#------------------------------------------------------------------------------
#$Date: 2016-03-24 14:10:54 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179655 $
#$URL: svn://www.crystallography.net/cod/cif/4/51/08/4510834.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4510834
loop_
_publ_author_name
'Yang, Jin'
'Hu, Ting'
'Mak, Thomas C. W.'
_publ_section_title
;
 Flexible Bis(imidazole) Mediated Assembly of Silver(I)--Organic
 Frameworks with Ethynide and Trifluoroacetate Ligands
;
_journal_issue                   6
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              2990
_journal_paper_doi               10.1021/cg500271f
_journal_volume                  14
_journal_year                    2014
_chemical_formula_sum            'C30 H32 Ag6 F12 N4 O8'
_chemical_formula_weight         1451.79
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                107.235(3)
_cell_angle_beta                 103.377(3)
_cell_angle_gamma                108.095(2)
_cell_formula_units_Z            2
_cell_length_a                   12.7287(14)
_cell_length_b                   12.9642(14)
_cell_length_c                   14.910(3)
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      25.03
_cell_measurement_theta_min      1.53
_cell_volume                     2087.2(5)
_computing_cell_refinement       'SAINT(Bruker, 2001)'
_computing_data_collection       'APEX2(Bruker, 2003)'
_computing_data_reduction        'APEX2(Bruker, 2003)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0732
_diffrn_reflns_av_sigmaI/netI    0.0774
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            25615
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         1.53
_exptl_absorpt_coefficient_mu    2.863
_exptl_absorpt_correction_T_max  0.7205
_exptl_absorpt_correction_T_min  0.5700
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    2.310
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1388
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_refine_diff_density_max         2.972
_refine_diff_density_min         -2.201
_refine_diff_density_rms         0.445
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.092
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     541
_refine_ls_number_reflns         7365
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.092
_refine_ls_R_factor_all          0.0960
_refine_ls_R_factor_gt           0.0921
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1840P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2302
_refine_ls_wR_factor_ref         0.2365
_reflns_number_gt                6550
_reflns_number_total             7365
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg500271f_si_002.cif
_cod_data_source_block           5
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 4510825--4510834.cif.
;
_cod_database_code               4510834
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.0460(7) 0.4419(7) 0.1164(6) 0.0254(16) Uani 1 1 d .
C2 C 0.1152(7) 0.3935(7) 0.1126(6) 0.0248(16) Uani 1 1 d .
C3 C 0.2047(8) 0.3442(8) 0.0986(6) 0.0302(18) Uani 1 1 d .
C4 C 0.1630(9) 0.2212(8) 0.1051(7) 0.038(2) Uani 1 1 d .
H4A H 0.2192 0.1877 0.0960 0.057 Uiso 1 1 calc R
H4B H 0.0871 0.1697 0.0536 0.057 Uiso 1 1 calc R
H4C H 0.1571 0.2305 0.1699 0.057 Uiso 1 1 calc R
C5 C 0.3243(8) 0.4274(8) 0.1797(6) 0.0351(19) Uani 1 1 d .
H5A H 0.3816 0.3956 0.1705 0.053 Uiso 1 1 calc R
H5B H 0.3188 0.4361 0.2445 0.053 Uiso 1 1 calc R
H5C H 0.3481 0.5033 0.1756 0.053 Uiso 1 1 calc R
C6 C 0.2065(9) 0.3271(10) -0.0070(7) 0.044(2) Uani 1 1 d .
H6A H 0.2632 0.2952 -0.0185 0.066 Uiso 1 1 calc R
H6B H 0.2281 0.4020 -0.0129 0.066 Uiso 1 1 calc R
H6C H 0.1295 0.2735 -0.0558 0.066 Uiso 1 1 calc R
C7 C 0.0440(7) 0.5728(7) 0.4039(5) 0.0247(16) Uani 1 1 d .
C8 C 0.1420(7) 0.6460(7) 0.4272(6) 0.0276(17) Uani 1 1 d .
