#------------------------------------------------------------------------------
#$Date: 2016-03-24 02:29:14 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179581 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/46/4504690.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4504690
loop_
_publ_author_name
'Ren, Yan-Ping'
'Kong, Xiang-Jian'
'Long, La-Sheng'
'Huang, Rong-Bin'
'Zheng, Lan-Sun'
_publ_section_title
;
 Anion-Dependent Assembly of Cyclic Structure
;
_journal_issue                   2
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              572
_journal_paper_doi               10.1021/cg050459a
_journal_volume                  6
_journal_year                    2006
_chemical_formula_sum            'C40 H32 Ag3 N8 O40 P W12'
_chemical_formula_weight         3825.52
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                105.404(2)
_cell_angle_beta                 100.976(2)
_cell_angle_gamma                104.254(2)
_cell_formula_units_Z            1
_cell_length_a                   11.4489(17)
_cell_length_b                   12.2137(19)
_cell_length_c                   13.357(2)
_cell_measurement_temperature    123(2)
_cell_volume                     1678.6(4)
_computing_cell_refinement       'SHELXTL-Plus (Sheldrick, 1990)'
_computing_data_collection       'SHELXTL-Plus (Sheldrick, 1990)'
_computing_data_reduction        'SHELXTL-Plus (Sheldrick, 1990)'
_computing_molecular_graphics    'SHELXTL V.5.0 (Sheldrick, 1997)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.961
_diffrn_measured_fraction_theta_max 0.961
_diffrn_measurement_device_type  'Bruker Smart Apex CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0521
_diffrn_reflns_av_sigmaI/netI    0.0774
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            12007
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.64
_exptl_absorpt_coefficient_mu    21.436
_exptl_absorpt_correction_type   sadabs
_exptl_crystal_colour            pale-yellow
_exptl_crystal_density_diffrn    3.784
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1692
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.07
_refine_diff_density_max         3.906
_refine_diff_density_min         -4.148
_refine_diff_density_rms         0.490
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.065
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     472
_refine_ls_number_reflns         6334
_refine_ls_number_restraints     22
_refine_ls_restrained_S_all      1.069
_refine_ls_R_factor_all          0.0642
_refine_ls_R_factor_gt           0.0582
_refine_ls_shift/su_max          0.049
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0860P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1463
_refine_ls_wR_factor_ref         0.1513
_reflns_number_gt                5657
_reflns_number_total             6334
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg050459asi20050907_112157.cif
_cod_data_source_block           complex_3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      p-1
_cod_database_code               4504690
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
W1 W 0.95521(3) 0.65538(3) 0.24924(3) 0.01599(8) Uani 1 1 d .
W2 W 0.70066(3) 0.42064(3) 0.04997(3) 0.01660(8) Uani 1 1 d .
W3 W 1.25145(3) 0.74142(3) 0.19533(3) 0.01679(9) Uani 1 1 d .
W4 W 1.25681(3) 0.44155(4) 0.14875(3) 0.02638(10) Uani 1 1 d .
W5 W 0.98985(4) 0.79955(4) 0.05203(3) 0.02586(10) Uani 1 1 d .
W6 W 0.95599(4) 0.35248(4) 0.19223(3) 0.02512(10) Uani 1 1 d .
P1 P 1.0000 0.5000 0.0000 0.0142(7) Uani 1 2 d SD
O1 O 1.0369(8) 0.4116(6) 0.0535(6) 0.0118(14) Uani 0.50 1 d PD
O2 O 1.0354(9) 0.6174(6) 0.0886(6) 0.0118(14) Uani 0.50 1 d PD
O3 O 1.0692(6) 0.5068(8) -0.0830(5) 0.0118(14) Uani 0.50 1 d PD
O4 O 0.8608(5) 0.4507(8) -0.0488(7) 0.0118(14) Uani 0.50 1 d PD
O5 O 0.7896(8) 0.3412(6) 0.1284(6) 0.053(3) Uani 1 1 d .
O6 O 1.3189(9) 0.7096(7) 0.0766(5) 0.059(2) Uani 1 1 d .
O7 O 0.6809(9) 0.5132(7) -0.0390(6) 0.070(2) Uani 1 1 d .
O8 O 0.9412(7) 0.7585(7) 0.1666(7) 0.060(2) Uani 1 1 d .
O9 O 1.3697(7) 0.8538(8) 0.2891(6) 0.046(3) Uani 1 1 d .
