#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/14/4501497.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4501497
loop_
_publ_author_name
'Feng, Rui'
'Jiang, Fei-Long'
'Wu, Ming-Yan'
'Chen, Lian'
'Yan, Chun-Feng'
'Hong, Mao-Chun'
_publ_section_title
;
 Structures and Photoluminescent Properties of the Lanthanide Coordination
 Complexes with Hydroxyquinoline Carboxylate Ligands
;
_journal_issue                   5
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              2306
_journal_paper_doi               10.1021/cg100026d
_journal_volume                  10
_journal_year                    2010
_chemical_formula_moiety         'C66 H54 Eu2 N8 O22, 2(O)'
_chemical_formula_sum            'C66 H54 Eu2 N8 O24'
_chemical_formula_weight         1647.09
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                106.855(2)
_cell_angle_beta                 94.907(3)
_cell_angle_gamma                96.179(2)
_cell_formula_units_Z            1
_cell_length_a                   9.919(3)
_cell_length_b                   11.466(3)
_cell_length_c                   15.009(4)
_cell_measurement_reflns_used    4286
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.4797
_cell_measurement_theta_min      3.1132
_cell_volume                     1611.9(8)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.940
_diffrn_measured_fraction_theta_max 0.940
_diffrn_measurement_device_type
;
Mercury70 (2x2 bin mode)
;
_diffrn_measurement_method       CCD_Profile_fitting
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0214
_diffrn_reflns_av_sigmaI/netI    0.0322
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            8606
_diffrn_reflns_theta_full        23.12
_diffrn_reflns_theta_max         23.12
_diffrn_reflns_theta_min         2.38
_diffrn_standards_number         6682
_exptl_absorpt_coefficient_mu    2.018
_exptl_absorpt_correction_T_max  0.8237
_exptl_absorpt_correction_T_min  0.6883
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            White
_exptl_crystal_density_diffrn    1.697
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             824
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.251
_refine_diff_density_min         -1.148
_refine_diff_density_rms         0.093
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.092
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     430
_refine_ls_number_reflns         4283
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.092
_refine_ls_R_factor_all          0.0346
_refine_ls_R_factor_gt           0.0324
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0341P)²+4.8970P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0777
_refine_ls_wR_factor_ref         0.0797
_reflns_number_gt                4067
_reflns_number_total             4283
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg100026d_si_001.cif
_cod_data_source_block           complex2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_Hall     -P_1
_cod_original_sg_symbol_H-M      p_-1
_cod_database_code               4501497
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.88031(2) 0.98326(2) 0.101836(15) 0.01870(11) Uani 1 1 d .
O1 O 0.6935(4) 0.9354(5) -0.0301(3) 0.0496(12) Uani 1 1 d .
O2 O 0.8868(4) 0.9714(3) -0.0836(2) 0.0287(8) Uani 1 1 d .
O3 O 0.4311(4) 1.0797(3) -0.2876(2) 0.0374(10) Uani 1 1 d .
O4 O 0.9332(4) 0.7906(3) 0.0119(2) 0.0266(8) Uani 1 1 d .
O6 O 1.2377(4) 0.3933(3) -0.1511(3) 0.0362(9) Uani 1 1 d .
O7 O 1.0167(4) 0.8997(3) 0.2193(2) 0.0360(7) Uani 1 1 d .
O8 O 0.9571(4) 1.0825(3) 0.2664(2) 0.0360(7) Uani 1 1 d .
O9 O 1.3529(5) 0.8819(4) 0.4792(3) 0.0497(12) Uani 1 1 d .
O10 O 0.7005(4) 1.0901(3) 0.1653(3) 0.0402(10) Uani 1 1 d .
O11 O 0.7199(4) 0.8362(3) 0.1409(3) 0.0338(10) Uani 1 1 d .
N1 N 0.5209(5) 0.9047(4) -0.3545(3) 0.0313(11) Uani 1 1 d .
H1 H 0.4738 0.8975 -0.4071 0.038 Uiso 1 1 calc R
N2 N 1.0077(5) 0.3616(4) -0.1493(3) 0.0291(11) Uani 1 1 d .
