#------------------------------------------------------------------------------
#$Date: 2019-10-28 05:06:41 +0200 (Mon, 28 Oct 2019) $
#$Revision: 219656 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/51/44/4514467.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4514467
loop_
_publ_author_name
'Wang, Chun-Yun'
'Takeda, Takashi'
'Melvin Ten Kate, Otmar'
'Funahashi, Shiro'
'Xie, Rong-Jun'
'Takahashi, Kohsei'
'Hirosaki, Naoto'
_publ_section_title
;
 New Deep-Blue-Emitting Ce-Doped A₄₋ₘB n
 C₁₉₊₂ₘX₂₉₊ₘ (A = Sr, La; B =
 Li; C = Si, Al; X = O, N; 0 ≤ m ≤ 1; 0 ≤
 n ≤ 1) Phosphors for High-Color-Rendering Warm White
 Light-Emitting Diodes.
;
_journal_issue                   32
_journal_name_full               'ACS applied materials & interfaces'
_journal_page_first              29047
_journal_page_last               29055
_journal_paper_doi               10.1021/acsami.9b09982
_journal_volume                  11
_journal_year                    2019
_chemical_absolute_configuration unk
_chemical_formula_sum
'Al4.51 Eu0.41 La3.19 Li N27.28 O2.12 Si15.29'
_chemical_formula_weight         1479.60
_space_group_IT_number           156
_space_group_name_Hall           'P 3 -2"'
_space_group_name_H-M_alt        'P 3 m 1'
_symmetry_cell_setting           trigonal
_symmetry_space_group_name_Hall  'P 3 -2"'
_symmetry_space_group_name_H-M   'P 3 m 1'
_audit_creation_date             2019-03-18T15:44:28-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            1
_cell_length_a                   12.1680(6)
_cell_length_b                   12.1680(6)
_cell_length_c                   4.8290(3)
_cell_measurement_reflns_used    3528
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      36.291
_cell_measurement_theta_min      3.867
_cell_volume                     619.19(6)
_computing_cell_refinement       'APEX2 (Bruker AXS, 2009)'
_computing_data_collection       'APEX2 (Bruker AXS, 2009)'
_computing_data_reduction        'SAINT (Bruker AXS, 2009)'
_computing_molecular_graphics    'VESTA (Momma and Izumi, 2011)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 8.333
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 1
_diffrn_measurement_device_type  'Bruker APEXII CCD area detector'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  'Bruker Helios multilayer confocal mirror'
_diffrn_radiation_source         'Bruker TXS fine-focus rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0272
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 1
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       6
_diffrn_reflns_limit_l_min       -7
_diffrn_reflns_number            7432
_diffrn_reflns_point_group_measured_fraction_full 0.992
_diffrn_reflns_point_group_measured_fraction_max 0.957
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         35.605
_diffrn_reflns_theta_min         1.933
_exptl_absorpt_coefficient_mu    7.408
_exptl_absorpt_correction_T_max  0.945
_exptl_absorpt_correction_T_min  0.943
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS Sheldrick 2001
;
_exptl_crystal_colour            clear
_exptl_crystal_density_diffrn    3.968
_exptl_crystal_description       columnar
_exptl_crystal_F_000             691.3
_exptl_crystal_size_max          0.029
_exptl_crystal_size_mid          0.010
_exptl_crystal_size_min          0.008
_refine_diff_density_max         1.31
_refine_diff_density_min         -0.829
_refine_diff_density_rms         0.16
_refine_ls_abs_structure_details
;
 Flack x determined using 882 quotients [(I+)-(I-)]/[(I+)+(I-)]
 (Parsons and Flack (2004), Acta Cryst. A60, s61).
