#------------------------------------------------------------------------------
#$Date: 2015-07-05 10:43:49 +0300 (Sun, 05 Jul 2015) $
#$Revision: 140066 $
#$URL: svn://www.crystallography.net/cod/cif/4/51/32/4513234.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4513234
loop_
_publ_author_name
'Geyer, Florian L.'
'Rominger, Frank'
'Vogtland, Maximilian'
'Bunz, Uwe H. F.'
_publ_section_title
;
 Interpenetrated Frameworks with Anisotropic Pore Structures from a
 Tetrahedral Pyridine Ligand
;
_journal_issue                   7
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              3539
_journal_paper_doi               10.1021/acs.cgd.5b00719
_journal_volume                  15
_journal_year                    2015
_chemical_formula_sum            'C60 H44 N4 O8 Si Zn2'
_chemical_formula_weight         1107.82
_chemical_name_common            '1*Zn(OAc)2 in manuscript'
_chemical_name_systematic
; 
 ? 
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014
_cell_angle_alpha                90
_cell_angle_beta                 102.143(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   33.224(3)
_cell_length_b                   21.0248(17)
_cell_length_c                   8.4989(7)
_cell_measurement_reflns_used    1599
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      17.33
_cell_measurement_theta_min      2.83
_cell_volume                     5803.9(9)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      200(2)
_diffrn_measured_fraction_theta_full 0.767
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX-II Quazar area detector'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1034
_diffrn_reflns_av_unetI/netI     0.1093
_diffrn_reflns_laue_measured_fraction_full 0.767
_diffrn_reflns_laue_measured_fraction_max 1.000
_diffrn_reflns_limit_h_max       36
_diffrn_reflns_limit_h_min       -36
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_limit_l_min       -9
_diffrn_reflns_number            15321
_diffrn_reflns_point_group_measured_fraction_full 0.767
_diffrn_reflns_point_group_measured_fraction_max 1.000
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         22.983
_diffrn_reflns_theta_min         1.154
_diffrn_source                   'ImuS microsource'
_exptl_absorpt_coefficient_mu    0.902
_exptl_absorpt_correction_T_max  0.9558
_exptl_absorpt_correction_T_min  0.8578
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
Sheldrick, G. M. (2008). SADABS. University of Göttingen, Germany.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.268
_exptl_crystal_description       polyhedron
_exptl_crystal_F_000             2280
_exptl_crystal_size_max          0.110
_exptl_crystal_size_mid          0.060
_exptl_crystal_size_min          0.060
_refine_diff_density_max         0.605
_refine_diff_density_min         -0.355
_refine_diff_density_rms         0.078
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.041
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     394
_refine_ls_number_reflns         4027
_refine_ls_number_restraints     339
_refine_ls_restrained_S_all      1.020
_refine_ls_R_factor_all          0.1325
_refine_ls_R_factor_gt           0.0661
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0615P)²+27.1472P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1497
_refine_ls_wR_factor_ref         0.1798
_reflns_Friedel_coverage         0.000
_reflns_number_gt                2292
_reflns_number_total             4027
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            cg5b00719_si_002.cif
_cod_data_source_block           fge27
_cod_depositor_comments
'Adding full bibliography for 4513232--4513239.cif.'
_cod_original_cell_volume        5803.9(8)
_cod_database_code               4513234
_shelx_space_group_comment
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
_shelx_estimated_absorpt_t_min   0.907
_shelx_estimated_absorpt_t_max   0.948
_shelxl_version_number           2014-3
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Zn1 Zn 0.31392(3) 0.84278(5) -0.22187(10) 0.0452(3) Uani 1 1 d D U . . .
C1 C 0.2901(2) 0.7231(4) -0.3008(9) 0.0488(19) Uani 1 1 d D U . . .
O1 O 0.31049(17) 0.7658(3) -0.3484(6) 0.0600(16) Uani 1 1 d D U . . .
