#------------------------------------------------------------------------------
#$Date: 2016-03-24 01:53:47 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179545 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/14/4501490.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4501490
loop_
_publ_author_name
'Su, Zhi'
'Fan, Jian'
'Okamura, Taka-aki'
'Chen, Man-Sheng'
'Chen, Shui-Sheng'
'Sun, Wei-Yin'
'Ueyama, Norikazu'
_publ_section_title
;
 Interpenetrating and Self-Penetrating Zinc(II) Complexes with Rigid
 Tripodal Imidazole-Containing Ligand and Benzenedicarboxylate
;
_journal_issue                   4
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              1911
_journal_paper_doi               10.1021/cg100020t
_journal_volume                  10
_journal_year                    2010
_chemical_formula_moiety         'C54 H38 N12 O14 Zn4, 4(H2 O)'
_chemical_formula_sum            'C54 H46 N12 O18 Zn4'
_chemical_formula_weight         1412.51
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 93.091(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   8.7150(8)
_cell_length_b                   11.6095(10)
_cell_length_c                   27.890(3)
_cell_measurement_reflns_used    2735
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      24.17
_cell_measurement_theta_min      2.28
_cell_volume                     2817.7(5)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0715
_diffrn_reflns_av_sigmaI/netI    0.0853
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -5
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            13992
_diffrn_reflns_theta_full        25.24
_diffrn_reflns_theta_max         25.24
_diffrn_reflns_theta_min         1.90
_exptl_absorpt_coefficient_mu    1.768
_exptl_absorpt_correction_T_max  0.836
_exptl_absorpt_correction_T_min  0.771
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs,bruker(2000)
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.665
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1420
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.1
_refine_diff_density_max         0.936
_refine_diff_density_min         -0.415
_refine_diff_density_rms         0.084
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.975
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     420
_refine_ls_number_reflns         5069
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      0.975
_refine_ls_R_factor_all          0.0729
_refine_ls_R_factor_gt           0.0488
_refine_ls_shift/su_max          0.009
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0386P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1009
_refine_ls_wR_factor_ref         0.1082
_reflns_number_gt                3605
_reflns_number_total             5069
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg100020t_si_002.cif
_cod_data_source_block           2
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               4501490
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Zn1 Zn 1.46599(6) -0.28356(4) 0.06409(2) 0.02987(17) Uani 1 1 d . . .
Zn2 Zn 1.67852(6) -0.15023(4) 0.15136(2) 0.03276(18) Uani 1 1 d . . .
C1 C 1.9466(5) -0.5706(3) 0.12621(16) 0.0247(10) Uani 1 1 d . . .
C2 C 1.9256(5) -0.6820(3) 0.14106(17) 0.0300(11) Uani 1 1 d . . .
H2A H 1.8590 -0.6990 0.1650 0.036 Uiso 1 1 calc R . .
C3 C 2.0062(5) -0.7678(3) 0.11935(17) 0.0283(11) Uani 1 1 d . . .
C4 C 2.1012(5) -0.7470(3) 0.08357(17) 0.0288(11) Uani 1 1 d . . .
H4A H 2.1522 -0.8070 0.0691 0.035 Uiso 1 1 calc R . .
C5 C 2.1204(5) -0.6339(4) 0.06904(16) 0.0262(10) Uani 1 1 d . . .
C6 C 2.0460(5) -0.5447(4) 0.09086(16) 0.0261(11) Uani 1 1 d . . .
H6A H 2.0626 -0.4687 0.0819 0.031 Uiso 1 1 calc R . .
C7 C 1.7885(5) -0.4874(4) 0.19082(18) 0.0361(12) Uani 1 1 d . . .
H7A H 1.7787 -0.5526 0.2098 0.043 Uiso 1 1 calc R . .
C8 C 1.7299(5) -0.3831(4) 0.19828(17) 0.0354(12) Uani 1 1 d . . .
H8A H 1.6723 -0.3632 0.2241 0.043 Uiso 1 1 calc R . .
