#------------------------------------------------------------------------------
#$Date: 2016-03-24 03:07:40 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179614 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/78/4507831.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4507831
loop_
_publ_author_name
'Zhang, Han'
'Zhuang, Gui-Lin'
'Kong, Xiang-Jian'
'Ren, Yan-Ping'
'Long, La-Sheng'
'Huang, Rong-Bin'
'Zheng, Lan-Sun'
_publ_section_title
;
 Synthesis, Structures, and Magnetic Properties of Three Decanuclear
 Ln2Cu8Clusters of Alkylsulfonate
;
_journal_issue                   6
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              2493
_journal_paper_doi               10.1021/cg400206s
_journal_volume                  13
_journal_year                    2013
_chemical_formula_sum            'C28 H102 Cl2 Cu8 Dy2 N4 O63 S4'
_chemical_formula_weight         2535.60
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 109.51(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   16.119(3)
_cell_length_b                   13.126(3)
_cell_length_c                   19.973(4)
_cell_measurement_reflns_used    20344
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      55.12
_cell_measurement_theta_min      6.14
_cell_volume                     3983.2(16)
_computing_cell_refinement       RAPID-AUTO
_computing_data_collection       'RAPID-AUTO (Rigaku Corporation, 1998)'
_computing_data_reduction
'CrystalStructure (Rigaku/MSC and Rigaku Corporation, 2002)'
_computing_molecular_graphics    'SHELXL-97 (Sheldrick, 1997)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.989
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID'
_diffrn_measurement_method       'ω scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1144
_diffrn_reflns_av_sigmaI/netI    0.0914
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            29819
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         3.10
_exptl_absorpt_coefficient_mu    4.229
_exptl_absorpt_correction_T_max  0.4851
_exptl_absorpt_correction_T_min  0.4060
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'ABSCOR (Higashi, 1995)'
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    2.114
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2528
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.523
_refine_diff_density_min         -1.217
_refine_diff_density_rms         0.212
_refine_ls_extinction_coef       0.00226(16)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.083
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     587
_refine_ls_number_reflns         6940
_refine_ls_number_restraints     140
_refine_ls_restrained_S_all      1.075
_refine_ls_R_factor_all          0.0977
_refine_ls_R_factor_gt           0.0708
_refine_ls_shift/su_max          0.099
_refine_ls_shift/su_mean         0.004
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0924P)²+24.4605P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1777
_refine_ls_wR_factor_ref         0.2048
_reflns_number_gt                4919
_reflns_number_total             6940
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg400206s_si_004.cif
_cod_data_source_block           complex3
_cod_original_cell_volume        3983.3(14)
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               4507831
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Dy1 Dy 0.45972(2) 1.66127(3) -0.359472(18) 0.03913(11) Uani 1 1 d . . .
Cu1 Cu 0.38300(6) 1.41763(7) -0.39283(4) 0.0374(2) Uani 1 1 d . . .
Cu2 Cu 0.23927(6) 1.36663(8) -0.34321(5) 0.0393(2) Uani 1 1 d . A .
Cu3 Cu 0.34541(6) 1.53641(8) -0.26479(5) 0.0405(3) Uani 1 1 d . . .
Cu4 Cu 0.08140(6) 1.46259(9) -0.44932(5) 0.0521(3) Uani 1 1 d . . .
S1 S 0.42376(13) 1.70150(16) -0.55037(10) 0.0440(5) Uani 1 1 d . . .
S2 S 0.34661(17) 1.8884(2) -0.35711(17) 0.0739(8) Uani 1 1 d . . .
O1 O 0.3044(3) 1.4023(4) -0.2453(2) 0.0393(14) Uani 1 1 d . . .
O1W O 0.5819(3) 1.7706(5) -0.3459(3) 0.0526(16) Uani 1 1 d . . .
O2W O 0.5316(4) 1.6872(5) -0.2375(3) 0.0567(17) Uani 1 1 d . . .
O3W O 0.5831(4) 1.5514(5) -0.3484(3) 0.0584(17) Uani 1 1 d . . .
O4W O 0.4612(3) 1.5721(4) -0.1522(3) 0.0495(16) Uani 1 1 d . . .
O5W O 0.5848(5) 0.4869(5) -0.0149(4) 0.087(2) Uani 1 1 d . . .
O6W O 0.1302(14) 1.5083(18) -0.0001(11) 0.1341(8) Uani 0.50 1 d PU . .
