#------------------------------------------------------------------------------
#$Date: 2016-02-13 14:50:18 +0200 (Sat, 13 Feb 2016) $
#$Revision: 176428 $
#$URL: svn://www.crystallography.net/cod/cif/4/51/35/4513542.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4513542
loop_
_publ_author_name
'Andreychuk, Nicholas R.'
'Allard, Sheena R.'
'Parent, Shawna L. M.'
'Assoud, Abdeljalil'
'MacKinnon, Craig D.'
_publ_section_title
;
 Not Too Big and Not Too Small: “Goldilocks” Anion Size for
 Three-Dimensional Metal--Organic Frameworks Containing Oligothiophene
 Dinitrile Ligands (C4H2S)n(CN)2(n= 1, 2, 3) Bridging Silver(I) Cations
;
_journal_issue                   9
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              4377
_journal_paper_doi               10.1021/acs.cgd.5b00698
_journal_volume                  15
_journal_year                    2015
_chemical_formula_sum            'C42 H30 Ag B F4 P2 S2'
_chemical_formula_weight         855.40
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 92.100(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   8.202(2)
_cell_length_b                   23.559(7)
_cell_length_c                   19.614(6)
_cell_measurement_temperature    296(2)
_cell_volume                     3787.5(19)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0739
_diffrn_reflns_av_sigmaI/netI    0.0528
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            39037
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         2.86
_exptl_absorpt_coefficient_mu    0.777
_exptl_absorpt_correction_T_max  0.9333
_exptl_absorpt_correction_T_min  0.7673
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'APEX II'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.500
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             1728
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.09
_refine_diff_density_max         1.159
_refine_diff_density_min         -0.927
_refine_diff_density_rms         0.101
_refine_ls_extinction_coef       0.00050(11)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.098
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     475
_refine_ls_number_reflns         7420
_refine_ls_number_restraints     252
_refine_ls_restrained_S_all      1.090
_refine_ls_R_factor_all          0.0925
_refine_ls_R_factor_gt           0.0591
_refine_ls_shift/su_max          0.012
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0150P)²+15.8795P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1131
_refine_ls_wR_factor_ref         0.1275
_reflns_number_gt                5158
_reflns_number_total             7420
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg5b00698_si_002.cif
_cod_data_source_block           4_AgBF4_C6H6
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3271 2015-04-21 07:52:19Z andrius 

 Adding full bibliography for 4513539--4513545.cif.
;
_cod_original_cell_volume        3787.4(19)
_cod_original_sg_symbol_H-M      P2_1/c
_cod_database_code               4513542
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.16751(6) 0.326330(17) 0.68685(2) 0.04233(15) Uani 1 1 d .
S1 S 0.25849(15) 0.52971(5) 0.75552(6) 0.0297(3) Uani 1 1 d .
S2 S 0.29806(16) 0.12702(5) 0.77690(7) 0.0320(3) Uani 1 1 d .
P1 P 0.08233(16) 0.42478(5) 0.69184(7) 0.0286(3) Uani 1 1 d .
P2 P 0.11109(16) 0.22802(5) 0.71244(7) 0.0312(3) Uani 1 1 d .
