#------------------------------------------------------------------------------
#$Date: 2016-03-24 02:37:24 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179589 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/54/4505468.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4505468
loop_
_publ_author_name
'Mu, Yajuan'
'Han, Gang'
'Li, Zhen'
'Liu, Xiaoting'
'Hou, Hongwei'
'Fan, Yaoting'
_publ_section_title
;
 Effect of Organic Polycarboxylate Ligands on the Structures of a Series
 of Zinc(II) Coordination Polymers Based on a Conformational Bis-triazole
 Ligand
;
_journal_issue                   3
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              1193
_journal_paper_doi               10.1021/cg201180u
_journal_volume                  12
_journal_year                    2012
_chemical_formula_sum            'C24 H28 N6 O6 Zn'
_chemical_formula_weight         561.89
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                104.26(3)
_cell_angle_beta                 110.35(3)
_cell_angle_gamma                107.40(3)
_cell_formula_units_Z            2
_cell_length_a                   9.2779(19)
_cell_length_b                   12.140(2)
_cell_length_c                   13.159(3)
_cell_measurement_reflns_used    3927
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.8764
_cell_measurement_theta_min      2.0454
_cell_volume                     1220.2(7)
_computing_cell_refinement       'CrystalClear (Rigaku/MSC Inc., 2006)'
_computing_data_collection       'CrystalClear (Rigaku/MSC Inc., 2006)'
_computing_data_reduction        'CrystalClear (Rigaku/MSC Inc., 2006)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXS-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'Rigaku Saturn'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0369
_diffrn_reflns_av_sigmaI/netI    0.0446
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            15204
_diffrn_reflns_theta_full        27.95
_diffrn_reflns_theta_max         27.95
_diffrn_reflns_theta_min         1.91
_exptl_absorpt_coefficient_mu    1.060
_exptl_absorpt_correction_T_max  0.8160
_exptl_absorpt_correction_T_min  0.7701
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'CrystalClear (Rigaku/MSC Inc., 2006)'
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.529
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             584
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.26
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.826
_refine_diff_density_min         -0.703
_refine_diff_density_rms         0.082
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.106
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     338
_refine_ls_number_reflns         5787
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.119
_refine_ls_R_factor_all          0.0683
_refine_ls_R_factor_gt           0.0580
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0849P)²+0.5188P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1563
_refine_ls_wR_factor_ref         0.1667
_reflns_number_gt                4884
_reflns_number_total             5787
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg201180u_si_002.cif
_cod_data_source_block           2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4505468
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Zn1 Zn 0.06260(4) 0.70167(4) 0.44123(3) 0.03908(15) Uani 1 1 d .
N1 N 0.2726(3) 0.7175(3) 0.5742(2) 0.0391(6) Uani 1 1 d .
N2 N 0.5419(4) 0.7659(3) 0.6950(3) 0.0472(7) Uani 1 1 d .
N3 N 0.4337(3) 0.7003(3) 0.7287(2) 0.0391(6) Uani 1 1 d .
N4 N 1.1014(4) 0.8747(3) 1.4404(3) 0.0472(7) Uani 1 1 d .
N5 N 1.2424(5) 1.0604(4) 1.4445(3) 0.0752(12) Uani 1 1 d .
N6 N 1.0817(4) 1.0050(3) 1.3570(3) 0.0501(7) Uani 1 1 d .
C1 C 0.2748(4) 0.6717(3) 0.6557(3) 0.0388(7) Uani 1 1 d .
H1 H 0.1793 0.6262 0.6611 0.047 Uiso 1 1 calc R
C2 C 0.4405(4) 0.7740(3) 0.6024(3) 0.0435(7) Uani 1 1 d .
H2 H 0.4789 0.8147 0.5593 0.052 Uiso 1 1 calc R
C3 C 0.4965(5) 0.6632(3) 0.8272(3) 0.0481(8) Uani 1 1 d .
H3A H 0.5416 0.6035 0.8062 0.058 Uiso 1 1 calc R
H3B H 0.4024 0.6216 0.8410 0.058 Uiso 1 1 calc R
C4 C 0.6338(5) 0.7739(3) 0.9404(3) 0.0429(7) Uani 1 1 d .