O7W O 0.003(2) 1.401(3) -0.0975(18) 0.2233(8) Uani 0.50 1 d PU . .
O8W O 0.011(2) 1.270(3) -0.2346(19) 0.2352(8) Uani 0.50 1 d PU . .
O2 O 0.1513(3) 1.4677(5) -0.3501(3) 0.0481(16) Uani 1 1 d . . .
O3 O 0.2126(5) 1.5641(7) -0.1043(4) 0.095(3) Uani 1 1 d . . .
O4 O 0.3427(3) 1.6643(4) -0.3133(3) 0.0390(13) Uani 1 1 d . . .
O5 O 0.3870(4) 1.8160(5) -0.3931(4) 0.085(2) Uani 1 1 d . . .
O6 O 0.4071(6) 1.9244(8) -0.2897(6) 0.134(4) Uani 1 1 d . . .
O7 O 0.3043(5) 1.9686(5) -0.4073(5) 0.097(2) Uani 1 1 d . . .
O8 O 0.1784(3) 1.3757(4) -0.4439(3) 0.0463(15) Uani 1 1 d . . .
O9 O 0.3429(3) 1.2965(4) -0.3562(2) 0.0404(14) Uani 1 1 d . . .
O10 O 0.3603(3) 1.1697(4) -0.5437(3) 0.0483(16) Uani 1 1 d . . .
O11 O 0.3824(3) 1.5443(4) -0.4409(3) 0.0436(15) Uani 1 1 d . . .
O12 O 0.4701(4) 1.6539(5) -0.5951(3) 0.0535(17) Uani 1 1 d . . .
O13 O 0.4775(4) 1.7010(5) -0.4749(3) 0.0545(17) Uani 1 1 d . . .
O14 O 0.3917(4) 1.8038(4) -0.5759(3) 0.0531(17) Uani 1 1 d . . .
O15 O 0.4334(3) 1.4935(4) -0.3057(3) 0.0389(14) Uani 1 1 d . . .
H15A H 0.4874 1.4622 -0.2711 0.047 Uiso 1 1 calc R . .
O16 O 0.0168(4) 1.4519(5) -0.5501(3) 0.0599(19) Uani 1 1 d . . .
H16A H 0.0292 1.4164 -0.5871 0.072 Uiso 1 1 calc R . .
O17 O 0.1631(4) 1.2221(6) -0.3254(4) 0.083(2) Uani 1 1 d D . .
C1 C 0.3203(5) 1.2211(6) -0.4106(4) 0.043(2) Uani 1 1 d . . .
H1A H 0.2801 1.1708 -0.4007 0.051 Uiso 1 1 calc R . .
H1B H 0.3743 1.1846 -0.4100 0.051 Uiso 1 1 calc R . .
C2 C 0.2756(5) 1.2671(5) -0.4848(4) 0.0344(18) Uani 1 1 d . . .
C3 C 0.2740(5) 1.1907(7) -0.5426(4) 0.045(2) Uani 1 1 d . . .
H3A H 0.2465 1.1266 -0.5344 0.055 Uiso 1 1 calc R . .
H3B H 0.2376 1.2182 -0.5894 0.055 Uiso 1 1 calc R . .
C4 C 0.1831(5) 1.3008(6) -0.4947(4) 0.041(2) Uani 1 1 d . . .
H4A H 0.1566 1.3293 -0.5431 0.049 Uiso 1 1 calc R . .
H4B H 0.1479 1.2407 -0.4909 0.049 Uiso 1 1 calc R . .
C5 C 0.2962(5) 1.4408(6) -0.5378(4) 0.042(2) Uani 1 1 d . . .
H5A H 0.2390 1.4633 -0.5348 0.050 Uiso 1 1 calc R . .
H5B H 0.2877 1.4195 -0.5872 0.050 Uiso 1 1 calc R . .
C6 C 0.3647(6) 1.5260(7) -0.5145(4) 0.048(2) Uani 1 1 d . . .
H6A H 0.4202 1.5024 -0.5216 0.057 Uiso 1 1 calc R . .
C7 C 0.3341(5) 1.6268(6) -0.5572(4) 0.045(2) Uani 1 1 d . . .
H7A H 0.2934 1.6639 -0.5382 0.054 Uiso 1 1 calc R . .
H7B H 0.3024 1.6107 -0.6077 0.054 Uiso 1 1 calc R . .
C8 C 0.2498(5) 1.4181(7) -0.2025(4) 0.046(2) Uani 1 1 d . . .
