#------------------------------------------------------------------------------
#$Date: 2016-03-24 02:58:16 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179606 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/70/4507026.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4507026
loop_
_publ_author_name
'Cai, Song-Liang'
'Zheng, Sheng-Run'
'Wen, Zhen-Zhen'
'Fan, Jun'
'Zhang, Wei-Guang'
_publ_section_title
;
 A Series of New Three-Dimensional d--f Heterometallic Coordination
 Polymers with Rare 10-ConnectedbctNet Topology Based on Planar
 Hexanuclear Heterometallic Second Building Units
;
_journal_issue                   11
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              5737
_journal_paper_doi               10.1021/cg301256g
_journal_volume                  12
_journal_year                    2012
_chemical_formula_moiety         'C22 H12 Cd Eu N5 O8, 3(H2 O)'
_chemical_formula_sum            'C22 H18 Cd Eu N5 O11'
_chemical_formula_weight         792.77
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 121.247(8)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.062(2)
_cell_length_b                   13.563(3)
_cell_length_c                   20.895(4)
_cell_measurement_reflns_used    3995
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      27.65
_cell_measurement_theta_min      2.28
_cell_volume                     2680.2(9)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0434
_diffrn_reflns_av_sigmaI/netI    0.0573
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            14100
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.89
_exptl_absorpt_coefficient_mu    3.179
_exptl_absorpt_correction_T_max  0.5037
_exptl_absorpt_correction_T_min  0.4697
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.965
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1536
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.26
_exptl_crystal_size_min          0.25
_refine_diff_density_max         1.115
_refine_diff_density_min         -1.354
_refine_diff_density_rms         0.152
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.051
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     361
_refine_ls_number_reflns         5258
_refine_ls_number_restraints     25
_refine_ls_restrained_S_all      1.077
_refine_ls_R_factor_all          0.0627
_refine_ls_R_factor_gt           0.0394
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0387P)²+1.1772P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0828
_refine_ls_wR_factor_ref         0.0943
_reflns_number_gt                3902
_reflns_number_total             5258
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg301256g_si_002.cif
_cod_data_source_block           Eu-Cd
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      'P2(1)/c  '
_cod_database_code               4507026
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.55787(3) 0.86299(2) 0.495952(16) 0.01991(10) Uani 1 1 d U
Cd1 Cd 0.99235(4) 0.85495(3) 0.73333(2) 0.02164(13) Uani 1 1 d .
O1 O 0.7724(4) 0.9011(3) 0.6261(2) 0.0217(9) Uani 1 1 d U
O2 O 0.6133(4) 1.0184(3) 0.5784(2) 0.0261(10) Uani 1 1 d .
O3 O 0.6438(5) 1.2254(3) 0.5778(2) 0.0411(13) Uani 1 1 d .
O4 O 0.7906(5) 1.3307(3) 0.6629(3) 0.0415(13) Uani 1 1 d .
O5 O 0.4308(5) 0.8612(3) 0.5631(3) 0.0367(12) Uani 1 1 d .
O6 O 0.6764(5) 0.9911(4) 0.4700(3) 0.0415(13) Uani 1 1 d .
O7 O 0.7524(5) 0.7846(4) 0.4876(3) 0.0470(14) Uani 1 1 d .
O8 O 0.5555(5) 0.8144(4) 0.3812(3) 0.0449(10) Uani 1 1 d U
N1 N 0.9723(5) 1.0231(4) 0.7345(3) 0.0231(12) Uani 1 1 d .
N2 N 0.9728(5) 1.1874(4) 0.7482(3) 0.0254(12) Uani 1 1 d .
N3 N 1.3830(5) 1.1940(4) 0.9369(3) 0.0357(14) Uani 1 1 d .
N4 N 0.0954(6) 0.8620(4) 0.6581(3) 0.0357(14) Uani 1 1 d .
N5 N 0.8671(7) 0.6693(5) 0.2969(3) 0.0428(16) Uani 1 1 d .
C1 C 0.7372(6) 0.9906(4) 0.6262(3) 0.0204(13) Uani 1 1 d .
C2 C 0.8431(6) 1.0591(4) 0.6798(3) 0.0214(14) Uani 1 1 d .
C3 C 0.8453(6) 1.1616(4) 0.6868(3) 0.0230(14) Uani 1 1 d .
