#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/37/4503726.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4503726
loop_
_publ_author_name
'Chen, Xiao-Li'
'Zhang, Bo'
'Hu, Huai-Ming'
'Fu, Feng'
'Wu, Xing-Long'
'Qin, Ting'
'Yang, Meng-Lin'
'Xue, Gang-Lin'
'Wang, Ji-Wu'
_publ_section_title
;
 Three Novel Heterobimetallic Cd/Zn−Na Coordination Polymers:
 Syntheses, Crystal Structure, and Luminescence
;
_journal_issue                   10
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              3706
_journal_paper_doi               10.1021/cg8003257
_journal_volume                  8
_journal_year                    2008
_chemical_formula_sum            'C32 H25 Cd3 Na2 O24.5'
_chemical_formula_weight         1184.70
_chemical_name_systematic
;

 ?

;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                104.344(5)
_cell_angle_beta                 97.349(6)
_cell_angle_gamma                105.907(6)
_cell_formula_units_Z            2
_cell_length_a                   8.649(4)
_cell_length_b                   14.763(6)
_cell_length_c                   16.033(7)
_cell_measurement_reflns_used    1933
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      23.05
_cell_measurement_theta_min      2.29
_cell_volume                     1864.8(14)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.967
_diffrn_measured_fraction_theta_max 0.967
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0375
_diffrn_reflns_av_sigmaI/netI    0.0863
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            9176
_diffrn_reflns_theta_full        25.05
_diffrn_reflns_theta_max         25.05
_diffrn_reflns_theta_min         1.34
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.818
_exptl_absorpt_correction_T_max  0.890
_exptl_absorpt_correction_T_min  0.793
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.110
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1158
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.06
_refine_diff_density_max         1.956
_refine_diff_density_min         -1.241
_refine_diff_density_rms         0.227
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.070
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     559
_refine_ls_number_reflns         6393
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.069
_refine_ls_R_factor_all          0.0980
_refine_ls_R_factor_gt           0.0734
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0410P)²+55.8551P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1818
_refine_ls_wR_factor_ref         0.1961
_reflns_number_gt                4633
_reflns_number_total             6393
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg8003257_si_004.cif
_cod_data_source_block           nwh006
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        1864.7(14)
_cod_original_sg_symbol_H-M      P-1
_cod_original_formula_sum        'C32 H25 Cd3 Na2 O24.50'
_cod_database_code               4503726
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Cd1 Cd 0.76379(12) 0.46542(7) -0.00184(6) 0.0258(3) Uani 1 1 d .
Cd2 Cd 0.32799(13) 0.81269(7) 0.13929(6) 0.0268(3) Uani 1 1 d .
Cd3 Cd 0.74416(12) 0.04198(7) 0.56738(6) 0.0243(3) Uani 1 1 d .
Na1 Na 0.7687(8) 0.7647(5) 0.1317(4) 0.0494(16) Uani 1 1 d .
Na2 Na 0.6051(7) 0.8754(4) 0.3519(3) 0.0370(13) Uani 1 1 d .
O1 O 0.5882(13) 0.4378(7) 0.0860(6) 0.038(2) Uani 1 1 d .
O2 O 0.7309(13) 0.5951(7) 0.1229(7) 0.038(2) Uani 1 1 d .
O3 O 0.4340(12) 0.6458(7) 0.1190(5) 0.031(2) Uani 1 1 d .
O4 O 0.4162(12) 0.7467(7) 0.2416(6) 0.029(2) Uani 1 1 d .
O5 O 0.5784(14) 0.4254(6) 0.4018(6) 0.040(3) Uani 1 1 d .
O6 O 0.5249(15) 0.1089(8) 0.5139(6) 0.043(3) Uani 1 1 d .
O7 O 0.7345(12) 0.1080(7) 0.4502(6) 0.036(2) Uani 1 1 d .
O8 O 0.4134(11) -0.0383(6) 0.3268(6) 0.027(2) Uani 1 1 d .
O9 O 0.3354(13) -0.0302(7) 0.1918(6) 0.037(2) Uani 1 1 d .
O10 O 0.9793(13) 0.4806(7) -0.1031(7) 0.041(3) Uani 1 1 d .
O11 O 0.8197(13) 0.5737(8) -0.0787(6) 0.041(3) Uani 1 1 d .
O12 O 1.1877(12) 0.6829(6) 0.0083(6) 0.030(2) Uani 1 1 d .
O13 O 1.2801(19) 0.8317(8) -0.0038(7) 0.070(4) Uani 1 1 d .
O14 O 0.9196(14) 0.5923(6) -0.4014(6) 0.039(3) Uani 1 1 d .
O15 O 0.8515(12) 0.9229(7) -0.3952(6) 0.034(2) Uani 1 1 d .
O16 O 0.8229(11) 0.9262(6) -0.5323(6) 0.026(2) Uani 1 1 d .
O17 O 1.0591(11) 0.8400(6) -0.6689(6) 0.030(2) Uani 1 1 d .
O18 O 0.7858(11) 0.7869(6) -0.7078(6) 0.028(2) Uani 1 1 d .
C1 C 0.6317(17) 0.5260(10) 0.1370(8) 0.028(3) Uani 1 1 d .
C2 C 0.5677(16) 0.5376(8) 0.2222(8) 0.022(3) Uani 1 1 d .
C3 C 0.5964(17) 0.4771(9) 0.2702(9) 0.030(3) Uani 1 1 d .
H3 H 0.6480 0.4312 0.2490 0.036 Uiso 1 1 calc R
C4 C 0.5483(18) 0.4840(9) 0.3518(8) 0.027(3) Uani 1 1 d .
C5 C 0.4810(17) 0.5547(9) 0.3851(8) 0.027(3) Uani 1 1 d .
H5 H 0.4547 0.5619 0.4403 0.033 Uiso 1 1 calc R
C6 C 0.4519(18) 0.6157(10) 0.3362(9) 0.031(3) Uani 1 1 d .
