#------------------------------------------------------------------------------
#$Date: 2016-03-24 02:37:24 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179589 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/54/4505467.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4505467
loop_
_publ_author_name
'Mu, Yajuan'
'Han, Gang'
'Li, Zhen'
'Liu, Xiaoting'
'Hou, Hongwei'
'Fan, Yaoting'
_publ_section_title
;
 Effect of Organic Polycarboxylate Ligands on the Structures of a Series
 of Zinc(II) Coordination Polymers Based on a Conformational Bis-triazole
 Ligand
;
_journal_issue                   3
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              1193
_journal_paper_doi               10.1021/cg201180u
_journal_volume                  12
_journal_year                    2012
_chemical_formula_sum            'C24 H24 N6 O4 Zn'
_chemical_formula_weight         525.86
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                112.94(3)
_cell_angle_beta                 97.04(3)
_cell_angle_gamma                105.01(3)
_cell_formula_units_Z            2
_cell_length_a                   10.293(2)
_cell_length_b                   10.613(2)
_cell_length_c                   12.534(3)
_cell_measurement_reflns_used    3543
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.8644
_cell_measurement_theta_min      2.1163
_cell_volume                     1178.8(6)
_computing_cell_refinement       'CrystalClear (Rigaku/MSC Inc., 2006)'
_computing_data_collection       'CrystalClear (Rigaku/MSC Inc., 2006)'
_computing_data_reduction        'CrystalClear (Rigaku/MSC Inc., 2006)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.968
_diffrn_measured_fraction_theta_max 0.968
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0375
_diffrn_reflns_av_sigmaI/netI    0.0577
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            7789
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.16
_exptl_absorpt_coefficient_mu    1.086
_exptl_absorpt_correction_T_max  0.8286
_exptl_absorpt_correction_T_min  0.8121
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'CrystalClear (Rigaku/MSC Inc., 2006)'
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.481
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             544
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.18
_refine_diff_density_max         1.611
_refine_diff_density_min         -0.472
_refine_diff_density_rms         0.105
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.123
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     320
_refine_ls_number_reflns         4018
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.123
_refine_ls_R_factor_all          0.0846
_refine_ls_R_factor_gt           0.0744
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1041P)²+2.7391P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2020
_refine_ls_wR_factor_ref         0.2104
_reflns_number_gt                3449
_reflns_number_total             4018
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg201180u_si_002.cif
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4505467
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Zn1 Zn 0.89579(7) 0.89027(8) 0.68630(6) 0.0361(3) Uani 1 1 d .
N1 N 0.9063(5) 0.8489(5) 0.8305(4) 0.0377(11) Uani 1 1 d .
N2 N 0.9731(6) 0.7923(7) 0.9775(5) 0.0520(15) Uani 1 1 d .
N3 N 0.8358(4) 0.7677(5) 0.9576(4) 0.0287(10) Uani 1 1 d .
N4 N -0.0368(5) 0.0920(6) 0.6962(5) 0.0414(12) Uani 1 1 d .
N5 N 0.0183(6) 0.3329(6) 0.7616(6) 0.0555(15) Uani 1 1 d .
N6 N 0.1033(5) 0.2810(6) 0.6920(4) 0.0389(12) Uani 1 1 d .
C1 C 0.6200(6) 0.8439(7) 0.6470(5) 0.0354(13) Uani 1 1 d .
C2 C 0.4660(5) 0.7672(7) 0.5895(5) 0.0363(13) Uani 1 1 d .
C3 C 0.4156(6) 0.6321(7) 0.4908(6) 0.0417(14) Uani 1 1 d .
H3 H 0.4771 0.5873 0.4580 0.050 Uiso 1 1 calc R
C4 C 0.2734(7) 0.5636(7) 0.4410(7) 0.0517(17) Uani 1 1 d .
H4 H 0.2399 0.4727 0.3755 0.062 Uiso 1 1 calc R
C5 C 0.1812(6) 0.6308(7) 0.4890(6) 0.0436(15) Uani 1 1 d .
