#------------------------------------------------------------------------------
#$Date: 2016-03-24 03:00:20 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179608 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/72/4507263.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4507263
loop_
_publ_author_name
'Yang, Guang'
'Baran, Peter'
'Martínez, Angel R.'
'Raptis, Raphael G.'
_publ_section_title
;
 Substituent Effects on the Supramolecular Aggregation of AgI-Pyrazolato
 Trimers
;
_journal_issue                   1
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              264
_journal_paper_doi               10.1021/cg301411j
_journal_volume                  13
_journal_year                    2013
_chemical_formula_sum            'C21 H30 Ag3 Br3 N6'
_chemical_formula_weight         929.85
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                113.598(10)
_cell_angle_beta                 100.645(13)
_cell_angle_gamma                101.305(13)
_cell_formula_units_Z            2
_cell_length_a                   11.144(18)
_cell_length_b                   11.983(9)
_cell_length_c                   13.076(10)
_cell_measurement_temperature    298(2)
_cell_volume                     1500(3)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.940
_diffrn_measured_fraction_theta_max 0.940
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0287
_diffrn_reflns_av_sigmaI/netI    0.0677
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            9676
_diffrn_reflns_theta_full        27.00
_diffrn_reflns_theta_max         27.00
_diffrn_reflns_theta_min         1.94
_exptl_absorpt_coefficient_mu    5.953
_exptl_absorpt_correction_T_max  0.6474
_exptl_absorpt_correction_T_min  0.4138
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.058
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             888
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.839
_refine_diff_density_min         -1.095
_refine_diff_density_rms         0.148
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.107
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     307
_refine_ls_number_reflns         6167
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.107
_refine_ls_R_factor_all          0.1003
_refine_ls_R_factor_gt           0.0526
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0672P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1324
_refine_ls_wR_factor_ref         0.1506
_reflns_number_gt                3733
_reflns_number_total             6167
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg301411j_si_007.cif
_cod_data_source_block           am106-New
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4507263
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.17494(5) 0.93687(6) 0.54353(6) 0.0558(2) Uani 1 1 d .
Ag2 Ag 0.25405(6) 1.15804(7) 0.44106(6) 0.0580(2) Uani 1 1 d .
Ag3 Ag -0.02264(6) 0.91609(6) 0.29694(6) 0.0549(2) Uani 1 1 d .
Br1 Br 0.75569(8) 1.20048(11) 0.74541(10) 0.0784(3) Uani 1 1 d .
Br2 Br -0.20441(15) 0.41230(12) 0.32718(14) 0.1237(6) Uani 1 1 d .
Br3 Br -0.04705(11) 1.22524(12) 0.02912(11) 0.0880(4) Uani 1 1 d .
C1 C 0.5204(7) 1.1931(8) 0.5998(8) 0.059(2) Uani 1 1 d .
H1 H 0.5653 1.2466 0.5752 0.070 Uiso 1 1 calc R
C2 C 0.5747(7) 1.1539(8) 0.6790(7) 0.053(2) Uani 1 1 d .
C3 C 0.4732(6) 1.0768(7) 0.6964(7) 0.047(2) Uani 1 1 d .
C4 C 0.4739(7) 1.0149(8) 0.7779(8) 0.057(2) Uani 1 1 d .
C5 C 0.5341(11) 1.1256(12) 0.9069(11) 0.108(4) Uani 1 1 d .
H5A H 0.6173 1.1750 0.9147 0.163 Uiso 1 1 calc R
H5B H 0.5417 1.0894 0.9605 0.163 Uiso 1 1 calc R
H5C H 0.4799 1.1797 0.9238 0.163 Uiso 1 1 calc R
C6 C 0.3404(11) 0.9496(13) 0.7763(13) 0.123(5) Uani 1 1 d .
H6A H 0.2896 1.0071 0.7856 0.184 Uiso 1 1 calc R
H6B H 0.3478 0.9265 0.8390 0.184 Uiso 1 1 calc R
H6C H 0.3003 0.8742 0.7032 0.184 Uiso 1 1 calc R
C7 C 0.5461(16) 0.9171(15) 0.7510(15) 0.165(8) Uani 1 1 d .