O10 O 1.1292(6) 0.7157(6) 0.2746(7) 0.0468(19) Uani 1 1 d .
O11 O 1.2893(9) 0.6066(6) 0.2222(5) 0.051(2) Uani 1 1 d .
O12 O 1.3762(6) 0.4166(6) 0.2219(5) 0.0313(18) Uani 1 1 d .
O13 O 0.9764(7) 0.5148(6) 0.2746(6) 0.042(2) Uani 1 1 d .
O14 O 0.9857(6) 0.9401(6) 0.0809(6) 0.0274(17) Uani 1 1 d .
O15 O 0.9350(6) 0.2864(5) 0.2857(5) 0.0256(17) Uani 1 1 d .
O16 O 1.1698(9) 0.2944(10) 0.0394(8) 0.071(2) Uani 1 1 d U
O17 O 0.9507(7) 0.2231(11) 0.0758(8) 0.094(5) Uani 1 1 d .
O18 O 0.5622(7) 0.3802(7) 0.0733(8) 0.053(3) Uani 1 1 d .
O19 O 1.1571(6) 0.8216(7) 0.1297(7) 0.052(2) Uani 1 1 d .
O20 O 0.9354(7) 0.7305(9) 0.3670(6) 0.060(3) Uani 1 1 d .
O21 O 0.7872(8) 0.5594(6) 0.1662(7) 0.053(3) Uani 1 1 d .
O22 O 1.1338(7) 0.4013(11) 0.2203(8) 0.100(5) Uani 1 1 d .
Ag1 Ag 1.0000 0.5000 0.5000 0.0247(3) Uani 1 2 d S
Ag2 Ag 0.46808(7) 0.06919(7) 0.23511(6) 0.02505(18) Uani 1 1 d .
N1 N 0.3523(7) 0.1840(7) 0.3085(6) 0.0203(19) Uani 1 1 d .
C1 C 0.2244(8) 0.1322(9) 0.2784(8) 0.028(3) Uani 1 1 d .
H1A H 0.1871 0.0652 0.2142 0.034 Uiso 1 1 calc R
C2 C 0.1485(9) 0.1722(8) 0.3363(9) 0.032(3) Uani 1 1 d .
H2A H 0.0601 0.1369 0.3113 0.039 Uiso 1 1 calc R
C3 C 0.2028(8) 0.2640(9) 0.4305(8) 0.029(2) Uani 1 1 d .
H3A H 0.1526 0.2920 0.4740 0.035 Uiso 1 1 calc R
C4 C 0.3342(9) 0.3179(9) 0.4642(8) 0.027(3) Uani 1 1 d .
H4A H 0.3732 0.3831 0.5296 0.032 Uiso 1 1 calc R
C5 C 0.4041(8) 0.2743(8) 0.4008(7) 0.018(2) Uani 1 1 d .
C6 C 0.5431(8) 0.3295(8) 0.4261(7) 0.018(2) Uani 1 1 d .
C7 C 0.6229(9) 0.3568(8) 0.5287(7) 0.024(2) Uani 1 1 d .
H7A H 0.5888 0.3430 0.5853 0.028 Uiso 1 1 calc R
C8 C 0.7477(8) 0.4023(8) 0.5477(7) 0.021(2) Uani 1 1 d .
H8A H 0.8001 0.4165 0.6172 0.025 Uiso 1 1 calc R
C9 C 0.7249(8) 0.4061(8) 0.3721(7) 0.020(2) Uani 1 1 d .
H9A H 0.7595 0.4257 0.3175 0.023 Uiso 1 1 calc R
C10 C 0.5968(8) 0.3548(8) 0.3476(7) 0.017(2) Uani 1 1 d .
H10A H 0.5458 0.3370 0.2767 0.021 Uiso 1 1 calc R
N2 N 0.8030(7) 0.4296(7) 0.4692(6) 0.0211(19) Uani 1 1 d .
N3 N 0.3687(7) 0.0421(7) 0.0628(6) 0.023(2) Uani 1 1 d .
C11 C 0.3493(9) -0.0487(9) -0.4308(8) 0.028(3) Uani 1 1 d .
H11A H 0.3969 -0.0869 -0.4707 0.034 Uiso 1 1 calc R
C12 C 0.2613(10) -0.0079(10) -0.4822(9) 0.037(3) Uani 1 1 d .
H12A H 0.2504 -0.0175 -0.5566 0.045 Uiso 1 1 calc R
C13 C 0.1915(11) 0.0443(10) -0.4304(9) 0.042(3) Uani 1 1 d .