H2 H 1.0092 0.2835 -0.1698 0.035 Uiso 1 1 calc R
N3 N 1.2632(5) 1.0562(4) 0.5423(3) 0.0389(12) Uani 1 1 d .
H3 H 1.3180 1.0698 0.5929 0.047 Uiso 1 1 calc R
N4 N 0.6399(7) 1.2792(6) 0.2138(6) 0.0780(12) Uani 1 1 d .
C1 C 0.7595(5) 0.9456(4) -0.0950(3) 0.0231(12) Uani 1 1 d .
C2 C 0.6789(5) 0.9302(4) -0.1889(3) 0.0246(12) Uani 1 1 d .
C3 C 0.5935(5) 1.0120(4) -0.1947(3) 0.0264(12) Uani 1 1 d .
H3A H 0.5883 1.0765 -0.1412 0.032 Uiso 1 1 calc R
C4 C 0.5098(5) 1.0040(5) -0.2799(3) 0.0280(12) Uani 1 1 d .
C5 C 0.6017(6) 0.8155(5) -0.3515(3) 0.0280(12) Uani 1 1 d .
C6 C 0.6873(5) 0.8259(5) -0.2695(4) 0.0283(12) Uani 1 1 d .
C7 C 0.7695(6) 0.7330(5) -0.2686(4) 0.0375(14) Uani 1 1 d .
H7 H 0.8271 0.7390 -0.2147 0.045 Uiso 1 1 calc R
C8 C 0.7645(7) 0.6348(6) -0.3461(4) 0.0500(17) Uani 1 1 d .
H8 H 0.8189 0.5738 -0.3453 0.060 Uiso 1 1 calc R
C9 C 0.6783(7) 0.6250(6) -0.4270(4) 0.0513(17) Uani 1 1 d .
H9 H 0.6749 0.5566 -0.4792 0.062 Uiso 1 1 calc R
C10 C 0.5986(7) 0.7138(6) -0.4312(4) 0.0432(15) Uani 1 1 d .
H10 H 0.5431 0.7069 -0.4862 0.052 Uiso 1 1 calc R
C11 C 1.0047(5) 0.7492(4) -0.0515(3) 0.0225(11) Uani 1 1 d .
C12 C 0.9998(5) 0.6112(4) -0.0880(3) 0.0220(11) Uani 1 1 d .
C13 C 1.1176(6) 0.5664(4) -0.1068(4) 0.0292(13) Uani 1 1 d .
H13 H 1.1961 0.6220 -0.1001 0.035 Uiso 1 1 calc R
C14 C 1.1285(6) 0.4360(4) -0.1371(4) 0.0266(12) Uani 1 1 d .
C15 C 0.8836(6) 0.4002(4) -0.1316(3) 0.0271(12) Uani 1 1 d .
C16 C 0.8734(5) 0.5269(4) -0.0994(3) 0.0239(12) Uani 1 1 d .
C17 C 0.7458(6) 0.5627(5) -0.0808(4) 0.0325(13) Uani 1 1 d .
H17 H 0.7369 0.6459 -0.0594 0.039 Uiso 1 1 calc R
C18 C 0.6336(6) 0.4755(6) -0.0941(4) 0.0447(16) Uani 1 1 d .
H18 H 0.5487 0.5001 -0.0826 0.054 Uiso 1 1 calc R
C19 C 0.6455(7) 0.3508(5) -0.1245(5) 0.0479(17) Uani 1 1 d .
H19 H 0.5692 0.2928 -0.1315 0.058 Uiso 1 1 calc R
C20 C 0.7689(6) 0.3129(5) -0.1443(4) 0.0403(15) Uani 1 1 d .
H20 H 0.7760 0.2295 -0.1661 0.048 Uiso 1 1 calc R
C21 C 1.0157(5) 0.9983(4) 0.2826(3) 0.0239(11) Uani 1 1 d .
C22 C 1.0950(5) 1.0188(4) 0.3783(3) 0.0238(11) Uani 1 1 d .
