#------------------------------------------------------------------------------
#$Date: 2016-03-24 02:54:37 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179603 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/67/4506786.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4506786
loop_
_publ_author_name
'Zhu, Xian-Dong'
'Lin, Zu-Jin'
'Liu, Tian-Fu'
'Xu, Bo'
'Cao, Rong'
_publ_section_title
;
 Two Novel 3d-4f Heterometallic Frameworks Assembled from a Flexible
 Bifunctional Macrocyclic Ligand
;
_journal_issue                   10
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              4708
_journal_paper_doi               10.1021/cg300848f
_journal_volume                  12
_journal_year                    2012
_chemical_formula_sum            'C54 H116 Eu2 N12 O40 Zn3'
_chemical_formula_weight         2073.62
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                95.672(14)
_cell_angle_beta                 102.223(10)
_cell_angle_gamma                101.053(10)
_cell_formula_units_Z            1
_cell_length_a                   8.619(2)
_cell_length_b                   17.818(6)
_cell_length_c                   18.385(6)
_cell_measurement_reflns_used    6686
_cell_measurement_temperature    293.15
_cell_measurement_theta_max      27.4797
_cell_measurement_theta_min      2.2911
_cell_volume                     2679.5(14)
_computing_cell_refinement       'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_data_collection       'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_data_reduction        'CrystalClear (Rigaku/MSC Inc., 2005)'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293.15
_diffrn_measured_fraction_theta_full 0.985
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measurement_device_type  'mercury CCD'
_diffrn_measurement_method       dtprofit.ref
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0435
_diffrn_reflns_av_sigmaI/netI    0.0836
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            21194
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         2.29
_exptl_absorpt_coefficient_mu    1.889
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.8635
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.285
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             1060
_exptl_crystal_size_max          0.2200
_exptl_crystal_size_mid          0.0600
_exptl_crystal_size_min          0.0300
_refine_diff_density_max         1.597
_refine_diff_density_min         -1.123
_refine_diff_density_rms         0.208
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.038
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     550
_refine_ls_number_reflns         12129
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.038
_refine_ls_R_factor_all          0.0840
_refine_ls_R_factor_gt           0.0670
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1104P)²+11.3132P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1892
_refine_ls_wR_factor_ref         0.2098
_reflns_number_gt                9884
_reflns_number_total             12129
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg300848f_si_002.cif
_cod_data_source_block           ZXD-Eu,Zn
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_cell_volume        2679.6(14)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4506786
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu -0.05715(4) 0.226428(18) 0.856834(19) 0.02363(12) Uani 1 1 d .
Zn1 Zn 0.5000 0.5000 1.0000 0.0269(3) Uani 1 2 d S
Zn2 Zn 0.0000 0.0000 0.5000 0.0357(3) Uani 1 2 d S
Zn3 Zn 0.5000 0.0000 1.0000 0.0254(2) Uani 1 2 d S
OW1 O -0.3402(7) 0.1746(4) 0.7767(4) 0.0503(16) Uani 1 1 d .
OW10 O 1.184(4) 0.1795(14) 1.2171(17) 0.151(11) Uani 0.50 1 d P
OW11 O 0.078(2) 0.2907(9) 1.1332(7) 0.093(7) Uani 0.50 1 d P
OW12 O 0.980(3) 0.5889(16) 0.7591(13) 0.120(8) Uani 0.50 1 d P
OW2 O 0.0856(7) 0.2853(3) 0.9866(3) 0.0445(14) Uani 1 1 d .
OW3 O 0.3278(17) 0.3104(8) 0.7116(8) 0.136(5) Uani 1 1 d .
OW4 O 0.611(3) 0.2418(16) 0.6371(12) 0.155(13) Uani 0.50 1 d P
OW5 O 0.6684(18) 0.1626(10) 0.4639(11) 0.080(5) Uani 0.50 1 d P
OW6 O 0.855(2) 0.4246(9) 0.7311(8) 0.066(4) Uani 0.50 1 d P
OW7 O 1.038(3) 0.3538(13) 0.6492(12) 0.108(7) Uani 0.50 1 d P
OW8 O 0.096(3) -0.1965(12) 0.6951(10) 0.114(8) Uani 0.50 1 d P
OW9 O 0.542(4) 0.1240(18) 0.3113(14) 0.162(12) Uani 0.50 1 d P
O1 O 0.1266(7) 0.3467(3) 0.8490(3) 0.0380(12) Uani 1 1 d .
O2 O 0.3056(6) 0.4026(3) 0.9550(3) 0.0310(11) Uani 1 1 d .
O3 O 0.7389(7) 0.2621(3) 0.9270(3) 0.0350(12) Uani 1 1 d .
O4 O 0.7974(8) 0.3346(3) 0.8441(4) 0.0510(16) Uani 1 1 d .
O5 O -0.0400(7) 0.2221(3) 0.7252(3) 0.0385(12) Uani 1 1 d .
O6 O -0.0717(7) 0.1067(3) 0.7605(3) 0.0396(13) Uani 1 1 d .
O7 O 0.0908(13) 0.2228(5) 0.4586(6) 0.100(3) Uani 1 1 d .
O8 O -0.0406(8) 0.1059(4) 0.4666(3) 0.0488(15) Uani 1 1 d .
O9 O 0.1957(6) 0.1922(3) 0.8774(3) 0.0351(12) Uani 1 1 d .
O10 O 0.3798(7) 0.2072(3) 0.8082(3) 0.0371(12) Uani 1 1 d .
O11 O 0.8725(7) 0.1195(3) 0.9183(3) 0.0368(12) Uani 1 1 d .
O12 O 0.6654(6) 0.0281(3) 0.9297(3) 0.0316(11) Uani 1 1 d .
N1 N 0.4038(8) 0.5350(3) 0.8962(4) 0.0321(13) Uani 1 1 d .
N2 N 0.6727(7) 0.4421(3) 0.9546(4) 0.0327(14) Uani 1 1 d .
N3 N -0.0198(9) 0.0394(4) 0.6176(4) 0.0417(16) Uani 1 1 d .
N4 N 0.2431(9) 0.0584(4) 0.5189(4) 0.0434(17) Uani 1 1 d .
