#------------------------------------------------------------------------------
#$Date: 2016-03-24 02:15:46 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179565 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/34/4503416.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4503416
loop_
_publ_author_name
'Zhu, Xiandong'
'Lü, Jian'
'Li, Xiaoju'
'Gao, Shuiying'
'Li, Guoliang'
'Xiao, Fuxian'
'Cao, Rong'
_publ_section_title
;
 Syntheses, Structures, Near-Infrared, and Visible Luminescence of
 Lanthanide-Organic Frameworks with Flexible Macrocyclic Polyamine Ligands
;
_journal_issue                   6
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              1897
_journal_paper_doi               10.1021/cg701098t
_journal_volume                  8
_journal_year                    2008
_chemical_formula_sum            'C18 H34 Eu N5 O13'
_chemical_formula_weight         680.46
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                65.094(7)
_cell_angle_beta                 71.784(9)
_cell_angle_gamma                68.418(9)
_cell_formula_units_Z            2
_cell_length_a                   8.8994(12)
_cell_length_b                   11.8747(15)
_cell_length_c                   13.5596(19)
_cell_measurement_reflns_used    3692
_cell_measurement_temperature    294.1500
_cell_measurement_theta_max      27.4835
_cell_measurement_theta_min      2.5052
_cell_volume                     1187.3(3)
_computing_cell_refinement       'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_data_collection       'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_data_reduction        'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      294.1500
_diffrn_measured_fraction_theta_full 0.976
_diffrn_measured_fraction_theta_max 0.976
_diffrn_measurement_device_type  'mercury CCD'
_diffrn_measurement_method       dtprofit.ref
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0209
_diffrn_reflns_av_sigmaI/netI    0.0339
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            9322
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         2.10
_exptl_absorpt_coefficient_mu    2.720
_exptl_absorpt_correction_T_max  0.013
_exptl_absorpt_correction_T_min  0.002
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.903
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             688
_exptl_crystal_size_max          0.1100
_exptl_crystal_size_mid          0.0900
_exptl_crystal_size_min          0.0600
_refine_diff_density_max         2.072
_refine_diff_density_min         -0.745
_refine_diff_density_rms         0.196
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.172
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     342
_refine_ls_number_reflns         5333
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.172
_refine_ls_R_factor_all          0.0348
_refine_ls_R_factor_gt           0.0306
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0468P)²+1.9713P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0766
_refine_ls_wR_factor_ref         0.0910
_reflns_number_gt                4882
_reflns_number_total             5333
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg701098t-file002.cif
_cod_data_source_block           CCDC_661349_Eu
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4503416
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.24283(2) -0.000417(18) 0.011008(14) 0.01660(8) Uani 1 1 d .
O1 O 0.2921(4) 0.0516(3) 0.1514(2) 0.0225(6) Uani 1 1 d .
O2 O 0.5316(3) 0.0956(3) 0.1187(2) 0.0225(6) Uani 1 1 d .
O3 O -0.0457(3) 0.0537(3) 0.8216(2) 0.0241(6) Uani 1 1 d .
O4 O 0.1680(4) 0.1076(3) 0.8271(2) 0.0243(6) Uani 1 1 d .
O5 O 0.0607(4) 0.2238(3) -0.0053(2) 0.0240(6) Uani 1 1 d .
O6 O -0.1289(4) 0.1392(3) 0.0054(2) 0.0275(7) Uani 1 1 d .
O7 O -0.6289(3) 0.7872(3) 0.1401(3) 0.0259(6) Uani 1 1 d .
O8 O -0.4103(4) 0.8605(3) 0.0795(2) 0.0265(7) Uani 1 1 d .
O9 O 0.6123(9) -0.2759(7) 0.6073(7) 0.112(2) Uani 1 1 d .
O10 O 0.5593(18) -0.4357(12) 0.6428(13) 0.264(8) Uani 1 1 d .
O11 O 0.7479(13) -0.3952(8) 0.5202(9) 0.170(5) Uani 1 1 d .
N1 N 0.2711(4) -0.0251(4) 0.3813(3) 0.0225(7) Uani 1 1 d .
N2 N 0.0204(4) 0.1261(4) 0.5980(3) 0.0218(7) Uani 1 1 d .