C4 C 0.7511(6) 1.2447(5) 0.6397(4) 0.0294(16) Uani 1 1 d .
C5 C 1.0469(6) 1.1021(5) 0.7736(3) 0.0271(15) Uani 1 1 d .
C6 C 1.1983(6) 1.1036(5) 0.8334(4) 0.0296(16) Uani 1 1 d .
C7 C 1.2462(6) 1.1756(5) 0.8862(3) 0.0308(16) Uani 1 1 d .
H7 H 1.1789 1.2154 0.8874 0.037 Uiso 1 1 calc R
C8 C 1.2981(7) 1.0404(5) 0.8349(4) 0.047(2) Uani 1 1 d .
H8 H 1.2705 0.9889 0.8006 0.056 Uiso 1 1 calc R
C9 C 1.4378(8) 1.0546(6) 0.8874(5) 0.066(3) Uani 1 1 d .
H9 H 1.5063 1.0123 0.8899 0.079 Uiso 1 1 calc R
C10 C 1.4761(8) 1.1328(6) 0.9368(5) 0.061(3) Uani 1 1 d .
H10 H 1.5716 1.1428 0.9714 0.074 Uiso 1 1 calc R
C11 C 0.3444(7) 0.9242(5) 0.5595(4) 0.0318(16) Uani 1 1 d .
C12 C 0.2563(6) 0.8995(5) 0.5928(4) 0.0283(15) Uani 1 1 d .
C13 C 0.1548(7) 0.9653(5) 0.5862(4) 0.0410(19) Uani 1 1 d .
H13 H 0.1392 1.0239 0.5599 0.049 Uiso 1 1 calc R
C14 C 0.2700(8) 0.8143(6) 0.6306(4) 0.045(2) Uani 1 1 d .
H14 H 0.3338 0.7665 0.6345 0.054 Uiso 1 1 calc R
C15 C 0.0770(8) 0.9440(6) 0.6186(4) 0.047(2) Uani 1 1 d .
H15 H 0.0083 0.9887 0.6129 0.056 Uiso 1 1 calc R
C16 C 0.1912(8) 0.7983(6) 0.6626(4) 0.048(2) Uani 1 1 d .
H16 H 0.2050 0.7399 0.6889 0.057 Uiso 1 1 calc R
C17 C 0.6808(8) 0.7838(6) 0.4178(4) 0.0433(19) Uani 1 1 d .
C18 C 0.7466(8) 0.7416(6) 0.3754(4) 0.0416(19) Uani 1 1 d .
C19 C 0.8870(9) 0.7210(7) 0.4116(5) 0.063(3) Uani 1 1 d .
H19 H 0.9436 0.7297 0.4631 0.075 Uiso 1 1 calc R
C20 C 0.6657(9) 0.7257(7) 0.2992(5) 0.062(3) Uani 1 1 d .
H20 H 0.5694 0.7396 0.2728 0.075 Uiso 1 1 calc R
C21 C 0.9446(9) 0.6868(7) 0.3706(5) 0.065(3) Uani 1 1 d .
H21 H 1.0415 0.6755 0.3954 0.077 Uiso 1 1 calc R
C22 C 0.7300(9) 0.6892(6) 0.2631(5) 0.055(2) Uani 1 1 d .
H22 H 0.6743 0.6778 0.2119 0.066 Uiso 1 1 calc R
O1W O 0.422(2) 0.9324(16) 0.2487(10) 0.417(14) Uani 1 1 d .
H1WA H 0.4438 0.8855 0.2797 0.501 Uiso 1 1 d R
H1WB H 0.4647 0.9839 0.2734 0.501 Uiso 1 1 d R
O2W O 0.851(8) 0.950(6) 0.030(5) 1.27(3) Uani 1 1 d U
H2WA H 0.8232 1.0080 0.0135 1.518 Uiso 1 1 d R
H2WB H 0.9351 0.9504 0.0388 1.518 Uiso 1 1 d R
O3W O 0.170(5) 0.957(3) 0.095(3) 0.81(2) Uani 1 1 d U
H3WA H 0.1781 0.9483 0.1376 0.978 Uiso 1 1 d R
H3WB H 0.2562 0.9655 0.1082 0.978 Uiso 1 1 d R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O3 Eu1 O2 75.16(15) 3_676 3_676
O3 Eu1 O6 133.14(17) 3_676 .