C9 C 0.2620(7) 0.7394(8) 0.4534(6) 0.0296(17) Uani 1 1 d .
C10 C 0.2784(10) 0.7495(12) 0.3573(9) 0.063(3) Uani 1 1 d .
H10A H 0.3555 0.8087 0.3739 0.095 Uiso 1 1 calc R
H10B H 0.2192 0.7713 0.3251 0.095 Uiso 1 1 calc R
H10C H 0.2706 0.6747 0.3125 0.095 Uiso 1 1 calc R
C11 C 0.2731(11) 0.8574(11) 0.5241(10) 0.071(4) Uani 1 1 d .
H11A H 0.3501 0.9171 0.5412 0.107 Uiso 1 1 calc R
H11B H 0.2623 0.8508 0.5841 0.107 Uiso 1 1 calc R
H11C H 0.2138 0.8788 0.4916 0.107 Uiso 1 1 calc R
C12 C 0.3568(9) 0.7053(12) 0.5040(11) 0.071(4) Uani 1 1 d .
H12A H 0.4336 0.7651 0.5206 0.107 Uiso 1 1 calc R
H12B H 0.3494 0.6309 0.4590 0.107 Uiso 1 1 calc R
H12C H 0.3470 0.6986 0.5642 0.107 Uiso 1 1 calc R
C13 C 0.2459(7) 0.3745(8) 0.4447(6) 0.0305(18) Uani 1 1 d .
C14 C 0.3526(8) 0.3423(8) 0.4733(6) 0.0348(19) Uani 1 1 d .
C15 C -0.0807(6) 0.1618(7) 0.2500(6) 0.0256(16) Uani 1 1 d .
C16 C -0.1213(9) 0.0305(8) 0.1810(7) 0.042(2) Uani 1 1 d .
C17 C -0.1662(7) 0.1162(7) -0.1677(6) 0.0249(16) Uani 1 1 d .
C18 C -0.2195(8) 0.0057(7) -0.2675(6) 0.0333(19) Uani 1 1 d .
C19 C 0.3373(7) 0.6846(7) 0.0390(7) 0.0320(18) Uani 1 1 d .
C20 C 0.4680(8) 0.7009(9) 0.0615(7) 0.041(2) Uani 1 1 d .
C21 C -0.3381(7) 0.2164(8) 0.2184(6) 0.0318(18) Uani 1 1 d .
H21 H -0.2839 0.1843 0.2077 0.038 Uiso 1 1 calc R
C22 C -0.4147(7) 0.3402(8) 0.2681(6) 0.0306(18) Uani 1 1 d .
H22 H -0.4232 0.4098 0.2974 0.037 Uiso 1 1 calc R
C23 C -0.5034(7) 0.2302(8) 0.2202(6) 0.0330(18) Uani 1 1 d .
H23 H -0.5830 0.2111 0.2109 0.040 Uiso 1 1 calc R
C24 C -0.5158(8) 0.0238(8) 0.1306(7) 0.040(2) Uani 1 1 d .
H24A H -0.5857 -0.0061 0.1469 0.049 Uiso 1 1 calc R
H24B H -0.4640 -0.0129 0.1509 0.049 Uiso 1 1 calc R
C25 C -0.5519(8) -0.0110(8) 0.0190(7) 0.037(2) Uani 1 1 d .
H25A H -0.5962 0.0330 0.0003 0.045 Uiso 1 1 calc R
H25B H -0.6043 -0.0943 -0.0145 0.045 Uiso 1 1 calc R
C26 C -0.2764(8) 0.5799(8) 0.2108(7) 0.0332(19) Uani 1 1 d .
H26 H -0.3380 0.5059 0.1718 0.040 Uiso 1 1 calc R
C27 C -0.2839(7) 0.6735(9) 0.2751(7) 0.038(2) Uani 1 1 d .
H27 H -0.3514 0.6754 0.2882 0.045 Uiso 1 1 calc R
C28 C -0.1039(8) 0.7243(8) 0.2776(7) 0.036(2) Uani 1 1 d .
