#------------------------------------------------------------------------------
#$Date: 2019-11-22 18:58:41 +0200 (Fri, 22 Nov 2019) $
#$Revision: 231246 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/51/63/4516320.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4516320
loop_
_publ_author_name
'Li, Han-Ning'
'Li, Hai-Yang'
'Li, Lin-Ke'
'Xu, Li'
'Hou, Kai'
'Zang, Shuang-Quan'
'Mak, Thomas C. W.'
_publ_section_title
;
 Syntheses, Structures, and Photoluminescent Properties of Lanthanide
 Coordination Polymers Based on a Zwitterionic Aromatic Polycarboxylate
 Ligand
;
_journal_issue                   9
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              4331
_journal_paper_doi               10.1021/acs.cgd.5b00625
_journal_volume                  15
_journal_year                    2015
_chemical_formula_moiety         'C15 H13 Eu N O8, Cl, 3(H2 O)'
_chemical_formula_sum            'C15 H19 Cl Eu N O11'
_chemical_formula_weight         576.73
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                95.853(4)
_cell_angle_beta                 112.751(6)
_cell_angle_gamma                110.950(5)
_cell_formula_units_Z            2
_cell_length_a                   9.8876(7)
_cell_length_b                   10.2189(4)
_cell_length_c                   12.3454(6)
_cell_measurement_reflns_used    4169
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.1531
_cell_measurement_theta_min      3.2682
_cell_volume                     1031.64(13)
_computing_cell_refinement       'Bruker FRAMBO'
_computing_data_collection       'Bruker FRAMBO'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Xcalibur, Eos, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0476
_diffrn_reflns_av_sigmaI/netI    0.0796
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            7699
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         3.27
_exptl_absorpt_coefficient_mu    3.226
_exptl_absorpt_correction_T_max  0.595
_exptl_absorpt_correction_T_min  0.527
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.857
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             596
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_refine_diff_density_max         2.093
_refine_diff_density_min         -1.623
_refine_diff_density_rms         0.241
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.083
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     256
_refine_ls_number_reflns         3618
_refine_ls_number_restraints     388
_refine_ls_restrained_S_all      1.054
_refine_ls_R_factor_all          0.0628
_refine_ls_R_factor_gt           0.0552
_refine_ls_shift/su_max          0.059
_refine_ls_shift/su_mean         0.003
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0957P)²+2.0456P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1550
_refine_ls_wR_factor_ref         0.1622
_reflns_number_gt                3213
_reflns_number_total             3618
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg5b00625_si_002.cif