N5 N 0.3482(7) 0.0794(3) 0.9527(3) 0.0291(12) Uani 1 1 d .
N6 N 0.6777(7) 0.0892(3) 1.0746(3) 0.0271(12) Uani 1 1 d .
C1 C 0.2352(8) 0.4001(4) 0.8867(4) 0.0276(14) Uani 1 1 d .
C2 C 0.2888(9) 0.4678(4) 0.8468(4) 0.0328(15) Uani 1 1 d .
H2A H 0.3405 0.4496 0.8072 0.039 Uiso 1 1 calc R
H2B H 0.1911 0.4851 0.8217 0.039 Uiso 1 1 calc R
C3 C 0.5331(11) 0.5706(5) 0.8611(5) 0.0420(19) Uani 1 1 d .
H3A H 0.5985 0.6182 0.8945 0.050 Uiso 1 1 calc R
H3B H 0.4817 0.5861 0.8131 0.050 Uiso 1 1 calc R
C4 C 0.6483(11) 0.5179(5) 0.8451(5) 0.046(2) Uani 1 1 d .
H4A H 0.5810 0.4693 0.8144 0.056 Uiso 1 1 calc R
H4B H 0.7174 0.5435 0.8140 0.056 Uiso 1 1 calc R
C5 C 0.7583(10) 0.4973(5) 0.9116(5) 0.042(2) Uani 1 1 d .
H5A H 0.8156 0.5454 0.9462 0.050 Uiso 1 1 calc R
H5B H 0.8415 0.4741 0.8937 0.050 Uiso 1 1 calc R
C6 C 0.7833(9) 0.4328(4) 1.0255(5) 0.0389(18) Uani 1 1 d .
H6A H 0.8600 0.4827 1.0473 0.047 Uiso 1 1 calc R
H6B H 0.8475 0.3944 1.0145 0.047 Uiso 1 1 calc R
C7 C 0.3154(11) 0.5941(5) 0.9180(5) 0.0424(19) Uani 1 1 d .
H7A H 0.2413 0.6039 0.8726 0.051 Uiso 1 1 calc R
H7B H 0.3944 0.6432 0.9406 0.051 Uiso 1 1 calc R
C8 C 0.5972(9) 0.3644(4) 0.9082(5) 0.0320(16) Uani 1 1 d .
H8A H 0.5295 0.3718 0.8599 0.038 Uiso 1 1 calc R
H8B H 0.5243 0.3341 0.9350 0.038 Uiso 1 1 calc R
C9 C 0.7188(9) 0.3180(4) 0.8917(5) 0.0329(16) Uani 1 1 d .
C10 C -0.0488(9) 0.1505(5) 0.7128(4) 0.0345(17) Uani 1 1 d .
C11 C -0.0326(11) 0.1200(5) 0.6331(5) 0.0429(19) Uani 1 1 d .
H11A H -0.1281 0.1274 0.5960 0.052 Uiso 1 1 calc R
H11B H 0.0649 0.1533 0.6234 0.052 Uiso 1 1 calc R
C12 C 0.1229(11) 0.0229(5) 0.6703(5) 0.046(2) Uani 1 1 d .
H12A H 0.1216 -0.0329 0.6608 0.055 Uiso 1 1 calc R
H12B H 0.1128 0.0349 0.7226 0.055 Uiso 1 1 calc R
C13 C 0.2882(11) 0.0701(6) 0.6623(5) 0.052(2) Uani 1 1 d .
H13A H 0.2815 0.1250 0.6642 0.063 Uiso 1 1 calc R
H13B H 0.3733 0.0663 0.7065 0.063 Uiso 1 1 calc R
C14 C 0.3437(11) 0.0464(6) 0.5914(5) 0.049(2) Uani 1 1 d .
H14A H 0.4564 0.0757 0.5969 0.059 Uiso 1 1 calc R
H14B H 0.3467 -0.0090 0.5885 0.059 Uiso 1 1 calc R
C15 C 0.3001(10) 0.0231(6) 0.4552(5) 0.048(2) Uani 1 1 d .
H15A H 0.3191 -0.0285 0.4647 0.057 Uiso 1 1 calc R
H15B H 0.4046 0.0557 0.4522 0.057 Uiso 1 1 calc R
C16 C 0.2509(12) 0.1420(5) 0.5152(5) 0.052(2) Uani 1 1 d .
H16A H 0.3338 0.1614 0.4876 0.063 Uiso 1 1 calc R
H16B H 0.2856 0.1708 0.5669 0.063 Uiso 1 1 calc R
C17 C 0.0891(14) 0.1578(6) 0.4767(6) 0.057(3) Uani 1 1 d .
C18 C -0.1753(11) -0.0150(5) 0.6197(5) 0.048(2) Uani 1 1 d .
H18A H -0.2192 0.0052 0.6613 0.058 Uiso 1 1 calc R
H18B H -0.1533 -0.0662 0.6287 0.058 Uiso 1 1 calc R
C19 C 0.3190(8) 0.1790(4) 0.8581(4) 0.0274(14) Uani 1 1 d .
C20 C 0.4139(8) 0.1251(4) 0.8989(4) 0.0290(14) Uani 1 1 d .
H20A H 0.4336 0.0881 0.8598 0.035 Uiso 1 1 calc R
H20B H 0.5216 0.1569 0.9263 0.035 Uiso 1 1 calc R
C21 C 0.3264(9) 0.1311(4) 1.0182(4) 0.0322(15) Uani 1 1 d .
H21A H 0.2714 0.0984 1.0499 0.039 Uiso 1 1 calc R
H21B H 0.2540 0.1651 0.9986 0.039 Uiso 1 1 calc R
C22 C 0.4864(11) 0.1819(4) 1.0679(5) 0.0378(18) Uani 1 1 d .
H22A H 0.5458 0.2098 1.0346 0.045 Uiso 1 1 calc R
H22B H 0.4577 0.2213 1.1015 0.045 Uiso 1 1 calc R
C23 C 0.6023(10) 0.1431(4) 1.1162(4) 0.0353(17) Uani 1 1 d .