;
_refine_ls_abs_structure_Flack   -0.05(2)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.044
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     111
_refine_ls_number_reflns         2011
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.044
_refine_ls_R_factor_all          0.0302
_refine_ls_R_factor_gt           0.0282
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;
 w=1/[σ²(Fo²)+(0.0320P)²+2.8759P]
 where P=(Fo²+2Fc²)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.067
_reflns_number_gt                1938
_reflns_number_total             2011
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            am9b09982_si_003.cif
_cod_data_source_block           149b_01_01_p3m1
_cod_original_cell_volume        619.19(7)
_cod_original_formula_sum
' Al4.51 Eu0.41 La3.19 Li N27.28 O2.12 Si15.29 '
_cod_database_code               4514467
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'-x+y, y, z'
'x, x-y, z'
'-y, -x, z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_occupancy
_atom_site_type_symbol
La1 0.55166(2) 0.10333(5) 0.3223(2) 0.01180(10) Uani d 0.8852 La
Eu1 0.55166(2) 0.10333(5) 0.3223(2) 0.01180(10) Uani d 0.1148 Eu
La2 1 0 0.6152(17) 0.0080(10) Uani d 0.136 La
Eu2 1 0 0.6152(17) 0.0080(10) Uani d 0.0176 Eu
La3 1 0 0.7620(10) 0.0393(11) Uani d 0.3938 La
Eu3 1 0 0.7620(10) 0.0393(11) Uani d 0.0511 Eu
Li1 0.3333 0.6667 0.876(5) 0.002(5) Uiso d 1 Li
Si1 0.59039(15) 0.92235(14) 0.8203(6) 0.0047(2) Uani d 0.7722 Si
Al1 0.59039(15) 0.92235(14) 0.8203(6) 0.0047(2) Uani d 0.2278 Al
Si2 0.5078(3) 0.75388(13) 0.3263(10) 0.0093(4) Uani d 0.7722 Si
Al2 0.5078(3) 0.75388(13) 0.3263(10) 0.0093(4) Uani d 0.2278 Al
Si3 0.75925(16) 0.00193(17) 0.3015(6) 0.0052(3) Uani d 0.7722 Si
Al3 0.75925(16) 0.00193(17) 0.3015(6) 0.0052(3) Uani d 0.2278 Al
Si4 0.81844(12) 0.18156(12) 0.7875(6) 0.0053(5) Uani d 0.7722 Si
Al4 0.81844(12) 0.18156(12) 0.7875(6) 0.0053(5) Uani d 0.2278 Al
Si5 0.6667 0.3333 0.7874(12) 0.0059(9) Uani d 0.7723 Si
Al5 0.6667 0.3333 0.7874(12) 0.0059(9) Uani d 0.2278 Al
Si6 1 0 0.116(3) 0.0092(16) Uani d 0.3101 Si
Al6 1 0 0.116(3) 0.0092(16) Uani d 0.0914 Al
Si7 1 0 0.430(3) 0.0092(16) Uani d 0.3101 Si
Al7 1 0 0.430(3) 0.0092(16) Uani d 0.0914 Al
N1 0.8634(5) 0.1366(5) 0.489(2) 0.0147(17) Uani d 0.9279 N
O1 0.8634(5) 0.1366(5) 0.489(2) 0.0147(17) Uani d 0.0721 O
N2 0.6107(6) 0.9245(6) 0.4640(13) 0.0080(9) Uani d 0.9279 N
O2 0.6107(6) 0.9245(6) 0.4640(13) 0.0080(9) Uani d 0.0721 O
N3 0.8402(8) 0.9201(4) 0.2677(19) 0.0117(18) Uani d 0.9279 N
O3 0.8402(8) 0.9201(4) 0.2677(19) 0.0117(18) Uani d 0.0721 O
N4 0.3333 0.6667 0.386(6) 0.031(7) Uani d 0.9279 N
O4 0.3333 0.6667 0.386(6) 0.031(7) Uani d 0.0721 O
N5 0.5521(12) 0.7760(6) 0.956(2) 0.0139(16) Uani d 0.9279 N
O5 0.5521(12) 0.7760(6) 0.956(2) 0.0139(16) Uani d 0.0721 O
N6 0.4825(5) 0.9650(10) 0.8893(18) 0.0125(17) Uani d 0.9279 N
O6 0.4825(5) 0.9650(10) 0.8893(18) 0.0125(17) Uani d 0.0721 O
N7 0.7246(6) 0.0474(6) 0.9843(13) 0.0116(11) Uani d 0.9279 N
O7 0.7246(6) 0.0474(6) 0.9843(13) 0.0116(11) Uani d 0.0721 O
N8 0.6667 0.3333 0.134(3) 0.010(3) Uani d 0.9279 N
O8 0.6667 0.3333 0.134(3) 0.010(3) Uani d 0.0721 O
N9 0.7422(5) 0.2578(5) 0.663(2) 0.0125(16) Uani d 0.9279 N
O9 0.7422(5) 0.2578(5) 0.663(2) 0.0125(16) Uani d 0.0721 O
N10 1 0 0.7620(10) 0.0393(11) Uani d 0.3725 N
O10 1 0 0.7620(10) 0.0393(11) Uani d 0.029 O
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
La La -0.2871 2.4523 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Li Li -0.0003 0.0001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Al Al 0.0645 0.0514 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O6 La1 N6 0.0(5) 1_544 1_544
O6 La1 N8 104.3(4) 1_544 .
