#------------------------------------------------------------------------------
#$Date: 2016-03-24 01:32:20 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179534 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/03/4500374.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4500374
loop_
_publ_author_name
'Wan, Chong-Qing'
'Mak, Thomas C. W.'
_publ_section_title
;
 Unusual Carbonyl···Carbonyl Interaction in
 Supramolecular Structures of Silver(I) Complexes with
 2,6-Pyridinediylbis(4-pyridinyl)methanone
;
_journal_issue                   3
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              832
_journal_paper_doi               10.1021/cg101490a
_journal_volume                  11
_journal_year                    2011
_chemical_formula_sum            'C34 H24 Ag3 N9 O11'
_chemical_formula_weight         1058.23
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           4
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 91.677(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   6.8745(15)
_cell_length_b                   10.444(2)
_cell_length_c                   25.018(5)
_cell_measurement_temperature    293(2)
_cell_volume                     1795.5(6)
_computing_cell_refinement       'bruker Smart'
_computing_data_collection       'bruker Smart'
_computing_data_reduction        'bruker Saint'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0260
_diffrn_reflns_av_sigmaI/netI    0.0518
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -7
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            12525
_diffrn_reflns_theta_full        28.28
_diffrn_reflns_theta_max         28.28
_diffrn_reflns_theta_min         0.81
_exptl_absorpt_coefficient_mu    1.695
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_correction_T_min  0.776479
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.957
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1040
_exptl_crystal_size_max          0.45
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.29
_refine_diff_density_max         0.643
_refine_diff_density_min         -1.002
_refine_diff_density_rms         0.086
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.03(3)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.085
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     541
_refine_ls_number_reflns         8468
_refine_ls_number_restraints     114
_refine_ls_restrained_S_all      1.097
_refine_ls_R_factor_all          0.0658
_refine_ls_R_factor_gt           0.0434
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0235P)²+1.3541P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0854
_refine_ls_wR_factor_ref         0.0964
_reflns_number_gt                6286
_reflns_number_total             8468
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg101490a_si_001.cif
_cod_data_source_block           compound3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'MOnoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      P21
_cod_database_code               4500374
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.56579(9) 0.14372(4) 0.738495(19) 0.05817(16) Uani 1 1 d . . .
Ag2 Ag -0.01903(9) 0.57215(5) 0.762519(19) 0.06162(17) Uani 1 1 d . . .
Ag3 Ag 0.27559(8) 0.35750(9) 0.75025(3) 0.06568(15) Uani 1 1 d . . .
C1 C 0.3703(8) 0.0923(7) 0.6242(2) 0.0427(15) Uani 1 1 d . . .
H1A H 0.3306 0.0186 0.6417 0.051 Uiso 1 1 calc R . .
C2 C 0.3386(8) 0.1010(6) 0.5695(2) 0.0403(15) Uani 1 1 d . . .
H2A H 0.2841 0.0325 0.5506 0.048 Uiso 1 1 calc R . .
C3 C 0.3884(8) 0.2122(6) 0.5429(2) 0.0335(13) Uani 1 1 d . . .
C4 C 0.4773(8) 0.3090(6) 0.5724(2) 0.0358(13) Uani 1 1 d . . .
H4A H 0.5146 0.3847 0.5561 0.043 Uiso 1 1 calc R . .
C5 C 0.5094(8) 0.2907(7) 0.6269(2) 0.0405(14) Uani 1 1 d . . .
H5A H 0.5719 0.3553 0.6463 0.049 Uiso 1 1 calc R . .
N1 N 0.4556(7) 0.1855(5) 0.6530(2) 0.0420(12) Uani 1 1 d . . .
C6 C 0.3564(8) 0.2178(6) 0.4834(2) 0.0378(14) Uani 1 1 d . . .
O1 O 0.3822(7) 0.1224(5) 0.45618(17) 0.0553(13) Uani 1 1 d . . .
C7 C 0.2846(8) 0.3384(7) 0.4582(2) 0.0389(14) Uani 1 1 d . . .
C8 C 0.2563(8) 0.3488(8) 0.4028(2) 0.0430(14) Uani 1 1 d . . .
H8A H 0.2850 0.2805 0.3805 0.052 Uiso 1 1 calc R . .
C9 C 0.1848(9) 0.4627(7) 0.3816(3) 0.0515(19) Uani 1 1 d . . .