_cod_data_source_block           Eu
_cod_original_cell_volume        1031.64(10)
_cod_database_code               4516320
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.32125(5) -0.42775(4) 0.46493(3) 0.01736(19) Uani 1 1 d U
O2 O 0.2059(8) -0.3151(7) 0.5730(6) 0.0306(14) Uani 1 1 d U
O1 O 0.3819(8) -0.1673(7) 0.5233(6) 0.0298(14) Uani 1 1 d DU
O6 O 0.2649(8) 0.3859(7) 1.2981(6) 0.0306(14) Uani 1 1 d U
O5 O 0.4813(8) 0.3438(7) 1.3226(6) 0.0322(15) Uani 1 1 d U
O4 O 0.2200(8) 0.3787(7) 0.5450(6) 0.0302(14) Uani 1 1 d U
O3 O 0.4238(8) 0.3494(7) 0.5357(6) 0.0307(15) Uani 1 1 d U
O2W O 0.0235(8) -0.5469(8) 0.3452(6) 0.0370(16) Uani 1 1 d U
H2WB H -0.0188 -0.5560 0.3938 0.056 Uiso 1 1 d R
H2WA H -0.0068 -0.4946 0.3008 0.056 Uiso 1 1 d R
O1W O 0.2576(10) -0.3359(8) 0.2858(6) 0.049(2) Uani 1 1 d U
H1WA H 0.2605 -0.3892 0.2300 0.074 Uiso 1 1 d R
H1WB H 0.1631 -0.3390 0.2605 0.074 Uiso 1 1 d R
N1 N 0.0969(9) 0.0993(8) 0.8859(6) 0.0239(15) Uani 1 1 d U
C14 C 0.2446(12) 0.1154(12) 0.9546(9) 0.038(2) Uani 1 1 d U
H14 H 0.2929 0.0734 0.9198 0.045 Uiso 1 1 calc R
C13 C 0.3304(13) 0.1921(12) 1.0762(9) 0.038(2) Uani 1 1 d U
H13 H 0.4354 0.2031 1.1234 0.045 Uiso 1 1 calc R
C1 C 0.2773(11) -0.1905(10) 0.5649(8) 0.0243(15) Uani 1 1 d U
C4 C 0.2545(10) 0.1726(9) 0.5972(7) 0.0191(15) Uani 1 1 d U
C8 C 0.1044(10) 0.0263(9) 0.6878(7) 0.0192(15) Uani 1 1 d U
C6 C 0.1563(10) 0.1508(9) 0.6540(7) 0.0196(15) Uani 1 1 d U
H6 H 0.1243 0.2228 0.6699 0.023 Uiso 1 1 calc R
C15 C 0.3429(11) 0.3362(10) 1.2624(8) 0.0251(17) Uani 1 1 d U
C3 C 0.2978(11) 0.0626(9) 0.5709(7) 0.0212(16) Uani 1 1 d U
H3 H 0.3645 0.0758 0.5328 0.025 Uiso 1 1 calc R
C5 C 0.3045(11) 0.3074(9) 0.5573(8) 0.0227(16) Uani 1 1 d U
C12 C 0.2547(11) 0.2525(10) 1.1261(8) 0.0265(17) Uani 1 1 d U
C7 C 0.1479(11) -0.0824(9) 0.6600(7) 0.0217(16) Uani 1 1 d U
H7 H 0.1120 -0.1681 0.6818 0.026 Uiso 1 1 calc R
C2 C 0.2428(10) -0.0663(9) 0.6010(7) 0.0200(15) Uani 1 1 d U
C9 C -0.0013(11) 0.0031(10) 0.7533(7) 0.0246(18) Uani 1 1 d U
H9A H -0.0914 0.0262 0.7103 0.030 Uiso 1 1 calc R
H9B H -0.0458 -0.0986 0.7524 0.030 Uiso 1 1 calc R
C11 C 0.1018(12) 0.2315(11) 1.0543(9) 0.031 Uani 1 1 d U
H11 H 0.0484 0.2682 1.0875 0.038 Uiso 1 1 calc R
C10 C 0.0244(12) 0.1572(11) 0.9337(8) 0.0306(19) Uani 1 1 d U
H10 H -0.0797 0.1468 0.8844 0.037 Uiso 1 1 calc R
Cl1 Cl 0.6668(10) 0.0569(9) 0.7260(7) 0.165(3) Uani 1 1 d DU
O3W O 0.392(3) 0.882(2) 0.058(2) 0.198(9) Uani 1 1 d U
H3WB H 0.3903 0.8742 0.1256 0.237 Uiso 1 1 d R
H3WA H 0.4124 0.9691 0.0546 0.297 Uiso 1 1 d R
O4W O 0.844(4) 0.493(3) 0.116(3) 0.277(14) Uani 1 1 d U
H4WA H 0.9000 0.5726 0.1079 0.416 Uiso 1 1 d R
H4WB H 0.7768 0.4327 0.0456 0.416 Uiso 1 1 d R
O5W O 0.450(10) 0.565(9) 0.073(7) 0.74(7) Uani 1 1 d U
H5WA H 0.4419 0.6013 0.1343 0.890 Uiso 1 1 d R
H5WB H 0.5204 0.5311 0.0976 1.113 Uiso 1 1 d R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O3 Eu1 O4 123.5(2) 2_656 1_545
O3 Eu1 O6 78.4(2) 2_656 1_544
O4 Eu1 O6 85.9(2) 1_545 1_544
O3 Eu1 O1 87.0(2) 2_656 .
