17) . .
C3 C4 H4 121.3 . .
C5 C4 C3 117(3) . .
C5 C4 H4 121.3 . .
C4 C5 H5 118.0 . .
N1 C5 C4 124(3) . .
N1 C5 H5 118.0 . .
H6A C6 H6B 108.1 . .
N1 C6 H6A 109.6 . .
N1 C6 H6B 109.6 . .
N1 C6 N2 110.2(14) . .
N2 C6 H6A 109.6 . .
N2 C6 H6B 109.6 . .
C8 C7 H7 119.5 . .
N2 C7 H7 119.5 . .
N2 C7 C8 121(3) . .
C7 C8 H8 121.9 . .
C9 C8 C7 116(2) . .
C9 C8 H8 121.9 . .
C8 C9 C10 123.4(19) . .
C8 C9 O2 113(3) . .
O2 C9 C10 123(3) . .
C9 C10 H10 120.5 . .
C9 C10 C11 119(2) . .
C11 C10 H10 120.5 . .
C10 C11 H11 122.3 . .
C10 C11 N2 115(2) . .
N2 C11 H11 122.3 . .
N3 Eu2 N3 108.7(7) 2_665 .
O1 Eu2 N3 149.6(9) 3_565 2_665
O1 Eu2 N3 73.9(9) . .
O1 Eu2 N3 149.6(9) 2_665 .
O1 Eu2 N3 98.4(7) 3_565 .
O1 Eu2 N3 98.4(7) . 2_665
O1 Eu2 N3 73.9(9) 2_665 2_665
O1 Eu2 O1 75.7(9) . 2_665
O1 Eu2 O1 75.7(9) . 3_565
O1 Eu2 O1 75.7(9) 2_665 3_565
O1 Eu2 O3 134.9(5) 3_565 .
O1 Eu2 O3 134.9(6) 2_665 .
O1 Eu2 O3 134.9(6) . .
O1 Eu2 O4 68.4(7) 3_565 3_565
O1 Eu2 O4 135.4(7) 3_565 2_665
O1 Eu2 O4 118.0(9) . 2_665
O1 Eu2 O4 68.4(7) 2_665 2_665
O1 Eu2 O4 135.4(7) . 3_565
O1 Eu2 O4 135.4(7) 2_665 .
O1 Eu2 O4 118.0(9) 3_565 .
O1 Eu2 O4 68.4(7) . .
O1 Eu2 O4 118.0(9) 2_665 3_565
O1 Eu2 O5 82.0(6) . .
O1 Eu2 O5 148.0(6) 2_665 .
O1 Eu2 O5 82.0(6) 3_565 3_565
O1 Eu2 O5 76.7(7) 3_565 .
O1 Eu2 O5 76.7(7) 2_665 3_565
O1 Eu2 O5 148.0(6) 3_565 2_665
O1 Eu2 O5 148.0(6) . 3_565
O1 Eu2 O5 76.7(7) . 2_665
O1 Eu2 O5 82.0(6) 2_665 2_665
O3 Eu2 N3 69.8(6) . 2_665
O3 Eu2 N3 69.8(6) . .
O3 Eu2 O4 67.4(5) . 3_565
O3 Eu2 O4 67.4(5) . 2_665
O3 Eu2 O4 67.4(5) . .
O3 Eu2 O5 76.9(4) . .
O3 Eu2 O5 76.9(4) . 3_565
O3 Eu2 O5 76.9(4) . 2_665
O4 Eu2 N3 24.4(4) . .
O4 Eu2 N3 85.7(5) 3_565 .
O4 Eu2 N3 125.9(5) 3_565 2_665
O4 Eu2 N3 85.7(5) . 2_665
O4 Eu2 N3 125.9(5) 2_665 .
O4 Eu2 N3 24.4(4) 2_665 2_665
O4 Eu2 O4 106.1(6) . 3_565
O4 Eu2 O4 106.1(6) 2_665 3_565
O4 Eu2 O4 106.1(6) 2_665 .
O4 Eu2 O5 50.2(6) 3_565 3_565
O4 Eu2 O5 143.4(6) 3_565 2_665
O4 Eu2 O5 143.4(6) 2_665 .
O4 Eu2 O5 50.2(6) . .