C5 C 0.8058(5) 0.8019(3) 0.9717(3) 0.0444(8) Uani 1 1 d .
C6 C 0.9334(5) 0.8968(3) 1.0815(3) 0.0475(8) Uani 1 1 d .
C7 C 0.8848(6) 0.9648(3) 1.1565(3) 0.0518(9) Uani 1 1 d .
C8 C 0.7146(6) 0.9389(4) 1.1244(3) 0.0536(10) Uani 1 1 d .
C9 C 0.5868(5) 0.8426(3) 1.0147(3) 0.0465(8) Uani 1 1 d .
C10 C 0.8613(6) 0.7329(4) 0.8916(4) 0.0582(10) Uani 1 1 d .
H10A H 0.8954 0.6749 0.9204 0.087 Uiso 1 1 calc R
H10B H 0.9551 0.7921 0.8898 0.087 Uiso 1 1 calc R
H10C H 0.7687 0.6879 0.8134 0.087 Uiso 1 1 calc R
C11 C 1.1164(5) 0.9218(4) 1.1173(4) 0.0664(12) Uani 1 1 d .
H11A H 1.1305 0.8467 1.1173 0.100 Uiso 1 1 calc R
H11B H 1.1859 0.9868 1.1949 0.100 Uiso 1 1 calc R
H11C H 1.1495 0.9480 1.0627 0.100 Uiso 1 1 calc R
C12 C 0.6585(8) 1.0062(5) 1.2054(4) 0.0846(16) Uani 1 1 d .
H12A H 0.5969 1.0475 1.1676 0.127 Uiso 1 1 calc R
H12B H 0.7563 1.0673 1.2772 0.127 Uiso 1 1 calc R
H12C H 0.5866 0.9466 1.2229 0.127 Uiso 1 1 calc R
C13 C 0.4014(6) 0.8148(5) 0.9807(4) 0.0662(11) Uani 1 1 d .
H13A H 0.3334 0.7623 0.8984 0.099 Uiso 1 1 calc R
H13B H 0.3889 0.8921 0.9962 0.099 Uiso 1 1 calc R
H13C H 0.3650 0.7726 1.0262 0.099 Uiso 1 1 calc R
C14 C 1.0249(7) 1.0642(4) 1.2754(3) 0.0663(13) Uani 1 1 d .
H14A H 1.1199 1.1122 1.2656 0.080 Uiso 1 1 calc R
H14B H 0.9834 1.1214 1.3078 0.080 Uiso 1 1 calc R
C15 C 1.0006(5) 0.8948(4) 1.3561(3) 0.0513(9) Uani 1 1 d .
H15 H 0.8884 0.8396 1.3033 0.062 Uiso 1 1 calc R
C16 C 1.2499(5) 0.9805(4) 1.4928(4) 0.0633(11) Uani 1 1 d .
H16 H 1.3467 0.9935 1.5569 0.076 Uiso 1 1 calc R
C17 C -0.2354(4) 0.6260(3) 0.4465(3) 0.0427(7) Uani 1 1 d .
C18 C -0.3712(4) 0.5631(3) 0.4762(3) 0.0386(7) Uani 1 1 d .
C19 C -0.3342(4) 0.5190(3) 0.5653(3) 0.0427(7) Uani 1 1 d .
H19 H -0.2235 0.5313 0.6092 0.051 Uiso 1 1 calc R
C20 C -0.4617(4) 0.4568(3) 0.5890(3) 0.0418(7) Uani 1 1 d .
H20 H -0.4359 0.4278 0.6492 0.050 Uiso 1 1 calc R
C21 C 0.0976(7) 0.6250(5) 0.2490(4) 0.0608(11) Uani 1 1 d .
C22 C 0.0466(6) 0.5597(4) 0.1192(4) 0.0555(10) Uani 1 1 d .
C23 C 0.1693(7) 0.5718(5) 0.0811(4) 0.0662(12) Uani 1 1 d .
H23 H 0.2832 0.6202 0.1345 0.079 Uiso 1 1 calc R
C24 C -0.1220(7) 0.4887(5) 0.0376(4) 0.0662(12) Uani 1 1 d .
