#------------------------------------------------------------------------------
#$Date: 2017-03-04 15:04:28 +0200 (Sat, 04 Mar 2017) $
#$Revision: 193402 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/51/40/4514037.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4514037
loop_
_publ_author_name
'Zhou, Zhen'
'He, Cheng'
'Yang, Lu'
'Wang, Yefei'
'Liu, Tao'
'Duan, Chunying'
_publ_section_title
;
 Alkyne Activation by a Porous Silver Coordination Polymer for
 Heterogeneous Catalysis of Carbon Dioxide Cycloaddition
;
_journal_issue                   3
_journal_name_full               'ACS Catalysis'
_journal_page_first              2248
_journal_paper_doi               10.1021/acscatal.6b03404
_journal_volume                  7
_journal_year                    2017
_chemical_formula_sum            'C54.5 H45 Ag4 Cl5 O10'
_chemical_formula_weight         1468.64
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 97.2988(13)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.2473(3)
_cell_length_b                   18.5148(6)
_cell_length_c                   26.3786(8)
_cell_measurement_reflns_used    22795
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      27.4705
_cell_measurement_theta_min      2.333
_cell_volume                     5448.6(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      200(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0455
_diffrn_reflns_av_sigmaI/netI    0.1796
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            48379
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.19
_exptl_absorpt_coefficient_mu    1.719
_exptl_absorpt_correction_T_max  0.7142
_exptl_absorpt_correction_T_min  0.6635
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            dark-red
_exptl_crystal_density_diffrn    1.790
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             2900
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.21
_refine_diff_density_max         5.182
_refine_diff_density_min         -1.860
_refine_diff_density_rms         0.236
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.015
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     665
_refine_ls_number_reflns         9557
_refine_ls_number_restraints     237
_refine_ls_restrained_S_all      1.472
_refine_ls_R_factor_all          0.1489
_refine_ls_R_factor_gt           0.1043
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1291P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2712
_refine_ls_wR_factor_ref         0.2948
_reflns_number_gt                4732
_reflns_number_total             9557
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cs6b03404_si_003.cif
_cod_data_source_block           Ag-TCPE@1a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 

 Adding full bibliography for 4514037--4514038.cif.
;
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_original_formula_sum        'C54.50 H45 Ag4 Cl5 O10'
_cod_database_code               4514037
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.62643(9) 0.28925(7) 0.26588(4) 0.0634(3) Uani 1 1 d U . .
Ag2 Ag 0.40107(9) 0.22691(7) 0.23455(4) 0.0545(3) Uani 1 1 d U . .
Ag3 Ag 0.58968(10) 0.72925(9) 0.26785(4) 0.0814(5) Uani 1 1 d . . .
Ag4 Ag 0.36729(11) 0.71682(9) 0.20578(5) 0.0857(4) Uani 1 1 d U . .
Cl1 Cl 0.3055(6) 0.3351(3) 0.1382(2) 0.128(2) Uani 1 1 d . A .
Cl2 Cl 0.3135(11) 0.3230(5) 0.0285(4) 0.152(4) Uani 0.65 1 d P A 1
Cl0 Cl 0.501(2) 0.3222(13) 0.0835(12) 0.231(13) Uani 0.35 1 d P . 2
Cl3 Cl 0.1750(10) 0.0981(6) 0.6042(4) 0.254(6) Uani 1 1 d D . .
Cl4 Cl 0.2388(16) -0.0290(10) 0.5505(6) 0.411(11) Uani 1 1 d D . .
Cl5 Cl 0.4284(15) 0.1740(9) 0.5354(8) 0.226(8) Uani 0.50 1 d P . .
Cl6 Cl 0.5399(16) 0.0586(13) 0.5679(7) 0.237(10) Uani 0.50 1 d P . .
O1 O 0.1547(7) 0.7095(4) 0.7048(3) 0.040(2) Uani 1 1 d U . .
O2 O -0.0064(7) 0.7462(4) 0.6518(3) 0.038(2) Uani 1 1 d . . .
O3 O 0.4738(7) 0.7106(5) 0.3254(3) 0.049(3) Uani 1 1 d . . .
O4 O 0.3059(7) 0.6797(5) 0.2780(3) 0.036(2) Uani 1 1 d U . .
O5 O 0.5150(7) 0.3351(5) 0.3182(3) 0.044(2) Uani 1 1 d U . .
O6 O 0.3406(7) 0.2765(4) 0.3016(3) 0.038(2) Uani 1 1 d . . .