H28 H -0.0242 0.7691 0.2935 0.043 Uiso 1 1 calc R
C29 C -0.1429(9) 0.8836(9) 0.3925(8) 0.044(2) Uani 1 1 d .
H29A H -0.1950 0.8785 0.4309 0.053 Uiso 1 1 calc R
H29B H -0.1545 0.9342 0.3581 0.053 Uiso 1 1 calc R
C30 C -0.0179(8) 0.9380(8) 0.4627(7) 0.038(2) Uani 1 1 d .
H30A H 0.0339 0.9399 0.4241 0.046 Uiso 1 1 calc R
H30B H -0.0073 0.8889 0.4991 0.046 Uiso 1 1 calc R
N1 N -0.1620(6) 0.6131(6) 0.2131(5) 0.0288(15) Uani 1 1 d .
N2 N -0.1753(6) 0.7642(7) 0.3172(5) 0.0331(16) Uani 1 1 d .
N3 N -0.3092(6) 0.3316(6) 0.2660(5) 0.0280(14) Uani 1 1 d .
N4 N -0.4548(6) 0.1525(6) 0.1879(5) 0.0309(15) Uani 1 1 d .
O1 O -0.1045(5) 0.2109(5) -0.1695(4) 0.0325(13) Uani 1 1 d .
O2 O -0.1943(6) 0.0975(5) -0.0977(4) 0.0372(14) Uani 1 1 d .
O3 O -0.0785(5) 0.2294(5) 0.2060(4) 0.0344(13) Uani 1 1 d .
O4 O -0.0595(6) 0.1845(6) 0.3414(5) 0.0434(16) Uani 1 1 d .
O5 O 0.2174(6) 0.3754(6) 0.3589(5) 0.0366(14) Uani 1 1 d .
O6 O 0.2002(6) 0.3885(7) 0.5085(5) 0.0499(18) Uani 1 1 d .
O7 O 0.2966(5) 0.6634(7) 0.1019(5) 0.0460(17) Uani 1 1 d .
O8 O 0.2896(5) 0.6929(6) -0.0411(5) 0.0363(14) Uani 1 1 d .
F1 F -0.1209(12) 0.0144(7) 0.0920(6) 0.125(4) Uani 1 1 d .
F2 F -0.2311(7) -0.0304(7) 0.1719(8) 0.096(3) Uani 1 1 d .
F3 F -0.0598(7) -0.0207(6) 0.2176(7) 0.088(3) Uani 1 1 d .
F4 F 0.3193(6) 0.2385(5) 0.4832(5) 0.0521(14) Uani 1 1 d .
F5 F 0.4342(5) 0.4229(6) 0.5616(4) 0.0558(15) Uani 1 1 d .
F6 F 0.4053(5) 0.3324(5) 0.4056(4) 0.0476(14) Uani 1 1 d .
F7 F 0.4773(6) 0.5991(6) 0.0552(6) 0.071(2) Uani 1 1 d .
F8 F 0.5371(5) 0.7793(6) 0.1545(6) 0.076(2) Uani 1 1 d .
F9 F 0.5154(6) 0.7386(9) 0.0010(7) 0.097(3) Uani 1 1 d .
F10 F -0.1712(6) 0.0206(5) -0.3342(4) 0.0518(15) Uani 1 1 d .
F11 F -0.3351(5) -0.0227(6) -0.3102(4) 0.0586(16) Uani 1 1 d .
F12 F -0.2124(7) -0.0890(5) -0.2528(5) 0.0586(17) Uani 1 1 d .
Ag1 Ag 0.08070(6) 0.43469(6) 0.28482(4) 0.0296(2) Uani 1 1 d .
Ag2 Ag -0.13492(5) 0.46078(5) 0.33449(4) 0.0261(2) Uani 1 1 d .
Ag3 Ag -0.07100(5) 0.51257(5) 0.15562(4) 0.0256(2) Uani 1 1 d .