O2 O 0.27313(17) 0.7297(3) -0.1865(7) 0.0676(17) Uani 1 1 d D U . . .
C2 C 0.2875(3) 0.6588(4) -0.3807(12) 0.095(3) Uani 1 1 d D U . . .
H2A H 0.3021 0.6599 -0.4693 0.142 Uiso 1 1 calc R U . . .
H2B H 0.3000 0.6267 -0.3018 0.142 Uiso 1 1 calc R U . . .
H2C H 0.2585 0.6480 -0.4229 0.142 Uiso 1 1 calc R U . . .
C3 C 0.3422(5) 0.9277(9) -0.394(2) 0.061(5) Uani 0.609(18) 1 d D U P A 1
O3 O 0.3563(4) 0.9066(5) -0.2565(13) 0.063(4) Uani 0.609(18) 1 d D U P A 1
O4 O 0.3086(4) 0.9128(7) -0.4728(17) 0.095(5) Uani 0.609(18) 1 d D U P A 1
C4 C 0.3698(10) 0.9743(16) -0.460(4) 0.153(16) Uani 0.609(18) 1 d D U P A 1
H4A H 0.3954 0.9807 -0.3801 0.229 Uiso 0.609(18) 1 calc R U P A 1
H4B H 0.3762 0.9571 -0.5591 0.229 Uiso 0.609(18) 1 calc R U P A 1
H4C H 0.3556 1.0152 -0.4833 0.229 Uiso 0.609(18) 1 calc R U P A 1
C3B C 0.3593(8) 0.9281(13) -0.349(3) 0.066(7) Uani 0.391(18) 1 d D U P A 2
O3B O 0.3252(7) 0.9037(10) -0.379(3) 0.083(6) Uani 0.391(18) 1 d D U P A 2
O4B O 0.3863(8) 0.9153(9) -0.233(2) 0.083(7) Uani 0.391(18) 1 d D U P A 2
C4B C 0.3692(11) 0.9674(17) -0.488(4) 0.077(9) Uani 0.391(18) 1 d D U P A 2
H4B1 H 0.3441 0.9733 -0.5707 0.115 Uiso 0.391(18) 1 calc R U P A 2
H4B2 H 0.3800 1.0090 -0.4472 0.115 Uiso 0.391(18) 1 calc R U P A 2
H4B3 H 0.3899 0.9451 -0.5342 0.115 Uiso 0.391(18) 1 calc R U P A 2
Si1 Si 0.5000 0.64672(15) 1.2500 0.0354(7) Uani 1 2 d S TU P . .
C11 C 0.4711(2) 0.6962(4) 1.0808(8) 0.0352(17) Uani 1 1 d . U . . .
C12 C 0.4336(2) 0.6739(4) 0.9901(9) 0.050(2) Uani 1 1 d . U . . .
H12 H 0.4209 0.6381 1.0276 0.060 Uiso 1 1 calc R U . . .
C13 C 0.4147(2) 0.7025(4) 0.8479(9) 0.055(2) Uani 1 1 d . U . . .
H13 H 0.3895 0.6860 0.7876 0.066 Uiso 1 1 calc R U . . .
C14 C 0.4325(2) 0.7557(4) 0.7927(8) 0.0432(18) Uani 1 1 d . U . . .
C15 C 0.4679(2) 0.7813(4) 0.8874(8) 0.0454(19) Uani 1 1 d . U . . .
H15 H 0.4793 0.8192 0.8544 0.054 Uiso 1 1 calc R U . . .
C16 C 0.4864(2) 0.7521(4) 1.0291(8) 0.0400(18) Uani 1 1 d . U . . .
H16 H 0.5104 0.7707 1.0934 0.048 Uiso 1 1 calc R U . . .
C17 C 0.4142(2) 0.7796(4) 0.6357(9) 0.050(2) Uani 1 1 d . U . . .