H23A H 0.6905 0.1837 1.1494 0.042 Uiso 1 1 calc R
H23B H 0.5432 0.1139 1.1488 0.042 Uiso 1 1 calc R
C24 C 0.7685(10) 0.0463(4) 1.1283(4) 0.0335(16) Uani 1 1 d .
H24A H 0.7029 0.0293 1.1642 0.040 Uiso 1 1 calc R
H24B H 0.8715 0.0811 1.1573 0.040 Uiso 1 1 calc R
C25 C 0.7865(9) 0.1304(4) 1.0333(4) 0.0327(16) Uani 1 1 d .
H25A H 0.9001 0.1379 1.0627 0.039 Uiso 1 1 calc R
H25B H 0.7626 0.1821 1.0289 0.039 Uiso 1 1 calc R
C26 C 0.7729(9) 0.0892(4) 0.9550(4) 0.0285(14) Uani 1 1 d .
C27 C 0.1935(9) 0.0252(4) 0.9142(4) 0.0328(16) Uani 1 1 d .
H27A H 0.1270 0.0510 0.8781 0.039 Uiso 1 1 calc R
H27B H 0.1311 0.0088 0.9514 0.039 Uiso 1 1 calc R
OW13 O -0.302(3) -0.0202(9) 0.7879(8) 0.153(13) Uani 0.50 1 d P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O9 Eu1 O11 83.13(18) . 1_455
O9 Eu1 O1 77.57(19) . .
O11 Eu1 O1 151.1(2) 1_455 .
O9 Eu1 O5 85.37(19) . .
O11 Eu1 O5 126.42(19) 1_455 .
O1 Eu1 O5 73.42(19) . .
O9 Eu1 OW2 74.3(2) . .
O11 Eu1 OW2 81.4(2) 1_455 .
O1 Eu1 OW2 72.85(19) . .
O5 Eu1 OW2 143.6(2) . .
O9 Eu1 O4 145.7(2) . 1_455
O11 Eu1 O4 125.34(19) 1_455 1_455
O1 Eu1 O4 68.6(2) . 1_455
O5 Eu1 O4 90.1(2) . 1_455
OW2 Eu1 O4 90.1(2) . 1_455
O9 Eu1 OW1 138.3(2) . .
O11 Eu1 OW1 82.3(2) 1_455 .
O1 Eu1 OW1 126.2(2) . .
O5 Eu1 OW1 72.7(2) . .
OW2 Eu1 OW1 140.6(2) . .
O4 Eu1 OW1 70.9(2) 1_455 .
O9 Eu1 O3 141.13(19) . 1_455
O11 Eu1 O3 75.38(17) 1_455 1_455
O1 Eu1 O3 107.22(18) . 1_455
O5 Eu1 O3 133.39(19) . 1_455
OW2 Eu1 O3 70.74(19) . 1_455
O4 Eu1 O3 51.20(18) 1_455 1_455
OW1 Eu1 O3 70.55(18) . 1_455
O9 Eu1 O6 70.5(2) . .
O11 Eu1 O6 75.28(18) 1_455 .
O1 Eu1 O6 116.97(18) . .
O5 Eu1 O6 51.62(18) . .
OW2 Eu1 O6 139.6(2) . .
O4 Eu1 O6 130.3(2) 1_455 .
OW1 Eu1 O6 68.09(19) . .
O3 Eu1 O6 131.63(18) 1_455 .
O9 Eu1 C10 75.7(2) . .
O11 Eu1 C10 101.0(2) 1_455 .
O1 Eu1 C10 94.8(2) . .
O5 Eu1 C10 25.8(2) . .
OW2 Eu1 C10 149.4(2) . .
O4 Eu1 C10 111.7(2) 1_455 .
OW1 Eu1 C10 69.1(2) . .
O3 Eu1 C10 139.6(2) 1_455 .
O6 Eu1 C10 25.8(2) . .
O9 Eu1 C9 153.3(2) . 1_455
O11 Eu1 C9 100.6(2) 1_455 1_455
O1 Eu1 C9 87.9(2) . 1_455
O5 Eu1 C9 112.0(2) . 1_455
OW2 Eu1 C9 80.1(2) . 1_455
O4 Eu1 C9 25.3(2) 1_455 1_455
OW1 Eu1 C9 68.1(2) . 1_455
O3 Eu1 C9 25.87(19) 1_455 1_455
O6 Eu1 C9 136.2(2) . 1_455
C10 Eu1 C9 128.4(2) . 1_455
N1 Zn1 N1 180.000(3) 2_667 .
N1 Zn1 O2 80.9(2) 2_667 2_667
N1 Zn1 O2 99.1(2) . 2_667
N1 Zn1 O2 99.1(2) 2_667 .
N1 Zn1 O2 80.9(2) . .
O2 Zn1 O2 180.000(1) 2_667 .
N1 Zn1 N2 93.8(2) 2_667 2_667
N1 Zn1 N2 86.2(2) . 2_667
O2 Zn1 N2 91.4(2) 2_667 2_667
O2 Zn1 N2 88.6(2) . 2_667
N1 Zn1 N2 86.2(2) 2_667 .
N1 Zn1 N2 93.8(2) . .
O2 Zn1 N2 88.6(2) 2_667 .
O2 Zn1 N2 91.4(2) . .
N2 Zn1 N2 180.0(3) 2_667 .
N4 Zn2 N4 180.000(1) . 2_556
N4 Zn2 O8 81.8(3) . .
N4 Zn2 O8 98.2(3) 2_556 .
N4 Zn2 O8 98.2(3) . 2_556
N4 Zn2 O8 81.8(3) 2_556 2_556
O8 Zn2 O8 180.000(2) . 2_556
N4 Zn2 N3 93.8(3) . .
N4 Zn2 N3 86.2(3) 2_556 .
O8 Zn2 N3 90.7(2) . .
O8 Zn2 N3 89.3(2) 2_556 .
N4 Zn2 N3 86.2(3) . 2_556
N4 Zn2 N3 93.8(3) 2_556 2_556
O8 Zn2 N3 89.3(2) . 2_556
O8 Zn2 N3 90.7(2) 2_556 2_556
N3 Zn2 N3 180.000(1) . 2_556
N6 Zn3 N6 180.000(1) . 2_657
N6 Zn3 O12 99.7(2) . 2_657
N6 Zn3 O12 80.3(2) 2_657 2_657
N6 Zn3 O12 80.3(2) . .
