#------------------------------------------------------------------------------
#$Date: 2016-03-24 02:47:15 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179596 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/60/4506093.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4506093
loop_
_publ_author_name
'Zhu, Yan'
'Luo, Feng'
'Song, Yu-mei'
'Feng, Xue-feng'
'Luo, Ming-biao'
'Liao, Zhen-wei'
'Sun, Gong-ming'
'Tian, Xiao-zhao'
'Yuan, Zi-Jun'
_publ_section_title
;
 The First One-Pot Synthesis of Multinuclear 3d-4f Metal--Organic
 Compounds Involving a Polytopic N,O-Donor Ligand Formed in Situ
;
_journal_issue                   5
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              2158
_journal_paper_doi               10.1021/cg3002509
_journal_volume                  12
_journal_year                    2012
_chemical_formula_sum            'C120 H86 Cd4 Eu2 N12 O14'
_chemical_formula_weight         2673.53
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           176
_symmetry_cell_setting           hexagonal
_symmetry_space_group_name_Hall  '-P 6c'
_symmetry_space_group_name_H-M   'P 63/m'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            1
_cell_length_a                   13.6227(3)
_cell_length_b                   13.6227(3)
_cell_length_c                   18.3213(9)
_cell_measurement_reflns_used    9773
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.52
_cell_measurement_theta_min      2.82
_cell_volume                     2944.51(17)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0251
_diffrn_reflns_av_sigmaI/netI    0.0138
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            14242
_diffrn_reflns_theta_full        24.99
_diffrn_reflns_theta_max         24.99
_diffrn_reflns_theta_min         1.73
_exptl_absorpt_coefficient_mu    1.822
_exptl_absorpt_correction_T_max  0.8388
_exptl_absorpt_correction_T_min  0.7120
_exptl_absorpt_correction_type   none
_exptl_crystal_density_diffrn    1.508
_exptl_crystal_density_meas      0
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1320
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.562
_refine_diff_density_min         -0.725
_refine_diff_density_rms         0.067
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.049
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     130
_refine_ls_number_reflns         1773
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.048
_refine_ls_R_factor_all          0.0378
_refine_ls_R_factor_gt           0.0339
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0431P)²+3.8337P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0883
_refine_ls_wR_factor_ref         0.0919
_reflns_number_gt                1554
_reflns_number_total             1773
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg3002509_si_002.cif
_cod_data_source_block           5
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Hexagonal' changed to 'hexagonal'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      P6(3)/m
_cod_database_code               4506093
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'-x, -y, z+1/2'
'y, -x+y, z+1/2'
'x-y, x, z+1/2'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'x, y, -z-1/2'
'-y, x-y, -z-1/2'
'-x+y, -x, -z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.6849(6) 1.0063(5) -0.0217(3) 0.0964(18) Uani 1 1 d .
H1 H 0.7515 1.0675 -0.0392 0.116 Uiso 1 1 calc R
C2 C 0.5913(6) 0.9630(5) -0.0628(3) 0.0994(19) Uani 1 1 d .
H2 H 0.5922 0.9946 -0.1079 0.119 Uiso 1 1 calc R
C3 C 0.4924(5) 0.8697(5) -0.0371(3) 0.0861(15) Uani 1 1 d .
H3 H 0.4280 0.8389 -0.0663 0.103 Uiso 1 1 calc R
C4 C 0.5798(4) 0.8679(3) 0.0710(2) 0.0566(9) Uani 1 1 d .
C5 C 0.6846(5) 0.9617(4) 0.0470(2) 0.0747(13) Uani 1 1 d .
C6 C 0.7794(5) 1.0001(5) 0.0912(3) 0.1046(19) Uani 1 1 d .
H6 H 0.8477 1.0623 0.0768 0.126 Uiso 1 1 calc R
C7 C 0.7731(4) 0.9476(5) 0.1553(3) 0.0920(18) Uani 1 1 d .
H7 H 0.8383 0.9741 0.1834 0.110 Uiso 1 1 calc R
C8 C 0.6713(3) 0.8540(4) 0.1811(2) 0.0622(10) Uani 1 1 d .
C9 C 0.5727(3) 0.8156(3) 0.1404(2) 0.0487(8) Uani 1 1 d .