H6 H 0.4035 0.6628 0.3588 0.037 Uiso 1 1 calc R
C7 C 0.4927(15) 0.6089(9) 0.2541(8) 0.021(3) Uani 1 1 d .
C8 C 0.4430(15) 0.6709(8) 0.2007(8) 0.020(3) Uani 1 1 d .
C9 C 0.6011(17) 0.1247(9) 0.4548(8) 0.026(3) Uani 1 1 d .
C10 C 0.5376(14) 0.1725(9) 0.3914(8) 0.020(3) Uani 1 1 d .
C11 C 0.5829(17) 0.2748(9) 0.4212(9) 0.026(3) Uani 1 1 d .
H11 H 0.6494 0.3097 0.4766 0.031 Uiso 1 1 calc R
C12 C 0.5260(18) 0.3243(9) 0.3656(8) 0.028(3) Uani 1 1 d .
C13 C 0.4240(19) 0.2736(10) 0.2843(8) 0.033(3) Uani 1 1 d .
H13 H 0.3829 0.3072 0.2496 0.039 Uiso 1 1 calc R
C14 C 0.3835(17) 0.1718(10) 0.2549(9) 0.032(3) Uani 1 1 d .
H14 H 0.3160 0.1372 0.1997 0.038 Uiso 1 1 calc R
C15 C 0.4434(16) 0.1200(9) 0.3078(8) 0.021(3) Uani 1 1 d .
C16 C 0.3934(16) 0.0093(9) 0.2741(8) 0.023(3) Uani 1 1 d .
C17 C 0.9327(17) 0.5521(10) -0.1123(9) 0.030(3) Uani 1 1 d .
C18 C 1.0066(16) 0.6122(9) -0.1689(8) 0.025(3) Uani 1 1 d .
C19 C 0.9387(18) 0.5772(10) -0.2587(9) 0.031(3) Uani 1 1 d .
H19 H 0.8564 0.5165 -0.2821 0.037 Uiso 1 1 calc R
C20 C 0.9950(18) 0.6339(9) -0.3138(8) 0.027(3) Uani 1 1 d .
C21 C 1.1199(17) 0.7237(10) -0.2798(9) 0.030(3) Uani 1 1 d .
H21A H 1.1571 0.7615 -0.3161 0.036 Uiso 1 1 calc R
C22 C 1.1882(18) 0.7556(11) -0.1899(9) 0.035(3) Uani 1 1 d .
H22A H 1.2736 0.8149 -0.1668 0.042 Uiso 1 1 calc R
C23 C 1.1338(17) 0.7025(9) -0.1342(8) 0.027(3) Uani 1 1 d .
C24 C 1.2089(18) 0.7426(10) -0.0379(9) 0.031(3) Uani 1 1 d .
C25 C 0.8512(15) 0.8847(9) -0.4739(8) 0.021(3) Uani 1 1 d .
C26 C 0.8858(15) 0.7899(9) -0.5001(8) 0.023(3) Uani 1 1 d .
C27 C 0.8886(17) 0.7370(10) -0.4390(9) 0.029(3) Uani 1 1 d .
H27 H 0.8668 0.7612 -0.3840 0.034 Uiso 1 1 calc R
C28 C 0.9228(18) 0.6506(10) -0.4592(8) 0.028(3) Uani 1 1 d .
C29 C 0.9536(18) 0.6125(10) -0.5394(9) 0.032(3) Uani 1 1 d .
H29 H 0.9771 0.5533 -0.5522 0.038 Uiso 1 1 calc R
C30 C 0.9495(17) 0.6634(9) -0.6028(8) 0.026(3) Uani 1 1 d .
H30 H 0.9724 0.6384 -0.6574 0.032 Uiso 1 1 calc R
C31 C 0.9115(15) 0.7509(9) -0.5843(8) 0.023(3) Uani 1 1 d .
C32 C 0.9134(16) 0.7970(9) -0.6560(8) 0.024(3) Uani 1 1 d .
O19 O 0.0649(12) 0.7529(8) 0.1672(7) 0.043(3) Uani 1 1 d .
O20 O 0.6099(13) 0.8829(8) 0.1380(7) 0.043(3) Uani 1 1 d .
O21 O 0.974(2) 0.9356(16) 0.1477(17) 0.143(8) Uani 1 1 d .
O22 O 0.6987(18) 0.7301(9) -0.0273(8) 0.067(4) Uani 1 1 d .
O23 O 0.7907(15) 1.0084(9) 0.2948(8) 0.058(3) Uani 1 1 d .
O24 O 0.674(4) 0.9642(18) 0.0060(15) 0.186(12) Uani 1 1 d U
O25 O 0.056(7) 0.100(4) 0.063(3) 0.16(2) Uani 0.50 1 d P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Cd1 O11 133.2(4) . .
O1 Cd1 O3 89.2(3) . 2_665
O11 Cd1 O3 90.9(3) . 2_665
O1 Cd1 O12 91.1(3) . 2_765
O11 Cd1 O12 134.1(3) . 2_765
O3 Cd1 O12 76.4(3) 2_665 2_765
O1 Cd1 O10 100.0(4) . 2_765
O11 Cd1 O10 100.5(4) . 2_765
O3 Cd1 O10 153.3(3) 2_665 2_765
O12 Cd1 O10 78.4(3) 2_765 2_765
O1 Cd1 O2 54.9(3) . .
O11 Cd1 O2 90.5(3) . .
O3 Cd1 O2 128.4(3) 2_665 .
O12 Cd1 O2 131.9(3) 2_765 .
O10 Cd1 O2 76.1(3) 2_765 .
O1 Cd1 O10 173.6(3) . .
O11 Cd1 O10 53.2(3) . .
O3 Cd1 O10 90.2(3) 2_665 .
O12 Cd1 O10 82.5(3) 2_765 .
O10 Cd1 O10 77.8(4) 2_765 .
O2 Cd1 O10 129.5(3) . .
O9 Cd2 O4 114.9(3) 1_565 .
O9 Cd2 O19 92.0(4) 1_565 .
O4 Cd2 O19 86.4(4) . .