H8A H 0.2876 1.4242 -0.1521 0.055 Uiso 1 1 calc R . .
H8B H 0.2113 1.3580 -0.2067 0.055 Uiso 1 1 calc R . .
C9 C 0.1917(5) 1.5152(7) -0.2245(4) 0.043(2) Uani 1 1 d . . .
C10 C 0.1492(6) 1.5397(8) -0.1681(4) 0.064(3) Uani 1 1 d . . .
H10A H 0.1081 1.5976 -0.1844 0.077 Uiso 1 1 calc R . .
H10B H 0.1152 1.4801 -0.1616 0.077 Uiso 1 1 calc R . .
C11 C 0.1196(5) 1.4980(7) -0.2932(4) 0.050(2) Uani 1 1 d . . .
H11A H 0.0798 1.4443 -0.2865 0.060 Uiso 1 1 calc R . .
H11B H 0.0848 1.5614 -0.3071 0.060 Uiso 1 1 calc R . .
C12 C 0.2219(6) 1.6874(7) -0.2720(5) 0.056(3) Uani 1 1 d . . .
H12A H 0.1978 1.7360 -0.2453 0.067 Uiso 1 1 calc R . .
H12B H 0.1743 1.6689 -0.3163 0.067 Uiso 1 1 calc R . .
C13 C 0.2960(5) 1.7354(7) -0.2891(5) 0.051(2) Uani 1 1 d . . .
H13A H 0.3374 1.7638 -0.2437 0.061 Uiso 1 1 calc R . .
C14 C 0.2643(6) 1.8225(7) -0.3385(5) 0.060(3) Uani 1 1 d . . .
H14A H 0.2322 1.8704 -0.3177 0.072 Uiso 1 1 calc R . .
H14B H 0.2221 1.7967 -0.3836 0.072 Uiso 1 1 calc R . .
N1 N 0.2547(4) 1.5946(6) -0.2285(3) 0.051(2) Uani 1 1 d . . .
H1C H 0.2838 1.6164 -0.1823 0.061 Uiso 1 1 calc R . .
N2 N 0.3331(4) 1.3576(4) -0.4881(3) 0.0365(16) Uani 1 1 d . . .
H2A H 0.3802 1.3316 -0.4997 0.044 Uiso 1 1 calc R . .
Cl1 Cl 0.1767(7) 1.1373(9) -0.2738(6) 0.2294(8) Uani 0.50 1 d PDU A 1
O18 O 0.2568(10) 1.0673(14) -0.2616(11) 0.1282(8) Uani 0.50 1 d PDU A 1
O19 O 0.138(3) 1.059(2) -0.3262(16) 0.3203(8) Uani 0.50 1 d PDU A 1
O20 O 0.1309(15) 1.157(3) -0.2212(12) 0.2242(8) Uani 0.50 1 d PDU A 1
Cl1' Cl 0.1346(4) 1.0206(6) -0.2230(4) 0.1145(8) Uani 0.50 1 d PDU B 2
O21 O 0.0687(8) 1.0448(12) -0.2890(6) 0.1398(8) Uani 0.50 1 d PDU B 2
O22 O 0.1489(10) 0.9124(7) -0.2204(9) 0.1428(8) Uani 0.50 1 d PDU B 2
O23 O 0.1058(9) 1.0469(14) -0.1641(6) 0.1927(8) Uani 0.50 1 d PDU B 2
O24 O 0.2177(7) 1.0686(12) -0.2164(9) 0.1636(6) Uani 0.50 1 d PDU B 2
O12W O 0.1709(10) 1.6272(12) -0.4685(8) 0.0829(8) Uani 0.50 1 d PU . .
O10W O 0.1274(14) 1.4504(18) 0.0665(12) 0.1392(8) Uani 0.50 1 d PU . .
O14W O -0.1044(16) 1.084(2) 0.1081(13) 0.1524(8) Uani 0.50 1 d PU . .
O9W' O -0.0114(17) 1.252(2) -0.1189(14) 0.1588(8) Uani 0.50 1 d PU . .
O9W O -0.0475(12) 1.2422(15) -0.0641(10) 0.1105(8) Uani 0.50 1 d PU . .
O15W O -0.0937(9) 1.2226(11) 0.0540(8) 0.1762(8) Uani 1 1 d U C 1
O13W O 0.0011(12) 1.2108(15) 0.0795(10) 0.1085(8) Uani 0.50 1 d PU D 2
O11W O -0.1287(17) 1.228(2) 0.1066(14) 0.1643(8) Uani 0.50 1 d PU E 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O11 Dy1 O5 106.2(2) . .