H5 H 0.0862 0.5851 0.4545 0.052 Uiso 1 1 calc R
C6 C 0.2289(6) 0.7644(7) 0.5871(5) 0.0353(13) Uani 1 1 d .
C7 C 0.1321(5) 0.8378(7) 0.6445(5) 0.0350(13) Uani 1 1 d .
C8 C 0.3740(5) 0.8340(6) 0.6390(5) 0.0313(12) Uani 1 1 d .
H8 H 0.4073 0.9238 0.7058 0.038 Uiso 1 1 calc R
C9 C 0.7966(6) 0.8020(8) 0.8683(6) 0.0478(16) Uani 1 1 d .
H9 H 0.7062 0.7940 0.8378 0.057 Uiso 1 1 calc R
C10 C 1.0112(6) 0.8419(8) 0.9009(6) 0.0511(17) Uani 1 1 d .
H10 H 1.1028 0.8697 0.8959 0.061 Uiso 1 1 calc R
C11 C 0.7442(7) 0.7081(8) 1.0198(6) 0.0453(15) Uani 1 1 d .
H11A H 0.7377 0.7870 1.0894 0.054 Uiso 1 1 calc R
H11B H 0.7833 0.6488 1.0471 0.054 Uiso 1 1 calc R
C12 C 0.6014(6) 0.6175(7) 0.9381(5) 0.0406(14) Uani 1 1 d .
C13 C 0.5779(6) 0.4741(7) 0.8586(6) 0.0382(13) Uani 1 1 d .
C14 C 0.6906(8) 0.4069(8) 0.8588(7) 0.0578(19) Uani 1 1 d .
H14A H 0.7439 0.4217 0.8043 0.087 Uiso 1 1 calc R
H14B H 0.6491 0.3047 0.8341 0.087 Uiso 1 1 calc R
H14C H 0.7505 0.4517 0.9379 0.087 Uiso 1 1 calc R
C15 C 0.4489(6) 0.3927(6) 0.7751(5) 0.0378(13) Uani 1 1 d .
C16 C 0.4210(8) 0.2340(7) 0.6894(7) 0.0540(17) Uani 1 1 d .
H16A H 0.5077 0.2170 0.6844 0.081 Uiso 1 1 calc R
H16B H 0.3704 0.2133 0.6115 0.081 Uiso 1 1 calc R
H16C H 0.3672 0.1720 0.7186 0.081 Uiso 1 1 calc R
C17 C 0.3472(6) 0.4584(7) 0.7702(5) 0.0366(13) Uani 1 1 d .
C18 C 0.3704(6) 0.6015(7) 0.8531(6) 0.0393(14) Uani 1 1 d .
C19 C 0.2577(8) 0.6710(8) 0.8535(7) 0.0569(18) Uani 1 1 d .
H19A H 0.2600 0.7312 0.9346 0.085 Uiso 1 1 calc R
H19B H 0.1684 0.5963 0.8155 0.085 Uiso 1 1 calc R
H19C H 0.2739 0.7291 0.8108 0.085 Uiso 1 1 calc R
C20 C 0.4992(7) 0.6821(6) 0.9371(5) 0.0386(14) Uani 1 1 d .
C21 C 0.5265(9) 0.8409(8) 1.0190(7) 0.061(2) Uani 1 1 d .
H21A H 0.4704 0.8477 1.0754 0.092 Uiso 1 1 calc R
H21B H 0.5035 0.8887 0.9720 0.092 Uiso 1 1 calc R
H21C H 0.6229 0.8866 1.0612 0.092 Uiso 1 1 calc R
C22 C 0.2161(6) 0.3766(7) 0.6692(6) 0.0435(15) Uani 1 1 d .
H22A H 0.1826 0.4466 0.6534 0.052 Uiso 1 1 calc R
H22B H 0.2394 0.3185 0.5976 0.052 Uiso 1 1 calc R
C23 C 0.0688(6) 0.1412(7) 0.6557(6) 0.0436(15) Uani 1 1 d .
