#------------------------------------------------------------------------------
#$Date: 2020-10-04 06:23:51 +0300 (Sun, 04 Oct 2020) $
#$Revision: 257106 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/35/07/4350771.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4350771
loop_
_publ_author_name
'Li, Lei-Lei'
'Cao, Gao-Juan'
'Zhao, Jun-Wei'
'He, Huan'
'Yang, Bai-Feng'
'Yang, Guo-Yu'
_publ_section_title
;
 Correction to Lanthanide Germanate Cluster Organic Frameworks Based on
 {Ln₈Ge₁₂} Clusters: From One-Dimensional Chains to
 Two- Dimensional Layers and Three-Dimensional Frameworks.
;
_journal_issue                   5
_journal_name_full               'Inorganic chemistry'
_journal_page_first              3340
_journal_page_last               3340
_journal_paper_doi               10.1021/acs.inorgchem.9b03158
_journal_volume                  59
_journal_year                    2020
_chemical_formula_sum            'C60 H108 Ge12 N6 Nd10 O84'
_chemical_formula_weight         4571.00
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_space_group_name_H-M_alt        'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_cell_angle_alpha                90
_cell_angle_beta                 106.542(5)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   16.425(6)
_cell_length_b                   18.842(6)
_cell_length_c                   19.184(7)
_cell_measurement_reflns_used    14001
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.4820
_cell_measurement_theta_min      2.1616
_cell_volume                     5691(3)
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0387
_diffrn_reflns_av_unetI/netI     0.0436
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.993
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -21
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            41959
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.993
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.490
_diffrn_reflns_theta_min         2.215
_exptl_absorpt_coefficient_mu    7.701
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            pink
_exptl_crystal_density_diffrn    2.667
_exptl_crystal_description       block
_exptl_crystal_F_000             4332
_exptl_crystal_size_max          0.290
_exptl_crystal_size_mid          0.220
_exptl_crystal_size_min          0.180
_refine_diff_density_max         2.469
_refine_diff_density_min         -1.457
_refine_diff_density_rms         0.214
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.047
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     793
_refine_ls_number_reflns         12980
_refine_ls_number_restraints     1770
_refine_ls_restrained_S_all      1.013
_refine_ls_R_factor_all          0.0498
_refine_ls_R_factor_gt           0.0377
_refine_ls_shift/su_max          0.028
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0588P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0934
_refine_ls_wR_factor_ref         0.1042
_reflns_Friedel_coverage         0.000
_reflns_number_gt                10630
_reflns_number_total             12980
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ic9b03158_si_002.cif
_cod_data_source_block           '_shelxl'
_cod_depositor_comments
;Adding full bibliography for 4350770--4350771.cif.

 Adding full bibliography for 4350770--4350771.cif.
;
_cod_original_cell_volume        5692(3)
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4350771
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.214
_shelx_estimated_absorpt_t_max   0.338
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Ge1 Ge 0.47024(4) 0.78846(4) 0.88839(3) 0.01825(14) Uani 1 1 d . . .
Ge2 Ge 0.32155(4) 0.81693(3) 0.96627(3) 0.01778(14) Uani 1 1 d . . .
Ge3 Ge 0.22262(4) 0.96542(3) 0.94870(3) 0.01716(14) Uani 1 1 d . . .
Ge4 Ge 0.26152(4) 1.09137(3) 0.84830(3) 0.01778(14) Uani 1 1 d . . .
Ge5 Ge 0.40749(4) 1.06225(4) 0.76848(3) 0.01866(14) Uani 1 1 d . . .
Ge6 Ge 0.50965(4) 0.91238(4) 0.78670(3) 0.01847(14) Uani 1 1 d . . .
Nd1 Nd 0.30384(2) 0.90755(2) 0.80274(2) 0.02056(9) Uani 1 1 d . . .
Nd2 Nd 0.25524(2) 0.85078(2) 1.25279(2) 0.01978(8) Uani 1 1 d . . .
Nd3 Nd 0.54858(2) 0.80777(2) 1.07882(2) 0.01626(8) Uani 1 1 d . . .
Nd4 Nd 0.38122(2) 0.92876(2) 1.11891(2) 0.01356(8) Uani 1 1 d . . .
Nd5 Nd 0.32385(2) 1.11631(2) 1.04917(2) 0.01547(8) Uani 1 1 d . . .
O1 O 0.4706(3) 0.7101(3) 1.0033(3) 0.0352(12) Uani 1 1 d . U .
O2 O 0.4250(15) 0.598(2) 1.010(2) 0.051(6) Uani 0.5 1 d . U P
O2' O 0.4521(16) 0.596(2) 1.0129(18) 0.050(5) Uani 0.5 1 d . U P
O3 O 0.2532(3) 0.8584(2) 1.0566(2) 0.0231(9) Uani 1 1 d . U .
O4 O 0.1934(3) 0.8000(3) 1.1304(3) 0.0334(11) Uani 1 1 d . U .
O5 O 0.1725(3) 1.1084(3) 0.9770(3) 0.0343(12) Uani 1 1 d . U .
O6 O 0.0458(3) 1.1496(3) 0.9147(3) 0.0411(13) Uani 1 1 d . U .
O7 O 0.3438(3) 1.2090(3) 0.8048(3) 0.0328(11) Uani 1 1 d . U .
O8 O 0.2872(3) 1.3050(3) 0.7429(3) 0.0403(13) Uani 1 1 d . U .
O9 O 0.5486(3) 1.0544(2) 0.7469(2) 0.0248(10) Uani 1 1 d . U .
O10 O 0.6075(3) 1.0998(3) 0.6661(3) 0.0322(11) Uani 1 1 d . U .
O11 O 0.6192(3) 0.8211(2) 0.8311(2) 0.0264(10) Uani 1 1 d . U .
O12 O 0.6980(3) 0.7564(3) 0.7785(3) 0.0330(11) Uani 1 1 d . U .
O13 O 0.4456(3) 0.8440(2) 0.8086(2) 0.0204(9) Uani 1 1 d . U .
O14 O 0.3639(3) 0.8004(2) 0.8910(2) 0.0243(10) Uani 1 1 d . U .
O15 O 0.2528(3) 0.8844(2) 0.9136(2) 0.0196(9) Uani 1 1 d . U .
O16 O 0.2135(3) 1.0108(2) 0.8661(2) 0.0252(10) Uani 1 1 d . U .
O17 O 0.3068(3) 1.0491(3) 0.7851(2) 0.0249(10) Uani 1 1 d . U .
O18 O 0.4157(3) 0.9683(2) 0.7583(2) 0.0221(9) Uani 1 1 d . U .
O19 O 0.5475(3) 0.8302(2) 0.9571(2) 0.0201(9) Uani 1 1 d . U .
O20 O 0.4084(3) 0.8526(2) 1.0322(2) 0.0220(9) Uani 1 1 d . U .
O21 O 0.3110(3) 0.9946(2) 1.0166(2) 0.0186(9) Uani 1 1 d . U .
O22 O 0.3336(3) 1.1215(2) 0.9278(2) 0.0213(9) Uani 1 1 d . U .
O23 O 0.4730(3) 1.0953(2) 0.8500(2) 0.0210(9) Uani 1 1 d . U .
O24 O 0.5747(3) 0.9537(2) 0.8636(2) 0.0208(9) Uani 1 1 d . U .
O25 O 0.4717(3) 0.7535(3) 1.1671(2) 0.0299(11) Uani 1 1 d . U .
O26 O 0.3704(3) 0.8210(2) 1.1909(2) 0.0235(9) Uani 1 1 d . U .
O27 O 0.2671(3) 0.9554(2) 1.1758(2) 0.0244(9) Uani 1 1 d . U .
O28 O 0.2460(3) 1.0697(3) 1.1442(3) 0.0289(10) Uani 1 1 d . U .
O29 O 0.2287(3) 0.8571(3) 1.3719(3) 0.0334(11) Uani 1 1 d . U .
