#------------------------------------------------------------------------------
#$Date: 2016-02-13 14:50:18 +0200 (Sat, 13 Feb 2016) $
#$Revision: 176428 $
#$URL: svn://www.crystallography.net/cod/cif/4/51/36/4513664.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4513664
loop_
_publ_author_name
'Liu, Qilun'
'Yuan, Zheliang'
'Wang, Hao-yang'
'Li, Yang'
'Wu, Yichen'
'Xu, Tao'
'Leng, Xuebing'
'Chen, Pinhong'
'Guo, Yin-long'
'Lin, Zhenyang'
'Liu, Guosheng'
_publ_section_title
;
 Abnormal Mesoionic Carbene Silver Complex: Synthesis, Reactivity, and
 Mechanistic Insight on Oxidative Fluorination
;
_journal_issue                   11
_journal_name_full               'ACS Catalysis'
_journal_page_first              6732
_journal_paper_doi               10.1021/acscatal.5b01885
_journal_volume                  5
_journal_year                    2015
_chemical_formula_sum            'C32 H40 Ag F2 N3 O3'
_chemical_formula_weight         660.54
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 98.130(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            16
_cell_length_a                   30.342(4)
_cell_length_b                   14.1754(17)
_cell_length_c                   27.882(3)
_cell_measurement_reflns_used    4468
_cell_measurement_temperature    140(2)
_cell_measurement_theta_max      25.49
_cell_measurement_theta_min      2.49
_cell_volume                     11872(2)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      140(2)
_diffrn_measured_fraction_theta_full 0.985
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1008
_diffrn_reflns_av_sigmaI/netI    0.1169
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       -43
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       39
_diffrn_reflns_limit_l_min       -40
_diffrn_reflns_number            58518
_diffrn_reflns_theta_full        30.74
_diffrn_reflns_theta_max         30.74
_diffrn_reflns_theta_min         1.36
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.729
_exptl_absorpt_correction_T_max  0.9306
_exptl_absorpt_correction_T_min  0.8678
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.478
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             5472
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.161
_refine_diff_density_min         -0.875
_refine_diff_density_rms         0.148
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.995
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     767
_refine_ls_number_reflns         18221
_refine_ls_number_restraints     48
_refine_ls_restrained_S_all      1.009
_refine_ls_R_factor_all          0.1307
_refine_ls_R_factor_gt           0.0561
_refine_ls_shift/su_max          0.030
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0700P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1319
_refine_ls_wR_factor_ref         0.1650
_reflns_number_gt                9339
_reflns_number_total             18221
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cs5b01885_si_002.cif
_cod_data_source_block           mo_dm13733_0m
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3271 2015-04-21 07:52:19Z andrius 

 Adding full bibliography for 4513663--4513664.cif.
;
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               4513664
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.108636(13) 0.36143(2) -0.000602(11) 0.01910(9) Uani 1 1 d .
Ag2 Ag 0.141675(13) 0.88986(2) 0.002434(11) 0.01768(9) Uani 1 1 d .
F1 F 0.27348(11) 0.0601(2) -0.05139(11) 0.0291(7) Uani 1 1 d .
F2 F -0.01224(11) 0.7275(2) 0.07789(11) 0.0304(7) Uani 1 1 d .
F3 F 0.26060(12) 0.5188(2) -0.07493(10) 0.0314(8) Uani 1 1 d .
F4 F -0.02419(11) 1.1923(2) 0.04972(11) 0.0305(7) Uani 1 1 d .
N1 N 0.16102(15) 0.3773(3) -0.13921(13) 0.0171(9) Uani 1 1 d .
N2 N 0.07147(15) 0.3621(3) 0.14535(14) 0.0185(9) Uani 1 1 d .
N3 N 0.17988(15) 0.8863(3) -0.14280(13) 0.0170(9) Uani 1 1 d .
N4 N 0.08736(15) 0.8761(3) 0.13952(13) 0.0177(9) Uani 1 1 d .
N5 N 0.24809(15) 0.2863(3) 0.24773(12) 0.0221(12) Uani 1 1 d .
O1 O 0.2548(2) 0.2907(3) 0.20586(15) 0.0648(17) Uani 1 1 d .
O2 O 0.2097(2) 0.3101(4) 0.2548(2) 0.088(2) Uani 1 1 d .
O3 O 0.2736(2) 0.2559(5) 0.28063(19) 0.094(2) Uani 1 1 d .
C1 C 0.14256(17) 0.3358(3) -0.06025(15) 0.0181(10) Uani 1 1 d .
C2 C 0.17656(19) 0.2662(3) -0.05774(16) 0.0197(11) Uani 1 1 d .
C3 C 0.18772(19) 0.2079(3) -0.01597(16) 0.0204(12) Uani 1 1 d .
H3A H 0.1721 0.2157 0.0110 0.024 Uiso 1 1 calc R
C4 C 0.21994(19) 0.1422(4) -0.01398(18) 0.0241(12) Uani 1 1 d .
H4A H 0.2275 0.1053 0.0144 0.029 Uiso 1 1 calc R
C5 C 0.24213(18) 0.1288(3) -0.05399(17) 0.0216(11) Uani 1 1 d .
C6 C 0.23363(18) 0.1797(3) -0.09510(17) 0.0195(11) Uani 1 1 d .
H6A H 0.2491 0.1682 -0.1218 0.023 Uiso 1 1 calc R
C7 C 0.20045(18) 0.2514(3) -0.09700(16) 0.0167(11) Uani 1 1 d .
C8 C 0.19130(19) 0.3095(4) -0.13743(16) 0.0184(12) Uani 1 1 d .
H8A H 0.2070 0.3004 -0.1642 0.022 Uiso 1 1 calc R
C9 C 0.13545(17) 0.3908(3) -0.10233(15) 0.0178(10) Uani 1 1 d .
C10 C 0.10016(18) 0.4661(3) -0.10792(17) 0.0211(11) Uani 1 1 d .
H10A H 0.0746 0.4452 -0.0921 0.025 Uiso 1 1 calc R
H10B H 0.0894 0.4759 -0.1428 0.025 Uiso 1 1 calc R
C11 C 0.11845(19) 0.5607(3) -0.08502(19) 0.0264(12) Uani 1 1 d .
H11A H 0.1292 0.5500 -0.0503 0.032 Uiso 1 1 calc R
H11B H 0.1443 0.5802 -0.1007 0.032 Uiso 1 1 calc R
C12 C 0.0853(2) 0.6405(4) -0.0894(2) 0.0322(13) Uani 1 1 d .