H13A H 0.1315 0.0723 -0.4669 0.050 Uiso 1 1 calc R
C14 C 0.2075(10) 0.0573(10) -0.3237(9) 0.041(3) Uani 1 1 d .
H14A H 0.1577 0.0937 -0.2852 0.050 Uiso 1 1 calc R
C15 C 0.2960(9) 0.0175(8) -0.2721(8) 0.024(2) Uani 1 1 d .
C16 C 0.3199(8) 0.0257(9) -0.1559(8) 0.024(3) Uani 1 1 d .
C17 C 0.3348(9) 0.1306(9) -0.0752(8) 0.027(2) Uani 1 1 d .
H17A H 0.3275 0.1990 -0.0937 0.032 Uiso 1 1 calc R
C18 C 0.3598(8) 0.1366(8) 0.0297(8) 0.027(2) Uani 1 1 d .
H18A H 0.3717 0.2106 0.0830 0.033 Uiso 1 1 calc R
C19 C 0.3458(9) -0.0633(8) -0.0200(7) 0.022(2) Uani 1 1 d .
H19A H 0.3468 -0.1329 -0.0012 0.027 Uiso 1 1 calc R
C20 C 0.3222(8) -0.0737(8) -0.1259(7) 0.0202(19) Uani 1 1 d U
H20A H 0.3074 -0.1486 -0.1790 0.024 Uiso 1 1 calc R
N4 N 0.3687(7) -0.0353(7) -0.3249(6) 0.0208(18) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O20 W1 O10 101.4(4) . .
O20 W1 O8 102.5(5) . .
O10 W1 O8 87.1(3) . .
O20 W1 O13 102.1(5) . .
O10 W1 O13 88.8(3) . .
O8 W1 O13 155.3(4) . .
O20 W1 O21 103.0(4) . .
O10 W1 O21 155.6(4) . .
O8 W1 O21 86.9(3) . .
O13 W1 O21 86.8(3) . .
O20 W1 O3 161.3(4) . 2_765
O10 W1 O3 93.4(3) . 2_765
O8 W1 O3 89.5(3) . 2_765
O13 W1 O3 66.5(3) . 2_765
O21 W1 O3 62.9(3) . 2_765
O20 W1 O2 159.4(4) . .
O10 W1 O2 63.9(3) . .
O8 W1 O2 64.1(3) . .
O13 W1 O2 92.3(3) . .
O21 W1 O2 92.3(3) . .
O3 W1 O2 39.3(2) 2_765 .
O18 W2 O21 102.6(4) . .
O18 W2 O7 104.1(5) . .
O21 W2 O7 89.6(3) . .
O18 W2 O6 101.3(4) . 2_765
O21 W2 O6 155.9(4) . 2_765
O7 W2 O6 88.1(3) . 2_765
O18 W2 O5 100.7(5) . .
O21 W2 O5 86.3(3) . .
O7 W2 O5 155.2(4) . .
O6 W2 O5 85.8(3) 2_765 .
O18 W2 O4 160.3(4) . .
O21 W2 O4 93.9(4) . .
O7 W2 O4 64.9(4) . .
O6 W2 O4 63.5(3) 2_765 .
O5 W2 O4 91.0(4) . .
O18 W2 O3 160.1(4) . 2_765
O21 W2 O3 63.4(3) . 2_765
O7 W2 O3 90.5(4) . 2_765
O6 W2 O3 92.6(3) 2_765 2_765
O5 W2 O3 65.8(3) . 2_765
O4 W2 O3 39.5(2) . 2_765
O9 W3 O19 102.9(4) . .
O9 W3 O6 102.3(4) . .
O19 W3 O6 89.8(4) . .
O9 W3 O11 100.8(4) . .
O19 W3 O11 156.2(3) . .
O6 W3 O11 87.1(3) . .
O9 W3 O10 101.5(4) . .
O19 W3 O10 87.4(3) . .
O6 W3 O10 156.1(3) . .
O11 W3 O10 86.0(4) . .
O9 W3 O4 159.9(4) . 2_765
O19 W3 O4 92.0(3) . 2_765
O6 W3 O4 63.8(3) . 2_765
O11 W3 O4 65.5(3) . 2_765
O10 W3 O4 92.5(3) . 2_765
O9 W3 O2 159.9(4) . .
O19 W3 O2 65.2(3) . .