C1 C 0.2502(6) 0.47358(19) 0.6990(2) 0.0259(10) Uani 1 1 d U
C2 C 0.3833(6) 0.4735(2) 0.6595(3) 0.0341(12) Uani 1 1 d U
H2A H 0.4014 0.4464 0.6263 0.041 Uiso 1 1 calc R
C3 C 0.4907(6) 0.5188(2) 0.6743(3) 0.0356(12) Uani 1 1 d U
H3A H 0.5862 0.5248 0.6512 0.043 Uiso 1 1 calc R
C4 C 0.4418(6) 0.5530(2) 0.7254(2) 0.0268(10) Uani 1 1 d U
C5 C 0.2827(6) 0.1806(2) 0.7169(3) 0.0330(11) Uani 1 1 d U
C6 C 0.4125(6) 0.1795(2) 0.6754(3) 0.0382(12) Uani 1 1 d U
H6A H 0.4265 0.2054 0.6403 0.046 Uiso 1 1 calc R
C7 C 0.5232(6) 0.1353(2) 0.6910(3) 0.0346(12) Uani 1 1 d U
H7A H 0.6175 0.1288 0.6672 0.041 Uiso 1 1 calc R
C8 C 0.4773(6) 0.1030(2) 0.7447(2) 0.0290(11) Uani 1 1 d U
C9 C -0.0246(6) 0.4369(2) 0.7698(3) 0.0345(12) Uani 1 1 d U
C10 C -0.1244(7) 0.4830(2) 0.7799(3) 0.0400(13) Uani 1 1 d U
H10A H -0.1420 0.5092 0.7449 0.048 Uiso 1 1 calc R
C11 C -0.1988(7) 0.4908(3) 0.8414(3) 0.0508(16) Uani 1 1 d U
H11A H -0.2648 0.5223 0.8481 0.061 Uiso 1 1 calc R
C12 C -0.1745(10) 0.4521(4) 0.8919(4) 0.090(3) Uani 1 1 d U
H12A H -0.2249 0.4569 0.9332 0.108 Uiso 1 1 calc R
C13 C -0.0760(13) 0.4060(4) 0.8825(4) 0.124(4) Uani 1 1 d U
H13A H -0.0587 0.3800 0.9177 0.148 Uiso 1 1 calc R
C14 C -0.0027(10) 0.3980(3) 0.8214(3) 0.078(3) Uani 1 1 d U
H14A H 0.0618 0.3662 0.8150 0.093 Uiso 1 1 calc R
C15 C -0.0507(6) 0.4543(2) 0.6245(3) 0.0320(11) Uani 1 1 d U
C16 C -0.0449(7) 0.5108(2) 0.6049(3) 0.0397(13) Uani 1 1 d U
H16A H 0.0316 0.5348 0.6259 0.048 Uiso 1 1 calc R
C17 C -0.1510(7) 0.5319(3) 0.5546(3) 0.0511(16) Uani 1 1 d U
H17A H -0.1462 0.5699 0.5420 0.061 Uiso 1 1 calc R
C18 C -0.2641(7) 0.4961(3) 0.5233(3) 0.0549(17) Uani 1 1 d U
H18A H -0.3353 0.5100 0.4893 0.066 Uiso 1 1 calc R
C19 C -0.2720(8) 0.4405(3) 0.5419(3) 0.0571(17) Uani 1 1 d U
H19A H -0.3488 0.4168 0.5206 0.069 Uiso 1 1 calc R
C20 C -0.1661(7) 0.4188(3) 0.5927(3) 0.0435(14) Uani 1 1 d U
H20A H -0.1725 0.3809 0.6053 0.052 Uiso 1 1 calc R
C21 C 0.0177(6) 0.2138(2) 0.7934(3) 0.0336(12) Uani 1 1 d U
C22 C 0.0766(8) 0.2423(3) 0.8509(3) 0.0503(15) Uani 1 1 d U
H22A H 0.1548 0.2705 0.8467 0.060 Uiso 1 1 calc R
C23 C 0.0201(9) 0.2291(3) 0.9142(3) 0.0595(18) Uani 1 1 d U
H23A H 0.0625 0.2478 0.9527 0.071 Uiso 1 1 calc R
C24 C -0.0986(9) 0.1885(3) 0.9208(3) 0.0599(18) Uani 1 1 d U
H24A H -0.1395 0.1806 0.9633 0.072 Uiso 1 1 calc R
C25 C -0.1567(9) 0.1596(3) 0.8642(3) 0.0583(17) Uani 1 1 d U
H25A H -0.2344 0.1312 0.8687 0.070 Uiso 1 1 calc R
C26 C -0.1005(7) 0.1724(3) 0.8006(3) 0.0456(14) Uani 1 1 d U
H26A H -0.1422 0.1533 0.7623 0.055 Uiso 1 1 calc R
C27 C -0.0243(6) 0.1978(2) 0.6467(3) 0.0328(11) Uani 1 1 d U
C28 C -0.1430(7) 0.2323(3) 0.6153(3) 0.0474(15) Uani 1 1 d U