C10 C 0.6701(5) 0.7923(6) 0.2500 0.0614(14) Uani 1 2 d S
C11 C 0.7648(6) 0.7626(8) 0.2500 0.095(2) Uani 1 2 d S
H11A H 0.7656 0.7294 0.2961 0.142 Uiso 0.50 1 calc PR
H11B H 0.8365 0.8302 0.2424 0.142 Uiso 0.50 1 calc PR
H11C H 0.7516 0.7096 0.2115 0.142 Uiso 0.50 1 calc PR
Cd1 Cd 0.3333 0.6667 0.07072(2) 0.05723(19) Uani 1 3 d S
Eu1 Eu 0.3333 0.6667 0.2500 0.05028(18) Uani 1 6 d S
H1A H 0.604(4) 0.722(4) 0.2500 0.044(13) Uiso 1 2 d S
H1W H 0.460(8) 0.493(7) 0.2500 0.01(2) Uiso 0.33 2 d SPD
N1 N 0.4867(3) 0.8232(3) 0.02754(17) 0.0643(9) Uani 1 1 d .
O1 O 0.4751(2) 0.7295(2) 0.16113(11) 0.0489(6) Uani 1 1 d .
O2 O 0.4293(7) 0.5339(7) 0.2500 0.0353(19) Uani 0.33 2 d SPD
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C2 C1 C5 121.4(5) . .
C2 C1 H1 119.3 . .
C5 C1 H1 119.3 . .
C1 C2 C3 119.1(5) . .
C1 C2 H2 120.5 . .
C3 C2 H2 120.5 . .
N1 C3 C2 122.5(6) . .
N1 C3 H3 118.8 . .
C2 C3 H3 118.8 . .
N1 C4 C5 120.8(4) . .
N1 C4 C9 118.8(3) . .
C5 C4 C9 120.3(4) . .
C6 C5 C1 124.3(5) . .
C6 C5 C4 118.9(4) . .
C1 C5 C4 116.8(5) . .
C7 C6 C5 120.4(4) . .
C7 C6 H6 119.8 . .
C5 C6 H6 119.8 . .
C6 C7 C8 122.7(5) . .
C6 C7 H7 118.7 . .
C8 C7 H7 118.7 . .
C9 C8 C7 119.1(4) . .
C9 C8 C10 119.9(4) . .
C7 C8 C10 120.9(4) . .
O1 C9 C8 122.5(3) . .
O1 C9 C4 119.0(3) . .
C8 C9 C4 118.4(3) . .
C8 C10 C8 113.2(5) 10_556 .
C8 C10 C11 111.7(3) 10_556 .
C8 C10 C11 111.7(3) . .
C8 C10 H1A 107.9(15) 10_556 .
C8 C10 H1A 107.9(15) . .
C11 C10 H1A 104(3) . .
C10 C11 H11A 109.5 . .
C10 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
C10 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
N1 Cd1 N1 108.38(9) 2_665 .
N1 Cd1 N1 108.38(9) 2_665 3_565
N1 Cd1 N1 108.38(9) . 3_565
N1 Cd1 O1 72.53(11) 2_665 2_665
N1 Cd1 O1 101.02(11) . 2_665
N1 Cd1 O1 148.12(11) 3_565 2_665
N1 Cd1 O1 148.12(11) 2_665 .
N1 Cd1 O1 72.53(11) . .
N1 Cd1 O1 101.02(11) 3_565 .
O1 Cd1 O1 76.04(8) 2_665 .
N1 Cd1 O1 101.02(11) 2_665 3_565
N1 Cd1 O1 148.12(11) . 3_565
N1 Cd1 O1 72.53(11) 3_565 3_565
O1 Cd1 O1 76.04(8) 2_665 3_565
O1 Cd1 O1 76.04(8) . 3_565
N1 Cd1 Eu1 110.54(9) 2_665 .
N1 Cd1 Eu1 110.54(9) . .
N1 Cd1 Eu1 110.54(9) 3_565 .
O1 Cd1 Eu1 45.33(5) 2_665 .
O1 Cd1 Eu1 45.33(5) . .
O1 Cd1 Eu1 45.33(5) 3_565 .
O1 Eu1 O1 88.35(11) 11_666 2_665
O1 Eu1 O1 76.80(9) 11_666 10_556
O1 Eu1 O1 137.97(4) 2_665 10_556
O1 Eu1 O1 137.97(4) 11_666 3_565
O1 Eu1 O1 76.80(9) 2_665 3_565
O1 Eu1 O1 137.97(4) 10_556 3_565
O1 Eu1 O1 76.80(9) 11_666 12_566
O1 Eu1 O1 137.97(4) 2_665 12_566
O1 Eu1 O1 76.80(9) 10_556 12_566
O1 Eu1 O1 88.35(11) 3_565 12_566
O1 Eu1 O1 137.97(4) 11_666 .
O1 Eu1 O1 76.80(9) 2_665 .