O9 Cd2 O12 134.5(3) 1_565 1_455
O4 Cd2 O12 108.5(3) . 1_455
O19 Cd2 O12 77.2(3) . 1_455
O9 Cd2 O13 87.1(4) 1_565 1_455
O4 Cd2 O13 155.3(4) . 1_455
O19 Cd2 O13 104.9(5) . 1_455
O12 Cd2 O13 54.9(3) 1_455 1_455
O9 Cd2 O20 84.5(4) 1_565 .
O4 Cd2 O20 86.6(3) . .
O19 Cd2 O20 170.1(4) . .
O12 Cd2 O20 111.8(3) 1_455 .
O13 Cd2 O20 84.3(4) 1_455 .
O9 Cd2 C24 111.1(4) 1_565 1_455
O4 Cd2 C24 134.0(4) . 1_455
O19 Cd2 C24 91.6(4) . 1_455
O12 Cd2 C24 28.0(3) 1_455 1_455
O13 Cd2 C24 26.9(4) 1_455 1_455
O20 Cd2 C24 98.3(4) . 1_455
O17 Cd3 O8 87.4(3) 2_765 2_656
O17 Cd3 O7 102.1(3) 2_765 .
O8 Cd3 O7 130.8(3) 2_656 .
O17 Cd3 O16 117.3(3) 2_765 1_546
O8 Cd3 O16 136.1(3) 2_656 1_546
O7 Cd3 O16 81.6(3) . 1_546
O17 Cd3 O15 90.0(3) 2_765 1_546
O8 Cd3 O15 91.5(3) 2_656 1_546
O7 Cd3 O15 135.8(3) . 1_546
O16 Cd3 O15 55.5(3) 1_546 1_546
O17 Cd3 O6 110.1(4) 2_765 .
O8 Cd3 O6 77.6(3) 2_656 .
O7 Cd3 O6 53.7(3) . .
O16 Cd3 O6 120.2(3) 1_546 .
O15 Cd3 O6 156.3(4) 1_546 .
O17 Cd3 O6 163.3(3) 2_765 2_656
O8 Cd3 O6 76.7(3) 2_656 2_656
O7 Cd3 O6 92.3(3) . 2_656
O16 Cd3 O6 72.8(3) 1_546 2_656
O15 Cd3 O6 85.3(3) 1_546 2_656
O6 Cd3 O6 71.8(4) . 2_656
O17 Cd3 C25 107.0(4) 2_765 1_546
O8 Cd3 C25 113.3(3) 2_656 1_546
O7 Cd3 C25 109.6(4) . 1_546
O16 Cd3 C25 28.2(3) 1_546 1_546
O15 Cd3 C25 27.6(3) 1_546 1_546
O6 Cd3 C25 141.8(4) . 1_546
O6 Cd3 C25 75.3(3) 2_656 1_546
O17 Cd3 Na2 150.0(2) 2_765 1_545
O8 Cd3 Na2 122.4(2) 2_656 1_545
O7 Cd3 Na2 62.3(3) . 1_545
O16 Cd3 Na2 39.4(2) 1_546 1_545
O15 Cd3 Na2 86.3(2) 1_546 1_545
O6 Cd3 Na2 82.2(3) . 1_545
O6 Cd3 Na2 45.7(2) 2_656 1_545
C25 Cd3 Na2 60.8(3) 1_546 1_545
O17 Cd3 Na2 95.0(3) 2_765 2_666
O8 Cd3 Na2 36.9(2) 2_656 2_666
O7 Cd3 Na2 94.0(2) . 2_666
O16 Cd3 Na2 147.6(2) 1_546 2_666
O15 Cd3 Na2 127.4(2) 1_546 2_666
O6 Cd3 Na2 41.4(2) . 2_666
O6 Cd3 Na2 75.4(2) 2_656 2_666
C25 Cd3 Na2 142.8(3) 1_546 2_666
Na2 Cd3 Na2 110.72(10) 1_545 2_666
O2 Na1 O22 93.3(4) . .
O2 Na1 O20 140.6(5) . .
O22 Na1 O20 85.7(5) . .
O2 Na1 O18 84.1(4) . 1_556
O22 Na1 O18 169.6(5) . 1_556
O20 Na1 O18 89.9(4) . 1_556
O2 Na1 O21 146.9(6) . .
O22 Na1 O21 91.2(7) . .
O20 Na1 O21 72.4(6) . .
O18 Na1 O21 96.5(7) 1_556 .
O2 Na1 O19 74.5(4) . 1_655
O22 Na1 O19 105.9(5) . 1_655
O20 Na1 O19 143.4(4) . 1_655
O18 Na1 O19 83.2(4) 1_556 1_655
O21 Na1 O19 72.8(6) . 1_655
O2 Na1 O3 64.6(3) . .
O22 Na1 O3 86.9(4) . .
O20 Na1 O3 76.0(4) . .
O18 Na1 O3 82.9(3) 1_556 .
O21 Na1 O3 148.4(6) . .
O19 Na1 O3 137.8(4) 1_655 .
O16 Na2 O4 148.0(4) 1_556 .
O16 Na2 O8 126.4(4) 1_556 1_565
O4 Na2 O8 83.6(4) . 1_565
O16 Na2 O18 77.8(4) 1_556 1_556
O4 Na2 O18 79.9(3) . 1_556
O8 Na2 O18 147.8(4) 1_565 1_556
O16 Na2 O6 75.9(4) 1_556 2_666
O4 Na2 O6 105.7(4) . 2_666
O8 Na2 O6 75.5(3) 1_565 2_666
O18 Na2 O6 135.7(4) 1_556 2_666
O16 Na2 O23 84.6(4) 1_556 .
O4 Na2 O23 113.7(4) . .
O8 Na2 O23 81.6(4) 1_565 .
O18 Na2 O23 80.0(4) 1_556 .
O6 Na2 O23 131.4(4) 2_666 .