O30 O 0.1832(12) 0.9098(13) 1.4560(13) 0.037(4) Uani 0.5 1 d . U P
O30' O 0.2110(15) 0.9206(14) 1.4678(14) 0.054(5) Uani 0.5 1 d . U P
N1 N 0.3771(4) 0.7500(3) 1.3100(3) 0.0320(13) Uani 1 1 d . U .
N2 N 0.5178(5) 0.6660(5) 1.3753(4) 0.062(2) Uani 1 1 d . U .
N3 N 0.2254(3) 0.9754(3) 1.2965(3) 0.0249(11) Uani 1 1 d . U .
C1 C 0.4997(5) 0.6934(4) 0.8670(4) 0.0322(15) Uani 1 1 d . U .
H1A H 0.483346 0.687195 0.814607 0.039 Uiso 1 1 calc R U .
H1B H 0.560905 0.688054 0.884583 0.039 Uiso 1 1 calc R U .
C2 C 0.4577(6) 0.6344(4) 0.9006(4) 0.048(2) Uani 1 1 d . U .
H2A H 0.399729 0.628282 0.870554 0.058 Uiso 1 1 calc R U .
H2B H 0.487592 0.590242 0.899243 0.058 Uiso 1 1 calc R U .
C3 C 0.4563(5) 0.6474(4) 0.9776(4) 0.0400(18) Uani 1 1 d . U .
C4 C 0.2620(5) 0.7331(4) 0.9836(4) 0.0296(14) Uani 1 1 d . U .
H4A H 0.239885 0.708016 0.937947 0.036 Uiso 1 1 calc R U .
H4B H 0.302273 0.701981 1.016426 0.036 Uiso 1 1 calc R U .
C5 C 0.1892(5) 0.7482(4) 1.0156(4) 0.0332(16) Uani 1 1 d . U .
H5A H 0.139617 0.762947 0.977249 0.040 Uiso 1 1 calc R U .
H5B H 0.174834 0.705277 1.037412 0.040 Uiso 1 1 calc R U .
C6 C 0.2137(4) 0.8056(4) 1.0722(4) 0.0254(13) Uani 1 1 d . U .
C7 C 0.1180(4) 0.9670(4) 0.9746(4) 0.0264(14) Uani 1 1 d . U .
H7A H 0.090196 0.921301 0.963389 0.032 Uiso 1 1 calc R U .
H7B H 0.130276 0.974719 1.026533 0.032 Uiso 1 1 calc R U .
C8 C 0.0587(4) 1.0244(4) 0.9348(4) 0.0338(16) Uani 1 1 d . U .
H8A H 0.008602 1.024279 0.952028 0.041 Uiso 1 1 calc R U .
H8B H 0.040438 1.012319 0.883489 0.041 Uiso 1 1 calc R U .
C9 C 0.0954(4) 1.1006(4) 0.9425(4) 0.0270(14) Uani 1 1 d . U .
C10 C 0.1758(5) 1.1580(4) 0.8012(4) 0.0386(17) Uani 1 1 d . U .
H10A H 0.126188 1.131805 0.773715 0.046 Uiso 1 1 calc R U .
H10B H 0.159483 1.184735 0.838344 0.046 Uiso 1 1 calc R U .
C11 C 0.1998(7) 1.2097(6) 0.7509(6) 0.075(3) Uani 1 1 d . U .
H11A H 0.195296 1.184692 0.705699 0.091 Uiso 1 1 calc R U .
H11B H 0.156734 1.246465 0.739937 0.091 Uiso 1 1 calc R U .
C12 C 0.2814(5) 1.2450(4) 0.7711(4) 0.0417(19) Uani 1 1 d . U .
C13 C 0.3918(4) 1.1131(4) 0.6783(4) 0.0289(14) Uani 1 1 d . U .
H13A H 0.334661 1.104248 0.647645 0.035 Uiso 1 1 calc R U .
H13B H 0.396621 1.163511 0.688828 0.035 Uiso 1 1 calc R U .
C14 C 0.4540(5) 1.0938(5) 0.6363(4) 0.0397(18) Uani 1 1 d . U .
H14A H 0.455284 1.131441 0.602132 0.048 Uiso 1 1 calc R U .
H14B H 0.435033 1.050740 0.608637 0.048 Uiso 1 1 calc R U .
C15 C 0.5443(4) 1.0822(4) 0.6873(4) 0.0269(14) Uani 1 1 d . U .
C16 C 0.5437(4) 0.8906(4) 0.7005(4) 0.0271(14) Uani 1 1 d . U .
H16A H 0.496049 0.898109 0.657670 0.032 Uiso 1 1 calc R U .
H16B H 0.589150 0.922242 0.697575 0.032 Uiso 1 1 calc R U .
C17 C 0.5742(5) 0.8128(4) 0.7019(4) 0.0381(17) Uani 1 1 d . U .
H17A H 0.525640 0.781177 0.691994 0.046 Uiso 1 1 calc R U .
H17B H 0.602352 0.805898 0.664344 0.046 Uiso 1 1 calc R U .
C18 C 0.6352(4) 0.7951(4) 0.7757(4) 0.0263(14) Uani 1 1 d . U .
C19 C 0.4258(4) 0.7724(4) 1.2058(3) 0.0243(13) Uani 1 1 d . U .
C20 C 0.4366(4) 0.7364(4) 1.2773(4) 0.0274(14) Uani 1 1 d . U .
C21 C 0.5070(5) 0.6949(4) 1.3094(4) 0.0420(18) Uani 1 1 d . U .
H21 H 0.547457 0.686998 1.284839 0.050 Uiso 1 1 calc R U .
C22 C 0.4574(6) 0.6791(6) 1.4066(5) 0.060(2) Uani 1 1 d . U .
H22 H 0.463399 0.660908 1.452839 0.071 Uiso 1 1 calc R U .
C23 C 0.3872(5) 0.7178(5) 1.3744(4) 0.0463(19) Uani 1 1 d . U .
H23 H 0.344745 0.722084 1.397581 0.056 Uiso 1 1 calc R U .
C24 C 0.2115(5) 0.9134(4) 1.4023(4) 0.0365(17) Uani 1 1 d . U .
C25 C 0.2114(5) 0.9819(4) 1.3623(4) 0.0316(15) Uani 1 1 d . U .
C26 C 0.1955(5) 1.0482(4) 1.3884(4) 0.0396(17) Uani 1 1 d . U .
H26 H 0.183307 1.052270 1.432658 0.048 Uiso 1 1 calc R U .
C27 C 0.1985(6) 1.1075(4) 1.3467(4) 0.0390(17) Uani 1 1 d . U .
H27 H 0.190506 1.152493 1.363674 0.047 Uiso 1 1 calc R U .
C28 C 0.2133(5) 1.0996(4) 1.2802(4) 0.0354(16) Uani 1 1 d . U .
H28 H 0.214375 1.139180 1.251451 0.042 Uiso 1 1 calc R U .
C29 C 0.2266(4) 1.0330(4) 1.2564(4) 0.0251(13) Uani 1 1 d . U .
C30 C 0.2477(4) 1.0192(4) 1.1862(3) 0.0244(13) Uani 1 1 d . U .
O1W O 0.4117(3) 0.9604(2) 0.9134(2) 0.0253(10) Uani 1 1 d . U .
O2W O 0.1737(4) 0.9486(4) 0.7091(4) 0.064(2) Uani 1 1 d . U .
O3W O 0.3030(5) 0.8695(5) 0.6669(4) 0.094(3) Uani 1 1 d . U .
O4W O 0.6497(4) 0.6979(3) 1.0692(3) 0.0453(14) Uani 1 1 d . U .
O5W O 0.2679(3) 1.2433(3) 1.0337(3) 0.0339(12) Uani 1 1 d . U .
O6W O 0.0975(3) 0.8803(3) 1.2068(3) 0.0448(14) Uani 1 1 d . U .