O7 O 0.1901(7) 0.2655(5) 0.6999(3) 0.045(2) Uani 1 1 d . . .
O8 O 0.0046(8) 0.3033(5) 0.6748(4) 0.060(3) Uani 1 1 d U . .
O9 O 0.0563(10) -0.0934(6) 0.7224(4) 0.080(4) Uani 1 1 d . . .
H9A H 0.0581 -0.0904 0.6907 0.120 Uiso 1 1 calc R . .
O10 O 0.0030(10) 0.1137(6) 0.3823(4) 0.082(4) Uani 1 1 d . . .
H10B H -0.0001 0.1572 0.3731 0.123 Uiso 1 1 calc R . .
C1 C 0.0900(10) 0.7113(6) 0.6615(4) 0.026(3) Uani 1 1 d . . .
C2 C 0.1338(9) 0.6679(5) 0.6197(4) 0.021(3) Uani 1 1 d . . .
C3 C 0.2132(9) 0.6092(6) 0.6318(4) 0.024(3) Uani 1 1 d . . .
H3A H 0.2421 0.5979 0.6663 0.029 Uiso 1 1 calc R . .
C4 C 0.2471(8) 0.5694(5) 0.5929(3) 0.016(2) Uani 1 1 d . . .
H4A H 0.3014 0.5306 0.6012 0.020 Uiso 1 1 calc R . .
C5 C 0.2073(8) 0.5818(5) 0.5419(3) 0.012(2) Uani 1 1 d U . .
C6 C 0.1348(8) 0.6427(5) 0.5312(4) 0.018(2) Uani 1 1 d . . .
H6A H 0.1110 0.6559 0.4966 0.022 Uiso 1 1 calc R . .
C7 C 0.0971(9) 0.6840(6) 0.5695(4) 0.022(3) Uani 1 1 d . . .
H7A H 0.0454 0.7240 0.5610 0.027 Uiso 1 1 calc R . .
C8 C 0.3746(10) 0.6844(6) 0.3201(4) 0.028(3) Uani 1 1 d . . .
C9 C 0.3317(9) 0.6494(6) 0.3669(4) 0.024(3) Uani 1 1 d U . .
C10 C 0.3817(9) 0.6706(6) 0.4151(4) 0.028(3) Uani 1 1 d . . .
H10A H 0.4381 0.7090 0.4186 0.033 Uiso 1 1 calc R . .
C11 C 0.3509(8) 0.6370(5) 0.4586(4) 0.018(3) Uani 1 1 d . . .
H11A H 0.3832 0.6534 0.4916 0.021 Uiso 1 1 calc R . .
C12 C 0.2708(8) 0.5779(5) 0.4530(3) 0.013(2) Uani 1 1 d . . .
C13 C 0.2195(9) 0.5595(5) 0.4033(4) 0.019(3) Uani 1 1 d . . .
H13A H 0.1624 0.5215 0.3985 0.023 Uiso 1 1 calc R . .
C14 C 0.2508(9) 0.5955(6) 0.3620(4) 0.023(3) Uani 1 1 d . . .
H14A H 0.2145 0.5823 0.3288 0.027 Uiso 1 1 calc R . .
C15 C 0.4134(9) 0.3179(6) 0.3287(4) 0.026(3) Uani 1 1 d . . .
C16 C 0.3716(9) 0.3504(6) 0.3751(4) 0.021(3) Uani 1 1 d . . .
C17 C 0.4451(9) 0.4018(6) 0.4021(4) 0.024(3) Uani 1 1 d . . .
H17A H 0.5205 0.4133 0.3915 0.028 Uiso 1 1 calc R . .
C18 C 0.4100(9) 0.4359(5) 0.4437(4) 0.021(3) Uani 1 1 d . . .
H18A H 0.4625 0.4695 0.4622 0.025 Uiso 1 1 calc R . .
C19 C 0.2984(8) 0.4221(5) 0.4596(3) 0.011(2) Uani 1 1 d . . .
C20 C 0.2301(10) 0.3676(6) 0.4352(4) 0.027(3) Uani 1 1 d . . .
H20A H 0.1576 0.3537 0.4475 0.032 Uiso 1 1 calc R . .
C21 C 0.2651(10) 0.3325(6) 0.3929(4) 0.035(3) Uani 1 1 d . . .
H21A H 0.2154 0.2959 0.3761 0.042 Uiso 1 1 calc R . .