N6 La1 N8 104.3(4) 1_544 .
O6 La1 N9 147.8(2) 1_544 .
N6 La1 N9 147.8(2) 1_544 .
N8 La1 N9 69.4(3) . .
O6 La1 O9 147.8(2) 1_544 3_665
N6 La1 O9 147.8(2) 1_544 3_665
N8 La1 O9 69.4(3) . 3_665
N9 La1 O9 61.6(4) . 3_665
O6 La1 N9 147.8(2) 1_544 3_665
N6 La1 N9 147.8(2) 1_544 3_665
N8 La1 N9 69.4(3) . 3_665
N9 La1 N9 61.6(4) . 3_665
O9 La1 N9 0.0(5) 3_665 3_665
O6 La1 O2 79.0(2) 1_544 1_545
N6 La1 O2 79.0(2) 1_544 1_545
N8 La1 O2 137.98(13) . 1_545
N9 La1 O2 85.7(2) . 1_545
O9 La1 O2 127.6(2) 3_665 1_545
N9 La1 O2 127.6(2) 3_665 1_545
O6 La1 N2 79.0(2) 1_544 1_545
N6 La1 N2 79.0(2) 1_544 1_545
N8 La1 N2 137.98(13) . 1_545
N9 La1 N2 85.7(2) . 1_545
O9 La1 N2 127.6(2) 3_665 1_545
N9 La1 N2 127.6(2) 3_665 1_545
O2 La1 N2 0.0(3) 1_545 1_545
O6 La1 O2 79.0(2) 1_544 4_545
N6 La1 O2 79.0(2) 1_544 4_545
N8 La1 O2 137.98(13) . 4_545
N9 La1 O2 127.6(2) . 4_545
O9 La1 O2 85.7(2) 3_665 4_545
N9 La1 O2 85.7(2) 3_665 4_545
O2 La1 O2 84.0(3) 1_545 4_545
N2 La1 O2 84.0(3) 1_545 4_545
O6 La1 N2 79.0(2) 1_544 4_545
N6 La1 N2 79.0(2) 1_544 4_545
N8 La1 N2 137.98(13) . 4_545
N9 La1 N2 127.6(2) . 4_545
O9 La1 N2 85.7(2) 3_665 4_545
N9 La1 N2 85.7(2) 3_665 4_545
O2 La1 N2 84.0(3) 1_545 4_545
N2 La1 N2 84.0(3) 1_545 4_545
O2 La1 N2 0.0(5) 4_545 4_545
O3 La2 N3 0.0(4) 1_545 1_545
O3 La2 O3 75.7(4) 1_545 3_665
N3 La2 O3 75.7(4) 1_545 3_665
O3 La2 N3 75.7(4) 1_545 3_665
N3 La2 N3 75.7(4) 1_545 3_665
O3 La2 N3 0.0(5) 3_665 3_665
O3 La2 O3 75.7(4) 1_545 2_755
N3 La2 O3 75.7(4) 1_545 2_755
O3 La2 O3 75.7(4) 3_665 2_755
N3 La2 O3 75.7(4) 3_665 2_755
O3 La2 N3 75.7(4) 1_545 2_755
N3 La2 N3 75.7(4) 1_545 2_755
O3 La2 N3 75.7(4) 3_665 2_755
N3 La2 N3 75.7(4) 3_665 2_755
O3 La2 N3 0.0(4) 2_755 2_755
O3 La3 N3 0.0(3) 1_545 1_545