O4 Eu2 O5 64.9(6) . 2_665
O4 Eu2 O5 64.9(6) 2_665 3_565
O4 Eu2 O5 143.4(6) . 3_565
O4 Eu2 O5 64.9(6) 3_565 .
O4 Eu2 O5 50.2(6) 2_665 2_665
O5 Eu2 N3 132.7(7) 3_565 .
O5 Eu2 N3 25.8(4) . .
O5 Eu2 N3 89.3(4) 2_665 .
O5 Eu2 N3 132.7(7) . 2_665
O5 Eu2 N3 25.8(4) 2_665 2_665
O5 Eu2 N3 89.3(4) 3_565 2_665
O5 Eu2 O5 115.0(3) . 3_565
O5 Eu2 O5 115.0(3) 2_665 .
O5 Eu2 O5 115.0(3) 2_665 3_565
N4 Eu1 N4 94.3(8) 3_565 2_665
N4 Eu1 N4 94.3(8) . 3_565
N4 Eu1 N4 94.3(8) . 2_665
O2 Eu1 N4 170.9(9) 2_665 3_565
O2 Eu1 N4 90.9(9) . 3_565
O2 Eu1 N4 170.9(9) . 2_665
O2 Eu1 N4 92.7(8) 3_565 3_565
O2 Eu1 N4 92.7(8) 2_665 2_665
O2 Eu1 N4 92.7(8) . .
O2 Eu1 N4 90.9(9) 3_565 2_665
O2 Eu1 N4 170.9(9) 3_565 .
O2 Eu1 N4 90.9(9) 2_665 .
O2 Eu1 O2 81.4(10) . 2_665
O2 Eu1 O2 81.4(10) . 3_565
O2 Eu1 O2 81.4(10) 2_665 3_565
O2 Eu1 O7 149.7(8) 2_665 3_565
O2 Eu1 O7 68.2(8) 3_565 3_565
O2 Eu1 O7 92.9(10) 3_565 2_665
O2 Eu1 O7 92.9(10) . 3_565
O2 Eu1 O7 68.2(7) 2_665 2_665
O2 Eu1 O7 149.7(8) 3_565 .
O2 Eu1 O7 149.7(8) . 2_665
O2 Eu1 O7 68.2(7) . .
O2 Eu1 O7 92.9(10) 2_665 .
O2 Eu1 O8 158.7(9) 2_665 3_565
O2 Eu1 O8 117.1(8) 3_565 3_565
O2 Eu1 O8 117.1(7) . .
O2 Eu1 O8 158.7(9) . 2_665
O2 Eu1 O8 90.6(8) 2_665 .
O2 Eu1 O8 90.6(8) . 3_565
O2 Eu1 O8 158.7(9) 3_565 .
O2 Eu1 O8 117.1(7) 2_665 2_665
O2 Eu1 O8 90.6(8) 3_565 2_665
O7 Eu1 N4 119.2(7) 3_565 .
O7 Eu1 N4 25.1(4) . .
O7 Eu1 N4 25.1(4) 2_665 2_665
O7 Eu1 N4 88.7(7) 2_665 .
O7 Eu1 N4 88.7(7) 3_565 2_665
O7 Eu1 N4 88.7(7) . 3_565
O7 Eu1 N4 119.2(7) . 2_665
O7 Eu1 N4 119.2(7) 2_665 3_565
O7 Eu1 N4 25.1(4) 3_565 3_565
O7 Eu1 O7 112.7(4) . 2_665
O7 Eu1 O7 112.7(4) 3_565 2_665
O7 Eu1 O7 112.7(4) . 3_565
O8 Eu1 N4 24.8(4) 2_665 2_665
O8 Eu1 N4 69.6(7) 2_665 3_565
O8 Eu1 N4 69.6(7) . 2_665
O8 Eu1 N4 97.2(6) 3_565 2_665
O8 Eu1 N4 97.2(6) . 3_565
O8 Eu1 N4 24.8(4) . .
O8 Eu1 N4 69.6(7) 3_565 .
O8 Eu1 N4 24.8(4) 3_565 3_565
O8 Eu1 N4 97.2(6) 2_665 .
O8 Eu1 O7 49.9(6) . .
O8 Eu1 O7 118.0(6) 2_665 .
O8 Eu1 O7 118.0(6) 3_565 2_665
O8 Eu1 O7 65.8(8) 3_565 .
