#------------------------------------------------------------------------------
#$Date: 2019-11-24 23:48:06 +0200 (Sun, 24 Nov 2019) $
#$Revision: 239737 $
#$URL: file:///home/coder/svn-repositories/cod/cif/4/51/70/4517091.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4517091
loop_
_publ_author_name
'Liu, Ke'
'Zhou, Jing-Min'
'Li, Hui-Min'
'Xu, Na'
'Cheng, Peng'
_publ_section_title
;
 A Series of CuII--LnIII Metal--Organic Frameworks Based on
 2,2′-Bipyridine-3,3′-dicarboxylic Acid: Syntheses,
 Structures, and Magnetic Properties
;
_journal_issue                   12
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              6409
_journal_paper_doi               10.1021/cg5012617
_journal_volume                  14
_journal_year                    2014
_chemical_formula_moiety         'C60 H42 Cu2 Eu2 N10 O27, 8(O)'
_chemical_formula_sum            'C60 H42 Cu2 Eu2 N10 O35'
_chemical_formula_weight         1894.08
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_cell_setting           monoclinic
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_date             2014-08-23
_audit_creation_method
;
Olex2 1.2
(compiled 2014.03.20 svn.r2914 for OlexSys, GUI svn.r4816)
;
_cell_angle_alpha                90.00
_cell_angle_beta                 99.148(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.2835(3)
_cell_length_b                   22.3634(7)
_cell_length_c                   27.3143(14)
_cell_measurement_temperature    120.0
_cell_measurement_theta_max      29.2481
_cell_measurement_theta_min      2.3564
_cell_volume                     6804.8(5)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'XL (Sheldrick, 2008)'
_computing_structure_solution    'XS (Sheldrick, 2008)'
_diffrn_ambient_temperature      120.0(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_details
;
#__ type_ start__ end____ width___ exp.time_
  1 omega  -74.00  -42.00   1.0000   40.0000
omega____ theta____ kappa____ phi______ frames
    -      -18.8185  135.0000  -50.0000 32

#__ type_ start__ end____ width___ exp.time_
  2 omega  -92.00   16.00   1.0000   40.0000
omega____ theta____ kappa____ phi______ frames
    -      -18.8185  -17.0000  -93.0000 108

#__ type_ start__ end____ width___ exp.time_
  3 omega  -91.00  -41.00   1.0000   40.0000
omega____ theta____ kappa____ phi______ frames
    -      -18.8185  -37.0000 -150.0000 50

;
_diffrn_measurement_device_type  'SuperNova, Single source at offset), Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      -0.0593251000
_diffrn_orient_matrix_UB_12      0.0070609000
_diffrn_orient_matrix_UB_13      0.0035651000
_diffrn_orient_matrix_UB_21      0.0180835000
_diffrn_orient_matrix_UB_22      -0.0012540000
_diffrn_orient_matrix_UB_23      0.0260598000
_diffrn_orient_matrix_UB_31      0.0142921000
_diffrn_orient_matrix_UB_32      0.0308991000
_diffrn_orient_matrix_UB_33      0.0002672000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0537
_diffrn_reflns_av_sigmaI/netI    0.1929
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            22236
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         2.36
_diffrn_source                   'SuperNova (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    2.540
_exptl_absorpt_correction_T_max  0.776
_exptl_absorpt_correction_T_min  0.608
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.19 (release 27-10-2011 CrysAlis171 .NET)
(compiled Oct 27 2011,15:02:11)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.849
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       flaky
_exptl_crystal_F_000             3744
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_platon_squeeze_details          ' '
_refine_diff_density_max         1.293
_refine_diff_density_min         -1.070
_refine_diff_density_rms         0.169
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.075
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     988
_refine_ls_number_reflns         11559
_refine_ls_number_restraints     222
_refine_ls_restrained_S_all      1.059
_refine_ls_R_factor_all          0.0981
_refine_ls_R_factor_gt           0.0592
_refine_ls_shift/su_max          0.007
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0425P)²+36.6849P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1203
_refine_ls_wR_factor_ref         0.1501
_reflns_number_gt                7362
_reflns_number_total             11559
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg5012617_si_002.cif
_cod_data_source_block           7-Eu2Cu2
_cod_original_cell_volume        6804.8(4)
_cod_original_sg_symbol_Hall     '-p 2ybc'
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               4517091
_reflns_odcompleteness_completeness 95.52
_reflns_odcompleteness_theta     26.32
_reflns_odcompleteness_iscentric 1
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All O(H,H) groups
2. Uiso/Uaniso restraints and constraints
 C7 \\sim C8 \\sim C9 \\sim C10 \\sim N4: within 1.7A with sigma of 0.01 and 
sigma for terminal atoms of 0.02
C7 \\del N4 \\del C8 \\del C9 \\del C10 \\del C11: with sigma of 0.001
N1 \\del C18 \\del C19 \\del C20: with sigma of 0.001
C26 \\del C27 \\del C28 \\del C30: with sigma of 0.001
Uains(C8) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uains(N4) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uains(C9) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uains(C10) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uains(C11) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uains(C12) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uains(O4) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uains(O3) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uains(C48) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uains(O13) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uains(C13) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uains(C20) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uains(C7) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uains(C24) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uains(C26) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uains(C28) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uains(C50) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uains(O10) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uains(C34) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uains(C18) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uains(C36) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uains(C19) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uains(C53) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uains(C59) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
3.a Rotating group:
 O21(H21a,H21b), O22(H22a,H22b),O23(H23a,H23b), O24(H24a,H24b), O25(H25a,H25b), 
O26(H26a,H26b)
3.b Aromatic/amide H refined with riding coordinates:
 C3(H3), C4(H4), C5(H5), C8(H8), C9(H9), C10(H10), C15(H15), C16(H16),
 C17(H17), C20(H20), C21(H21), C22(H22), C27(H27), C28(H28), C29(H29), 
C32(H32), C33(H33), C34(H34), C39(H39), C40(H40), C41(H41), C44(H44), 
C45(H45), C46(H46), C51(H51), C52(H52), C53(H53), C57(H57), C58(H58), 
C56(H56)
;
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C -0.2056(9) 0.2748(3) 0.5822(4) 0.021(2) Uani 1 1 d .