C18 C 0.3999(2) 0.7943(4) 0.5022(9) 0.050(2) Uani 1 1 d . U . . .
C21 C 0.3800(2) 0.8071(4) 0.3378(8) 0.0413(18) Uani 1 1 d . U . . .
C22 C 0.3384(2) 0.7962(4) 0.2806(9) 0.055(2) Uani 1 1 d . U . . .
H22 H 0.3217 0.7815 0.3509 0.066 Uiso 1 1 calc R U . . .
C23 C 0.3219(2) 0.8068(4) 0.1225(9) 0.057(2) Uani 1 1 d . U . . .
H23 H 0.2933 0.7987 0.0857 0.068 Uiso 1 1 calc R U . . .
N24 N 0.34271(17) 0.8276(3) 0.0163(7) 0.0392(15) Uani 1 1 d . U . . .
C25 C 0.3826(2) 0.8402(4) 0.0707(8) 0.0452(19) Uani 1 1 d . U . . .
H25 H 0.3981 0.8559 -0.0032 0.054 Uiso 1 1 calc R U . . .
C26 C 0.4023(2) 0.8317(4) 0.2273(9) 0.054(2) Uani 1 1 d . U . . .
H26 H 0.4306 0.8422 0.2614 0.064 Uiso 1 1 calc R U . . .
C31 C 0.4609(2) 0.5977(4) 1.3263(8) 0.0377(17) Uani 1 1 d . U . . .
C32 C 0.4358(3) 0.6283(4) 1.4116(11) 0.069(3) Uani 1 1 d . U . . .
H32 H 0.4419 0.6711 1.4434 0.083 Uiso 1 1 calc R U . . .
C33 C 0.4024(3) 0.5998(4) 1.4530(11) 0.074(3) Uani 1 1 d . U . . .
H33 H 0.3845 0.6238 1.5041 0.088 Uiso 1 1 calc R U . . .
C34 C 0.3950(2) 0.5372(4) 1.4204(9) 0.052(2) Uani 1 1 d . U . . .
C35 C 0.4193(3) 0.5043(4) 1.3348(10) 0.063(2) Uani 1 1 d . U . . .
H35 H 0.4139 0.4608 1.3084 0.076 Uiso 1 1 calc R U . . .
C36 C 0.4515(2) 0.5353(4) 1.2878(10) 0.058(2) Uani 1 1 d . U . . .
H36 H 0.4677 0.5126 1.2269 0.069 Uiso 1 1 calc R U . . .
C37 C 0.3606(3) 0.5057(4) 1.4660(11) 0.065(3) Uani 1 1 d . U . . .
C38 C 0.3331(3) 0.4804(4) 1.5101(10) 0.064(2) Uani 1 1 d . U . . .
C41 C 0.3005(2) 0.4496(4) 1.5677(9) 0.052(2) Uani 1 1 d . U . . .
C42 C 0.2658(3) 0.4808(5) 1.5882(12) 0.077(3) Uani 1 1 d . U . . .
H42 H 0.2627 0.5248 1.5643 0.093 Uiso 1 1 calc R U . . .
C43 C 0.2356(3) 0.4485(4) 1.6434(12) 0.070(3) Uani 1 1 d . U . . .
H43 H 0.2121 0.4715 1.6585 0.085 Uiso 1 1 calc R U . . .
N44 N 0.23770(18) 0.3868(3) 1.6765(7) 0.0409(15) Uani 1 1 d . U . . .
C45 C 0.2707(2) 0.3564(4) 1.6571(10) 0.055(2) Uani 1 1 d . U . . .
H45 H 0.2727 0.3121 1.6802 0.066 Uiso 1 1 calc R U . . .
C46 C 0.3030(2) 0.3856(4) 1.6042(10) 0.057(2) Uani 1 1 d . U . . .
H46 H 0.3265 0.3618 1.5933 0.069 Uiso 1 1 calc R U . . .
