#------------------------------------------------------------------------------
#$Date: 2016-03-24 02:38:42 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179590 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/55/4505546.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4505546
loop_
_publ_author_name
'Hou, Yu'
'Rodriguez, Mark A.'
'Nyman, May'
_publ_section_title
;
 Cation-Bonding and Protonation of the Fe4-Square Cluster
;
_journal_issue                   3
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              1422
_journal_paper_doi               10.1021/cg2015397
_journal_volume                  12
_journal_year                    2012
_chemical_formula_sum            'C52 H64 Fe8 N8 Na5 O80'
_chemical_formula_weight         2642.86
_chemical_name_common            'sodium iron(4) dioxo di-HPDTA diacetate'
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           11
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yb'
_symmetry_space_group_name_H-M   'P 1 21/m 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 100.6140(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            1
_cell_length_a                   11.0473(11)
_cell_length_b                   20.418(2)
_cell_length_c                   11.7437(12)
_cell_measurement_reflns_used    256
_cell_measurement_temperature    188(2)
_cell_measurement_theta_max      25.0
_cell_measurement_theta_min      1.0
_cell_volume                     2603.6(5)
_computing_cell_refinement       'SMART 5.054 (Bruker, 1998)'
_computing_data_collection       'SMART 5.054 (Bruker, 1998)'
_computing_data_reduction        'SAINT 6.02 (Bruker, 2001)'
_computing_molecular_graphics    'SHELXTL 5.1  (Bruker, 1998)'
_computing_publication_material  'SHELXTL 5.1  (Bruker, 1998)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      188(2)
_diffrn_detector_area_resol_mean 0
_diffrn_measured_fraction_theta_full 0.916
_diffrn_measured_fraction_theta_max 0.916
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0400
_diffrn_reflns_av_sigmaI/netI    0.0430
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            21680
_diffrn_reflns_theta_full        28.16
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.76
_exptl_absorpt_coefficient_mu    1.225
_exptl_absorpt_correction_T_max  0.802
_exptl_absorpt_correction_T_min  0.620
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'Bruker 2000'
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.686
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       rectangle
_exptl_crystal_F_000             1335
_exptl_crystal_size_max          0.39
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.803
_refine_diff_density_min         -0.829
_refine_diff_density_rms         0.153
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.054
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     369
_refine_ls_number_reflns         6006
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.054
_refine_ls_R_factor_all          0.1034
_refine_ls_R_factor_gt           0.0717
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1111P)²+11.3708P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1981
_refine_ls_wR_factor_ref         0.2197
_reflns_number_gt                4218
_reflns_number_total             6006
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg2015397_si_006.cif
_cod_data_source_block           nafe4-p2_m
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      'P 21/m'
_cod_database_code               4505546
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z'
'-x, -y, -z'
'x, -y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Fe1 Fe 0.27383(6) 0.16566(3) 0.67504(6) 0.0193(2) Uani 1 1 d .
Fe2 Fe 0.60996(6) 0.16484(3) 0.78680(6) 0.0201(2) Uani 1 1 d .
O1 O 0.5525(5) 0.2500 0.7621(5) 0.0327(13) Uani 1 2 d S
O2 O 0.2425(4) 0.14783(19) 0.8373(3) 0.0311(9) Uani 1 1 d .
O3 O 0.4424(3) 0.12500(17) 0.7207(3) 0.0234(8) Uani 1 1 d .
O4 O 0.5815(4) 0.14752(19) 0.9492(3) 0.0311(9) Uani 1 1 d .
O5 O 0.3359(5) 0.2500 0.6802(5) 0.0287(12) Uani 1 2 d S
O6 O 0.7835(4) 0.1951(2) 0.8579(4) 0.0341(9) Uani 1 1 d .
N1 N 0.6619(4) 0.0612(2) 0.8079(4) 0.0269(10) Uani 1 1 d .
O8 O 0.6770(4) 0.14424(19) 0.6409(3) 0.0327(9) Uani 1 1 d .
O9 O 0.2608(4) 0.1455(2) 0.5035(3) 0.0354(9) Uani 1 1 d .
N2 N 0.2137(4) 0.0631(2) 0.6607(4) 0.0231(9) Uani 1 1 d .
