#------------------------------------------------------------------------------
#$Date: 2016-08-05 00:44:57 +0300 (Fri, 05 Aug 2016) $
#$Revision: 184846 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/51/39/4513929.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4513929
loop_
_publ_author_name
'Xu, Liang-Jin'
'Zeng, Xian-Chong'
'Wang, Jin-Yun'
'Zhang, Li-Yi'
'Chi, Yun'
'Chen, Zhong-Ning'
_publ_section_title
;
 Phosphorescent PtAu2 Complexes with Differently Positioned
 Carbazole-Acetylide Ligands for Solution-Processed Organic Light-Emitting
 Diodes with External Quantum Efficiencies of over 20.
;
_journal_name_full               'ACS applied materials & interfaces'
_journal_paper_doi               10.1021/acsami.6b06707
_journal_year                    2016
_chemical_formula_sum            'C108 H92 Au2 Cl2 N2 O9 P6 Pt'
_chemical_formula_weight         2407.58
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                116.697(13)
_cell_angle_beta                 98.59(3)
_cell_angle_gamma                94.41(2)
_cell_formula_units_Z            1
_cell_length_a                   12.401(6)
_cell_length_b                   14.396(6)
_cell_length_c                   15.709(9)
_cell_measurement_reflns_used    11069
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.5204
_cell_measurement_theta_min      2.0006
_cell_volume                     2444(2)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.981
_diffrn_measured_fraction_theta_max 0.981
_diffrn_measurement_device_type  Meccury
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1015
_diffrn_reflns_av_sigmaI/netI    0.1394
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            19275
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.93
_exptl_absorpt_coefficient_mu    4.633
_exptl_absorpt_correction_T_max  0.4576
_exptl_absorpt_correction_T_min  0.3905
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.636
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       cubic
_exptl_crystal_F_000             1186
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.454
_refine_diff_density_min         -1.931
_refine_diff_density_rms         0.169
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.162
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     610
_refine_ls_number_reflns         8450
_refine_ls_number_restraints     1293
_refine_ls_restrained_S_all      1.100
_refine_ls_R_factor_all          0.1036
_refine_ls_R_factor_gt           0.0810
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0119P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1257
_refine_ls_wR_factor_ref         0.1367
_reflns_number_gt                6702
_reflns_number_total             8450
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            am6b06707_si_001.cif
_cod_data_source_block           1-Et2O
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 
;
_cod_original_sg_symbol_H-M      'P-1   '
_cod_database_code               4513929
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au -0.88112(4) 0.44942(4) 0.33914(3) 0.03791(15) Uani 1 1 d . . .
Pt1 Pt -1.0000 0.5000 0.5000 0.02649(16) Uani 1 2 d S . .
Cl1 Cl -1.3206(5) 0.7503(6) 0.3292(6) 0.126(3) Uani 1 1 d . . .
P1 P -0.7946(2) 0.3333(2) 0.3782(2) 0.0328(7) Uani 1 1 d . . .
P2 P -0.9626(3) 0.5598(2) 0.2873(2) 0.0343(7) Uani 1 1 d . . .
P3 P -1.0507(2) 0.6391(2) 0.4774(2) 0.0250(6) Uani 1 1 d U . .
O1 O -1.2960(19) 0.8190(15) 0.4332(14) 0.243(12) Uani 1 1 d . . .
O2 O -1.2261(13) 0.7644(15) 0.2996(17) 0.242(12) Uani 1 1 d . . .
O3 O -1.3504(11) 0.6477(11) 0.3177(10) 0.154(7) Uani 1 1 d . . .
O4 O -1.4021(11) 0.7916(13) 0.2934(12) 0.187(8) Uani 1 1 d . . .
N1 N -0.6623(8) 0.9762(8) 1.0013(7) 0.043(3) Uani 1 1 d . . .
C1 C -1.0750(9) 0.6088(9) 0.3496(8) 0.045(2) Uani 1 1 d U . .
H1A H -1.0891 0.6721 0.3453 0.054 Uiso 1 1 calc R . .
H1B H -1.1413 0.5565 0.3153 0.054 Uiso 1 1 calc R . .