N3 N -0.1346(5) 0.4761(4) -0.0967(4) 0.0350(9) Uani 1 1 d .
N4 N -0.2227(5) 0.5922(4) 0.1678(4) 0.0369(10) Uani 1 1 d .
N5 N 0.6395(8) -0.3762(6) 0.5942(5) 0.0570(14) Uani 1 1 d .
C1 C 0.4024(5) 0.0674(4) 0.1797(3) 0.0182(8) Uani 1 1 d .
C2 C 0.3734(6) 0.0591(5) 0.2997(3) 0.0270(9) Uani 1 1 d .
H2A H 0.4817 0.0281 0.3219 0.032 Uiso 1 1 calc R
H2B H 0.3210 0.1473 0.3028 0.032 Uiso 1 1 calc R
C3 C 0.2390(5) -0.0053(4) 0.4881(3) 0.0264(10) Uani 1 1 d .
H3A H 0.3412 -0.0021 0.5003 0.032 Uiso 1 1 calc R
H3B H 0.2027 -0.0781 0.5499 0.032 Uiso 1 1 calc R
C4 C 0.1063(5) 0.1205(4) 0.4849(3) 0.0262(9) Uani 1 1 d .
H4A H 0.1567 0.1932 0.4438 0.031 Uiso 1 1 calc R
H4B H 0.0241 0.1315 0.4441 0.031 Uiso 1 1 calc R
C5 C 0.1413(5) 0.1222(5) 0.6560(3) 0.0272(9) Uani 1 1 d .
H5A H 0.1664 0.2067 0.6230 0.033 Uiso 1 1 calc R
H5B H 0.2448 0.0557 0.6437 0.033 Uiso 1 1 calc R
C6 C 0.0796(5) 0.0925(4) 0.7802(3) 0.0193(8) Uani 1 1 d .
C7 C -0.1231(6) 0.2457(4) 0.5928(4) 0.0297(10) Uani 1 1 d .
H7A H -0.0811 0.3226 0.5496 0.036 Uiso 1 1 calc R
H7B H -0.1705 0.2471 0.6688 0.036 Uiso 1 1 calc R
C8 C 0.3604(5) -0.1590(5) 0.3917(4) 0.0281(9) Uani 1 1 d .
H8A H 0.4557 -0.1845 0.4269 0.034 Uiso 1 1 calc R
H8B H 0.4041 -0.1639 0.3165 0.034 Uiso 1 1 calc R
C9 C 0.2598(6) -0.2568(5) 0.4585(4) 0.0312(10) Uani 1 1 d .
H9A H 0.3360 -0.3447 0.4706 0.037 Uiso 1 1 calc R
H9B H 0.2104 -0.2478 0.5320 0.037 Uiso 1 1 calc R
C10 C -0.0766(5) 0.2342(4) -0.0214(3) 0.0216(8) Uani 1 1 d .
C11 C -0.1863(7) 0.3650(5) -0.0755(6) 0.0496(16) Uani 1 1 d .
H11A H -0.1976 0.3676 -0.1468 0.060 Uiso 1 1 calc R
H11B H -0.2969 0.3732 -0.0278 0.060 Uiso 1 1 calc R
C12 C -0.2706(8) 0.5796(5) -0.0634(7) 0.0575(18) Uani 1 1 d .
H12A H -0.2276 0.6536 -0.0824 0.069 Uiso 1 1 calc R
H12B H -0.3569 0.6096 -0.1075 0.069 Uiso 1 1 calc R
C13 C -0.3466(8) 0.5416(11) 0.0547(8) 0.094(4) Uani 1 1 d .
H13A H -0.4022 0.4754 0.0712 0.113 Uiso 1 1 calc R
H13B H -0.4323 0.6178 0.0683 0.113 Uiso 1 1 calc R
C14 C -0.2255(9) 0.4863(7) 0.1381(7) 0.0618(19) Uani 1 1 d .
H14A H -0.2622 0.4184 0.2057 0.074 Uiso 1 1 calc R
H14B H -0.1134 0.4471 0.1037 0.074 Uiso 1 1 calc R
C15 C -0.3878(6) 0.6554(5) 0.2179(5) 0.0434(14) Uani 1 1 d .