O3 La3 O3 59.9(3) 1_545 3_665
N3 La3 O3 59.9(3) 1_545 3_665
O3 La3 N3 59.9(3) 1_545 3_665
N3 La3 N3 59.9(3) 1_545 3_665
O3 La3 N3 0.0(4) 3_665 3_665
O3 La3 O3 59.9(3) 1_545 2_755
N3 La3 O3 59.9(3) 1_545 2_755
O3 La3 O3 59.9(3) 3_665 2_755
N3 La3 O3 59.9(3) 3_665 2_755
O3 La3 N3 59.9(3) 1_545 2_755
N3 La3 N3 59.9(3) 1_545 2_755
O3 La3 N3 59.9(3) 3_665 2_755
N3 La3 N3 59.9(3) 3_665 2_755
O3 La3 N3 0.0(3) 2_755 2_755
O5 Li1 N5 0.00(18) 2_665 2_665
O5 Li1 O5 117.3(4) 2_665 3_565
N5 Li1 O5 117.3(4) 2_665 3_565
O5 Li1 N5 117.3(4) 2_665 3_565
N5 Li1 N5 117.3(4) 2_665 3_565
O5 Li1 N5 0.0(3) 3_565 3_565
O5 Li1 N5 117.3(4) 2_665 .
N5 Li1 N5 117.3(4) 2_665 .
O5 Li1 N5 117.3(4) 3_565 .
N5 Li1 N5 117.3(4) 3_565 .
O5 Li1 N4 99.5(6) 2_665 .
N5 Li1 N4 99.5(6) 2_665 .
O5 Li1 N4 99.5(6) 3_565 .
N5 Li1 N4 99.5(6) 3_565 .
N5 Li1 N4 99.5(6) . .
O5 Li1 O4 80.5(6) 2_665 1_556
N5 Li1 O4 80.5(6) 2_665 1_556
O5 Li1 O4 80.5(6) 3_565 1_556
N5 Li1 O4 80.5(6) 3_565 1_556
N5 Li1 O4 80.5(6) . 1_556
N4 Li1 O4 180 . 1_556
O5 Li1 N4 80.5(6) 2_665 1_556
N5 Li1 N4 80.5(6) 2_665 1_556
O5 Li1 N4 80.5(6) 3_565 1_556
N5 Li1 N4 80.5(6) 3_565 1_556
N5 Li1 N4 80.5(6) . 1_556
N4 Li1 N4 180 . 1_556
O4 Li1 N4 0.000(10) 1_556 1_556
O5 Li1 Al2 40.3(4) 2_665 2_666
N5 Li1 Al2 40.3(4) 2_665 2_666
O5 Li1 Al2 101.1(7) 3_565 2_666
N5 Li1 Al2 101.1(7) 3_565 2_666
N5 Li1 Al2 101.1(7) . 2_666
N4 Li1 Al2 139.8(3) . 2_666
O4 Li1 Al2 40.2(3) 1_556 2_666
N4 Li1 Al2 40.2(3) 1_556 2_666
O5 Li1 Si2 40.3(4) 2_665 2_666
N5 Li1 Si2 40.3(4) 2_665 2_666
O5 Li1 Si2 101.1(7) 3_565 2_666
N5 Li1 Si2 101.1(7) 3_565 2_666
N5 Li1 Si2 101.1(7) . 2_666
N4 Li1 Si2 139.8(3) . 2_666
O4 Li1 Si2 40.2(3) 1_556 2_666
N4 Li1 Si2 40.2(3) 1_556 2_666
N6 Si1 N5 113.3(5) . .