C2 C -1.1884(9) 0.6577(9) 0.5060(8) 0.042(2) Uani 1 1 d U . .
H2A H -1.2059 0.7216 0.5046 0.050 Uiso 1 1 calc R . .
H2B H -1.2420 0.5994 0.4549 0.050 Uiso 1 1 calc R . .
C3 C -0.8886(9) 0.5909(9) 0.6246(9) 0.040(2) Uani 1 1 d U . .
C4 C -0.8289(10) 0.6425(10) 0.7026(9) 0.044(2) Uani 1 1 d U . .
C11 C -1.0310(11) 0.4926(11) 0.1594(10) 0.058(2) Uani 1 1 d U . .
C12 C -1.0197(11) 0.3905(11) 0.1051(10) 0.070(3) Uani 1 1 d U . .
H12A H -0.9768 0.3561 0.1319 0.084 Uiso 1 1 calc R . .
C13 C -1.0764(12) 0.3374(12) 0.0046(11) 0.078(3) Uani 1 1 d U . .
H13A H -1.0714 0.2672 -0.0345 0.093 Uiso 1 1 calc R . .
C14 C -1.1358(11) 0.3885(12) -0.0325(11) 0.069(3) Uani 1 1 d U . .
H14A H -1.1697 0.3543 -0.0981 0.083 Uiso 1 1 calc R . .
C15 C -1.1480(12) 0.4888(12) 0.0231(10) 0.070(3) Uani 1 1 d U . .
H15A H -1.1926 0.5218 -0.0039 0.084 Uiso 1 1 calc R . .
C16 C -1.0955(11) 0.5426(11) 0.1189(10) 0.065(2) Uani 1 1 d U . .
H16A H -1.1032 0.6124 0.1565 0.078 Uiso 1 1 calc R . .
C21 C -0.7021(11) 1.0575(11) 0.9827(10) 0.0545(19) Uani 1 1 d U . .
C22 C -0.7593(11) 1.1287(10) 1.0480(9) 0.060(2) Uani 1 1 d U . .
H22A H -0.7708 1.1252 1.1037 0.071 Uiso 1 1 calc R . .
C23 C -0.7981(11) 1.2053(11) 1.0246(10) 0.066(2) Uani 1 1 d U . .
H23A H -0.8348 1.2537 1.0674 0.079 Uiso 1 1 calc R . .
C24 C -0.7858(11) 1.2129(11) 0.9467(10) 0.064(2) Uani 1 1 d U . .
H24A H -0.8148 1.2639 0.9334 0.077 Uiso 1 1 calc R . .
C25 C -0.7296(11) 1.1444(11) 0.8858(10) 0.062(2) Uani 1 1 d U . .
H25A H -0.7182 1.1510 0.8315 0.075 Uiso 1 1 calc R . .
C26 C -0.6870(10) 1.0624(10) 0.9008(9) 0.057(2) Uani 1 1 d U . .
H26A H -0.6507 1.0148 0.8568 0.069 Uiso 1 1 calc R . .
C31 C -0.8497(10) 0.1965(10) 0.2901(10) 0.052(2) Uani 1 1 d U . .
C32 C -0.9487(11) 0.1758(11) 0.2286(10) 0.059(3) Uani 1 1 d U . .
H32A H -0.9870 0.2298 0.2311 0.071 Uiso 1 1 calc R . .
C33 C -0.9904(11) 0.0708(11) 0.1616(10) 0.068(3) Uani 1 1 d U . .
H33A H -1.0579 0.0537 0.1189 0.082 Uiso 1 1 calc R . .
C34 C -0.9323(11) -0.0069(11) 0.1587(10) 0.066(3) Uani 1 1 d U . .
H34A H -0.9638 -0.0767 0.1169 0.079 Uiso 1 1 calc R . .
C35 C -0.8329(11) 0.0137(11) 0.2133(10) 0.061(3) Uani 1 1 d U . .
H35A H -0.7917 -0.0400 0.2050 0.074 Uiso 1 1 calc R . .
C36 C -0.7904(11) 0.1173(10) 0.2837(10) 0.056(2) Uani 1 1 d U . .