C22 C 0.1127(11) 0.2995(7) 0.6691(5) 0.038(3) Uani 1 1 d . . .
C23 C 0.1525(9) 0.3392(6) 0.6256(4) 0.022(3) Uani 1 1 d . . .
C24 C 0.2608(10) 0.3301(6) 0.6084(4) 0.027(3) Uani 1 1 d . . .
H24A H 0.3152 0.2954 0.6246 0.032 Uiso 1 1 calc R . .
C25 C 0.2931(9) 0.3696(6) 0.5687(4) 0.024(3) Uani 1 1 d . . .
H25A H 0.3693 0.3620 0.5576 0.028 Uiso 1 1 calc R . .
C26 C 0.2163(8) 0.4204(5) 0.5444(3) 0.010(2) Uani 1 1 d . . .
C27 C 0.1030(9) 0.4279(5) 0.5598(4) 0.020(3) Uani 1 1 d . . .
H27A H 0.0462 0.4599 0.5419 0.024 Uiso 1 1 calc R . .
C28 C 0.0730(9) 0.3888(6) 0.6012(4) 0.031(3) Uani 1 1 d . . .
H28A H -0.0025 0.3962 0.6129 0.037 Uiso 1 1 calc R . .
C29 C 0.2429(7) 0.5379(5) 0.4989(3) 0.008(2) Uani 1 1 d U . .
C30 C 0.2528(7) 0.4633(5) 0.5009(3) 0.009(2) Uani 1 1 d . . .
C31 C 0.123(3) 0.0190(10) 0.4328(8) 0.154(11) Uani 1 1 d . . .
H31A H 0.0537 0.0068 0.4503 0.231 Uiso 1 1 calc R . .
H31B H 0.1967 0.0131 0.4565 0.231 Uiso 1 1 calc R . .
H31C H 0.1250 -0.0131 0.4034 0.231 Uiso 1 1 calc R . .
C32 C 0.1245(19) 0.1505(11) 0.4576(8) 0.108(8) Uani 1 1 d . . .
H32A H 0.1156 0.2004 0.4453 0.162 Uiso 1 1 calc R . .
H32B H 0.2039 0.1443 0.4772 0.162 Uiso 1 1 calc R . .
H32C H 0.0625 0.1398 0.4795 0.162 Uiso 1 1 calc R . .
C33 C 0.1119(15) 0.1008(11) 0.4137(6) 0.075(6) Uani 1 1 d . . .
C34 C 0.2251(18) 0.1112(10) 0.3877(7) 0.088(6) Uani 1 1 d . . .
C35 C 0.3178(17) 0.1228(10) 0.3733(8) 0.093(7) Uani 1 1 d . . .
C36 C 0.4372(9) 0.1359(5) 0.3569(5) 0.121(8) Uani 1 1 d G . .
C37 C 0.5199(11) 0.1750(6) 0.3897(5) 0.151(12) Uani 1 1 d G . .
H37A H 0.4975 0.1947 0.4203 0.181 Uiso 1 1 calc R . .
C38 C 0.6356(10) 0.1851(7) 0.3776(7) 0.143(10) Uani 1 1 d G . .
H38A H 0.6921 0.2118 0.4001 0.172 Uiso 1 1 calc R . .
C39 C 0.6684(10) 0.1563(8) 0.3328(7) 0.124(5) Uani 1 1 d GU . .
H39A H 0.7475 0.1632 0.3246 0.149 Uiso 1 1 calc R . .
C40 C 0.5857(13) 0.1172(8) 0.3000(6) 0.155(9) Uani 1 1 d G . .
H40A H 0.6082 0.0975 0.2694 0.186 Uiso 1 1 calc R . .
C41 C 0.4701(12) 0.1071(6) 0.3120(5) 0.127(8) Uani 1 1 d GU . .
H41A H 0.4135 0.0804 0.2896 0.153 Uiso 1 1 calc R . .
C42 C -0.041(2) 0.0274(13) 0.7136(9) 0.145(8) Uani 1 1 d U . .
H42A H -0.0245 0.0311 0.6781 0.217 Uiso 1 1 calc R . .
H42B H -0.0409 0.0758 0.7286 0.217 Uiso 1 1 calc R . .
H42C H -0.1199 0.0051 0.7144 0.217 Uiso 1 1 calc R . .
C43 C 0.0500(19) -0.0312(10) 0.7991(7) 0.102(6) Uani 1 1 d U . .