N6 Zn3 O12 99.7(2) 2_657 .
O12 Zn3 O12 180.000(2) 2_657 .
N6 Zn3 N5 94.3(2) . .
N6 Zn3 N5 85.7(2) 2_657 .
O12 Zn3 N5 88.0(2) 2_657 .
O12 Zn3 N5 92.0(2) . .
N6 Zn3 N5 85.7(2) . 2_657
N6 Zn3 N5 94.3(2) 2_657 2_657
O12 Zn3 N5 92.0(2) 2_657 2_657
O12 Zn3 N5 88.0(2) . 2_657
N5 Zn3 N5 180.000(3) . 2_657
C1 O1 Eu1 143.2(5) . .
C1 O2 Zn1 115.2(4) . .
C9 O3 Eu1 93.2(4) . 1_655
C9 O4 Eu1 95.1(5) . 1_655
C10 O5 Eu1 96.2(5) . .
C10 O6 Eu1 89.4(4) . .
C17 O8 Zn2 113.7(6) . .
C19 O9 Eu1 153.9(5) . .
C26 O11 Eu1 143.5(4) . 1_655
C26 O12 Zn3 114.1(5) . .
C3 N1 C2 112.7(6) . .
C3 N1 C7 109.4(6) . .
C2 N1 C7 110.3(6) . .
C3 N1 Zn1 112.0(5) . .
C2 N1 Zn1 108.8(4) . .
C7 N1 Zn1 103.2(5) . .
C6 N2 C8 109.7(6) . .
C6 N2 C5 111.8(6) . .
C8 N2 C5 112.1(6) . .
C6 N2 Zn1 100.8(4) . .
C8 N2 Zn1 114.7(4) . .
C5 N2 Zn1 107.2(4) . .
C11 N3 C12 111.7(7) . .
C11 N3 C18 110.7(7) . .
C12 N3 C18 111.3(7) . .
C11 N3 Zn2 115.7(5) . .
C12 N3 Zn2 106.7(5) . .
C18 N3 Zn2 100.1(5) . .
C16 N4 C15 110.2(7) . .
C16 N4 C14 111.2(7) . .
C15 N4 C14 109.5(7) . .
C16 N4 Zn2 109.5(6) . .
C15 N4 Zn2 103.8(5) . .
C14 N4 Zn2 112.4(6) . .
C27 N5 C20 110.3(6) . .
C27 N5 C21 111.0(6) . .
C20 N5 C21 111.3(5) . .
C27 N5 Zn3 102.1(4) . .
C20 N5 Zn3 114.4(4) . .
C21 N5 Zn3 107.2(4) . .
C25 N6 C24 110.0(6) . .
C25 N6 C23 111.7(5) . .
C24 N6 C23 109.8(6) . .
C25 N6 Zn3 109.8(4) . .
C24 N6 Zn3 103.2(4) . .
C23 N6 Zn3 112.0(5) . .
O1 C1 O2 125.4(7) . .
O1 C1 C2 116.5(7) . .
O2 C1 C2 118.1(6) . .
N1 C2 C1 114.8(6) . .
N1 C2 H2A 108.6 . .
C1 C2 H2A 108.6 . .
N1 C2 H2B 108.6 . .
C1 C2 H2B 108.6 . .
H2A C2 H2B 107.5 . .
N1 C3 C4 114.4(6) . .
N1 C3 H3A 108.7 . .
C4 C3 H3A 108.7 . .
N1 C3 H3B 108.7 . .
C4 C3 H3B 108.7 . .
H3A C3 H3B 107.6 . .
C5 C4 C3 117.6(7) . .
C5 C4 H4A 107.9 . .
C3 C4 H4A 107.9 . .
C5 C4 H4B 107.9 . .
C3 C4 H4B 107.9 . .
H4A C4 H4B 107.2 . .
C4 C5 N2 114.5(6) . .
C4 C5 H5A 108.6 . .
N2 C5 H5A 108.6 . .
C4 C5 H5B 108.6 . .
N2 C5 H5B 108.6 . .
H5A C5 H5B 107.6 . .
N2 C6 C7 110.2(6) . 2_667
N2 C6 H6A 109.6 . .
C7 C6 H6A 109.6 2_667 .
N2 C6 H6B 109.6 . .
C7 C6 H6B 109.6 2_667 .
H6A C6 H6B 108.1 . .
N1 C7 C6 110.9(6) . 2_667
N1 C7 H7A 109.5 . .
C6 C7 H7A 109.5 2_667 .
N1 C7 H7B 109.5 . .
C6 C7 H7B 109.5 2_667 .
H7A C7 H7B 108.1 . .
N2 C8 C9 114.2(6) . .
N2 C8 H8A 108.7 . .
C9 C8 H8A 108.7 . .
N2 C8 H8B 108.7 . .
C9 C8 H8B 108.7 . .
H8A C8 H8B 107.6 . .
O4 C9 O3 120.4(7) . .
O4 C9 C8 120.6(7) . .
O3 C9 C8 119.0(7) . .
O4 C9 Eu1 59.5(4) . 1_655
O3 C9 Eu1 60.9(4) . 1_655
C8 C9 Eu1 178.2(5) . 1_655
O5 C10 O6 122.6(6) . .
O5 C10 C11 115.0(7) . .
O6 C10 C11 122.4(7) . .
O5 C10 Eu1 57.9(4) . .
O6 C10 Eu1 64.8(4) . .
C11 C10 Eu1 172.4(6) . .
N3 C11 C10 118.2(7) . .
N3 C11 H11A 107.8 . .
C10 C11 H11A 107.8 . .
N3 C11 H11B 107.8 . .
C10 C11 H11B 107.8 . .
H11A C11 H11B 107.1 . .
N3 C12 C13 113.0(8) . .
N3 C12 H12A 109.0 . .
C13 C12 H12A 109.0 . .
N3 C12 H12B 109.0 . .