C9 C 1.8496(5) -0.3704(3) 0.13295(17) 0.0309(11) Uani 1 1 d . . .
H9A H 1.8900 -0.3421 0.1051 0.037 Uiso 1 1 calc R . .
C10 C 2.0913(6) -0.9691(4) 0.1416(2) 0.0478(15) Uani 1 1 d . . .
H10A H 2.1970 -0.9618 0.1396 0.057 Uiso 1 1 calc R . .
C11 C 2.0129(6) -1.0640(4) 0.1528(2) 0.0500(15) Uani 1 1 d . . .
H11A H 2.0577 -1.1350 0.1601 0.060 Uiso 1 1 calc R . .
C12 C 1.8452(5) -0.9339(4) 0.14010(18) 0.0381(13) Uani 1 1 d . . .
H12A H 1.7519 -0.8952 0.1364 0.046 Uiso 1 1 calc R . .
C13 C 2.2247(5) -0.5067(4) 0.00527(17) 0.0335(12) Uani 1 1 d . . .
H13A H 2.1701 -0.4394 0.0104 0.040 Uiso 1 1 calc R . .
C14 C 2.3269(5) -0.5240(4) -0.02799(17) 0.0335(12) Uani 1 1 d . . .
H14A H 2.3544 -0.4699 -0.0506 0.040 Uiso 1 1 calc R . .
C15 C 2.3159(5) -0.6826(4) 0.01186(17) 0.0348(12) Uani 1 1 d . . .
H15A H 2.3336 -0.7576 0.0225 0.042 Uiso 1 1 calc R . .
C16 C 1.3731(5) -0.0190(4) 0.24537(18) 0.0363(12) Uani 1 1 d . . .
C17 C 1.3137(5) -0.1110(4) 0.26950(18) 0.0388(13) Uani 1 1 d . . .
H17A H 1.3378 -0.1858 0.2606 0.047 Uiso 1 1 calc R . .
C18 C 1.2182(5) -0.0928(4) 0.30691(18) 0.0398(13) Uani 1 1 d . . .
H18A H 1.1760 -0.1554 0.3222 0.048 Uiso 1 1 calc R . .
C19 C 1.1853(5) 0.0175(4) 0.32162(17) 0.0352(12) Uani 1 1 d . . .
C20 C 1.2441(6) 0.1090(4) 0.29734(19) 0.0482(15) Uani 1 1 d . . .
H20A H 1.2222 0.1838 0.3068 0.058 Uiso 1 1 calc R . .
C21 C 1.3350(6) 0.0913(4) 0.2593(2) 0.0515(15) Uani 1 1 d . . .
H21A H 1.3713 0.1543 0.2426 0.062 Uiso 1 1 calc R . .
C22 C 1.4814(5) -0.0362(4) 0.20581(19) 0.0385(13) Uani 1 1 d . . .
C23 C 1.0956(6) 0.0384(5) 0.36525(18) 0.0407(13) Uani 1 1 d . . .
C24 C 1.1634(6) -0.2050(4) 0.03339(18) 0.0379(13) Uani 1 1 d . . .
C25 C 1.0791(5) -0.0984(4) 0.01559(17) 0.0302(11) Uani 1 1 d . . .
C26 C 1.1501(5) -0.0153(4) -0.01091(18) 0.0389(13) Uani 1 1 d . . .
H26A H 1.2519 -0.0253 -0.0184 0.047 Uiso 1 1 calc R . .
C27 C 1.0724(5) 0.0818(4) -0.02627(18) 0.0354(12) Uani 1 1 d . . .
H27A H 1.1220 0.1370 -0.0440 0.042 Uiso 1 1 calc R . .
N1 N 1.7672(4) -0.3097(3) 0.16230(14) 0.0298(9) Uani 1 1 d . . .
N2 N 1.8667(4) -0.4789(3) 0.14909(13) 0.0273(9) Uani 1 1 d . . .