H36A H -0.7228 0.1328 0.3259 0.067 Uiso 1 1 calc R . .
C41 C -0.5930(11) 0.8938(11) 1.0883(9) 0.0532(19) Uani 1 1 d U . .
C42 C -0.6042(11) 0.9924(11) 1.0926(10) 0.0536(19) Uani 1 1 d U . .
C43 C -0.5608(10) 1.0880(11) 1.1762(9) 0.058(2) Uani 1 1 d U . .
H43A H -0.5640 1.1529 1.1774 0.070 Uiso 1 1 calc R . .
C44 C -0.5141(10) 1.0792(11) 1.2552(10) 0.061(2) Uani 1 1 d U . .
H44A H -0.4857 1.1410 1.3125 0.073 Uiso 1 1 calc R . .
C45 C -0.5056(10) 0.9857(11) 1.2568(9) 0.058(2) Uani 1 1 d U . .
H45A H -0.4750 0.9860 1.3148 0.069 Uiso 1 1 calc R . .
C46 C -0.5420(10) 0.8910(11) 1.1733(9) 0.054(2) Uani 1 1 d U . .
H46A H -0.5332 0.8274 1.1732 0.065 Uiso 1 1 calc R . .
C51 C -0.9618(11) 0.7682(10) 0.5396(9) 0.0509(19) Uani 1 1 d U . .
C52 C -1.0043(11) 0.8586(10) 0.5561(10) 0.060(2) Uani 1 1 d U . .
H52A H -1.0802 0.8572 0.5422 0.071 Uiso 1 1 calc R . .
C53 C -0.9287(12) 0.9548(11) 0.5953(10) 0.066(3) Uani 1 1 d U . .
H53A H -0.9549 1.0178 0.6093 0.079 Uiso 1 1 calc R . .
C54 C -0.8211(12) 0.9535(11) 0.6117(10) 0.069(3) Uani 1 1 d U . .
H54A H -0.7726 1.0169 0.6387 0.083 Uiso 1 1 calc R . .
C55 C -0.7766(12) 0.8578(11) 0.5891(10) 0.066(3) Uani 1 1 d U . .
H55A H -0.7009 0.8572 0.5970 0.079 Uiso 1 1 calc R . .
C56 C -0.8520(11) 0.7669(11) 0.5552(9) 0.058(2) Uani 1 1 d U . .
H56A H -0.8268 0.7038 0.5429 0.069 Uiso 1 1 calc R . .
C61 C -0.6463(10) 0.3508(10) 0.3860(10) 0.052(2) Uani 1 1 d U . .
C62 C -0.6050(10) 0.3724(10) 0.3194(10) 0.057(2) Uani 1 1 d U . .
H62A H -0.6531 0.3804 0.2727 0.069 Uiso 1 1 calc R . .
C63 C -0.4942(11) 0.3822(10) 0.3207(10) 0.062(2) Uani 1 1 d U . .
H63A H -0.4678 0.3908 0.2718 0.075 Uiso 1 1 calc R . .
C64 C -0.4215(11) 0.3793(10) 0.3949(10) 0.062(3) Uani 1 1 d U . .
H64A H -0.3459 0.3903 0.3977 0.075 Uiso 1 1 calc R . .
C65 C -0.4578(10) 0.3610(10) 0.4630(10) 0.062(2) Uani 1 1 d U . .
H65A H -0.4081 0.3589 0.5124 0.075 Uiso 1 1 calc R . .
C66 C -0.5708(10) 0.3453(10) 0.4587(10) 0.056(2) Uani 1 1 d U . .
H66A H -0.5968 0.3309 0.5047 0.067 Uiso 1 1 calc R . .
C71 C -0.7597(10) 0.7053(10) 0.7969(9) 0.045(2) Uani 1 1 d U . .
C72 C -0.7433(10) 0.8161(10) 0.8440(9) 0.0472(18) Uani 1 1 d U . .
H72A H -0.7711 0.8527 0.8120 0.057 Uiso 1 1 calc R . .
C73 C -0.6842(10) 0.8696(11) 0.9400(9) 0.0494(17) Uani 1 1 d U . .