H12A H 0.0566 0.6163 -0.0814 0.039 Uiso 1 1 calc R
H12B H 0.0959 0.6895 -0.0652 0.039 Uiso 1 1 calc R
C13 C 0.0776(2) 0.6848(5) -0.1384(2) 0.0465(19) Uani 1 1 d .
H13A H 0.0556 0.7356 -0.1386 0.070 Uiso 1 1 calc R
H13B H 0.0664 0.6371 -0.1626 0.070 Uiso 1 1 calc R
H13C H 0.1056 0.7108 -0.1462 0.070 Uiso 1 1 calc R
C14 C 0.1549(2) 0.4371(4) -0.18450(18) 0.0218(12) Uani 1 1 d .
H14A H 0.1399 0.4970 -0.1770 0.026 Uiso 1 1 calc R
C15 C 0.1243(2) 0.3861(4) -0.22342(19) 0.0386(17) Uani 1 1 d .
H15A H 0.0963 0.3712 -0.2115 0.058 Uiso 1 1 calc R
H15B H 0.1386 0.3275 -0.2319 0.058 Uiso 1 1 calc R
H15C H 0.1183 0.4264 -0.2522 0.058 Uiso 1 1 calc R
C16 C 0.1993(2) 0.4625(4) -0.2006(2) 0.0308(14) Uani 1 1 d .
H16A H 0.2179 0.4955 -0.1743 0.046 Uiso 1 1 calc R
H16B H 0.1941 0.5035 -0.2291 0.046 Uiso 1 1 calc R
H16C H 0.2144 0.4048 -0.2088 0.046 Uiso 1 1 calc R
C17 C 0.07934(17) 0.3923(3) 0.06172(16) 0.0179(9) Uani 1 1 d .
C18 C 0.05626(18) 0.4780(3) 0.06550(16) 0.0168(11) Uani 1 1 d .
C19 C 0.04807(18) 0.5433(3) 0.02687(16) 0.0186(11) Uani 1 1 d .
H19A H 0.0588 0.5296 -0.0028 0.022 Uiso 1 1 calc R
C20 C 0.02548(19) 0.6247(3) 0.03063(17) 0.0225(11) Uani 1 1 d .
H20A H 0.0206 0.6674 0.0041 0.027 Uiso 1 1 calc R
C21 C 0.00937(17) 0.6451(3) 0.07451(17) 0.0181(10) Uani 1 1 d .
C22 C 0.01549(18) 0.5870(3) 0.11367(17) 0.0192(10) Uani 1 1 d .
H22A H 0.0042 0.6023 0.1428 0.023 Uiso 1 1 calc R
C23 C 0.03949(19) 0.5025(4) 0.10908(17) 0.0187(11) Uani 1 1 d .
C24 C 0.04847(19) 0.4409(4) 0.14852(18) 0.0197(11) Uani 1 1 d .
H24A H 0.0379 0.4558 0.1781 0.024 Uiso 1 1 calc R
C25 C 0.08541(17) 0.3346(3) 0.10228(15) 0.0166(9) Uani 1 1 d .
C26 C 0.10841(17) 0.2398(3) 0.10083(17) 0.0202(10) Uani 1 1 d .
H26A H 0.0959 0.1961 0.1231 0.024 Uiso 1 1 calc R
H26B H 0.1016 0.2137 0.0677 0.024 Uiso 1 1 calc R
C27 C 0.15826(18) 0.2434(3) 0.11460(16) 0.0216(11) Uani 1 1 d .
H27A H 0.1654 0.2667 0.1483 0.026 Uiso 1 1 calc R
H27B H 0.1709 0.2885 0.0931 0.026 Uiso 1 1 calc R
C28 C 0.17991(19) 0.1464(3) 0.11067(17) 0.0235(11) Uani 1 1 d .
H28A H 0.2122 0.1550 0.1102 0.028 Uiso 1 1 calc R
H28B H 0.1672 0.1168 0.0796 0.028 Uiso 1 1 calc R
C29 C 0.1732(2) 0.0795(4) 0.15248(19) 0.0277(13) Uani 1 1 d .
H29A H 0.1875 0.0188 0.1479 0.041 Uiso 1 1 calc R
H29B H 0.1413 0.0695 0.1528 0.041 Uiso 1 1 calc R
H29C H 0.1864 0.1074 0.1833 0.041 Uiso 1 1 calc R
C30 C 0.0824(2) 0.3056(4) 0.19151(17) 0.0202(12) Uani 1 1 d .
H30A H 0.1035 0.2541 0.1855 0.024 Uiso 1 1 calc R
C31 C 0.0403(2) 0.2603(4) 0.2043(2) 0.0325(14) Uani 1 1 d .
H31A H 0.0270 0.2205 0.1774 0.049 Uiso 1 1 calc R
H31B H 0.0191 0.3096 0.2104 0.049 Uiso 1 1 calc R
H31C H 0.0476 0.2216 0.2334 0.049 Uiso 1 1 calc R
C32 C 0.1054(2) 0.3683(4) 0.23156(19) 0.0389(17) Uani 1 1 d .
H32A H 0.1324 0.3953 0.2214 0.058 Uiso 1 1 calc R
H32B H 0.1135 0.3308 0.2610 0.058 Uiso 1 1 calc R
H32C H 0.0853 0.4193 0.2381 0.058 Uiso 1 1 calc R
C33 C 0.17196(17) 0.8582(3) -0.05907(15) 0.0173(9) Uani 1 1 d .
C34 C 0.19447(17) 0.7710(3) -0.06275(15) 0.0156(10) Uani 1 1 d .
C35 C 0.20196(19) 0.7052(4) -0.02356(16) 0.0188(11) Uani 1 1 d .
H35A H 0.1912 0.7192 0.0060 0.023 Uiso 1 1 calc R
C36 C 0.22421(19) 0.6230(3) -0.02785(16) 0.0206(11) Uani 1 1 d .
H36A H 0.2293 0.5800 -0.0015 0.025 Uiso 1 1 calc R
C37 C 0.23954(19) 0.6026(4) -0.07193(17) 0.0225(11) Uani 1 1 d .
C38 C 0.23458(18) 0.6611(3) -0.11029(16) 0.0179(10) Uani 1 1 d .
H38A H 0.2464 0.6459 -0.1391 0.021 Uiso 1 1 calc R
C39 C 0.21083(19) 0.7470(3) -0.10596(16) 0.0167(11) Uani 1 1 d .
C40 C 0.20232(19) 0.8066(4) -0.14496(16) 0.0171(11) Uani 1 1 d .