C2 C -0.1028(8) 0.2607(3) 0.5547(3) 0.021(2) Uani 1 1 d .
C3 C -0.0040(8) 0.2322(4) 0.5812(4) 0.030(2) Uani 1 1 d .
H3 H 0.0017 0.2271 0.6153 0.037 Uiso 1 1 calc R
C4 C 0.0875(9) 0.2110(4) 0.5565(4) 0.033(3) Uani 1 1 d U
H4 H 0.1537 0.1911 0.5736 0.040 Uiso 1 1 calc R
C5 C 0.0762(8) 0.2208(4) 0.5049(3) 0.023(2) Uani 1 1 d .
H5 H 0.1365 0.2074 0.4880 0.027 Uiso 1 1 calc R
C6 C -0.1082(8) 0.2694(3) 0.5033(3) 0.018(2) Uani 1 1 d .
C7 C -0.2162(11) 0.2942(5) 0.4691(4) 0.046(2) Uani 1 1 d U
C8 C -0.3618(11) 0.2642(5) 0.4055(5) 0.0589(18) Uani 1 1 d U
H8 H -0.3944 0.2337 0.3845 0.071 Uiso 1 1 calc R
C9 C -0.4244(13) 0.3153(5) 0.4054(5) 0.074(3) Uani 1 1 d U
H9 H -0.4996 0.3198 0.3861 0.088 Uiso 1 1 calc R
C10 C -0.3703(12) 0.3618(5) 0.4360(5) 0.060(2) Uani 1 1 d U
H10 H -0.4037 0.3999 0.4330 0.072 Uiso 1 1 calc R
C11 C -0.2653(11) 0.3515(5) 0.4713(4) 0.046(3) Uani 1 1 d U
C12 C -0.2089(12) 0.4011(5) 0.5014(5) 0.056(3) Uani 1 1 d U
C13 C -0.2097(8) 0.4368(3) 0.3086(3) 0.0153(19) Uani 1 1 d U
C14 C -0.1173(7) 0.4139(3) 0.3516(3) 0.015(2) Uani 1 1 d .
C15 C -0.0782(7) 0.4536(3) 0.3909(3) 0.0147(19) Uani 1 1 d U
H15 H -0.1008 0.4936 0.3884 0.018 Uiso 1 1 calc R
C16 C -0.0067(7) 0.4330(3) 0.4329(3) 0.016(2) Uani 1 1 d .
H16 H 0.0260 0.4593 0.4578 0.019 Uiso 1 1 calc R
C17 C 0.0157(7) 0.3719(3) 0.4375(3) 0.019(2) Uani 1 1 d .
H17 H 0.0555 0.3569 0.4674 0.022 Uiso 1 1 calc R
C18 C -0.0759(7) 0.3556(3) 0.3562(3) 0.0119(12) Uani 1 1 d U
C19 C -0.0843(7) 0.3118(3) 0.3158(3) 0.0117(11) Uani 1 1 d U
C20 C -0.1125(7) 0.2104(3) 0.2966(3) 0.0127(12) Uani 1 1 d U
H20 H -0.1272 0.1716 0.3063 0.015 Uiso 1 1 calc R
C21 C -0.1034(7) 0.2217(3) 0.2470(3) 0.018(2) Uani 1 1 d .
H21 H -0.1161 0.1912 0.2236 0.022 Uiso 1 1 calc R
C22 C -0.0753(8) 0.2791(3) 0.2330(3) 0.018(2) Uani 1 1 d .
H22 H -0.0663 0.2871 0.2004 0.021 Uiso 1 1 calc R
C23 C -0.0605(7) 0.3247(3) 0.2685(3) 0.0103(18) Uani 1 1 d .
C24 C -0.0044(8) 0.3839(3) 0.2565(3) 0.0148(19) Uani 1 1 d U
C25 C 0.3636(7) 0.4125(3) 0.1950(3) 0.0106(18) Uani 1 1 d .
C26 C 0.3405(7) 0.3512(3) 0.1691(3) 0.0105(14) Uani 1 1 d U
C27 C 0.2679(7) 0.3114(3) 0.1905(3) 0.0153(16) Uani 1 1 d U
H27 H 0.2239 0.3244 0.2146 0.018 Uiso 1 1 calc R
C28 C 0.2630(7) 0.2531(3) 0.1754(3) 0.019(2) Uani 1 1 d U
H28 H 0.2133 0.2259 0.1881 0.022 Uiso 1 1 calc R
C29 C 0.3331(7) 0.2354(3) 0.1412(3) 0.0140(19) Uani 1 1 d .
H29 H 0.3344 0.1951 0.1328 0.017 Uiso 1 1 calc R
C30 C 0.3977(7) 0.3323(3) 0.1316(3) 0.0124(16) Uani 1 1 d U
C31 C 0.4668(7) 0.3693(3) 0.0996(3) 0.0121(18) Uani 1 1 d U
C32 C 0.6261(8) 0.3664(3) 0.0547(3) 0.017(2) Uani 1 1 d .