C74 C -0.6426(10) 0.8156(11) 0.9907(9) 0.0497(18) Uani 1 1 d U . .
C75 C -0.6539(10) 0.7088(10) 0.9427(9) 0.0480(19) Uani 1 1 d U . .
H75A H -0.6248 0.6730 0.9751 0.058 Uiso 1 1 calc R . .
C76 C -0.7087(9) 0.6521(10) 0.8453(9) 0.0472(19) Uani 1 1 d U . .
H76A H -0.7119 0.5794 0.8121 0.057 Uiso 1 1 calc R . .
C81 C -0.8704(11) 0.6725(11) 0.3079(10) 0.059(2) Uani 1 1 d U . .
C82 C -0.9025(12) 0.7684(11) 0.3233(10) 0.064(2) Uani 1 1 d U . .
H82A H -0.9761 0.7772 0.3227 0.077 Uiso 1 1 calc R . .
C83 C -0.8228(12) 0.8500(12) 0.3396(11) 0.075(3) Uani 1 1 d U . .
H83A H -0.8427 0.9147 0.3501 0.090 Uiso 1 1 calc R . .
C84 C -0.7151(12) 0.8367(12) 0.3403(11) 0.077(3) Uani 1 1 d U . .
H84A H -0.6629 0.8940 0.3539 0.093 Uiso 1 1 calc R . .
C85 C -0.6800(13) 0.7421(12) 0.3218(11) 0.079(3) Uani 1 1 d U . .
H85A H -0.6067 0.7338 0.3197 0.095 Uiso 1 1 calc R . .
C86 C -0.7590(12) 0.6605(12) 0.3067(10) 0.069(2) Uani 1 1 d U . .
H86A H -0.7381 0.5960 0.2954 0.083 Uiso 1 1 calc R . .
O01 O -0.489(3) 0.492(2) -0.024(2) 0.179(11) Uani 0.50 1 d PDU A -1
C04 C -0.575(3) 0.468(3) 0.094(3) 0.193(12) Uani 0.50 1 d PDU A -1
H04A H -0.6290 0.4216 0.1006 0.290 Uiso 0.50 1 calc PR A -1
H04B H -0.5929 0.5381 0.1221 0.290 Uiso 0.50 1 calc PR A -1
H04C H -0.5032 0.4692 0.1283 0.290 Uiso 0.50 1 calc PR A -1
C03 C -0.573(3) 0.430(2) -0.013(3) 0.190(11) Uani 0.50 1 d PDU A -1
H03A H -0.5626 0.3572 -0.0422 0.228 Uiso 0.50 1 calc PR A -1
H03B H -0.6441 0.4342 -0.0459 0.228 Uiso 0.50 1 calc PR A -1
C01 C -0.399(3) 0.515(3) -0.141(2) 0.187(12) Uani 0.50 1 d PDU A -1
H01A H -0.3980 0.4837 -0.2091 0.280 Uiso 0.50 1 calc PR A -1
H01B H -0.3271 0.5206 -0.1047 0.280 Uiso 0.50 1 calc PR A -1
H01C H -0.4185 0.5841 -0.1200 0.280 Uiso 0.50 1 calc PR A -1
C02 C -0.483(3) 0.447(2) -0.123(2) 0.190(11) Uani 0.50 1 d PDU A -1
H02A H -0.5555 0.4395 -0.1615 0.228 Uiso 0.50 1 calc PR A -1
H02B H -0.4634 0.3773 -0.1440 0.228 Uiso 0.50 1 calc PR A -1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P1 Au1 P2 175.03(10) . .
P1 Au1 Pt1 90.58(8) . .
P2 Au1 Pt1 94.27(8) . .
C3 Pt1 C3 180.000(2) 2_366 .
C3 Pt1 P3 85.2(3) 2_366 .
C3 Pt1 P3 94.8(3) . .