H24 H -0.2055 0.4812 0.0626 0.079 Uiso 1 1 calc R
O1 O -0.0863(3) 0.6387(3) 0.5088(2) 0.0544(7) Uani 1 1 d .
O2 O -0.2706(4) 0.6592(3) 0.3635(3) 0.0676(8) Uani 1 1 d .
O3 O -0.0161(4) 0.5852(3) 0.2809(3) 0.0676(8) Uani 1 1 d .
O4 O 0.2406(5) 0.7103(4) 0.3150(3) 0.0774(9) Uani 1 1 d .
O5 O 0.5211(14) 0.7868(9) 0.2827(8) 0.288(6) Uani 1 1 d .
H5A H 0.4181 0.7390 0.2334 0.433 Uiso 1 1 d R
H5B H 0.5824 0.7498 0.3068 0.433 Uiso 1 1 d R
O6 O 0.5906(13) 0.6170(11) 0.1174(9) 0.286(6) Uani 1 1 d D
H6A H 0.5668 0.5867 0.1643 0.428 Uiso 1 1 d RD
H6B H 0.5560 0.6091 0.0460 0.428 Uiso 1 1 d RD
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O3 Zn1 O1 111.62(13) . .
O3 Zn1 N4 108.39(13) . 1_454
O1 Zn1 N4 116.02(13) . 1_454
O3 Zn1 N1 119.12(13) . .
O1 Zn1 N1 93.36(11) . .
N4 Zn1 N1 108.05(13) 1_454 .
C1 N1 C2 103.1(3) . .
C1 N1 Zn1 126.1(2) . .
C2 N1 Zn1 130.8(2) . .
C2 N2 N3 103.0(3) . .
C1 N3 N2 110.0(3) . .
C1 N3 C3 129.0(3) . .
N2 N3 C3 120.8(3) . .
C15 N4 C16 103.5(3) . .
C15 N4 Zn1 123.4(3) . 1_656
C16 N4 Zn1 129.1(3) . 1_656
C16 N5 N6 103.7(3) . .
C15 N6 N5 109.6(3) . .
C15 N6 C14 129.6(4) . .
N5 N6 C14 120.6(3) . .
N1 C1 N3 109.8(3) . .
N1 C1 H1 125.1 . .
N3 C1 H1 125.1 . .
N2 C2 N1 114.0(3) . .
N2 C2 H2 123.0 . .
N1 C2 H2 123.0 . .
N3 C3 C4 112.9(3) . .
N3 C3 H3A 109.0 . .
C4 C3 H3A 109.0 . .
N3 C3 H3B 109.0 . .
C4 C3 H3B 109.0 . .
H3A C3 H3B 107.8 . .
C9 C4 C5 120.9(3) . .
C9 C4 C3 119.3(3) . .
C5 C4 C3 119.7(3) . .
C4 C5 C6 120.1(3) . .
C4 C5 C10 122.3(3) . .
C6 C5 C10 117.6(4) . .
C5 C6 C7 118.6(4) . .
C5 C6 C11 120.0(4) . .
C7 C6 C11 121.4(4) . .
C8 C7 C6 121.2(3) . .
C8 C7 C14 121.4(4) . .
C6 C7 C14 117.3(4) . .
C7 C8 C9 120.0(3) . .
C7 C8 C12 122.3(4) . .
C9 C8 C12 117.6(4) . .
C4 C9 C8 119.1(4) . .
C4 C9 C13 121.4(4) . .
C8 C9 C13 119.5(4) . .
C5 C10 H10A 109.5 . .
C5 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C5 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
C6 C11 H11A 109.5 . .
C6 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
C6 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
C8 C12 H12A 109.5 . .
C8 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C8 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
C9 C13 H13A 109.5 . .
C9 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
C9 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
N6 C14 C7 110.2(3) . .
N6 C14 H14A 109.6 . .
C7 C14 H14A 109.6 . .
N6 C14 H14B 109.6 . .
C7 C14 H14B 109.6 . .
H14A C14 H14B 108.1 . .
N4 C15 N6 109.9(3) . .
N4 C15 H15 125.1 . .
N6 C15 H15 125.1 . .
N5 C16 N4 113.2(4) . .
N5 C16 H16 123.4 . .
N4 C16 H16 123.4 . .
O2 C17 O1 123.2(3) . .