H32 H 0.6869 0.3447 0.0436 0.020 Uiso 1 1 calc R
C33 C 0.6094(8) 0.4253(3) 0.0412(3) 0.018(2) Uani 1 1 d .
H33 H 0.6596 0.4439 0.0220 0.021 Uiso 1 1 calc R
C34 C 0.5141(7) 0.4569(3) 0.0571(3) 0.0106(18) Uani 1 1 d U
H34 H 0.5019 0.4970 0.0487 0.013 Uiso 1 1 calc R
C35 C 0.4392(7) 0.4288(3) 0.0850(3) 0.0131(19) Uani 1 1 d .
C36 C 0.3279(7) 0.4606(3) 0.0940(3) 0.0084(17) Uani 1 1 d U
C37 C 0.2800(7) 0.5573(3) 0.3061(3) 0.0113(19) Uani 1 1 d .
C38 C 0.3611(7) 0.5809(3) 0.3510(3) 0.0129(19) Uani 1 1 d .
C39 C 0.3807(8) 0.5456(4) 0.3931(3) 0.021(2) Uani 1 1 d .
H39 H 0.3532 0.5063 0.3914 0.025 Uiso 1 1 calc R
C40 C 0.4396(8) 0.5672(3) 0.4371(3) 0.023(2) Uani 1 1 d .
H40 H 0.4574 0.5426 0.4648 0.027 Uiso 1 1 calc R
C41 C 0.4722(8) 0.6271(3) 0.4393(3) 0.022(2) Uani 1 1 d .
H41 H 0.5053 0.6435 0.4697 0.026 Uiso 1 1 calc R
C42 C 0.4058(7) 0.6395(3) 0.3545(3) 0.0116(18) Uani 1 1 d U
C43 C 0.4083(7) 0.6813(3) 0.3112(3) 0.0111(18) Uani 1 1 d .
C44 C 0.3789(8) 0.7795(3) 0.2856(3) 0.019(2) Uani 1 1 d .
H44 H 0.3586 0.8187 0.2921 0.023 Uiso 1 1 calc R
C45 C 0.4068(7) 0.7657(3) 0.2392(3) 0.015(2) Uani 1 1 d .
H45 H 0.4024 0.7947 0.2146 0.018 Uiso 1 1 calc R
C46 C 0.4416(7) 0.7072(3) 0.2304(3) 0.016(2) Uani 1 1 d .
H46 H 0.4627 0.6968 0.1999 0.019 Uiso 1 1 calc R
C47 C 0.4442(7) 0.6649(3) 0.2675(3) 0.0129(19) Uani 1 1 d .
C48 C 0.5012(7) 0.6052(3) 0.2601(3) 0.0098(17) Uani 1 1 d U
C49 C -0.1356(8) 0.5776(3) 0.1951(3) 0.014(2) Uani 1 1 d .
C50 C -0.1695(7) 0.6384(3) 0.1712(3) 0.0097(17) Uani 1 1 d U
C51 C -0.2445(7) 0.6757(3) 0.1933(3) 0.0138(19) Uani 1 1 d .
H51 H -0.2804 0.6618 0.2195 0.017 Uiso 1 1 calc R
C52 C -0.2654(8) 0.7336(3) 0.1758(3) 0.023(2) Uani 1 1 d .
H52 H -0.3156 0.7595 0.1896 0.028 Uiso 1 1 calc R
C53 C -0.2079(8) 0.7513(4) 0.1367(3) 0.019(2) Uani 1 1 d U
H53 H -0.2193 0.7905 0.1255 0.023 Uiso 1 1 calc R
C54 C -0.1223(7) 0.6591(3) 0.1306(3) 0.0126(18) Uani 1 1 d U
C55 C -0.0447(7) 0.6242(3) 0.1011(3) 0.0110(18) Uani 1 1 d .
C56 C 0.1263(8) 0.6285(4) 0.0638(3) 0.023(2) Uani 1 1 d .
H56 H 0.1917 0.6501 0.0566 0.027 Uiso 1 1 calc R
C57 C 0.1114(8) 0.5698(3) 0.0471(3) 0.016(2) Uani 1 1 d .
H57 H 0.1656 0.5521 0.0292 0.019 Uiso 1 1 calc R
C58 C 0.0128(8) 0.5387(3) 0.0582(3) 0.019(2) Uani 1 1 d .
H58 H 0.0005 0.4993 0.0479 0.022 Uiso 1 1 calc R
C59 C -0.0672(7) 0.5658(3) 0.0844(3) 0.0106(18) Uani 1 1 d U
C60 C -0.1780(7) 0.5310(3) 0.0935(3) 0.0142(19) Uani 1 1 d .
N1 N -0.1005(6) 0.2547(3) 0.3308(2) 0.0120(11) Uani 1 1 d U
N2 N -0.0186(6) 0.3341(3) 0.3999(2) 0.0130(15) Uani 1 1 d U
N3 N -0.0194(7) 0.2490(3) 0.4797(3) 0.0182(17) Uani 1 1 d .
N4 N -0.2541(9) 0.2543(4) 0.4343(4) 0.0531(17) Uani 1 1 d U
N5 N 0.5567(6) 0.3395(3) 0.0836(3) 0.0128(16) Uani 1 1 d .
N6 N 0.3986(6) 0.2732(3) 0.1197(3) 0.0136(17) Uani 1 1 d .
N7 N 0.3802(6) 0.7386(3) 0.3211(3) 0.0132(16) Uani 1 1 d .
N8 N 0.4575(6) 0.6614(3) 0.3996(3) 0.0149(16) Uani 1 1 d .
N9 N -0.1381(6) 0.7165(3) 0.1143(3) 0.0191(18) Uani 1 1 d .