H9A H 0.1640 0.4723 0.3449 0.062 Uiso 1 1 calc R . .
C10 C 0.1448(8) 0.5623(8) 0.4166(2) 0.0449(15) Uani 1 1 d . . .
H10A H 0.0973 0.6401 0.4037 0.054 Uiso 1 1 calc R . .
C11 C 0.1766(8) 0.5439(6) 0.4708(2) 0.0401(15) Uani 1 1 d . . .
N2 N 0.2425(6) 0.4333(5) 0.49163(18) 0.0352(11) Uani 1 1 d . . .
O2 O 0.1436(8) 0.7611(5) 0.4968(2) 0.0663(16) Uani 1 1 d . . .
C12 C 0.1486(8) 0.6488(7) 0.5106(2) 0.0427(14) Uani 1 1 d . . .
C13 C 0.1282(8) 0.6161(6) 0.5685(2) 0.0372(14) Uani 1 1 d . . .
C14 C 0.2142(10) 0.6943(7) 0.6071(3) 0.0546(18) Uani 1 1 d . A .
H14A H 0.2902 0.7635 0.5972 0.066 Uiso 1 1 calc R . .
C15 C 0.1861(10) 0.6688(8) 0.6605(3) 0.0578(19) Uani 1 1 d . . .
H15A H 0.2503 0.7193 0.6861 0.069 Uiso 1 1 calc R A .
C16 C -0.0110(9) 0.4965(7) 0.6395(2) 0.0466(16) Uani 1 1 d . . .
H16A H -0.0882 0.4289 0.6506 0.056 Uiso 1 1 calc R A .
C17 C 0.0168(8) 0.5140(7) 0.5856(2) 0.0422(15) Uani 1 1 d . A .
H17A H -0.0389 0.4575 0.5608 0.051 Uiso 1 1 calc R . .
N3 N 0.0713(7) 0.5752(7) 0.67689(19) 0.0509(13) Uani 1 1 d . A .
O3 O 0.3533(7) -0.0382(5) 1.0026(2) 0.0629(15) Uani 1 1 d . . .
C18 C 0.5169(9) 0.2318(7) 0.8635(2) 0.0446(15) Uani 1 1 d . . .
H18A H 0.5983 0.2986 0.8540 0.054 Uiso 1 1 calc R . .
C19 C 0.4885(8) 0.2120(6) 0.9172(2) 0.0384(14) Uani 1 1 d . . .
H19A H 0.5452 0.2661 0.9427 0.046 Uiso 1 1 calc R . .
C20 C 0.3758(8) 0.1114(5) 0.9321(2) 0.0377(14) Uani 1 1 d . . .
C21 C 0.2908(10) 0.0365(7) 0.8920(3) 0.0536(19) Uani 1 1 d . . .
H21A H 0.2149 -0.0340 0.9005 0.064 Uiso 1 1 calc R . .
C22 C 0.3204(10) 0.0680(10) 0.8401(3) 0.066(2) Uani 1 1 d . . .
H22A H 0.2556 0.0205 0.8136 0.079 Uiso 1 1 calc R . .
N4 N 0.4361(8) 0.1622(6) 0.8248(2) 0.0536(15) Uani 1 1 d . . .
C23 C 0.3525(8) 0.0730(7) 0.9896(2) 0.0409(13) Uani 1 1 d . . .
C24 C 0.3215(8) 0.1769(6) 1.0300(2) 0.0379(15) Uani 1 1 d . . .
C25 C 0.3519(8) 0.1578(8) 1.0843(2) 0.0458(16) Uani 1 1 d . . .
H25A H 0.3978 0.0795 1.0971 0.055 Uiso 1 1 calc R . .
C26 C 0.3141(9) 0.2546(7) 1.1190(2) 0.0474(18) Uani 1 1 d . . .
H26A H 0.3373 0.2438 1.1555 0.057 Uiso 1 1 calc R . .
C27 C 0.2415(8) 0.3684(8) 1.0994(2) 0.0468(16) Uani 1 1 d . . .
H27A H 0.2114 0.4352 1.1223 0.056 Uiso 1 1 calc R . .
C28 C 0.2140(7) 0.3812(6) 1.0437(2) 0.0347(13) Uani 1 1 d . . .
N5 N 0.2561(6) 0.2874(5) 1.00949(18) 0.0354(11) Uani 1 1 d . . .