O11 O 0.0963(4) 0.19554(18) 0.6369(4) 0.0349(9) Uani 1 1 d .
C1 C 0.4366(5) 0.0576(3) 0.7449(6) 0.0349(14) Uani 1 1 d .
H1 H 0.4221 0.0540 0.8245 0.042 Uiso 1 1 calc .
C5 C 0.0434(7) 0.2500 0.6250(7) 0.0277(16) Uani 1 2 d S
C6 C 0.6145(6) 0.0923(3) 0.9983(5) 0.0388(14) Uani 1 1 d .
C2 C 0.1356(6) 0.0565(3) 0.5447(5) 0.0379(14) Uani 1 1 d .
H2A H 0.0515 0.0686 0.5486 0.046 Uiso 1 1 calc R
H2B H 0.1356 0.0113 0.5195 0.046 Uiso 1 1 calc R
C7 C 0.7709(6) 0.0543(3) 0.7535(6) 0.0367(14) Uani 1 1 d .
H7A H 0.7801 0.0089 0.7321 0.044 Uiso 1 1 calc R
H7B H 0.8441 0.0671 0.8080 0.044 Uiso 1 1 calc R
C3 C 0.1820(7) 0.0992(3) 0.4600(6) 0.0464(17) Uani 1 1 d .
O12 O 0.1481(6) 0.0864(2) 0.9486(4) 0.0563(14) Uani 1 1 d .
C8 C 0.8358(7) 0.2500 0.8761(7) 0.0295(17) Uani 1 2 d S
C9 C 0.1480(6) 0.0488(3) 0.7577(6) 0.0379(14) Uani 1 1 d .
H9A H 0.1688 0.0049 0.7866 0.046 Uiso 1 1 calc R
H9B H 0.0598 0.0504 0.7294 0.046 Uiso 1 1 calc R
O13 O 0.5962(6) 0.0762(3) 1.0939(4) 0.0644(16) Uani 1 1 d .
C10 C -0.0936(8) 0.2500 0.5969(11) 0.056(3) Uani 1 2 d S
H10A H -0.1251 0.2815 0.6446 0.084 Uiso 0.50 1 calc PR
H10B H -0.1239 0.2072 0.6110 0.084 Uiso 0.50 1 calc PR
H10C H -0.1203 0.2613 0.5168 0.084 Uiso 0.50 1 calc PR
O14 O 0.8214(5) 0.0859(2) 0.5736(5) 0.0608(16) Uani 1 1 d .
C11 C 0.1822(6) 0.0977(3) 0.8561(5) 0.0347(13) Uani 1 1 d .
C12 C 0.3285(5) 0.0249(3) 0.6682(6) 0.0352(13) Uani 1 1 d .
H12A H 0.3469 0.0196 0.5911 0.042 Uiso 1 1 calc R
H12B H 0.3166 -0.0183 0.6985 0.042 Uiso 1 1 calc R
C13 C 0.5569(5) 0.0242(3) 0.7425(6) 0.0369(14) Uani 1 1 d .
H13A H 0.5555 -0.0193 0.7754 0.044 Uiso 1 1 calc R
H13B H 0.5676 0.0195 0.6628 0.044 Uiso 1 1 calc R
C14 C 0.9708(8) 0.2500 0.9248(9) 0.047(2) Uani 1 2 d S
H14A H 1.0007 0.2942 0.9309 0.070 Uiso 0.50 1 calc PR
H14B H 1.0135 0.2256 0.8746 0.070 Uiso 0.50 1 calc PR
H14C H 0.9849 0.2302 1.0002 0.070 Uiso 0.50 1 calc PR
C15 C 0.7569(6) 0.0972(3) 0.6465(6) 0.0394(15) Uani 1 1 d .
O15 O 0.1443(7) 0.0917(3) 0.3554(4) 0.079(2) Uani 1 1 d .
C16 C 0.6821(7) 0.0460(3) 0.9322(6) 0.0490(18) Uani 1 1 d .