N10 N 0.0496(6) 0.6554(3) 0.0901(3) 0.0142(16) Uani 1 1 d .
O1 O -0.3076(5) 0.2598(2) 0.5601(2) 0.0171(14) Uani 1 1 d .
O2 O -0.1784(5) 0.2954(3) 0.6253(2) 0.0289(16) Uani 1 1 d .
O3 O -0.1199(7) 0.3903(3) 0.5337(3) 0.048(2) Uani 1 1 d U
O4 O -0.2521(7) 0.4527(3) 0.4895(3) 0.062(2) Uani 1 1 d U
O5 O 0.1046(5) 0.3926(2) 0.2757(2) 0.0160(14) Uani 1 1 d .
O6 O -0.0613(5) 0.4213(2) 0.2278(2) 0.0152(14) Uani 1 1 d .
O7 O -0.2772(5) 0.4004(2) 0.2824(2) 0.0173(14) Uani 1 1 d .
O8 O -0.2207(5) 0.4932(2) 0.3032(2) 0.0150(14) Uani 1 1 d .
O9 O 0.2821(5) 0.4351(2) 0.2142(2) 0.0179(14) Uani 1 1 d .
O10 O 0.4680(5) 0.4335(2) 0.1961(2) 0.0140(13) Uani 1 1 d U
O11 O 0.2320(5) 0.4321(2) 0.0860(2) 0.0182(14) Uani 1 1 d .
O12 O 0.3411(5) 0.5153(2) 0.1070(2) 0.0152(13) Uani 1 1 d .
O13 O 0.4417(5) 0.5660(2) 0.2319(2) 0.0138(13) Uani 1 1 d U
O14 O 0.6077(5) 0.5957(2) 0.2801(2) 0.0194(15) Uani 1 1 d .
O15 O 0.2793(5) 0.5000(2) 0.3008(2) 0.0160(14) Uani 1 1 d .
O16 O 0.2132(5) 0.5899(2) 0.2774(2) 0.0167(14) Uani 1 1 d .
O17 O -0.0320(5) 0.5590(2) 0.1928(2) 0.0143(13) Uani 1 1 d .
O18 O -0.2122(5) 0.5529(2) 0.2167(2) 0.0153(13) Uani 1 1 d .
O19 O -0.1626(5) 0.4765(2) 0.1048(2) 0.0164(14) Uani 1 1 d .
O20 O -0.2767(5) 0.5583(2) 0.0867(2) 0.0200(15) Uani 1 1 d .
O21 O 0.0138(5) 0.5209(2) 0.2973(2) 0.0175(14) Uani 1 1 d .
H21A H 0.0465 0.5519 0.3118 0.026 Uiso 1 1 d R
H21B H 0.0177 0.4922 0.3181 0.026 Uiso 1 1 d R
O22 O 0.0644(5) 0.4483(2) 0.1486(2) 0.0167(14) Uani 1 1 d .
H22A H -0.0118 0.4508 0.1393 0.025 Uiso 1 1 d R
H22B H 0.0849 0.4113 0.1499 0.025 Uiso 1 1 d R
O23 O 0.2209(5) 0.5590(2) 0.1788(2) 0.0153(13) Uani 1 1 d U
H23A H 0.1741 0.5879 0.1675 0.023 Uiso 1 1 d R
H23B H 0.2402 0.5392 0.1543 0.023 Uiso 1 1 d R
O24 O -0.2835(5) 0.4330(2) 0.1777(2) 0.0137(13) Uani 1 1 d U
H24A H -0.3327 0.4055 0.1651 0.020 Uiso 1 1 d R
H24B H -0.2207 0.4163 0.1942 0.020 Uiso 1 1 d R
O25 O -0.4350(5) 0.5456(2) 0.1531(2) 0.0174(14) Uani 1 1 d .
H25A H -0.5102 0.5392 0.1416 0.026 Uiso 1 1 d R
H25B H -0.3922 0.5313 0.1321 0.026 Uiso 1 1 d R
O26 O -0.4812(5) 0.4696(2) 0.3023(2) 0.0185(14) Uani 1 1 d .
H26A H -0.4429 0.4846 0.3300 0.028 Uiso 1 1 d R
H26B H -0.4838 0.4307 0.3056 0.028 Uiso 1 1 d R
Cu5 Cu -0.04110(9) 0.24561(4) 0.40533(4) 0.0130(2) Uani 1 1 d .
Cu6 Cu 0.55112(9) 0.25074(4) 0.09202(4) 0.0148(3) Uani 1 1 d .
Eu1 Eu 0.11771(4) 0.493241(16) 0.230138(16) 0.00952(13) Uani 1 1 d .
Eu3 Eu -0.37956(4) 0.497193(15) 0.233120(16) 0.01061(13) Uani 1 1 d .
O35 O 0.4125(7) 0.2486(3) 0.0082(3) 0.053(2) Uani 1 1 d .
O29 O -0.3059(8) 0.5612(3) 0.5238(4) 0.079(3) Uani 1 1 d .
O32 O 0.7864(7) 0.6063(3) 0.3695(3) 0.049(2) Uani 1 1 d .
O34 O 0.2517(9) 0.3995(3) 0.3757(3) 0.083(4) Uani 1 1 d .
O30 O -0.0356(7) 0.3961(3) 0.6307(3) 0.054(2) Uani 1 1 d .
O28 O -0.3499(7) 0.4992(3) 0.3952(3) 0.062(3) Uani 1 1 d .
O31 O -0.2934(7) 0.6381(3) 0.0063(3) 0.058(3) Uani 1 1 d .