O4 Eu1 O1 131.0(2) 1_545 .
O6 Eu1 O1 141.3(2) 1_544 .
O3 Eu1 O5 74.8(2) 2_656 2_657
O4 Eu1 O5 76.5(2) 1_545 2_657
O6 Eu1 O5 131.4(2) 1_544 2_657
O1 Eu1 O5 76.6(2) . 2_657
O3 Eu1 O1W 81.5(3) 2_656 .
O4 Eu1 O1W 143.9(2) 1_545 .
O6 Eu1 O1W 73.4(2) 1_544 .
O1 Eu1 O1W 69.1(2) . .
O5 Eu1 O1W 139.0(2) 2_657 .
O3 Eu1 O2W 147.5(2) 2_656 .
O4 Eu1 O2W 72.5(2) 1_545 .
O6 Eu1 O2W 74.7(2) 1_544 .
O1 Eu1 O2W 102.9(2) . .
O5 Eu1 O2W 137.4(2) 2_657 .
O1W Eu1 O2W 73.7(3) . .
O3 Eu1 O2 134.0(2) 2_656 .
O4 Eu1 O2 81.3(2) 1_545 .
O6 Eu1 O2 146.4(2) 1_544 .
O1 Eu1 O2 52.5(2) . .
O5 Eu1 O2 75.2(2) 2_657 .
O1W Eu1 O2 99.8(3) . .
O2W Eu1 O2 71.9(2) . .
O3 Eu1 C1 112.0(2) 2_656 .
O4 Eu1 C1 106.6(2) 1_545 .
O6 Eu1 C1 152.5(2) 1_544 .
O1 Eu1 C1 26.7(2) . .
O5 Eu1 C1 76.0(2) 2_657 .
O1W Eu1 C1 82.8(3) . .
O2W Eu1 C1 85.6(2) . .
O2 Eu1 C1 26.0(2) . .
O3 Eu1 O3 76.7(2) 2_656 1_545
O4 Eu1 O3 47.8(2) 1_545 1_545
O6 Eu1 O3 65.3(2) 1_544 1_545
O1 Eu1 O3 145.2(2) . 1_545
O5 Eu1 O3 69.5(2) 2_657 1_545
O1W Eu1 O3 136.1(2) . 1_545
O2W Eu1 O3 107.4(2) . 1_545
O2 Eu1 O3 122.7(2) . 1_545
C1 Eu1 O3 140.7(2) . 1_545
O3 Eu1 C5 100.6(2) 2_656 1_545
O4 Eu1 C5 23.6(2) 1_545 1_545
O6 Eu1 C5 73.8(2) 1_544 1_545
O1 Eu1 C5 144.6(2) . 1_545
O5 Eu1 C5 72.3(2) 2_657 1_545
O1W Eu1 C5 146.0(2) . 1_545
O2W Eu1 C5 89.1(2) . 1_545
O2 Eu1 C5 102.4(2) . 1_545
C1 Eu1 C5 125.7(2) . 1_545
O3 Eu1 C5 24.2(2) 1_545 1_545
O3 Eu1 Eu1 42.92(17) 2_656 2_646
O4 Eu1 Eu1 81.10(17) 1_545 2_646
O6 Eu1 Eu1 65.94(16) 1_544 2_646
O1 Eu1 Eu1 122.95(15) . 2_646
O5 Eu1 Eu1 66.74(17) 2_657 2_646
O1W Eu1 Eu1 114.8(2) . 2_646
O2W Eu1 Eu1 133.72(18) . 2_646
O2 Eu1 Eu1 140.83(16) . 2_646
C1 Eu1 Eu1 139.11(18) . 2_646
O3 Eu1 Eu1 33.80(12) 1_545 2_646
C5 Eu1 Eu1 57.81(17) 1_545 2_646
C1 O2 Eu1 93.4(6) . .