C3 Pt1 P3 94.8(3) 2_366 2_366
C3 Pt1 P3 85.2(3) . 2_366
P3 Pt1 P3 180.00(13) . 2_366
C3 Pt1 Au1 106.8(3) 2_366 2_366
C3 Pt1 Au1 73.2(3) . 2_366
P3 Pt1 Au1 92.07(7) . 2_366
P3 Pt1 Au1 87.93(7) 2_366 2_366
C3 Pt1 Au1 73.2(3) 2_366 .
C3 Pt1 Au1 106.8(3) . .
P3 Pt1 Au1 87.93(7) . .
P3 Pt1 Au1 92.07(7) 2_366 .
Au1 Pt1 Au1 180.000(1) 2_366 .
O2 Cl1 O4 109.8(9) . .
O2 Cl1 O3 114.5(11) . .
O4 Cl1 O3 116.8(10) . .
O2 Cl1 O1 104.8(14) . .
O4 Cl1 O1 104.2(12) . .
O3 Cl1 O1 105.4(9) . .
C2 P1 C61 105.1(6) 2_366 .
C2 P1 C31 104.5(5) 2_366 .
C61 P1 C31 107.1(6) . .
C2 P1 Au1 113.9(4) 2_366 .
C61 P1 Au1 113.6(4) . .
C31 P1 Au1 111.9(4) . .
C81 P2 C11 108.2(6) . .
C81 P2 C1 106.7(6) . .
C11 P2 C1 103.2(6) . .
C81 P2 Au1 114.2(5) . .
C11 P2 Au1 113.1(5) . .
C1 P2 Au1 110.7(3) . .
C1 P3 C51 103.5(5) . .
C1 P3 C2 102.4(5) . .
C51 P3 C2 108.0(6) . .
C1 P3 Pt1 112.2(4) . .
C51 P3 Pt1 121.0(4) . .
C2 P3 Pt1 108.1(3) . .
C73 N1 C42 107.8(10) . .
C73 N1 C21 127.3(11) . .
C42 N1 C21 124.4(11) . .
P3 C1 P2 115.4(6) . .
P1 C2 P3 116.1(6) 2_366 .
C4 C3 Pt1 174.2(11) . .
C3 C4 C71 178.7(15) . .
C12 C11 C16 120.7(14) . .
C12 C11 P2 118.2(11) . .
C16 C11 P2 121.1(11) . .
C11 C12 C13 117.7(13) . .
C14 C13 C12 120.1(15) . .
C13 C14 C15 121.3(15) . .
C14 C15 C16 120.8(14) . .
C15 C16 C11 119.5(14) . .
C26 C21 C22 121.3(13) . .
C26 C21 N1 119.2(11) . .
C22 C21 N1 119.5(11) . .
C23 C22 C21 116.6(12) . .
C24 C23 C22 124.3(13) . .
C23 C24 C25 117.9(14) . .
C24 C25 C26 123.3(13) . .
C21 C26 C25 116.6(12) . .
C32 C31 C36 121.3(14) . .
C32 C31 P1 118.0(10) . .
C36 C31 P1 120.6(11) . .
C31 C32 C33 117.6(14) . .
C34 C33 C32 120.1(15) . .
C35 C34 C33 122.2(15) . .
C34 C35 C36 119.0(14) . .
C31 C36 C35 119.4(14) . .
C46 C41 C42 118.7(13) . .
C46 C41 C74 134.8(14) . .
C42 C41 C74 106.5(12) . .
C43 C42 C41 122.7(13) . .
C43 C42 N1 128.3(13) . .
C41 C42 N1 109.0(12) . .
C44 C43 C42 115.1(14) . .
C43 C44 C45 124.7(14) . .
C44 C45 C46 120.6(13) . .
C45 C46 C41 117.9(13) . .
C56 C51 C52 122.4(13) . .
C56 C51 P3 115.8(11) . .
C52 C51 P3 121.2(11) . .
C51 C52 C53 118.0(13) . .
C54 C53 C52 119.5(14) . .
C53 C54 C55 122.3(14) . .
C56 C55 C54 116.6(14) . .
C51 C56 C55 121.0(14) . .
C62 C61 C66 117.8(12) . .
C62 C61 P1 119.3(11) . .
C66 C61 P1 122.9(10) . .
C63 C62 C61 121.0(14) . .