N3 N 1.8587(4) -1.0425(3) 0.15192(15) 0.0359(10) Uani 1 1 d . . .
N4 N 1.9821(4) -0.8850(3) 0.13395(14) 0.0323(10) Uani 1 1 d . . .
N5 N 2.3853(4) -0.6335(3) -0.02389(14) 0.0307(9) Uani 1 1 d . . .
N6 N 2.2163(4) -0.6092(3) 0.03067(13) 0.0282(9) Uani 1 1 d . . .
O1 O 1.5491(4) -0.1341(3) 0.20618(12) 0.0449(9) Uani 1 1 d . . .
O2 O 1.5019(4) 0.0393(3) 0.17647(14) 0.0613(12) Uani 1 1 d . . .
O3 O 1.0966(4) 0.1418(3) 0.37917(13) 0.0550(11) Uani 1 1 d . . .
O4 O 1.0334(4) -0.0427(3) 0.38476(13) 0.0590(11) Uani 1 1 d . . .
O5 O 1.3051(4) -0.2116(3) 0.02330(12) 0.0453(9) Uani 1 1 d . . .
O6 O 1.0934(4) -0.2782(3) 0.05557(14) 0.0511(10) Uani 1 1 d . . .
O7 O 1.5812(4) -0.1508(3) 0.08862(13) 0.0397(8) Uani 1 1 d D . .
H7 H 1.534(6) -0.093(3) 0.081(2) 0.08(2) Uiso 1 1 d D . .
O8A O 1.4927(7) 0.0890(5) 0.0499(3) 0.097(2) Uani 0.816(7) 1 d P A 1
O8B O 1.421(2) 0.0659(15) 0.0828(9) 0.052(7) Uani 0.184(7) 1 d P A 2
O9A O 1.5434(7) 0.2387(5) 0.1269(3) 0.118(3) Uani 0.816(7) 1 d P A 1
O9B O 1.6259(17) 0.2436(13) 0.0774(6) 0.028(5) Uani 0.184(7) 1 d P A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O3 Zn1 O7 103.50(16) 2_745 .
O3 Zn1 O5 116.76(14) 2_745 .
O7 Zn1 O5 101.98(15) . .
O3 Zn1 N5 117.88(15) 2_745 3_945
O7 Zn1 N5 103.91(14) . 3_945
O5 Zn1 N5 110.28(15) . 3_945
O7 Zn2 O1 118.15(15) . .
O7 Zn2 N3 108.59(16) . 1_565
O1 Zn2 N3 114.72(15) . 1_565
O7 Zn2 N1 106.46(15) . .
O1 Zn2 N1 101.61(14) . .
N3 Zn2 N1 106.06(15) 1_565 .
C2 C1 C6 121.3(4) . .
C2 C1 N2 119.1(4) . .
C6 C1 N2 119.6(4) . .
C1 C2 C3 118.0(4) . .
C1 C2 H2A 121.0 . .
C3 C2 H2A 121.0 . .
C4 C3 C2 122.9(4) . .
C4 C3 N4 118.8(4) . .
C2 C3 N4 118.3(4) . .
C3 C4 C5 118.2(4) . .
C3 C4 H4A 120.9 . .
C5 C4 H4A 120.9 . .
C6 C5 C4 121.0(4) . .
C6 C5 N6 119.3(4) . .
C4 C5 N6 119.7(4) . .
C1 C6 C5 118.7(4) . .
C1 C6 H6A 120.7 . .
C5 C6 H6A 120.7 . .
C8 C7 N2 106.0(4) . .
C8 C7 H7A 127.0 . .
N2 C7 H7A 127.0 . .
C7 C8 N1 110.0(4) . .
C7 C8 H8A 125.0 . .
N1 C8 H8A 125.0 . .
N1 C9 N2 110.3(4) . .
N1 C9 H9A 124.9 . .
N2 C9 H9A 124.9 . .
C11 C10 N4 105.3(4) . .
C11 C10 H10A 127.4 . .
N4 C10 H10A 127.4 . .