O7W O -0.0035(5) -0.0166(4) 0.2584(4) 0.082(2) Uani 1 1 d . U .
O8W O 0.5671(8) 0.1056(8) 0.5082(6) 0.153(5) Uani 1 1 d . U .
O9W O 0.0129(4) 0.8938(3) 0.6554(3) 0.0580(17) Uani 1 1 d . U .
O10W O 0.3350(8) 0.4941(5) 0.9305(5) 0.123(3) Uani 1 1 d . U .
O11W O 0.1657(11) 0.4580(10) 0.9333(8) 0.206(5) Uani 1 1 d . U .
O12W O 0.1181(4) 0.2795(4) 0.9354(4) 0.074(2) Uani 1 1 d . U .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Nd Nd -0.1943 3.0179 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O19 Ge1 O14 115.7(2) . .
O19 Ge1 O13 108.7(2) . .
O14 Ge1 O13 88.0(2) . .
O19 Ge1 C1 114.1(3) . .
O14 Ge1 C1 115.6(3) . .
O13 Ge1 C1 111.5(3) . .
O19 Ge1 Nd3 36.38(14) . .
O14 Ge1 Nd3 91.67(14) . .
O13 Ge1 Nd3 138.30(14) . .
C1 Ge1 Nd3 106.1(2) . .
O20 Ge2 O14 103.0(2) . .
O20 Ge2 O15 112.6(2) . .
O14 Ge2 O15 89.8(2) . .
O20 Ge2 C4 122.5(3) . .
O14 Ge2 C4 109.0(3) . .
O15 Ge2 C4 113.9(3) . .
O20 Ge2 Nd1 107.60(15) . .
O14 Ge2 Nd1 47.14(15) . .
O15 Ge2 Nd1 43.83(14) . .
C4 Ge2 Nd1 129.3(2) . .
O20 Ge2 Nd4 35.90(14) . .
O14 Ge2 Nd4 133.84(14) . .
O15 Ge2 Nd4 91.45(13) . .
C4 Ge2 Nd4 112.4(2) . .
Nd1 Ge2 Nd4 112.69(3) . .
O21 Ge3 O16 111.0(2) . .
O21 Ge3 O15 106.80(19) . .
O16 Ge3 O15 92.1(2) . .
O21 Ge3 C7 114.7(2) . .
O16 Ge3 C7 111.7(3) . .
O15 Ge3 C7 118.3(3) . .
O22 Ge4 O17 115.5(2) . .
O22 Ge4 O16 109.7(2) . .
O17 Ge4 O16 92.5(2) . .
O22 Ge4 C10 115.2(3) . .
O17 Ge4 C10 111.5(3) . .
O16 Ge4 C10 110.0(3) . .
O23 Ge5 O17 104.8(2) . .
O23 Ge5 O18 113.9(2) . .
O17 Ge5 O18 89.1(2) . .
O23 Ge5 C13 121.2(3) . .
O17 Ge5 C13 109.5(3) . .
O18 Ge5 C13 112.8(3) . .
O24 Ge6 O13 112.6(2) . .
O24 Ge6 O18 105.0(2) . .
O13 Ge6 O18 89.0(2) . .
O24 Ge6 C16 124.3(3) . .
O13 Ge6 C16 112.3(3) . .
O18 Ge6 C16 107.1(2) . .
O24 Ge6 Nd1 108.29(15) . .
O13 Ge6 Nd1 46.31(14) . .
O18 Ge6 Nd1 43.90(14) . .
C16 Ge6 Nd1 126.4(2) . .
O8 Nd1 O2W 71.06(19) 2_546 .
O8 Nd1 O18 132.07(17) 2_546 .
O2W Nd1 O18 100.0(2) . .
O8 Nd1 O15 81.39(17) 2_546 .
O2W Nd1 O15 103.7(2) . .
O18 Nd1 O15 144.26(14) . .
O8 Nd1 O1W 144.63(17) 2_546 .
O2W Nd1 O1W 136.86(19) . .
O18 Nd1 O1W 72.69(14) . .
O15 Nd1 O1W 71.69(14) . .
O8 Nd1 O13 95.79(16) 2_546 .
O2W Nd1 O13 138.6(2) . .
O18 Nd1 O13 59.35(14) . .
O15 Nd1 O13 113.06(13) . .
O1W Nd1 O13 75.02(14) . .
O8 Nd1 O14 72.82(16) 2_546 .
O2W Nd1 O14 141.93(19) . .
O18 Nd1 O14 112.99(14) . .
O15 Nd1 O14 58.86(14) . .
O1W Nd1 O14 73.73(14) . .
O13 Nd1 O14 56.76(14) . .
O8 Nd1 O17 140.21(15) 2_546 .
O2W Nd1 O17 69.16(17) . .
O18 Nd1 O17 57.60(14) . .
O15 Nd1 O17 107.33(14) . .
O1W Nd1 O17 71.61(14) . .
O13 Nd1 O17 114.53(13) . .
O14 Nd1 O17 145.29(13) . .
O8 Nd1 O3W 67.1(2) 2_546 .
O2W Nd1 O3W 67.6(3) . .
O18 Nd1 O3W 66.2(2) . .
O15 Nd1 O3W 148.4(2) . .
O1W Nd1 O3W 136.0(2) . .
O13 Nd1 O3W 71.1(2) . .
O14 Nd1 O3W 108.3(2) . .
O17 Nd1 O3W 97.9(2) . .
O8 Nd1 O16 110.12(16) 2_546 .
O2W Nd1 O16 70.1(2) . .
O18 Nd1 O16 110.27(13) . .
O15 Nd1 O16 55.63(13) . .
O1W Nd1 O16 73.01(14) . .
O13 Nd1 O16 148.02(12) . .
O14 Nd1 O16 112.62(13) . .
O17 Nd1 O16 54.59(13) . .
O3W Nd1 O16 135.8(2) . .
O8 Nd1 Ge6 119.92(14) 2_546 .
O2W Nd1 Ge6 125.71(19) . .
O18 Nd1 Ge6 30.16(10) . .
O15 Nd1 Ge6 129.77(9) . .
O1W Nd1 Ge6 66.50(11) . .
O13 Nd1 Ge6 29.90(10) . .
O14 Nd1 Ge6 83.20(10) . .
O17 Nd1 Ge6 84.85(10) . .
O3W Nd1 Ge6 70.10(17) . .
O16 Nd1 Ge6 129.96(9) . .
O8 Nd1 Ge2 79.78(13) 2_546 .
O2W Nd1 Ge2 129.11(18) . .
O18 Nd1 Ge2 130.00(10) . .
O15 Nd1 Ge2 29.54(10) . .
O1W Nd1 Ge2 65.45(11) . .
O13 Nd1 Ge2 83.79(9) . .
O14 Nd1 Ge2 29.98(10) . .
O17 Nd1 Ge2 126.49(9) . .
O3W Nd1 Ge2 135.2(2) . .
O16 Nd1 Ge2 82.77(9) . .
Ge6 Nd1 Ge2 104.847(18) . .
O12 Nd2 O29 69.90(17) 4_576 .
O12 Nd2 O4 77.59(17) 4_576 .
O29 Nd2 O4 140.53(17) . .
O12 Nd2 O27 155.19(16) 4_576 .
O29 Nd2 O27 125.21(16) . .
O4 Nd2 O27 79.85(16) . .
O12 Nd2 O10 122.04(17) 4_576 3_677
O29 Nd2 O10 76.81(17) . 3_677
O4 Nd2 O10 141.45(16) . 3_677
O27 Nd2 O10 82.38(15) . 3_677
O12 Nd2 O6W 80.31(19) 4_576 .
O29 Nd2 O6W 83.02(18) . .
O4 Nd2 O6W 69.73(18) . .
O27 Nd2 O6W 82.31(17) . .
O10 Nd2 O6W 140.70(18) 3_677 .
O12 Nd2 O26 107.58(17) 4_576 .
O29 Nd2 O26 142.52(16) . .