H40A H 0.2128 0.7902 -0.1744 0.021 Uiso 1 1 calc R
C41 C 0.16602(16) 0.9155(3) -0.09971(15) 0.0157(9) Uani 1 1 d .
C42 C 0.14328(16) 1.0093(3) -0.09892(15) 0.0163(9) Uani 1 1 d .
H42A H 0.1565 1.0530 -0.1206 0.020 Uiso 1 1 calc R
H42B H 0.1493 1.0353 -0.0657 0.020 Uiso 1 1 calc R
C43 C 0.09303(17) 1.0067(3) -0.11439(17) 0.0180(10) Uani 1 1 d .
H43A H 0.0867 0.9812 -0.1477 0.022 Uiso 1 1 calc R
H43B H 0.0795 0.9635 -0.0927 0.022 Uiso 1 1 calc R
C44 C 0.07155(18) 1.1037(3) -0.11299(16) 0.0209(10) Uani 1 1 d .
H44A H 0.0390 1.0957 -0.1141 0.025 Uiso 1 1 calc R
H44B H 0.0830 1.1346 -0.0819 0.025 Uiso 1 1 calc R
C45 C 0.0801(2) 1.1673(4) -0.15416(17) 0.0256(13) Uani 1 1 d .
H45A H 0.0657 1.2284 -0.1511 0.038 Uiso 1 1 calc R
H45B H 0.0681 1.1382 -0.1851 0.038 Uiso 1 1 calc R
H45C H 0.1123 1.1767 -0.1530 0.038 Uiso 1 1 calc R
C46 C 0.1689(2) 0.9408(4) -0.18948(17) 0.0231(14) Uani 1 1 d .
H46A H 0.1510 0.9973 -0.1828 0.028 Uiso 1 1 calc R
C47 C 0.1397(2) 0.8783(4) -0.22578(18) 0.0340(15) Uani 1 1 d .
H47A H 0.1131 0.8591 -0.2120 0.051 Uiso 1 1 calc R
H47B H 0.1565 0.8221 -0.2328 0.051 Uiso 1 1 calc R
H47C H 0.1308 0.9136 -0.2558 0.051 Uiso 1 1 calc R
C48 C 0.2112(2) 0.9751(4) -0.2068(2) 0.0319(14) Uani 1 1 d .
H48A H 0.2278 1.0148 -0.1818 0.048 Uiso 1 1 calc R
H48B H 0.2036 1.0119 -0.2366 0.048 Uiso 1 1 calc R
H48C H 0.2294 0.9208 -0.2133 0.048 Uiso 1 1 calc R
C49 C 0.10677(18) 0.9162(3) 0.06079(14) 0.0175(10) Uani 1 1 d .
C50 C 0.07240(18) 0.9858(3) 0.05747(16) 0.0176(11) Uani 1 1 d .
C51 C 0.0624(2) 1.0449(4) 0.01609(17) 0.0224(12) Uani 1 1 d .
H51A H 0.0788 1.0374 -0.0103 0.027 Uiso 1 1 calc R
C52 C 0.03000(19) 1.1117(3) 0.01342(16) 0.0215(11) Uani 1 1 d .
H52A H 0.0228 1.1485 -0.0151 0.026 Uiso 1 1 calc R
C53 C 0.00751(19) 1.1253(3) 0.05315(17) 0.0223(11) Uani 1 1 d .
C54 C 0.01496(18) 1.0727(3) 0.09404(16) 0.0189(11) Uani 1 1 d .
H54A H -0.0017 1.0825 0.1200 0.023 Uiso 1 1 calc R
C55 C 0.0485(2) 1.0022(3) 0.09687(16) 0.0177(11) Uani 1 1 d .
C56 C 0.05693(18) 0.9436(3) 0.13689(16) 0.0160(11) Uani 1 1 d .
H56A H 0.0405 0.9521 0.1631 0.019 Uiso 1 1 calc R
C57 C 0.11365(17) 0.8627(3) 0.10274(14) 0.0163(9) Uani 1 1 d .
C58 C 0.14878(17) 0.7862(3) 0.10968(16) 0.0172(10) Uani 1 1 d .
H58A H 0.1589 0.7774 0.1447 0.021 Uiso 1 1 calc R
H58B H 0.1748 0.8061 0.0943 0.021 Uiso 1 1 calc R
C59 C 0.13087(18) 0.6917(3) 0.08738(17) 0.0224(11) Uani 1 1 d .
H59A H 0.1043 0.6735 0.1021 0.027 Uiso 1 1 calc R
H59B H 0.1213 0.7010 0.0523 0.027 Uiso 1 1 calc R
C60 C 0.1641(2) 0.6112(4) 0.09405(19) 0.0285(12) Uani 1 1 d .
H60A H 0.1543 0.5612 0.0701 0.034 Uiso 1 1 calc R
H60B H 0.1934 0.6345 0.0874 0.034 Uiso 1 1 calc R
C61 C 0.1694(2) 0.5690(5) 0.1444(2) 0.0413(17) Uani 1 1 d .
H61A H 0.1913 0.5178 0.1466 0.062 Uiso 1 1 calc R
H61B H 0.1407 0.5441 0.1509 0.062 Uiso 1 1 calc R
H61C H 0.1797 0.6178 0.1682 0.062 Uiso 1 1 calc R
C62 C 0.0930(2) 0.8164(4) 0.18521(17) 0.0204(12) Uani 1 1 d .
H62A H 0.1074 0.7557 0.1778 0.024 Uiso 1 1 calc R
C63 C 0.1251(2) 0.8685(4) 0.22302(17) 0.0291(14) Uani 1 1 d .
H63A H 0.1297 0.8318 0.2531 0.044 Uiso 1 1 calc R
H63B H 0.1127 0.9304 0.2293 0.044 Uiso 1 1 calc R
H63C H 0.1537 0.8770 0.2110 0.044 Uiso 1 1 calc R
C64 C 0.0493(2) 0.7929(4) 0.20178(19) 0.0268(13) Uani 1 1 d .