O2 C17 C18 120.2(3) . .
O1 C17 C18 116.6(3) . .
C19 C18 C20 119.1(3) . 2_466
C19 C18 C17 120.5(3) . .
C20 C18 C17 120.3(3) 2_466 .
C20 C19 C18 120.0(3) . .
C20 C19 H19 120.0 . .
C18 C19 H19 120.0 . .
C19 C20 C18 120.8(3) . 2_466
C19 C20 H20 119.6 . .
C18 C20 H20 119.6 2_466 .
O4 C21 O3 124.7(4) . .
O4 C21 C22 119.8(4) . .
O3 C21 C22 115.4(4) . .
C23 C22 C24 118.9(4) . .
C23 C22 C21 120.0(4) . .
C24 C22 C21 121.1(4) . .
C22 C23 C24 119.8(5) . 2_565
C22 C23 H23 120.1 . .
C24 C23 H23 120.1 2_565 .
C22 C24 C23 121.3(4) . 2_565
C22 C24 H24 119.3 . .
C23 C24 H24 119.3 2_565 .
C17 O1 Zn1 109.4(2) . .
C21 O3 Zn1 107.7(3) . .
H5A O5 H5B 115.5 . .
H6A O6 H6B 144.6 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Zn1 O3 1.955(3) .
Zn1 O1 1.960(3) .
Zn1 N4 2.026(3) 1_454
Zn1 N1 2.033(3) .
N1 C1 1.321(4) .
N1 C2 1.366(4) .
N2 C2 1.303(4) .
N2 N3 1.357(4) .
N3 C1 1.327(4) .
N3 C3 1.464(4) .
N4 C15 1.309(5) .
N4 C16 1.366(5) .
N4 Zn1 2.026(3) 1_656
N5 C16 1.290(6) .
N5 N6 1.352(5) .
N6 C15 1.319(5) .
N6 C14 1.470(5) .
C1 H1 0.9300 .
C2 H2 0.9300 .
C3 C4 1.522(5) .
C3 H3A 0.9700 .
C3 H3B 0.9700 .
C4 C9 1.398(5) .
C4 C5 1.407(5) .
C5 C6 1.411(5) .
C5 C10 1.509(5) .
C6 C7 1.411(6) .
C6 C11 1.504(6) .
C7 C8 1.394(6) .
C7 C14 1.520(5) .
C8 C9 1.416(6) .
C8 C12 1.513(6) .
C9 C13 1.522(6) .
C10 H10A 0.9600 .
C10 H10B 0.9600 .
C10 H10C 0.9600 .
C11 H11A 0.9600 .
C11 H11B 0.9600 .
C11 H11C 0.9600 .
C12 H12A 0.9600 .
C12 H12B 0.9600 .
C12 H12C 0.9600 .
C13 H13A 0.9600 .
C13 H13B 0.9600 .
C13 H13C 0.9600 .
C14 H14A 0.9700 .
C14 H14B 0.9700 .
C15 H15 0.9300 .
C16 H16 0.9300 .
C17 O2 1.228(5) .
C17 O1 1.277(4) .
C17 C18 1.497(4) .
C18 C19 1.385(5) .
C18 C20 1.395(5) 2_466
C19 C20 1.380(5) .
C19 H19 0.9300 .
C20 C18 1.395(5) 2_466
C20 H20 0.9300 .
C21 O4 1.233(6) .
C21 O3 1.275(5) .
C21 C22 1.522(6) .
C22 C23 1.379(6) .
C22 C24 1.383(7) .
C23 C24 1.392(6) 2_565
C23 H23 0.9300 .
C24 C23 1.392(6) 2_565
C24 H24 0.9300 .
O5 H5A 0.8500 .
O5 H5B 0.8500 .
O6 H6A 0.8499 .
O6 H6B 0.8500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O3 Zn1 N1 C1 -105.6(3) . .
O1 Zn1 N1 C1 11.5(3) . .
N4 Zn1 N1 C1 130.2(3) 1_454 .
O3 Zn1 N1 C2 73.9(3) . .
O1 Zn1 N1 C2 -169.0(3) . .
N4 Zn1 N1 C2 -50.2(3) 1_454 .