C13 C12 H12B 109.0 . .
H12A C12 H12B 107.8 . .
C14 C13 C12 116.7(8) . .
C14 C13 H13A 108.1 . .
C12 C13 H13A 108.1 . .
C14 C13 H13B 108.1 . .
C12 C13 H13B 108.1 . .
H13A C13 H13B 107.3 . .
N4 C14 C13 116.4(7) . .
N4 C14 H14A 108.2 . .
C13 C14 H14A 108.2 . .
N4 C14 H14B 108.2 . .
C13 C14 H14B 108.2 . .
H14A C14 H14B 107.3 . .
N4 C15 C18 111.4(7) . 2_556
N4 C15 H15A 109.4 . .
C18 C15 H15A 109.4 2_556 .
N4 C15 H15B 109.4 . .
C18 C15 H15B 109.4 2_556 .
H15A C15 H15B 108.0 . .
N4 C16 C17 112.5(8) . .
N4 C16 H16A 109.1 . .
C17 C16 H16A 109.1 . .
N4 C16 H16B 109.1 . .
C17 C16 H16B 109.1 . .
H16A C16 H16B 107.8 . .
O7 C17 O8 123.3(11) . .
O7 C17 C16 116.8(10) . .
O8 C17 C16 119.9(9) . .
N3 C18 C15 109.8(7) . 2_556
N3 C18 H18A 109.7 . .
C15 C18 H18A 109.7 2_556 .
N3 C18 H18B 109.7 . .
C15 C18 H18B 109.7 2_556 .
H18A C18 H18B 108.2 . .
O9 C19 O10 126.5(7) . .
O9 C19 C20 119.6(6) . .
O10 C19 C20 113.8(6) . .
N5 C20 C19 120.7(6) . .
N5 C20 H20A 107.1 . .
C19 C20 H20A 107.1 . .
N5 C20 H20B 107.1 . .
C19 C20 H20B 107.1 . .
H20A C20 H20B 106.8 . .
N5 C21 C22 114.3(6) . .
N5 C21 H21A 108.7 . .
C22 C21 H21A 108.7 . .
N5 C21 H21B 108.7 . .
C22 C21 H21B 108.7 . .
H21A C21 H21B 107.6 . .
C23 C22 C21 118.3(6) . .
C23 C22 H22A 107.7 . .
C21 C22 H22A 107.7 . .
C23 C22 H22B 107.7 . .
C21 C22 H22B 107.7 . .
H22A C22 H22B 107.1 . .
N6 C23 C22 115.7(6) . .
N6 C23 H23A 108.4 . .
C22 C23 H23A 108.4 . .
N6 C23 H23B 108.4 . .
C22 C23 H23B 108.4 . .
H23A C23 H23B 107.4 . .
N6 C24 C27 110.9(6) . 2_657
N6 C24 H24A 109.5 . .
C27 C24 H24A 109.5 2_657 .
N6 C24 H24B 109.5 . .
C27 C24 H24B 109.5 2_657 .
H24A C24 H24B 108.0 . .
N6 C25 C26 114.2(6) . .
N6 C25 H25A 108.7 . .
C26 C25 H25A 108.7 . .
N6 C25 H25B 108.7 . .
C26 C25 H25B 108.7 . .
H25A C25 H25B 107.6 . .
O12 C26 O11 123.5(7) . .
O12 C26 C25 119.4(6) . .
O11 C26 C25 117.1(6) . .
N5 C27 C24 109.0(6) . 2_657
N5 C27 H27A 109.9 . .
C24 C27 H27A 109.9 2_657 .
N5 C27 H27B 109.9 . .
C24 C27 H27B 109.9 2_657 .
H27A C27 H27B 108.3 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O9 2.338(5) .
Eu1 O11 2.356(5) 1_455
Eu1 O1 2.445(5) .
Eu1 O5 2.450(5) .
Eu1 OW2 2.464(6) .
Eu1 O4 2.497(6) 1_455
Eu1 OW1 2.514(6) .
Eu1 O3 2.527(5) 1_455
Eu1 O6 2.600(5) .
Eu1 C10 2.873(7) .
Eu1 C9 2.886(7) 1_455
Zn1 N1 2.117(6) 2_667
Zn1 N1 2.117(6) .
Zn1 O2 2.125(5) 2_667
Zn1 O2 2.125(5) .
Zn1 N2 2.218(6) 2_667
Zn1 N2 2.218(6) .
Zn2 N4 2.093(7) .
Zn2 N4 2.093(7) 2_556
Zn2 O8 2.109(6) .
Zn2 O8 2.109(6) 2_556
Zn2 N3 2.259(6) .
Zn2 N3 2.259(6) 2_556
Zn3 N6 2.122(6) .
Zn3 N6 2.122(6) 2_657
Zn3 O12 2.142(5) 2_657
Zn3 O12 2.142(5) .
Zn3 N5 2.223(6) .
Zn3 N5 2.223(6) 2_657
O1 C1 1.231(9) .
O2 C1 1.266(9) .
O3 C9 1.261(9) .
O3 Eu1 2.527(5) 1_655
O4 C9 1.240(10) .
O4 Eu1 2.497(6) 1_655
O5 C10 1.259(9) .
O6 C10 1.252(10) .
O7 C17 1.235(13) .
O8 C17 1.273(12) .
O9 C19 1.245(8) .
O10 C19 1.251(9) .
O11 C26 1.274(8) .
O11 Eu1 2.356(5) 1_655
O12 C26 1.262(9) .
N1 C3 1.475(10) .
N1 C2 1.479(9) .
N1 C7 1.485(10) .
N2 C6 1.486(11) .
N2 C8 1.502(9) .
N2 C5 1.504(10) .
N3 C11 1.466(11) .
N3 C12 1.493(11) .
N3 C18 1.505(11) .
N4 C16 1.487(12) .
N4 C15 1.491(10) .
N4 C14 1.487(12) .
N5 C27 1.478(9) .
N5 C20 1.477(9) .
N5 C21 1.508(9) .
N6 C25 1.463(9) .
N6 C24 1.491(9) .
N6 C23 1.494(9) .
C1 C2 1.520(10) .