C29 C 0.1418(8) 0.5029(7) 1.0188(2) 0.0373(13) Uani 1 1 d . A .
O4 O 0.1113(6) 0.5965(5) 1.04616(16) 0.0508(12) Uani 1 1 d . . .
C30 C 0.1367(8) 0.6318(7) 0.8793(2) 0.0423(14) Uani 1 1 d . . .
H30A H 0.1758 0.7066 0.8625 0.051 Uiso 1 1 calc R A .
C31 C 0.1638(8) 0.6236(6) 0.9337(2) 0.0366(14) Uani 1 1 d . A .
H31A H 0.2148 0.6923 0.9531 0.044 Uiso 1 1 calc R . .
C32 C 0.1134(7) 0.5104(6) 0.9593(2) 0.0334(13) Uani 1 1 d . . .
C33 C 0.0325(8) 0.4136(7) 0.9275(2) 0.0392(14) Uani 1 1 d . A .
H33A H -0.0038 0.3364 0.9428 0.047 Uiso 1 1 calc R . .
C34 C 0.0067(8) 0.4326(6) 0.8739(2) 0.0406(14) Uani 1 1 d . . .
H34A H -0.0500 0.3673 0.8535 0.049 Uiso 1 1 calc R A .
N6 N 0.0587(7) 0.5401(5) 0.84901(18) 0.0395(12) Uani 1 1 d . A .
N7' N -0.100(2) 0.2119(15) 0.7341(6) 0.063(3) Uani 0.50 1 d PU . 1
N7 N 0.009(2) 0.2469(14) 0.7366(4) 0.063(3) Uani 0.50 1 d PDU . 2
O5 O -0.0695(15) 0.2580(11) 0.7714(4) 0.136(3) Uani 1 1 d DU . .
O6 O -0.0073(12) 0.2052(9) 0.6986(3) 0.120(3) Uani 1 1 d DU . .
N8 N -0.3790(15) 0.5210(9) 0.7632(4) 0.055(3) Uani 0.74(2) 1 d PU A 1
N8' N -0.477(6) 0.467(4) 0.7588(12) 0.073(6) Uani 0.26(2) 1 d PU . 2
O7 O -0.4286(12) 0.4773(10) 0.7218(3) 0.116(3) Uani 1 1 d U . .
O8 O -0.4705(10) 0.5078(7) 0.8016(2) 0.093(2) Uani 1 1 d U . .
N9 N 0.5437(11) -0.1455(6) 0.7418(3) 0.076(2) Uani 1 1 d . . .
O9 O 0.6876(8) -0.0758(5) 0.7506(2) 0.0806(16) Uani 1 1 d . . .
O10 O 0.3894(9) -0.0901(6) 0.7301(2) 0.0716(15) Uani 1 1 d . . .
O1W O 0.0376(9) 0.8132(6) 0.7774(2) 0.0681(15) Uani 1 1 d D A .
H1WA H 0.134(8) 0.848(8) 0.760(3) 0.08(3) Uiso 1 1 d D . .
H1WB H -0.073(11) 0.855(12) 0.770(5) 0.20(8) Uiso 1 1 d D . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ag1 N4 135.5(2) . .
N1 Ag1 N7' 101.0(4) . 1_655
N4 Ag1 N7' 113.8(4) . 1_655
N1 Ag1 O9 113.3(2) . .
N4 Ag1 O9 95.7(2) . .
N7' Ag1 O9 87.7(4) 1_655 .
N1 Ag1 Ag3 75.42(14) . .
N4 Ag1 Ag3 65.34(16) . .
N7' Ag1 Ag3 114.8(4) 1_655 .
O9 Ag1 Ag3 154.63(14) . .
N6 Ag2 N3 149.15(19) . .
N6 Ag2 N8 99.6(3) . .
N3 Ag2 N8 107.9(3) . .
N6 Ag2 O1W 88.58(19) . .
N3 Ag2 O1W 94.6(2) . .
N8 Ag2 O1W 110.4(2) . .
N6 Ag2 Ag3 81.18(13) . .
N3 Ag2 Ag3 73.21(17) . .
N8 Ag2 Ag3 119.9(2) . .
O1W Ag2 Ag3 129.58(15) . .
N7 Ag3 O7 154.5(3) . 1_655
N7 Ag3 N8' 176.5(10) . 1_655
O7 Ag3 N8' 22.6(8) 1_655 1_655
N7 Ag3 Ag1 98.5(4) . .