O1 Eu1 O1 88.35(11) 10_556 .
O1 Eu1 O1 76.80(9) 3_565 .
O1 Eu1 O1 137.97(4) 12_566 .
O1 Eu1 O2 67.96(14) 11_666 3_565
O1 Eu1 O2 67.96(14) 2_665 3_565
O1 Eu1 O2 135.80(6) 10_556 3_565
O1 Eu1 O2 70.02(14) 3_565 3_565
O1 Eu1 O2 70.02(14) 12_566 3_565
O1 Eu1 O2 135.80(6) . 3_565
O1 Eu1 O2 70.02(14) 11_666 2_665
O1 Eu1 O2 70.02(14) 2_665 2_665
O1 Eu1 O2 67.96(14) 10_556 2_665
O1 Eu1 O2 135.80(6) 3_565 2_665
O1 Eu1 O2 135.80(6) 12_566 2_665
O1 Eu1 O2 67.96(14) . 2_665
O2 Eu1 O2 120.0 3_565 2_665
O1 Eu1 O2 135.80(6) 11_666 .
O1 Eu1 O2 135.80(6) 2_665 .
O1 Eu1 O2 70.02(14) 10_556 .
O1 Eu1 O2 67.96(14) 3_565 .
O1 Eu1 O2 67.96(14) 12_566 .
O1 Eu1 O2 70.02(14) . .
O2 Eu1 O2 120.000(2) 3_565 .
O2 Eu1 O2 120.000(2) 2_665 .
O1 Eu1 Cd1 45.82(6) 11_666 10_556
O1 Eu1 Cd1 134.18(6) 2_665 10_556
O1 Eu1 Cd1 45.82(6) 10_556 10_556
O1 Eu1 Cd1 134.18(6) 3_565 10_556
O1 Eu1 Cd1 45.82(6) 12_566 10_556
O1 Eu1 Cd1 134.18(6) . 10_556
O2 Eu1 Cd1 90.0 3_565 10_556
O2 Eu1 Cd1 90.0 2_665 10_556
O2 Eu1 Cd1 90.0 . 10_556
O1 Eu1 Cd1 134.18(6) 11_666 .
O1 Eu1 Cd1 45.82(6) 2_665 .
O1 Eu1 Cd1 134.18(6) 10_556 .
O1 Eu1 Cd1 45.82(6) 3_565 .
O1 Eu1 Cd1 134.18(6) 12_566 .
O1 Eu1 Cd1 45.82(6) . .
O2 Eu1 Cd1 90.0 3_565 .
O2 Eu1 Cd1 90.0 2_665 .
O2 Eu1 Cd1 90.0 . .
Cd1 Eu1 Cd1 180.0 10_556 .
C3 N1 C4 119.4(4) . .
C3 N1 Cd1 124.8(4) . .
C4 N1 Cd1 115.7(2) . .
C9 O1 Eu1 144.1(2) . .
C9 O1 Cd1 113.6(2) . .
Eu1 O1 Cd1 88.84(8) . .
Eu1 O2 H1W 179(7) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C2 1.337(8) .
C1 C5 1.396(7) .
C1 H1 0.9300 .
C2 C3 1.392(8) .
C2 H2 0.9300 .
C3 N1 1.327(5) .
C3 H3 0.9300 .
C4 N1 1.357(5) .
C4 C5 1.429(6) .
C4 C9 1.436(5) .
C5 C6 1.386(8) .
C6 C7 1.354(7) .
C6 H6 0.9300 .
C7 C8 1.415(6) .
C7 H7 0.9300 .
C8 C9 1.389(6) .
C8 C10 1.513(6) .
C9 O1 1.316(4) .
C10 C8 1.513(6) 10_556
C10 C11 1.533(9) .
C10 H1A 0.93(5) .
C11 H11A 0.9600 .
C11 H11B 0.9600 .
C11 H11C 0.9600 .
Cd1 N1 2.255(3) 2_665
Cd1 N1 2.255(4) .
Cd1 N1 2.255(3) 3_565
Cd1 O1 2.356(2) 2_665
Cd1 O1 2.356(2) .
Cd1 O1 2.356(2) 3_565
Cd1 Eu1 3.2846(5) .
Eu1 O1 2.337(2) 11_666
Eu1 O1 2.337(2) 2_665
Eu1 O1 2.337(2) 10_556
Eu1 O1 2.337(2) 3_565
Eu1 O1 2.337(2) 12_566
Eu1 O1 2.337(2) .
Eu1 O2 2.711(8) 3_565
Eu1 O2 2.711(8) 2_665
Eu1 O2 2.711(8) .