H16A H 0.7696 0.0482 0.9637 0.059 Uiso 1 1 calc R
H16B H 0.6548 0.0016 0.9425 0.059 Uiso 1 1 calc R
Na1 Na 0.5459(3) 0.2500 1.0456(3) 0.0398(8) Uani 1 2 d S
Na2 Na 0.3071(5) 0.2500 1.1804(4) 0.0734(15) Uani 1 2 d S
Na3 Na 0.6792(7) 0.2500 1.3136(5) 0.0333(15) Uani 0.50 2 d SP
O1W O 0.3330(6) 0.2500 0.9873(5) 0.0350(13) Uani 1 2 d S
O2W O 0.7547(8) 0.2500 1.1376(8) 0.071(2) Uani 1 2 d S
O3W O 0.5037(7) 0.1738(3) 1.2094(5) 0.0706(17) Uani 1 1 d .
O4W O 0.3242(11) 0.2500 1.3804(7) 0.085(3) Uani 1 2 d S
O5W O 0.5897(13) 0.2500 1.4744(11) 0.125(5) Uani 1 2 d S
O6W O 0.1869(12) 0.1532(4) 1.1584(6) 0.135(4) Uani 1 1 d .
O7W O 0.7988(11) 0.1496(4) 1.3615(7) 0.133(4) Uani 1 1 d .
O8W O 0.4950(11) 0.1098(5) 0.4359(9) 0.145(4) Uani 1 1 d .
O9W O 0.9117(9) 0.1401(5) 0.1688(10) 0.134(3) Uani 1 1 d .
O10W O 0.9727(10) 0.0376(6) 0.0486(11) 0.158(4) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Na Na 0.0362 0.0249 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 Fe1 O3 93.18(18) . .
O5 Fe1 O11 93.73(19) . .
O3 Fe1 O11 172.54(15) . .
O5 Fe1 O2 105.2(2) . .
O3 Fe1 O2 89.15(16) . .
O11 Fe1 O2 86.33(18) . .
O5 Fe1 O9 100.3(2) . .
O3 Fe1 O9 94.19(16) . .
O11 Fe1 O9 87.33(18) . .
O2 Fe1 O9 154.04(17) . .
O5 Fe1 N2 174.8(2) . .
O3 Fe1 N2 83.08(15) . .
O11 Fe1 N2 90.19(16) . .
O2 Fe1 N2 78.44(16) . .
O9 Fe1 N2 76.43(16) . .
O1 Fe2 O4 101.7(2) . .
O1 Fe2 O8 103.3(2) . .
O4 Fe2 O8 154.70(17) . .
O1 Fe2 O3 93.10(18) . .
O4 Fe2 O3 90.06(16) . .
O8 Fe2 O3 92.45(15) . .
O1 Fe2 O6 92.77(19) . .
O4 Fe2 O6 87.98(17) . .
O8 Fe2 O6 86.96(17) . .
O3 Fe2 O6 174.08(15) . .
O1 Fe2 N1 174.95(19) . .
O4 Fe2 N1 78.91(16) . .
O8 Fe2 N1 76.55(16) . .
O3 Fe2 N1 81.88(16) . .
O6 Fe2 N1 92.26(17) . .
Fe2 O1 Fe2 139.2(3) 4_565 .
C11 O2 Fe1 119.7(4) . .
C1 O3 Fe1 112.4(3) . .
C1 O3 Fe2 112.6(3) . .
Fe1 O3 Fe2 131.69(18) . .
C6 O4 Fe2 119.7(4) . .
C6 O4 Na1 126.8(4) . .
Fe2 O4 Na1 110.69(18) . .
Fe1 O5 Fe1 137.0(3) 4_565 .
C8 O6 Fe2 134.8(4) . .
C16 N1 C7 115.2(5) . .
C16 N1 C13 111.7(5) . .
C7 N1 C13 110.7(5) . .
C16 N1 Fe2 107.7(4) . .
C7 N1 Fe2 105.1(3) . .
C13 N1 Fe2 105.7(3) . .
C15 O8 Fe2 117.4(4) . .
C3 O9 Fe1 116.7(4) . .
C12 N2 C2 110.9(5) . .
C12 N2 C9 112.6(5) . .
C2 N2 C9 113.8(5) . .
C12 N2 Fe1 104.8(3) . .
C2 N2 Fe1 106.0(3) . .
C9 N2 Fe1 108.2(3) . .
C5 O11 Fe1 134.9(4) . .
O3 C1 C13 111.5(5) . .