C1 O1 Eu1 93.6(5) . .
C15 O6 Eu1 137.6(6) . 1_566
C15 O5 Eu1 136.4(6) . 2_657
C5 O4 Eu1 107.9(6) . 1_565
C5 O3 Eu1 168.5(6) . 2_656
C5 O3 Eu1 83.7(5) . 1_565
Eu1 O3 Eu1 103.3(2) 2_656 1_565
Eu1 O2W H2WB 109.1 . .
Eu1 O2W H2WA 109.3 . .
H2WB O2W H2WA 109.5 . .
Eu1 O1W H1WA 108.7 . .
Eu1 O1W H1WB 109.8 . .
H1WA O1W H1WB 109.5 . .
C14 N1 C10 120.1(8) . .
C14 N1 C9 121.2(8) . .
C10 N1 C9 118.5(8) . .
N1 C14 C13 122.3(10) . .
N1 C14 H14 118.8 . .
C13 C14 H14 118.8 . .
C14 C13 C12 117.6(10) . .
C14 C13 H13 121.2 . .
C12 C13 H13 121.2 . .
O2 C1 O1 119.9(8) . .
O2 C1 C2 121.8(8) . .
O1 C1 C2 118.3(8) . .
O2 C1 Eu1 60.6(5) . .
O1 C1 Eu1 59.7(5) . .
C2 C1 Eu1 172.8(6) . .
C6 C4 C3 118.6(8) . .
C6 C4 C5 120.6(8) . .
C3 C4 C5 120.7(8) . .
C6 C8 C7 118.6(8) . .
C6 C8 C9 122.0(8) . .
C7 C8 C9 119.4(8) . .
C8 C6 C4 121.8(8) . .
C8 C6 H6 119.1 . .
C4 C6 H6 119.1 . .
O5 C15 O6 128.7(8) . .
O5 C15 C12 116.2(8) . .
O6 C15 C12 115.1(8) . .
C2 C3 C4 120.7(8) . .
C2 C3 H3 119.7 . .
C4 C3 H3 119.6 . .
O3 C5 O4 120.5(8) . .
O3 C5 C4 122.0(8) . .
O4 C5 C4 117.5(8) . .
O3 C5 Eu1 72.1(5) . 1_565
O4 C5 Eu1 48.5(4) . 1_565
C4 C5 Eu1 165.5(6) . 1_565
C11 C12 C13 118.9(9) . .
C11 C12 C15 121.1(9) . .
C13 C12 C15 120.0(8) . .
C2 C7 C8 121.4(8) . .
C2 C7 H7 119.3 . .
C8 C7 H7 119.3 . .
C7 C2 C3 118.8(8) . .
C7 C2 C1 119.6(8) . .
C3 C2 C1 121.5(8) . .
N1 C9 C8 111.2(7) . .
N1 C9 H9A 109.4 . .
C8 C9 H9A 109.4 . .
N1 C9 H9B 109.4 . .
C8 C9 H9B 109.4 . .
H9A C9 H9B 108.0 . .
C12 C11 C10 120.8(9) . .
C12 C11 H11 119.6 . .
C10 C11 H11 119.6 . .
N1 C10 C11 120.3(9) . .
N1 C10 H10 119.8 . .
C11 C10 H10 119.8 . .
H3WB O3W H3WA 109.5 . .
H4WA O4W H4WB 109.5 . .
H5WA O5W H5WB 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O3 2.360(6) 2_656
Eu1 O4 2.375(6) 1_545
Eu1 O6 2.394(6) 1_544
Eu1 O1 2.469(6) .
Eu1 O5 2.411(6) 2_657
Eu1 O1W 2.436(7) .
Eu1 O2W 2.457(6) .
Eu1 O2 2.492(7) .