O4 Nd2 O26 68.46(15) . .
O27 Nd2 O26 73.01(14) . .
O10 Nd2 O26 73.71(15) 3_677 .
O6W Nd2 O26 134.29(16) . .
O12 Nd2 N3 126.23(18) 4_576 .
O29 Nd2 N3 63.42(17) . .
O4 Nd2 N3 126.50(18) . .
O27 Nd2 N3 61.99(16) . .
O10 Nd2 N3 71.57(17) 3_677 .
O6W Nd2 N3 69.27(18) . .
O26 Nd2 N3 125.56(16) . .
O12 Nd2 N1 67.06(18) 4_576 .
O29 Nd2 N1 87.95(17) . .
O4 Nd2 N1 99.66(18) . .
O27 Nd2 N1 127.50(16) . .
O10 Nd2 N1 65.66(18) 3_677 .
O6W Nd2 N1 147.27(19) . .
O26 Nd2 N1 59.00(16) . .
N3 Nd2 N1 132.91(18) . .
O12 Nd2 Nd4 139.77(13) 4_576 .
O29 Nd2 Nd4 147.34(13) . .
O4 Nd2 Nd4 71.35(11) . .
O27 Nd2 Nd4 36.12(10) . .
O10 Nd2 Nd4 74.12(11) 3_677 .
O6W Nd2 Nd4 110.96(14) . .
O26 Nd2 Nd4 36.91(10) . .
N3 Nd2 Nd4 93.15(12) . .
N1 Nd2 Nd4 93.38(13) . .
O23 Nd3 O19 118.09(15) 3_677 .
O23 Nd3 O20 69.76(15) 3_677 .
O19 Nd3 O20 80.28(14) . .
O23 Nd3 O22 81.76(15) 3_677 3_677
O19 Nd3 O22 68.01(14) . 3_677
O20 Nd3 O22 119.72(15) . 3_677
O23 Nd3 O7 76.18(16) 3_677 3_677
O19 Nd3 O7 136.46(16) . 3_677
O20 Nd3 O7 139.64(16) . 3_677
O22 Nd3 O7 74.58(16) 3_677 3_677
O23 Nd3 O1 141.05(16) 3_677 .
O19 Nd3 O1 72.34(16) . .
O20 Nd3 O1 76.04(16) . .
O22 Nd3 O1 132.87(16) 3_677 .
O7 Nd3 O1 124.09(17) 3_677 .
O23 Nd3 O25 75.34(16) 3_677 .
O19 Nd3 O25 147.76(15) . .
O20 Nd3 O25 77.64(16) . .
O22 Nd3 O25 144.04(15) 3_677 .
O7 Nd3 O25 73.27(17) 3_677 .
O1 Nd3 O25 79.70(17) . .
O23 Nd3 O4W 146.04(16) 3_677 .
O19 Nd3 O4W 84.32(16) . .
O20 Nd3 O4W 142.96(16) . .
O22 Nd3 O4W 84.27(17) 3_677 .
O7 Nd3 O4W 70.30(17) 3_677 .
O1 Nd3 O4W 67.21(18) . .
O25 Nd3 O4W 99.56(18) . .
O23 Nd3 Ge1 127.32(10) 3_677 .
O19 Nd3 Ge1 25.79(10) . .
O20 Nd3 Ge1 67.58(10) . .
O22 Nd3 Ge1 93.70(10) 3_677 .
O7 Nd3 Ge1 152.71(12) 3_677 .
O1 Nd3 Ge1 48.62(12) . .
O25 Nd3 Ge1 122.23(11) . .
O4W Nd3 Ge1 84.25(12) . .
O23 Nd3 Nd4 35.66(10) 3_677 .
O19 Nd3 Nd4 106.79(10) . .
O20 Nd3 Nd4 35.54(10) . .
O22 Nd3 Nd4 108.63(11) 3_677 .
O7 Nd3 Nd4 105.59(12) 3_677 .
O1 Nd3 Nd4 106.34(13) . .
O25 Nd3 Nd4 65.87(11) . .
O4W Nd3 Nd4 165.27(14) . .
Ge1 Nd3 Nd4 101.484(19) . .
O23 Nd3 Nd5 105.91(11) 3_677 3_677
O19 Nd3 Nd5 34.24(10) . 3_677
O20 Nd3 Nd5 105.54(11) . 3_677
O22 Nd3 Nd5 34.51(10) 3_677 3_677
O7 Nd3 Nd5 104.06(13) 3_677 3_677
O1 Nd3 Nd5 100.66(13) . 3_677
O25 Nd3 Nd5 176.80(11) . 3_677
O4W Nd3 Nd5 77.74(14) . 3_677
Ge1 Nd3 Nd5 59.48(2) . 3_677
Nd4 Nd3 Nd5 116.89(2) . 3_677
O24 Nd4 O21 70.92(14) 3_677 .
O24 Nd4 O20 124.98(16) 3_677 .
O21 Nd4 O20 82.89(15) . .
O24 Nd4 O23 83.89(15) 3_677 3_677
O21 Nd4 O23 122.85(15) . 3_677
O20 Nd4 O23 70.94(14) . 3_677
O24 Nd4 O27 89.26(15) 3_677 .
O21 Nd4 O27 90.44(15) . .
O20 Nd4 O27 139.62(15) . .
O23 Nd4 O27 140.84(15) 3_677 .
O24 Nd4 O3 139.81(15) 3_677 .
O21 Nd4 O3 74.40(14) . .
O20 Nd4 O3 68.67(15) . .
O23 Nd4 O3 133.08(15) 3_677 .
O27 Nd4 O3 71.17(15) . .
O24 Nd4 O26 139.96(15) 3_677 .
O21 Nd4 O26 143.58(14) . .
O20 Nd4 O26 87.27(16) . .
O23 Nd4 O26 86.01(15) 3_677 .
O27 Nd4 O26 74.84(15) . .
O3 Nd4 O26 69.36(14) . .
O24 Nd4 O9 72.55(14) 3_677 3_677
O21 Nd4 O9 139.89(15) . 3_677
O20 Nd4 O9 132.84(15) . 3_677
O23 Nd4 O9 68.12(15) 3_677 3_677
O27 Nd4 O9 73.03(15) . 3_677
O3 Nd4 O9 129.51(14) . 3_677
O26 Nd4 O9 67.72(15) . 3_677
O24 Nd4 Ge2 133.87(10) 3_677 .
O21 Nd4 Ge2 70.35(10) . .
O20 Nd4 Ge2 26.07(10) . .
O23 Nd4 Ge2 96.81(10) 3_677 .
O27 Nd4 Ge2 115.01(11) . .
O3 Nd4 Ge2 44.10(11) . .
O26 Nd4 Ge2 85.76(11) . .
O9 Nd4 Ge2 149.76(11) 3_677 .
O24 Nd4 Nd5 36.94(10) 3_677 .
O21 Nd4 Nd5 36.39(10) . .
O20 Nd4 Nd5 113.52(11) . .
O23 Nd4 Nd5 113.74(11) 3_677 .
O27 Nd4 Nd5 79.82(10) . .
O3 Nd4 Nd5 103.64(10) . .
O26 Nd4 Nd5 154.63(10) . .
O9 Nd4 Nd5 103.75(11) 3_677 .
Ge2 Nd4 Nd5 106.37(3) . .
O24 Nd4 Nd3 112.68(11) 3_677 .
O21 Nd4 Nd3 111.14(11) . .
O20 Nd4 Nd3 36.28(10) . .
O23 Nd4 Nd3 36.12(10) 3_677 .
O27 Nd4 Nd3 152.92(10) . .
O3 Nd4 Nd3 98.25(11) . .
O26 Nd4 Nd3 78.10(10) . .
O9 Nd4 Nd3 97.74(11) 3_677 .
Ge2 Nd4 Nd3 61.28(2) . .
Nd5 Nd4 Nd3 127.250(16) . .