C2 N2 N3 C1 0.4(4) . .
C2 N2 N3 C3 176.1(3) . .
C16 N5 N6 C15 -0.4(5) . .
C16 N5 N6 C14 -176.3(4) . .
C2 N1 C1 N3 0.7(4) . .
Zn1 N1 C1 N3 -179.6(2) . .
N2 N3 C1 N1 -0.7(4) . .
C3 N3 C1 N1 -176.0(3) . .
N3 N2 C2 N1 0.1(4) . .
C1 N1 C2 N2 -0.5(4) . .
Zn1 N1 C2 N2 179.9(2) . .
C1 N3 C3 C4 -129.6(4) . .
N2 N3 C3 C4 55.5(4) . .
N3 C3 C4 C9 86.1(4) . .
N3 C3 C4 C5 -97.1(4) . .
C9 C4 C5 C6 2.7(5) . .
C3 C4 C5 C6 -174.1(3) . .
C9 C4 C5 C10 -177.7(3) . .
C3 C4 C5 C10 5.5(5) . .
C4 C5 C6 C7 -2.1(5) . .
C10 C5 C6 C7 178.3(3) . .
C4 C5 C6 C11 176.8(3) . .
C10 C5 C6 C11 -2.9(5) . .
C5 C6 C7 C8 0.7(5) . .
C11 C6 C7 C8 -178.1(3) . .
C5 C6 C7 C14 178.6(3) . .
C11 C6 C7 C14 -0.3(5) . .
C6 C7 C8 C9 0.0(5) . .
C14 C7 C8 C9 -177.7(3) . .
C6 C7 C8 C12 177.1(4) . .
C14 C7 C8 C12 -0.7(6) . .
C5 C4 C9 C8 -1.9(5) . .
C3 C4 C9 C8 174.9(3) . .
C5 C4 C9 C13 178.8(3) . .
C3 C4 C9 C13 -4.4(5) . .
C7 C8 C9 C4 0.6(5) . .
C12 C8 C9 C4 -176.6(3) . .
C7 C8 C9 C13 179.8(3) . .
C12 C8 C9 C13 2.7(5) . .
C15 N6 C14 C7 -23.6(7) . .
N5 N6 C14 C7 151.4(4) . .
C8 C7 C14 N6 100.6(4) . .
C6 C7 C14 N6 -77.2(5) . .
C16 N4 C15 N6 -0.1(5) . .
Zn1 N4 C15 N6 -159.3(3) 1_656 .
N5 N6 C15 N4 0.3(5) . .
C14 N6 C15 N4 175.7(4) . .
N6 N5 C16 N4 0.4(6) . .
C15 N4 C16 N5 -0.2(6) . .
Zn1 N4 C16 N5 157.4(4) 1_656 .
O2 C17 C18 C19 176.3(3) . .
O1 C17 C18 C19 -1.5(5) . .
O2 C17 C18 C20 -0.9(5) . 2_466
O1 C17 C18 C20 -178.7(3) . 2_466
C20 C18 C19 C20 -0.3(5) 2_466 .
C17 C18 C19 C20 -177.5(3) . .
C18 C19 C20 C18 0.3(6) . 2_466
O4 C21 C22 C23 16.6(6) . .
O3 C21 C22 C23 -163.5(4) . .
O4 C21 C22 C24 -162.7(4) . .
O3 C21 C22 C24 17.1(6) . .
C24 C22 C23 C24 -1.0(7) . 2_565
C21 C22 C23 C24 179.6(4) . 2_565
C23 C22 C24 C23 1.0(8) . 2_565
C21 C22 C24 C23 -179.6(4) . 2_565
O2 C17 O1 Zn1 -5.4(5) . .
C18 C17 O1 Zn1 172.3(2) . .
O3 Zn1 O1 C17 -61.2(3) . .
N4 Zn1 O1 C17 63.7(3) 1_454 .
N1 Zn1 O1 C17 175.6(2) . .
O4 C21 O3 Zn1 10.0(6) . .
C22 C21 O3 Zn1 -169.8(3) . .
O1 Zn1 O3 C21 -172.2(3) . .
N4 Zn1 O3 C21 58.9(3) 1_454 .
N1 Zn1 O3 C21 -65.1(3) . .