C2 H2A 0.9900 .
C2 H2B 0.9900 .
C3 C4 1.543(12) .
C3 H3A 0.9900 .
C3 H3B 0.9900 .
C4 C5 1.502(13) .
C4 H4A 0.9900 .
C4 H4B 0.9900 .
C5 H5A 0.9900 .
C5 H5B 0.9900 .
C6 C7 1.534(12) 2_667
C6 H6A 0.9900 .
C6 H6B 0.9900 .
C7 C6 1.534(12) 2_667
C7 H7A 0.9900 .
C7 H7B 0.9900 .
C8 C9 1.513(9) .
C8 H8A 0.9900 .
C8 H8B 0.9900 .
C9 Eu1 2.886(7) 1_655
C10 C11 1.557(10) .
C11 H11A 0.9900 .
C11 H11B 0.9900 .
C12 C13 1.553(13) .
C12 H12A 0.9900 .
C12 H12B 0.9900 .
C13 C14 1.530(12) .
C13 H13A 0.9900 .
C13 H13B 0.9900 .
C14 H14A 0.9900 .
C14 H14B 0.9900 .
C15 C18 1.532(13) 2_556
C15 H15A 0.9900 .
C15 H15B 0.9900 .
C16 C17 1.515(15) .
C16 H16A 0.9900 .
C16 H16B 0.9900 .
C18 C15 1.532(13) 2_556
C18 H18A 0.9900 .
C18 H18B 0.9900 .
C19 C20 1.529(10) .
C20 H20A 0.9900 .
C20 H20B 0.9900 .
C21 C22 1.543(12) .
C21 H21A 0.9900 .
C21 H21B 0.9900 .
C22 C23 1.507(11) .
C22 H22A 0.9900 .
C22 H22B 0.9900 .
C23 H23A 0.9900 .
C23 H23B 0.9900 .
C24 C27 1.553(10) 2_657
C24 H24A 0.9900 .
C24 H24B 0.9900 .
C25 C26 1.519(11) .
C25 H25A 0.9900 .
C25 H25B 0.9900 .
C27 C24 1.553(10) 2_657
C27 H27A 0.9900 .
C27 H27B 0.9900 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O9 Eu1 O1 C1 -71.0(8) . .
O11 Eu1 O1 C1 -21.8(11) 1_455 .
O5 Eu1 O1 C1 -159.8(9) . .
OW2 Eu1 O1 C1 6.2(8) . .
O4 Eu1 O1 C1 103.3(9) 1_455 .
OW1 Eu1 O1 C1 147.2(8) . .
O3 Eu1 O1 C1 69.0(8) 1_455 .
O6 Eu1 O1 C1 -131.2(8) . .
C10 Eu1 O1 C1 -145.2(8) . .
C9 Eu1 O1 C1 86.5(8) 1_455 .
N1 Zn1 O2 C1 -170.3(5) 2_667 .
N1 Zn1 O2 C1 9.7(5) . .
O2 Zn1 O2 C1 -75(100) 2_667 .
N2 Zn1 O2 C1 96.0(5) 2_667 .
N2 Zn1 O2 C1 -84.0(5) . .
O9 Eu1 O5 C10 66.4(5) . .
O11 Eu1 O5 C10 -11.6(5) 1_455 .
O1 Eu1 O5 C10 144.8(5) . .
OW2 Eu1 O5 C10 121.9(5) . .
O4 Eu1 O5 C10 -147.7(5) 1_455 .
OW1 Eu1 O5 C10 -77.7(5) . .
O3 Eu1 O5 C10 -117.0(5) 1_455 .
O6 Eu1 O5 C10 -2.3(4) . .
C9 Eu1 O5 C10 -134.5(5) 1_455 .
O9 Eu1 O6 C10 -97.6(5) . .
O11 Eu1 O6 C10 174.6(5) 1_455 .
O1 Eu1 O6 C10 -33.5(5) . .
O5 Eu1 O6 C10 2.3(4) . .
OW2 Eu1 O6 C10 -128.5(5) . .
O4 Eu1 O6 C10 50.5(5) 1_455 .
OW1 Eu1 O6 C10 87.1(5) . .
O3 Eu1 O6 C10 120.2(5) 1_455 .
C9 Eu1 O6 C10 84.6(5) 1_455 .
N4 Zn2 O8 C17 -4.6(6) . .
N4 Zn2 O8 C17 175.4(6) 2_556 .
O8 Zn2 O8 C17 -106(94) 2_556 .
N3 Zn2 O8 C17 89.2(7) . .
N3 Zn2 O8 C17 -90.8(7) 2_556 .
O11 Eu1 O9 C19 133.9(12) 1_455 .
O1 Eu1 O9 C19 -67.7(11) . .
O5 Eu1 O9 C19 6.3(11) . .
OW2 Eu1 O9 C19 -143.1(12) . .
O4 Eu1 O9 C19 -77.1(12) 1_455 .
OW1 Eu1 O9 C19 63.7(12) . .
O3 Eu1 O9 C19 -169.8(10) 1_455 .
O6 Eu1 O9 C19 57.1(11) . .
C10 Eu1 O9 C19 30.6(11) . .
C9 Eu1 O9 C19 -126.2(11) 1_455 .
N6 Zn3 O12 C26 -11.1(5) . .
N6 Zn3 O12 C26 168.9(5) 2_657 .
O12 Zn3 O12 C26 177(100) 2_657 .
N5 Zn3 O12 C26 82.9(5) . .
N5 Zn3 O12 C26 -97.1(5) 2_657 .
N1 Zn1 N1 C3 -92(100) 2_667 .
O2 Zn1 N1 C3 41.8(5) 2_667 .
O2 Zn1 N1 C3 -138.2(5) . .
N2 Zn1 N1 C3 132.6(5) 2_667 .
N2 Zn1 N1 C3 -47.4(5) . .
N1 Zn1 N1 C2 34(100) 2_667 .
O2 Zn1 N1 C2 167.1(5) 2_667 .
O2 Zn1 N1 C2 -12.9(5) . .
N2 Zn1 N1 C2 -102.1(5) 2_667 .
N2 Zn1 N1 C2 77.9(5) . .