O5 O 0.4823(5) 0.9264(7) 0.424(3) 0.408(15) Uani 1 1 d . . . . .
O6 O 0.4537(6) 0.9523(8) -0.158(2) 0.346(10) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Zn1 O3B 99.7(8) . .
O1 Zn1 O3 116.0(3) . .
O1 Zn1 N44 121.8(2) . 4_556
O3B Zn1 N44 96.9(7) . 4_556
O3 Zn1 N44 111.4(4) . 4_556
O1 Zn1 N24 112.1(2) . .
O3B Zn1 N24 131.0(8) . .
O3 Zn1 N24 93.0(4) . .
N44 Zn1 N24 96.8(2) 4_556 .
O2 C1 O1 123.3(8) . .
O2 C1 C2 117.6(8) . .
O1 C1 C2 119.1(8) . .
C1 O1 Zn1 113.3(5) . .
C1 C2 H2A 109.5 . .
C1 C2 H2B 109.5 . .
H2A C2 H2B 109.5 . .
C1 C2 H2C 109.5 . .
H2A C2 H2C 109.5 . .
H2B C2 H2C 109.5 . .
O4 C3 O3 123.2(14) . .
O4 C3 C4 120.9(18) . .
O3 C3 C4 115.9(17) . .
C3 O3 Zn1 103.8(9) . .
C3 C4 H4A 109.5 . .
C3 C4 H4B 109.5 . .
H4A C4 H4B 109.5 . .
C3 C4 H4C 109.5 . .
H4A C4 H4C 109.5 . .
H4B C4 H4C 109.5 . .
O4B C3B O3B 124.8(19) . .
O4B C3B C4B 120(2) . .
O3B C3B C4B 114(2) . .
C3B O3B Zn1 116.0(14) . .
C3B C4B H4B1 109.5 . .
C3B C4B H4B2 109.5 . .
H4B1 C4B H4B2 109.5 . .
C3B C4B H4B3 109.5 . .
H4B1 C4B H4B3 109.5 . .
H4B2 C4B H4B3 109.5 . .
C11 Si1 C11 112.4(5) . 2_657
C11 Si1 C31 106.9(3) . .
C11 Si1 C31 108.7(3) 2_657 .
C11 Si1 C31 108.7(3) . 2_657
C11 Si1 C31 106.8(3) 2_657 2_657
C31 Si1 C31 113.4(5) . 2_657
C16 C11 C12 116.9(7) . .
C16 C11 Si1 123.4(5) . .
C12 C11 Si1 119.4(6) . .
C13 C12 C11 121.6(8) . .
C13 C12 H12 119.2 . .
C11 C12 H12 119.2 . .
C12 C13 C14 120.0(7) . .
C12 C13 H13 120.0 . .
C14 C13 H13 120.0 . .
C15 C14 C13 119.0(7) . .
C15 C14 C17 123.0(8) . .
C13 C14 C17 118.0(7) . .
C16 C15 C14 120.2(8) . .
C16 C15 H15 119.9 . .
C14 C15 H15 119.9 . .
C15 C16 C11 121.8(7) . .
C15 C16 H16 119.1 . .
C11 C16 H16 119.1 . .
C18 C17 C14 174.4(9) . .
C17 C18 C21 174.7(10) . .
C22 C21 C26 116.9(7) . .
C22 C21 C18 122.0(7) . .
C26 C21 C18 121.2(7) . .
C23 C22 C21 119.1(8) . .
C23 C22 H22 120.4 . .
C21 C22 H22 120.4 . .
N24 C23 C22 124.6(8) . .
N24 C23 H23 117.7 . .
C22 C23 H23 117.7 . .
C23 N24 C25 116.9(6) . .
C23 N24 Zn1 121.1(5) . .
C25 N24 Zn1 121.9(5) . .
N24 C25 C26 123.2(7) . .
N24 C25 H25 118.4 . .