Eu1 C1 2.854(9) .
Eu1 O3 2.889(7) 1_545
Eu1 C5 3.018(9) 1_545
Eu1 Eu1 4.1293(8) 2_646
O2 C1 1.251(11) .
O1 C1 1.285(11) .
O6 C15 1.243(11) .
O6 Eu1 2.394(6) 1_566
O5 C15 1.248(11) .
O5 Eu1 2.411(6) 2_657
O4 C5 1.269(11) .
O4 Eu1 2.375(6) 1_565
O3 C5 1.246(11) .
O3 Eu1 2.360(6) 2_656
O3 Eu1 2.889(7) 1_565
O2W H2WB 0.8500 .
O2W H2WA 0.8500 .
O1W H1WA 0.8499 .
O1W H1WB 0.8500 .
N1 C14 1.312(12) .
N1 C10 1.331(12) .
N1 C9 1.533(10) .
C14 C13 1.373(14) .
C14 H14 0.9300 .
C13 C12 1.390(14) .
C13 H13 0.9300 .
C1 C2 1.496(12) .
C4 C6 1.374(12) .
C4 C3 1.389(12) .
C4 C5 1.491(12) .
C8 C6 1.365(12) .
C8 C7 1.384(12) .
C8 C9 1.522(11) .
C6 H6 0.9300 .
C15 C12 1.536(12) .
C3 C2 1.383(12) .
C3 H3 0.9300 .
C5 Eu1 3.018(9) 1_565
C12 C11 1.345(13) .
C7 C2 1.372(12) .
C7 H7 0.9300 .
C9 H9A 0.9700 .
C9 H9B 0.9700 .
C11 C10 1.361(13) .
C11 H11 0.9300 .
C10 H10 0.9300 .
O3W H3WB 0.8500 .
O3W H3WA 0.8500 .
O4W H4WA 0.8500 .
O4W H4WB 0.8500 .
O5W H5WA 0.8499 .
O5W H5WB 0.8500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O3 Eu1 O2 C1 37.5(7) 2_656 .
O4 Eu1 O2 C1 166.5(6) 1_545 .
O6 Eu1 O2 C1 -124.6(6) 1_544 .
O1 Eu1 O2 C1 4.0(5) . .
O5 Eu1 O2 C1 88.3(5) 2_657 .
O1W Eu1 O2 C1 -50.0(6) . .
O2W Eu1 O2 C1 -119.1(6) . .
O3 Eu1 O2 C1 141.5(5) 1_545 .
C5 Eu1 O2 C1 155.9(5) 1_545 .
Eu1 Eu1 O2 C1 102.3(5) 2_646 .
O3 Eu1 O1 C1 -160.5(5) 2_656 .
O4 Eu1 O1 C1 -27.1(6) 1_545 .
O6 Eu1 O1 C1 132.4(5) 1_544 .
O5 Eu1 O1 C1 -85.4(5) 2_657 .
O1W Eu1 O1 C1 117.5(6) . .
O2W Eu1 O1 C1 50.8(5) . .
O2 Eu1 O1 C1 -3.9(5) . .
O3 Eu1 O1 C1 -99.1(6) 1_545 .
C5 Eu1 O1 C1 -56.3(7) 1_545 .
Eu1 Eu1 O1 C1 -135.7(5) 2_646 .
C10 N1 C14 C13 -0.6(16) . .
C9 N1 C14 C13 -175.1(10) . .
N1 C14 C13 C12 0.6(17) . .
Eu1 O2 C1 O1 -7.1(9) . .
Eu1 O2 C1 C2 172.1(7) . .
Eu1 O1 C1 O2 7.1(9) . .
Eu1 O1 C1 C2 -172.0(7) . .
O3 Eu1 C1 O2 -151.8(5) 2_656 .
O4 Eu1 C1 O2 -13.9(6) 1_545 .
O6 Eu1 C1 O2 100.3(7) 1_544 .