O6 W3 O2 94.1(3) . .
O11 W3 O2 91.5(3) . .
O10 W3 O2 63.3(3) . .
O4 W3 O2 40.2(2) 2_765 .
O12 W4 O16 104.8(4) . .
O12 W4 O22 100.3(5) . .
O16 W4 O22 86.8(4) . .
O12 W4 O7 104.1(4) . 2_765
O16 W4 O7 84.8(4) . 2_765
O22 W4 O7 155.4(5) . 2_765
O12 W4 O11 100.3(3) . .
O16 W4 O11 154.8(4) . .
O22 W4 O11 90.3(4) . .
O7 W4 O11 87.6(3) 2_765 .
O12 W4 O1 158.5(3) . .
O16 W4 O1 62.8(4) . .
O22 W4 O1 63.1(4) . .
O7 W4 O1 92.6(3) 2_765 .
O11 W4 O1 93.7(3) . .
O14 W5 O8 101.2(4) . .
O14 W5 O16 104.7(4) . 2_765
O8 W5 O16 89.2(4) . 2_765
O14 W5 O19 102.0(3) . .
O8 W5 O19 86.2(3) . .
O16 W5 O19 153.2(4) 2_765 .
O14 W5 O17 102.8(5) . 2_765
O8 W5 O17 155.9(5) . 2_765
O16 W5 O17 87.2(4) 2_765 2_765
O19 W5 O17 86.4(4) . 2_765
O14 W5 O1 160.6(3) . 2_765
O8 W5 O1 93.5(3) . 2_765
O16 W5 O1 62.5(4) 2_765 2_765
O19 W5 O1 91.5(3) . 2_765
O17 W5 O1 63.8(4) 2_765 2_765
O15 W6 O17 101.4(5) . .
O15 W6 O5 101.0(4) . .
O17 W6 O5 91.2(4) . .
O15 W6 O22 101.7(5) . .
O17 W6 O22 87.4(4) . .
O5 W6 O22 157.1(5) . .
O15 W6 O13 99.7(3) . .
O17 W6 O13 158.8(5) . .
O5 W6 O13 86.7(3) . .
O22 W6 O13 86.4(4) . .
O15 W6 O1 160.7(3) . .
O17 W6 O1 66.2(4) . .
O5 W6 O1 94.3(3) . .
O22 W6 O1 64.3(4) . .
O13 W6 O1 92.9(3) . .
O3 P1 O3 180.0(8) 2_765 .
O3 P1 O2 67.5(5) 2_765 .
O3 P1 O2 112.5(5) . .
O3 P1 O2 112.5(5) 2_765 2_765
O3 P1 O2 67.5(5) . 2_765
O2 P1 O2 180.0(4) . 2_765
O3 P1 O4 67.9(4) 2_765 .
O3 P1 O4 112.1(4) . .
O2 P1 O4 111.1(5) . .
O2 P1 O4 68.9(5) 2_765 .
O3 P1 O4 112.1(4) 2_765 2_765
O3 P1 O4 67.9(4) . 2_765
O2 P1 O4 68.9(5) . 2_765
O2 P1 O4 111.1(5) 2_765 2_765
O4 P1 O4 180.000(1) . 2_765
O3 P1 O1 107.7(5) 2_765 2_765
O3 P1 O1 72.3(5) . 2_765
O2 P1 O1 73.5(4) . 2_765
O2 P1 O1 106.5(4) 2_765 2_765
O4 P1 O1 73.6(5) . 2_765
O4 P1 O1 106.4(5) 2_765 2_765
O3 P1 O1 72.3(5) 2_765 .
O3 P1 O1 107.7(5) . .
O2 P1 O1 106.5(4) . .
O2 P1 O1 73.5(4) 2_765 .
O4 P1 O1 106.4(5) . .
O4 P1 O1 73.6(5) 2_765 .
O1 P1 O1 180.0(5) 2_765 .
P1 O1 O3 52.5(3) . 2_765
P1 O1 O2 52.2(3) . 2_765
O3 O1 O2 87.1(5) 2_765 2_765
P1 O1 W6 125.9(5) . .
O3 O1 W6 73.4(4) 2_765 .
O2 O1 W6 132.1(5) 2_765 .
P1 O1 W4 122.6(4) . .
O3 O1 W4 132.0(4) 2_765 .
O2 O1 W4 130.3(6) 2_765 .
W6 O1 W4 92.9(2) . .