N1 Zn1 N1 C7 151(100) 2_667 .
O2 Zn1 N1 C7 -75.7(5) 2_667 .
O2 Zn1 N1 C7 104.3(5) . .
N2 Zn1 N1 C7 15.1(5) 2_667 .
N2 Zn1 N1 C7 -164.9(5) . .
N1 Zn1 N2 C6 -15.1(4) 2_667 .
N1 Zn1 N2 C6 164.9(4) . .
O2 Zn1 N2 C6 65.8(4) 2_667 .
O2 Zn1 N2 C6 -114.2(4) . .
N2 Zn1 N2 C6 -139(100) 2_667 .
N1 Zn1 N2 C8 102.6(5) 2_667 .
N1 Zn1 N2 C8 -77.4(5) . .
O2 Zn1 N2 C8 -176.4(5) 2_667 .
O2 Zn1 N2 C8 3.6(5) . .
N2 Zn1 N2 C8 -21(100) 2_667 .
N1 Zn1 N2 C5 -132.2(5) 2_667 .
N1 Zn1 N2 C5 47.8(5) . .
O2 Zn1 N2 C5 -51.2(5) 2_667 .
O2 Zn1 N2 C5 128.8(5) . .
N2 Zn1 N2 C5 104(100) 2_667 .
N4 Zn2 N3 C11 75.3(6) . .
N4 Zn2 N3 C11 -104.7(6) 2_556 .
O8 Zn2 N3 C11 -6.6(6) . .
O8 Zn2 N3 C11 173.4(6) 2_556 .
N3 Zn2 N3 C11 -134(100) 2_556 .
N4 Zn2 N3 C12 -49.7(6) . .
N4 Zn2 N3 C12 130.3(6) 2_556 .
O8 Zn2 N3 C12 -131.6(6) . .
O8 Zn2 N3 C12 48.4(6) 2_556 .
N3 Zn2 N3 C12 101(100) 2_556 .
N4 Zn2 N3 C18 -165.7(5) . .
N4 Zn2 N3 C18 14.3(5) 2_556 .
O8 Zn2 N3 C18 112.4(5) . .
O8 Zn2 N3 C18 -67.6(5) 2_556 .
N3 Zn2 N3 C18 -15(100) 2_556 .
N4 Zn2 N4 C16 126(48) 2_556 .
O8 Zn2 N4 C16 12.1(5) . .
O8 Zn2 N4 C16 -167.9(5) 2_556 .
N3 Zn2 N4 C16 -78.0(6) . .
N3 Zn2 N4 C16 102.0(6) 2_556 .
N4 Zn2 N4 C15 8(49) 2_556 .
O8 Zn2 N4 C15 -105.6(6) . .
O8 Zn2 N4 C15 74.4(6) 2_556 .
N3 Zn2 N4 C15 164.3(6) . .
N3 Zn2 N4 C15 -15.7(6) 2_556 .
N4 Zn2 N4 C14 -110(48) 2_556 .
O8 Zn2 N4 C14 136.2(6) . .
O8 Zn2 N4 C14 -43.8(6) 2_556 .
N3 Zn2 N4 C14 46.0(6) . .
N3 Zn2 N4 C14 -134.0(6) 2_556 .
N6 Zn3 N5 C27 -164.9(4) . .
N6 Zn3 N5 C27 15.1(4) 2_657 .
O12 Zn3 N5 C27 -65.3(4) 2_657 .
O12 Zn3 N5 C27 114.7(4) . .
N5 Zn3 N5 C27 39(100) 2_657 .
N6 Zn3 N5 C20 75.9(5) . .
N6 Zn3 N5 C20 -104.1(5) 2_657 .
O12 Zn3 N5 C20 175.5(5) 2_657 .
O12 Zn3 N5 C20 -4.5(5) . .
N5 Zn3 N5 C20 -80(100) 2_657 .
N6 Zn3 N5 C21 -48.1(4) . .
N6 Zn3 N5 C21 131.9(4) 2_657 .
O12 Zn3 N5 C21 51.5(4) 2_657 .
O12 Zn3 N5 C21 -128.5(4) . .
N5 Zn3 N5 C21 156(100) 2_657 .
N6 Zn3 N6 C25 42(100) 2_657 .
O12 Zn3 N6 C25 -167.1(4) 2_657 .
O12 Zn3 N6 C25 12.9(4) . .
N5 Zn3 N6 C25 -78.4(5) . .
N5 Zn3 N6 C25 101.6(5) 2_657 .
N6 Zn3 N6 C24 -76(100) 2_657 .
O12 Zn3 N6 C24 75.6(4) 2_657 .
O12 Zn3 N6 C24 -104.4(4) . .
N5 Zn3 N6 C24 164.3(4) . .
N5 Zn3 N6 C24 -15.7(4) 2_657 .
N6 Zn3 N6 C23 166(100) 2_657 .
O12 Zn3 N6 C23 -42.5(5) 2_657 .
O12 Zn3 N6 C23 137.5(5) . .
N5 Zn3 N6 C23 46.2(5) . .
N5 Zn3 N6 C23 -133.8(5) 2_657 .
Eu1 O1 C1 O2 9.0(13) . .
Eu1 O1 C1 C2 -171.8(6) . .
Zn1 O2 C1 O1 175.6(6) . .
Zn1 O2 C1 C2 -3.7(8) . .
C3 N1 C2 C1 140.0(7) . .
C7 N1 C2 C1 -97.4(7) . .
Zn1 N1 C2 C1 15.1(7) . .
O1 C1 C2 N1 172.5(6) . .
O2 C1 C2 N1 -8.2(9) . .
C2 N1 C3 C4 -64.3(9) . .
C7 N1 C3 C4 172.5(7) . .
Zn1 N1 C3 C4 58.7(8) . .
N1 C3 C4 C5 -67.4(10) . .
C3 C4 C5 N2 71.4(9) . .
C6 N2 C5 C4 -171.8(6) . .
C8 N2 C5 C4 64.5(8) . .
Zn1 N2 C5 C4 -62.2(7) . .