C23 C 1.1818(6) 0.9388(5) 0.3860(4) 0.0314(13) Uani 1 1 d .
H23 H 1.1841 0.8705 0.3346 0.038 Uiso 1 1 calc R
C24 C 1.2715(6) 0.9544(5) 0.4708(4) 0.0373(14) Uani 1 1 d .
C25 C 1.1736(6) 1.1400(5) 0.5406(4) 0.0324(13) Uani 1 1 d .
C26 C 1.0838(6) 1.1236(5) 0.4583(3) 0.0299(13) Uani 1 1 d .
C27 C 0.9926(7) 1.2090(5) 0.4616(4) 0.0450(16) Uani 1 1 d .
H27 H 0.9307 1.1996 0.4090 0.054 Uiso 1 1 calc R
C28 C 0.9922(8) 1.3057(6) 0.5399(4) 0.058(2) Uani 1 1 d .
H28 H 0.9297 1.3607 0.5405 0.070 Uiso 1 1 calc R
C29 C 1.0847(8) 1.3222(6) 0.6187(4) 0.0548(19) Uani 1 1 d .
H29 H 1.0853 1.3898 0.6712 0.066 Uiso 1 1 calc R
C30 C 1.1741(7) 1.2412(5) 0.6203(4) 0.0447(16) Uani 1 1 d .
H30 H 1.2352 1.2525 0.6736 0.054 Uiso 1 1 calc R
C31 C 0.6394(9) 1.1725(7) 0.1592(7) 0.0780(12) Uani 1 1 d .
H31 H 0.5807 1.1544 0.1038 0.094 Uiso 1 1 calc R
C32 C 0.7398(8) 1.3110(7) 0.3021(7) 0.0780(12) Uani 1 1 d .
H32A H 0.7401 1.2406 0.3244 0.117 Uiso 1 1 calc R
H32B H 0.7130 1.3779 0.3493 0.117 Uiso 1 1 calc R
H32C H 0.8298 1.3348 0.2886 0.117 Uiso 1 1 calc R
C33 C 0.5637(8) 1.3725(7) 0.2118(7) 0.0780(12) Uani 1 1 d .
H33A H 0.5079 1.3511 0.1524 0.117 Uiso 1 1 calc R
H33B H 0.6238 1.4474 0.2206 0.117 Uiso 1 1 calc R
H33C H 0.5063 1.3839 0.2612 0.117 Uiso 1 1 calc R
O5 O 1.0833(4) 0.8113(3) -0.0874(2) 0.0299(9) Uani 1 1 d .
H11B H 0.671(6) 0.854(5) 0.175(4) 0.036 Uiso 1 1 d .
H11A H 0.734(6) 0.774(6) 0.140(4) 0.036 Uiso 1 1 d .
O12 O 0.3885(15) 0.6576(13) -0.6407(10) 0.249(6) Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 Eu1 O4 77.05(12) 2_775 .
O2 Eu1 O10 138.47(12) 2_775 .
O4 Eu1 O10 144.20(13) . .
O2 Eu1 O8 84.01(13) 2_775 .
O4 Eu1 O8 125.53(12) . .
O10 Eu1 O8 73.55(14) . .
O2 Eu1 O5 71.87(12) 2_775 2_775
O4 Eu1 O5 133.32(11) . 2_775
O10 Eu1 O5 71.76(12) . 2_775
O8 Eu1 O5 85.04(12) . 2_775
O2 Eu1 O11 142.91(13) 2_775 .
O4 Eu1 O11 76.70(13) . .
O10 Eu1 O11 72.94(13) . .
O8 Eu1 O11 90.38(14) . .
O5 Eu1 O11 144.25(13) 2_775 .
O2 Eu1 O1 122.68(12) 2_775 .
O4 Eu1 O1 81.26(14) . .
O10 Eu1 O1 74.42(15) . .
O8 Eu1 O1 147.90(14) . .
O5 Eu1 O1 87.09(14) 2_775 .
O11 Eu1 O1 78.21(14) . .