O2 Eu1 O6 72.70(15) 3_676 .
O3 Eu1 O5 74.41(17) 3_676 .
O2 Eu1 O5 83.15(15) 3_676 .
O6 Eu1 O5 132.79(16) . .
O3 Eu1 O8 72.00(17) 3_676 .
O2 Eu1 O8 86.68(16) 3_676 .
O6 Eu1 O8 72.95(17) . .
O5 Eu1 O8 146.37(16) . .
O3 Eu1 O7 107.83(18) 3_676 .
O2 Eu1 O7 132.50(15) 3_676 .
O6 Eu1 O7 72.55(17) . .
O5 Eu1 O7 144.21(16) . .
O8 Eu1 O7 52.59(16) . .
O3 Eu1 O1 149.52(15) 3_676 .
O2 Eu1 O1 123.13(13) 3_676 .
O6 Eu1 O1 77.33(15) . .
O5 Eu1 O1 83.38(14) . .
O8 Eu1 O1 128.26(14) . .
O7 Eu1 O1 78.60(14) . .
O3 Eu1 O2 133.46(15) 3_676 .
O2 Eu1 O2 73.40(15) 3_676 .
O6 Eu1 O2 65.94(15) . .
O5 Eu1 O2 68.55(14) . .
O8 Eu1 O2 137.95(16) . .
O7 Eu1 O2 118.70(15) . .
O1 Eu1 O2 50.29(12) . .
O3 Eu1 N3 77.54(16) 3_676 2_746
O2 Eu1 N3 148.67(16) 3_676 2_746
O6 Eu1 N3 138.50(16) . 2_746
O5 Eu1 N3 74.91(17) . 2_746
O8 Eu1 N3 99.29(18) . 2_746
O7 Eu1 N3 70.99(18) . 2_746
O1 Eu1 N3 76.68(15) . 2_746
O2 Eu1 N3 117.05(16) . 2_746
O3 Eu1 Eu1 107.27(12) 3_676 3_676
O2 Eu1 Eu1 38.72(10) 3_676 3_676
O6 Eu1 Eu1 63.73(11) . 3_676
O5 Eu1 Eu1 71.97(11) . 3_676
O8 Eu1 Eu1 116.76(12) . 3_676
O7 Eu1 Eu1 135.61(13) . 3_676
O1 Eu1 Eu1 84.69(9) . 3_676
O2 Eu1 Eu1 34.68(9) . 3_676
N3 Eu1 Eu1 143.52(13) 2_746 3_676
O4 Cd1 N1 101.17(17) 2_746 .
O4 Cd1 N2 72.27(17) 2_746 2_746
N1 Cd1 N2 171.17(18) . 2_746
O4 Cd1 N4 90.26(19) 2_746 1_655
N1 Cd1 N4 92.81(19) . 1_655
N2 Cd1 N4 93.12(19) 2_746 1_655
O4 Cd1 O1 173.01(15) 2_746 .
N1 Cd1 O1 72.02(15) . .
N2 Cd1 O1 114.66(16) 2_746 .
N4 Cd1 O1 88.51(16) 1_655 .
O4 Cd1 N5 94.6(2) 2_746 4_576
N1 Cd1 N5 92.5(2) . 4_576
N2 Cd1 N5 82.3(2) 2_746 4_576
N4 Cd1 N5 171.9(2) 1_655 4_576
O1 Cd1 N5 87.41(18) . 4_576
C1 O1 Cd1 114.3(3) . .
C1 O1 Eu1 94.5(3) . .
Cd1 O1 Eu1 150.99(18) . .
C1 O2 Eu1 153.8(4) . 3_676
C1 O2 Eu1 93.9(3) . .
Eu1 O2 Eu1 106.60(15) 3_676 .
C4 O3 Eu1 151.6(5) . 3_676
C4 O4 Cd1 119.2(4) . 2_756
C11 O5 Eu1 127.2(4) . .
C11 O6 Eu1 141.5(4) 3_676 .
C17 O7 Eu1 92.2(4) . .
C17 O8 Eu1 92.5(4) . .
C5 N1 C2 105.6(5) . .
C5 N1 Cd1 140.3(4) . .
C2 N1 Cd1 114.1(4) . .
C5 N2 C3 105.6(5) . .
C5 N2 Cd1 139.5(4) . 2_756
C3 N2 Cd1 114.2(4) . 2_756
C10 N3 C7 116.1(6) . .