H28A H -0.1547 0.2696 0.6298 0.057 Uiso 1 1 calc R
C29 C -0.2444(7) 0.2114(3) 0.5625(3) 0.0569(18) Uani 1 1 d U
H29A H -0.3240 0.2346 0.5421 0.068 Uiso 1 1 calc R
C30 C -0.2263(8) 0.1566(3) 0.5407(3) 0.0602(19) Uani 1 1 d U
H30A H -0.2918 0.1431 0.5046 0.072 Uiso 1 1 calc R
C31 C -0.1125(8) 0.1217(3) 0.5716(3) 0.0564(17) Uani 1 1 d U
H31A H -0.1031 0.0842 0.5573 0.068 Uiso 1 1 calc R
C32 C -0.0110(7) 0.1420(2) 0.6243(3) 0.0427(14) Uani 1 1 d U
H32A H 0.0666 0.1181 0.6449 0.051 Uiso 1 1 calc R
B1 B 0.3715(14) 0.3194(3) 0.5463(4) 0.069(2) Uani 1 1 d U
F1 F 0.4522(10) 0.3259(3) 0.6067(3) 0.170(3) Uani 1 1 d U
F2 F 0.2428(14) 0.3505(4) 0.5525(4) 0.269(6) Uani 1 1 d U
F3 F 0.4343(10) 0.3366(4) 0.4907(4) 0.184(4) Uani 1 1 d U
F4 F 0.3319(8) 0.2660(2) 0.5409(3) 0.141(3) Uani 1 1 d U
C33 C 0.4993(13) 0.2859(6) 0.8759(6) 0.109(4) Uani 1 1 d U
H33A H 0.4964 0.2605 0.9122 0.130 Uiso 1 1 calc R
C34 C 0.5631(12) 0.3022(5) 0.7620(7) 0.111(3) Uani 1 1 d U
H34A H 0.5991 0.2886 0.7206 0.133 Uiso 1 1 calc R
C35 C 0.5528(12) 0.2681(4) 0.8153(7) 0.105(3) Uani 1 1 d U
H35A H 0.5836 0.2304 0.8108 0.126 Uiso 1 1 calc R
C36 C 0.4662(14) 0.3779(5) 0.8262(8) 0.126(4) Uani 1 1 d U
H36A H 0.4390 0.4161 0.8289 0.151 Uiso 1 1 calc R
C37 C 0.4491(13) 0.3410(7) 0.8851(7) 0.134(5) Uani 1 1 d U
H37A H 0.4073 0.3537 0.9258 0.160 Uiso 1 1 calc R
C38 C 0.5207(12) 0.3567(5) 0.7689(7) 0.110(4) Uani 1 1 d U
H38A H 0.5301 0.3807 0.7317 0.132 Uiso 1 1 calc R
C39B C -0.514(4) 0.4881(11) 1.0036(17) 0.057(9) Uiso 0.30(2) 1 d PU
C40A C -0.361(4) 0.5792(14) 0.9653(14) 0.075(12) Uiso 0.32(3) 1 d PU
C40B C -0.437(3) 0.5506(11) 0.9694(10) 0.085(9) Uiso 0.53(4) 1 d PU
C41A C -0.525(3) 0.5333(9) 0.9488(9) 0.064(8) Uiso 0.49(4) 1 d PU
C41B C -0.603(3) 0.5106(9) 0.9414(8) 0.074(7) Uiso 0.57(4) 1 d PU
C42A C -0.729(4) 0.4718(11) 0.9368(15) 0.088(11) Uiso 0.37(3) 1 d PU
C42B C -0.743(4) 0.4291(12) 0.9817(15) 0.098(12) Uiso 0.35(3) 1 d PU
C43 C -0.628(4) 0.4739(12) 0.9688(15) 0.083(11) Uiso 0.38(3) 1 d PU
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P2 Ag1 P1 148.21(5) . .
P2 Ag1 F1 106.05(13) . .
P1 Ag1 F1 105.53(13) . .
C4 S1 C1 92.2(2) . .
C8 S2 C5 91.9(2) . .
C1 P1 C9 103.1(2) . .
C1 P1 C15 104.5(2) . .
C9 P1 C15 104.9(2) . .
C1 P1 Ag1 113.22(16) . .
C9 P1 Ag1 109.50(17) . .
C15 P1 Ag1 120.13(17) . .
C5 P2 C27 104.4(2) . .
C5 P2 C21 101.3(2) . .
C27 P2 C21 106.4(2) . .
C5 P2 Ag1 116.74(17) . .
C27 P2 Ag1 110.17(17) . .
C21 P2 Ag1 116.61(17) . .
C2 C1 S1 110.6(4) . .
C2 C1 P1 125.8(4) . .
S1 C1 P1 123.6(3) . .
C1 C2 C3 113.1(5) . .
C4 C3 C2 113.7(5) . .
C3 C4 C8 129.1(4) . 2_656
C3 C4 S1 110.5(4) . .