H7A H 0.5018 0.8472 0.6750 0.248 Uiso 1 1 calc R
H7B H 0.5515 0.8861 0.8084 0.248 Uiso 1 1 calc R
H7C H 0.6307 0.9559 0.7523 0.248 Uiso 1 1 calc R
C8 C -0.0315(8) 0.6724(9) 0.4575(9) 0.073(3) Uani 1 1 d .
H8 H 0.0056 0.6572 0.5186 0.087 Uiso 1 1 calc R
C9 C -0.1307(8) 0.5861(8) 0.3586(8) 0.063(2) Uani 1 1 d .
C10 C -0.1556(7) 0.6436(7) 0.2860(8) 0.053(2) Uani 1 1 d .
C11 C -0.2526(8) 0.5908(8) 0.1663(8) 0.061(2) Uani 1 1 d .
C12 C -0.2143(15) 0.4931(13) 0.0744(11) 0.144(6) Uani 1 1 d .
H12A H -0.1312 0.5313 0.0722 0.217 Uiso 1 1 calc R
H12B H -0.2755 0.4621 -0.0003 0.217 Uiso 1 1 calc R
H12C H -0.2116 0.4233 0.0925 0.217 Uiso 1 1 calc R
C13 C -0.3936(10) 0.5357(15) 0.1732(13) 0.139(6) Uani 1 1 d .
H13A H -0.3940 0.4698 0.1973 0.209 Uiso 1 1 calc R
H13B H -0.4546 0.5011 0.0978 0.209 Uiso 1 1 calc R
H13C H -0.4160 0.6034 0.2286 0.209 Uiso 1 1 calc R
C14 C -0.2677(12) 0.6961(11) 0.1275(10) 0.106(4) Uani 1 1 d .
H14A H -0.2773 0.7671 0.1906 0.159 Uiso 1 1 calc R
H14B H -0.3420 0.6617 0.0612 0.159 Uiso 1 1 calc R
H14C H -0.1932 0.7242 0.1069 0.159 Uiso 1 1 calc R
C15 C -0.0455(8) 1.0645(8) 0.1486(8) 0.056(2) Uani 1 1 d .
H15 H -0.1210 1.0043 0.0940 0.067 Uiso 1 1 calc R
C16 C 0.0169(8) 1.1773(8) 0.1457(8) 0.057(2) Uani 1 1 d .
C17 C 0.1283(7) 1.2393(8) 0.2444(8) 0.053(2) Uani 1 1 d .
C18 C 0.2302(8) 1.3687(10) 0.2859(10) 0.075(3) Uani 1 1 d .
C19 C 0.3352(9) 1.4010(11) 0.3964(12) 0.116(5) Uani 1 1 d .
H19A H 0.2975 1.4047 0.4576 0.175 Uiso 1 1 calc R
H19B H 0.3961 1.4821 0.4206 0.175 Uiso 1 1 calc R
H19C H 0.3778 1.3362 0.3802 0.175 Uiso 1 1 calc R
C20 C 0.2931(11) 1.3593(16) 0.1901(14) 0.149(7) Uani 1 1 d .
H20A H 0.3838 1.3776 0.2206 0.224 Uiso 1 1 calc R
H20B H 0.2768 1.4199 0.1628 0.224 Uiso 1 1 calc R
H20C H 0.2585 1.2747 0.1266 0.224 Uiso 1 1 calc R
C21 C 0.1666(11) 1.4763(10) 0.3141(14) 0.120(5) Uani 1 1 d .
H21A H 0.0992 1.4572 0.2466 0.180 Uiso 1 1 calc R
H21B H 0.2293 1.5556 0.3359 0.180 Uiso 1 1 calc R
H21C H 0.1317 1.4833 0.3775 0.180 Uiso 1 1 calc R
N1 N 0.3621(5) 1.0714(6) 0.6245(6) 0.0513(17) Uani 1 1 d .
N2 N 0.3924(6) 1.1412(6) 0.5642(6) 0.0526(18) Uani 1 1 d .
N3 N 0.1281(6) 1.1645(7) 0.3007(7) 0.0584(19) Uani 1 1 d .
N4 N 0.0197(6) 1.0569(6) 0.2412(6) 0.0547(18) Uani 1 1 d .