O16 Na2 Cd3 40.7(2) 1_556 1_565
O4 Na2 Cd3 153.9(3) . 1_565
O8 Na2 Cd3 87.3(3) 1_565 1_565
O18 Na2 Cd3 118.4(3) 1_556 1_565
O6 Na2 Cd3 48.3(3) 2_666 1_565
O23 Na2 Cd3 88.9(3) . 1_565
O16 Na2 Cd3 108.6(3) 1_556 2_666
O4 Na2 Cd3 89.8(3) . 2_666
O8 Na2 Cd3 35.2(2) 1_565 2_666
O18 Na2 Cd3 167.6(3) 1_556 2_666
O6 Na2 Cd3 40.9(2) 2_666 2_666
O23 Na2 Cd3 110.8(3) . 2_666
Cd3 Na2 Cd3 69.28(10) 1_565 2_666
C1 O1 Cd1 97.1(8) . .
C1 O2 Na1 138.8(9) . .
C1 O2 Cd1 85.1(8) . .
Na1 O2 Cd1 127.0(4) . .
C8 O3 Cd1 133.5(8) . 2_665
C8 O3 Na1 94.2(8) . .
Cd1 O3 Na1 132.0(4) 2_665 .
C8 O4 Cd2 106.5(7) . .
C8 O4 Na2 124.9(8) . .
Cd2 O4 Na2 106.5(4) . .
C4 O5 C12 120.1(10) . .
C9 O6 Cd3 87.4(8) . .
C9 O6 Na2 165.4(9) . 2_666
Cd3 O6 Na2 97.7(3) . 2_666
C9 O6 Cd3 105.4(9) . 2_656
Cd3 O6 Cd3 108.2(4) . 2_656
Na2 O6 Cd3 86.0(4) 2_666 2_656
C9 O7 Cd3 96.6(8) . .
C16 O8 Cd3 118.9(8) . 2_656
C16 O8 Na2 133.1(8) . 1_545
Cd3 O8 Na2 107.9(4) 2_656 1_545
C16 O9 Cd2 115.3(8) . 1_545
C17 O10 Cd1 112.0(9) . 2_765
C17 O10 Cd1 83.0(8) . .
Cd1 O10 Cd1 102.2(4) 2_765 .
C17 O11 Cd1 101.2(9) . .
C24 O12 Cd1 135.3(8) . 2_765
C24 O12 Cd2 91.4(8) . 1_655
Cd1 O12 Cd2 114.7(4) 2_765 1_655
C24 O13 Cd2 92.3(9) . 1_655
C20 O14 C28 121.0(10) . .
C25 O15 Cd3 91.1(7) . 1_564
C25 O16 Na2 129.1(8) . 1_554
C25 O16 Cd3 91.4(7) . 1_564
Na2 O16 Cd3 99.9(4) 1_554 1_564
C32 O17 Cd3 124.3(7) . 2_765
C32 O18 Na2 116.2(8) . 1_554
C32 O18 Na1 123.4(8) . 1_554
Na2 O18 Na1 112.6(4) 1_554 1_554
O2 C1 O1 122.5(11) . .
O2 C1 C2 122.1(12) . .
O1 C1 C2 115.1(11) . .
C3 C2 C7 120.5(11) . .
C3 C2 C1 115.4(11) . .
C7 C2 C1 123.9(11) . .
C2 C3 C4 120.4(12) . .
C2 C3 H3 119.8 . .
C4 C3 H3 119.8 . .
C5 C4 O5 118.7(11) . .
C5 C4 C3 119.8(12) . .
O5 C4 C3 121.4(11) . .
C4 C5 C6 119.5(12) . .
C4 C5 H5 120.2 . .
C6 C5 H5 120.2 . .
C5 C6 C7 122.2(12) . .
C5 C6 H6 118.9 . .
C7 C6 H6 118.9 . .
C6 C7 C2 117.4(11) . .
C6 C7 C8 119.3(11) . .
C2 C7 C8 123.0(11) . .
O4 C8 O3 123.6(11) . .
O4 C8 C7 117.0(11) . .
O3 C8 C7 119.4(11) . .
O7 C9 O6 122.2(12) . .
O7 C9 C10 118.6(11) . .
O6 C9 C10 119.1(12) . .
C15 C10 C11 121.3(11) . .
C15 C10 C9 123.2(11) . .
C11 C10 C9 115.5(11) . .
C10 C11 C12 118.5(12) . .
C10 C11 H11 120.8 . .
C12 C11 H11 120.8 . .
C13 C12 O5 125.0(11) . .
C13 C12 C11 121.5(12) . .
O5 C12 C11 113.5(11) . .
C12 C13 C14 119.1(12) . .
C12 C13 H13 120.4 . .
C14 C13 H13 120.4 . .
C13 C14 C15 120.8(12) . .
C13 C14 H14 119.6 . .
C15 C14 H14 119.6 . .
C10 C15 C14 118.6(11) . .
C10 C15 C16 122.2(10) . .
C14 C15 C16 119.0(11) . .
O8 C16 O9 123.8(11) . .
O8 C16 C15 119.2(11) . .
O9 C16 C15 117.0(10) . .
O11 C17 O10 122.5(12) . .
O11 C17 C18 117.0(12) . .
O10 C17 C18 120.5(12) . .
C19 C18 C23 120.0(12) . .
C19 C18 C17 117.2(12) . .
C23 C18 C17 122.7(11) . .
C18 C19 C20 119.6(13) . .
C18 C19 H19 120.2 . .
C20 C19 H19 120.2 . .
O14 C20 C21 124.5(11) . .
O14 C20 C19 114.9(12) . .
C21 C20 C19 120.6(12) . .
C20 C21 C22 118.3(12) . .
C20 C21 H21A 120.9 . .
C22 C21 H21A 120.9 . .
C23 C22 C21 122.3(13) . .
C23 C22 H22A 118.8 . .
C21 C22 H22A 118.8 . .
C22 C23 C18 119.0(12) . .
C22 C23 C24 119.5(12) . .
C18 C23 C24 121.4(11) . .
O13 C24 O12 121.4(13) . .
O13 C24 C23 120.6(12) . .
O12 C24 C23 117.8(12) . .