C10 C11 N3 111.0(4) . .
C10 C11 H11A 124.5 . .
N3 C11 H11A 124.5 . .
N3 C12 N4 111.8(4) . .
N3 C12 H12A 124.1 . .
N4 C12 H12A 124.1 . .
C14 C13 N6 106.3(4) . .
C14 C13 H13A 126.8 . .
N6 C13 H13A 126.8 . .
C13 C14 N5 109.9(4) . .
C13 C14 H14A 125.1 . .
N5 C14 H14A 125.1 . .
N5 C15 N6 110.6(4) . .
N5 C15 H15A 124.7 . .
N6 C15 H15A 124.7 . .
C17 C16 C21 118.6(4) . .
C17 C16 C22 121.5(4) . .
C21 C16 C22 119.9(4) . .
C16 C17 C18 120.4(4) . .
C16 C17 H17A 119.8 . .
C18 C17 H17A 119.8 . .
C19 C18 C17 120.6(5) . .
C19 C18 H18A 119.7 . .
C17 C18 H18A 119.7 . .
C20 C19 C18 118.8(4) . .
C20 C19 C23 120.0(4) . .
C18 C19 C23 121.1(5) . .
C19 C20 C21 120.7(5) . .
C19 C20 H20A 119.6 . .
C21 C20 H20A 119.6 . .
C20 C21 C16 120.8(5) . .
C20 C21 H21A 119.6 . .
C16 C21 H21A 119.6 . .
O2 C22 O1 124.0(4) . .
O2 C22 C16 121.2(4) . .
O1 C22 C16 114.8(4) . .
O4 C23 O3 126.1(5) . .
O4 C23 C19 119.8(5) . .
O3 C23 C19 114.1(5) . .
O6 C24 O5 125.2(4) . .
O6 C24 C25 119.1(4) . .
O5 C24 C25 115.7(4) . .
C26 C25 C27 118.6(4) . 3_755
C26 C25 C24 121.7(4) . .
C27 C25 C24 119.7(4) 3_755 .
C27 C26 C25 120.9(4) . .
C27 C26 H26A 119.6 . .
C25 C26 H26A 119.6 . .
C26 C27 C25 120.5(4) . 3_755
C26 C27 H27A 119.7 . .
C25 C27 H27A 119.7 3_755 .
C9 N1 C8 106.3(3) . .
C9 N1 Zn2 127.6(3) . .
C8 N1 Zn2 125.2(3) . .
C9 N2 C7 107.3(3) . .
C9 N2 C1 126.3(4) . .
C7 N2 C1 126.3(4) . .
C12 N3 C11 104.8(4) . .
C12 N3 Zn2 122.6(3) . 1_545
C11 N3 Zn2 130.9(3) . 1_545
C12 N4 C10 107.1(4) . .
C12 N4 C3 125.5(4) . .
C10 N4 C3 127.4(4) . .
C15 N5 C14 106.2(3) . .
C15 N5 Zn1 123.4(3) . 3_945
C14 N5 Zn1 130.3(3) . 3_945
C15 N6 C13 106.9(4) . .
C15 N6 C5 125.8(4) . .
C13 N6 C5 127.3(3) . .
C22 O1 Zn2 111.3(3) . .
C23 O3 Zn1 133.6(3) . 2_755
C24 O5 Zn1 124.7(3) . .
Zn2 O7 Zn1 121.48(18) . .
Zn2 O7 H7 116(4) . .
Zn1 O7 H7 108(4) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Zn1 O3 1.909(3) 2_745
Zn1 O7 1.944(3) .
Zn1 O5 1.946(3) .
Zn1 N5 2.005(3) 3_945
Zn2 O7 1.903(4) .
Zn2 O1 1.957(3) .
Zn2 N3 2.007(4) 1_565
Zn2 N1 2.023(3) .
C1 C2 1.374(5) .
C1 C6 1.380(6) .
C1 N2 1.439(5) .
C2 C3 1.377(6) .
C2 H2A 0.9300 .