N5 N -0.0725(6) 0.7657(6) 0.3435(6) 0.0495(16) Uani 1 1 d .
N6 N 0.0025(6) 0.7851(6) 0.4494(6) 0.0566(18) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
N6 Ag1 N1 171.7(3) .
N6 Ag1 Ag3 87.5(2) 2_576
N1 Ag1 Ag3 100.6(2) 2_576
N2 Ag2 N3 172.3(3) .
N4 Ag3 N5 176.7(3) .
N4 Ag3 Ag1 92.2(2) 2_576
N5 Ag3 Ag1 89.05(19) 2_576
N2 C1 C2 109.2(7) .
N2 C1 H1 125.4 .
C2 C1 H1 125.4 .
C1 C2 C3 107.8(7) .
C1 C2 Br1 122.5(6) .
C3 C2 Br1 129.7(6) .
N1 C3 C2 105.3(7) .
N1 C3 C4 123.2(6) .
C2 C3 C4 131.5(7) .
C7 C4 C6 107.7(10) .
C7 C4 C3 111.8(8) .
C6 C4 C3 114.1(7) .
C7 C4 C5 111.9(10) .
C6 C4 C5 103.8(10) .
C3 C4 C5 107.2(8) .
C4 C5 H5A 109.5 .
C4 C5 H5B 109.5 .
H5A C5 H5B 109.5 .
C4 C5 H5C 109.5 .
H5A C5 H5C 109.5 .
H5B C5 H5C 109.5 .
C4 C6 H6A 109.5 .
C4 C6 H6B 109.5 .
H6A C6 H6B 109.5 .
C4 C6 H6C 109.5 .
H6A C6 H6C 109.5 .
H6B C6 H6C 109.5 .
C4 C7 H7A 109.5 .
C4 C7 H7B 109.5 .
H7A C7 H7B 109.5 .
C4 C7 H7C 109.5 .
H7A C7 H7C 109.5 .
H7B C7 H7C 109.5 .
N6 C8 C9 107.8(8) .
N6 C8 H8 126.1 .
C9 C8 H8 126.1 .
C8 C9 C10 108.6(8) .
C8 C9 Br2 122.9(7) .
C10 C9 Br2 128.2(7) .
N5 C10 C9 106.3(7) .
N5 C10 C11 123.3(7) .
C9 C10 C11 130.4(7) .
C12 C11 C10 110.7(8) .
C12 C11 C14 107.7(10) .
C10 C11 C14 113.1(7) .
C12 C11 C13 112.9(10) .
C10 C11 C13 109.3(8) .
C14 C11 C13 103.1(9) .
C11 C12 H12A 109.5 .
C11 C12 H12B 109.5 .
H12A C12 H12B 109.5 .
C11 C12 H12C 109.5 .
H12A C12 H12C 109.5 .
H12B C12 H12C 109.5 .
C11 C13 H13A 109.5 .
C11 C13 H13B 109.5 .
H13A C13 H13B 109.5 .
C11 C13 H13C 109.5 .
H13A C13 H13C 109.5 .
H13B C13 H13C 109.5 .
C11 C14 H14A 109.5 .
C11 C14 H14B 109.5 .
H14A C14 H14B 109.5 .
C11 C14 H14C 109.5 .
H14A C14 H14C 109.5 .
H14B C14 H14C 109.5 .
N4 C15 C16 110.2(8) .
N4 C15 H15 124.9 .
C16 C15 H15 124.9 .
C15 C16 C17 105.7(7) .
C15 C16 Br3 123.2(7) .
C17 C16 Br3 131.1(6) .
N3 C17 C16 107.2(7) .
N3 C17 C18 124.8(7) .
C16 C17 C18 128.0(8) .
C20 C18 C19 107.9(9) .
C20 C18 C17 108.5(10) .
C19 C18 C17 111.5(8) .
C20 C18 C21 111.1(10) .
C19 C18 C21 108.0(10) .
C17 C18 C21 109.8(8) .
C18 C19 H19A 109.5 .
C18 C19 H19B 109.5 .
H19A C19 H19B 109.5 .
C18 C19 H19C 109.5 .
H19A C19 H19C 109.5 .
H19B C19 H19C 109.5 .
C18 C20 H20A 109.5 .