O11 Dy1 O2W 143.2(2) . .
O5 Dy1 O2W 101.5(3) . .
O11 Dy1 O4 88.41(19) . .
O5 Dy1 O4 73.0(2) . .
O2W Dy1 O4 76.92(19) . .
O11 Dy1 O1W 136.2(2) . .
O5 Dy1 O1W 79.9(2) . .
O2W Dy1 O1W 72.0(2) . .
O4 Dy1 O1W 133.23(19) . .
O11 Dy1 O3W 84.2(2) . .
O5 Dy1 O3W 150.5(2) . .
O2W Dy1 O3W 83.4(2) . .
O4 Dy1 O3W 135.9(2) . .
O1W Dy1 O3W 74.0(2) . .
O11 Dy1 O13 71.52(19) . .
O5 Dy1 O13 75.6(3) . .
O2W Dy1 O13 140.1(2) . .
O4 Dy1 O13 135.86(18) . .
O1W Dy1 O13 68.23(18) . .
O3W Dy1 O13 82.1(2) . .
O11 Dy1 O15 65.81(17) . .
O5 Dy1 O15 137.5(2) . .
O2W Dy1 O15 77.39(19) . .
O4 Dy1 O15 65.33(17) . .
O1W Dy1 O15 136.22(17) . .
O3W Dy1 O15 72.04(19) . .
O13 Dy1 O15 131.53(19) . .
O11 Dy1 Cu1 32.21(13) . .
O5 Dy1 Cu1 130.26(17) . .
O2W Dy1 Cu1 111.07(16) . .
O4 Dy1 Cu1 78.88(12) . .
O1W Dy1 Cu1 145.08(15) . .
O3W Dy1 Cu1 71.98(15) . .
O13 Dy1 Cu1 99.38(14) . .
O15 Dy1 Cu1 34.07(11) . .
O11 Dy1 Cu3 78.87(14) . .
O5 Dy1 Cu3 105.19(19) . .
O2W Dy1 Cu3 70.72(16) . .
O4 Dy1 Cu3 32.21(12) . .
O1W Dy1 Cu3 142.68(13) . .
O3W Dy1 Cu3 103.91(16) . .
O13 Dy1 Cu3 149.09(13) . .
O15 Dy1 Cu3 33.54(12) . .
Cu1 Dy1 Cu3 55.86(2) . .
O11 Cu1 O15 86.2(2) . .
O11 Cu1 O9 161.5(2) . .
O15 Cu1 O9 100.0(2) . .
O11 Cu1 N2 86.1(2) . .
O15 Cu1 N2 172.3(2) . .
O9 Cu1 N2 87.5(2) . .
O11 Cu1 Cu2 120.17(18) . .
O15 Cu1 Cu2 87.41(17) . .
O9 Cu1 Cu2 43.67(16) . .
N2 Cu1 Cu2 97.1(2) . .
O11 Cu1 Dy1 39.33(14) . .
O15 Cu1 Dy1 47.60(15) . .
O9 Cu1 Dy1 146.61(15) . .
N2 Cu1 Dy1 124.69(18) . .
Cu2 Cu1 Dy1 115.49(4) . .
O2 Cu2 O8 77.0(2) . .
O2 Cu2 O1 92.5(2) . .
O8 Cu2 O1 162.3(2) . .
O2 Cu2 O9 160.3(2) . .
O8 Cu2 O9 92.8(2) . .
O1 Cu2 O9 92.7(2) . .
O2 Cu2 O17 99.1(3) . .
O8 Cu2 O17 95.6(2) . .
O1 Cu2 O17 100.1(2) . .
O9 Cu2 O17 98.6(2) . .
O2 Cu2 Cu1 118.35(18) . .
O8 Cu2 Cu1 79.29(17) . .
O1 Cu2 Cu1 93.68(16) . .
O9 Cu2 Cu1 42.34(16) . .
O17 Cu2 Cu1 139.4(2) . .
O2 Cu2 Cu3 78.27(16) . .
O8 Cu2 Cu3 121.01(18) . .
O1 Cu2 Cu3 41.82(16) . .
O9 Cu2 Cu3 93.18(15) . .
O17 Cu2 Cu3 140.86(19) . .
Cu1 Cu2 Cu3 67.30(4) . .