C8 C4 S1 120.5(4) 2_656 .
C6 C5 S2 110.7(4) . .
C6 C5 P2 127.6(4) . .
S2 C5 P2 121.7(3) . .
C5 C6 C7 113.3(5) . .
C8 C7 C6 112.8(5) . .
C7 C8 C4 128.7(4) . 2_646
C7 C8 S2 111.3(4) . .
C4 C8 S2 120.0(4) 2_646 .
C14 C9 C10 118.9(5) . .
C14 C9 P1 117.5(4) . .
C10 C9 P1 123.6(4) . .
C9 C10 C11 120.8(5) . .
C12 C11 C10 119.3(6) . .
C11 C12 C13 120.4(6) . .
C12 C13 C14 120.4(7) . .
C13 C14 C9 120.1(6) . .
C16 C15 C20 118.7(5) . .
C16 C15 P1 122.8(4) . .
C20 C15 P1 118.4(4) . .
C17 C16 C15 121.1(5) . .
C18 C17 C16 119.4(6) . .
C19 C18 C17 120.4(6) . .
C18 C19 C20 120.6(6) . .
C15 C20 C19 119.7(6) . .
C26 C21 C22 119.0(5) . .
C26 C21 P2 122.4(4) . .
C22 C21 P2 118.4(4) . .
C23 C22 C21 120.4(6) . .
C22 C23 C24 120.3(6) . .
C25 C24 C23 119.7(6) . .
C24 C25 C26 120.4(6) . .
C25 C26 C21 120.2(5) . .
C32 C27 C28 118.3(5) . .
C32 C27 P2 122.8(4) . .
C28 C27 P2 118.9(4) . .
C27 C28 C29 120.7(6) . .
C30 C29 C28 119.7(6) . .
C31 C30 C29 120.6(6) . .
C30 C31 C32 120.2(6) . .
C31 C32 C27 120.6(6) . .
F3 B1 F4 110.0(8) . .
F3 B1 F2 104.7(8) . .
F4 B1 F2 110.6(11) . .
F3 B1 F1 120.7(10) . .
F4 B1 F1 107.1(7) . .
F2 B1 F1 103.3(8) . .
B1 F1 Ag1 95.7(6) . .
C35 C33 C37 121.1(12) . .
C35 C34 C38 118.5(13) . .
C34 C35 C33 122.7(11) . .
C38 C36 C37 119.5(11) . .
C33 C37 C36 115.0(12) . .
C36 C38 C34 123.1(12) . .
C39B C39B C41A 120(8) 3_467 3_467
C39B C39B C43 115(8) 3_467 .
C41A C39B C43 124(3) 3_467 .
C39B C39B C40B 165(8) 3_467 3_467
C41A C39B C40B 48.1(18) 3_467 3_467
C43 C39B C40B 76(2) . 3_467
C39B C39B C41B 85(7) 3_467 3_467
C41A C39B C41B 36.3(17) 3_467 3_467
C43 C39B C41B 160(3) . 3_467
C40B C39B C41B 84(2) 3_467 3_467
C39B C39B C41B 71(6) 3_467 .
C41A C39B C41B 167(3) 3_467 .
C43 C39B C41B 43.9(19) . .
C40B C39B C41B 120(3) 3_467 .
C41B C39B C41B 155(2) 3_467 .
C39B C39B C41A 39(6) 3_467 .
C41A C39B C41A 159(3) 3_467 .
C43 C39B C41A 76(3) . .
C40B C39B C41A 152(3) 3_467 .
C41B C39B C41A 123(2) 3_467 .
C41B C39B C41A 32.5(12) . .
C39B C39B C43 44(6) 3_467 3_467
C41A C39B C43 77(3) 3_467 3_467
C43 C39B C43 159(3) . 3_467
C40B C39B C43 125(3) 3_467 3_467
C41B C39B C43 40.8(16) 3_467 3_467
C41B C39B C43 115(2) . 3_467
C41A C39B C43 82(2) . 3_467
C39B C39B C40B 10(5) 3_467 .
C41A C39B C40B 128(3) 3_467 .
C43 C39B C40B 108(3) . .
C40B C39B C40B 175(3) 3_467 .
C41B C39B C40B 92(2) 3_467 .
C41B C39B C40B 63.9(17) . .
C41A C39B C40B 31.5(12) . .
C43 C39B C40B 51.0(15) 3_467 .