O2 Eu1 O7 74.42(13) 2_775 .
O4 Eu1 O7 74.36(11) . .
O10 Eu1 O7 113.65(13) . .
O8 Eu1 O7 51.33(11) . .
O5 Eu1 O7 126.78(12) 2_775 .
O11 Eu1 O7 73.59(14) . .
O1 Eu1 O7 146.12(14) . .
O2 Eu1 O2 73.71(12) 2_775 .
O4 Eu1 O2 68.33(11) . .
O10 Eu1 O2 111.18(13) . .
O8 Eu1 O2 150.55(12) . .
O5 Eu1 O2 70.03(11) 2_775 .
O11 Eu1 O2 118.99(12) . .
O1 Eu1 O2 48.97(12) . .
O7 Eu1 O2 135.13(11) . .
O2 Eu1 C21 77.87(13) 2_775 .
O4 Eu1 C21 100.07(13) . .
O10 Eu1 C21 93.78(15) . .
O8 Eu1 C21 25.53(13) . .
O5 Eu1 C21 106.27(13) 2_775 .
O11 Eu1 C21 81.45(14) . .
O1 Eu1 C21 158.74(14) . .
O7 Eu1 C21 25.80(12) . .
O2 Eu1 C21 151.03(13) . .
O2 Eu1 C1 98.49(13) 2_775 .
O4 Eu1 C1 73.70(12) . .
O10 Eu1 C1 92.52(14) . .
O8 Eu1 C1 160.41(12) . .
O5 Eu1 C1 77.40(12) 2_775 .
O11 Eu1 C1 98.76(14) . .
O1 Eu1 C1 24.19(14) . .
O7 Eu1 C1 148.07(12) . .
O2 Eu1 C1 24.78(12) . .
C21 Eu1 C1 173.46(14) . .
O2 Eu1 Eu1 40.07(8) 2_775 2_775
O4 Eu1 Eu1 67.85(8) . 2_775
O10 Eu1 Eu1 132.40(9) . 2_775
O8 Eu1 Eu1 121.58(10) . 2_775
O5 Eu1 Eu1 65.88(8) 2_775 2_775
O11 Eu1 Eu1 141.76(10) . 2_775
O1 Eu1 Eu1 82.61(9) . 2_775
O7 Eu1 Eu1 108.67(9) . 2_775
O2 Eu1 Eu1 33.64(7) . 2_775
C21 Eu1 Eu1 117.73(10) . 2_775
C1 Eu1 Eu1 58.42(10) . 2_775
C1 O1 Eu1 100.9(3) . .
C1 O2 Eu1 165.8(3) . 2_775
C1 O2 Eu1 87.9(3) . .
Eu1 O2 Eu1 106.29(12) 2_775 .
C11 O4 Eu1 138.9(3) . .
C21 O7 Eu1 89.8(3) . .
C21 O8 Eu1 98.1(3) . .
C31 O10 Eu1 141.1(5) . .
Eu1 O11 H11B 123(5) . .
Eu1 O11 H11A 124(5) . .
H11B O11 H11A 107(7) . .
C4 N1 C5 124.8(4) . .
C4 N1 H1 117.6 . .
C5 N1 H1 117.6 . .
C14 N2 C15 125.7(4) . .
C14 N2 H2 117.1 . .
C15 N2 H2 117.1 . .
C24 N3 C25 125.2(5) . .
C24 N3 H3 117.4 . .
C25 N3 H3 117.4 . .
C31 N4 C33 133.2(9) . .
C31 N4 C32 114.2(7) . .
C33 N4 C32 112.6(7) . .
O1 C1 O2 122.2(5) . .
O1 C1 C2 117.2(5) . .
O2 C1 C2 120.5(4) . .
O1 C1 Eu1 55.0(3) . .
O2 C1 Eu1 67.3(3) . .
C2 C1 Eu1 171.6(4) . .
C3 C2 C6 120.6(5) . .
C3 C2 C1 118.5(4) . .
C6 C2 C1 120.8(5) . .
C2 C3 C4 122.9(5) . .