O8 Eu1 O7 65.8(8) . 2_665
O8 Eu1 O7 49.9(6) 3_565 3_565
O8 Eu1 O7 49.9(6) 2_665 2_665
O8 Eu1 O7 65.8(8) 2_665 3_565
O8 Eu1 O7 118.0(6) . 3_565
O8 Eu1 O8 75.3(6) 3_565 .
O8 Eu1 O8 75.3(6) 3_565 2_665
O8 Eu1 O8 75.3(6) . 2_665
C1 N1 C6 120.4(19) . .
C5 N1 C1 120(2) . .
C5 N1 C6 119(2) . .
C7 N2 C6 121(2) . .
C7 N2 C11 123(2) . .
C11 N2 C6 116.4(18) . .
O4 N3 Eu2 59.4(13) . .
O4 N3 O5 120(2) . .
O4 N3 O6 116(2) . .
O5 N3 Eu2 60.2(10) . .
O6 N3 Eu2 170(3) . .
O6 N3 O5 123(2) . .
O7 N4 Eu1 60.8(12) . .
O8 N4 Eu1 58.3(11) . .
O8 N4 O7 119(2) . .
O9 N4 Eu1 175(2) . .
O9 N4 O7 114(3) . .
O9 N4 O8 126(3) . .
C3 O1 Eu2 155.6(16) . .
C9 O2 Eu1 157(2) . .
Eu2 O3 H3A 111.6 . .
Eu2 O3 H3B 111.6 . .
H3A O3 H3B 107.3 . .
N3 O4 Eu2 96.2(15) . .
N3 O5 Eu2 94.1(12) . .
N4 O7 Eu1 94.0(13) . .
N4 O8 Eu1 96.9(13) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 H1 0.9300 .
C1 C2 1.372(18) .
C1 N1 1.38(3) .
C2 H2 0.9300 .
C2 C3 1.373(19) .
C3 C4 1.381(18) .
C3 O1 1.329(16) .
C4 H4 0.9300 .
C4 C5 1.352(17) .
C5 H5 0.9300 .
C5 N1 1.35(3) .
C6 H6A 0.9700 .
C6 H6B 0.9700 .
C6 N1 1.42(2) .
C6 N2 1.54(2) .
C7 H7 0.9300 .
C7 C8 1.35(3) .
C7 N2 1.32(3) .
C8 H8 0.9300 .
C8 C9 1.327(18) .
C9 C10 1.349(18) .
C9 O2 1.34(3) .
C10 H10 0.9300 .
C10 C11 1.355(19) .
C11 H11 0.9300 .
C11 N2 1.361(17) .
Eu2 N3 2.92(2) 2_665
Eu2 N3 2.92(2) .
Eu2 O1 2.265(17) 3_565
Eu2 O1 2.265(17) .
Eu2 O1 2.265(17) 2_665
Eu2 O3 2.51(3) .
Eu2 O4 2.525(19) 2_665
Eu2 O4 2.525(19) 3_565
Eu2 O4 2.525(19) .
Eu2 O5 2.537(12) 3_565
Eu2 O5 2.537(12) 2_665
Eu2 O5 2.537(12) .
Eu1 N4 2.967(19) 2_665
Eu1 N4 2.967(19) 3_565
Eu1 N4 2.967(19) .
Eu1 O2 2.291(18) .
Eu1 O2 2.291(18) 2_665
Eu1 O2 2.291(18) 3_565
Eu1 O7 2.598(19) 2_665
Eu1 O7 2.60(2) 3_565
Eu1 O7 2.598(19) .
Eu1 O8 2.544(15) 3_565
Eu1 O8 2.544(15) .
Eu1 O8 2.544(15) 2_665
N3 O4 1.213(17) .
N3 O5 1.271(16) .
N3 O6 1.247(17) .
N4 O7 1.264(18) .
N4 O8 1.252(17) .
N4 O9 1.240(17) .
O3 H3A 0.8971 .
O3 H3B 0.8970 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
C1 C2 C3 C4 8(5) .
C1 C2 C3 O1 -178(3) .
C2 C1 N1 C5 -6(3) .
C2 C1 N1 C6 -175(2) .
C2 C3 C4 C5 -6(4) .
C2 C3 O1 Eu2 140(4) .
C3 C4 C5 N1 -2(4) .
C4 C3 O1 Eu2 -46(6) .