O13 C24 Cd2 60.8(8) . 1_655
O12 C24 Cd2 60.6(7) . 1_655
C23 C24 Cd2 176.7(10) . 1_655
O15 C25 O16 121.0(11) . .
O15 C25 C26 119.7(11) . .
O16 C25 C26 119.3(11) . .
O15 C25 Cd3 61.3(6) . 1_564
O16 C25 Cd3 60.5(6) . 1_564
C26 C25 Cd3 172.1(9) . 1_564
C27 C26 C31 119.4(11) . .
C27 C26 C25 118.4(11) . .
C31 C26 C25 122.2(11) . .
C28 C27 C26 120.7(12) . .
C28 C27 H27 119.7 . .
C26 C27 H27 119.7 . .
C29 C28 C27 121.3(12) . .
C29 C28 O14 115.9(11) . .
C27 C28 O14 122.7(11) . .
C28 C29 C30 119.4(12) . .
C28 C29 H29 120.3 . .
C30 C29 H29 120.3 . .
C31 C30 C29 120.3(11) . .
C31 C30 H30 119.8 . .
C29 C30 H30 119.8 . .
C30 C31 C26 118.8(11) . .
C30 C31 C32 114.7(10) . .
C26 C31 C32 126.3(11) . .
O18 C32 O17 121.0(11) . .
O18 C32 C31 122.4(12) . .
O17 C32 C31 116.2(11) . .
Cd2 O19 Na1 140.6(5) . 1_455
Cd2 O20 Na1 113.6(4) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Cd1 O1 2.224(9) .
Cd1 O11 2.238(10) .
Cd1 O3 2.294(9) 2_665
Cd1 O12 2.320(8) 2_765
Cd1 O10 2.410(11) 2_765
Cd1 O2 2.509(10) .
Cd1 O10 2.624(11) .
Cd2 O9 2.243(9) 1_565
Cd2 O4 2.258(9) .
Cd2 O19 2.348(10) .
Cd2 O12 2.374(9) 1_455
Cd2 O13 2.378(11) 1_455
Cd2 O20 2.379(11) .
Cd2 C24 2.723(13) 1_455
Cd3 O17 2.201(9) 2_765
Cd3 O8 2.310(9) 2_656
Cd3 O7 2.324(10) .
Cd3 O16 2.345(9) 1_546
Cd3 O15 2.364(9) 1_546
Cd3 O6 2.517(11) .
Cd3 O6 2.649(12) 2_656
Cd3 C25 2.695(12) 1_546
Cd3 Na2 3.541(6) 1_545
Cd3 Na2 3.811(6) 2_666
Na1 O2 2.400(11) .
Na1 O22 2.433(14) .
Na1 O20 2.489(12) .
Na1 O18 2.491(11) 1_556
Na1 O21 2.58(2) .
Na1 O19 2.615(12) 1_655
Na1 O3 2.896(12) .
Na2 O16 2.281(10) 1_556
Na2 O4 2.302(11) .
Na2 O8 2.402(10) 1_565
Na2 O18 2.439(10) 1_556
Na2 O6 2.542(11) 2_666
Na2 O23 2.609(14) .
Na2 Cd3 3.541(6) 1_565
Na2 Cd3 3.811(6) 2_666
O1 C1 1.277(16) .
O2 C1 1.229(16) .
O3 C8 1.255(14) .
O3 Cd1 2.294(9) 2_665
O4 C8 1.246(14) .
O5 C4 1.368(15) .
O5 C12 1.379(15) .
O6 C9 1.255(16) .
O6 Na2 2.542(11) 2_666
O6 Cd3 2.649(12) 2_656
O7 C9 1.251(16) .
O8 C16 1.249(15) .
O8 Cd3 2.310(9) 2_656
O8 Na2 2.402(10) 1_545
O9 C16 1.273(15) .
O9 Cd2 2.243(9) 1_545
O10 C17 1.262(16) .
O10 Cd1 2.410(11) 2_765
O11 C17 1.252(17) .
O12 C24 1.277(15) .
O12 Cd1 2.320(8) 2_765
O12 Cd2 2.374(9) 1_655
O13 C24 1.233(17) .
O13 Cd2 2.378(11) 1_655
O14 C20 1.375(15) .
O14 C28 1.410(14) .
O15 C25 1.248(14) .
O15 Cd3 2.364(9) 1_564
O16 C25 1.272(14) .
O16 Na2 2.281(10) 1_554
O16 Cd3 2.345(9) 1_564
O17 C32 1.314(15) .
O17 Cd3 2.201(9) 2_765
O18 C32 1.243(15) .
O18 Na2 2.439(10) 1_554
O18 Na1 2.491(11) 1_554
C1 C2 1.527(16) .
C2 C3 1.365(18) .
C2 C7 1.408(17) .
C3 C4 1.412(18) .
C3 H3 0.9300 .
C4 C5 1.360(17) .
C5 C6 1.383(18) .
C5 H5 0.9300 .
C6 C7 1.392(17) .
C6 H6 0.9300 .
C7 C8 1.506(16) .
C9 C10 1.502(16) .
C10 C15 1.386(17) .
C10 C11 1.390(17) .
C11 C12 1.407(17) .
C11 H11 0.9300 .
C12 C13 1.377(19) .
C13 C14 1.386(18) .
C13 H13 0.9300 .
C14 C15 1.414(17) .
C14 H14 0.9300 .
C15 C16 1.505(16) .
C17 C18 1.503(17) .
C18 C19 1.390(18) .
C18 C23 1.403(18) .
C19 C20 1.405(17) .
C19 H19 0.9300 .
C20 C21 1.388(19) .
C21 C22 1.394(19) .
C21 H21A 0.9300 .
C22 C23 1.373(17) .
C22 H22A 0.9300 .
C23 C24 1.495(18) .
C24 Cd2 2.723(13) 1_655
C25 C26 1.481(17) .
C25 Cd3 2.695(12) 1_564
C26 C27 1.397(17) .
C26 C31 1.402(16) .
C27 C28 1.360(18) .
C27 H27 0.9300 .
C28 C29 1.360(18) .