O24 Nd4 Nd2 116.97(11) 3_677 .
O21 Nd4 Nd2 120.85(11) . .
O20 Nd4 Nd2 118.02(12) . .
O23 Nd4 Nd2 116.30(11) 3_677 .
O27 Nd4 Nd2 36.65(10) . .
O3 Nd4 Nd2 65.94(10) . .
O26 Nd4 Nd2 38.22(10) . .
O9 Nd4 Nd2 64.00(11) 3_677 .
Ge2 Nd4 Nd2 104.00(3) . .
Nd5 Nd4 Nd2 116.417(16) . .
Nd3 Nd4 Nd2 116.32(2) . .
O21 Nd5 O19 114.26(15) . 3_677
O21 Nd5 O22 78.94(15) . .
O19 Nd5 O22 67.90(14) 3_677 .
O21 Nd5 O24 69.07(14) . 3_677
O19 Nd5 O24 79.46(15) 3_677 3_677
O22 Nd5 O24 118.60(15) . 3_677
O21 Nd5 O5 78.17(16) . .
O19 Nd5 O5 139.61(16) 3_677 .
O22 Nd5 O5 78.07(16) . .
O24 Nd5 O5 138.08(16) 3_677 .
O21 Nd5 O11 132.57(14) . 3_677
O19 Nd5 O11 75.06(15) 3_677 3_677
O22 Nd5 O11 139.72(15) . 3_677
O24 Nd5 O11 67.41(15) 3_677 3_677
O5 Nd5 O11 126.24(16) . 3_677
O21 Nd5 O5W 151.06(15) . .
O19 Nd5 O5W 83.82(16) 3_677 .
O22 Nd5 O5W 88.28(16) . .
O24 Nd5 O5W 139.00(15) 3_677 .
O5 Nd5 O5W 73.80(16) . .
O11 Nd5 O5W 72.20(15) 3_677 .
O21 Nd5 O28 80.59(15) . .
O19 Nd5 O28 141.65(14) 3_677 .
O22 Nd5 O28 149.82(15) . .
O24 Nd5 O28 73.33(15) 3_677 .
O5 Nd5 O28 76.20(17) . .
O11 Nd5 O28 69.81(15) 3_677 .
O5W Nd5 O28 99.35(16) . .
O21 Nd5 Nd4 35.68(9) . .
O19 Nd5 Nd4 106.12(11) 3_677 .
O22 Nd5 Nd4 107.67(11) . .
O24 Nd5 Nd4 35.71(10) 3_677 .
O5 Nd5 Nd4 104.41(12) . .
O11 Nd5 Nd4 97.12(11) 3_677 .
O5W Nd5 Nd4 163.40(12) . .
O28 Nd5 Nd4 64.55(10) . .
O21 Nd5 Nd3 102.19(10) . 3_677
O19 Nd5 Nd3 34.10(9) 3_677 3_677
O22 Nd5 Nd3 34.54(10) . 3_677
O24 Nd5 Nd3 104.40(11) 3_677 3_677
O5 Nd5 Nd3 107.56(13) . 3_677
O11 Nd5 Nd3 105.93(11) 3_677 3_677
O5W Nd5 Nd3 79.87(12) . 3_677
O28 Nd5 Nd3 175.64(11) . 3_677
Nd4 Nd5 Nd3 115.859(16) . 3_677
C3 O1 Nd3 157.9(5) . .
C6 O3 Nd4 136.3(4) . .
C6 O4 Nd2 132.1(4) . .
C9 O5 Nd5 176.3(5) . .
C12 O7 Nd3 145.1(5) . 3_677
C12 O8 Nd1 138.0(6) . 2_556
C15 O9 Nd4 140.9(4) . 3_677
C15 O10 Nd2 124.8(4) . 3_677
C18 O11 Nd5 146.9(4) . 3_677
C18 O12 Nd2 150.4(5) . 4_675
Ge6 O13 Ge1 127.8(2) . .
Ge6 O13 Nd1 103.79(19) . .
Ge1 O13 Nd1 106.65(19) . .
Ge1 O14 Ge2 130.8(2) . .
Ge1 O14 Nd1 105.6(2) . .
Ge2 O14 Nd1 102.88(19) . .
Ge3 O15 Ge2 125.8(2) . .
Ge3 O15 Nd1 111.16(19) . .
Ge2 O15 Nd1 106.63(19) . .
Ge3 O16 Ge4 130.7(2) . .
Ge3 O16 Nd1 97.36(19) . .
Ge4 O16 Nd1 100.50(19) . .
Ge4 O17 Ge5 130.3(3) . .
Ge4 O17 Nd1 109.3(2) . .
Ge5 O17 Nd1 102.1(2) . .
Ge5 O18 Ge6 128.6(2) . .
Ge5 O18 Nd1 109.2(2) . .
Ge6 O18 Nd1 105.9(2) . .
Ge1 O19 Nd3 117.8(2) . .
Ge1 O19 Nd5 128.4(2) . 3_677
Nd3 O19 Nd5 111.66(16) . 3_677
Ge2 O20 Nd4 118.0(2) . .
Ge2 O20 Nd3 129.7(2) . .
Nd4 O20 Nd3 108.18(16) . .
Ge3 O21 Nd4 124.7(2) . .
Ge3 O21 Nd5 119.7(2) . .
Nd4 O21 Nd5 107.93(16) . .
Ge4 O22 Nd5 128.7(2) . .
Ge4 O22 Nd3 119.8(2) . 3_677
Nd5 O22 Nd3 110.95(16) . 3_677
Ge5 O23 Nd4 119.0(2) . 3_677
Ge5 O23 Nd3 129.6(2) . 3_677
Nd4 O23 Nd3 108.22(16) 3_677 3_677
Ge6 O24 Nd4 129.7(2) . 3_677
Ge6 O24 Nd5 118.9(2) . 3_677
Nd4 O24 Nd5 107.35(16) 3_677 3_677
C19 O25 Nd3 139.8(4) . .
C19 O26 Nd4 123.8(4) . .
C19 O26 Nd2 129.1(4) . .
Nd4 O26 Nd2 104.87(16) . .
C30 O27 Nd4 121.0(4) . .
C30 O27 Nd2 125.8(4) . .
Nd4 O27 Nd2 107.23(17) . .
C30 O28 Nd5 140.6(4) . .
C24 O29 Nd2 125.9(5) . .
C20 N1 C23 115.7(7) . .
C20 N1 Nd2 119.6(4) . .
C23 N1 Nd2 124.3(5) . .
C22 N2 C21 116.0(7) . .
C29 N3 C25 120.0(6) . .
C29 N3 Nd2 121.1(4) . .
C25 N3 Nd2 118.9(4) . .
C2 C1 Ge1 114.2(6) . .
C2 C1 H1A 108.7 . .
Ge1 C1 H1A 108.7 . .
C2 C1 H1B 108.7 . .
Ge1 C1 H1B 108.7 . .
H1A C1 H1B 107.6 . .
C3 C2 C1 115.3(7) . .
C3 C2 H2A 108.5 . .
C1 C2 H2A 108.5 . .
C3 C2 H2B 108.5 . .
C1 C2 H2B 108.5 . .
H2A C2 H2B 107.5 . .
O2' C3 O1 124.6(19) . .
O2' C3 O2 19(2) . .
O1 C3 O2 122(2) . .
O2' C3 C2 116(2) . .
O1 C3 C2 118.5(7) . .
O2 C3 C2 118.4(19) . .
C5 C4 Ge2 114.3(5) . .
C5 C4 H4A 108.7 . .
Ge2 C4 H4A 108.7 . .
C5 C4 H4B 108.7 . .
Ge2 C4 H4B 108.7 . .
H4A C4 H4B 107.6 . .
C6 C5 C4 110.3(6) . .
C6 C5 H5A 109.6 . .
C4 C5 H5A 109.6 . .
C6 C5 H5B 109.6 . .
C4 C5 H5B 109.6 . .