P1 O1 W5 122.6(4) . 2_765
O3 O1 W5 134.1(5) 2_765 2_765
O2 O1 W5 70.4(3) 2_765 2_765
W6 O1 W5 92.4(2) . 2_765
W4 O1 W5 91.1(3) . 2_765
P1 O2 O3 55.9(3) . 2_765
P1 O2 O4 55.6(3) . 2_765
O3 O2 O4 95.2(5) 2_765 2_765
P1 O2 O1 54.3(3) . 2_765
O3 O2 O1 89.2(4) 2_765 2_765
O4 O2 O1 87.6(5) 2_765 2_765
P1 O2 W1 126.2(5) . .
O3 O2 W1 70.3(4) 2_765 .
O4 O2 W1 135.3(6) 2_765 .
O1 O2 W1 132.2(6) 2_765 .
P1 O2 W3 125.4(5) . .
O3 O2 W3 137.6(5) 2_765 .
O4 O2 W3 69.9(4) 2_765 .
O1 O2 W3 127.7(5) 2_765 .
W1 O2 W3 92.3(2) . .
P1 O3 O2 56.6(4) . 2_765
P1 O3 O4 56.4(3) . 2_765
O2 O3 O4 96.1(6) 2_765 2_765
P1 O3 O1 55.2(4) . 2_765
O2 O3 O1 89.9(5) 2_765 2_765
O4 O3 O1 89.6(5) 2_765 2_765
P1 O3 W1 127.0(5) . 2_765
O2 O3 W1 70.4(4) 2_765 2_765
O4 O3 W1 138.2(6) 2_765 2_765
O1 O3 W1 128.3(4) 2_765 2_765
P1 O3 W2 126.4(4) . 2_765
O2 O3 W2 136.0(6) 2_765 2_765
O4 O3 W2 70.0(4) 2_765 2_765
O1 O3 W2 129.8(5) 2_765 2_765
W1 O3 W2 92.2(2) 2_765 2_765
P1 O4 O3 55.7(3) . 2_765
P1 O4 O2 55.5(3) . 2_765
O3 O4 O2 95.2(5) 2_765 2_765
P1 O4 W2 126.2(5) . .
O3 O4 W2 70.5(4) 2_765 .
O2 O4 W2 137.5(6) 2_765 .
P1 O4 W3 125.5(5) . 2_765
O3 O4 W3 136.0(6) 2_765 2_765
O2 O4 W3 69.9(4) 2_765 2_765
W2 O4 W3 92.5(2) . 2_765
W6 O5 W2 139.4(5) . .
W3 O6 W2 139.3(5) . 2_765
W2 O7 W4 141.0(5) . 2_765
W5 O8 W1 142.3(5) . .
W1 O10 W3 139.5(5) . .
W4 O11 W3 139.2(4) . .
W1 O13 W6 138.4(4) . .
W5 O16 W4 142.8(6) 2_765 .
W6 O17 W5 137.2(7) . 2_765
W3 O19 W5 140.8(4) . .
W2 O21 W1 140.8(6) . .
W4 O22 W6 139.2(6) . .
N2 Ag1 N2 180.0(4) . 2_766
N4 Ag2 N3 139.1(3) 2_655 .
N4 Ag2 N1 126.5(3) 2_655 .
N3 Ag2 N1 93.9(3) . .
C5 N1 C1 118.0(9) . .
C5 N1 Ag2 120.9(6) . .
C1 N1 Ag2 117.0(6) . .
C2 C1 N1 123.2(9) . .
C3 C2 C1 118.1(9) . .
C2 C3 C4 120.0(10) . .
C5 C4 C3 118.6(8) . .
N1 C5 C4 122.2(8) . .
N1 C5 C6 115.0(8) . .
C4 C5 C6 122.7(8) . .
C10 C6 C7 117.5(8) . .
C10 C6 C5 120.5(7) . .
C7 C6 C5 122.0(9) . .
C8 C7 C6 120.5(9) . .
C7 C8 N2 122.4(8) . .
N2 C9 C10 123.2(9) . .
C6 C10 C9 119.9(8) . .
C9 N2 C8 116.3(7) . .
C9 N2 Ag1 121.6(6) . .
C8 N2 Ag1 122.0(5) . .
C18 N3 C19 114.7(8) . .
C18 N3 Ag2 121.2(6) . .
C19 N3 Ag2 121.8(6) . .
N4 C11 C12 121.0(10) . .