O7 Ag3 Ag1 78.3(2) 1_655 .
N8' Ag3 Ag1 82.9(9) 1_655 .
N7 Ag3 Ag2 81.2(4) . .
O7 Ag3 Ag2 102.0(2) 1_655 .
N8' Ag3 Ag2 97.4(10) 1_655 .
Ag1 Ag3 Ag2 179.63(4) . .
N1 C1 C2 122.7(6) . .
N1 C1 H1A 118.7 . .
C2 C1 H1A 118.7 . .
C1 C2 C3 119.7(5) . .
C1 C2 H2A 120.2 . .
C3 C2 H2A 120.2 . .
C4 C3 C2 118.0(5) . .
C4 C3 C6 123.4(5) . .
C2 C3 C6 118.5(5) . .
C3 C4 C5 118.6(6) . .
C3 C4 H4A 120.7 . .
C5 C4 H4A 120.7 . .
N1 C5 C4 123.7(6) . .
N1 C5 H5A 118.1 . .
C4 C5 H5A 118.1 . .
C1 N1 C5 117.3(5) . .
C1 N1 Ag1 119.5(4) . .
C5 N1 Ag1 121.6(4) . .
O1 C6 C7 120.4(5) . .
O1 C6 C3 120.1(6) . .
C7 C6 C3 119.4(5) . .
N2 C7 C8 122.5(6) . .
N2 C7 C6 116.1(5) . .
C8 C7 C6 121.4(6) . .
C9 C8 C7 118.9(7) . .
C9 C8 H8A 120.5 . .
C7 C8 H8A 120.5 . .
C8 C9 C10 118.4(6) . .
C8 C9 H9A 120.8 . .
C10 C9 H9A 120.8 . .
C11 C10 C9 119.0(6) . .
C11 C10 H10A 120.5 . .
C9 C10 H10A 120.5 . .
N2 C11 C10 123.0(6) . .
N2 C11 C12 114.9(5) . .
C10 C11 C12 122.1(6) . .
C7 N2 C11 118.2(5) . .
O2 C12 C13 119.2(6) . .
O2 C12 C11 121.2(6) . .
C13 C12 C11 119.6(6) . .
C14 C13 C17 117.8(6) . .
C14 C13 C12 119.4(6) . .
C17 C13 C12 122.7(6) . .
C15 C14 C13 119.5(6) . .
C15 C14 H14A 120.2 . .
C13 C14 H14A 120.2 . .
N3 C15 C14 122.8(6) . .
N3 C15 H15A 118.6 . .
C14 C15 H15A 118.6 . .
N3 C16 C17 121.8(6) . .
N3 C16 H16A 119.1 . .
C17 C16 H16A 119.1 . .
C16 C17 C13 119.7(6) . .
C16 C17 H17A 120.1 . .
C13 C17 H17A 120.1 . .
C15 N3 C16 118.2(5) . .
C15 N3 Ag2 119.2(5) . .
C16 N3 Ag2 121.8(4) . .
N4 C18 C19 124.3(6) . .
N4 C18 H18A 117.8 . .
C19 C18 H18A 117.8 . .
C20 C19 C18 118.7(6) . .
C20 C19 H19A 120.7 . .
C18 C19 H19A 120.7 . .
C19 C20 C21 117.9(6) . .
C19 C20 C23 122.9(6) . .
C21 C20 C23 119.0(6) . .
C22 C21 C20 118.8(7) . .
C22 C21 H21A 120.6 . .
C20 C21 H21A 120.6 . .
N4 C22 C21 124.1(6) . .
N4 C22 H22A 117.9 . .
C21 C22 H22A 117.9 . .
C18 N4 C22 116.0(6) . .
C18 N4 Ag1 123.6(4) . .
C22 N4 Ag1 116.5(5) . .
O3 C23 C24 121.0(6) . .
O3 C23 C20 120.9(6) . .
C24 C23 C20 118.1(6) . .
N5 C24 C25 122.7(6) . .
N5 C24 C23 114.8(5) . .
C25 C24 C23 122.4(6) . .
C26 C25 C24 119.5(6) . .
C26 C25 H25A 120.3 . .
C24 C25 H25A 120.3 . .
C25 C26 C27 119.3(6) . .
C25 C26 H26A 120.3 . .
C27 C26 H26A 120.3 . .
C26 C27 C28 118.2(7) . .