C18 C20 H20B 109.5 .
H20A C20 H20B 109.5 .
C18 C20 H20C 109.5 .
H20A C20 H20C 109.5 .
H20B C20 H20C 109.5 .
C18 C21 H21A 109.5 .
C18 C21 H21B 109.5 .
H21A C21 H21B 109.5 .
C18 C21 H21C 109.5 .
H21A C21 H21C 109.5 .
H21B C21 H21C 109.5 .
C3 N1 N2 109.7(6) .
C3 N1 Ag1 133.2(5) .
N2 N1 Ag1 112.9(4) .
C1 N2 N1 107.9(6) .
C1 N2 Ag2 128.5(6) .
N1 N2 Ag2 123.6(4) .
C17 N3 N4 109.4(6) .
C17 N3 Ag2 137.6(5) .
N4 N3 Ag2 112.6(5) .
C15 N4 N3 107.6(6) .
C15 N4 Ag3 129.3(6) .
N3 N4 Ag3 123.1(5) .
C10 N5 N6 109.7(6) .
C10 N5 Ag3 134.3(6) .
N6 N5 Ag3 115.6(4) .
C8 N6 N5 107.5(6) .
C8 N6 Ag1 127.3(6) .
N5 N6 Ag1 121.9(5) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N6 2.116(7) .
Ag1 N1 2.138(6) .
Ag1 Ag3 3.142(3) 2_576
Ag2 N2 2.115(6) .
Ag2 N3 2.133(7) .
Ag3 N4 2.097(7) .
Ag3 N5 2.130(6) .
Ag3 Ag1 3.142(3) 2_576
Br1 C2 1.912(8) .
Br2 C9 1.923(9) .
Br3 C16 1.903(8) .
C1 N2 1.346(9) .
C1 C2 1.389(11) .
C1 H1 0.9300 .
C2 C3 1.428(10) .
C3 N1 1.382(9) .
C3 C4 1.523(11) .
C4 C7 1.513(14) .
C4 C6 1.530(13) .
C4 C5 1.580(14) .
C5 H5A 0.9600 .
C5 H5B 0.9600 .
C5 H5C 0.9600 .
C6 H6A 0.9600 .
C6 H6B 0.9600 .
C6 H6C 0.9600 .
C7 H7A 0.9600 .
C7 H7B 0.9600 .
C7 H7C 0.9600 .
C8 N6 1.381(11) .
C8 C9 1.385(12) .
C8 H8 0.9300 .
C9 C10 1.398(12) .
C10 N5 1.376(9) .
C10 C11 1.527(12) .
C11 C12 1.502(14) .
C11 C14 1.563(14) .
C11 C13 1.615(14) .
C12 H12A 0.9600 .
C12 H12B 0.9600 .
C12 H12C 0.9600 .
C13 H13A 0.9600 .
C13 H13B 0.9600 .
C13 H13C 0.9600 .
C14 H14A 0.9600 .
C14 H14B 0.9600 .
C14 H14C 0.9600 .
C15 N4 1.340(10) .
C15 C16 1.411(12) .
C15 H15 0.9300 .
C16 C17 1.427(11) .
C17 N3 1.369(10) .
C17 C18 1.548(12) .
C18 C20 1.521(17) .
C18 C19 1.536(14) .
C18 C21 1.542(15) .
C19 H19A 0.9600 .
C19 H19B 0.9600 .
C19 H19C 0.9600 .
C20 H20A 0.9600 .
C20 H20B 0.9600 .
C20 H20C 0.9600 .
C21 H21A 0.9600 .
C21 H21B 0.9600 .
C21 H21C 0.9600 .
N1 N2 1.396(9) .
N3 N4 1.403(9) .
N5 N6 1.381(9) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
N2 C1 C2 C3 -2.2(11) .
N2 C1 C2 Br1 177.1(6) .
C1 C2 C3 N1 1.1(10) .
Br1 C2 C3 N1 -178.2(6) .
C1 C2 C3 C4 -175.8(9) .
Br1 C2 C3 C4 4.8(15) .
N1 C3 C4 C7 120.6(11) .
C2 C3 C4 C7 -62.8(14) .
N1 C3 C4 C6 -1.9(13) .
C2 C3 C4 C6 174.6(11) .