O3 C1 C12 111.8(5) . .
C13 C1 C12 113.2(5) . .
O11 C5 O11 125.2(7) . 4_565
O11 C5 C10 117.4(4) . .
O11 C5 C10 117.4(4) 4_565 .
O13 C6 O4 124.4(6) . .
O13 C6 C16 119.1(6) . .
O4 C6 C16 116.5(5) . .
N2 C2 C3 110.4(5) . .
N1 C7 C15 109.8(5) . .
O15 C3 O9 123.5(7) . .
O15 C3 C2 120.0(7) . .
O9 C3 C2 116.4(5) . .
O6 C8 O6 125.5(7) . 4_565
O6 C8 C14 117.3(4) . .
O6 C8 C14 117.3(4) 4_565 .
N2 C9 C11 111.4(5) . .
O12 C11 O2 124.2(6) . .
O12 C11 C9 118.1(5) . .
O2 C11 C9 117.7(5) . .
N2 C12 C1 112.2(5) . .
N1 C13 C1 111.9(5) . .
O14 C15 O8 125.3(6) . .
O14 C15 C7 119.0(6) . .
O8 C15 C7 115.7(5) . .
N1 C16 C6 112.4(5) . .
O1W Na1 O2W 170.1(3) . .
O1W Na1 O4 95.96(16) . 4_565
O2W Na1 O4 89.15(18) . 4_565
O1W Na1 O4 95.96(16) . .
O2W Na1 O4 89.15(18) . .
O4 Na1 O4 117.7(2) 4_565 .
O1W Na1 O3W 84.7(2) . 4_565
O2W Na1 O3W 87.4(3) . 4_565
O4 Na1 O3W 84.02(16) 4_565 4_565
O4 Na1 O3W 157.9(2) . 4_565
O1W Na1 O3W 84.7(2) . .
O2W Na1 O3W 87.4(3) . .
O4 Na1 O3W 157.9(2) 4_565 .
O4 Na1 O3W 84.02(16) . .
O3W Na1 O3W 74.1(3) 4_565 .
O1W Na1 Na3 122.9(2) . .
O2W Na1 Na3 47.2(3) . .
O4 Na1 Na3 111.65(14) 4_565 .
O4 Na1 Na3 111.65(14) . .
O3W Na1 Na3 52.01(18) 4_565 .
O3W Na1 Na3 52.01(19) . .
O1W Na1 Na2 44.80(17) . .
O2W Na1 Na2 125.3(3) . .
O4 Na1 Na2 115.51(13) 4_565 .
O4 Na1 Na2 115.51(13) . .
O3W Na1 Na2 51.39(17) 4_565 .
O3W Na1 Na2 51.39(17) . .
Na3 Na1 Na2 78.12(17) . .
O4W Na2 O1W 168.5(4) . .
O4W Na2 O6W 92.8(3) . .
O1W Na2 O6W 93.5(2) . .
O4W Na2 O6W 92.8(3) . 4_565
O1W Na2 O6W 93.5(2) . 4_565
O6W Na2 O6W 113.1(6) . 4_565
O4W Na2 O3W 87.6(3) . 4_565
O1W Na2 O3W 83.1(2) . 4_565
O6W Na2 O3W 159.5(4) . 4_565
O6W Na2 O3W 87.4(3) 4_565 4_565
O4W Na2 O3W 87.6(3) . .
O1W Na2 O3W 83.1(2) . .
O6W Na2 O3W 87.4(3) . .
O6W Na2 O3W 159.5(4) 4_565 .
O3W Na2 O3W 72.1(3) 4_565 .
O4W Na2 Na1 124.0(4) . .
O1W Na2 Na1 44.51(18) . .
O6W Na2 Na1 115.3(3) . .
O6W Na2 Na1 115.3(3) 4_565 .
O3W Na2 Na1 49.79(16) 4_565 .
O3W Na2 Na1 49.79(16) . .
O4W Na2 Na3 74.1(3) . .
O1W Na2 Na3 94.4(2) . .
O6W Na2 Na3 122.8(3) . .
O6W Na2 Na3 122.8(3) 4_565 .
O3W Na2 Na3 38.00(16) 4_565 .
O3W Na2 Na3 38.00(16) . .
Na1 Na2 Na3 49.88(12) . .