C10 N3 Eu1 125.3(5) . 2_756
C7 N3 Eu1 117.1(4) . 2_756
C16 N4 C15 116.4(6) . .
C16 N4 Cd1 124.4(5) . 1_455
C15 N4 Cd1 118.0(5) . 1_455
C22 N5 C21 116.7(7) . .
C22 N5 Cd1 124.4(5) . 4_575
C21 N5 Cd1 117.0(5) . 4_575
O2 C1 O1 119.3(5) . .
O2 C1 C2 121.8(5) . .
O1 C1 C2 118.9(5) . .
N1 C2 C3 108.2(5) . .
N1 C2 C1 119.1(5) . .
C3 C2 C1 132.7(5) . .
N2 C3 C2 107.8(5) . .
N2 C3 C4 116.7(5) . .
C2 C3 C4 135.1(5) . .
O3 C4 O4 123.3(6) . .
O3 C4 C3 119.0(6) . .
O4 C4 C3 117.4(5) . .
N1 C5 N2 112.8(5) . .
N1 C5 C6 126.4(6) . .
N2 C5 C6 120.5(6) . .
C7 C6 C8 117.1(6) . .
C7 C6 C5 119.2(6) . .
C8 C6 C5 123.4(6) . .
N3 C7 C6 125.3(6) . .
N3 C7 H7 117.3 . .
C6 C7 H7 117.3 . .
C9 C8 C6 119.1(7) . .
C9 C8 H8 120.4 . .
C6 C8 H8 120.4 . .
C8 C9 C10 119.2(7) . .
C8 C9 H9 120.4 . .
C10 C9 H9 120.4 . .
N3 C10 C9 123.0(7) . .
N3 C10 H10 118.5 . .
C9 C10 H10 118.5 . .
O5 C11 O6 126.0(6) . 3_676
O5 C11 C12 118.6(6) . .
O6 C11 C12 115.5(6) 3_676 .
C14 C12 C13 116.4(6) . .
C14 C12 C11 123.6(6) . .
C13 C12 C11 119.9(6) . .
C15 C13 C12 119.9(7) . .
C15 C13 H13 120.1 . .
C12 C13 H13 120.1 . .
C12 C14 C16 120.8(7) . .
C12 C14 H14 119.6 . .
C16 C14 H14 119.6 . .
N4 C15 C13 123.1(7) . .
N4 C15 H15 118.5 . .
C13 C15 H15 118.5 . .
N4 C16 C14 123.3(7) . .
N4 C16 H16 118.3 . .
C14 C16 H16 118.3 . .
O7 C17 O8 122.7(7) . .
O7 C17 C18 118.6(7) . .
O8 C17 C18 118.7(7) . .
C19 C18 C20 118.6(7) . .
C19 C18 C17 120.6(7) . .
C20 C18 C17 120.8(7) . .
C18 C19 C21 119.0(8) . .
C18 C19 H19 120.5 . .
C21 C19 H19 120.5 . .
C22 C20 C18 118.8(8) . .
C22 C20 H20 120.6 . .
C18 C20 H20 120.6 . .
N5 C21 C19 123.0(8) . .
N5 C21 H21 118.5 . .
C19 C21 H21 118.5 . .
N5 C22 C20 123.9(8) . .
N5 C22 H22 118.0 . .
C20 C22 H22 118.0 . .
H1WA O1W H1WB 107.7 . .
H2WA O2W H2WB 101.8 . .
H3WA O3W H3WB 101.3 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O3 2.285(4) 3_676
Eu1 O2 2.353(4) 3_676
Eu1 O6 2.402(5) .
Eu1 O5 2.448(4) .
Eu1 O8 2.474(5) .
Eu1 O7 2.486(5) .
Eu1 O1 2.569(4) .
Eu1 O2 2.587(4) .
Eu1 N3 2.588(6) 2_746
Cd1 O4 2.274(4) 2_746
Cd1 N1 2.293(5) .
Cd1 N2 2.304(5) 2_746
Cd1 N4 2.375(6) 1_655
Cd1 O1 2.383(4) .
Cd1 N5 2.388(6) 4_576
O1 C1 1.275(7) .
O2 C1 1.264(6) .
O2 Eu1 2.353(4) 3_676
O3 C4 1.249(7) .