N1 C3 C4 C5 -116.3(9) .
C2 C3 C4 C5 60.2(12) .
N6 C8 C9 C10 2.3(11) .
N6 C8 C9 Br2 176.8(7) .
C8 C9 C10 N5 -1.4(11) .
Br2 C9 C10 N5 -175.4(7) .
C8 C9 C10 C11 178.8(9) .
Br2 C9 C10 C11 4.7(15) .
N5 C10 C11 C12 109.1(11) .
C9 C10 C11 C12 -71.1(14) .
N5 C10 C11 C14 -11.8(13) .
C9 C10 C11 C14 168.0(10) .
N5 C10 C11 C13 -126.0(10) .
C9 C10 C11 C13 53.8(13) .
N4 C15 C16 C17 0.6(10) .
N4 C15 C16 Br3 -178.8(6) .
C15 C16 C17 N3 -0.2(10) .
Br3 C16 C17 N3 179.1(7) .
C15 C16 C17 C18 -178.3(9) .
Br3 C16 C17 C18 1.1(15) .
N3 C17 C18 C20 121.0(11) .
C16 C17 C18 C20 -61.3(13) .
N3 C17 C18 C19 2.3(14) .
C16 C17 C18 C19 -180.0(10) .
N3 C17 C18 C21 -117.4(11) .
C16 C17 C18 C21 60.3(14) .
C2 C3 N1 N2 0.3(9) .
C4 C3 N1 N2 177.6(7) .
C2 C3 N1 Ag1 155.0(6) .
C4 C3 N1 Ag1 -27.7(12) .
N6 Ag1 N1 C3 -65(2) .
Ag3 Ag1 N1 C3 104.5(8) 2_576
N6 Ag1 N1 N2 88.6(19) .
Ag3 Ag1 N1 N2 -101.4(5) 2_576
C2 C1 N2 N1 2.4(10) .
C2 C1 N2 Ag2 -178.1(6) .
C3 N1 N2 C1 -1.7(9) .
Ag1 N1 N2 C1 -161.9(6) .
C3 N1 N2 Ag2 178.8(5) .
Ag1 N1 N2 Ag2 18.6(8) .
N3 Ag2 N2 C1 58(2) .
N3 Ag2 N2 N1 -122.5(18) .
C16 C17 N3 N4 -0.2(9) .
C18 C17 N3 N4 177.9(8) .
C16 C17 N3 Ag2 172.2(7) .
C18 C17 N3 Ag2 -9.6(15) .
N2 Ag2 N3 C17 -77(2) .
N2 Ag2 N3 N4 95.0(19) .
C16 C15 N4 N3 -0.8(10) .
C16 C15 N4 Ag3 178.9(6) .
C17 N3 N4 C15 0.6(9) .
Ag2 N3 N4 C15 -173.9(5) .
C17 N3 N4 Ag3 -179.1(5) .
Ag2 N3 N4 Ag3 6.4(8) .
N5 Ag3 N4 C15 21(5) .
Ag1 Ag3 N4 C15 -91.2(7) 2_576
N5 Ag3 N4 N3 -159(4) .
Ag1 Ag3 N4 N3 88.4(6) 2_576
C9 C10 N5 N6 -0.1(9) .
C11 C10 N5 N6 179.8(8) .
C9 C10 N5 Ag3 171.5(6) .
C11 C10 N5 Ag3 -8.7(13) .
N4 Ag3 N5 C10 -5(5) .
Ag1 Ag3 N5 C10 107.3(7) 2_576
N4 Ag3 N5 N6 166(4) .
Ag1 Ag3 N5 N6 -81.5(5) 2_576
C9 C8 N6 N5 -2.3(10) .
C9 C8 N6 Ag1 -161.9(7) .
C10 N5 N6 C8 1.5(9) .
Ag3 N5 N6 C8 -171.8(6) .
C10 N5 N6 Ag1 162.5(5) .
Ag3 N5 N6 Ag1 -10.9(8) .
N1 Ag1 N6 C8 68(2) .
Ag3 Ag1 N6 C8 -101.9(8) 2_576
N1 Ag1 N6 N5 -88.7(19) .
Ag3 Ag1 N6 N5 101.1(6) 2_576