H23 H 0.1125 0.0834 0.6076 0.052 Uiso 1 1 calc R
C24 C -0.0644(7) 0.2126(8) 0.7599(7) 0.0514(17) Uani 1 1 d .
H24 H -0.1353 0.2120 0.7994 0.062 Uiso 1 1 calc R
O1 O 0.7008(4) 0.7827(5) 0.5926(4) 0.0440(11) Uani 1 1 d .
O2 O 0.6613(4) 0.9574(5) 0.7398(4) 0.0552(13) Uani 1 1 d .
O3 O 0.0038(4) 0.7843(5) 0.5861(4) 0.0468(11) Uani 1 1 d .
O4 O 0.1767(4) 0.9459(5) 0.7434(4) 0.0472(11) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Zn1 O3 103.97(18) . 1_655
O1 Zn1 N1 104.1(2) . .
O3 Zn1 N1 106.6(2) 1_655 .
O1 Zn1 N4 112.1(2) . 1_665
O3 Zn1 N4 104.6(2) 1_655 1_665
N1 Zn1 N4 123.8(2) . 1_665
C9 N1 C10 103.0(5) . .
C9 N1 Zn1 124.4(4) . .
C10 N1 Zn1 132.2(4) . .
C10 N2 N3 104.2(5) . .
N2 N3 C9 108.5(5) . .
N2 N3 C11 125.1(5) . .
C9 N3 C11 126.4(5) . .
C23 N4 C24 103.0(5) . .
C23 N4 Zn1 125.0(4) . 1_445
C24 N4 Zn1 130.9(4) . 1_445
C24 N5 N6 102.1(5) . .
C23 N6 N5 109.5(5) . .
C23 N6 C22 128.1(6) . .
N5 N6 C22 122.4(5) . .
O2 C1 O1 123.9(5) . .
O2 C1 C2 120.3(5) . .
O1 C1 C2 115.8(5) . .
C3 C2 C8 119.9(5) . .
C3 C2 C1 121.6(5) . .
C8 C2 C1 118.5(5) . .
C4 C3 C2 120.2(5) . .
C4 C3 H3 119.9 . .
C2 C3 H3 119.9 . .
C5 C4 C3 120.1(6) . .
C5 C4 H4 120.0 . .
C3 C4 H4 120.0 . .
C6 C5 C4 120.7(6) . .
C6 C5 H5 119.7 . .
C4 C5 H5 119.7 . .
C5 C6 C8 119.4(5) . .
C5 C6 C7 122.2(5) . .
C8 C6 C7 118.3(5) . .
O4 C7 O3 122.6(5) . .
O4 C7 C6 120.4(5) . .
O3 C7 C6 116.9(5) . .
C2 C8 C6 119.7(5) . .
C2 C8 H8 120.2 . .
C6 C8 H8 120.2 . .
N1 C9 N3 110.0(5) . .
N1 C9 H9 125.0 . .
N3 C9 H9 125.0 . .
N2 C10 N1 114.2(6) . .
N2 C10 H10 122.9 . .
N1 C10 H10 122.9 . .
N3 C11 C12 110.7(5) . .
N3 C11 H11A 109.5 . .
C12 C11 H11A 109.5 . .
N3 C11 H11B 109.5 . .
C12 C11 H11B 109.5 . .
H11A C11 H11B 108.1 . .
C13 C12 C20 121.6(6) . .
C13 C12 C11 118.8(6) . .
C20 C12 C11 119.4(6) . .
C12 C13 C15 119.2(5) . .
C12 C13 C14 121.0(6) . .
C15 C13 C14 119.8(6) . .
C13 C14 H14A 109.5 . .
C13 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C13 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C13 C15 C17 119.7(6) . .
C13 C15 C16 119.5(6) . .
C17 C15 C16 120.8(6) . .
C15 C16 H16A 109.5 . .
C15 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C15 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C18 C17 C15 120.6(5) . .