H15A H -0.3760 0.6790 0.2764 0.052 Uiso 1 1 calc R
H15B H -0.4534 0.5921 0.2541 0.052 Uiso 1 1 calc R
C16 C -0.4832(5) 0.7757(4) 0.1381(3) 0.0193(8) Uani 1 1 d .
C17 C -0.1043(8) 0.5370(8) 0.2483(5) 0.067(2) Uani 1 1 d .
H17A H -0.0938 0.6091 0.2619 0.081 Uiso 1 1 calc R
H17B H -0.1526 0.4802 0.3197 0.081 Uiso 1 1 calc R
C18 C -0.0611(8) 0.5371(8) -0.2098(6) 0.0632(19) Uani 1 1 d .
H18A H -0.0549 0.6220 -0.2176 0.076 Uiso 1 1 calc R
H18B H -0.1345 0.5530 -0.2589 0.076 Uiso 1 1 calc R
H2D H 0.597(7) 0.230(5) 0.251(5) 0.022(15) Uiso 1 1 d .
H2N H -0.008(5) 0.060(4) 0.637(4) 0.010(10) Uiso 1 1 d .
OW1 O -0.0344(4) 0.1628(4) 0.2671(3) 0.0378(8) Uani 1 1 d .
OW2 O 0.6625(6) 0.2133(5) 0.2136(4) 0.0527(12) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O8 Eu1 O6 145.83(11) 2_565 2
O8 Eu1 O3 139.02(11) 2_565 2_556
O6 Eu1 O3 74.46(10) 2 2_556
O8 Eu1 O1 72.75(10) 2_565 .
O6 Eu1 O1 140.62(10) 2 .
O3 Eu1 O1 69.82(10) 2_556 .
O8 Eu1 O4 78.10(10) 2_565 1_554
O6 Eu1 O4 74.99(11) 2 1_554
O3 Eu1 O4 122.84(10) 2_556 1_554
O1 Eu1 O4 139.68(10) . 1_554
O8 Eu1 O7 114.68(10) 2_565 1_645
O6 Eu1 O7 77.58(11) 2 1_645
O3 Eu1 O7 71.35(10) 2_556 1_645
O1 Eu1 O7 75.80(10) . 1_645
O4 Eu1 O7 143.10(11) 1_554 1_645
O8 Eu1 O2 73.58(10) 2_565 2_655
O6 Eu1 O2 78.42(10) 2 2_655
O3 Eu1 O2 142.88(10) 2_556 2_655
O1 Eu1 O2 123.07(9) . 2_655
O4 Eu1 O2 72.26(10) 1_554 2_655
O7 Eu1 O2 78.46(10) 1_645 2_655
O8 Eu1 O5 72.80(10) 2_565 .
O6 Eu1 O5 116.44(11) 2 .
O3 Eu1 O5 81.48(10) 2_556 .
O1 Eu1 O5 74.27(10) . .
O4 Eu1 O5 70.85(10) 1_554 .
O7 Eu1 O5 144.96(10) 1_645 .
O2 Eu1 O5 134.03(10) 2_655 .
O8 Eu1 O6 113.26(10) 2_565 .
O6 Eu1 O6 72.63(11) 2 .
O3 Eu1 O6 61.35(9) 2_556 .
O1 Eu1 O6 103.16(9) . .
O4 Eu1 O6 63.91(9) 1_554 .
O7 Eu1 O6 129.00(9) 1_645 .
O2 Eu1 O6 132.10(9) 2_655 .
O5 Eu1 O6 44.44(9) . .