H43A H -0.0201 -0.0610 0.8032 0.153 Uiso 1 1 calc R . .
H43B H 0.0425 0.0156 0.8158 0.153 Uiso 1 1 calc R . .
H43C H 0.1228 -0.0556 0.8148 0.153 Uiso 1 1 calc R . .
C44 C 0.0571(17) -0.0198(10) 0.7447(7) 0.085(5) Uani 1 1 d U . .
C47 C 0.4066(8) 0.0591(5) 0.7475(4) 0.106(4) Uani 1 1 d GDU . .
C48 C 0.4943(10) 0.0438(7) 0.7881(4) 0.097(4) Uani 1 1 d GU . .
H48A H 0.4744 0.0168 0.8165 0.116 Uiso 1 1 calc R . .
C49 C 0.6110(9) 0.0679(8) 0.7871(5) 0.113(5) Uani 1 1 d GU . .
H49A H 0.6709 0.0574 0.8149 0.136 Uiso 1 1 calc R . .
C50 C 0.6401(9) 0.1073(7) 0.7456(6) 0.090(5) Uani 1 1 d GU . .
H50A H 0.7199 0.1238 0.7449 0.108 Uiso 1 1 calc R . .
C51 C 0.5524(12) 0.1226(7) 0.7050(5) 0.107(5) Uani 1 1 d GU . .
H51A H 0.5723 0.1495 0.6766 0.128 Uiso 1 1 calc R . .
C52 C 0.4357(10) 0.0985(6) 0.7059(4) 0.134(9) Uani 1 1 d G . .
H52A H 0.3758 0.1090 0.6782 0.161 Uiso 1 1 calc R . .
C53 C 0.3722(18) 0.2915(11) 0.0888(8) 0.106(7) Uani 1 1 d . . .
H53A H 0.4598 0.3001 0.0940 0.127 Uiso 1 1 calc R A 1
H53B H 0.3586 0.2388 0.0905 0.127 Uiso 1 1 calc R A 1
C55 C 0.401(5) 0.131(3) 0.5804(17) 0.175(6) Uani 0.50 1 d PU . .
H55A H 0.3207 0.1088 0.5759 0.210 Uiso 0.50 1 calc PR . .
H55B H 0.4163 0.1573 0.6132 0.210 Uiso 0.50 1 calc PR . .
C46 C 0.1679(19) 0.0193(12) 0.7375(8) 0.111(5) Uani 1 1 d DU . .
C45 C 0.274(2) 0.0412(12) 0.7430(8) 0.114(5) Uani 1 1 d DU . .
C54 C 0.219(4) -0.0034(13) 0.6218(11) 0.49(2) Uani 1 1 d DU . .
H54A H 0.2937 -0.0078 0.6456 0.589 Uiso 1 1 calc R . .
H54B H 0.1532 -0.0307 0.6349 0.589 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 Ag1 O7 163.5(3) . 4_665
O5 Ag1 O1 115.5(3) . 3_666
O7 Ag1 O1 80.9(3) 4_665 3_666
O5 Ag1 Ag2 76.9(2) . .
O7 Ag1 Ag2 87.2(2) 4_665 .
O1 Ag1 Ag2 156.3(2) 3_666 .
O8 Ag2 O6 163.7(3) 4_665 .
O8 Ag2 O4 113.5(3) 4_665 2_545
O6 Ag2 O4 82.6(3) . 2_545
O8 Ag2 Ag1 76.7(2) 4_665 .
O6 Ag2 Ag1 87.2(2) . .
O4 Ag2 Ag1 169.70(17) 2_545 .
O3 Ag3 O1 154.3(3) . 4_675
O3 Ag3 O7 115.2(3) . 3_666
O1 Ag3 O7 80.2(3) 4_675 3_666
O3 Ag3 Ag4 79.9(2) . .
O1 Ag3 Ag4 87.6(2) 4_675 .
O7 Ag3 Ag4 164.1(2) 3_666 .
O4 Ag4 O2 158.8(3) . 4_675
O4 Ag4 O6 79.6(3) . 2
O2 Ag4 O6 117.7(3) 4_675 2
O4 Ag4 Ag3 82.9(2) . .
O2 Ag4 Ag3 75.9(2) 4_675 .
O6 Ag4 Ag3 137.8(2) 2 .