H64A H 0.0303 0.7592 0.1759 0.040 Uiso 1 1 calc R
H64B H 0.0345 0.8512 0.2095 0.040 Uiso 1 1 calc R
H64C H 0.0546 0.7529 0.2307 0.040 Uiso 1 1 calc R
N6 N 0.0000 0.5469(5) 0.2500 0.0468(17) Uani 1 2 d SDU
O4 O 0.0076(4) 0.6157(5) 0.2756(3) 0.058(2) Uani 0.50 1 d PDU
O5 O 0.0188(3) 0.4760(5) 0.2700(3) 0.053(2) Uani 0.50 1 d PDU
O6 O -0.0205(4) 0.5284(8) 0.2116(2) 0.066(2) Uani 0.50 1 d PDU
N7 N 0.0000 0.0294(6) 0.2500 0.0498(18) Uani 1 2 d SDU
O7 O -0.0171(3) 0.0260(8) 0.2102(3) 0.055(2) Uani 0.50 1 d PDU
O8 O 0.0431(2) 0.0290(6) 0.2492(3) 0.048(2) Uani 0.50 1 d PDU
O9 O -0.0099(4) 0.0387(7) 0.2870(3) 0.050(2) Uani 0.50 1 d PDU
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C1 Ag1 C17 175.47(18) . .
C49 Ag2 C33 175.31(18) . .
C8 N1 C9 122.0(4) . .
C8 N1 C14 116.2(4) . .
C9 N1 C14 121.8(4) . .
C24 N2 C25 121.6(4) . .
C24 N2 C30 116.3(4) . .
C25 N2 C30 122.1(4) . .
C40 N3 C41 120.9(4) . .
C40 N3 C46 116.7(4) . .
C41 N3 C46 122.4(4) . .
C56 N4 C57 121.5(4) . .
C56 N4 C62 116.3(4) . .
C57 N4 C62 122.1(4) . .
O3 N5 O1 125.3(6) . .
O3 N5 O2 119.5(5) . .
O1 N5 O2 115.0(5) . .
C9 C1 C2 116.9(4) . .
C9 C1 Ag1 122.0(4) . .
C2 C1 Ag1 120.8(3) . .
C7 C2 C1 120.9(4) . .
C7 C2 C3 117.3(5) . .
C1 C2 C3 121.9(5) . .
C4 C3 C2 121.4(5) . .
C4 C3 H3A 119.3 . .
C2 C3 H3A 119.3 . .
C3 C4 C5 119.4(5) . .
C3 C4 H4A 120.3 . .
C5 C4 H4A 120.3 . .
C6 C5 F1 118.6(5) . .
C6 C5 C4 123.4(5) . .
F1 C5 C4 118.0(4) . .
C5 C6 C7 117.5(5) . .
C5 C6 H6A 121.2 . .
C7 C6 H6A 121.2 . .
C8 C7 C2 118.4(5) . .
C8 C7 C6 120.7(5) . .
C2 C7 C6 120.9(4) . .
N1 C8 C7 121.1(5) . .
N1 C8 H8A 119.4 . .
C7 C8 H8A 119.4 . .
N1 C9 C1 120.5(4) . .
N1 C9 C10 119.1(4) . .
C1 C9 C10 120.4(4) . .
C9 C10 C11 111.2(4) . .
C9 C10 H10A 109.4 . .
C11 C10 H10A 109.4 . .
C9 C10 H10B 109.4 . .
C11 C10 H10B 109.4 . .
H10A C10 H10B 108.0 . .
C12 C11 C10 114.8(5) . .
C12 C11 H11A 108.6 . .
C10 C11 H11A 108.6 . .
C12 C11 H11B 108.6 . .
C10 C11 H11B 108.6 . .
H11A C11 H11B 107.6 . .
C13 C12 C11 113.9(5) . .
C13 C12 H12A 108.8 . .
C11 C12 H12A 108.8 . .
C13 C12 H12B 108.8 . .
C11 C12 H12B 108.8 . .
H12A C12 H12B 107.7 . .
C12 C13 H13A 109.5 . .
C12 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
C12 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
C15 C14 N1 108.9(4) . .
C15 C14 C16 112.4(5) . .
N1 C14 C16 111.7(5) . .
C15 C14 H14A 107.9 . .
N1 C14 H14A 107.9 . .
C16 C14 H14A 107.9 . .
C14 C15 H15A 109.5 . .
C14 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
C14 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
C14 C16 H16A 109.5 . .
C14 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C14 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C25 C17 C18 117.1(4) . .
C25 C17 Ag1 121.8(3) . .
C18 C17 Ag1 120.7(3) . .
C17 C18 C19 122.8(4) . .
C17 C18 C23 120.9(4) . .
C19 C18 C23 116.4(5) . .
C20 C19 C18 122.3(5) . .
C20 C19 H19A 118.8 . .
C18 C19 H19A 118.8 . .
C19 C20 C21 118.9(4) . .
C19 C20 H20A 120.5 . .
C21 C20 H20A 120.5 . .
F2 C21 C22 118.8(4) . .
F2 C21 C20 118.0(4) . .
C22 C21 C20 123.2(4) . .
C21 C22 C23 117.0(4) . .
C21 C22 H22A 121.5 . .
C23 C22 H22A 121.5 . .
C24 C23 C22 120.1(4) . .
C24 C23 C18 117.7(5) . .
C22 C23 C18 122.2(5) . .
N2 C24 C23 121.2(5) . .
N2 C24 H24A 119.4 . .
C23 C24 H24A 119.4 . .
N2 C25 C17 121.3(4) . .
N2 C25 C26 118.1(4) . .
C17 C25 C26 120.6(4) . .
C27 C26 C25 114.3(4) . .
C27 C26 H26A 108.7 . .
C25 C26 H26A 108.7 . .
C27 C26 H26B 108.7 . .
C25 C26 H26B 108.7 . .
H26A C26 H26B 107.6 . .
C26 C27 C28 112.1(4) . .
C26 C27 H27A 109.2 . .
C28 C27 H27A 109.2 . .
C26 C27 H27B 109.2 . .
C28 C27 H27B 109.2 . .
H27A C27 H27B 107.9 . .
C27 C28 C29 113.2(4) . .
C27 C28 H28A 108.9 . .
C29 C28 H28A 108.9 . .
C27 C28 H28B 108.9 . .
C29 C28 H28B 108.9 . .
H28A C28 H28B 107.7 . .
C28 C29 H29A 109.5 . .
C28 C29 H29B 109.5 . .
H29A C29 H29B 109.5 . .
C28 C29 H29C 109.5 . .
H29A C29 H29C 109.5 . .
H29B C29 H29C 109.5 . .
N2 C30 C31 109.6(5) . .
N2 C30 C32 109.7(4) . .
C31 C30 C32 113.0(5) . .
N2 C30 H30A 108.1 . .
C31 C30 H30A 108.1 . .
C32 C30 H30A 108.1 . .
C30 C31 H31A 109.5 . .
C30 C31 H31B 109.5 . .
H31A C31 H31B 109.5 . .
C30 C31 H31C 109.5 . .
H31A C31 H31C 109.5 . .