O8 Eu1 O8 70.47(11) 2_565 1_645
O6 Eu1 O8 112.98(10) 2 1_645
O3 Eu1 O8 105.89(9) 2_556 1_645
O1 Eu1 O8 63.41(9) . 1_645
O4 Eu1 O8 130.35(9) 1_554 1_645
O7 Eu1 O8 44.28(9) 1_645 1_645
O2 Eu1 O8 62.65(9) 2_655 1_645
O5 Eu1 O8 130.11(9) . 1_645
O6 Eu1 O8 165.07(8) . 1_645
O8 Eu1 C16 93.24(11) 2_565 1_645
O6 Eu1 C16 94.83(11) 2 1_645
O3 Eu1 C16 88.13(10) 2_556 1_645
O1 Eu1 C16 68.33(10) . 1_645
O4 Eu1 C16 141.47(10) 1_554 1_645
O7 Eu1 C16 21.48(10) 1_645 1_645
O2 Eu1 C16 69.29(10) 2_655 1_645
O5 Eu1 C16 142.50(10) . 1_645
O6 Eu1 C16 148.93(9) . 1_645
O8 Eu1 C16 22.80(9) 1_645 1_645
O8 Eu1 Eu1 135.75(8) 2_565 2
O6 Eu1 Eu1 42.29(8) 2 2
O3 Eu1 Eu1 61.33(7) 2_556 2
O1 Eu1 Eu1 124.72(7) . 2
O4 Eu1 Eu1 63.44(7) 1_554 2
O7 Eu1 Eu1 109.26(7) 1_645 2
O2 Eu1 Eu1 111.50(7) 2_655 2
O5 Eu1 Eu1 74.47(7) . 2
O6 Eu1 Eu1 30.34(6) . 2
O8 Eu1 Eu1 152.61(6) 1_645 2
C16 Eu1 Eu1 130.43(7) 1_645 2
C1 O1 Eu1 142.3(2) . .
C1 O2 Eu1 133.4(3) . 2_655
C6 O3 Eu1 143.4(3) . 2_556
C6 O4 Eu1 134.2(3) . 1_556
C10 O5 Eu1 108.9(3) . .
C10 O6 Eu1 158.9(3) . 2
C10 O6 Eu1 80.3(3) . .
Eu1 O6 Eu1 107.37(11) 2 .
C16 O7 Eu1 111.8(3) . 1_465
C16 O8 Eu1 170.6(3) . 2_565
C16 O8 Eu1 79.4(2) . 1_465
Eu1 O8 Eu1 109.53(11) 2_565 1_465
C8 N1 C2 108.9(3) . .
C8 N1 C3 110.8(3) . .
C2 N1 C3 107.1(3) . .
C5 N2 C4 109.2(3) . .
C5 N2 C7 110.1(4) . .
C4 N2 C7 112.0(3) . .
C5 N2 H2N 103(3) . .
C4 N2 H2N 110(3) . .
C7 N2 H2N 112(3) . .
C11 N3 C18 116.1(6) . .
C11 N3 C12 112.8(4) . .
C18 N3 C12 106.3(5) . .
C15 N4 C14 111.9(5) . .
C15 N4 C17 110.0(5) . .
C14 N4 C17 108.8(5) . .
O10 N5 O11 124.9(12) . .
O10 N5 O9 118.7(12) . .
O11 N5 O9 116.1(8) . .
O2 C1 O1 127.0(3) . .
O2 C1 C2 115.7(4) . .
O1 C1 C2 117.3(3) . .
N1 C2 C1 115.7(4) . .
N1 C2 H2A 108.3 . .
C1 C2 H2A 108.3 . .
N1 C2 H2B 108.3 . .
C1 C2 H2B 108.3 . .
H2A C2 H2B 107.4 . .
N1 C3 C4 109.2(3) . .
N1 C3 H3A 109.8 . .
C4 C3 H3A 109.8 . .
N1 C3 H3B 109.8 . .
C4 C3 H3B 109.8 . .
H3A C3 H3B 108.3 . .
N2 C4 C3 113.1(3) . .
N2 C4 H4A 109.0 . .
C3 C4 H4A 109.0 . .
N2 C4 H4B 109.0 . .
C3 C4 H4B 109.0 . .
H4A C4 H4B 107.8 . .
N2 C5 C6 113.3(3) . .
N2 C5 H5A 108.9 . .
C6 C5 H5A 108.9 . .
N2 C5 H5B 108.9 . .
C6 C5 H5B 108.9 . .
H5A C5 H5B 107.7 . .
O3 C6 O4 128.9(4) . .
O3 C6 C5 117.2(4) . .
O4 C6 C5 113.9(3) . .
N2 C7 C9 115.1(4) . 2_556
N2 C7 H7A 108.5 . .
C9 C7 H7A 108.5 2_556 .