C18 C17 C22 120.0(6) . .
C15 C17 C22 119.3(6) . .
C17 C18 C20 119.4(6) . .
C17 C18 C19 121.1(6) . .
C20 C18 C19 119.5(6) . .
C18 C19 H19A 109.5 . .
C18 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
C18 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
C12 C20 C18 119.4(6) . .
C12 C20 C21 121.9(6) . .
C18 C20 C21 118.5(6) . .
C20 C21 H21A 109.5 . .
C20 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
C20 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
N6 C22 C17 114.8(5) . .
N6 C22 H22A 108.6 . .
C17 C22 H22A 108.6 . .
N6 C22 H22B 108.6 . .
C17 C22 H22B 108.6 . .
H22A C22 H22B 107.5 . .
N6 C23 N4 111.2(6) . .
N6 C23 H23 124.4 . .
N4 C23 H23 124.4 . .
N5 C24 N4 114.1(6) . .
N5 C24 H24 122.9 . .
N4 C24 H24 122.9 . .
C1 O1 Zn1 109.9(4) . .
C7 O3 Zn1 109.0(4) . 1_455
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Zn1 O1 1.975(4) .
Zn1 O3 1.991(4) 1_655
Zn1 N1 2.016(5) .
Zn1 N4 2.021(5) 1_665
N1 C9 1.331(8) .
N1 C10 1.345(8) .
N2 C10 1.316(9) .
N2 N3 1.342(7) .
N3 C9 1.353(8) .
N3 C11 1.468(7) .
N4 C23 1.327(8) .
N4 C24 1.343(9) .
N4 Zn1 2.021(5) 1_445
N5 C24 1.329(9) .
N5 N6 1.375(7) .
N6 C23 1.302(8) .
N6 C22 1.468(8) .
C1 O2 1.228(7) .
C1 O1 1.285(7) .
C1 C2 1.513(8) .
C2 C3 1.390(8) .
C2 C8 1.391(8) .
C3 C4 1.390(9) .
C3 H3 0.9300 .
C4 C5 1.388(9) .
C4 H4 0.9300 .
C5 C6 1.377(9) .
C5 H5 0.9300 .
C6 C8 1.419(8) .
C6 C7 1.503(8) .
C7 O4 1.242(7) .
C7 O3 1.286(7) .
C8 H8 0.9300 .
C9 H9 0.9300 .
C10 H10 0.9300 .
C11 C12 1.505(8) .
C11 H11A 0.9700 .
C11 H11B 0.9700 .
C12 C13 1.391(9) .
C12 C20 1.397(9) .
C13 C15 1.402(9) .
C13 C14 1.511(9) .
C14 H14A 0.9600 .
C14 H14B 0.9600 .
C14 H14C 0.9600 .
C15 C17 1.408(8) .
C15 C16 1.529(9) .
C16 H16A 0.9600 .
C16 H16B 0.9600 .
C16 H16C 0.9600 .
C17 C18 1.401(9) .
C17 C22 1.514(8) .
C18 C20 1.403(9) .
C18 C19 1.527(9) .
C19 H19A 0.9600 .
C19 H19B 0.9600 .
C19 H19C 0.9600 .
C20 C21 1.520(9) .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
C22 H22A 0.9700 .
C22 H22B 0.9700 .
C23 H23 0.9300 .
C24 H24 0.9300 .
O3 Zn1 1.991(4) 1_455
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 Zn1 N1 C9 -19.5(6) . .
O3 Zn1 N1 C9 -129.1(5) 1_655 .
N4 Zn1 N1 C9 109.8(6) 1_665 .
O1 Zn1 N1 C10 151.2(6) . .
O3 Zn1 N1 C10 41.6(6) 1_655 .
N4 Zn1 N1 C10 -79.5(7) 1_665 .
C10 N2 N3 C9 0.8(7) . .
C10 N2 N3 C11 178.5(6) . .
C24 N5 N6 C23 -0.4(7) . .
C24 N5 N6 C22 -178.8(6) . .