H31B C31 H31C 109.5 . .
C30 C32 H32A 109.5 . .
C30 C32 H32B 109.5 . .
H32A C32 H32B 109.5 . .
C30 C32 H32C 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
C41 C33 C34 117.3(4) . .
C41 C33 Ag2 121.3(3) . .
C34 C33 Ag2 120.9(3) . .
C39 C34 C33 120.2(4) . .
C39 C34 C35 117.3(5) . .
C33 C34 C35 122.5(4) . .
C36 C35 C34 121.3(4) . .
C36 C35 H35A 119.4 . .
C34 C35 H35A 119.4 . .
C35 C36 C37 118.8(4) . .
C35 C36 H36A 120.6 . .
C37 C36 H36A 120.6 . .
C38 C37 F3 119.4(4) . .
C38 C37 C36 123.8(5) . .
F3 C37 C36 116.8(4) . .
C37 C38 C39 117.3(4) . .
C37 C38 H38A 121.3 . .
C39 C38 H38A 121.3 . .
C40 C39 C34 118.7(5) . .
C40 C39 C38 119.9(4) . .
C34 C39 C38 121.4(4) . .
N3 C40 C39 122.0(4) . .
N3 C40 H40A 119.0 . .
C39 C40 H40A 119.0 . .
C33 C41 N3 120.8(4) . .
C33 C41 C42 121.0(4) . .
N3 C41 C42 118.2(4) . .
C41 C42 C43 114.7(4) . .
C41 C42 H42A 108.6 . .
C43 C42 H42A 108.6 . .
C41 C42 H42B 108.6 . .
C43 C42 H42B 108.6 . .
H42A C42 H42B 107.6 . .
C44 C43 C42 112.6(4) . .
C44 C43 H43A 109.1 . .
C42 C43 H43A 109.1 . .
C44 C43 H43B 109.1 . .
C42 C43 H43B 109.1 . .
H43A C43 H43B 107.8 . .
C45 C44 C43 113.5(4) . .
C45 C44 H44A 108.9 . .
C43 C44 H44A 108.9 . .
C45 C44 H44B 108.9 . .
C43 C44 H44B 108.9 . .
H44A C44 H44B 107.7 . .
C44 C45 H45A 109.5 . .
C44 C45 H45B 109.5 . .
H45A C45 H45B 109.5 . .
C44 C45 H45C 109.5 . .
H45A C45 H45C 109.5 . .
H45B C45 H45C 109.5 . .
N3 C46 C48 110.3(5) . .
N3 C46 C47 108.1(4) . .
C48 C46 C47 114.4(5) . .
N3 C46 H46A 108.0 . .
C48 C46 H46A 108.0 . .
C47 C46 H46A 108.0 . .
C46 C47 H47A 109.5 . .
C46 C47 H47B 109.5 . .
H47A C47 H47B 109.5 . .
C46 C47 H47C 109.5 . .
H47A C47 H47C 109.5 . .
H47B C47 H47C 109.5 . .
C46 C48 H48A 109.5 . .
C46 C48 H48B 109.5 . .
H48A C48 H48B 109.5 . .
C46 C48 H48C 109.5 . .
H48A C48 H48C 109.5 . .
H48B C48 H48C 109.5 . .
C57 C49 C50 117.0(4) . .
C57 C49 Ag2 121.7(4) . .
C50 C49 Ag2 121.1(3) . .
C55 C50 C51 117.3(5) . .
C55 C50 C49 120.7(4) . .
C51 C50 C49 121.9(4) . .
C52 C51 C50 121.6(5) . .
C52 C51 H51A 119.2 . .
C50 C51 H51A 119.2 . .
C51 C52 C53 119.0(5) . .
C51 C52 H52A 120.5 . .
C53 C52 H52A 120.5 . .
F4 C53 C54 118.8(5) . .
F4 C53 C52 117.8(4) . .
C54 C53 C52 123.4(5) . .
C53 C54 C55 117.8(5) . .
C53 C54 H54A 121.1 . .
C55 C54 H54A 121.1 . .
C56 C55 C50 118.1(5) . .
C56 C55 C54 121.0(5) . .
C50 C55 C54 120.8(4) . .
N4 C56 C55 121.7(5) . .
N4 C56 H56A 119.2 . .
C55 C56 H56A 119.2 . .
C49 C57 N4 120.8(4) . .
C49 C57 C58 121.3(4) . .
N4 C57 C58 117.9(4) . .
C57 C58 C59 111.7(4) . .
C57 C58 H58A 109.3 . .
C59 C58 H58A 109.3 . .
C57 C58 H58B 109.3 . .
C59 C58 H58B 109.3 . .
H58A C58 H58B 108.0 . .
C60 C59 C58 114.5(5) . .
C60 C59 H59A 108.6 . .
C58 C59 H59A 108.6 . .
C60 C59 H59B 108.6 . .
C58 C59 H59B 108.6 . .
H59A C59 H59B 107.6 . .
C61 C60 C59 113.2(5) . .
C61 C60 H60A 108.9 . .
C59 C60 H60A 108.9 . .
C61 C60 H60B 108.9 . .
C59 C60 H60B 108.9 . .
H60A C60 H60B 107.8 . .
C60 C61 H61A 109.5 . .
C60 C61 H61B 109.5 . .
H61A C61 H61B 109.5 . .
C60 C61 H61C 109.5 . .
H61A C61 H61C 109.5 . .
H61B C61 H61C 109.5 . .
C64 C62 N4 112.5(5) . .
C64 C62 C63 113.7(4) . .
N4 C62 C63 107.1(4) . .
C64 C62 H62A 107.8 . .
N4 C62 H62A 107.8 . .
C63 C62 H62A 107.8 . .
C62 C63 H63A 109.5 . .
C62 C63 H63B 109.5 . .
H63A C63 H63B 109.5 . .
C62 C63 H63C 109.5 . .
H63A C63 H63C 109.5 . .
H63B C63 H63C 109.5 . .
C62 C64 H64A 109.5 . .
C62 C64 H64B 109.5 . .
H64A C64 H64B 109.5 . .
C62 C64 H64C 109.5 . .
H64A C64 H64C 109.5 . .
H64B C64 H64C 109.5 . .
O6 N6 O6 154.5(12) 2 .
O6 N6 O4 137.8(9) 2 2
O6 N6 O4 67.3(6) . 2
O6 N6 O4 67.3(6) 2 .
O6 N6 O4 137.8(9) . .
O4 N6 O4 72.8(9) 2 .
O6 N6 O5 43.3(6) 2 .
O6 N6 O5 111.8(8) . .