C40B C40A C42B 104(3) . 3_467
C40B C40A C41A 17.6(19) . .
C42B C40A C41A 121(3) 3_467 .
C40B C40A C43 52(2) . 3_467
C42B C40A C43 52(2) 3_467 3_467
C41A C40A C43 69.2(19) . 3_467
C40A C40B C41A 145(4) . .
C40A C40B C39B 151(4) . 3_467
C41A C40B C39B 64(3) . 3_467
C40A C40B C43 98(3) . 3_467
C41A C40B C43 117(3) . 3_467
C39B C40B C43 54(2) 3_467 3_467
C40A C40B C42B 46(2) . 3_467
C41A C40B C42B 168(3) . 3_467
C39B C40B C42B 105(2) 3_467 3_467
C43 C40B C42B 51.6(18) 3_467 3_467
C40A C40B C41B 154(3) . .
C41A C40B C41B 9.1(17) . .
C39B C40B C41B 55(2) 3_467 .
C43 C40B C41B 108(2) 3_467 .
C42B C40B C41B 159.6(18) 3_467 .
C40A C40B C39B 155(3) . .
C41A C40B C39B 60(3) . .
C39B C40B C39B 5(3) 3_467 .
C43 C40B C39B 57(2) 3_467 .
C42B C40B C39B 108.7(19) 3_467 .
C41B C40B C39B 51.0(16) . .
C41B C41A C40B 161(3) . .
C41B C41A C39B 93(3) . 3_467
C40B C41A C39B 68(2) . 3_467
C41B C41A C39B 73(2) . .
C40B C41A C39B 89(3) . .
C39B C41A C39B 21(3) 3_467 .
C41B C41A C43 29.7(18) . .
C40B C41A C43 132(3) . .
C39B C41A C43 64(2) 3_467 .
C39B C41A C43 43.0(15) . .
C41B C41A C40A 179(3) . .
C40B C41A C40A 17.8(19) . .
C39B C41A C40A 86(2) 3_467 .
C39B C41A C40A 106(2) . .
C43 C41A C40A 149(2) . .
C41B C41A C43 122(2) . 3_467
C40B C41A C43 38.9(19) . 3_467
C39B C41A C43 29.1(18) 3_467 3_467
C39B C41A C43 49.6(18) . 3_467
C43 C41A C43 92.6(16) . 3_467
C40A C41A C43 56.7(16) . 3_467
C41A C41B C43 127(3) . .
C41A C41B C42A 174(3) . .
C43 C41B C42A 48(2) . .
C41A C41B C39B 50.6(19) . 3_467
C43 C41B C39B 76(2) . 3_467
C42A C41B C39B 123(2) . 3_467
C41A C41B C39B 75(2) . .
C43 C41B C39B 52(2) . .
C42A C41B C39B 99.2(19) . .
C39B C41B C39B 25(2) 3_467 .
C41A C41B C40B 9.8(17) . .
C43 C41B C40B 117(2) . .
C42A C41B C40B 163.9(18) . .
C39B C41B C40B 40.8(12) 3_467 .
C39B C41B C40B 65.1(16) . .
C43 C42A C42B 74(3) . .
C43 C42A C41B 49(2) . .
C42B C42A C41B 122(3) . .
C42A C42B C40A 123(3) . 3_467
C42A C42B C43 42.8(16) . .
C40A C42B C43 81(3) 3_467 .
C42A C42B C40B 94(2) . 3_467
C40A C42B C40B 29.9(16) 3_467 3_467
C43 C42B C40B 50.9(18) . 3_467
C42A C43 C41B 84(3) . .
C42A C43 C39B 166(4) . .
C41B C43 C39B 84(3) . .
C42A C43 C40B 141(4) . 3_467
C41B C43 C40B 134(3) . 3_467
C39B C43 C40B 50(2) . 3_467
C42A C43 C42B 63(2) . .
C41B C43 C42B 147(3) . .
C39B C43 C42B 128(3) . .
C40B C43 C42B 77(2) 3_467 .
C42A C43 C39B 145(3) . 3_467
C41B C43 C39B 63(2) . 3_467
C39B C43 C39B 21(3) . 3_467
C40B C43 C39B 72(2) 3_467 3_467
C42B C43 C39B 148(3) . 3_467
C42A C43 C41A 107(3) . .
C41B C43 C41A 23.6(15) . .