O2 Cu2 Cu4 38.97(15) . .
O8 Cu2 Cu4 38.52(17) . .
O1 Cu2 Cu4 131.09(16) . .
O9 Cu2 Cu4 130.71(14) . .
O17 Cu2 Cu4 94.77(16) . .
Cu1 Cu2 Cu4 104.45(4) . .
Cu3 Cu2 Cu4 105.40(5) . .
O4 Cu3 O15 86.5(2) . .
O4 Cu3 O1 157.74(19) . .
O15 Cu3 O1 99.5(2) . .
O4 Cu3 N1 87.3(3) . .
O15 Cu3 N1 173.8(3) . .
O1 Cu3 N1 86.2(3) . .
O4 Cu3 Cu2 118.84(15) . .
O15 Cu3 Cu2 86.13(15) . .
O1 Cu3 Cu2 41.25(13) . .
N1 Cu3 Cu2 96.8(2) . .
O4 Cu3 Dy1 40.67(15) . .
O15 Cu3 Dy1 46.44(15) . .
O1 Cu3 Dy1 143.94(15) . .
N1 Cu3 Dy1 127.4(2) . .
Cu2 Cu3 Dy1 113.02(4) . .
O8 Cu4 O2 77.0(2) . .
O8 Cu4 O16 176.9(2) . 3_584
O2 Cu4 O16 100.5(2) . 3_584
O8 Cu4 O16 99.3(2) . .
O2 Cu4 O16 176.3(3) . .
O16 Cu4 O16 83.2(3) 3_584 .
O8 Cu4 Cu4 140.85(16) . 3_584
O2 Cu4 Cu4 142.08(18) . 3_584
O16 Cu4 Cu4 41.62(16) 3_584 3_584
O16 Cu4 Cu4 41.59(18) . 3_584
O8 Cu4 Cu2 38.87(15) . .
O2 Cu4 Cu2 38.64(17) . .
O16 Cu4 Cu2 138.40(17) 3_584 .
O16 Cu4 Cu2 137.74(19) . .
Cu4 Cu4 Cu2 174.21(7) 3_584 .
O13 S1 O14 112.3(4) . .
O13 S1 O12 112.0(4) . .
O14 S1 O12 111.5(4) . .
O13 S1 C7 105.8(4) . .
O14 S1 C7 107.8(4) . .
O12 S1 C7 107.0(4) . .
O6 S2 O7 114.7(6) . .
O6 S2 O5 113.2(5) . .
O7 S2 O5 108.2(5) . .
O6 S2 C14 106.9(6) . .
O7 S2 C14 107.0(5) . .
O5 S2 C14 106.2(5) . .
C8 O1 Cu2 113.8(4) . .
C8 O1 Cu3 107.7(5) . .
Cu2 O1 Cu3 96.9(2) . .
C11 O2 Cu2 125.5(5) . .
C11 O2 Cu4 125.3(4) . .
Cu2 O2 Cu4 102.4(3) . .
C13 O4 Cu3 109.6(5) . .
C13 O4 Dy1 138.3(5) . .
Cu3 O4 Dy1 107.1(2) . .
S2 O5 Dy1 133.3(5) . .
C4 O8 Cu4 127.3(4) . .
C4 O8 Cu2 124.7(4) . .
Cu4 O8 Cu2 102.6(3) . .
C1 O9 Cu1 108.2(4) . .
C1 O9 Cu2 114.0(4) . .
Cu1 O9 Cu2 94.0(2) . .
C6 O11 Cu1 109.7(5) . .
C6 O11 Dy1 136.4(5) . .
Cu1 O11 Dy1 108.5(2) . .
S1 O13 Dy1 138.3(4) . .
Cu1 O15 Cu3 112.4(2) . .
Cu1 O15 Dy1 98.3(2) . .
Cu3 O15 Dy1 100.0(2) . .
Cu4 O16 Cu4 96.8(3) 3_584 .
Cl1 O17 Cu2 138.4(6) . .
O9 C1 C2 112.4(6) . .
C4 C2 N2 110.8(6) . .
C4 C2 C3 109.3(6) . .
N2 C2 C3 109.8(6) . .
C4 C2 C1 111.5(7) . .
N2 C2 C1 104.5(5) . .
C3 C2 C1 110.9(6) . .
O10 C3 C2 111.7(6) . .
O8 C4 C2 113.2(6) . .
N2 C5 C6 104.5(6) . .
O11 C6 C5 108.3(7) . .