H5A C5 H5B 108.1 . .
O4 C6 O3 124.0(6) . .
O4 C6 C5 119.8(6) . .
O3 C6 C5 116.2(6) . .
C8 C7 Ge3 112.2(5) . .
C8 C7 H7A 109.2 . .
Ge3 C7 H7A 109.2 . .
C8 C7 H7B 109.2 . .
Ge3 C7 H7B 109.2 . .
H7A C7 H7B 107.9 . .
C7 C8 C9 115.9(6) . .
C7 C8 H8A 108.3 . .
C9 C8 H8A 108.3 . .
C7 C8 H8B 108.3 . .
C9 C8 H8B 108.3 . .
H8A C8 H8B 107.4 . .
O6 C9 O5 125.1(7) . .
O6 C9 C8 117.2(6) . .
O5 C9 C8 117.7(6) . .
C11 C10 Ge4 115.9(6) . .
C11 C10 H10A 108.3 . .
Ge4 C10 H10A 108.3 . .
C11 C10 H10B 108.3 . .
Ge4 C10 H10B 108.3 . .
H10A C10 H10B 107.4 . .
C12 C11 C10 121.2(8) . .
C12 C11 H11A 107.0 . .
C10 C11 H11A 107.0 . .
C12 C11 H11B 107.0 . .
C10 C11 H11B 107.0 . .
H11A C11 H11B 106.8 . .
O7 C12 O8 123.7(8) . .
O7 C12 C11 116.9(8) . .
O8 C12 C11 118.2(7) . .
C14 C13 Ge5 114.8(5) . .
C14 C13 H13A 108.6 . .
Ge5 C13 H13A 108.6 . .
C14 C13 H13B 108.6 . .
Ge5 C13 H13B 108.6 . .
H13A C13 H13B 107.5 . .
C13 C14 C15 111.6(6) . .
C13 C14 H14A 109.3 . .
C15 C14 H14A 109.3 . .
C13 C14 H14B 109.3 . .
C15 C14 H14B 109.3 . .
H14A C14 H14B 108.0 . .
O9 C15 O10 124.8(6) . .
O9 C15 C14 115.9(6) . .
O10 C15 C14 119.3(6) . .
C17 C16 Ge6 110.9(5) . .
C17 C16 H16A 109.5 . .
Ge6 C16 H16A 109.5 . .
C17 C16 H16B 109.5 . .
Ge6 C16 H16B 109.5 . .
H16A C16 H16B 108.0 . .
C18 C17 C16 110.5(6) . .
C18 C17 H17A 109.6 . .
C16 C17 H17A 109.6 . .
C18 C17 H17B 109.6 . .
C16 C17 H17B 109.6 . .
H17A C17 H17B 108.1 . .
O12 C18 O11 123.8(6) . .
O12 C18 C17 119.0(6) . .
O11 C18 C17 117.2(6) . .
O25 C19 O26 126.0(6) . .
O25 C19 C20 118.8(6) . .
O26 C19 C20 115.2(6) . .
N1 C20 C21 122.1(7) . .
N1 C20 C19 115.8(6) . .
C21 C20 C19 122.0(7) . .
N2 C21 C20 121.2(8) . .
N2 C21 H21 119.4 . .
C20 C21 H21 119.4 . .
N2 C22 C23 123.1(8) . .
N2 C22 H22 118.5 . .
C23 C22 H22 118.5 . .
N1 C23 C22 121.8(8) . .
N1 C23 H23 119.1 . .
C22 C23 H23 119.1 . .
O30 C24 O30' 22.6(13) . .
O30 C24 O29 120.8(13) . .
O30' C24 O29 127.2(14) . .
O30 C24 C25 121.6(14) . .
O30' C24 C25 114.7(13) . .
O29 C24 C25 116.6(6) . .
N3 C25 C26 120.9(7) . .
N3 C25 C24 115.1(6) . .
C26 C25 C24 123.9(6) . .
C27 C26 C25 118.3(7) . .
C27 C26 H26 120.8 . .
C25 C26 H26 120.8 . .
C28 C27 C26 119.6(7) . .
C28 C27 H27 120.2 . .
C26 C27 H27 120.2 . .
C29 C28 C27 119.7(7) . .
C29 C28 H28 120.2 . .
C27 C28 H28 120.2 . .
N3 C29 C28 121.4(6) . .
N3 C29 C30 114.8(6) . .
C28 C29 C30 123.7(6) . .
O28 C30 O27 125.5(6) . .
O28 C30 C29 118.7(6) . .
O27 C30 C29 115.8(6) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ge1 O19 1.737(4) .
Ge1 O14 1.776(5) .
Ge1 O13 1.803(4) .
Ge1 C1 1.929(7) .
Ge1 Nd3 3.5294(13) .
Ge2 O20 1.749(4) .
Ge2 O14 1.799(5) .
Ge2 O15 1.806(4) .
Ge2 C4 1.936(7) .
Ge2 Nd1 3.5102(12) .
Ge2 Nd4 3.5130(11) .
Ge3 O21 1.741(4) .
Ge3 O16 1.768(4) .
Ge3 O15 1.793(4) .
Ge3 C7 1.920(7) .
Ge4 O22 1.739(4) .
Ge4 O17 1.781(5) .
Ge4 O16 1.789(5) .
Ge4 C10 1.911(7) .
Ge5 O23 1.742(4) .
Ge5 O17 1.788(5) .
Ge5 O18 1.790(4) .
Ge5 C13 1.929(7) .
Ge6 O24 1.740(4) .
Ge6 O13 1.787(4) .
Ge6 O18 1.819(4) .
Ge6 C16 1.935(7) .
Ge6 Nd1 3.4817(14) .
Nd1 O8 2.447(5) 2_546
Nd1 O2W 2.492(6) .
Nd1 O18 2.511(5) .
Nd1 O15 2.537(4) .
Nd1 O1W 2.548(4) .
Nd1 O13 2.592(4) .
Nd1 O14 2.640(5) .
Nd1 O17 2.691(5) .
Nd1 O3W 2.699(8) .
Nd1 O16 2.914(5) .
Nd2 O12 2.338(5) 4_576
Nd2 O29 2.448(5) .
Nd2 O4 2.470(5) .
Nd2 O27 2.505(5) .
Nd2 O10 2.525(5) 3_677
Nd2 O6W 2.550(5) .
Nd2 O26 2.565(4) .
Nd2 N3 2.586(6) .
Nd2 N1 2.751(6) .
Nd2 Nd4 4.0079(10) .
Nd3 O23 2.367(4) 3_677
Nd3 O19 2.367(4) .
Nd3 O20 2.376(4) .
Nd3 O22 2.382(4) 3_677
Nd3 O7 2.441(5) 3_677
Nd3 O1 2.464(5) .
Nd3 O25 2.594(5) .
Nd3 O4W 2.693(6) .
Nd3 Nd4 3.8143(10) .
Nd3 Nd5 3.9236(10) 3_677
Nd4 O24 2.324(4) 3_677
Nd4 O21 2.330(4) .
Nd4 O20 2.333(4) .
Nd4 O23 2.341(4) 3_677
Nd4 O27 2.474(5) .
Nd4 O3 2.486(4) .
Nd4 O26 2.490(4) .
Nd4 O9 2.523(4) 3_677
Nd4 Nd5 3.8011(12) .
Nd5 O21 2.370(4) .
Nd5 O19 2.375(4) 3_677
Nd5 O22 2.380(4) .
Nd5 O24 2.393(4) 3_677
Nd5 O5 2.482(5) .
Nd5 O11 2.513(4) 3_677
Nd5 O5W 2.550(5) .
Nd5 O28 2.657(5) .
O1 C3 1.275(9) .
O2 C3 1.31(4) .
O2' C3 1.20(4) .
O3 C6 1.268(8) .
O4 C6 1.256(8) .
O5 C9 1.259(8) .
O6 C9 1.246(8) .
O7 C12 1.245(9) .
O8 C12 1.270(9) .