C53 Cl0 Cl3 156(2) . 4_665
C54 Cl3 Cl0 142.0(16) . 4_566
C1 O1 Ag3 117.0(7) . 4_576
C1 O1 Ag1 135.2(7) . 3_666
Ag3 O1 Ag1 99.8(3) 4_576 3_666
C1 O2 Ag4 128.8(7) . 4_576
C8 O3 Ag3 128.0(8) . .
C8 O4 Ag4 120.5(7) . .
C8 O4 Ag2 123.3(7) . 2
Ag4 O4 Ag2 99.6(3) . 2
C15 O5 Ag1 131.7(7) . .
C15 O6 Ag2 117.6(7) . .
C15 O6 Ag4 144.7(7) . 2_545
Ag2 O6 Ag4 97.6(3) . 2_545
C22 O7 Ag1 117.6(7) . 4_566
C22 O7 Ag3 139.2(8) . 3_666
Ag1 O7 Ag3 98.9(3) 4_566 3_666
C22 O8 Ag2 134.5(8) . 4_566
O2 C1 O1 125.0(10) . .
O2 C1 C2 118.8(9) . .
O1 C1 C2 116.2(9) . .
C7 C2 C3 119.2(9) . .
C7 C2 C1 120.6(9) . .
C3 C2 C1 120.2(9) . .
C4 C3 C2 118.4(9) . .
C3 C4 C5 124.0(9) . .
C4 C5 C6 116.1(9) . .
C4 C5 C29 124.3(8) . .
C6 C5 C29 119.5(8) . .
C7 C6 C5 121.7(9) . .
C2 C7 C6 120.4(9) . .
O3 C8 O4 125.3(10) . .
O3 C8 C9 117.3(10) . .
O4 C8 C9 117.2(9) . .
C14 C9 C10 119.3(10) . .
C14 C9 C8 121.1(9) . .
C10 C9 C8 119.4(10) . .
C9 C10 C11 121.2(10) . .
C10 C11 C12 119.0(9) . .
C13 C12 C11 117.8(9) . .
C13 C12 C29 122.2(8) . .
C11 C12 C29 120.0(8) . .
C14 C13 C12 120.6(9) . .
C9 C14 C13 121.8(10) . .
O5 C15 O6 124.8(10) . .
O5 C15 C16 118.1(10) . .
O6 C15 C16 117.1(9) . .
C21 C16 C17 118.3(9) . .
C21 C16 C15 123.9(9) . .
C17 C16 C15 117.8(9) . .
C18 C17 C16 120.8(9) . .
C17 C18 C19 121.3(9) . .
C20 C19 C18 117.5(9) . .
C20 C19 C30 119.9(9) . .
C18 C19 C30 122.5(8) . .
C19 C20 C21 121.3(10) . .
C16 C21 C20 120.4(10) . .
O8 C22 O7 123.2(11) . .
O8 C22 C23 117.5(10) . .
O7 C22 C23 119.3(10) . .
C24 C23 C28 118.8(10) . .
C24 C23 C22 124.6(10) . .
C28 C23 C22 116.7(10) . .
C23 C24 C25 121.7(10) . .
C24 C25 C26 120.6(10) . .
C25 C26 C27 118.4(9) . .
C25 C26 C30 120.1(8) . .
C27 C26 C30 121.4(8) . .
C28 C27 C26 120.0(9) . .
C23 C28 C27 120.3(10) . .
C30 C29 C12 120.3(8) . .
C30 C29 C5 122.8(8) . .
C12 C29 C5 116.9(8) . .
C29 C30 C19 121.4(8) . .
C29 C30 C26 122.1(8) . .
C19 C30 C26 116.6(8) . .
O10 C33 C32 110.3(16) . .
O10 C33 C34 115.3(14) . .
C32 C33 C34 105.7(16) . .
O10 C33 C31 111.9(16) . .
C32 C33 C31 110.4(15) . .
C34 C33 C31 103.0(16) . .
C35 C34 C33 172(2) . .
C34 C35 C36 178(2) . .
C37 C36 C41 120.0 . .
C37 C36 C35 117.6(11) . .
C41 C36 C35 122.3(11) . .
C36 C37 C38 120.0 . .
C39 C38 C37 120.0 . .
C38 C39 C40 120.0 . .
C39 C40 C41 120.0 . .
C40 C41 C36 120.0 . .
C43 C44 C46 110.5(17) . .
C43 C44 O9 105.0(15) . .
C46 C44 O9 111.2(16) . .
C43 C44 C42 118.3(18) . .