O4 N6 O5 161.6(7) 2 .
O4 N6 O5 110.4(5) . .
O6 N6 O5 111.8(8) 2 2
O6 N6 O5 43.3(6) . 2
O4 N6 O5 110.4(5) 2 2
O4 N6 O5 161.6(7) . 2
O5 N6 O5 72.6(9) . 2
N6 O4 O6 55.5(4) . 2
N6 O4 O4 53.6(5) . 2
O6 O4 O4 107.9(4) 2 2
O6 O5 N6 64.8(6) 2 .
O6 O5 O5 113.8(10) 2 2
N6 O5 O5 53.7(4) . 2
O5 O6 N6 72.0(7) 2 .
O5 O6 O4 128.7(9) 2 2
N6 O6 O4 57.2(6) . 2
O9 N7 O9 166.6(14) . 2
O9 N7 O7 42.7(6) . 2
O9 N7 O7 138.1(6) 2 2
O9 N7 O7 138.1(6) . .
O9 N7 O7 42.7(6) 2 .
O7 N7 O7 175.2(15) 2 .
O9 N7 O8 65.8(6) . 2
O9 N7 O8 114.3(6) 2 2
O7 N7 O8 107.3(5) 2 2
O7 N7 O8 72.6(5) . 2
O9 N7 O8 114.3(6) . .
O9 N7 O8 65.8(6) 2 .
O7 N7 O8 72.6(5) 2 .
O7 N7 O8 107.3(5) . .
O8 N7 O8 179.5(11) 2 .
O9 O7 N7 66.3(7) 2 .
O9 O7 O8 123.4(10) 2 2
N7 O7 O8 58.5(4) . 2
N7 O8 O9 50.3(4) . 2
N7 O8 O7 48.9(4) . 2
O9 O8 O7 99.1(6) 2 2
O7 O9 N7 71.0(7) 2 .
O7 O9 O8 132.8(11) 2 2
N7 O9 O8 63.9(5) . 2
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 C1 2.108(5) .
Ag1 C17 2.107(4) .
Ag2 C49 2.097(5) .
Ag2 C33 2.105(4) .
F1 C5 1.356(6) .
F2 C21 1.349(5) .
F3 C37 1.358(5) .
F4 C53 1.346(6) .
N1 C8 1.325(7) .
N1 C9 1.386(6) .
N1 C14 1.510(6) .
N2 C24 1.326(6) .
N2 C25 1.385(6) .
N2 C30 1.513(6) .
N3 C40 1.326(6) .
N3 C41 1.391(5) .
N3 C46 1.509(6) .
N4 C56 1.325(6) .
N4 C57 1.398(6) .
N4 C62 1.519(6) .
N5 O3 1.193(6) .
N5 O1 1.215(5) .
N5 O2 1.256(7) .
C1 C9 1.400(6) .
C1 C2 1.422(7) .
C2 C7 1.411(7) .
C2 C3 1.429(6) .
C3 C4 1.345(7) .
C3 H3A 0.9500 .
C4 C5 1.395(7) .
C4 H4A 0.9500 .
C5 C6 1.348(7) .
C6 C7 1.427(7) .
C6 H6A 0.9500 .
C7 C8 1.392(6) .
C8 H8A 0.9500 .
C9 C10 1.504(7) .
C10 C11 1.554(7) .
C10 H10A 0.9900 .
C10 H10B 0.9900 .
C11 C12 1.507(7) .
C11 H11A 0.9900 .
C11 H11B 0.9900 .
C12 C13 1.493(8) .
C12 H12A 0.9900 .
C12 H12B 0.9900 .
C13 H13A 0.9800 .
C13 H13B 0.9800 .
C13 H13C 0.9800 .
C14 C15 1.508(7) .
C14 C16 1.523(8) .
C14 H14A 1.0000 .
C15 H15A 0.9800 .
C15 H15B 0.9800 .
C15 H15C 0.9800 .
C16 H16A 0.9800 .
C16 H16B 0.9800 .
C16 H16C 0.9800 .
C17 C25 1.386(6) .
C17 C18 1.414(6) .
C18 C19 1.416(6) .
C18 C23 1.425(6) .
C19 C20 1.353(7) .
C19 H19A 0.9500 .
C20 C21 1.410(7) .
C20 H20A 0.9500 .
C21 C22 1.359(6) .
C22 C23 1.417(7) .
C22 H22A 0.9500 .
C23 C24 1.400(7) .
C24 H24A 0.9500 .
C25 C26 1.517(6) .
C26 C27 1.508(7) .
C26 H26A 0.9900 .
C26 H26B 0.9900 .
C27 C28 1.535(7) .
C27 H27A 0.9900 .
C27 H27B 0.9900 .
C28 C29 1.539(7) .
C28 H28A 0.9900 .
C28 H28B 0.9900 .
C29 H29A 0.9800 .
C29 H29B 0.9800 .
C29 H29C 0.9800 .
C30 C31 1.515(8) .
C30 C32 1.519(7) .
C30 H30A 1.0000 .
C31 H31A 0.9800 .
C31 H31B 0.9800 .
C31 H31C 0.9800 .
C32 H32A 0.9800 .
C32 H32B 0.9800 .
C32 H32C 0.9800 .
C33 C41 1.385(6) .
C33 C34 1.423(7) .
C34 C39 1.408(6) .
C34 C35 1.430(6) .
C35 C36 1.361(7) .
C35 H35A 0.9500 .
C36 C37 1.404(6) .
C36 H36A 0.9500 .
C37 C38 1.345(6) .
C38 C39 1.428(7) .
C38 H38A 0.9500 .
C39 C40 1.373(6) .
C40 H40A 0.9500 .
C41 C42 1.500(6) .
C42 C43 1.525(7) .
C42 H42A 0.9900 .
C42 H42B 0.9900 .
C43 C44 1.525(6) .
C43 H43A 0.9900 .
C43 H43B 0.9900 .
C44 C45 1.511(6) .
C44 H44A 0.9900 .
C44 H44B 0.9900 .
C45 H45A 0.9800 .
C45 H45B 0.9800 .
C45 H45C 0.9800 .
C46 C48 1.512(8) .
C46 C47 1.530(7) .
C46 H46A 1.0000 .
C47 H47A 0.9800 .
C47 H47B 0.9800 .
C47 H47C 0.9800 .
C48 H48A 0.9800 .
C48 H48B 0.9800 .
C48 H48C 0.9800 .
C49 C57 1.385(6) .
C49 C50 1.429(7) .
C50 C55 1.418(7) .
C50 C51 1.423(6) .