C2 C3 H3A 118.5 . .
C4 C3 H3A 118.5 . .
O3 C4 N1 121.0(5) . .
O3 C4 C3 124.2(5) . .
N1 C4 C3 114.8(5) . .
N1 C5 C6 120.3(5) . .
N1 C5 C10 119.7(5) . .
C6 C5 C10 120.0(5) . .
C5 C6 C7 119.1(5) . .
C5 C6 C2 116.4(5) . .
C7 C6 C2 124.4(5) . .
C8 C7 C6 120.1(6) . .
C8 C7 H7 119.9 . .
C6 C7 H7 119.9 . .
C7 C8 C9 120.3(6) . .
C7 C8 H8 119.9 . .
C9 C8 H8 119.9 . .
C10 C9 C8 121.4(6) . .
C10 C9 H9 119.3 . .
C8 C9 H9 119.3 . .
C9 C10 C5 119.1(6) . .
C9 C10 H10 120.5 . .
C5 C10 H10 120.5 . .
O4 C11 O5 126.4(4) . .
O4 C11 C12 117.6(4) . .
O5 C11 C12 116.0(4) . .
C13 C12 C16 120.1(4) . .
C13 C12 C11 117.8(5) . .
C16 C12 C11 122.1(4) . .
C12 C13 C14 123.4(5) . .
C12 C13 H13 118.3 . .
C14 C13 H13 118.3 . .
O6 C14 N2 121.6(4) . .
O6 C14 C13 124.2(5) . .
N2 C14 C13 114.2(5) . .
N2 C15 C20 119.3(5) . .
N2 C15 C16 120.1(5) . .
C20 C15 C16 120.5(5) . .
C17 C16 C15 118.5(5) . .
C17 C16 C12 125.1(4) . .
C15 C16 C12 116.4(5) . .
C18 C17 C16 120.2(5) . .
C18 C17 H17 119.9 . .
C16 C17 H17 119.9 . .
C17 C18 C19 120.7(6) . .
C17 C18 H18 119.7 . .
C19 C18 H18 119.7 . .
C20 C19 C18 120.5(6) . .
C20 C19 H19 119.8 . .
C18 C19 H19 119.8 . .
C19 C20 C15 119.6(5) . .
C19 C20 H20 120.2 . .
C15 C20 H20 120.2 . .
O7 C21 O8 120.7(5) . .
O7 C21 C22 119.3(4) . .
O8 C21 C22 119.9(4) . .
O7 C21 Eu1 64.4(3) . .
O8 C21 Eu1 56.4(2) . .
C22 C21 Eu1 174.2(3) . .
C23 C22 C26 120.4(5) . .
C23 C22 C21 117.5(4) . .
C26 C22 C21 122.0(5) . .
C22 C23 C24 122.7(5) . .
C22 C23 H23 118.6 . .
C24 C23 H23 118.6 . .
O9 C24 N3 121.0(5) . .
O9 C24 C23 123.7(5) . .
N3 C24 C23 115.3(5) . .
N3 C25 C30 119.6(5) . .
N3 C25 C26 119.6(5) . .
C30 C25 C26 120.8(5) . .
C27 C26 C25 117.1(5) . .
C27 C26 C22 126.2(5) . .
C25 C26 C22 116.7(5) . .
C28 C27 C26 121.6(6) . .
C28 C27 H27 119.2 . .
C26 C27 H27 119.2 . .
C27 C28 C29 120.2(6) . .
C27 C28 H28 119.9 . .
C29 C28 H28 119.9 . .
C30 C29 C28 120.9(6) . .
C30 C29 H29 119.6 . .
C28 C29 H29 119.6 . .
C29 C30 C25 119.3(6) . .
C29 C30 H30 120.3 . .
C25 C30 H30 120.3 . .
O10 C31 N4 132.0(10) . .
O10 C31 H31 114.0 . .
N4 C31 H31 114.0 . .
N4 C32 H32A 109.5 . .
N4 C32 H32B 109.5 . .
H32A C32 H32B 109.5 . .