C29 C30 1.410(17) .
C29 H29 0.9300 .
C30 C31 1.389(18) .
C30 H30 0.9300 .
C31 C32 1.474(17) .
O19 Na1 2.615(12) 1_455
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O11 Cd1 O1 C1 -53.1(10) . .
O3 Cd1 O1 C1 -143.5(9) 2_665 .
O12 Cd1 O1 C1 140.1(8) 2_765 .
O10 Cd1 O1 C1 61.7(9) 2_765 .
O2 Cd1 O1 C1 -3.3(8) . .
O10 Cd1 O1 C1 132(3) . .
O22 Na1 O2 C1 -106.9(14) . .
O20 Na1 O2 C1 -19.5(18) . .
O18 Na1 O2 C1 63.1(14) 1_556 .
O21 Na1 O2 C1 155.9(16) . .
O19 Na1 O2 C1 147.6(14) 1_655 .
O3 Na1 O2 C1 -21.8(13) . .
O22 Na1 O2 Cd1 27.5(7) . .
O20 Na1 O2 Cd1 114.8(7) . .
O18 Na1 O2 Cd1 -162.6(6) 1_556 .
O21 Na1 O2 Cd1 -69.8(14) . .
O19 Na1 O2 Cd1 -78.1(6) 1_655 .
O3 Na1 O2 Cd1 112.5(6) . .
O1 Cd1 O2 C1 3.4(8) . .
O11 Cd1 O2 C1 149.6(8) . .
O3 Cd1 O2 C1 58.1(9) 2_665 .
O12 Cd1 O2 C1 -49.9(10) 2_765 .
O10 Cd1 O2 C1 -109.8(8) 2_765 .
O10 Cd1 O2 C1 -170.7(8) . .
O1 Cd1 O2 Na1 -148.4(8) . .
O11 Cd1 O2 Na1 -2.2(6) . .
O3 Cd1 O2 Na1 -93.7(6) 2_665 .
O12 Cd1 O2 Na1 158.3(5) 2_765 .
O10 Cd1 O2 Na1 98.4(6) 2_765 .
O10 Cd1 O2 Na1 37.5(8) . .
O2 Na1 O3 C8 95.6(8) . .
O22 Na1 O3 C8 -169.2(8) . .
O20 Na1 O3 C8 -82.9(7) . .
O18 Na1 O3 C8 8.8(7) 1_556 .
O21 Na1 O3 C8 -82.0(14) . .
O19 Na1 O3 C8 80.4(9) 1_655 .
O2 Na1 O3 Cd1 -79.1(6) . 2_665
O22 Na1 O3 Cd1 16.1(6) . 2_665
O20 Na1 O3 Cd1 102.4(6) . 2_665
O18 Na1 O3 Cd1 -165.9(5) 1_556 2_665
O21 Na1 O3 Cd1 103.3(13) . 2_665
O19 Na1 O3 Cd1 -94.3(7) 1_655 2_665
O9 Cd2 O4 C8 -163.9(8) 1_565 .
O19 Cd2 O4 C8 105.5(8) . .
O12 Cd2 O4 C8 30.3(9) 1_455 .
O13 Cd2 O4 C8 -13.0(14) 1_455 .
O20 Cd2 O4 C8 -81.5(8) . .
C24 Cd2 O4 C8 16.8(10) 1_455 .
O9 Cd2 O4 Na2 -28.6(5) 1_565 .
O19 Cd2 O4 Na2 -119.2(4) . .
O12 Cd2 O4 Na2 165.6(4) 1_455 .
O13 Cd2 O4 Na2 122.2(9) 1_455 .
O20 Cd2 O4 Na2 53.7(4) . .
C24 Cd2 O4 Na2 152.0(5) 1_455 .
O16 Na2 O4 C8 -33.5(14) 1_556 .
O8 Na2 O4 C8 165.1(9) 1_565 .
O18 Na2 O4 C8 12.9(9) 1_556 .
O6 Na2 O4 C8 -122.0(9) 2_666 .
O23 Na2 O4 C8 87.2(10) . .
Cd3 Na2 O4 C8 -124.4(9) 1_565 .
Cd3 Na2 O4 C8 -160.1(9) 2_666 .
O16 Na2 O4 Cd2 -158.1(6) 1_556 .
O8 Na2 O4 Cd2 40.5(4) 1_565 .
O18 Na2 O4 Cd2 -111.7(4) 1_556 .
O6 Na2 O4 Cd2 113.5(4) 2_666 .
O23 Na2 O4 Cd2 -37.4(5) . .
Cd3 Na2 O4 Cd2 111.0(6) 1_565 .
Cd3 Na2 O4 Cd2 75.3(3) 2_666 .
O17 Cd3 O6 C9 92.2(8) 2_765 .
O8 Cd3 O6 C9 174.7(8) 2_656 .
O7 Cd3 O6 C9 1.7(7) . .
O16 Cd3 O6 C9 -48.8(9) 1_546 .
O15 Cd3 O6 C9 -121.1(9) 1_546 .
O6 Cd3 O6 C9 -105.4(9) 2_656 .
C25 Cd3 O6 C9 -73.3(10) 1_546 .
Na2 Cd3 O6 C9 -59.6(8) 1_545 .
Na2 Cd3 O6 C9 166.3(10) 2_666 .
O17 Cd3 O6 Na2 -74.1(4) 2_765 2_666
O8 Cd3 O6 Na2 8.4(3) 2_656 2_666
O7 Cd3 O6 Na2 -164.6(6) . 2_666
O16 Cd3 O6 Na2 144.9(3) 1_546 2_666
O15 Cd3 O6 Na2 72.6(9) 1_546 2_666
O6 Cd3 O6 Na2 88.3(4) 2_656 2_666
C25 Cd3 O6 Na2 120.4(5) 1_546 2_666
Na2 Cd3 O6 Na2 134.2(3) 1_545 2_666
O17 Cd3 O6 Cd3 -162.4(3) 2_765 2_656
O8 Cd3 O6 Cd3 -79.9(3) 2_656 2_656
O7 Cd3 O6 Cd3 107.1(5) . 2_656
O16 Cd3 O6 Cd3 56.6(4) 1_546 2_656
O15 Cd3 O6 Cd3 -15.7(9) 1_546 2_656
O6 Cd3 O6 Cd3 0.0 2_656 2_656
C25 Cd3 O6 Cd3 32.1(7) 1_546 2_656
Na2 Cd3 O6 Cd3 45.9(3) 1_545 2_656
Na2 Cd3 O6 Cd3 -88.3(4) 2_666 2_656
O17 Cd3 O7 C9 -107.8(8) 2_765 .