O11 C6 C7 109.8(7) . .
C5 C6 C7 112.8(6) . .
C6 C7 S1 109.7(5) . .
O1 C8 C9 112.5(6) . .
N1 C9 C11 113.3(7) . .
N1 C9 C10 112.0(7) . .
C11 C9 C10 107.7(7) . .
N1 C9 C8 103.5(6) . .
C11 C9 C8 110.3(7) . .
C10 C9 C8 109.9(7) . .
O3 C10 C9 110.7(8) . .
O2 C11 C9 113.1(7) . .
N1 C12 C13 109.0(7) . .
O4 C13 C14 113.2(8) . .
O4 C13 C12 111.5(7) . .
C14 C13 C12 110.8(7) . .
C13 C14 S2 114.2(6) . .
C9 N1 C12 119.6(6) . .
C9 N1 Cu3 110.6(5) . .
C12 N1 Cu3 105.2(5) . .
C5 N2 C2 119.8(5) . .
C5 N2 Cu1 107.5(4) . .
C2 N2 Cu1 109.3(4) . .
O19 Cl1 O17 95.9(15) . .
O19 Cl1 O20 116(2) . .
O17 Cl1 O20 111.4(15) . .
O19 Cl1 O18 80.1(18) . .
O17 Cl1 O18 118.7(12) . .
O20 Cl1 O18 125.4(15) . .
O21 Cl1' O22 108.3(9) . .
O21 Cl1' O23 111.0(9) . .
O22 Cl1' O23 107.4(10) . .
O21 Cl1' O24 111.6(9) . .
O22 Cl1' O24 107.1(9) . .
O23 Cl1' O24 111.3(9) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 O11 2.281(5) .
Dy1 O5 2.329(6) .
Dy1 O2W 2.346(5) .
Dy1 O4 2.361(5) .
Dy1 O1W 2.378(6) .
Dy1 O3W 2.406(6) .
Dy1 O13 2.471(6) .
Dy1 O15 2.547(5) .
Dy1 Cu1 3.4132(12) .
Dy1 Cu3 3.4619(13) .
Cu1 O11 1.918(5) .
Cu1 O15 1.933(5) .
Cu1 O9 1.949(6) .
Cu1 N2 1.966(6) .
Cu1 Cu2 2.8865(15) .
Cu2 O2 1.913(6) .
Cu2 O8 1.924(5) .
Cu2 O1 1.943(5) .
Cu2 O9 1.998(5) .
Cu2 O17 2.351(7) .
Cu2 Cu3 2.9252(14) .
Cu2 Cu4 2.9920(16) .
Cu3 O4 1.931(5) .
Cu3 O15 1.943(6) .
Cu3 O1 1.965(6) .
Cu3 N1 1.989(8) .
Cu4 O8 1.909(6) .
Cu4 O2 1.927(5) .
Cu4 O16 1.937(6) 3_584
Cu4 O16 1.939(5) .
Cu4 Cu4 2.898(2) 3_584
S1 O13 1.467(5) .
S1 O14 1.467(6) .
S1 O12 1.480(7) .
S1 C7 1.714(8) .
S2 O6 1.453(10) .
S2 O7 1.456(8) .
S2 O5 1.468(8) .
S2 C14 1.724(10) .
O1 C8 1.431(10) .
O6W O10W 1.54(3) .
O2 C11 1.450(10) .
O3 C10 1.378(11) .
O4 C13 1.384(10) .
O8 C4 1.433(9) .
O9 C1 1.425(9) .
O10 C3 1.426(10) .
O11 C6 1.422(9) .
O16 Cu4 1.937(6) 3_584
O17 Cl1 1.483(11) .
C1 C2 1.539(10) .
C2 C4 1.503(10) .
C2 N2 1.521(9) .
C2 C3 1.522(11) .
C5 N2 1.463(9) .
C5 C6 1.530(11) .
C6 C7 1.562(11) .
C8 C9 1.556(11) .
C9 N1 1.475(11) .
C9 C11 1.491(10) .
C9 C10 1.534(12) .
C12 N1 1.486(11) .
C12 C13 1.488(13) .
C13 C14 1.486(13) .
Cl1 O19 1.456(18) .
Cl1 O20 1.494(17) .
Cl1 O18 1.537(15) .
Cl1' O21 1.426(10) .
Cl1' O22 1.437(11) .
Cl1' O23 1.443(12) .
Cl1' O24 1.445(11) .
O9W' O9W 1.41(3) .