Ag4 Ag 0.00882(6) 0.38193(7) 0.45268(5) 0.0383(2) Uani 1 1 d .
Ag5 Ag -0.12209(6) 0.25397(6) 0.04937(5) 0.0339(2) Uani 1 1 d .
Ag6 Ag 0.09780(6) 0.60670(6) 0.07183(5) 0.0345(2) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0030 0.0020 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0060 0.0030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0110 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0170 0.0100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8970 1.1020 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C2 C1 Ag3 164.8(6) . .
C2 C1 Ag6 112.6(6) . .
Ag3 C1 Ag6 79.8(3) . .
C2 C1 Ag5 91.9(6) . .
Ag3 C1 Ag5 84.4(3) . .
Ag6 C1 Ag5 135.2(3) . .
C2 C1 Ag1 82.9(5) . .
Ag3 C1 Ag1 82.3(2) . .
Ag6 C1 Ag1 129.9(3) . .
Ag5 C1 Ag1 88.3(2) . .
C1 C2 C3 171.5(7) . .
C1 C2 Ag1 69.4(5) . .
C3 C2 Ag1 117.8(5) . .
C2 C3 C5 109.6(7) . .
C2 C3 C6 107.4(6) . .
C5 C3 C6 112.3(7) . .
C2 C3 C4 108.0(7) . .
C5 C3 C4 110.4(7) . .
C6 C3 C4 108.8(8) . .
C3 C4 H4A 109.5 . .
C3 C4 H4B 109.5 . .
H4A C4 H4B 109.5 . .
C3 C4 H4C 109.5 . .
H4A C4 H4C 109.5 . .
H4B C4 H4C 109.5 . .
C3 C5 H5A 109.5 . .
C3 C5 H5B 109.5 . .
H5A C5 H5B 109.5 . .
C3 C5 H5C 109.5 . .
H5A C5 H5C 109.5 . .
H5B C5 H5C 109.5 . .
C3 C6 H6A 109.5 . .
C3 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
C3 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
C8 C7 Ag2 165.5(7) . .
C8 C7 Ag4 106.3(6) . 2_566
Ag2 C7 Ag4 82.5(2) . 2_566
C8 C7 Ag1 90.3(5) . .
Ag2 C7 Ag1 87.9(3) . .
Ag4 C7 Ag1 147.3(4) 2_566 .
C7 C8 C9 177.5(8) . .
C7 C8 Ag1 62.8(5) . .
C9 C8 Ag1 117.6(5) . .
C8 C9 C11 109.5(8) . .
C8 C9 C12 109.4(7) . .
C11 C9 C12 109.8(10) . .
C8 C9 C10 109.5(7) . .
C11 C9 C10 109.6(9) . .
C12 C9 C10 109.0(9) . .
C9 C10 H10A 109.5 . .
C9 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C9 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
C9 C11 H11A 109.5 . .
C9 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
C9 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
C9 C12 H12A 109.5 . .
C9 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C9 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
O6 C13 O5 131.2(8) . .
O6 C13 C14 113.7(7) . .
O5 C13 C14 115.0(7) . .
F6 C14 F5 107.7(7) . .
F6 C14 F4 106.8(7) . .
F5 C14 F4 106.4(7) . .
F6 C14 C13 113.4(7) . .
F5 C14 C13 111.1(7) . .
F4 C14 C13 111.0(7) . .
O3 C15 O4 128.9(8) . .
O3 C15 C16 115.1(7) . .
O4 C15 C16 116.0(7) . .
F1 C16 F3 108.1(10) . .
F1 C16 F2 107.1(10) . .
F3 C16 F2 104.8(9) . .
F1 C16 C15 113.7(8) . .
F3 C16 C15 113.3(8) . .
F2 C16 C15 109.4(8) . .
O2 C17 O1 129.4(8) . .
O2 C17 C18 114.4(7) . .
O1 C17 C18 116.1(7) . .
F10 C18 F12 108.4(7) . .