C39B C43 C41A 61(2) . .
C40B C43 C41A 111(2) 3_467 .
C42B C43 C41A 169(3) . .
C39B C43 C41A 39.4(14) 3_467 .
C42A C43 C40A 110(3) . 3_467
C41B C43 C40A 164(3) . 3_467
C39B C43 C40A 81(2) . 3_467
C40B C43 C40A 30.5(15) 3_467 3_467
C42B C43 C40A 47.0(18) . 3_467
C39B C43 C40A 102(2) 3_467 3_467
C41A C43 C40A 141(2) . 3_467
C42A C43 C41A 163(3) . 3_467
C41B C43 C41A 111(2) . 3_467
C39B C43 C41A 26.8(16) . 3_467
C40B C43 C41A 23.6(14) 3_467 3_467
C42B C43 C41A 101(2) . 3_467
C39B C43 C41A 48.0(18) 3_467 3_467
C41A C43 C41A 87.4(16) . 3_467
C40A C43 C41A 54.1(16) 3_467 3_467
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 P2 2.4182(15) .
Ag1 P1 2.4254(15) .
Ag1 F1 2.862(9) .
S1 C4 1.724(5) .
S1 C1 1.726(5) .
S2 C8 1.718(5) .
S2 C5 1.728(5) .
P1 C1 1.795(5) .
P1 C9 1.814(5) .
P1 C15 1.820(5) .
P2 C5 1.796(5) .
P2 C27 1.816(5) .
P2 C21 1.820(6) .
C1 C2 1.361(7) .
C2 C3 1.406(7) .
C3 C4 1.359(7) .
C4 C8 1.464(6) 2_656
C5 C6 1.364(7) .
C6 C7 1.408(7) .
C7 C8 1.364(7) .
C8 C4 1.464(6) 2_646
C9 C14 1.372(8) .
C9 C10 1.379(7) .
C10 C11 1.385(7) .
C11 C12 1.356(8) .
C12 C13 1.370(10) .
C13 C14 1.373(9) .
C15 C16 1.387(7) .
C15 C20 1.392(7) .
C16 C17 1.384(7) .
C17 C18 1.382(9) .
C18 C19 1.361(9) .
C19 C20 1.395(8) .
C21 C26 1.385(7) .
C21 C22 1.384(7) .
C22 C23 1.377(9) .
C23 C24 1.375(9) .
C24 C25 1.372(9) .
C25 C26 1.379(8) .
C27 C32 1.391(7) .
C27 C28 1.394(7) .
C28 C29 1.394(8) .
C29 C30 1.370(10) .
C30 C31 1.370(9) .
C31 C32 1.389(8) .
B1 F3 1.287(10) .
B1 F4 1.303(9) .
B1 F2 1.295(11) .
B1 F1 1.344(10) .
C33 C35 1.350(15) .
C33 C37 1.374(15) .
C34 C35 1.323(14) .
C34 C38 1.338(13) .
C36 C38 1.323(15) .
C36 C37 1.456(17) .
C39B C39B 0.62(5) 3_467
C39B C41A 1.10(3) 3_467
C39B C43 1.18(4) .
C39B C40B 1.13(3) 3_467
C39B C41B 1.42(4) 3_467
C39B C41B 1.50(4) .
C39B C41A 1.51(4) .
C39B C43 1.55(5) 3_467
C39B C40B 1.74(4) .
C40A C40B 0.92(3) .
C40A C42B 1.34(4) 3_467
C40A C41A 1.75(5) .
C40A C43 1.80(5) 3_467
C40B C41A 0.91(3) .
C40B C39B 1.13(3) 3_467
C40B C43 1.43(4) 3_467
C40B C42B 1.80(4) 3_467
C40B C41B 1.73(4) .
C41A C41B 0.84(2) .
C41A C39B 1.10(3) 3_467
C41A C43 1.69(4) .
C41A C43 2.02(4) 3_467
C41B C43 1.04(3) .
C41B C42A 1.38(4) .
C41B C39B 1.42(4) 3_467
C42A C43 1.02(3) .
C42A C42B 1.34(4) .
C42B C40A 1.34(4) 3_467
C42B C43 1.44(4) .
C42B C40B 1.80(4) 3_467
C43 C40B 1.43(4) 3_467
C43 C39B 1.55(5) 3_467
C43 C40A 1.80(5) 3_467
C43 C41A 2.02(4) 3_467