Eu1 Cd1 3.2846(5) 10_556
O2 H1W 0.850(10) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C5 C1 C2 C3 -1.5(9) . .
C1 C2 C3 N1 1.3(8) . .
C2 C1 C5 C6 177.7(6) . .
C2 C1 C5 C4 -0.1(8) . .
N1 C4 C5 C6 -175.9(5) . .
C9 C4 C5 C6 0.9(6) . .
N1 C4 C5 C1 2.0(6) . .
C9 C4 C5 C1 178.8(4) . .
C1 C5 C6 C7 -176.1(6) . .
C4 C5 C6 C7 1.6(9) . .
C5 C6 C7 C8 -1.3(10) . .
C6 C7 C8 C9 -1.7(9) . .
C6 C7 C8 C10 175.2(6) . .
C7 C8 C9 O1 -179.7(4) . .
C10 C8 C9 O1 3.4(6) . .
C7 C8 C9 C4 4.0(6) . .
C10 C8 C9 C4 -172.9(4) . .
N1 C4 C9 O1 -3.2(5) . .
C5 C4 C9 O1 179.9(3) . .
N1 C4 C9 C8 173.2(4) . .
C5 C4 C9 C8 -3.7(5) . .
C9 C8 C10 C8 -104.7(5) . 10_556
C7 C8 C10 C8 78.5(6) . 10_556
C9 C8 C10 C11 128.2(5) . .
C7 C8 C10 C11 -48.6(7) . .
N1 Cd1 Eu1 O1 -34.78(13) 2_665 11_666
N1 Cd1 Eu1 O1 85.22(13) . 11_666
N1 Cd1 Eu1 O1 -154.78(13) 3_565 11_666
O1 Cd1 Eu1 O1 0.0 2_665 11_666
O1 Cd1 Eu1 O1 120.000(1) . 11_666
O1 Cd1 Eu1 O1 -120.000(1) 3_565 11_666
N1 Cd1 Eu1 O1 -34.78(13) 2_665 2_665
N1 Cd1 Eu1 O1 85.22(13) . 2_665
N1 Cd1 Eu1 O1 -154.78(13) 3_565 2_665
O1 Cd1 Eu1 O1 120.0 . 2_665
O1 Cd1 Eu1 O1 -120.0 3_565 2_665
N1 Cd1 Eu1 O1 -154.78(13) 2_665 10_556
N1 Cd1 Eu1 O1 -34.78(13) . 10_556
N1 Cd1 Eu1 O1 85.22(13) 3_565 10_556
O1 Cd1 Eu1 O1 -120.0 2_665 10_556
O1 Cd1 Eu1 O1 0.0 . 10_556
O1 Cd1 Eu1 O1 120.0 3_565 10_556
N1 Cd1 Eu1 O1 85.22(13) 2_665 3_565
N1 Cd1 Eu1 O1 -154.78(13) . 3_565
N1 Cd1 Eu1 O1 -34.78(13) 3_565 3_565
O1 Cd1 Eu1 O1 120.0 2_665 3_565
O1 Cd1 Eu1 O1 -120.0 . 3_565
N1 Cd1 Eu1 O1 85.22(13) 2_665 12_566
N1 Cd1 Eu1 O1 -154.78(13) . 12_566
N1 Cd1 Eu1 O1 -34.78(13) 3_565 12_566
O1 Cd1 Eu1 O1 120.0 2_665 12_566
O1 Cd1 Eu1 O1 -120.0 . 12_566
O1 Cd1 Eu1 O1 0.0 3_565 12_566
N1 Cd1 Eu1 O1 -154.78(13) 2_665 .
N1 Cd1 Eu1 O1 -34.78(13) . .
N1 Cd1 Eu1 O1 85.22(13) 3_565 .
O1 Cd1 Eu1 O1 -120.0 2_665 .
O1 Cd1 Eu1 O1 120.0 3_565 .
N1 Cd1 Eu1 O2 23.7(2) 2_665 3_565
N1 Cd1 Eu1 O2 143.7(2) . 3_565
N1 Cd1 Eu1 O2 -96.3(2) 3_565 3_565
O1 Cd1 Eu1 O2 58.5(2) 2_665 3_565
O1 Cd1 Eu1 O2 178.5(2) . 3_565
O1 Cd1 Eu1 O2 -61.5(2) 3_565 3_565
N1 Cd1 Eu1 O2 -96.3(2) 2_665 2_665
N1 Cd1 Eu1 O2 23.7(2) . 2_665
N1 Cd1 Eu1 O2 143.7(2) 3_565 2_665
O1 Cd1 Eu1 O2 -61.5(2) 2_665 2_665
O1 Cd1 Eu1 O2 58.5(2) . 2_665
O1 Cd1 Eu1 O2 178.5(2) 3_565 2_665
N1 Cd1 Eu1 O2 143.7(2) 2_665 .