F10 C18 F11 106.6(7) . .
F12 C18 F11 105.9(7) . .
F10 C18 C17 113.7(7) . .
F12 C18 C17 111.9(7) . .
F11 C18 C17 109.8(7) . .
O7 C19 O8 130.6(8) . .
O7 C19 C20 114.2(7) . .
O8 C19 C20 115.2(7) . .
F9 C20 F8 106.0(9) . .
F9 C20 F7 108.5(9) . .
F8 C20 F7 106.0(8) . .
F9 C20 C19 113.6(8) . .
F8 C20 C19 111.9(8) . .
F7 C20 C19 110.4(8) . .
N3 C21 N4 111.8(7) . .
N3 C21 H21 124.1 . .
N4 C21 H21 124.1 . .
C23 C22 N3 108.6(7) . .
C23 C22 H22 125.7 . .
N3 C22 H22 125.7 . .
C22 C23 N4 107.7(7) . .
C22 C23 H23 126.2 . .
N4 C23 H23 126.2 . .
N4 C24 C25 112.8(7) . .
N4 C24 H24A 109.0 . .
C25 C24 H24A 109.0 . .
N4 C24 H24B 109.0 . .
C25 C24 H24B 109.0 . .
H24A C24 H24B 107.8 . .
C24 C25 C25 114.2(10) . 2_455
C24 C25 H25A 108.7 . .
C25 C25 H25A 108.7 2_455 .
C24 C25 H25B 108.7 . .
C25 C25 H25B 108.7 2_455 .
H25A C25 H25B 107.6 . .
C27 C26 N1 108.1(8) . .
C27 C26 H26 125.9 . .
N1 C26 H26 125.9 . .
C26 C27 N2 107.8(7) . .
C26 C27 H27 126.1 . .
N2 C27 H27 126.1 . .
N1 C28 N2 111.0(8) . .
N1 C28 H28 124.5 . .
N2 C28 H28 124.5 . .
N2 C29 C30 112.4(7) . .
N2 C29 H29A 109.1 . .
C30 C29 H29A 109.1 . .
N2 C29 H29B 109.1 . .
C30 C29 H29B 109.1 . .
H29A C29 H29B 107.9 . .
C29 C30 C30 112.9(10) . 2_576
C29 C30 H30A 109.0 . .
C30 C30 H30A 109.0 2_576 .
C29 C30 H30B 109.0 . .
C30 C30 H30B 109.0 2_576 .
H30A C30 H30B 107.8 . .
C28 N1 C26 106.4(7) . .
C28 N1 Ag3 121.0(5) . .
C26 N1 Ag3 131.5(6) . .
C28 N2 C27 106.8(7) . .
C28 N2 C29 127.1(8) . .
C27 N2 C29 126.1(7) . .
C21 N3 C22 105.2(7) . .
C21 N3 Ag2 124.1(5) . .
C22 N3 Ag2 130.4(6) . .
C21 N4 C23 106.6(7) . .
C21 N4 C24 125.5(7) . .
C23 N4 C24 127.8(7) . .
C17 O1 Ag6 121.9(5) . 2_565
C17 O2 Ag5 116.7(5) . .
C15 O3 Ag5 148.4(6) . .
C15 O3 Ag1 120.1(5) . .
Ag5 O3 Ag1 87.99(19) . .
C15 O4 Ag4 118.5(5) . .
C13 O5 Ag1 129.6(5) . .
C13 O6 Ag4 115.2(5) . .
C19 O7 Ag6 120.3(6) . .
C19 O8 Ag5 116.4(5) . 2_565
O5 Ag1 C7 112.5(2) . .
O5 Ag1 C1 124.7(2) . .
C7 Ag1 C1 116.6(3) . .
O5 Ag1 O3 92.3(2) . .
C7 Ag1 O3 114.3(2) . .
C1 Ag1 O3 89.6(2) . .
O5 Ag1 C2 97.2(2) . .
C7 Ag1 C2 141.3(2) . .