O9 C15 1.243(8) .
O10 C15 1.262(8) .
O11 C18 1.265(8) .
O12 C18 1.252(8) .
O25 C19 1.252(8) .
O26 C19 1.265(8) .
O27 C30 1.273(8) .
O28 C30 1.242(8) .
O29 C24 1.280(9) .
O30 C24 1.25(3) .
O30' C24 1.27(3) .
N1 C20 1.327(9) .
N1 C23 1.345(9) .
N2 C22 1.320(12) .
N2 C21 1.340(10) .
N3 C29 1.335(8) .
N3 C25 1.351(8) .
C1 C2 1.544(11) .
C1 H1A 0.9700 .
C1 H1B 0.9700 .
C2 C3 1.503(11) .
C2 H2A 0.9700 .
C2 H2B 0.9700 .
C4 C5 1.518(10) .
C4 H4A 0.9700 .
C4 H4B 0.9700 .
C5 C6 1.505(10) .
C5 H5A 0.9700 .
C5 H5B 0.9700 .
C7 C8 1.509(10) .
C7 H7A 0.9700 .
C7 H7B 0.9700 .
C8 C9 1.548(10) .
C8 H8A 0.9700 .
C8 H8B 0.9700 .
C10 C11 1.501(13) .
C10 H10A 0.9700 .
C10 H10B 0.9700 .
C11 C12 1.446(13) .
C11 H11A 0.9700 .
C11 H11B 0.9700 .
C13 C14 1.516(10) .
C13 H13A 0.9700 .
C13 H13B 0.9700 .
C14 C15 1.542(10) .
C14 H14A 0.9700 .
C14 H14B 0.9700 .
C16 C17 1.546(10) .
C16 H16A 0.9700 .
C16 H16B 0.9700 .
C17 C18 1.520(9) .
C17 H17A 0.9700 .
C17 H17B 0.9700 .
C19 C20 1.494(9) .
C20 C21 1.387(10) .
C21 H21 0.9300 .
C22 C23 1.356(12) .
C22 H22 0.9300 .
C23 H23 0.9300 .
C24 C25 1.500(10) .
C25 C26 1.398(10) .
C26 C27 1.383(11) .
C26 H26 0.9300 .
C27 C28 1.374(10) .
C27 H27 0.9300 .
C28 C29 1.375(10) .
C28 H28 0.9300 .
C29 C30 1.505(9) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O24 Ge6 O13 Ge1 -30.1(4) . .
O18 Ge6 O13 Ge1 -136.0(3) . .
C16 Ge6 O13 Ge1 116.0(3) . .
Nd1 Ge6 O13 Ge1 -124.3(4) . .
O24 Ge6 O13 Nd1 94.2(2) . .
O18 Ge6 O13 Nd1 -11.62(18) . .
C16 Ge6 O13 Nd1 -119.7(2) . .
O19 Ge1 O13 Ge6 21.4(4) . .
O14 Ge1 O13 Ge6 137.9(3) . .
C1 Ge1 O13 Ge6 -105.3(4) . .
Nd3 Ge1 O13 Ge6 47.6(4) . .
O19 Ge1 O13 Nd1 -101.8(2) . .
O14 Ge1 O13 Nd1 14.7(2) . .
C1 Ge1 O13 Nd1 131.6(3) . .
Nd3 Ge1 O13 Nd1 -75.6(2) . .
O19 Ge1 O14 Ge2 -27.7(4) . .
O13 Ge1 O14 Ge2 -137.6(4) . .
C1 Ge1 O14 Ge2 109.4(4) . .
Nd3 Ge1 O14 Ge2 0.7(3) . .
O19 Ge1 O14 Nd1 95.5(2) . .
O13 Ge1 O14 Nd1 -14.37(19) . .
C1 Ge1 O14 Nd1 -127.4(3) . .
Nd3 Ge1 O14 Nd1 123.91(14) . .
O20 Ge2 O14 Ge1 22.2(4) . .
O15 Ge2 O14 Ge1 135.4(3) . .
C4 Ge2 O14 Ge1 -109.4(4) . .
Nd1 Ge2 O14 Ge1 124.2(4) . .
Nd4 Ge2 O14 Ge1 43.5(4) . .
O20 Ge2 O14 Nd1 -102.1(2) . .
O15 Ge2 O14 Nd1 11.14(19) . .
C4 Ge2 O14 Nd1 126.4(3) . .
Nd4 Ge2 O14 Nd1 -80.7(2) . .
O21 Ge3 O15 Ge2 37.0(3) . .
O16 Ge3 O15 Ge2 149.6(3) . .
C7 Ge3 O15 Ge2 -94.2(4) . .
O21 Ge3 O15 Nd1 -94.2(2) . .
O16 Ge3 O15 Nd1 18.5(2) . .
C7 Ge3 O15 Nd1 134.6(3) . .
O20 Ge2 O15 Ge3 -40.6(3) . .
O14 Ge2 O15 Ge3 -144.6(3) . .
C4 Ge2 O15 Ge3 104.6(3) . .
Nd1 Ge2 O15 Ge3 -132.8(4) . .
Nd4 Ge2 O15 Ge3 -10.8(3) . .
O20 Ge2 O15 Nd1 92.2(2) . .
O14 Ge2 O15 Nd1 -11.8(2) . .
C4 Ge2 O15 Nd1 -122.6(3) . .
Nd4 Ge2 O15 Nd1 122.06(14) . .
O21 Ge3 O16 Ge4 -16.8(4) . .
O15 Ge3 O16 Ge4 -125.7(4) . .
C7 Ge3 O16 Ge4 112.6(4) . .
O21 Ge3 O16 Nd1 93.83(19) . .
O15 Ge3 O16 Nd1 -15.07(17) . .
C7 Ge3 O16 Nd1 -136.7(2) . .
O22 Ge4 O16 Ge3 5.5(4) . .
O17 Ge4 O16 Ge3 123.7(4) . .
C10 Ge4 O16 Ge3 -122.3(4) . .
O22 Ge4 O16 Nd1 -103.87(19) . .
O17 Ge4 O16 Nd1 14.42(18) . .
C10 Ge4 O16 Nd1 128.4(3) . .
O22 Ge4 O17 Ge5 -29.2(4) . .
O16 Ge4 O17 Ge5 -142.4(3) . .
C10 Ge4 O17 Ge5 104.9(4) . .
O22 Ge4 O17 Nd1 96.9(2) . .
O16 Ge4 O17 Nd1 -16.3(2) . .
C10 Ge4 O17 Nd1 -129.0(3) . .
O23 Ge5 O17 Ge4 25.5(4) . .
O18 Ge5 O17 Ge4 140.1(3) . .
C13 Ge5 O17 Ge4 -106.0(4) . .
O23 Ge5 O17 Nd1 -103.22(19) . .
O18 Ge5 O17 Nd1 11.29(18) . .
C13 Ge5 O17 Nd1 125.3(3) . .
O23 Ge5 O18 Ge6 -37.2(4) . .
O17 Ge5 O18 Ge6 -143.1(3) . .
C13 Ge5 O18 Ge6 106.1(4) . .
O23 Ge5 O18 Nd1 93.3(2) . .
O17 Ge5 O18 Nd1 -12.5(2) . .
C13 Ge5 O18 Nd1 -123.4(3) . .
O24 Ge6 O18 Ge5 30.7(4) . .
O13 Ge6 O18 Ge5 143.8(3) . .
C16 Ge6 O18 Ge5 -103.1(4) . .
Nd1 Ge6 O18 Ge5 131.7(4) . .
O24 Ge6 O18 Nd1 -101.0(2) . .
O13 Ge6 O18 Nd1 12.13(19) . .
C16 Ge6 O18 Nd1 125.2(3) . .
O14 Ge1 O19 Nd3 53.3(3) . .
O13 Ge1 O19 Nd3 150.4(2) . .
C1 Ge1 O19 Nd3 -84.5(3) . .