C51 C52 1.360(7) .
C51 H51A 0.9500 .
C52 C53 1.394(7) .
C52 H52A 0.9500 .
C53 C54 1.354(6) .
C54 C55 1.421(7) .
C54 H54A 0.9500 .
C55 C56 1.385(6) .
C56 H56A 0.9500 .
C57 C58 1.513(7) .
C58 C59 1.544(6) .
C58 H58A 0.9900 .
C58 H58B 0.9900 .
C59 C60 1.516(7) .
C59 H59A 0.9900 .
C59 H59B 0.9900 .
C60 C61 1.512(8) .
C60 H60A 0.9900 .
C60 H60B 0.9900 .
C61 H61A 0.9800 .
C61 H61B 0.9800 .
C61 H61C 0.9800 .
C62 C64 1.501(8) .
C62 C63 1.523(7) .
C62 H62A 1.0000 .
C63 H63A 0.9800 .
C63 H63B 0.9800 .
C63 H63C 0.9800 .
C64 H64A 0.9800 .
C64 H64B 0.9800 .
C64 H64C 0.9800 .
N6 O6 1.188(7) 2
N6 O6 1.188(7) .
N6 O4 1.211(7) 2
N6 O4 1.211(7) .
N6 O5 1.249(7) .
N6 O5 1.249(7) 2
O4 O6 1.330(12) 2
O4 O4 1.438(17) 2
O5 O6 0.901(11) 2
O5 O5 1.479(16) 2
O6 O5 0.901(11) 2
O6 O4 1.330(12) 2
N7 O9 1.122(6) .
N7 O9 1.122(6) 2
N7 O7 1.158(6) 2
N7 O7 1.158(6) .
N7 O8 1.310(6) 2
N7 O8 1.310(6) .
O7 O9 0.831(12) 2
O7 O8 1.467(11) 2
O8 O9 1.330(12) 2
O8 O7 1.467(11) 2
O9 O7 0.831(12) 2
O9 O8 1.330(12) 2
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C17 Ag1 C1 C9 -102(2) . .
C17 Ag1 C1 C2 73(2) . .
C9 C1 C2 C7 -2.6(7) . .
Ag1 C1 C2 C7 -177.6(4) . .
C9 C1 C2 C3 178.0(5) . .
Ag1 C1 C2 C3 3.0(7) . .
C7 C2 C3 C4 0.6(8) . .
C1 C2 C3 C4 180.0(5) . .
C2 C3 C4 C5 -1.8(8) . .
C3 C4 C5 C6 1.1(8) . .
C3 C4 C5 F1 -178.0(5) . .
F1 C5 C6 C7 179.9(4) . .
C4 C5 C6 C7 0.8(8) . .
C1 C2 C7 C8 2.8(8) . .
C3 C2 C7 C8 -177.8(5) . .
C1 C2 C7 C6 -178.1(5) . .
C3 C2 C7 C6 1.4(7) . .
C5 C6 C7 C8 177.1(5) . .
C5 C6 C7 C2 -2.0(8) . .
C9 N1 C8 C7 -3.3(8) . .
C14 N1 C8 C7 178.6(5) . .
C2 C7 C8 N1 0.2(8) . .
C6 C7 C8 N1 -179.0(5) . .
C8 N1 C9 C1 3.5(7) . .
C14 N1 C9 C1 -178.5(4) . .
C8 N1 C9 C10 -177.0(5) . .
C14 N1 C9 C10 1.0(7) . .
C2 C1 C9 N1 -0.5(7) . .
Ag1 C1 C9 N1 174.4(3) . .
C2 C1 C9 C10 -179.9(4) . .
Ag1 C1 C9 C10 -5.0(6) . .
N1 C9 C10 C11 -93.1(5) . .
C1 C9 C10 C11 86.4(6) . .
C9 C10 C11 C12 179.5(4) . .
C10 C11 C12 C13 -77.2(7) . .
C8 N1 C14 C15 82.5(6) . .
C9 N1 C14 C15 -95.6(6) . .
C8 N1 C14 C16 -42.1(6) . .
C9 N1 C14 C16 139.7(5) . .
C1 Ag1 C17 C25 -84(2) . .
C1 Ag1 C17 C18 90(2) . .
C25 C17 C18 C19 179.7(5) . .
Ag1 C17 C18 C19 5.7(7) . .
C25 C17 C18 C23 -1.0(7) . .
Ag1 C17 C18 C23 -174.9(4) . .
C17 C18 C19 C20 179.2(5) . .
C23 C18 C19 C20 -0.2(8) . .
C18 C19 C20 C21 -0.2(8) . .
C19 C20 C21 F2 178.6(5) . .
C19 C20 C21 C22 0.2(8) . .
F2 C21 C22 C23 -178.2(5) . .
C20 C21 C22 C23 0.2(8) . .
C21 C22 C23 C24 177.7(5) . .
C21 C22 C23 C18 -0.6(8) . .
C17 C18 C23 C24 2.9(8) . .
C19 C18 C23 C24 -177.7(5) . .
C17 C18 C23 C22 -178.7(5) . .
C19 C18 C23 C22 0.6(8) . .
C25 N2 C24 C23 -3.7(8) . .
C30 N2 C24 C23 175.0(5) . .
C22 C23 C24 N2 -178.9(5) . .
C18 C23 C24 N2 -0.5(8) . .
C24 N2 C25 C17 5.8(8) . .
C30 N2 C25 C17 -172.9(5) . .
C24 N2 C25 C26 -175.3(5) . .
C30 N2 C25 C26 6.0(7) . .
C18 C17 C25 N2 -3.2(7) . .
Ag1 C17 C25 N2 170.6(4) . .
C18 C17 C25 C26 177.9(5) . .
Ag1 C17 C25 C26 -8.3(6) . .
N2 C25 C26 C27 -89.6(5) . .
C17 C25 C26 C27 89.3(6) . .
C25 C26 C27 C28 -177.9(4) . .
C26 C27 C28 C29 -75.6(5) . .
C24 N2 C30 C31 70.9(6) . .
C25 N2 C30 C31 -110.3(5) . .
C24 N2 C30 C32 -53.7(7) . .
C25 N2 C30 C32 125.1(5) . .
C49 Ag2 C33 C41 82(2) . .
C49 Ag2 C33 C34 -90(2) . .
C41 C33 C34 C39 1.8(7) . .
Ag2 C33 C34 C39 173.9(4) . .
C41 C33 C34 C35 -179.0(5) . .
Ag2 C33 C34 C35 -6.8(7) . .
C39 C34 C35 C36 0.3(8) . .