C4 C5 N1 C1 8(3) .
C4 C5 N1 C6 178(2) .
C7 C8 C9 C10 8(4) .
C7 C8 C9 O2 -175(2) .
C8 C7 N2 C6 179(2) .
C8 C7 N2 C11 -1(3) .
C8 C9 C10 C11 -17(5) .
C8 C9 O2 Eu1 -99(6) .
C9 C10 C11 N2 16(4) .
C10 C9 O2 Eu1 79(6) .
C10 C11 N2 C6 173(2) .
C10 C11 N2 C7 -7(3) .
N1 C1 C2 C3 -3(4) .
N1 C6 N2 C7 107(2) .
N1 C6 N2 C11 -73(2) .
N2 C6 N1 C1 -70(2) .
N2 C6 N1 C5 121(2) .
N2 C7 C8 C9 1(4) .
N3 Eu2 N3 O4 20(3) 2_665
N3 Eu2 N3 O5 -161.1(12) 2_665
N3 Eu2 N3 O6 86(10) 2_665
N3 Eu2 O1 C3 166(4) .
N3 Eu2 O1 C3 59(4) 2_665
N3 Eu2 O4 N3 -161(3) 2_665
N3 Eu2 O5 N3 24.7(16) 2_665
N4 Eu1 N4 O7 172.4(19) 2_665
N4 Eu1 N4 O7 78(3) 3_565
N4 Eu1 N4 O8 -97.9(13) 3_565
N4 Eu1 N4 O8 -3(2) 2_665
N4 Eu1 N4 O9 64(30) 3_565
N4 Eu1 N4 O9 159(29) 2_665
N4 Eu1 O2 C9 -144(6) .
N4 Eu1 O2 C9 121(6) 3_565
N4 Eu1 O2 C9 -4(10) 2_665
N4 Eu1 O7 N4 -9(2) 2_665
N4 Eu1 O7 N4 -103(3) 3_565
N4 Eu1 O8 N4 177(2) 2_665
N4 Eu1 O8 N4 84.6(14) 3_565
O1 C3 C4 C5 180(2) .
O1 Eu2 N3 O4 -73(2) .
O1 Eu2 N3 O4 -69(2) 2_665
O1 Eu2 N3 O4 -146(2) 3_565
O1 Eu2 N3 O5 105.3(18) .
O1 Eu2 N3 O5 108.9(19) 2_665
O1 Eu2 N3 O5 32.9(18) 3_565
O1 Eu2 N3 O6 -80(9) 3_565
O1 Eu2 N3 O6 -4(10) 2_665
O1 Eu2 N3 O6 -7(9) .
O1 Eu2 O1 C3 -91(4) 3_565
O1 Eu2 O1 C3 -12(4) 2_665
O1 Eu2 O4 N3 99(2) .
O1 Eu2 O4 N3 138(2) 2_665
O1 Eu2 O4 N3 39(2) 3_565
O1 Eu2 O5 N3 -69.4(18) .
O1 Eu2 O5 N3 -115(2) 2_665
O1 Eu2 O5 N3 -146.5(19) 3_565
O2 C9 C10 C11 166(3) .
O2 Eu1 N4 O7 -62(5) 3_565
O2 Eu1 N4 O7 -95(2) 2_665
O2 Eu1 N4 O7 -13(2) .
O2 Eu1 N4 O8 122(5) 3_565
O2 Eu1 N4 O8 89.5(18) 2_665
O2 Eu1 N4 O8 171.0(18) .
O2 Eu1 N4 O9 -76(30) 3_565
O2 Eu1 N4 O9 -108(29) 2_665
O2 Eu1 N4 O9 -27(29) .
O2 Eu1 O2 C9 29(5) 3_565
O2 Eu1 O2 C9 -54(5) 2_665
O2 Eu1 O7 N4 166(3) .
O2 Eu1 O7 N4 86(2) 2_665
O2 Eu1 O7 N4 163.9(17) 3_565
O2 Eu1 O8 N4 -10(2) .
O2 Eu1 O8 N4 -90.8(18) 2_665
O2 Eu1 O8 N4 -158(2) 3_565
O3 Eu2 N3 O4 80(2) .
O3 Eu2 N3 O5 -102.0(17) .
O3 Eu2 N3 O6 145(9) .