O33 O 0.7610(8) 0.6543(4) 0.4691(4) 0.092(3) Uani 1 1 d .
O27 O -0.6236(10) 0.3639(4) 0.3108(4) 0.111(4) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0030 0.0020 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3200 1.2650 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1580 3.6680 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0060 0.0030 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0110 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 C1 O1 128.2(9) . .
O2 C1 C2 116.7(8) . .
O1 C1 C2 114.8(8) . .
C3 C2 C6 119.2(9) . .
C3 C2 C1 117.0(9) . .
C6 C2 C1 123.4(8) . .
C2 C3 C4 119.8(10) . .
C2 C3 H3 120.1 . .
C4 C3 H3 120.1 . .
C3 C4 C5 118.2(9) . .
C3 C4 H4 120.9 . .
C5 C4 H4 120.9 . .
N3 C5 C4 121.5(9) . .
N3 C5 H5 119.2 . .
C4 C5 H5 119.2 . .
N3 C6 C2 120.7(8) . .
N3 C6 C7 114.4(9) . .
C2 C6 C7 124.6(9) . .
N4 C7 C11 124.3(11) . .
N4 C7 C6 109.3(9) . .
C11 C7 C6 126.3(10) . .
C9 C8 N4 124.3(12) . .
C9 C8 H8 117.8 . .
N4 C8 H8 117.8 . .
C8 C9 C10 116.5(13) . .
C8 C9 H9 121.7 . .
C10 C9 H9 121.7 . .
C9 C10 C11 121.2(11) . .
C9 C10 H10 119.4 . .
C11 C10 H10 119.4 . .
C7 C11 C10 114.3(10) . .
C7 C11 C12 125.3(11) . .
C10 C11 C12 119.9(10) . .
O3 C12 O4 125.9(11) . .
O3 C12 C11 118.6(11) . .
O4 C12 C11 115.3(11) . .
O7 C13 O8 122.5(7) . .
O7 C13 C14 119.9(7) . .
O8 C13 C14 117.5(7) . .
O7 C13 Eu3 68.1(4) . .
O8 C13 Eu3 54.5(4) . .
C14 C13 Eu3 171.8(5) . .
C18 C14 C15 117.7(7) . .
C18 C14 C13 124.3(7) . .
C15 C14 C13 117.8(7) . .
C16 C15 C14 119.7(7) . .
C16 C15 H15 120.1 . .
C14 C15 H15 120.1 . .
C15 C16 C17 118.6(7) . .
C15 C16 H16 120.7 . .
C17 C16 H16 120.7 . .
N2 C17 C16 121.7(8) . .
N2 C17 H17 119.2 . .
C16 C17 H17 119.2 . .
N2 C18 C14 121.4(7) . .
N2 C18 C19 113.1(6) . .
C14 C18 C19 125.5(7) . .
N1 C19 C23 121.9(7) . .
N1 C19 C18 113.2(7) . .
C23 C19 C18 124.2(7) . .
N1 C20 C21 121.5(7) . .
N1 C20 H20 119.3 . .
C21 C20 H20 119.3 . .
C22 C21 C20 119.2(7) . .
C22 C21 H21 120.4 . .
C20 C21 H21 120.4 . .
C21 C22 C23 119.4(8) . .
C21 C22 H22 120.3 . .
C23 C22 H22 120.3 . .
C19 C23 C22 118.3(7) . .
C19 C23 C24 121.9(7) . .
C22 C23 C24 119.4(8) . .
O6 C24 O5 121.4(7) . .
O6 C24 C23 121.8(7) . .
O5 C24 C23 116.8(7) . .
O6 C24 Eu1 60.4(4) . .
O5 C24 Eu1 61.0(4) . .
C23 C24 Eu1 175.7(6) . .
O9 C25 O10 126.2(7) . .
O9 C25 C26 118.3(7) . .
O10 C25 C26 115.5(7) . .
C30 C26 C27 119.6(7) . .
C30 C26 C25 123.7(7) . .
C27 C26 C25 116.2(7) . .
C28 C27 C26 118.7(8) . .
C28 C27 H27 120.7 . .
C26 C27 H27 120.7 . .
C27 C28 C29 118.7(8) . .
C27 C28 H28 120.6 . .
C29 C28 H28 120.6 . .
N6 C29 C28 122.7(7) . .
N6 C29 H29 118.7 . .
C28 C29 H29 118.7 . .
N6 C30 C26 120.3(8) . .
N6 C30 C31 111.7(7) . .
C26 C30 C31 127.9(7) . .
N5 C31 C35 121.4(8) . .
N5 C31 C30 113.7(6) . .
C35 C31 C30 124.8(8) . .
N5 C32 C33 121.5(8) . .
N5 C32 H32 119.3 . .
C33 C32 H32 119.3 . .
C32 C33 C34 118.4(8) . .
C32 C33 H33 120.8 . .
C34 C33 H33 120.8 . .
C35 C34 C33 120.4(7) . .
C35 C34 H34 119.8 . .
C33 C34 H34 119.8 . .
C34 C35 C31 117.4(8) . .
C34 C35 C36 118.6(6) . .
C31 C35 C36 123.8(7) . .
O11 C36 O12 126.7(7) . .
O11 C36 C35 117.3(6) . .
O12 C36 C35 115.9(7) . .
O16 C37 O15 121.6(7) . .
O16 C37 C38 122.8(6) . .
O15 C37 C38 115.6(7) . .
O16 C37 Eu1 65.6(4) . .
O15 C37 Eu1 56.0(4) . .
C38 C37 Eu1 169.8(5) . .
C39 C38 C42 117.8(7) . .
C39 C38 C37 118.3(7) . .