C1 Ag1 C2 27.7(2) . .
O3 Ag1 C2 87.5(2) . .
O5 Ag1 C8 101.0(2) . .
C7 Ag1 C8 26.9(3) . .
C1 Ag1 C8 111.5(2) . .
O3 Ag1 C8 140.8(2) . .
C2 Ag1 C8 126.3(2) . .
O5 Ag1 Ag3 167.52(15) . .
C7 Ag1 Ag3 77.16(18) . .
C1 Ag1 Ag3 43.11(18) . .
O3 Ag1 Ag3 90.50(13) . .
C2 Ag1 Ag3 70.78(16) . .
C8 Ag1 Ag3 84.35(17) . .
O5 Ag1 Ag4 74.51(15) . .
C7 Ag1 Ag4 58.74(18) . .
C1 Ag1 Ag4 155.39(18) . .
O3 Ag1 Ag4 73.17(13) . .
C2 Ag1 Ag4 158.40(17) . .
C8 Ag1 Ag4 75.20(17) . .
Ag3 Ag1 Ag4 117.92(3) . .
O5 Ag1 Ag2 130.28(15) . .
C7 Ag1 Ag2 42.25(19) . .
C1 Ag1 Ag2 103.37(18) . .
O3 Ag1 Ag2 74.74(14) . .
C2 Ag1 Ag2 128.98(17) . .
C8 Ag1 Ag2 68.55(17) . .
Ag3 Ag1 Ag2 62.16(2) . .
Ag4 Ag1 Ag2 55.77(2) . .
C7 Ag2 N3 173.1(3) . .
C7 Ag2 Ag4 64.3(2) . .
N3 Ag2 Ag4 109.37(19) . .
C7 Ag2 Ag4 52.76(19) . 2_566
N3 Ag2 Ag4 127.93(17) . 2_566
Ag4 Ag2 Ag4 63.93(3) . 2_566
C7 Ag2 Ag1 49.9(2) . .
N3 Ag2 Ag1 125.56(18) . .
Ag4 Ag2 Ag1 61.22(2) . .
Ag4 Ag2 Ag1 97.47(3) 2_566 .
C7 Ag2 Ag3 77.89(19) . .
N3 Ag2 Ag3 104.15(17) . .
Ag4 Ag2 Ag3 118.95(3) . .
Ag4 Ag2 Ag3 124.73(3) 2_566 .
Ag1 Ag2 Ag3 57.741(18) . .
C1 Ag3 N1 169.5(3) . .
C1 Ag3 Ag6 54.5(2) . .
N1 Ag3 Ag6 119.48(18) . .
C1 Ag3 Ag1 54.6(2) . .
N1 Ag3 Ag1 122.04(18) . .
Ag6 Ag3 Ag1 96.77(3) . .
C1 Ag3 Ag5 52.5(2) . .
N1 Ag3 Ag5 137.52(19) . .
Ag6 Ag3 Ag5 97.25(2) . .
Ag1 Ag3 Ag5 68.71(2) . .
C1 Ag3 Ag2 112.38(19) . .
N1 Ag3 Ag2 68.46(17) . .
Ag6 Ag3 Ag2 151.32(3) . .
Ag1 Ag3 Ag2 60.10(2) . .
Ag5 Ag3 Ag2 89.94(2) . .
C1 Ag3 Ag6 58.5(2) . 2_565
N1 Ag3 Ag6 127.39(18) . 2_565
Ag6 Ag3 Ag6 56.37(3) . 2_565
Ag1 Ag3 Ag6 110.04(2) . 2_565
Ag5 Ag3 Ag6 55.935(19) . 2_565
Ag2 Ag3 Ag6 143.86(3) . 2_565
O4 Ag4 O6 89.8(3) . .
O4 Ag4 C7 120.0(2) . 2_566
O6 Ag4 C7 105.8(2) . 2_566
O4 Ag4 Ag2 100.03(16) . .
O6 Ag4 Ag2 143.53(18) . .