C8 N2 C6 C7 -78.5(7) . 2_667
C5 N2 C6 C7 156.4(6) . 2_667
Zn1 N2 C6 C7 42.8(6) . 2_667
C3 N1 C7 C6 -163.1(7) . 2_667
C2 N1 C7 C6 72.4(8) . 2_667
Zn1 N1 C7 C6 -43.7(7) . 2_667
C6 N2 C8 C9 -54.9(8) . .
C5 N2 C8 C9 70.0(8) . .
Zn1 N2 C8 C9 -167.5(5) . .
Eu1 O4 C9 O3 1.9(8) 1_655 .
Eu1 O4 C9 C8 -178.0(6) 1_655 .
Eu1 O3 C9 O4 -1.9(8) 1_655 .
Eu1 O3 C9 C8 178.0(6) 1_655 .
N2 C8 C9 O4 -75.4(10) . .
N2 C8 C9 O3 104.7(8) . .
N2 C8 C9 Eu1 -168(18) . 1_655
Eu1 O5 C10 O6 4.5(8) . .
Eu1 O5 C10 C11 -176.7(6) . .
Eu1 O6 C10 O5 -4.2(8) . .
Eu1 O6 C10 C11 177.1(7) . .
O9 Eu1 C10 O5 -109.6(5) . .
O11 Eu1 C10 O5 170.5(5) 1_455 .
O1 Eu1 C10 O5 -33.7(5) . .
OW2 Eu1 C10 O5 -97.7(6) . .
O4 Eu1 C10 O5 35.1(5) 1_455 .
OW1 Eu1 C10 O5 93.3(5) . .
O3 Eu1 C10 O5 90.2(5) 1_455 .
O6 Eu1 C10 O5 175.8(8) . .
C9 Eu1 C10 O5 57.4(5) 1_455 .
O9 Eu1 C10 O6 74.6(5) . .
O11 Eu1 C10 O6 -5.3(5) 1_455 .
O1 Eu1 C10 O6 150.4(5) . .
O5 Eu1 C10 O6 -175.8(8) . .
OW2 Eu1 C10 O6 86.5(6) . .
O4 Eu1 C10 O6 -140.7(5) 1_455 .
OW1 Eu1 C10 O6 -82.6(5) . .
O3 Eu1 C10 O6 -85.6(5) 1_455 .
C9 Eu1 C10 O6 -118.4(5) 1_455 .
O9 Eu1 C10 C11 -86(4) . .
O11 Eu1 C10 C11 -166(4) 1_455 .
O1 Eu1 C10 C11 -10(4) . .
O5 Eu1 C10 C11 23(4) . .
OW2 Eu1 C10 C11 -74(4) . .
O4 Eu1 C10 C11 58(4) 1_455 .
OW1 Eu1 C10 C11 117(4) . .
O3 Eu1 C10 C11 113(4) 1_455 .
O6 Eu1 C10 C11 -161(4) . .
C9 Eu1 C10 C11 81(4) 1_455 .
C12 N3 C11 C10 -58.4(10) . .
C18 N3 C11 C10 66.2(10) . .
Zn2 N3 C11 C10 179.2(5) . .
O5 C10 C11 N3 172.0(7) . .
O6 C10 C11 N3 -9.1(12) . .
Eu1 C10 C11 N3 150(4) . .
C11 N3 C12 C13 -63.4(9) . .
C18 N3 C12 C13 172.3(7) . .
Zn2 N3 C12 C13 64.0(7) . .
N3 C12 C13 C14 -72.0(10) . .
C16 N4 C14 C13 65.4(10) . .
C15 N4 C14 C13 -172.5(8) . .
Zn2 N4 C14 C13 -57.6(10) . .
C12 C13 C14 N4 66.0(12) . .
C16 N4 C15 C18 -72.2(9) . 2_556
C14 N4 C15 C18 165.1(8) . 2_556
Zn2 N4 C15 C18 44.9(8) . 2_556
C15 N4 C16 C17 96.2(9) . .
C14 N4 C16 C17 -142.2(8) . .
Zn2 N4 C16 C17 -17.4(9) . .
Zn2 O8 C17 O7 177.8(10) . .
Zn2 O8 C17 C16 -4.5(11) . .
N4 C16 C17 O7 -166.9(10) . .
N4 C16 C17 O8 15.3(13) . .
C11 N3 C18 C15 80.8(8) . 2_556
C12 N3 C18 C15 -154.3(7) . 2_556
Zn2 N3 C18 C15 -41.8(7) . 2_556
Eu1 O9 C19 O10 27.7(16) . .
Eu1 O9 C19 C20 -154.3(8) . .
C27 N5 C20 C19 62.1(8) . .
C21 N5 C20 C19 -61.7(9) . .
Zn3 N5 C20 C19 176.5(5) . .
O9 C19 C20 N5 9.4(10) . .
O10 C19 C20 N5 -172.4(7) . .
C27 N5 C21 C22 172.2(6) . .
C20 N5 C21 C22 -64.4(8) . .
Zn3 N5 C21 C22 61.5(6) . .
N5 C21 C22 C23 -70.2(9) . .
C25 N6 C23 C22 66.3(8) . .
C24 N6 C23 C22 -171.4(7) . .
Zn3 N6 C23 C22 -57.3(7) . .
C21 C22 C23 N6 65.7(9) . .
C25 N6 C24 C27 -72.6(7) . 2_657
C23 N6 C24 C27 164.1(6) . 2_657
Zn3 N6 C24 C27 44.5(6) . 2_657
C24 N6 C25 C26 99.4(7) . .
C23 N6 C25 C26 -138.4(6) . .
Zn3 N6 C25 C26 -13.6(7) . .
Zn3 O12 C26 O11 -173.2(5) . .
Zn3 O12 C26 C25 6.6(8) . .
Eu1 O11 C26 O12 110.7(8) 1_655 .
Eu1 O11 C26 C25 -69.0(11) 1_655 .
N6 C25 C26 O12 5.0(9) . .
N6 C25 C26 O11 -175.2(6) . .
C20 N5 C27 C24 79.6(7) . 2_657
C21 N5 C27 C24 -156.5(6) . 2_657
Zn3 N5 C27 C24 -42.5(6) . 2_657