O5W Na3 O2W 175.1(5) . .
O5W Na3 O7W 96.2(3) . 4_565
O2W Na3 O7W 86.5(3) . 4_565
O5W Na3 O7W 96.2(3) . .
O2W Na3 O7W 86.5(3) . .
O7W Na3 O7W 113.8(6) 4_565 .
O5W Na3 O3W 89.4(4) . .
O2W Na3 O3W 86.7(3) . .
O7W Na3 O3W 158.5(3) 4_565 .
O7W Na3 O3W 86.0(3) . .
O5W Na3 O3W 89.4(4) . 4_565
O2W Na3 O3W 86.7(3) . 4_565
O7W Na3 O3W 86.0(3) 4_565 4_565
O7W Na3 O3W 158.5(3) . 4_565
O3W Na3 O3W 73.2(3) . 4_565
O5W Na3 Na1 128.1(5) . .
O2W Na3 Na1 47.0(2) . .
O7W Na3 Na1 110.8(2) 4_565 .
O7W Na3 Na1 110.8(2) . .
O3W Na3 Na1 51.31(17) . .
O3W Na3 Na1 51.31(17) 4_565 .
O5W Na3 Na2 76.2(4) . .
O2W Na3 Na2 99.0(3) . .
O7W Na3 Na2 123.1(3) 4_565 .
O7W Na3 Na2 123.1(3) . .
O3W Na3 Na2 38.60(17) . .
O3W Na3 Na2 38.60(17) 4_565 .
Na1 Na3 Na2 51.99(13) . .
Na1 O1W Na2 90.7(3) . .
Na1 O2W Na3 85.8(4) . .
Na1 O3W Na3 76.7(2) . .
Na1 O3W Na2 78.82(19) . .
Na3 O3W Na2 103.4(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Fe1 O5 1.851(2) .
Fe1 O3 2.019(3) .
Fe1 O11 2.024(4) .
Fe1 O2 2.031(4) .
Fe1 O9 2.035(4) .
Fe1 N2 2.194(4) .
Fe2 O1 1.8553(19) .
Fe2 O4 2.021(4) .
Fe2 O8 2.032(4) .
Fe2 O3 2.040(3) .
Fe2 O6 2.042(4) .
Fe2 N1 2.195(4) .
O1 Fe2 1.8552(19) 4_565
O2 C11 1.262(7) .
O3 C1 1.409(7) .
O4 C6 1.288(7) .
O4 Na1 2.445(4) .
O5 Fe1 1.851(2) 4_565
O6 C8 1.260(5) .
N1 C16 1.468(8) .
N1 C7 1.470(7) .
N1 C13 1.476(8) .
O8 C15 1.298(7) .
O9 C3 1.322(8) .
N2 C12 1.478(7) .
N2 C2 1.478(7) .
N2 C9 1.489(7) .
O11 C5 1.252(5) .
C1 C13 1.498(8) .
C1 C12 1.512(8) .
C5 O11 1.252(5) 4_565
C5 C10 1.489(11) .
C6 O13 1.222(7) .
C6 C16 1.506(9) .
C2 C3 1.483(9) .
C7 C15 1.516(9) .
C3 O15 1.232(8) .
O12 C11 1.236(7) .
C8 O6 1.260(5) 4_565
C8 C14 1.496(11) .
C9 C11 1.521(8) .
O14 C15 1.232(7) .
Na1 O1W 2.326(7) .
Na1 O2W 2.361(9) .
Na1 O4 2.445(4) 4_565
Na1 O3W 2.582(6) 4_565
Na1 O3W 2.582(6) .
Na1 Na3 3.219(7) .
Na1 Na2 3.317(6) .
Na2 O4W 2.321(9) .
Na2 O1W 2.337(7) .
Na2 O6W 2.369(9) .
Na2 O6W 2.369(9) 4_565
Na2 O3W 2.642(8) 4_565
Na2 O3W 2.642(8) .
Na2 Na3 4.120(8) .
Na3 O5W 2.287(14) .
Na3 O2W 2.367(11) .
Na3 O7W 2.448(10) 4_565
Na3 O7W 2.448(10) .
Na3 O3W 2.607(9) .
Na3 O3W 2.607(9) 4_565