O3 Eu2 O1 C3 128(4) .
O3 Eu2 O4 N3 -91(2) .
O3 Eu2 O5 N3 70.5(17) .
O4 Eu2 N3 O4 147(2) 3_565
O4 Eu2 N3 O4 40(2) 2_665
O4 Eu2 N3 O5 -34.5(16) 3_565
O4 Eu2 N3 O5 178(4) .
O4 Eu2 N3 O5 -141.4(16) 2_665
O4 Eu2 N3 O6 -147(9) 3_565
O4 Eu2 N3 O6 66(9) .
O4 Eu2 N3 O6 106(10) 2_665
O4 Eu2 O1 C3 43(4) 2_665
O4 Eu2 O1 C3 141(4) .
O4 Eu2 O1 C3 -128(4) 3_565
O4 Eu2 O4 N3 -34(3) 3_565
O4 Eu2 O4 N3 -147.0(18) 2_665
O4 Eu2 O5 N3 141.4(18) 3_565
O4 Eu2 O5 N3 58(2) 2_665
O4 Eu2 O5 N3 -0.8(19) .
O4 N3 O5 Eu2 2(3) .
O5 Eu2 N3 O4 128(2) 3_565
O5 Eu2 N3 O4 -178(4) .
O5 Eu2 N3 O4 3(2) 2_665
O5 Eu2 N3 O5 -178.3(18) 2_665
O5 Eu2 N3 O5 -53.9(17) 3_565
O5 Eu2 N3 O6 -167(9) 3_565
O5 Eu2 N3 O6 -113(10) .
O5 Eu2 N3 O6 69(9) 2_665
O5 Eu2 O1 C3 -169(4) .
O5 Eu2 O1 C3 -44(5) 3_565
O5 Eu2 O1 C3 73(4) 2_665
O5 Eu2 O4 N3 -78(3) 3_565
O5 Eu2 O4 N3 1(2) .
O5 Eu2 O4 N3 -176(2) 2_665
O5 Eu2 O5 N3 139.1(16) 3_565
O5 Eu2 O5 N3 2(2) 2_665
O5 N3 O4 Eu2 -2(3) .
O6 N3 O4 Eu2 -169(3) .
O6 N3 O5 Eu2 168(3) .
O7 Eu1 N4 O7 81.4(17) 3_565
O7 Eu1 N4 O7 -163(2) 2_665
O7 Eu1 N4 O8 -94.2(19) 3_565
O7 Eu1 N4 O8 21.3(18) 2_665
O7 Eu1 N4 O8 -176(3) .
O7 Eu1 N4 O9 68(29) 3_565
O7 Eu1 N4 O9 -177(29) 2_665
O7 Eu1 N4 O9 -13(28) .
O7 Eu1 O2 C9 -151(6) .
O7 Eu1 O2 C9 96(6) 3_565
O7 Eu1 O2 C9 -52(6) 2_665
O7 Eu1 O7 N4 18(2) 2_665
O7 Eu1 O7 N4 -110.7(17) 3_565
O7 Eu1 O8 N4 -157(2) 2_665
O7 Eu1 O8 N4 100(2) 3_565
O7 Eu1 O8 N4 2.5(19) .
O7 N4 O8 Eu1 -4(3) .
O8 Eu1 N4 O7 148(2) 2_665
O8 Eu1 N4 O7 176(3) .
O8 Eu1 N4 O7 76(2) 3_565
O8 Eu1 N4 O8 -99(2) 3_565
O8 Eu1 N4 O8 -27.9(19) 2_665
O8 Eu1 N4 O9 134(29) 2_665
O8 Eu1 N4 O9 63(29) 3_565
O8 Eu1 N4 O9 162(30) .
O8 Eu1 O2 C9 146(6) 3_565
O8 Eu1 O2 C9 -140(5) .
O8 Eu1 O2 C9 98(6) 2_665
O8 Eu1 O7 N4 -93(2) 3_565
O8 Eu1 O7 N4 -37(2) 2_665
O8 Eu1 O7 N4 -2.4(19) .
O8 Eu1 O8 N4 73(2) 3_565
O8 Eu1 O8 N4 151.3(19) 2_665
O8 N4 O7 Eu1 4(3) .
O9 N4 O7 Eu1 179(2) .
O9 N4 O8 Eu1 -178(3) .