N2 C7 H7B 108.5 . .
C9 C7 H7B 108.5 2_556 .
H7A C7 H7B 107.5 . .
N1 C8 C9 115.3(4) . .
N1 C8 H8A 108.4 . .
C9 C8 H8A 108.4 . .
N1 C8 H8B 108.4 . .
C9 C8 H8B 108.4 . .
H8A C8 H8B 107.5 . .
C7 C9 C8 116.1(4) 2_556 .
C7 C9 H9A 108.3 2_556 .
C8 C9 H9A 108.3 . .
C7 C9 H9B 108.3 2_556 .
C8 C9 H9B 108.3 . .
H9A C9 H9B 107.4 . .
O6 C10 O5 122.7(4) . .
O6 C10 C11 116.6(4) . .
O5 C10 C11 120.6(4) . .
N3 C11 C10 117.0(4) . .
N3 C11 H11A 108.0 . .
C10 C11 H11A 108.0 . .
N3 C11 H11B 108.0 . .
C10 C11 H11B 108.0 . .
H11A C11 H11B 107.3 . .
C13 C12 N3 114.9(6) . .
C13 C12 H12A 108.5 . .
N3 C12 H12A 108.5 . .
C13 C12 H12B 108.5 . .
N3 C12 H12B 108.5 . .
H12A C12 H12B 107.5 . .
C12 C13 C14 115.7(6) . .
C12 C13 H13A 108.4 . .
C14 C13 H13A 108.4 . .
C12 C13 H13B 108.4 . .
C14 C13 H13B 108.4 . .
H13A C13 H13B 107.4 . .
N4 C14 C13 109.5(6) . .
N4 C14 H14A 109.8 . .
C13 C14 H14A 109.8 . .
N4 C14 H14B 109.8 . .
C13 C14 H14B 109.8 . .
H14A C14 H14B 108.2 . .
N4 C15 C16 115.4(4) . .
N4 C15 H15A 108.4 . .
C16 C15 H15A 108.4 . .
N4 C15 H15B 108.4 . .
C16 C15 H15B 108.4 . .
H15A C15 H15B 107.5 . .
O7 C16 O8 124.5(4) . .
O7 C16 C15 119.4(4) . .
O8 C16 C15 116.0(4) . .
O7 C16 Eu1 46.7(2) . 1_465
O8 C16 Eu1 77.8(2) . 1_465
C15 C16 Eu1 165.7(3) . 1_465
C18 C17 N4 114.5(6) 2_565 .
C18 C17 H17A 108.6 2_565 .
N4 C17 H17A 108.6 . .
C18 C17 H17B 108.6 2_565 .
N4 C17 H17B 108.6 . .
H17A C17 H17B 107.6 . .
N3 C18 C17 115.1(6) . 2_565
N3 C18 H18A 108.5 . .
C17 C18 H18A 108.5 2_565 .
N3 C18 H18B 108.5 . .
C17 C18 H18B 108.5 2_565 .
H18A C18 H18B 107.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O8 2.334(3) 2_565
Eu1 O6 2.340(3) 2
Eu1 O3 2.397(3) 2_556
Eu1 O1 2.430(3) .
Eu1 O4 2.454(3) 1_554
Eu1 O7 2.478(3) 1_645
Eu1 O2 2.490(3) 2_655
Eu1 O5 2.513(3) .
Eu1 O6 3.117(3) .
Eu1 O8 3.141(3) 1_645
Eu1 C16 3.160(4) 1_645
Eu1 Eu1 4.4207(7) 2
O1 C1 1.256(5) .
O2 C1 1.255(5) .
O2 Eu1 2.490(3) 2_655
O3 C6 1.241(5) .
O3 Eu1 2.397(3) 2_556
O4 C6 1.252(5) .
O4 Eu1 2.454(3) 1_556
O5 C10 1.261(5) .
O6 C10 1.247(5) .
O6 Eu1 2.340(3) 2
O7 C16 1.246(5) .
O7 Eu1 2.478(3) 1_465
O8 C16 1.245(5) .
O8 Eu1 2.334(3) 2_565
O8 Eu1 3.141(3) 1_465
O9 N5 1.203(8) .
O10 N5 1.062(9) .