C26 C27 H27A 120.9 . .
C28 C27 H27A 120.9 . .
N5 C28 C27 122.6(6) . .
N5 C28 C29 115.6(5) . .
C27 C28 C29 121.8(6) . .
C24 N5 C28 117.7(5) . .
O4 C29 C28 120.7(5) . .
O4 C29 C32 119.8(6) . .
C28 C29 C32 119.4(5) . .
N6 C30 C31 124.3(6) . .
N6 C30 H30A 117.9 . .
C31 C30 H30A 117.9 . .
C30 C31 C32 118.8(6) . .
C30 C31 H31A 120.6 . .
C32 C31 H31A 120.6 . .
C31 C32 C33 116.9(5) . .
C31 C32 C29 118.4(5) . .
C33 C32 C29 124.6(6) . .
C34 C33 C32 119.8(6) . .
C34 C33 H33A 120.1 . .
C32 C33 H33A 120.1 . .
N6 C34 C33 123.4(6) . .
N6 C34 H34A 118.3 . .
C33 C34 H34A 118.3 . .
C30 N6 C34 116.8(5) . .
C30 N6 Ag2 121.7(4) . .
C34 N6 Ag2 121.1(4) . .
O5 N7' O6 128.6(17) . .
O5 N7' Ag1 104.9(11) . 1_455
O6 N7' Ag1 126.2(11) . 1_455
O5 N7 O6 139(2) . .
O5 N7 Ag3 105.2(12) . .
O6 N7 Ag3 115.4(11) . .
N7' O5 N7 46.7(9) . .
N7 O6 N7' 45.5(9) . .
O7 N8 O8 121.9(11) . .
O7 N8 Ag2 109.5(8) . .
O8 N8 Ag2 125.4(8) . .
O7 N8' O8 145(5) . .
O7 N8' Ag3 105(3) . 1_455
O8 N8' Ag3 108(3) . 1_455
N8' O7 N8 47(2) . .
N8' O7 Ag3 52(3) . 1_455
N8 O7 Ag3 99.2(7) . 1_455
N8' O8 N8 45(2) . .
O10 N9 O9 116.1(7) . .
N9 O9 Ag1 105.0(5) . .
Ag2 O1W H1WA 116(6) . .
Ag2 O1W H1WB 109(10) . .
H1WA O1W H1WB 110(10) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.290(5) .
Ag1 N4 2.367(5) .
Ag1 N7' 2.409(14) 1_655
Ag1 O9 2.457(5) .
Ag1 Ag3 3.0143(11) .
Ag2 N6 2.239(5) .
Ag2 N3 2.248(5) .
Ag2 N8 2.533(11) .
Ag2 O1W 2.573(6) .
Ag2 Ag3 3.0429(11) .
Ag3 N7 2.185(18) .
Ag3 O7 2.508(9) 1_655
Ag3 N8' 2.06(5) 1_655
C1 N1 1.336(8) .
C1 C2 1.384(8) .
C1 H1A 0.9300 .
C2 C3 1.385(8) .
C2 H2A 0.9300 .
C3 C4 1.383(8) .
C3 C6 1.501(8) .
C4 C5 1.388(8) .
C4 H4A 0.9300 .
C5 N1 1.335(8) .
C5 H5A 0.9300 .
C6 O1 1.221(7) .
C6 C7 1.486(9) .
C7 N2 1.334(8) .
C7 C8 1.398(8) .
C8 C9 1.386(10) .
C8 H8A 0.9300 .
C9 C10 1.393(10) .
C9 H9A 0.9300 .
C10 C11 1.380(8) .
C10 H10A 0.9300 .
C11 N2 1.340(8) .
C11 C12 1.497(9) .
O2 C12 1.223(8) .
C12 C13 1.499(8) .
C13 C14 1.384(9) .
C13 C17 1.388(8) .
C14 C15 1.381(10) .
C14 H14A 0.9300 .
C15 N3 1.329(9) .
C15 H15A 0.9300 .
C16 N3 1.355(8) .
C16 C17 1.381(8) .
C16 H16A 0.9300 .
C17 H17A 0.9300 .
O3 C23 1.206(8) .
C18 N4 1.321(8) .
C18 C19 1.377(8) .
C18 H18A 0.9300 .
C19 C20 1.363(8) .
C19 H19A 0.9300 .
C20 C21 1.387(9) .
C20 C23 1.508(8) .