N6 Si1 N2 108.7(4) . .
N5 Si1 N2 110.7(4) . .
N6 Si1 O7 100.0(4) . 1_565
N5 Si1 O7 112.0(5) . 1_565
N2 Si1 O7 111.6(3) . 1_565
N6 Si1 N7 100.0(4) . 1_565
N5 Si1 N7 112.0(5) . 1_565
N2 Si1 N7 111.6(3) . 1_565
O7 Si1 N7 0.0(6) 1_565 1_565
O5 Si2 N5 0.0(5) 1_554 1_554
O5 Si2 N4 113.5(9) 1_554 .
N5 Si2 N4 113.5(9) 1_554 .
O5 Si2 O2 101.0(3) 1_554 5_565
N5 Si2 O2 101.0(3) 1_554 5_565
N4 Si2 O2 120.1(4) . 5_565
O5 Si2 N2 101.0(3) 1_554 5_565
N5 Si2 N2 101.0(3) 1_554 5_565
N4 Si2 N2 120.1(4) . 5_565
O2 Si2 N2 0.0(4) 5_565 5_565
O5 Si2 N2 101.0(3) 1_554 .
N5 Si2 N2 101.0(3) 1_554 .
N4 Si2 N2 120.1(4) . .
O2 Si2 N2 97.5(4) 5_565 .
N2 Si2 N2 97.5(4) 5_565 .
O3 Si3 N3 0.0(6) 1_545 1_545
O3 Si3 N1 103.6(5) 1_545 .
N3 Si3 N1 103.6(5) 1_545 .
O3 Si3 O7 113.4(4) 1_545 1_554
N3 Si3 O7 113.4(4) 1_545 1_554
N1 Si3 O7 109.5(4) . 1_554
O3 Si3 N7 113.4(4) 1_545 1_554
N3 Si3 N7 113.4(4) 1_545 1_554
N1 Si3 N7 109.5(4) . 1_554
O7 Si3 N7 0.0(5) 1_554 1_554
O3 Si3 O2 117.8(3) 1_545 1_545
N3 Si3 O2 117.8(3) 1_545 1_545
N1 Si3 O2 110.1(4) . 1_545
O7 Si3 O2 102.4(3) 1_554 1_545
N7 Si3 O2 102.4(3) 1_554 1_545
O3 Si3 N2 117.8(3) 1_545 1_545
N3 Si3 N2 117.8(3) 1_545 1_545
N1 Si3 N2 110.1(4) . 1_545
O7 Si3 N2 102.4(3) 1_554 1_545
N7 Si3 N2 102.4(3) 1_554 1_545
O2 Si3 N2 0.0(7) 1_545 1_545
N9 Si4 N1 102.8(5) . .
N9 Si4 N7 114.9(3) . .
N1 Si4 N7 108.9(3) . .
N9 Si4 O7 114.9(3) . 6_665
N1 Si4 O7 108.9(3) . 6_665
N7 Si4 O7 106.2(5) . 6_665
N9 Si4 N7 114.9(3) . 6_665
N1 Si4 N7 108.9(3) . 6_665
N7 Si4 N7 106.2(5) . 6_665
O7 Si4 N7 0.0(4) 6_665 6_665
O8 Si5 N8 0.000(5) 1_556 1_556
O8 Si5 N9 110.7(4) 1_556 .
N8 Si5 N9 110.7(4) 1_556 .