O8 Cd3 O7 C9 -10.7(10) 2_656 .
O16 Cd3 O7 C9 135.9(8) 1_546 .
O15 Cd3 O7 C9 149.3(7) 1_546 .
O6 Cd3 O7 C9 -1.7(7) . .
O6 Cd3 O7 C9 63.7(8) 2_656 .
C25 Cd3 O7 C9 139.0(8) 1_546 .
Na2 Cd3 O7 C9 99.6(8) 1_545 .
Na2 Cd3 O7 C9 -11.8(8) 2_666 .
O1 Cd1 O10 C17 178(3) . .
O11 Cd1 O10 C17 2.1(8) . .
O3 Cd1 O10 C17 93.0(8) 2_665 .
O12 Cd1 O10 C17 169.3(8) 2_765 .
O10 Cd1 O10 C17 -111.1(9) 2_765 .
O2 Cd1 O10 C17 -50.9(9) . .
O1 Cd1 O10 Cd1 -71(3) . 2_765
O11 Cd1 O10 Cd1 113.2(5) . 2_765
O3 Cd1 O10 Cd1 -155.9(4) 2_665 2_765
O12 Cd1 O10 Cd1 -79.6(4) 2_765 2_765
O10 Cd1 O10 Cd1 0.0 2_765 2_765
O2 Cd1 O10 Cd1 60.2(5) . 2_765
O1 Cd1 O11 C17 178.5(8) . .
O3 Cd1 O11 C17 -91.8(9) 2_665 .
O12 Cd1 O11 C17 -20.0(11) 2_765 .
O10 Cd1 O11 C17 63.9(9) 2_765 .
O2 Cd1 O11 C17 139.8(9) . .
O10 Cd1 O11 C17 -2.1(8) . .
Na1 O2 C1 O1 139.3(12) . .
Cd1 O2 C1 O1 -5.7(13) . .
Na1 O2 C1 C2 -48(2) . .
Cd1 O2 C1 C2 166.9(12) . .
Cd1 O1 C1 O2 6.5(15) . .
Cd1 O1 C1 C2 -166.6(10) . .
O2 C1 C2 C3 -121.4(15) . .
O1 C1 C2 C3 51.7(17) . .
O2 C1 C2 C7 55(2) . .
O1 C1 C2 C7 -132.1(13) . .
C7 C2 C3 C4 1(2) . .
C1 C2 C3 C4 177.5(12) . .
C12 O5 C4 C5 130.5(14) . .
C12 O5 C4 C3 -54(2) . .
C2 C3 C4 C5 -4(2) . .
C2 C3 C4 O5 -178.9(13) . .
O5 C4 C5 C6 179.0(13) . .
C3 C4 C5 C6 4(2) . .
C4 C5 C6 C7 -1(2) . .
C5 C6 C7 C2 -1(2) . .
C5 C6 C7 C8 174.2(13) . .
C3 C2 C7 C6 0.8(19) . .
C1 C2 C7 C6 -175.1(13) . .
C3 C2 C7 C8 -173.9(12) . .
C1 C2 C7 C8 10(2) . .
Cd2 O4 C8 O3 5.6(15) . .
Na2 O4 C8 O3 -119.0(12) . .
Cd2 O4 C8 C7 -176.0(8) . .
Na2 O4 C8 C7 59.5(13) . .
Cd1 O3 C8 O4 -99.6(13) 2_665 .
Na1 O3 C8 O4 85.8(12) . .
Cd1 O3 C8 C7 82.0(15) 2_665 .
Na1 O3 C8 C7 -92.6(11) . .
C6 C7 C8 O4 22.6(18) . .
C2 C7 C8 O4 -162.7(12) . .
C6 C7 C8 O3 -158.9(12) . .
C2 C7 C8 O3 15.7(19) . .
Cd3 O7 C9 O6 3.2(14) . .
Cd3 O7 C9 C10 178.3(9) . .
Cd3 O6 C9 O7 -2.9(13) . .
Na2 O6 C9 O7 108(4) 2_666 .
Cd3 O6 C9 O7 -111.1(12) 2_656 .
Cd3 O6 C9 C10 -178.0(10) . .
Na2 O6 C9 C10 -67(4) 2_666 .
Cd3 O6 C9 C10 73.8(12) 2_656 .
O7 C9 C10 C15 86.0(16) . .
O6 C9 C10 C15 -98.7(15) . .
O7 C9 C10 C11 -92.4(14) . .
O6 C9 C10 C11 82.9(15) . .
C15 C10 C11 C12 2.4(18) . .
C9 C10 C11 C12 -179.2(12) . .
C4 O5 C12 C13 -9(2) . .
C4 O5 C12 C11 172.7(12) . .
C10 C11 C12 C13 2(2) . .
C10 C11 C12 O5 180.0(11) . .
O5 C12 C13 C14 178.6(13) . .
C11 C12 C13 C14 -3(2) . .
C12 C13 C14 C15 1(2) . .
C11 C10 C15 C14 -4.6(18) . .
C9 C10 C15 C14 177.1(12) . .
C11 C10 C15 C16 179.8(12) . .
C9 C10 C15 C16 1.5(19) . .
C13 C14 C15 C10 3(2) . .
C13 C14 C15 C16 178.7(13) . .
Cd3 O8 C16 O9 -113.4(13) 2_656 .
Na2 O8 C16 O9 71.8(17) 1_545 .
Cd3 O8 C16 C15 68.0(14) 2_656 .