N1 Cd1 Eu1 O2 -96.3(2) . .
N1 Cd1 Eu1 O2 23.7(2) 3_565 .
O1 Cd1 Eu1 O2 178.5(2) 2_665 .
O1 Cd1 Eu1 O2 -61.5(2) . .
O1 Cd1 Eu1 O2 58.5(2) 3_565 .
N1 Cd1 Eu1 Cd1 89(100) 2_665 10_556
N1 Cd1 Eu1 Cd1 -151(100) . 10_556
N1 Cd1 Eu1 Cd1 -31(100) 3_565 10_556
O1 Cd1 Eu1 Cd1 124(100) 2_665 10_556
O1 Cd1 Eu1 Cd1 -116(100) . 10_556
O1 Cd1 Eu1 Cd1 4(100) 3_565 10_556
C2 C3 N1 C4 0.6(7) . .
C2 C3 N1 Cd1 -176.4(4) . .
C5 C4 N1 C3 -2.2(6) . .
C9 C4 N1 C3 -179.1(4) . .
C5 C4 N1 Cd1 175.0(3) . .
C9 C4 N1 Cd1 -1.8(4) . .
N1 Cd1 N1 C3 -32.9(4) 2_665 .
N1 Cd1 N1 C3 84.5(3) 3_565 .
O1 Cd1 N1 C3 -107.9(3) 2_665 .
O1 Cd1 N1 C3 -179.3(4) . .
O1 Cd1 N1 C3 170.8(3) 3_565 .
Eu1 Cd1 N1 C3 -154.2(3) . .
N1 Cd1 N1 C4 150.0(3) 2_665 .
N1 Cd1 N1 C4 -92.6(3) 3_565 .
O1 Cd1 N1 C4 74.9(3) 2_665 .
O1 Cd1 N1 C4 3.5(2) . .
O1 Cd1 N1 C4 -6.3(4) 3_565 .
Eu1 Cd1 N1 C4 28.7(3) . .
C8 C9 O1 Eu1 65.5(5) . .
C4 C9 O1 Eu1 -118.3(4) . .
C8 C9 O1 Cd1 -170.0(3) . .
C4 C9 O1 Cd1 6.2(4) . .
O1 Eu1 O1 C9 19.0(4) 11_666 .
O1 Eu1 O1 C9 91.3(4) 2_665 .
O1 Eu1 O1 C9 -49.1(4) 10_556 .
O1 Eu1 O1 C9 170.6(4) 3_565 .
O1 Eu1 O1 C9 -117.1(4) 12_566 .
O2 Eu1 O1 C9 128.7(4) 3_565 .
O2 Eu1 O1 C9 17.8(4) 2_665 .
O2 Eu1 O1 C9 -118.4(4) . .
Cd1 Eu1 O1 C9 -49.1(4) 10_556 .
Cd1 Eu1 O1 C9 130.9(4) . .
O1 Eu1 O1 Cd1 -111.92(2) 11_666 .
O1 Eu1 O1 Cd1 -39.64(3) 2_665 .
O1 Eu1 O1 Cd1 180.0 10_556 .
O1 Eu1 O1 Cd1 39.64(3) 3_565 .
O1 Eu1 O1 Cd1 111.92(2) 12_566 .
O2 Eu1 O1 Cd1 -2.2(3) 3_565 .
O2 Eu1 O1 Cd1 -113.16(17) 2_665 .
O2 Eu1 O1 Cd1 110.69(16) . .
Cd1 Eu1 O1 Cd1 180.0 10_556 .
N1 Cd1 O1 C9 -102.0(3) 2_665 .
N1 Cd1 O1 C9 -5.2(2) . .
N1 Cd1 O1 C9 100.8(2) 3_565 .
O1 Cd1 O1 C9 -111.7(3) 2_665 .
O1 Cd1 O1 C9 169.5(3) 3_565 .
Eu1 Cd1 O1 C9 -151.1(3) . .
N1 Cd1 O1 Eu1 49.1(2) 2_665 .
N1 Cd1 O1 Eu1 145.94(12) . .
N1 Cd1 O1 Eu1 -108.07(11) 3_565 .
O1 Cd1 O1 Eu1 39.40(3) 2_665 .
O1 Cd1 O1 Eu1 -39.40(3) 3_565 .