O14 Ge1 O19 Nd5 -144.5(3) . 3_677
O13 Ge1 O19 Nd5 -47.5(3) . 3_677
C1 Ge1 O19 Nd5 77.7(4) . 3_677
Nd3 Ge1 O19 Nd5 162.2(4) . 3_677
O14 Ge2 O20 Nd4 153.4(2) . .
O15 Ge2 O20 Nd4 58.0(3) . .
C4 Ge2 O20 Nd4 -83.7(4) . .
Nd1 Ge2 O20 Nd4 104.6(2) . .
O14 Ge2 O20 Nd3 -52.3(3) . .
O15 Ge2 O20 Nd3 -147.6(3) . .
C4 Ge2 O20 Nd3 70.6(4) . .
Nd1 Ge2 O20 Nd3 -101.1(3) . .
Nd4 Ge2 O20 Nd3 154.3(5) . .
O16 Ge3 O21 Nd4 -156.4(2) . .
O15 Ge3 O21 Nd4 -57.3(3) . .
C7 Ge3 O21 Nd4 75.8(3) . .
O16 Ge3 O21 Nd5 58.0(3) . .
O15 Ge3 O21 Nd5 157.0(2) . .
C7 Ge3 O21 Nd5 -69.9(3) . .
O17 Ge4 O22 Nd5 -139.5(3) . .
O16 Ge4 O22 Nd5 -36.7(3) . .
C10 Ge4 O22 Nd5 88.1(4) . .
O17 Ge4 O22 Nd3 50.0(3) . 3_677
O16 Ge4 O22 Nd3 152.8(2) . 3_677
C10 Ge4 O22 Nd3 -82.4(4) . 3_677
O17 Ge5 O23 Nd4 150.3(2) . 3_677
O18 Ge5 O23 Nd4 54.6(3) . 3_677
C13 Ge5 O23 Nd4 -85.3(3) . 3_677
O17 Ge5 O23 Nd3 -52.1(3) . 3_677
O18 Ge5 O23 Nd3 -147.8(3) . 3_677
C13 Ge5 O23 Nd3 72.3(4) . 3_677
O13 Ge6 O24 Nd4 -145.9(3) . 3_677
O18 Ge6 O24 Nd4 -50.6(3) . 3_677
C16 Ge6 O24 Nd4 72.7(4) . 3_677
Nd1 Ge6 O24 Nd4 -96.4(3) . 3_677
O13 Ge6 O24 Nd5 59.7(3) . 3_677
O18 Ge6 O24 Nd5 154.9(2) . 3_677
C16 Ge6 O24 Nd5 -81.7(3) . 3_677
Nd1 Ge6 O24 Nd5 109.1(2) . 3_677
Ge1 C1 C2 C3 -42.2(10) . .
Nd3 O1 C3 O2' 61(2) . .
Nd3 O1 C3 O2 84(2) . .
Nd3 O1 C3 C2 -108.7(14) . .
C1 C2 C3 O2' -155.3(15) . .
C1 C2 C3 O1 15.7(12) . .
C1 C2 C3 O2 -177.0(15) . .
Ge2 C4 C5 C6 -40.5(8) . .
Nd2 O4 C6 O3 -26.2(10) . .
Nd2 O4 C6 C5 155.2(5) . .
Nd4 O3 C6 O4 47.8(10) . .
Nd4 O3 C6 C5 -133.6(6) . .
C4 C5 C6 O4 -138.5(7) . .
C4 C5 C6 O3 42.8(9) . .
Ge3 C7 C8 C9 -54.9(7) . .
C7 C8 C9 O6 -174.8(6) . .
C7 C8 C9 O5 4.4(10) . .
Ge4 C10 C11 C12 -44.0(14) . .
Nd3 O7 C12 O8 81.2(13) 3_677 .
Nd3 O7 C12 C11 -111.7(10) 3_677 .
Nd1 O8 C12 O7 -162.8(6) 2_556 .
Nd1 O8 C12 C11 30.3(14) 2_556 .
C10 C11 C12 O7 39.0(16) . .
C10 C11 C12 O8 -153.2(10) . .
Ge5 C13 C14 C15 -39.3(8) . .
Nd4 O9 C15 O10 50.8(11) 3_677 .
Nd4 O9 C15 C14 -130.5(6) 3_677 .
Nd2 O10 C15 O9 -36.1(10) 3_677 .
Nd2 O10 C15 C14 145.3(5) 3_677 .
C13 C14 C15 O9 35.6(10) . .
C13 C14 C15 O10 -145.6(7) . .
Ge6 C16 C17 C18 -46.8(8) . .
Nd2 O12 C18 O11 122.6(8) 4_675 .
Nd2 O12 C18 C17 -57.9(13) 4_675 .
Nd5 O11 C18 O12 45.1(12) 3_677 .
Nd5 O11 C18 C17 -134.4(7) 3_677 .
C16 C17 C18 O12 -141.5(7) . .
C16 C17 C18 O11 38.0(9) . .
Nd3 O25 C19 O26 34.8(11) . .
Nd3 O25 C19 C20 -143.9(5) . .
Nd4 O26 C19 O25 -31.4(9) . .
Nd2 O26 C19 O25 168.2(5) . .
Nd4 O26 C19 C20 147.3(5) . .
Nd2 O26 C19 C20 -13.0(8) . .
C23 N1 C20 C21 -3.5(11) . .
Nd2 N1 C20 C21 169.5(6) . .
C23 N1 C20 C19 -179.8(7) . .
Nd2 N1 C20 C19 -6.8(8) . .
O25 C19 C20 N1 -169.0(6) . .
O26 C19 C20 N1 12.1(9) . .
O25 C19 C20 C21 14.6(11) . .
O26 C19 C20 C21 -164.2(7) . .
C22 N2 C21 C20 0.6(15) . .
N1 C20 C21 N2 0.5(13) . .
C19 C20 C21 N2 176.6(8) . .
C21 N2 C22 C23 1.6(17) . .
C20 N1 C23 C22 5.6(13) . .
Nd2 N1 C23 C22 -167.0(8) . .
N2 C22 C23 N1 -4.9(17) . .
Nd2 O29 C24 O30 166.2(11) . .
Nd2 O29 C24 O30' -167.6(14) . .
Nd2 O29 C24 C25 -2.8(10) . .
C29 N3 C25 C26 1.9(11) . .
Nd2 N3 C25 C26 179.6(6) . .
C29 N3 C25 C24 -180.0(7) . .
Nd2 N3 C25 C24 -2.4(9) . .
O30 C24 C25 N3 -165.6(11) . .
O30' C24 C25 N3 170.0(13) . .
O29 C24 C25 N3 3.3(11) . .
O30 C24 C25 C26 12.4(16) . .
O30' C24 C25 C26 -12.0(17) . .
O29 C24 C25 C26 -178.7(8) . .
N3 C25 C26 C27 -3.0(12) . .
C24 C25 C26 C27 179.1(8) . .
C25 C26 C27 C28 2.6(13) . .
C26 C27 C28 C29 -1.2(13) . .
C25 N3 C29 C28 -0.4(11) . .
Nd2 N3 C29 C28 -178.0(5) . .
C25 N3 C29 C30 176.6(6) . .
Nd2 N3 C29 C30 -0.9(8) . .
C27 C28 C29 N3 0.1(12) . .
C27 C28 C29 C30 -176.8(7) . .
Nd5 O28 C30 O27 -32.7(11) . .
Nd5 O28 C30 C29 146.5(5) . .
Nd4 O27 C30 O28 37.9(9) . .
Nd2 O27 C30 O28 -172.7(5) . .
Nd4 O27 C30 C29 -141.2(5) . .
Nd2 O27 C30 C29 8.1(8) . .
N3 C29 C30 O28 176.5(6) . .
C28 C29 C30 O28 -6.5(10) . .
N3 C29 C30 O27 -4.3(9) . .
C28 C29 C30 O27 172.7(7) . .