C42 C38 C37 123.4(7) . .
C40 C39 C38 121.4(8) . .
C40 C39 H39 119.3 . .
C38 C39 H39 119.3 . .
C39 C40 C41 117.9(8) . .
C39 C40 H40 121.0 . .
C41 C40 H40 121.0 . .
N8 C41 C40 122.0(8) . .
N8 C41 H41 119.0 . .
C40 C41 H41 119.0 . .
N8 C42 C38 119.6(7) . .
N8 C42 C43 115.2(6) . .
C38 C42 C43 125.1(7) . .
N7 C43 C47 122.4(7) . .
N7 C43 C42 113.2(7) . .
C47 C43 C42 124.2(7) . .
N7 C44 C45 122.3(7) . .
N7 C44 H44 118.9 . .
C45 C44 H44 118.9 . .
C44 C45 C46 118.5(8) . .
C44 C45 H45 120.8 . .
C46 C45 H45 120.8 . .
C47 C46 C45 119.1(8) . .
C47 C46 H46 120.5 . .
C45 C46 H46 120.5 . .
C43 C47 C46 118.8(7) . .
C43 C47 C48 122.9(7) . .
C46 C47 C48 117.8(8) . .
O14 C48 O13 121.3(7) . .
O14 C48 C47 119.3(7) . .
O13 C48 C47 119.4(7) . .
O14 C48 Eu3 61.5(4) . 1_655
O13 C48 Eu3 60.1(4) . 1_655
C47 C48 Eu3 171.8(6) . 1_655
O18 C49 O17 126.6(7) . .
O18 C49 C50 116.8(7) . .
O17 C49 C50 116.5(7) . .
C54 C50 C51 119.1(7) . .
C54 C50 C49 122.5(7) . .
C51 C50 C49 118.3(7) . .
C52 C51 C50 119.4(8) . .
C52 C51 H51 120.3 . .
C50 C51 H51 120.3 . .
C51 C52 C53 117.0(8) . .
C51 C52 H52 121.5 . .
C53 C52 H52 121.5 . .
N9 C53 C52 124.9(8) . .
N9 C53 H53 117.5 . .
C52 C53 H53 117.5 . .
N9 C54 C50 122.1(8) . .
N9 C54 C55 111.9(7) . .
C50 C54 C55 126.0(7) . .
N10 C55 C59 121.5(8) . .
N10 C55 C54 113.5(6) . .
C59 C55 C54 124.9(7) . .
N10 C56 C57 122.8(8) . .
N10 C56 H56 118.6 . .
C57 C56 H56 118.6 . .
C58 C57 C56 117.4(8) . .
C58 C57 H57 121.3 . .
C56 C57 H57 121.3 . .
C59 C58 C57 120.5(7) . .
C59 C58 H58 119.8 . .
C57 C58 H58 119.8 . .
C58 C59 C55 118.8(8) . .
C58 C59 C60 118.7(6) . .
C55 C59 C60 122.4(7) . .
O20 C60 O19 126.1(7) . .
O20 C60 C59 117.2(6) . .
O19 C60 C59 116.6(7) . .
C20 N1 C19 118.7(7) . .
C20 N1 Cu5 126.5(5) . .
C19 N1 Cu5 110.7(5) . .
C17 N2 C18 119.6(6) . .
C17 N2 Cu5 126.2(6) . .
C18 N2 Cu5 111.6(5) . .
C5 N3 C6 120.6(8) . .
C5 N3 Cu5 117.4(6) . .
C6 N3 Cu5 120.9(6) . .
C7 N4 C8 117.5(10) . .
C7 N4 Cu5 93.4(8) . .
C8 N4 Cu5 127.5(8) . .
C32 N5 C31 120.7(6) . .
C32 N5 Cu6 123.1(6) . .
C31 N5 Cu6 114.5(5) . .
C29 N6 C30 119.3(8) . .
C29 N6 Cu6 124.6(5) . .
C30 N6 Cu6 111.4(5) . .
C44 N7 C43 118.6(7) . .
C44 N7 Cu6 127.5(5) . 2_655
C43 N7 Cu6 104.8(5) . 2_655
C41 N8 C42 120.9(7) . .
C41 N8 Cu6 119.1(6) . 2_655
C42 N8 Cu6 115.8(5) . 2_655
C53 N9 C54 117.3(8) . .
C53 N9 Cu5 124.0(5) . 2
C54 N9 Cu5 105.8(5) . 2
C55 N10 C56 118.9(7) . .
C55 N10 Cu5 117.1(5) . 2
C56 N10 Cu5 121.2(6) . 2
C1 O1 Cu6 124.5(6) . 4_466
C24 O5 Eu1 93.5(4) . .
C24 O6 Eu1 94.6(5) . .
C13 O7 Eu3 86.4(4) . .
C13 O8 Eu3 100.0(5) . .
C25 O9 Eu1 164.2(6) . .
C25 O10 Eu3 148.9(5) . 1_655
C48 O13 Eu3 93.8(4) . 1_655
C48 O14 Eu3 93.0(4) . 1_655
C37 O15 Eu1 98.0(4) . .
C37 O16 Eu1 89.3(4) . .
C49 O17 Eu1 143.2(6) . .
C49 O18 Eu3 162.9(6) . .
Eu1 O21 H21A 109.6 . .
Eu1 O21 H21B 109.5 . .
H21A O21 H21B 109.2 . .
Eu1 O22 H22A 109.7 . .
Eu1 O22 H22B 109.6 . .
H22A O22 H22B 108.9 . .
Eu1 O23 H23A 109.6 . .
Eu1 O23 H23B 109.8 . .
H23A O23 H23B 108.8 . .