N4 C32 H32C 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
N4 C33 H33A 109.5 . .
N4 C33 H33B 109.5 . .
H33A C33 H33B 109.5 . .
N4 C33 H33C 109.5 . .
H33A C33 H33C 109.5 . .
H33B C33 H33C 109.5 . .
C11 O5 Eu1 139.0(3) . 2_775
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O2 2.370(4) 2_775
Eu1 O4 2.370(3) .
Eu1 O10 2.382(4) .
Eu1 O8 2.415(3) .
Eu1 O5 2.419(3) 2_775
Eu1 O11 2.424(4) .
Eu1 O1 2.486(4) .
Eu1 O7 2.589(3) .
Eu1 O2 2.753(4) .
Eu1 C21 2.872(5) .
Eu1 C1 2.983(5) .
Eu1 Eu1 4.1057(9) 2_775
O1 C1 1.245(6) .
O2 C1 1.251(6) .
O2 Eu1 2.370(4) 2_775
O3 C4 1.251(6) .
O4 C11 1.249(6) .
O6 C14 1.245(6) .
O7 C21 1.250(6) .
O8 C21 1.250(6) .
O9 C24 1.244(7) .
O10 C31 1.196(8) .
O11 H11B 0.73(6) .
O11 H11A 0.74(6) .
N1 C4 1.368(7) .
N1 C5 1.374(7) .
N1 H1 0.8600 .
N2 C14 1.360(7) .
N2 C15 1.374(7) .
N2 H2 0.8600 .
N3 C24 1.353(7) .
N3 C25 1.381(7) .
N3 H3 0.8600 .
N4 C31 1.259(10) .
N4 C33 1.381(9) .
N4 C32 1.513(11) .
C1 C2 1.512(7) .
C2 C3 1.345(7) .
C2 C6 1.450(7) .
C3 C4 1.438(7) .
C3 H3A 0.9300 .
C5 C6 1.402(7) .
C5 C10 1.403(8) .
C6 C7 1.412(8) .
C7 C8 1.358(8) .
C7 H7 0.9300 .
C8 C9 1.392(9) .
C8 H8 0.9300 .
C9 C10 1.367(9) .
C9 H9 0.9300 .
C10 H10 0.9300 .
C11 O5 1.258(6) .
C11 C12 1.511(7) .
C12 C13 1.346(7) .
C12 C16 1.463(7) .
C13 C14 1.450(7) .
C13 H13 0.9300 .
C15 C20 1.392(8) .
C15 C16 1.410(7) .
C16 C17 1.398(8) .
C17 C18 1.373(8) .
C17 H17 0.9300 .
C18 C19 1.391(8) .
C18 H18 0.9300 .
C19 C20 1.370(9) .
C19 H19 0.9300 .
C20 H20 0.9300 .
C21 C22 1.520(7) .
C22 C23 1.346(7) .
C22 C26 1.454(7) .
C23 C24 1.442(8) .
C23 H23 0.9300 .
C25 C30 1.403(8) .
C25 C26 1.412(8) .
C26 C27 1.396(8) .
C27 C28 1.363(8) .
C27 H27 0.9300 .
C28 C29 1.387(9) .
C28 H28 0.9300 .
C29 C30 1.355(9) .
C29 H29 0.9300 .
C30 H30 0.9300 .
C31 H31 0.9300 .
C32 H32A 0.9600 .
C32 H32B 0.9600 .
C32 H32C 0.9600 .
C33 H33A 0.9600 .
C33 H33B 0.9600 .
C33 H33C 0.9600 .
O5 Eu1 2.419(3) 2_775
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N1 H1 O9 0.86 1.95 2.810(6) 175.0 1_454
N2 H2 O7 0.86 1.99 2.848(5) 171.8 2_765
N3 H3 O3 0.86 2.00 2.853(6) 171.9 1_656
O11 H11B O3 0.73(6) 2.04(6) 2.769(5) 169(7) 2_675
O11 H11A O6 0.74(6) 2.02(6) 2.755(5) 174(6) 2_765