O11 N5 1.190(10) .
N1 C8 1.460(6) .
N1 C2 1.471(5) .
N1 C3 1.487(5) .
N2 C5 1.497(5) .
N2 C4 1.502(5) .
N2 C7 1.514(6) .
N2 H2N 0.82(5) .
N3 C11 1.442(7) .
N3 C18 1.446(8) .
N3 C12 1.486(7) .
N4 C15 1.476(6) .
N4 C14 1.483(7) .
N4 C17 1.529(8) .
C1 C2 1.533(5) .
C2 H2A 0.9900 .
C2 H2B 0.9900 .
C3 C4 1.519(6) .
C3 H3A 0.9900 .
C3 H3B 0.9900 .
C4 H4A 0.9900 .
C4 H4B 0.9900 .
C5 C6 1.526(5) .
C5 H5A 0.9900 .
C5 H5B 0.9900 .
C7 C9 1.521(7) 2_556
C7 H7A 0.9900 .
C7 H7B 0.9900 .
C8 C9 1.531(7) .
C8 H8A 0.9900 .
C8 H8B 0.9900 .
C9 C7 1.521(7) 2_556
C9 H9A 0.9900 .
C9 H9B 0.9900 .
C10 C11 1.508(7) .
C11 H11A 0.9900 .
C11 H11B 0.9900 .
C12 C13 1.471(12) .
C12 H12A 0.9900 .
C12 H12B 0.9900 .
C13 C14 1.578(11) .
C13 H13A 0.9900 .
C13 H13B 0.9900 .
C14 H14A 0.9900 .
C14 H14B 0.9900 .
C15 C16 1.521(6) .
C15 H15A 0.9900 .
C15 H15B 0.9900 .
C16 Eu1 3.160(4) 1_465
C17 C18 1.472(9) 2_565
C17 H17A 0.9900 .
C17 H17B 0.9900 .
C18 C17 1.472(9) 2_565
C18 H18A 0.9900 .
C18 H18B 0.9900 .
OW2 H2D 0.68(5) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O8 Eu1 O1 C1 -40.9(4) 2_565 .
O6 Eu1 O1 C1 129.9(4) 2 .
O3 Eu1 O1 C1 156.1(5) 2_556 .
O4 Eu1 O1 C1 -86.5(5) 1_554 .
O7 Eu1 O1 C1 81.1(4) 1_645 .
O2 Eu1 O1 C1 15.3(5) 2_655 .
O5 Eu1 O1 C1 -117.4(4) . .
O6 Eu1 O1 C1 -151.5(4) . .
O8 Eu1 O1 C1 35.4(4) 1_645 .
C16 Eu1 O1 C1 59.9(4) 1_645 .
Eu1 Eu1 O1 C1 -175.1(4) 2 .
O8 Eu1 O5 C10 144.3(3) 2_565 .
O6 Eu1 O5 C10 -0.2(3) 2 .
O3 Eu1 O5 C10 -68.0(3) 2_556 .
O1 Eu1 O5 C10 -139.4(3) . .
O4 Eu1 O5 C10 61.2(3) 1_554 .
O7 Eu1 O5 C10 -107.1(3) 1_645 .
O2 Eu1 O5 C10 99.6(3) 2_655 .
O6 Eu1 O5 C10 -10.7(2) . .
O8 Eu1 O5 C10 -171.7(2) 1_645 .
C16 Eu1 O5 C10 -143.6(3) 1_645 .
Eu1 Eu1 O5 C10 -5.5(2) 2 .
O8 Eu1 O6 C10 -15.8(3) 2_565 .
O6 Eu1 O6 C10 -159.8(3) 2 .
O3 Eu1 O6 C10 118.8(3) 2_556 .
O1 Eu1 O6 C10 60.9(2) . .
O4 Eu1 O6 C10 -78.4(2) 1_554 .
O7 Eu1 O6 C10 143.1(2) 1_645 .
O2 Eu1 O6 C10 -104.3(3) 2_655 .
O5 Eu1 O6 C10 10.4(2) . .
O8 Eu1 O6 C10 85.7(4) 1_645 .
C16 Eu1 O6 C10 130.6(3) 1_645 .
Eu1 Eu1 O6 C10 -159.8(3) 2 .