Eu3 O24 H24A 110.1 . .
Eu3 O24 H24B 109.7 . .
H24A O24 H24B 108.7 . .
Eu3 O25 H25A 110.4 . .
Eu3 O25 H25B 109.9 . .
H25A O25 H25B 108.4 . .
Eu3 O26 H26A 110.2 . .
Eu3 O26 H26B 111.0 . .
H26A O26 H26B 108.1 . .
N2 Cu5 N3 92.4(3) . .
N2 Cu5 N10 175.3(3) . 2_545
N3 Cu5 N10 88.5(3) . 2_545
N2 Cu5 N1 81.6(2) . .
N3 Cu5 N1 165.6(3) . .
N10 Cu5 N1 98.6(3) 2_545 .
N2 Cu5 N9 97.9(3) . 2_545
N3 Cu5 N9 106.2(3) . 2_545
N10 Cu5 N9 77.4(3) 2_545 2_545
N1 Cu5 N9 87.6(3) . 2_545
N2 Cu5 N4 94.7(3) . .
N3 Cu5 N4 70.5(3) . .
N10 Cu5 N4 90.0(3) 2_545 .
N1 Cu5 N4 96.9(3) . .
N9 Cu5 N4 167.2(2) 2_545 .
O1 Cu6 N5 91.4(3) 4_665 .
O1 Cu6 N8 89.3(3) 4_665 2_645
N5 Cu6 N8 179.1(3) . 2_645
O1 Cu6 N6 171.6(2) 4_665 .
N5 Cu6 N6 81.0(3) . .
N8 Cu6 N6 98.2(3) 2_645 .
O1 Cu6 N7 105.7(2) 4_665 2_645
N5 Cu6 N7 102.5(2) . 2_645
N8 Cu6 N7 77.8(2) 2_645 2_645
N6 Cu6 N7 79.7(2) . 2_645
O1 Cu6 O35 91.4(3) 4_665 .
N5 Cu6 O35 86.6(2) . .
N8 Cu6 O35 92.8(2) 2_645 .
N6 Cu6 O35 84.5(3) . .
N7 Cu6 O35 160.2(2) 2_645 .
O17 Eu1 O9 142.8(2) . .
O17 Eu1 O21 76.48(19) . .
O9 Eu1 O21 140.67(19) . .
O17 Eu1 O22 78.71(18) . .
O9 Eu1 O22 71.98(19) . .
O21 Eu1 O22 136.39(18) . .
O17 Eu1 O15 134.48(17) . .
O9 Eu1 O15 70.76(19) . .
O21 Eu1 O15 76.98(19) . .
O22 Eu1 O15 142.73(19) . .
O17 Eu1 O23 75.54(18) . .
O9 Eu1 O23 76.47(19) . .
O21 Eu1 O23 127.92(17) . .
O22 Eu1 O23 78.17(18) . .
O15 Eu1 O23 92.99(18) . .
O17 Eu1 O6 82.69(17) . .
O9 Eu1 O6 106.71(18) . .
O21 Eu1 O6 72.79(18) . .
O22 Eu1 O6 68.91(18) . .
O15 Eu1 O6 122.86(17) . .
O23 Eu1 O6 143.45(17) . .
O17 Eu1 O5 131.42(18) . .
O9 Eu1 O5 73.53(19) . .
O21 Eu1 O5 77.61(18) . .
O22 Eu1 O5 93.21(17) . .
O15 Eu1 O5 76.49(16) . .
O23 Eu1 O5 150.00(18) . .
O6 Eu1 O5 50.48(16) . .
O17 Eu1 O16 84.84(17) . .
O9 Eu1 O16 105.53(18) . .
O21 Eu1 O16 68.31(18) . .
O22 Eu1 O16 143.51(18) . .
O15 Eu1 O16 51.01(15) . .
O23 Eu1 O16 66.20(18) . .
O6 Eu1 O16 140.92(18) . .
O5 Eu1 O16 121.61(17) . .
O17 Eu1 C37 109.19(19) . .
O9 Eu1 C37 88.8(2) . .
O21 Eu1 C37 70.1(2) . .
O22 Eu1 C37 153.0(2) . .
O15 Eu1 C37 25.97(17) . .
O23 Eu1 C37 79.1(2) . .
O6 Eu1 C37 136.5(2) . .
O5 Eu1 C37 99.38(19) . .
O16 Eu1 C37 25.05(17) . .
O17 Eu1 C24 107.1(2) . .
O9 Eu1 C24 90.0(2) . .
O21 Eu1 C24 74.0(2) . .
O22 Eu1 C24 79.8(2) . .
O15 Eu1 C24 100.2(2) . .
O23 Eu1 C24 156.9(2) . .
O6 Eu1 C24 25.00(18) . .
O5 Eu1 C24 25.49(19) . .
O16 Eu1 C24 136.4(2) . .
C37 Eu1 C24 119.9(2) . .
O10 Eu3 O18 142.6(2) 1_455 .
O10 Eu3 O8 136.56(17) 1_455 .
O18 Eu3 O8 69.76(18) . .
O10 Eu3 O25 79.36(18) 1_455 .
O18 Eu3 O25 72.18(19) . .
O8 Eu3 O25 141.67(19) . .
O10 Eu3 O26 77.12(19) 1_455 .
O18 Eu3 O26 140.18(18) . .
O8 Eu3 O26 75.92(19) . .
O25 Eu3 O26 136.35(18) . .
O10 Eu3 O24 75.17(19) 1_455 .
O18 Eu3 O24 75.34(18) . .
O8 Eu3 O24 97.05(18) . .
O25 Eu3 O24 77.42(17) . .