C13 C12 C11 121.7(11) . .
C12 C13 C14 118.7(11) . .
C13 C14 C15 119.7(11) . .
N4 C15 C14 121.7(9) . .
N4 C15 C16 114.1(9) . .
C14 C15 C16 124.1(10) . .
C20 C16 C17 117.5(10) . .
C20 C16 C15 120.6(8) . .
C17 C16 C15 121.8(10) . .
C18 C17 C16 120.7(10) . .
C17 C18 N3 123.4(9) . .
C20 C19 N3 124.3(9) . .
C19 C20 C16 119.3(9) . .
C11 N4 C15 117.2(9) . .
C11 N4 Ag2 121.1(7) . 2_655
C15 N4 Ag2 120.9(6) . 2_655
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
W1 O20 1.685(8) .
W1 O10 1.874(6) .
W1 O8 1.897(8) .
W1 O13 1.899(7) .
W1 O21 1.921(7) .
W1 O3 2.467(7) 2_765
W1 O2 2.469(9) .
W2 O18 1.655(8) .
W2 O21 1.858(7) .
W2 O7 1.865(8) .
W2 O6 1.921(7) 2_765
W2 O5 1.922(8) .
W2 O4 2.466(9) .
W2 O3 2.474(7) 2_765
W3 O9 1.677(7) .
W3 O19 1.874(8) .
W3 O6 1.884(8) .
W3 O11 1.906(8) .
W3 O10 1.924(8) .
W3 O4 2.471(8) 2_765
W3 O2 2.472(8) .
W4 O12 1.665(7) .
W4 O16 1.878(9) .
W4 O22 1.886(9) .
W4 O7 1.897(9) 2_765
W4 O11 1.899(7) .
W4 O1 2.484(8) .
W5 O14 1.671(7) .
W5 O8 1.871(9) .
W5 O16 1.877(9) 2_765
W5 O19 1.912(7) .
W5 O17 1.933(10) 2_765
W5 O1 2.499(7) 2_765
W6 O15 1.680(7) .
W6 O17 1.879(10) .
W6 O5 1.888(8) .
W6 O22 1.906(8) .
W6 O13 1.927(7) .
W6 O1 2.419(9) .
P1 O3 1.488(6) 2_765
P1 O3 1.488(6) .
P1 O2 1.500(6) .
P1 O2 1.500(6) 2_765
P1 O4 1.501(5) .
P1 O4 1.501(5) 2_765
P1 O1 1.541(6) 2_765
P1 O1 1.541(6) .
O1 O3 1.787(12) 2_765
O1 O2 1.820(11) 2_765
O1 W5 2.499(7) 2_765
O2 O3 1.660(11) 2_765
O2 O4 1.697(12) 2_765
O2 O1 1.820(11) 2_765
O3 O2 1.660(11) 2_765
O3 O4 1.669(11) 2_765
O3 O1 1.787(12) 2_765
O3 W1 2.467(7) 2_765
O3 W2 2.474(7) 2_765
O4 O3 1.669(11) 2_765
O4 O2 1.697(12) 2_765
O4 W3 2.471(8) 2_765
O6 W2 1.921(7) 2_765
O7 W4 1.897(9) 2_765
O16 W5 1.877(9) 2_765
O17 W5 1.933(10) 2_765
Ag1 N2 2.122(7) .
Ag1 N2 2.122(7) 2_766
Ag2 N4 2.212(8) 2_655
Ag2 N3 2.262(8) .
Ag2 N1 2.315(8) .
N1 C5 1.329(10) .
N1 C1 1.376(11) .
C1 C2 1.362(15) .
C2 C3 1.355(14) .
C3 C4 1.413(13) .
C4 C5 1.367(14) .
C5 C6 1.499(12) .
C6 C10 1.377(14) .
C6 C7 1.398(12) .
C7 C8 1.345(13) .
C8 N2 1.395(13) .
C9 N2 1.341(11) .
C9 C10 1.381(12) .
N3 C18 1.359(13) .
N3 C19 1.384(11) .
C11 N4 1.348(13) .
C11 C12 1.379(16) .
C12 C13 1.322(17) .
C13 C14 1.362(16) .
C14 C15 1.376(15) .
C15 N4 1.361(13) .
C15 C16 1.496(15) .
C16 C20 1.379(15) .
C16 C17 1.386(13) .
C17 C18 1.354(15) .
C19 C20 1.354(13) .
N4 Ag2 2.212(8) 2_655