O1 Eu1 C1 O2 -172.9(9) . .
O5 Eu1 C1 O2 -84.9(5) 2_657 .
O1W Eu1 C1 O2 130.4(6) . .
O2W Eu1 C1 O2 56.4(5) . .
O3 Eu1 C1 O2 -55.9(7) 1_545 .
C5 Eu1 C1 O2 -29.4(6) 1_545 .
Eu1 Eu1 C1 O2 -109.5(5) 2_646 .
O3 Eu1 C1 O1 21.1(6) 2_656 .
O4 Eu1 C1 O1 159.0(5) 1_545 .
O6 Eu1 C1 O1 -86.8(7) 1_544 .
O5 Eu1 C1 O1 88.0(5) 2_657 .
O1W Eu1 C1 O1 -56.6(5) . .
O2W Eu1 C1 O1 -130.7(5) . .
O2 Eu1 C1 O1 172.9(9) . .
O3 Eu1 C1 O1 117.1(5) 1_545 .
C5 Eu1 C1 O1 143.6(5) 1_545 .
Eu1 Eu1 C1 O1 63.4(6) 2_646 .
C7 C8 C6 C4 -2.2(12) . .
C9 C8 C6 C4 178.6(7) . .
C3 C4 C6 C8 1.7(12) . .
C5 C4 C6 C8 177.8(8) . .
Eu1 O5 C15 O6 7.1(16) 2_657 .
Eu1 O5 C15 C12 -171.9(6) 2_657 .
Eu1 O6 C15 O5 21.8(16) 1_566 .
Eu1 O6 C15 C12 -159.2(6) 1_566 .
C6 C4 C3 C2 0.2(12) . .
C5 C4 C3 C2 -175.8(8) . .
Eu1 O3 C5 O4 124(3) 2_656 .
Eu1 O3 C5 O4 -3.4(8) 1_565 .
Eu1 O3 C5 C4 -56(3) 2_656 .
Eu1 O3 C5 C4 176.1(8) 1_565 .
Eu1 O3 C5 Eu1 128(3) 2_656 1_565
Eu1 O4 C5 O3 4.3(10) 1_565 .
Eu1 O4 C5 C4 -175.2(6) 1_565 .
C6 C4 C5 O3 160.9(8) . .
C3 C4 C5 O3 -23.1(12) . .
C6 C4 C5 O4 -19.7(12) . .
C3 C4 C5 O4 156.3(8) . .
C6 C4 C5 Eu1 -34(3) . 1_565
C3 C4 C5 Eu1 142(2) . 1_565
C14 C13 C12 C11 1.0(16) . .
C14 C13 C12 C15 178.5(9) . .
O5 C15 C12 C11 176.6(9) . .
O6 C15 C12 C11 -2.5(13) . .
O5 C15 C12 C13 -0.8(13) . .
O6 C15 C12 C13 -179.9(9) . .
C6 C8 C7 C2 0.8(12) . .
C9 C8 C7 C2 179.9(7) . .
C8 C7 C2 C3 1.1(12) . .
C8 C7 C2 C1 -175.8(7) . .
C4 C3 C2 C7 -1.6(12) . .
C4 C3 C2 C1 175.2(7) . .
O2 C1 C2 C7 9.1(13) . .
O1 C1 C2 C7 -171.7(8) . .
O2 C1 C2 C3 -167.7(8) . .
O1 C1 C2 C3 11.5(12) . .
C14 N1 C9 C8 -42.4(12) . .
C10 N1 C9 C8 143.0(9) . .
C6 C8 C9 N1 -72.3(11) . .
C7 C8 C9 N1 108.6(9) . .
C13 C12 C11 C10 -2.5(16) . .
C15 C12 C11 C10 -180.0(9) . .
C14 N1 C10 C11 -1.0(15) . .
C9 N1 C10 C11 173.7(9) . .
C12 C11 C10 N1 2.6(16) . .