C21 C22 1.362(9) .
C21 H21A 0.9300 .
C22 N4 1.328(10) .
C22 H22A 0.9300 .
C23 C24 1.501(9) .
C24 N5 1.335(8) .
C24 C25 1.385(8) .
C25 C26 1.361(9) .
C25 H25A 0.9300 .
C26 C27 1.374(10) .
C26 H26A 0.9300 .
C27 C28 1.407(7) .
C27 H27A 0.9300 .
C28 N5 1.338(8) .
C28 C29 1.493(9) .
C29 O4 1.216(8) .
C29 C32 1.497(8) .
C30 N6 1.324(8) .
C30 C31 1.371(8) .
C30 H30A 0.9300 .
C31 C32 1.393(9) .
C31 H31A 0.9300 .
C32 C33 1.393(9) .
C33 C34 1.362(8) .
C33 H33A 0.9300 .
C34 N6 1.338(8) .
C34 H34A 0.9300 .
N7' O5 1.067(14) .
N7' O6 1.110(15) .
N7' Ag1 2.409(14) 1_455
N7 O5 1.044(9) .
N7 O6 1.048(9) .
N8 O7 1.174(11) .
N8 O8 1.170(11) .
N8' O7 1.00(3) .
N8' O8 1.15(3) .
N8' Ag3 2.06(5) 1_455
O7 Ag3 2.508(9) 1_455
N9 O10 1.236(8) .
N9 O9 1.243(8) .
O1W H1WA 0.88(2) .
O1W H1WB 0.89(9) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 Ag1 Ag3 N7 74.2(3) . .
N4 Ag1 Ag3 N7 -84.3(3) . .
N7' Ag1 Ag3 N7 169.7(5) 1_655 .
O9 Ag1 Ag3 N7 -39.6(4) . .
N1 Ag1 Ag3 O7 -80.1(2) . 1_655
N4 Ag1 Ag3 O7 121.4(2) . 1_655
N7' Ag1 Ag3 O7 15.4(4) 1_655 1_655
O9 Ag1 Ag3 O7 166.0(4) . 1_655
N1 Ag1 Ag3 N8' -102.6(9) . 1_655
N4 Ag1 Ag3 N8' 98.9(9) . 1_655
N7' Ag1 Ag3 N8' -7.1(9) 1_655 1_655
O9 Ag1 Ag3 N8' 143.6(9) . 1_655
N1 Ag1 Ag3 Ag2 115(6) . .
N4 Ag1 Ag3 Ag2 -43(6) . .
N7' Ag1 Ag3 Ag2 -149(38) 1_655 .
O9 Ag1 Ag3 Ag2 2(6) . .
N6 Ag2 Ag3 N7 103.3(3) . .
N3 Ag2 Ag3 N7 -94.1(3) . .
N8 Ag2 Ag3 N7 7.2(4) . .
O1W Ag2 Ag3 N7 -176.0(3) . .
N6 Ag2 Ag3 O7 -102.5(2) . 1_655
N3 Ag2 Ag3 O7 60.1(2) . 1_655
N8 Ag2 Ag3 O7 161.5(3) . 1_655
O1W Ag2 Ag3 O7 -21.7(2) . 1_655
N6 Ag2 Ag3 N8' -80.0(9) . 1_655
N3 Ag2 Ag3 N8' 82.6(9) . 1_655
N8 Ag2 Ag3 N8' -176.0(8) . 1_655
O1W Ag2 Ag3 N8' 0.8(9) . 1_655
N6 Ag2 Ag3 Ag1 62(6) . .
N3 Ag2 Ag3 Ag1 -135(6) . .
N8 Ag2 Ag3 Ag1 -34(6) . .
O1W Ag2 Ag3 Ag1 143(38) . .
N1 C1 C2 C3 -2.9(9) . .
C1 C2 C3 C4 2.9(8) . .
C1 C2 C3 C6 178.7(5) . .
C2 C3 C4 C5 -0.9(8) . .
C6 C3 C4 C5 -176.4(5) . .
C3 C4 C5 N1 -1.5(9) . .
C2 C1 N1 C5 0.6(9) . .
C2 C1 N1 Ag1 -165.6(4) . .
C4 C5 N1 C1 1.6(9) . .
C4 C5 N1 Ag1 167.5(4) . .
N4 Ag1 N1 C1 -92.7(5) . .