C62 C63 C64 119.7(13) . .
C65 C64 C63 121.3(13) . .
C64 C65 C66 119.0(14) . .
C65 C66 C61 121.0(13) . .
C72 C71 C76 119.3(12) . .
C72 C71 C4 122.9(11) . .
C76 C71 C4 117.8(12) . .
C73 C72 C71 118.3(11) . .
N1 C73 C72 128.4(12) . .
N1 C73 C74 109.6(12) . .
C72 C73 C74 121.9(13) . .
C75 C74 C73 119.2(13) . .
C75 C74 C41 133.7(13) . .
C73 C74 C41 107.1(12) . .
C74 C75 C76 120.9(12) . .
C75 C76 C71 120.0(12) . .
C82 C81 C86 119.5(13) . .
C82 C81 P2 124.1(11) . .
C86 C81 P2 116.4(11) . .
C83 C82 C81 118.5(14) . .
C84 C83 C82 120.6(15) . .
C83 C84 C85 123.0(15) . .
C86 C85 C84 116.7(15) . .
C85 C86 C81 121.6(15) . .
C03 O01 C02 108.7(8) . .
O01 C03 C04 110.9(8) . .
O01 C02 C01 111.0(8) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 P1 2.308(3) .
Au1 P2 2.318(3) .
Au1 Pt1 2.9518(15) .
Pt1 C3 2.016(12) 2_366
Pt1 C3 2.016(12) .
Pt1 P3 2.302(3) .
Pt1 P3 2.302(3) 2_366
Pt1 Au1 2.9518(15) 2_366
Cl1 O2 1.358(13) .
Cl1 O4 1.385(12) .
Cl1 O3 1.416(12) .
Cl1 O1 1.447(19) .
P1 C2 1.809(10) 2_366
P1 C61 1.816(12) .
P1 C31 1.822(13) .
P2 C81 1.782(13) .
P2 C11 1.819(14) .
P2 C1 1.827(10) .
P3 C1 1.823(11) .
P3 C51 1.833(13) .
P3 C2 1.838(10) .
N1 C73 1.373(15) .
N1 C42 1.413(14) .
N1 C21 1.433(14) .
C2 P1 1.809(10) 2_366
C3 C4 1.195(16) .
C4 C71 1.430(16) .
C11 C12 1.360(17) .
C11 C16 1.384(16) .
C12 C13 1.440(17) .
C13 C14 1.328(17) .
C14 C15 1.345(17) .
C15 C16 1.367(17) .
C21 C26 1.359(15) .
C21 C22 1.411(16) .
C22 C23 1.404(16) .
C23 C24 1.308(15) .
C24 C25 1.353(16) .
C25 C26 1.427(15) .
C31 C32 1.364(17) .
C31 C36 1.377(15) .
C32 C33 1.396(17) .
C33 C34 1.364(16) .
C34 C35 1.320(17) .
C35 C36 1.396(17) .
C41 C46 1.408(16) .
C41 C42 1.409(16) .
C41 C74 1.435(17) .
C42 C43 1.400(17) .
C43 C44 1.353(15) .
C44 C45 1.369(16) .
C45 C46 1.380(16) .
C51 C56 1.350(15) .
C51 C52 1.371(16) .
C52 C53 1.427(16) .
C53 C54 1.324(16) .
C54 C55 1.437(16) .
C55 C56 1.381(16) .
C61 C62 1.371(15) .
C61 C66 1.399(16) .
C62 C63 1.367(15) .
C63 C64 1.381(17) .
C64 C65 1.339(15) .
C65 C66 1.390(15) .
C71 C72 1.406(15) .
C71 C76 1.421(14) .
C72 C73 1.394(16) .
C73 C74 1.414(15) .
C74 C75 1.359(16) .
C75 C76 1.397(15) .
C81 C82 1.392(16) .
C81 C86 1.408(16) .
C82 C83 1.378(16) .
C83 C84 1.363(17) .
C84 C85 1.379(18) .
C85 C86 1.378(17) .
O01 C03 1.405(6) .
O01 C02 1.410(6) .
C04 C03 1.521(6) .
C01 C02 1.520(6) .