C3 C4 1.352(6) .
C3 N4 1.440(5) .
C4 C5 1.388(5) .
C4 H4A 0.9300 .
C5 C6 1.380(5) .
C5 N6 1.422(5) .
C6 H6A 0.9300 .
C7 C8 1.335(6) .
C7 N2 1.384(5) .
C7 H7A 0.9300 .
C8 N1 1.369(5) .
C8 H8A 0.9300 .
C9 N1 1.321(5) .
C9 N2 1.343(5) .
C9 H9A 0.9300 .
C10 C11 1.341(6) .
C10 N4 1.372(5) .
C10 H10A 0.9300 .
C11 N3 1.366(6) .
C11 H11A 0.9300 .
C12 N3 1.307(5) .
C12 N4 1.341(5) .
C12 H12A 0.9300 .
C13 C14 1.335(6) .
C13 N6 1.389(5) .
C13 H13A 0.9300 .
C14 N5 1.371(5) .
C14 H14A 0.9300 .
C15 N5 1.323(5) .
C15 N6 1.343(5) .
C15 H15A 0.9300 .
C16 C17 1.379(6) .
C16 C21 1.384(6) .
C16 C22 1.503(6) .
C17 C18 1.385(6) .
C17 H17A 0.9300 .
C18 C19 1.379(6) .
C18 H18A 0.9300 .
C19 C20 1.374(6) .
C19 C23 1.501(6) .
C20 C21 1.374(7) .
C20 H20A 0.9300 .
C21 H21A 0.9300 .
C22 O2 1.219(6) .
C22 O1 1.281(5) .
C23 O4 1.228(6) .
C23 O3 1.262(6) .
C24 O6 1.232(5) .
C24 O5 1.284(5) .
C24 C25 1.510(6) .
C25 C26 1.381(6) .
C25 C27 1.383(5) 3_755
C26 C27 1.372(6) .
C26 H26A 0.9300 .
C27 C25 1.383(5) 3_755
C27 H27A 0.9300 .
N3 Zn2 2.007(4) 1_545
N5 Zn1 2.005(3) 3_945
O3 Zn1 1.909(3) 2_755
O7 H7 0.815(10) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C6 C1 C2 C3 -0.4(7) . .
N2 C1 C2 C3 -178.5(4) . .
C1 C2 C3 C4 -1.7(7) . .
C1 C2 C3 N4 -178.6(4) . .
C2 C3 C4 C5 1.5(7) . .
N4 C3 C4 C5 178.4(4) . .
C3 C4 C5 C6 0.7(7) . .
C3 C4 C5 N6 -178.4(4) . .
C2 C1 C6 C5 2.5(7) . .
N2 C1 C6 C5 -179.4(4) . .
C4 C5 C6 C1 -2.7(7) . .
N6 C5 C6 C1 176.4(4) . .
N2 C7 C8 N1 0.7(6) . .
N4 C10 C11 N3 0.5(7) . .
N6 C13 C14 N5 -1.0(6) . .
C21 C16 C17 C18 -0.2(8) . .
C22 C16 C17 C18 177.8(5) . .
C16 C17 C18 C19 -2.2(8) . .
C17 C18 C19 C20 2.4(8) . .
C17 C18 C19 C23 -173.6(5) . .
C18 C19 C20 C21 -0.4(8) . .
C23 C19 C20 C21 175.7(5) . .
C19 C20 C21 C16 -1.9(9) . .
C17 C16 C21 C20 2.2(9) . .
C22 C16 C21 C20 -175.8(5) . .
C17 C16 C22 O2 160.4(5) . .
C21 C16 C22 O2 -21.7(8) . .
C17 C16 C22 O1 -20.3(7) . .
C21 C16 C22 O1 157.6(5) . .
C20 C19 C23 O4 174.5(5) . .
C18 C19 C23 O4 -9.5(8) . .
C20 C19 C23 O3 -7.5(7) . .
C18 C19 C23 O3 168.5(5) . .