C26 C25 H25 118.4 . .
C25 C26 C21 119.1(7) . .
C25 C26 H26 120.4 . .
C21 C26 H26 120.4 . .
C36 C31 C32 116.2(7) . .
C36 C31 Si1 125.6(6) . .
C32 C31 Si1 117.7(6) . .
C33 C32 C31 123.0(8) . .
C33 C32 H32 118.5 . .
C31 C32 H32 118.5 . .
C34 C33 C32 119.5(8) . .
C34 C33 H33 120.2 . .
C32 C33 H33 120.2 . .
C33 C34 C35 119.5(8) . .
C33 C34 C37 120.7(8) . .
C35 C34 C37 119.7(8) . .
C36 C35 C34 119.4(8) . .
C36 C35 H35 120.3 . .
C34 C35 H35 120.3 . .
C31 C36 C35 122.2(8) . .
C31 C36 H36 118.9 . .
C35 C36 H36 118.9 . .
C38 C37 C34 177.2(10) . .
C37 C38 C41 178.5(10) . .
C42 C41 C46 116.8(8) . .
C42 C41 C38 123.0(9) . .
C46 C41 C38 120.2(8) . .
C41 C42 C43 120.2(9) . .
C41 C42 H42 119.9 . .
C43 C42 H42 119.9 . .
N44 C43 C42 123.0(9) . .
N44 C43 H43 118.5 . .
C42 C43 H43 118.5 . .
C45 N44 C43 117.4(7) . .
C45 N44 Zn1 123.8(6) . 4_546
C43 N44 Zn1 118.1(6) . 4_546
N44 C45 C46 123.2(8) . .
N44 C45 H45 118.4 . .
C46 C45 H45 118.4 . .
C41 C46 C45 119.4(8) . .
C41 C46 H46 120.3 . .
C45 C46 H46 120.3 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Zn1 O1 1.933(5) .
Zn1 O3B 1.942(13) .
Zn1 O3 2.011(11) .
Zn1 N44 2.056(6) 4_556
Zn1 N24 2.073(6) .
C1 O2 1.230(9) .
C1 O1 1.242(9) .
C1 C2 1.507(10) .
C2 H2A 0.9800 .
C2 H2B 0.9800 .
C2 H2C 0.9800 .
C3 O4 1.216(14) .
C3 O3 1.243(13) .
C3 C4 1.530(16) .
C4 H4A 0.9800 .
C4 H4B 0.9800 .
C4 H4C 0.9800 .
C3B O4B 1.212(17) .
C3B O3B 1.220(16) .
C3B C4B 1.533(17) .
C4B H4B1 0.9800 .
C4B H4B2 0.9800 .
C4B H4B3 0.9800 .
Si1 C11 1.868(7) .
Si1 C11 1.868(7) 2_657
Si1 C31 1.878(7) .
Si1 C31 1.878(7) 2_657
C11 C16 1.390(10) .
C11 C12 1.401(9) .
C12 C13 1.378(10) .
C12 H12 0.9500 .
C13 C14 1.391(11) .
C13 H13 0.9500 .
C14 C15 1.387(10) .
C14 C17 1.435(10) .
C15 C16 1.377(9) .
C15 H15 0.9500 .
C16 H16 0.9500 .
C17 C18 1.176(9) .
C18 C21 1.440(10) .
C21 C22 1.384(10) .
C21 C26 1.410(10) .
C22 C23 1.358(10) .
C22 H22 0.9500 .
C23 N24 1.323(9) .
C23 H23 0.9500 .
N24 C25 1.335(8) .
C25 C26 1.366(10) .
C25 H25 0.9500 .
C26 H26 0.9500 .
C31 C36 1.373(10) .
C31 C32 1.374(10) .
C32 C33 1.371(11) .
C32 H32 0.9500 .
C33 C34 1.356(11) .
C33 H33 0.9500 .
C34 C35 1.381(11) .