O2 C1 C2 C3 -174.0(6) . .
O1 C1 C2 C3 6.1(9) . .
O2 C1 C2 C8 4.9(9) . .
O1 C1 C2 C8 -175.0(5) . .
C8 C2 C3 C4 0.3(10) . .
C1 C2 C3 C4 179.2(6) . .
C2 C3 C4 C5 0.7(11) . .
C3 C4 C5 C6 -1.0(11) . .
C4 C5 C6 C8 0.3(10) . .
C4 C5 C6 C7 -177.5(6) . .
C5 C6 C7 O4 168.3(6) . .
C8 C6 C7 O4 -9.6(9) . .
C5 C6 C7 O3 -12.3(9) . .
C8 C6 C7 O3 169.8(5) . .
C3 C2 C8 C6 -0.9(9) . .
C1 C2 C8 C6 -179.8(5) . .
C5 C6 C8 C2 0.6(9) . .
C7 C6 C8 C2 178.6(5) . .
C10 N1 C9 N3 -0.4(8) . .
Zn1 N1 C9 N3 172.6(4) . .
N2 N3 C9 N1 -0.2(8) . .
C11 N3 C9 N1 -178.0(6) . .
N3 N2 C10 N1 -1.1(8) . .
C9 N1 C10 N2 0.9(8) . .
Zn1 N1 C10 N2 -171.2(5) . .
N2 N3 C11 C12 -147.4(6) . .
C9 N3 C11 C12 30.0(9) . .
N3 C11 C12 C13 82.4(7) . .
N3 C11 C12 C20 -92.5(7) . .
C20 C12 C13 C15 0.3(9) . .
C11 C12 C13 C15 -174.5(5) . .
C20 C12 C13 C14 178.5(6) . .
C11 C12 C13 C14 3.7(9) . .
C12 C13 C15 C17 2.2(9) . .
C14 C13 C15 C17 -176.0(6) . .
C12 C13 C15 C16 -178.5(6) . .
C14 C13 C15 C16 3.3(9) . .
C13 C15 C17 C18 -4.1(9) . .
C16 C15 C17 C18 176.6(6) . .
C13 C15 C17 C22 171.7(5) . .
C16 C15 C17 C22 -7.6(9) . .
C15 C17 C18 C20 3.6(9) . .
C22 C17 C18 C20 -172.2(5) . .
C15 C17 C18 C19 -176.3(6) . .
C22 C17 C18 C19 7.9(9) . .
C13 C12 C20 C18 -0.9(9) . .
C11 C12 C20 C18 173.9(5) . .
C13 C12 C20 C21 -176.6(6) . .
C11 C12 C20 C21 -1.8(9) . .
C17 C18 C20 C12 -1.1(9) . .
C19 C18 C20 C12 178.8(6) . .
C17 C18 C20 C21 174.8(6) . .
C19 C18 C20 C21 -5.3(9) . .
C23 N6 C22 C17 -98.9(8) . .
N5 N6 C22 C17 79.2(8) . .
C18 C17 C22 N6 -96.7(7) . .
C15 C17 C22 N6 87.5(7) . .
N5 N6 C23 N4 0.2(7) . .
C22 N6 C23 N4 178.4(5) . .
C24 N4 C23 N6 0.1(7) . .
Zn1 N4 C23 N6 -169.2(4) 1_445 .
N6 N5 C24 N4 0.5(8) . .
C23 N4 C24 N5 -0.4(8) . .
Zn1 N4 C24 N5 168.0(5) 1_445 .
O2 C1 O1 Zn1 4.1(8) . .
C2 C1 O1 Zn1 -176.1(4) . .
O3 Zn1 O1 C1 -178.2(4) 1_655 .
N1 Zn1 O1 C1 70.3(4) . .
N4 Zn1 O1 C1 -65.7(4) 1_665 .
O4 C7 O3 Zn1 -5.1(8) . 1_455
C6 C7 O3 Zn1 175.5(4) . 1_455