O6 C24 C25 C26 -177.7(5) . .
O5 C24 C25 C26 1.7(7) . .
O6 C24 C25 C27 3.0(7) . 3_755
O5 C24 C25 C27 -177.7(4) . 3_755
C27 C25 C26 C27 0.2(8) 3_755 .
C24 C25 C26 C27 -179.2(5) . .
C25 C26 C27 C25 -0.2(8) . 3_755
N2 C9 N1 C8 -0.4(5) . .
N2 C9 N1 Zn2 -170.1(3) . .
C7 C8 N1 C9 -0.2(6) . .
C7 C8 N1 Zn2 169.8(3) . .
O7 Zn2 N1 C9 47.4(4) . .
O1 Zn2 N1 C9 171.6(4) . .
N3 Zn2 N1 C9 -68.1(4) 1_565 .
O7 Zn2 N1 C8 -120.5(4) . .
O1 Zn2 N1 C8 3.8(4) . .
N3 Zn2 N1 C8 124.0(4) 1_565 .
N1 C9 N2 C7 0.8(5) . .
N1 C9 N2 C1 178.7(4) . .
C8 C7 N2 C9 -1.0(6) . .
C8 C7 N2 C1 -178.8(4) . .
C2 C1 N2 C9 -165.6(4) . .
C6 C1 N2 C9 16.3(7) . .
C2 C1 N2 C7 11.8(7) . .
C6 C1 N2 C7 -166.3(4) . .
N4 C12 N3 C11 -0.7(6) . .
N4 C12 N3 Zn2 -167.7(3) . 1_545
C10 C11 N3 C12 0.1(6) . .
C10 C11 N3 Zn2 165.6(4) . 1_545
N3 C12 N4 C10 1.0(6) . .
N3 C12 N4 C3 177.9(4) . .
C11 C10 N4 C12 -0.9(6) . .
C11 C10 N4 C3 -177.6(5) . .
C4 C3 N4 C12 -131.7(5) . .
C2 C3 N4 C12 45.4(7) . .
C4 C3 N4 C10 44.5(7) . .
C2 C3 N4 C10 -138.4(5) . .
N6 C15 N5 C14 -0.1(6) . .
N6 C15 N5 Zn1 -176.5(3) . 3_945
C13 C14 N5 C15 0.7(6) . .
C13 C14 N5 Zn1 176.8(3) . 3_945
N5 C15 N6 C13 -0.5(6) . .
N5 C15 N6 C5 178.9(4) . .
C14 C13 N6 C15 1.0(5) . .
C14 C13 N6 C5 -178.5(4) . .
C6 C5 N6 C15 167.5(4) . .
C4 C5 N6 C15 -13.4(7) . .
C6 C5 N6 C13 -13.1(7) . .
C4 C5 N6 C13 166.0(4) . .
O2 C22 O1 Zn2 -3.7(7) . .
C16 C22 O1 Zn2 177.0(3) . .
O7 Zn2 O1 C22 -64.2(4) . .
N3 Zn2 O1 C22 66.0(4) 1_565 .
N1 Zn2 O1 C22 179.9(3) . .
O4 C23 O3 Zn1 9.2(9) . 2_755
C19 C23 O3 Zn1 -168.7(3) . 2_755
O6 C24 O5 Zn1 -33.9(7) . .
C25 C24 O5 Zn1 146.8(3) . .
O3 Zn1 O5 C24 4.5(4) 2_745 .
O7 Zn1 O5 C24 -107.5(4) . .
N5 Zn1 O5 C24 142.6(4) 3_945 .
O1 Zn2 O7 Zn1 -74.2(2) . .
N3 Zn2 O7 Zn1 152.89(18) 1_565 .
N1 Zn2 O7 Zn1 39.1(2) . .
O3 Zn1 O7 Zn2 25.3(2) 2_745 .
O5 Zn1 O7 Zn2 146.94(19) . .
N5 Zn1 O7 Zn2 -98.4(2) 3_945 .