C7 Ag4 Ag2 99.40(19) 2_566 .
O4 Ag4 Ag2 141.72(15) . 2_566
O6 Ag4 Ag2 69.07(17) . 2_566
C7 Ag4 Ag2 44.77(19) 2_566 2_566
Ag2 Ag4 Ag2 116.07(3) . 2_566
O4 Ag4 Ag1 83.52(14) . .
O6 Ag4 Ag1 83.66(16) . .
C7 Ag4 Ag1 153.9(2) 2_566 .
Ag2 Ag4 Ag1 63.01(2) . .
Ag2 Ag4 Ag1 123.15(3) 2_566 .
O4 Ag4 Ag4 155.74(18) . 2_566
O6 Ag4 Ag4 114.3(2) . 2_566
C7 Ag4 Ag4 58.4(2) 2_566 2_566
Ag2 Ag4 Ag4 58.97(3) . 2_566
Ag2 Ag4 Ag4 57.10(2) 2_566 2_566
Ag1 Ag4 Ag4 95.59(3) . 2_566
O2 Ag5 O3 120.6(2) . .
O2 Ag5 C1 131.2(2) . .
O3 Ag5 C1 93.3(2) . .
O2 Ag5 O8 101.1(2) . 2_565
O3 Ag5 O8 103.3(2) . 2_565
C1 Ag5 O8 103.9(2) . 2_565
O2 Ag5 Ag6 84.85(15) . 2_565
O3 Ag5 Ag6 153.13(15) . 2_565
C1 Ag5 Ag6 60.94(17) . 2_565
O8 Ag5 Ag6 77.80(14) 2_565 2_565
O2 Ag5 Ag3 146.97(15) . .
O3 Ag5 Ag3 91.93(15) . .
C1 Ag5 Ag3 43.07(18) . .
O8 Ag5 Ag3 62.38(15) 2_565 .
Ag6 Ag5 Ag3 64.40(2) 2_565 .
O7 Ag6 O1 98.2(2) . 2_565
O7 Ag6 C1 103.8(3) . .
O1 Ag6 C1 121.9(2) 2_565 .
O7 Ag6 Ag6 129.8(2) . 2_565
O1 Ag6 Ag6 130.95(15) 2_565 2_565
C1 Ag6 Ag6 62.24(19) . 2_565
O7 Ag6 Ag3 138.83(15) . .
O1 Ag6 Ag3 83.90(14) 2_565 .
C1 Ag6 Ag3 45.70(18) . .
Ag6 Ag6 Ag3 67.25(3) 2_565 .
O7 Ag6 Ag5 81.48(16) . 2_565
O1 Ag6 Ag5 74.62(14) 2_565 2_565
C1 Ag6 Ag5 160.85(19) . 2_565
Ag6 Ag6 Ag5 100.07(4) 2_565 2_565
Ag3 Ag6 Ag5 137.25(3) . 2_565
O7 Ag6 Ag3 84.18(18) . 2_565
O1 Ag6 Ag3 133.44(14) 2_565 2_565
C1 Ag6 Ag3 102.12(19) . 2_565
Ag6 Ag6 Ag3 56.38(3) 2_565 2_565
Ag3 Ag6 Ag3 123.63(3) . 2_565
Ag5 Ag6 Ag3 59.67(2) 2_565 2_565
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C2 1.233(11) .
C1 Ag3 2.081(8) .
C1 Ag6 2.368(7) .
C1 Ag5 2.417(8) .
C1 Ag1 2.483(7) .
C2 C3 1.495(11) .
C2 Ag1 2.632(7) .
C3 C5 1.516(12) .
C3 C6 1.530(11) .
C3 C4 1.557(12) .
C4 H4A 0.9600 .
C4 H4B 0.9600 .
C4 H4C 0.9600 .
C5 H5A 0.9600 .
C5 H5B 0.9600 .
C5 H5C 0.9600 .
C6 H6A 0.9600 .
C6 H6B 0.9600 .