N7' Ag1 N1 C1 125.9(6) 1_655 .
O9 Ag1 N1 C1 33.7(5) . .
Ag3 Ag1 N1 C1 -121.1(5) . .
N4 Ag1 N1 C5 101.8(5) . .
N7' Ag1 N1 C5 -39.7(6) 1_655 .
O9 Ag1 N1 C5 -131.9(5) . .
Ag3 Ag1 N1 C5 73.3(5) . .
C4 C3 C6 O1 139.3(6) . .
C2 C3 C6 O1 -36.2(8) . .
C4 C3 C6 C7 -43.4(7) . .
C2 C3 C6 C7 141.0(5) . .
O1 C6 C7 N2 173.6(5) . .
C3 C6 C7 N2 -3.7(7) . .
O1 C6 C7 C8 -4.0(8) . .
C3 C6 C7 C8 178.7(5) . .
N2 C7 C8 C9 1.0(8) . .
C6 C7 C8 C9 178.5(5) . .
C7 C8 C9 C10 0.3(9) . .
C8 C9 C10 C11 -0.4(9) . .
C9 C10 C11 N2 -0.8(9) . .
C9 C10 C11 C12 176.2(6) . .
C8 C7 N2 C11 -2.2(8) . .
C6 C7 N2 C11 -179.8(5) . .
C10 C11 N2 C7 2.1(8) . .
C12 C11 N2 C7 -175.2(5) . .
N2 C11 C12 O2 159.0(6) . .
C10 C11 C12 O2 -18.3(9) . .
N2 C11 C12 C13 -20.3(7) . .
C10 C11 C12 C13 162.4(5) . .
O2 C12 C13 C14 -37.8(8) . .
C11 C12 C13 C14 141.5(6) . .
O2 C12 C13 C17 138.4(6) . .
C11 C12 C13 C17 -42.2(8) . .
C17 C13 C14 C15 -0.2(10) . .
C12 C13 C14 C15 176.2(6) . .
C13 C14 C15 N3 -3.4(12) . .
N3 C16 C17 C13 -1.4(10) . .
C14 C13 C17 C16 2.5(9) . .
C12 C13 C17 C16 -173.8(6) . .
C14 C15 N3 C16 4.5(12) . .
C14 C15 N3 Ag2 -165.5(6) . .
C17 C16 N3 C15 -2.1(11) . .
C17 C16 N3 Ag2 167.7(5) . .
N6 Ag2 N3 C15 -72.1(8) . .
N8 Ag2 N3 C15 136.0(6) . .
O1W Ag2 N3 C15 22.8(6) . .
Ag3 Ag2 N3 C15 -107.3(6) . .
N6 Ag2 N3 C16 118.2(5) . .
N8 Ag2 N3 C16 -33.7(6) . .
O1W Ag2 N3 C16 -146.9(6) . .
Ag3 Ag2 N3 C16 83.0(6) . .
N4 C18 C19 C20 2.5(10) . .
C18 C19 C20 C21 -1.8(9) . .
C18 C19 C20 C23 173.4(5) . .
C19 C20 C21 C22 -1.3(10) . .
C23 C20 C21 C22 -176.7(6) . .
C20 C21 C22 N4 4.3(13) . .
C19 C18 N4 C22 0.2(11) . .
C19 C18 N4 Ag1 -156.8(5) . .
C21 C22 N4 C18 -3.7(12) . .
C21 C22 N4 Ag1 154.9(7) . .
N1 Ag1 N4 C18 -121.7(5) . .
N7' Ag1 N4 C18 16.4(8) 1_655 .
O9 Ag1 N4 C18 106.4(6) . .
Ag3 Ag1 N4 C18 -91.2(6) . .
N1 Ag1 N4 C22 81.5(7) . .
N7' Ag1 N4 C22 -140.5(7) 1_655 .
O9 Ag1 N4 C22 -50.5(6) . .
Ag3 Ag1 N4 C22 111.9(6) . .
C19 C20 C23 O3 -138.3(7) . .
C21 C20 C23 O3 36.9(8) . .
C19 C20 C23 C24 43.7(8) . .
C21 C20 C23 C24 -141.0(6) . .
O3 C23 C24 N5 -157.4(6) . .
C20 C23 C24 N5 20.5(7) . .
O3 C23 C24 C25 20.4(9) . .
C20 C23 C24 C25 -161.7(5) . .
N5 C24 C25 C26 0.1(9) . .