O8 Si5 O9 110.7(4) 1_556 3_665
N8 Si5 O9 110.7(4) 1_556 3_665
N9 Si5 O9 108.2(4) . 3_665
O8 Si5 N9 110.7(4) 1_556 3_665
N8 Si5 N9 110.7(4) 1_556 3_665
N9 Si5 N9 108.2(4) . 3_665
O9 Si5 N9 0.0(9) 3_665 3_665
O8 Si5 O9 110.7(4) 1_556 2_655
N8 Si5 O9 110.7(4) 1_556 2_655
N9 Si5 O9 108.2(4) . 2_655
O9 Si5 O9 108.2(4) 3_665 2_655
N9 Si5 O9 108.2(4) 3_665 2_655
O8 Si5 N9 110.7(4) 1_556 2_655
N8 Si5 N9 110.7(4) 1_556 2_655
N9 Si5 N9 108.2(4) . 2_655
O9 Si5 N9 108.2(4) 3_665 2_655
N9 Si5 N9 108.2(4) 3_665 2_655
O9 Si5 N9 0.0(8) 2_655 2_655
Si7 Si6 O10 180 . 1_554
Si7 Si6 N10 180 . 1_554
O10 Si6 N10 0 1_554 1_554
O10 Si6 O3 113.5(5) 1_554 3_665
N10 Si6 O3 113.5(5) 1_554 3_665
O10 Si6 N3 113.5(5) 1_554 3_665
N10 Si6 N3 113.5(5) 1_554 3_665
O3 Si6 N3 0.0(6) 3_665 3_665
O10 Si6 O3 113.5(5) 1_554 1_545
N10 Si6 O3 113.5(5) 1_554 1_545
O3 Si6 O3 105.2(6) 3_665 1_545
N3 Si6 O3 105.2(6) 3_665 1_545
O10 Si6 N3 113.5(5) 1_554 1_545
N10 Si6 N3 113.5(5) 1_554 1_545
O3 Si6 N3 105.2(6) 3_665 1_545
N3 Si6 N3 105.2(6) 3_665 1_545
O3 Si6 N3 0.0(4) 1_545 1_545
O10 Si6 O3 113.5(5) 1_554 2_755
N10 Si6 O3 113.5(5) 1_554 2_755
O3 Si6 O3 105.2(6) 3_665 2_755
N3 Si6 O3 105.2(6) 3_665 2_755
O3 Si6 O3 105.2(6) 1_545 2_755
N3 Si6 O3 105.2(6) 1_545 2_755
O10 Si6 N3 113.5(5) 1_554 2_755
N10 Si6 N3 113.5(5) 1_554 2_755
O3 Si6 N3 105.2(6) 3_665 2_755
N3 Si6 N3 105.2(6) 3_665 2_755
O3 Si6 N3 105.2(6) 1_545 2_755
N3 Si6 N3 105.2(6) 1_545 2_755
O3 Si6 N3 0.0(4) 2_755 2_755
O3 Si7 N3 0.0(4) 1_545 1_545
O3 Si7 O3 103.5(6) 1_545 3_665
N3 Si7 O3 103.5(6) 1_545 3_665
O3 Si7 N3 103.5(6) 1_545 3_665
N3 Si7 N3 103.5(6) 1_545 3_665
O3 Si7 N3 0.0(7) 3_665 3_665
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
La1 O6 1_544 2.549(9)
La1 N6 1_544 2.549(9)
La1 N8 . 2.589(5)
La1 N9 . 2.694(6)
La1 O9 3_665 2.694(6)
La1 N9 3_665 2.694(6)
La1 O2 1_545 2.698(6)
La1 N2 1_545 2.698(6)
La1 O2 4_545 2.698(6)
La1 N2 4_545 2.698(6)
La2 O3 1_545 2.377(11)
La2 N3 1_545 2.377(11)
La2 O3 3_665 2.377(11)
La2 N3 3_665 2.377(11)
La2 O3 2_755 2.377(11)
La2 N3 2_755 2.377(11)
La3 O3 1_545 2.921(10)
La3 N3 1_545 2.921(10)
La3 O3 3_665 2.921(10)
La3 N3 3_665 2.921(10)