Na2 O8 C16 C15 -106.7(13) 1_545 .
Cd2 O9 C16 O8 -14.7(17) 1_545 .
Cd2 O9 C16 C15 163.9(9) 1_545 .
C10 C15 C16 O8 11.9(19) . .
C14 C15 C16 O8 -163.7(12) . .
C10 C15 C16 O9 -166.7(12) . .
C14 C15 C16 O9 17.6(18) . .
Cd1 O11 C17 O10 4.2(15) . .
Cd1 O11 C17 C18 -178.8(10) . .
Cd1 O10 C17 O11 -103.9(14) 2_765 .
Cd1 O10 C17 O11 -3.5(13) . .
Cd1 O10 C17 C18 79.2(13) 2_765 .
Cd1 O10 C17 C18 179.6(12) . .
O11 C17 C18 C19 -92.1(16) . .
O10 C17 C18 C19 85.0(17) . .
O11 C17 C18 C23 85.1(17) . .
O10 C17 C18 C23 -97.9(16) . .
C23 C18 C19 C20 -2(2) . .
C17 C18 C19 C20 175.5(12) . .
C28 O14 C20 C21 -22(2) . .
C28 O14 C20 C19 159.7(12) . .
C18 C19 C20 O14 179.9(12) . .
C18 C19 C20 C21 1(2) . .
O14 C20 C21 C22 -178.2(13) . .
C19 C20 C21 C22 0(2) . .
C20 C21 C22 C23 -1(2) . .
C21 C22 C23 C18 1(2) . .
C21 C22 C23 C24 -178.0(13) . .
C19 C18 C23 C22 1(2) . .
C17 C18 C23 C22 -176.4(13) . .
C19 C18 C23 C24 179.6(12) . .
C17 C18 C23 C24 2(2) . .
Cd2 O13 C24 O12 1.1(16) 1_655 .
Cd2 O13 C24 C23 176.6(12) 1_655 .
Cd1 O12 C24 O13 -129.4(14) 2_765 .
Cd2 O12 C24 O13 -1.1(16) 1_655 .
Cd1 O12 C24 C23 55.0(18) 2_765 .
Cd2 O12 C24 C23 -176.7(11) 1_655 .
Cd1 O12 C24 Cd2 -128.3(12) 2_765 1_655
C22 C23 C24 O13 22(2) . .
C18 C23 C24 O13 -157.1(15) . .
C22 C23 C24 O12 -162.6(13) . .
C18 C23 C24 O12 19(2) . .
C22 C23 C24 Cd2 136(16) . 1_655
C18 C23 C24 Cd2 -43(17) . 1_655
Cd3 O15 C25 O16 9.5(12) 1_564 .
Cd3 O15 C25 C26 -171.0(10) 1_564 .
Na2 O16 C25 O15 -113.6(12) 1_554 .
Cd3 O16 C25 O15 -9.6(13) 1_564 .
Na2 O16 C25 C26 67.0(15) 1_554 .
Cd3 O16 C25 C26 170.9(10) 1_564 .
Na2 O16 C25 Cd3 -104.0(9) 1_554 1_564
O15 C25 C26 C27 11.4(18) . .
O16 C25 C26 C27 -169.2(12) . .
Cd3 C25 C26 C27 -83(6) 1_564 .
O15 C25 C26 C31 -170.2(12) . .
O16 C25 C26 C31 9.3(18) . .
Cd3 C25 C26 C31 95(6) 1_564 .
C31 C26 C27 C28 3(2) . .
C25 C26 C27 C28 -178.7(13) . .
C26 C27 C28 C29 -1(2) . .
C26 C27 C28 O14 -177.0(13) . .
C20 O14 C28 C29 136.7(14) . .
C20 O14 C28 C27 -47(2) . .
C27 C28 C29 C30 0(2) . .
O14 C28 C29 C30 176.4(13) . .
C28 C29 C30 C31 -1(2) . .
C29 C30 C31 C26 3.2(19) . .
C29 C30 C31 C32 179.3(12) . .
C27 C26 C31 C30 -4.0(19) . .
C25 C26 C31 C30 177.6(12) . .
C27 C26 C31 C32 -179.7(13) . .
C25 C26 C31 C32 2(2) . .
Na2 O18 C32 O17 -115.7(10) 1_554 .
Na1 O18 C32 O17 31.1(16) 1_554 .
Na2 O18 C32 C31 72.5(13) 1_554 .
Na1 O18 C32 C31 -140.7(9) 1_554 .
Cd3 O17 C32 O18 131.0(10) 2_765 .
Cd3 O17 C32 C31 -56.7(14) 2_765 .
C30 C31 C32 O18 98.6(15) . .
C26 C31 C32 O18 -85.7(17) . .
C30 C31 C32 O17 -73.6(15) . .
C26 C31 C32 O17 102.2(15) . .
O9 Cd2 O19 Na1 55.2(7) 1_565 1_455
O4 Cd2 O19 Na1 170.0(7) . 1_455
O12 Cd2 O19 Na1 -80.1(7) 1_455 1_455
O13 Cd2 O19 Na1 -32.3(8) 1_455 1_455
O20 Cd2 O19 Na1 125(2) . 1_455
C24 Cd2 O19 Na1 -56.0(7) 1_455 1_455
O9 Cd2 O20 Na1 161.2(5) 1_565 .
O4 Cd2 O20 Na1 45.8(5) . .
O19 Cd2 O20 Na1 91(2) . .
O12 Cd2 O20 Na1 -62.7(5) 1_455 .
O13 Cd2 O20 Na1 -111.2(5) 1_455 .
C24 Cd2 O20 Na1 -88.2(5) 1_455 .
O2 Na1 O20 Cd2 1.9(9) . .
O22 Na1 O20 Cd2 91.9(5) . .
O18 Na1 O20 Cd2 -78.7(5) 1_556 .
O21 Na1 O20 Cd2 -175.5(8) . .
O19 Na1 O20 Cd2 -157.0(5) 1_655 .
O3 Na1 O20 Cd2 4.0(4) . .