C23 C24 C25 C26 -177.6(6) . .
C24 C25 C26 C27 1.7(9) . .
C25 C26 C27 C28 -1.7(9) . .
C26 C27 C28 N5 -0.1(8) . .
C26 C27 C28 C29 -178.0(5) . .
C25 C24 N5 C28 -1.9(8) . .
C23 C24 N5 C28 175.9(5) . .
C27 C28 N5 C24 1.9(8) . .
C29 C28 N5 C24 179.9(5) . .
N5 C28 C29 O4 -175.3(5) . .
C27 C28 C29 O4 2.7(9) . .
N5 C28 C29 C32 2.6(7) . .
C27 C28 C29 C32 -179.4(5) . .
N6 C30 C31 C32 2.5(9) . .
C30 C31 C32 C33 -1.9(8) . .
C30 C31 C32 C29 -179.5(5) . .
O4 C29 C32 C31 36.8(8) . .
C28 C29 C32 C31 -141.1(5) . .
O4 C29 C32 C33 -140.5(6) . .
C28 C29 C32 C33 41.6(8) . .
C31 C32 C33 C34 0.2(8) . .
C29 C32 C33 C34 177.5(5) . .
C32 C33 C34 N6 1.3(9) . .
C31 C30 N6 C34 -1.1(9) . .
C31 C30 N6 Ag2 171.1(4) . .
C33 C34 N6 C30 -0.8(9) . .
C33 C34 N6 Ag2 -173.1(4) . .
N3 Ag2 N6 C30 85.3(6) . .
N8 Ag2 N6 C30 -121.7(5) . .
O1W Ag2 N6 C30 -11.2(5) . .
Ag3 Ag2 N6 C30 119.3(5) . .
N3 Ag2 N6 C34 -102.8(6) . .
N8 Ag2 N6 C34 50.2(5) . .
O1W Ag2 N6 C34 160.7(5) . .
Ag3 Ag2 N6 C34 -68.9(4) . .
O7 Ag3 N7 O5 -158.9(10) 1_655 .
N8' Ag3 N7 O5 -126(18) 1_655 .
Ag1 Ag3 N7 O5 120.5(12) . .
Ag2 Ag3 N7 O5 -59.2(12) . .
O7 Ag3 N7 O6 18(2) 1_655 .
N8' Ag3 N7 O6 50(18) 1_655 .
Ag1 Ag3 N7 O6 -63.0(13) . .
Ag2 Ag3 N7 O6 117.3(13) . .
O6 N7' O5 N7 -0.5(18) . .
Ag1 N7' O5 N7 -174(2) 1_455 .
O6 N7 O5 N7' 1(2) . .
Ag3 N7 O5 N7' 176(2) . .
O5 N7 O6 N7' -1(2) . .
Ag3 N7 O6 N7' -175(2) . .
O5 N7' O6 N7 0.5(18) . .
Ag1 N7' O6 N7 173(3) 1_455 .
N6 Ag2 N8 O7 -148.7(7) . .
N3 Ag2 N8 O7 17.1(8) . .
O1W Ag2 N8 O7 119.2(7) . .
Ag3 Ag2 N8 O7 -63.4(8) . .
N6 Ag2 N8 O8 11.4(9) . .
N3 Ag2 N8 O8 177.2(8) . .
O1W Ag2 N8 O8 -80.7(9) . .
Ag3 Ag2 N8 O8 96.7(9) . .
O8 N8' O7 N8 13(4) . .
Ag3 N8' O7 N8 174(3) 1_455 .
O8 N8' O7 Ag3 -161(7) . 1_455
O8 N8 O7 N8' -9(3) . .
Ag2 N8 O7 N8' 152(3) . .
O8 N8 O7 Ag3 -4.3(12) . 1_455
Ag2 N8 O7 Ag3 156.7(3) . 1_455
O7 N8' O8 N8 -14(4) . .
Ag3 N8' O8 N8 -175(3) 1_455 .
O7 N8 O8 N8' 8(2) . .
Ag2 N8 O8 N8' -150(3) . .
O10 N9 O9 Ag1 0.2(8) . .
N1 Ag1 O9 N9 -63.6(5) . .
N4 Ag1 O9 N9 81.8(5) . .
N7' Ag1 O9 N9 -164.5(6) 1_655 .
Ag3 Ag1 O9 N9 41.9(7) . .