O8 Eu1 O6 Eu1 144.01(12) 2_565 2
O6 Eu1 O6 Eu1 0.0 2 2
O3 Eu1 O6 Eu1 -81.44(13) 2_556 2
O1 Eu1 O6 Eu1 -139.34(11) . 2
O4 Eu1 O6 Eu1 81.43(13) 1_554 2
O7 Eu1 O6 Eu1 -57.10(16) 1_645 2
O2 Eu1 O6 Eu1 55.53(16) 2_655 2
O5 Eu1 O6 Eu1 170.15(18) . 2
O8 Eu1 O6 Eu1 -114.5(3) 1_645 2
C16 Eu1 O6 Eu1 -69.6(2) 1_645 2
Eu1 O2 C1 O1 -52.7(6) 2_655 .
Eu1 O2 C1 C2 131.0(3) 2_655 .
Eu1 O1 C1 O2 22.5(7) . .
Eu1 O1 C1 C2 -161.2(3) . .
C8 N1 C2 C1 67.9(5) . .
C3 N1 C2 C1 -172.2(4) . .
O2 C1 C2 N1 -154.2(4) . .
O1 C1 C2 N1 29.1(6) . .
C8 N1 C3 C4 -163.7(4) . .
C2 N1 C3 C4 77.7(4) . .
C5 N2 C4 C3 64.1(5) . .
C7 N2 C4 C3 -173.8(4) . .
N1 C3 C4 N2 158.2(4) . .
C4 N2 C5 C6 -165.1(4) . .
C7 N2 C5 C6 71.6(5) . .
Eu1 O3 C6 O4 9.2(8) 2_556 .
Eu1 O3 C6 C5 -173.2(3) 2_556 .
Eu1 O4 C6 O3 31.2(7) 1_556 .
Eu1 O4 C6 C5 -146.4(3) 1_556 .
N2 C5 C6 O3 12.1(6) . .
N2 C5 C6 O4 -170.0(4) . .
C5 N2 C7 C9 -176.6(4) . 2_556
C4 N2 C7 C9 61.8(5) . 2_556
C2 N1 C8 C9 -170.0(4) . .
C3 N1 C8 C9 72.5(5) . .
N1 C8 C9 C7 67.3(5) . 2_556
Eu1 O6 C10 O5 -130.9(7) 2 .
Eu1 O6 C10 O5 -17.4(4) . .
Eu1 O6 C10 C11 48.9(10) 2 .
Eu1 O6 C10 C11 162.4(4) . .
Eu1 O5 C10 O6 22.7(5) . .
Eu1 O5 C10 C11 -157.1(4) . .
C18 N3 C11 C10 102.5(6) . .
C12 N3 C11 C10 -134.3(6) . .
O6 C10 C11 N3 174.0(5) . .
O5 C10 C11 N3 -6.2(8) . .
C11 N3 C12 C13 60.1(7) . .
C18 N3 C12 C13 -171.5(6) . .
N3 C12 C13 C14 56.2(9) . .
C15 N4 C14 C13 58.5(7) . .
C17 N4 C14 C13 -179.8(6) . .
C12 C13 C14 N4 93.9(8) . .
C14 N4 C15 C16 -94.7(6) . .
C17 N4 C15 C16 144.3(6) . .
Eu1 O7 C16 O8 0.6(5) 1_465 .
Eu1 O7 C16 C15 175.7(3) 1_465 .
Eu1 O8 C16 O7 162.8(15) 2_565 .
Eu1 O8 C16 O7 -0.5(4) 1_465 .
Eu1 O8 C16 C15 -12.3(19) 2_565 .
Eu1 O8 C16 C15 -175.7(4) 1_465 .
Eu1 O8 C16 Eu1 163.3(17) 2_565 1_465
N4 C15 C16 O7 131.9(5) . .
N4 C15 C16 O8 -52.6(7) . .
N4 C15 C16 Eu1 144.7(11) . 1_465
C15 N4 C17 C18 175.5(6) . 2_565
C14 N4 C17 C18 52.6(8) . 2_565
C11 N3 C18 C17 -71.2(8) . 2_565
C12 N3 C18 C17 162.3(6) . 2_565