O3 Eu1 2.285(4) 3_676
O4 C4 1.252(7) .
O4 Cd1 2.274(4) 2_756
O5 C11 1.254(8) .
O6 C11 1.267(8) 3_676
O7 C17 1.247(8) .
O8 C17 1.256(8) .
N1 C5 1.340(7) .
N1 C2 1.376(7) .
N2 C5 1.357(8) .
N2 C3 1.371(7) .
N2 Cd1 2.304(5) 2_756
N3 C10 1.324(9) .
N3 C7 1.346(7) .
N3 Eu1 2.588(6) 2_756
N4 C16 1.331(9) .
N4 C15 1.336(8) .
N4 Cd1 2.375(6) 1_455
N5 C22 1.327(9) .
N5 C21 1.340(9) .
N5 Cd1 2.388(6) 4_575
C1 C2 1.459(8) .
C2 C3 1.397(8) .
C3 C4 1.503(8) .
C5 C6 1.481(8) .
C6 C7 1.359(9) .
C6 C8 1.386(9) .
C7 H7 0.9300 .
C8 C9 1.368(10) .
C8 H8 0.9300 .
C9 C10 1.384(11) .
C9 H9 0.9300 .
C10 H10 0.9300 .
C11 O6 1.267(8) 3_676
C11 C12 1.500(8) .
C12 C14 1.363(9) .
C12 C13 1.385(9) .
C13 C15 1.374(9) .
C13 H13 0.9300 .
C14 C16 1.365(9) .
C14 H14 0.9300 .
C15 H15 0.9300 .
C16 H16 0.9300 .
C17 C18 1.521(10) .
C18 C19 1.357(10) .
C18 C20 1.381(10) .
C19 C21 1.386(10) .
C19 H19 0.9300 .
C20 C22 1.368(10) .
C20 H20 0.9300 .
C21 H21 0.9300 .
C22 H22 0.9300 .
O1W H1WA 0.8501 .
O1W H1WB 0.8500 .
O2W H2WA 0.8497 .
O2W H2WB 0.8519 .
O3W H3WA 0.8512 .
O3W H3WB 0.8515 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 Cd1 O1 C1 -10.9(4) . .
N2 Cd1 O1 C1 162.9(4) 2_746 .
N4 Cd1 O1 C1 -104.3(4) 1_655 .
N5 Cd1 O1 C1 82.6(4) 4_576 .
N1 Cd1 O1 Eu1 162.5(4) . .
N2 Cd1 O1 Eu1 -23.7(4) 2_746 .
N4 Cd1 O1 Eu1 69.1(4) 1_655 .
N5 Cd1 O1 Eu1 -104.0(4) 4_576 .
O3 Eu1 O1 C1 -118.5(4) 3_676 .
O2 Eu1 O1 C1 1.9(4) 3_676 .
O6 Eu1 O1 C1 61.2(3) . .
O5 Eu1 O1 C1 -75.4(3) . .
O8 Eu1 O1 C1 117.1(4) . .
O7 Eu1 O1 C1 135.6(4) . .
O2 Eu1 O1 C1 -7.9(3) . .
N3 Eu1 O1 C1 -151.4(4) 2_746 .
Eu1 Eu1 O1 C1 -3.0(3) 3_676 .
O3 Eu1 O1 Cd1 67.5(5) 3_676 .
O2 Eu1 O1 Cd1 -172.1(3) 3_676 .
O6 Eu1 O1 Cd1 -112.8(4) . .
O5 Eu1 O1 Cd1 110.6(4) . .
O8 Eu1 O1 Cd1 -56.8(4) . .
O7 Eu1 O1 Cd1 -38.3(4) . .
O2 Eu1 O1 Cd1 178.1(4) . .
N3 Eu1 O1 Cd1 34.6(4) 2_746 .
Eu1 Eu1 O1 Cd1 -177.0(4) 3_676 .
O3 Eu1 O2 C1 147.1(3) 3_676 .
O2 Eu1 O2 C1 -163.5(4) 3_676 .
O6 Eu1 O2 C1 -85.4(4) . .
O5 Eu1 O2 C1 107.5(4) . .
O8 Eu1 O2 C1 -98.3(4) . .
O7 Eu1 O2 C1 -33.6(4) . .
O1 Eu1 O2 C1 8.0(3) . .
N3 Eu1 O2 C1 48.5(4) 2_746 .