La3 O3 2_755 2.921(10)
La3 N3 2_755 2.921(10)
Li1 O5 2_665 2.337(13)
Li1 N5 2_665 2.337(13)
Li1 O5 3_565 2.337(13)
Li1 N5 3_565 2.337(13)
Li1 N5 . 2.337(13)
Li1 N4 . 2.37(4)
Li1 O4 1_556 2.46(4)
Li1 N4 1_556 2.46(4)
Si1 N6 . 1.669(4)
Si1 N5 . 1.728(5)
Si1 N2 . 1.736(7)
Si1 O7 1_565 1.768(7)
Si1 N7 1_565 1.768(7)
Si2 O5 1_554 1.850(11)
Si2 N5 1_554 1.850(11)
Si2 N4 . 1.860(5)
Si2 O2 5_565 1.929(6)
Si2 N2 5_565 1.929(6)
Si2 N2 . 1.929(6)
Si3 O3 1_545 1.723(5)
Si3 N3 1_545 1.723(5)
Si3 N1 . 1.741(6)
Si3 O7 1_554 1.751(7)
Si3 N7 1_554 1.751(7)
Si3 O2 1_545 1.752(6)
Si3 N2 1_545 1.752(6)
Si4 N9 . 1.716(10)
Si4 N1 . 1.726(11)
Si4 N7 . 1.734(7)
Si4 O7 6_665 1.734(7)
Si4 N7 6_665 1.734(7)
Si5 O8 1_556 1.673(16)
Si5 N8 1_556 1.673(16)
Si5 N9 . 1.701(10)
Si5 O9 3_665 1.701(10)
Si5 N9 3_665 1.701(10)
Si5 O9 2_655 1.701(10)
Si5 N9 2_655 1.701(10)
Si6 O10 1_554 1.711(16)
Si6 N10 1_554 1.711(16)
Si6 O3 3_665 1.836(11)
Si6 N3 3_665 1.836(11)
Si6 O3 1_545 1.836(11)
Si6 N3 1_545 1.836(11)
Si6 O3 2_755 1.836(11)
Si6 N3 2_755 1.836(11)
Si7 O3 1_545 1.856(11)
Si7 N3 1_545 1.856(11)
Si7 O3 3_665 1.856(11)
Si7 N3 3_665 1.856(11)
N1 Al3 6_665 1.741(6)
N1 Si3 6_665 1.741(6)
N2 Al3 1_565 1.752(6)
N2 Si3 1_565 1.752(6)
N2 La1 1_565 2.698(6)
N2 Eu1 1_565 2.698(6)
N3 Al3 5 1.723(5)
N3 Si3 5 1.723(5)
N3 Al3 1_565 1.723(5)
N3 Si3 1_565 1.723(5)
N3 Al6 1_565 1.836(11)
N3 Si6 1_565 1.836(11)
N3 Al7 1_565 1.856(11)
N3 Si7 1_565 1.856(11)
N3 Eu2 1_565 2.377(11)
N3 La2 1_565 2.377(11)
N3 La3 1_565 2.921(10)
N3 Eu3 1_565 2.921(10)
N4 Al2 2_665 1.861(5)
N4 Si2 2_665 1.861(5)
N4 Al2 3_565 1.861(5)
N4 Si2 3_565 1.861(5)
N4 Li1 1_554 2.46(4)
N5 Al1 5_565 1.728(5)
N5 Si1 5_565 1.728(5)
N5 Al2 1_556 1.850(11)
N5 Si2 1_556 1.850(11)
N6 Al1 4 1.669(4)
N6 Si1 4 1.669(4)
N6 La1 1_566 2.549(9)
N6 Eu1 1_566 2.549(9)
N6 Eu1 1_565 3.102(9)
N7 Al3 1_556 1.751(7)
N7 Si3 1_556 1.751(7)
N7 Al1 1_545 1.768(6)
N7 Si1 1_545 1.768(6)
N7 La1 1_556 2.998(7)
N7 Eu1 1_556 2.998(7)
N8 Al5 1_554 1.673(16)
N8 Si5 1_554 1.673(16)
N8 Eu1 2_655 2.589(5)
N8 La1 2_655 2.589(5)
N8 La1 3_665 2.589(5)
N8 Eu1 3_665 2.589(5)
N9 Eu1 2_655 2.694(6)
N9 La1 2_655 2.694(6)