C33 C34 C35 C36 -179.0(5) . .
C34 C35 C36 C37 -0.7(8) . .
C35 C36 C37 C38 1.8(9) . .
C35 C36 C37 F3 -178.4(5) . .
F3 C37 C38 C39 177.8(5) . .
C36 C37 C38 C39 -2.4(8) . .
C33 C34 C39 C40 -3.7(8) . .
C35 C34 C39 C40 177.0(5) . .
C33 C34 C39 C38 178.3(5) . .
C35 C34 C39 C38 -1.0(8) . .
C37 C38 C39 C40 -175.9(5) . .
C37 C38 C39 C34 2.0(8) . .
C41 N3 C40 C39 3.5(8) . .
C46 N3 C40 C39 -174.3(5) . .
C34 C39 C40 N3 1.1(8) . .
C38 C39 C40 N3 179.0(5) . .
C34 C33 C41 N3 2.8(7) . .
Ag2 C33 C41 N3 -169.3(4) . .
C34 C33 C41 C42 -179.1(4) . .
Ag2 C33 C41 C42 8.8(6) . .
C40 N3 C41 C33 -5.6(7) . .
C46 N3 C41 C33 172.1(5) . .
C40 N3 C41 C42 176.2(5) . .
C46 N3 C41 C42 -6.1(7) . .
C33 C41 C42 C43 -90.8(5) . .
N3 C41 C42 C43 87.4(5) . .
C41 C42 C43 C44 -180.0(4) . .
C42 C43 C44 C45 74.5(5) . .
C40 N3 C46 C48 -64.6(6) . .
C41 N3 C46 C48 117.7(5) . .
C40 N3 C46 C47 61.1(7) . .
C41 N3 C46 C47 -116.6(5) . .
C33 Ag2 C49 C57 104(2) . .
C33 Ag2 C49 C50 -72(2) . .
C57 C49 C50 C55 3.6(7) . .
Ag2 C49 C50 C55 179.1(4) . .
C57 C49 C50 C51 180.0(5) . .
Ag2 C49 C50 C51 -4.5(7) . .
C55 C50 C51 C52 -2.7(8) . .
C49 C50 C51 C52 -179.2(5) . .
C50 C51 C52 C53 3.0(8) . .
C51 C52 C53 F4 179.5(5) . .
C51 C52 C53 C54 -2.7(8) . .
F4 C53 C54 C55 179.9(5) . .
C52 C53 C54 C55 2.2(8) . .
C51 C50 C55 C56 178.2(5) . .
C49 C50 C55 C56 -5.2(7) . .
C51 C50 C55 C54 2.2(7) . .
C49 C50 C55 C54 178.7(5) . .
C53 C54 C55 C56 -177.8(5) . .
C53 C54 C55 C50 -1.9(8) . .
C57 N4 C56 C55 2.3(8) . .
C62 N4 C56 C55 -179.5(5) . .
C50 C55 C56 N4 2.3(8) . .
C54 C55 C56 N4 178.3(5) . .
C50 C49 C57 N4 1.0(7) . .
Ag2 C49 C57 N4 -174.5(3) . .
C50 C49 C57 C58 179.2(4) . .
Ag2 C49 C57 C58 3.7(6) . .
C56 N4 C57 C49 -4.1(7) . .
C62 N4 C57 C49 177.9(4) . .
C56 N4 C57 C58 177.7(4) . .
C62 N4 C57 C58 -0.4(6) . .
C49 C57 C58 C59 -85.8(6) . .
N4 C57 C58 C59 92.5(5) . .
C57 C58 C59 C60 -178.6(4) . .
C58 C59 C60 C61 77.7(6) . .
C56 N4 C62 C64 40.4(6) . .
C57 N4 C62 C64 -141.5(5) . .
C56 N4 C62 C63 -85.3(6) . .
C57 N4 C62 C63 92.9(5) . .
O6 N6 O4 O6 174.5(5) . 2
O4 N6 O4 O6 -165.8(11) 2 2
O5 N6 O4 O6 -4.9(9) . 2
O5 N6 O4 O6 91(2) 2 2
O6 N6 O4 O4 165.8(11) 2 2
O6 N6 O4 O4 -19.7(15) . 2
O5 N6 O4 O4 160.9(7) . 2
O5 N6 O4 O4 -103(2) 2 2
O6 N6 O5 O6 -173.0(5) . 2
O4 N6 O5 O6 103(2) 2 2
O4 N6 O5 O6 6.6(13) . 2
O5 N6 O5 O6 -154.2(14) 2 2
O6 N6 O5 O5 154.2(14) 2 2
O6 N6 O5 O5 -18.7(10) . 2
O4 N6 O5 O5 -102(2) 2 2
O4 N6 O5 O5 160.8(7) . 2
O6 N6 O6 O5 15.3(9) 2 2
O4 N6 O6 O5 -173.3(13) 2 2
O4 N6 O6 O5 -152.9(10) . 2
O5 N6 O6 O5 26.6(16) . 2
O6 N6 O6 O4 -171.4(6) 2 2
O4 N6 O6 O4 20.4(15) . 2
O5 N6 O6 O4 -160.2(7) . 2
O5 N6 O6 O4 173.3(13) 2 2
O9 N7 O7 O9 160(2) . 2
O7 N7 O7 O9 -102.5(12) 2 2
O8 N7 O7 O9 167.0(14) 2 2
O8 N7 O7 O9 -13.6(15) . 2
O9 N7 O7 O8 -6.9(13) . 2
O9 N7 O7 O8 -167.0(14) 2 2
O7 N7 O7 O8 90.5(5) 2 2
O8 N7 O7 O8 179.4(12) . 2
O9 N7 O8 O9 -165.3(15) . 2
O7 N7 O8 O9 -174.9(10) 2 2
O7 N7 O8 O9 10.1(11) . 2
O8 N7 O8 O9 97.3(8) 2 2
O9 N7 O8 O7 9.7(10) . 2
O9 N7 O8 O7 174.9(10) 2 2
O7 N7 O8 O7 -175.0(16) . 2
O8 N7 O8 O7 -87.8(12) 2 2
O9 N7 O9 O7 -100.9(12) 2 2
O7 N7 O9 O7 173(2) . 2
O8 N7 O9 O7 165.7(15) 2 2
O8 N7 O9 O7 -13.7(15) . 2
O9 N7 O9 O8 93.3(6) 2 2
O7 N7 O9 O8 -165.7(15) 2 2
O7 N7 O9 O8 7.3(14) . 2
O8 N7 O9 O8 -179.4(12) . 2