Eu1 Eu1 O2 C1 -163.5(4) 3_676 .
O3 Eu1 O2 Eu1 -49.4(3) 3_676 3_676
O2 Eu1 O2 Eu1 0.0 3_676 3_676
O6 Eu1 O2 Eu1 78.07(18) . 3_676
O5 Eu1 O2 Eu1 -89.05(18) . 3_676
O8 Eu1 O2 Eu1 65.1(3) . 3_676
O7 Eu1 O2 Eu1 129.83(17) . 3_676
O1 Eu1 O2 Eu1 171.4(2) . 3_676
N3 Eu1 O2 Eu1 -148.07(17) 2_746 3_676
O3 Eu1 O5 C11 -92.4(6) 3_676 .
O2 Eu1 O5 C11 -15.9(5) 3_676 .
O6 Eu1 O5 C11 42.8(6) . .
O8 Eu1 O5 C11 -89.3(6) . .
O7 Eu1 O5 C11 168.6(5) . .
O1 Eu1 O5 C11 108.7(5) . .
O2 Eu1 O5 C11 58.9(5) . .
N3 Eu1 O5 C11 -173.4(6) 2_746 .
Eu1 Eu1 O5 C11 22.1(5) 3_676 .
O3 Eu1 O6 C11 55.8(8) 3_676 3_676
O2 Eu1 O6 C11 7.1(7) 3_676 3_676
O5 Eu1 O6 C11 -55.6(8) . 3_676
O8 Eu1 O6 C11 98.9(7) . 3_676
O7 Eu1 O6 C11 154.2(8) . 3_676
O1 Eu1 O6 C11 -124.0(7) . 3_676
O2 Eu1 O6 C11 -72.0(7) . 3_676
N3 Eu1 O6 C11 -176.4(7) 2_746 3_676
Eu1 Eu1 O6 C11 -33.7(7) 3_676 3_676
O3 Eu1 O7 C17 50.1(5) 3_676 .
O2 Eu1 O7 C17 -35.9(6) 3_676 .
O6 Eu1 O7 C17 -80.6(5) . .
O5 Eu1 O7 C17 138.0(5) . .
O8 Eu1 O7 C17 1.0(5) . .
O1 Eu1 O7 C17 -160.7(5) . .
O2 Eu1 O7 C17 -129.3(5) . .
N3 Eu1 O7 C17 119.6(5) 2_746 .
Eu1 Eu1 O7 C17 -90.7(5) 3_676 .
O3 Eu1 O8 C17 -131.8(5) 3_676 .
O2 Eu1 O8 C17 152.7(5) 3_676 .
O6 Eu1 O8 C17 79.8(5) . .
O5 Eu1 O8 C17 -134.9(5) . .
O7 Eu1 O8 C17 -1.0(5) . .
O1 Eu1 O8 C17 22.0(5) . .
O2 Eu1 O8 C17 92.1(5) . .
N3 Eu1 O8 C17 -58.3(5) 2_746 .
Eu1 Eu1 O8 C17 127.5(4) 3_676 .
O4 Cd1 N1 C5 2.6(7) 2_746 .
N4 Cd1 N1 C5 -88.2(7) 1_655 .
O1 Cd1 N1 C5 -175.8(7) . .
N5 Cd1 N1 C5 97.8(7) 4_576 .
O4 Cd1 N1 C2 -175.1(4) 2_746 .
N4 Cd1 N1 C2 94.0(4) 1_655 .
O1 Cd1 N1 C2 6.5(4) . .
N5 Cd1 N1 C2 -79.9(4) 4_576 .
Eu1 O2 C1 O1 -156.2(6) 3_676 .
Eu1 O2 C1 O1 -14.3(6) . .
Eu1 O2 C1 C2 21.3(13) 3_676 .
Eu1 O2 C1 C2 163.3(5) . .
Cd1 O1 C1 O2 -168.8(4) . .
Eu1 O1 C1 O2 14.4(6) . .
Cd1 O1 C1 C2 13.6(7) . .
Eu1 O1 C1 C2 -163.2(5) . .
C5 N1 C2 C3 1.5(7) . .
Cd1 N1 C2 C3 180.0(4) . .
C5 N1 C2 C1 179.0(5) . .
Cd1 N1 C2 C1 -2.5(7) . .
O2 C1 C2 N1 174.5(5) . .