C34 C37 1.443(11) .
C35 C36 1.380(11) .
C35 H35 0.9500 .
C36 H36 0.9500 .
C37 C38 1.184(10) .
C38 C41 1.434(11) .
C41 C42 1.366(11) .
C41 C46 1.380(11) .
C42 C43 1.374(11) .
C42 H42 0.9500 .
C43 N44 1.325(10) .
C43 H43 0.9500 .
N44 C45 1.310(9) .
N44 Zn1 2.056(6) 4_546
C45 C46 1.389(10) .
C45 H45 0.9500 .
C46 H46 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O2 C1 O1 Zn1 1.4(10) . .
C2 C1 O1 Zn1 -175.6(6) . .
O4 C3 O3 Zn1 4(2) . .
C4 C3 O3 Zn1 -175(2) . .
O4B C3B O3B Zn1 3(4) . .
C4B C3B O3B Zn1 171(2) . .
C11 Si1 C11 C16 38.9(5) 2_657 .
C31 Si1 C11 C16 158.0(6) . .
C31 Si1 C11 C16 -79.2(7) 2_657 .
C11 Si1 C11 C12 -147.2(7) 2_657 .
C31 Si1 C11 C12 -28.0(7) . .
C31 Si1 C11 C12 94.8(6) 2_657 .
C16 C11 C12 C13 6.0(11) . .
Si1 C11 C12 C13 -168.4(6) . .
C11 C12 C13 C14 -1.2(12) . .
C12 C13 C14 C15 -3.9(12) . .
C12 C13 C14 C17 173.2(7) . .
C13 C14 C15 C16 4.0(11) . .
C17 C14 C15 C16 -172.9(7) . .
C14 C15 C16 C11 1.0(11) . .
C12 C11 C16 C15 -5.9(11) . .
Si1 C11 C16 C15 168.2(5) . .
C26 C21 C22 C23 2.9(12) . .
C18 C21 C22 C23 -177.3(8) . .
C21 C22 C23 N24 -0.5(14) . .
C22 C23 N24 C25 -1.5(13) . .
C22 C23 N24 Zn1 -179.5(7) . .
C23 N24 C25 C26 1.0(12) . .
Zn1 N24 C25 C26 178.9(6) . .
N24 C25 C26 C21 1.4(13) . .
C22 C21 C26 C25 -3.3(12) . .
C18 C21 C26 C25 176.8(7) . .
C11 Si1 C31 C36 99.3(7) . .
C11 Si1 C31 C36 -139.2(7) 2_657 .
C31 Si1 C31 C36 -20.5(6) 2_657 .
C11 Si1 C31 C32 -72.1(7) . .
C11 Si1 C31 C32 49.4(7) 2_657 .
C31 Si1 C31 C32 168.1(7) 2_657 .
C36 C31 C32 C33 -2.0(13) . .
Si1 C31 C32 C33 170.2(8) . .
C31 C32 C33 C34 5.3(15) . .
C32 C33 C34 C35 -5.1(14) . .
C32 C33 C34 C37 178.5(8) . .
C33 C34 C35 C36 1.9(13) . .
C37 C34 C35 C36 178.3(8) . .
C32 C31 C36 C35 -1.3(12) . .
Si1 C31 C36 C35 -172.9(6) . .
C34 C35 C36 C31 1.4(13) . .
C46 C41 C42 C43 0.2(14) . .
C38 C41 C42 C43 179.8(9) . .
C41 C42 C43 N44 -1.2(15) . .
C42 C43 N44 C45 1.0(13) . .
C42 C43 N44 Zn1 -170.1(8) . 4_546
C43 N44 C45 C46 0.0(12) . .
Zn1 N44 C45 C46 170.6(6) 4_546 .
C42 C41 C46 C45 0.7(12) . .
C38 C41 C46 C45 -178.8(7) . .
N44 C45 C46 C41 -0.9(13) . .