C46 C44 C42 102.1(17) . .
O9 C44 C42 109.7(15) . .
C48 C47 C52 120.0 . .
C48 C47 C45 127.5(10) . .
C52 C47 C45 112.4(10) . .
C47 C48 C49 120.0 . .
C50 C49 C48 120.0 . .
C49 C50 C51 120.0 . .
C50 C51 C52 120.0 . .
C51 C52 C47 120.0 . .
Cl0 C53 Cl2 92.6(16) . .
Cl0 C53 Cl1 112.3(17) . .
Cl2 C53 Cl1 111.8(12) . .
Cl5 C55 Cl6 89(3) . .
C45 C46 C44 162(2) . .
C46 C45 C47 173(2) . .
Cl4 C54 Cl3 93.4(14) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 O5 2.153(8) .
Ag1 O7 2.210(8) 4_665
Ag1 O1 2.485(8) 3_666
Ag1 Ag2 2.8120(15) .
Ag2 O8 2.150(9) 4_665
Ag2 O6 2.178(8) .
Ag2 O4 2.469(8) 2_545
Ag3 O3 2.151(8) .
Ag3 O1 2.213(8) 4_675
Ag3 O7 2.516(8) 3_666
Ag3 Ag4 2.8194(17) .
Ag4 O4 2.215(7) .
Ag4 O2 2.241(8) 4_675
Ag4 O6 2.571(8) 2
Cl1 C53 1.78(2) .
Cl2 C53 1.74(2) .
Cl0 C53 1.58(3) .
Cl0 Cl3 2.46(3) 4_665
Cl3 C54 1.98(2) .
Cl3 Cl0 2.46(3) 4_566
Cl4 C54 1.98(3) .
Cl5 C55 1.49(5) .
Cl6 C55 2.11(6) .
O1 C1 1.274(13) .
O1 Ag3 2.213(8) 4_576
O1 Ag1 2.485(8) 3_666
O2 C1 1.260(13) .
O2 Ag4 2.241(8) 4_576
O3 C8 1.207(13) .
O4 C8 1.274(13) .
O4 Ag2 2.469(7) 2
O5 C15 1.250(13) .
O6 C15 1.272(13) .
O6 Ag4 2.571(8) 2_545
O7 C22 1.279(14) .
O7 Ag1 2.210(8) 4_566
O7 Ag3 2.516(8) 3_666
O8 C22 1.245(15) .
O8 Ag2 2.150(9) 4_566
O9 C44 1.48(2) .
O10 C33 1.408(19) .
C1 C2 1.497(14) .
C2 C7 1.371(14) .
C2 C3 1.418(15) .
C3 C4 1.357(14) .
C4 C5 1.382(13) .
C5 C6 1.399(13) .
C5 C29 1.492(12) .
C6 C7 1.376(14) .
C8 C9 1.526(14) .
C9 C14 1.345(15) .
C9 C10 1.381(15) .
C10 C11 1.386(14) .
C11 C12 1.412(13) .
C12 C13 1.406(13) .
C12 C29 1.486(12) .
C13 C14 1.363(14) .
C15 C16 1.492(14) .
C16 C21 1.382(15) .
C16 C17 1.396(14) .
C17 C18 1.367(14) .
C18 C19 1.396(14) .
C19 C20 1.378(14) .
C19 C30 1.476(12) .
C20 C21 1.391(15) .
C22 C23 1.480(15) .
C23 C24 1.363(15) .
C23 C28 1.382(15) .
C24 C25 1.365(14) .
C25 C26 1.379(13) .
C26 C27 1.392(13) .
C26 C30 1.495(12) .
C27 C28 1.388(14) .
C29 C30 1.385(13) .
C31 C33 1.60(3) .
C32 C33 1.47(2) .
C33 C34 1.53(3) .
C34 C35 1.17(3) .
C35 C36 1.48(2) .
C36 C37 1.3900 .
C36 C41 1.3900 .
C37 C38 1.3900 .
C38 C39 1.3900 .
C39 C40 1.3900 .
C40 C41 1.3900 .
C42 C44 1.56(3) .
C43 C44 1.46(2) .
C44 C46 1.47(3) .
C47 C48 1.3900 .
C47 C52 1.3900 .
C47 C45 1.52(2) .
C48 C49 1.3900 .
C49 C50 1.3900 .
C50 C51 1.3900 .
C51 C52 1.3900 .
C46 C45 1.25(3) .