O1 C1 C2 N1 -7.9(8) . .
O2 C1 C2 C3 -8.7(11) . .
O1 C1 C2 C3 168.9(6) . .
C5 N2 C3 C2 3.6(7) . .
Cd1 N2 C3 C2 176.0(4) 2_756 .
C5 N2 C3 C4 -170.1(6) . .
Cd1 N2 C3 C4 2.3(7) 2_756 .
N1 C2 C3 N2 -3.2(7) . .
C1 C2 C3 N2 179.8(6) . .
N1 C2 C3 C4 168.8(7) . .
C1 C2 C3 C4 -8.3(12) . .
Eu1 O3 C4 O4 -136.7(8) 3_676 .
Eu1 O3 C4 C3 48.5(12) 3_676 .
Cd1 O4 C4 O3 -169.1(5) 2_756 .
Cd1 O4 C4 C3 5.8(8) 2_756 .
N2 C3 C4 O3 169.7(6) . .
C2 C3 C4 O3 -1.7(11) . .
N2 C3 C4 O4 -5.4(9) . .
C2 C3 C4 O4 -176.8(7) . .
C2 N1 C5 N2 0.8(7) . .
Cd1 N1 C5 N2 -177.0(4) . .
C2 N1 C5 C6 -172.8(6) . .
Cd1 N1 C5 C6 9.4(11) . .
C3 N2 C5 N1 -2.8(7) . .
Cd1 N2 C5 N1 -172.1(5) 2_756 .
C3 N2 C5 C6 171.2(6) . .
Cd1 N2 C5 C6 2.0(10) 2_756 .
N1 C5 C6 C7 -155.3(7) . .
N2 C5 C6 C7 31.6(9) . .
N1 C5 C6 C8 30.9(11) . .
N2 C5 C6 C8 -142.3(7) . .
C10 N3 C7 C6 -3.6(11) . .
Eu1 N3 C7 C6 163.4(5) 2_756 .
C8 C6 C7 N3 4.0(11) . .
C5 C6 C7 N3 -170.2(6) . .
C7 C6 C8 C9 -1.4(12) . .
C5 C6 C8 C9 172.5(8) . .
C6 C8 C9 C10 -1.1(14) . .
C7 N3 C10 C9 0.6(13) . .
Eu1 N3 C10 C9 -165.1(7) 2_756 .
C8 C9 C10 N3 1.6(15) . .
Eu1 O5 C11 O6 -12.5(10) . 3_676
Eu1 O5 C11 C12 167.8(4) . .
O5 C11 C12 C14 3.6(10) . .
O6 C11 C12 C14 -176.1(7) 3_676 .
O5 C11 C12 C13 -176.6(7) . .
O6 C11 C12 C13 3.7(9) 3_676 .
C14 C12 C13 C15 1.7(11) . .
C11 C12 C13 C15 -178.1(7) . .
C13 C12 C14 C16 -2.9(11) . .
C11 C12 C14 C16 176.9(7) . .
C16 N4 C15 C13 -2.4(11) . .
Cd1 N4 C15 C13 165.7(6) 1_455 .
C12 C13 C15 N4 1.0(12) . .
C15 N4 C16 C14 1.2(12) . .
Cd1 N4 C16 C14 -166.1(6) 1_455 .
C12 C14 C16 N4 1.5(13) . .
Eu1 O7 C17 O8 -1.9(8) . .
Eu1 O7 C17 C18 179.8(6) . .
Eu1 O8 C17 O7 1.9(8) . .
Eu1 O8 C17 C18 -179.8(6) . .
O7 C17 C18 C19 -11.1(12) . .
O8 C17 C18 C19 170.4(8) . .
O7 C17 C18 C20 170.5(8) . .
O8 C17 C18 C20 -7.9(12) . .
C20 C18 C19 C21 1.3(14) . .
C17 C18 C19 C21 -177.1(9) . .
C19 C18 C20 C22 0.4(14) . .
C17 C18 C20 C22 178.9(8) . .
C22 N5 C21 C19 2.0(14) . .
Cd1 N5 C21 C19 167.0(8) 4_575 .
C18 C19 C21 N5 -2.7(15) . .
C21 N5 C22 C20 -0.1(13) . .
Cd1 N5 C22 C20 -163.8(7) 4_575 .
C18 C20 C22 N5 -1.1(15) . .