C6 H6C 0.9600 .
C7 C8 1.203(11) .
C7 Ag2 2.081(8) .
C7 Ag4 2.352(7) 2_566
C7 Ag1 2.366(7) .
C8 C9 1.499(11) .
C8 Ag1 2.661(8) .
C9 C11 1.520(15) .
C9 C12 1.527(13) .
C9 C10 1.532(13) .
C10 H10A 0.9600 .
C10 H10B 0.9600 .
C10 H10C 0.9600 .
C11 H11A 0.9600 .
C11 H11B 0.9600 .
C11 H11C 0.9600 .
C12 H12A 0.9600 .
C12 H12B 0.9600 .
C12 H12C 0.9600 .
C13 O6 1.224(10) .
C13 O5 1.252(10) .
C13 C14 1.546(12) .
C14 F6 1.332(10) .
C14 F5 1.335(11) .
C14 F4 1.343(10) .
C15 O3 1.238(10) .
C15 O4 1.250(10) .
C15 C16 1.548(12) .
C16 F1 1.282(12) .
C16 F3 1.300(12) .
C16 F2 1.327(12) .
C17 O2 1.243(9) .
C17 O1 1.246(10) .
C17 C18 1.547(12) .
C18 F10 1.316(9) .
C18 F12 1.335(10) .
C18 F11 1.340(11) .
C19 O7 1.230(10) .
C19 O8 1.260(10) .
C19 C20 1.551(12) .
C20 F9 1.323(11) .
C20 F8 1.331(12) .
C20 F7 1.339(11) .
C21 N3 1.334(11) .
C21 N4 1.342(11) .
C21 H21 0.9300 .
C22 C23 1.357(12) .
C22 N3 1.389(10) .
C22 H22 0.9300 .
C23 N4 1.366(11) .
C23 H23 0.9300 .
C24 N4 1.469(12) .
C24 C25 1.502(13) .
C24 H24A 0.9700 .
C24 H24B 0.9700 .
C25 C25 1.535(17) 2_455
C25 H25A 0.9700 .
C25 H25B 0.9700 .
C26 C27 1.351(13) .
C26 N1 1.373(11) .
C26 H26 0.9300 .
C27 N2 1.356(12) .
C27 H27 0.9300 .
C28 N1 1.318(11) .
C28 N2 1.342(10) .
C28 H28 0.9300 .
C29 N2 1.478(12) .
C29 C30 1.490(14) .
C29 H29A 0.9700 .
C29 H29B 0.9700 .
C30 C30 1.510(18) 2_576
C30 H30A 0.9700 .
C30 H30B 0.9700 .
N1 Ag3 2.123(7) .
N3 Ag2 2.097(7) .
O1 Ag6 2.345(6) 2_565
O2 Ag5 2.245(6) .
O3 Ag5 2.411(6) .
O3 Ag1 2.503(6) .
O4 Ag4 2.344(7) .
O5 Ag1 2.298(6) .
O6 Ag4 2.350(7) .
O7 Ag6 2.295(6) .
O8 Ag5 2.425(6) 2_565
Ag1 Ag3 3.0168(8) .
Ag1 Ag4 3.0421(9) .
Ag1 Ag2 3.0927(9) .
Ag2 Ag4 2.8697(9) .
Ag2 Ag4 2.9291(10) 2_566
Ag2 Ag3 3.1545(9) .
Ag3 Ag6 2.8607(8) .
Ag3 Ag5 3.0322(10) .
Ag3 Ag6 3.1683(11) 2_565
Ag4 C7 2.352(7) 2_566
Ag4 Ag2 2.9291(10) 2_566
Ag4 Ag4 3.0703(15) 2_566
Ag5 O8 2.425(6) 2_565
Ag5 Ag6 2.9103(9) 2_565
Ag6 O1 2.345(6) 2_565
Ag6 Ag6 2.8605(14) 2_565
Ag6 Ag5 2.9103(9) 2_565
Ag6 Ag3 3.1683(11) 2_565