O26 Eu3 O24 129.52(17) . .
O10 Eu3 O13 80.47(17) 1_455 1_455
O18 Eu3 O13 109.66(17) . 1_455
O8 Eu3 O13 121.55(17) . 1_455
O25 Eu3 O13 68.10(18) . 1_455
O26 Eu3 O13 72.09(17) . 1_455
O24 Eu3 O13 140.77(17) . 1_455
O10 Eu3 O14 130.09(18) 1_455 1_455
O18 Eu3 O14 75.69(19) . 1_455
O8 Eu3 O14 74.18(16) . 1_455
O25 Eu3 O14 92.33(17) . 1_455
O26 Eu3 O14 76.05(18) . 1_455
O24 Eu3 O14 150.99(18) . 1_455
O13 Eu3 O14 51.46(16) 1_455 1_455
O10 Eu3 O7 87.41(16) 1_455 .
O18 Eu3 O7 102.97(17) . .
O8 Eu3 O7 51.00(15) . .
O25 Eu3 O7 146.23(18) . .
O26 Eu3 O7 68.23(17) . .
O24 Eu3 O7 69.16(17) . .
O13 Eu3 O7 140.16(18) 1_455 .
O14 Eu3 O7 119.41(17) 1_455 .
O10 Eu3 C13 112.3(2) 1_455 .
O18 Eu3 C13 85.6(2) . .
O8 Eu3 C13 25.53(17) . .
O25 Eu3 C13 152.8(2) . .
O26 Eu3 C13 70.9(2) . .
O24 Eu3 C13 81.9(2) . .
O13 Eu3 C13 136.4(2) 1_455 .
O14 Eu3 C13 97.31(19) 1_455 .
O7 Eu3 C13 25.49(17) . .
O10 Eu3 C48 106.1(2) 1_455 1_455
O18 Eu3 C48 91.5(2) . 1_455
O8 Eu3 C48 98.29(19) . 1_455
O25 Eu3 C48 78.2(2) . 1_455
O26 Eu3 C48 73.8(2) . 1_455
O24 Eu3 C48 154.9(2) . 1_455
O13 Eu3 C48 26.07(18) 1_455 1_455
O14 Eu3 C48 25.47(18) 1_455 1_455
O7 Eu3 C48 135.5(2) . 1_455
C13 Eu3 C48 118.9(2) . 1_455
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O2 1.255(10) .
C1 O1 1.257(10) .
C1 C2 1.512(13) .
C2 C3 1.384(11) .
C2 C6 1.411(12) .
C3 C4 1.403(13) .
C3 H3 0.9300 .
C4 C5 1.412(13) .
C4 H4 0.9300 .
C5 N3 1.342(10) .
C5 H5 0.9300 .
C6 N3 1.354(11) .
C6 C7 1.518(13) .
C7 N4 1.324(13) .
C7 C11 1.400(14) .
C8 C9 1.343(15) .
C8 N4 1.357(13) .
C8 H8 0.9300 .
C9 C10 1.411(15) .
C9 H9 0.9300 .
C10 C11 1.423(15) .
C10 H10 0.9300 .
C11 C12 1.465(15) .
C12 O3 1.250(12) .
C12 O4 1.275(13) .
C13 O7 1.256(9) .
C13 O8 1.275(8) .
C13 C14 1.531(11) .
C13 Eu3 2.914(8) .
C14 C18 1.384(10) .
C14 C15 1.409(11) .
C15 C16 1.374(10) .
C15 H15 0.9300 .
C16 C17 1.392(10) .
C16 H16 0.9300 .
C17 N2 1.338(10) .
C17 H17 0.9300 .
C18 N2 1.351(9) .
C18 C19 1.466(10) .
C19 N1 1.364(9) .
C19 C23 1.390(11) .
C20 N1 1.354(9) .
C20 C21 1.399(11) .
C20 H20 0.9300 .
C21 C22 1.390(11) .
C21 H21 0.9300 .
C22 C23 1.398(10) .
C22 H22 0.9300 .
C23 C24 1.526(10) .
C24 O6 1.252(9) .
C24 O5 1.273(9) .
C24 Eu1 2.952(8) .
C25 O9 1.237(9) .
C25 O10 1.265(9) .
C25 C26 1.543(10) .
C26 C30 1.364(11) .
C26 C27 1.399(11) .
C27 C28 1.366(10) .
C27 H27 0.9300 .
C28 C29 1.377(12) .
C28 H28 0.9300 .
C29 N6 1.321(10) .
C29 H29 0.9300 .
C30 N6 1.360(9) .
C30 C31 1.509(11) .
C31 N5 1.344(10) .
C31 C35 1.409(10) .
C32 N5 1.338(10) .
C32 C33 1.373(10) .
C32 H32 0.9300 .
C33 C34 1.411(11) .
C33 H33 0.9300 .
C34 C35 1.376(11) .
C34 H34 0.9300 .
C35 C36 1.497(11) .
C36 O11 1.244(9) .
C36 O12 1.278(8) .
C37 O16 1.235(9) .
C37 O15 1.289(8) .
C37 C38 1.503(11) .
C37 Eu1 2.916(8) .
C38 C39 1.385(11) .
C38 C42 1.403(10) .
C39 C40 1.367(11) .
C39 H39 0.9300 .
C40 C41 1.388(10) .
C40 H40 0.9300 .
C41 N8 1.316(10) .
C41 H41 0.9300 .
C42 N8 1.367(10) .
C42 C43 1.511(11) .
C43 N7 1.357(9) .
C43 C47 1.371(11) .
C44 N7 1.334(10) .
C44 C45 1.387(12) .
C44 H44 0.9300 .
C45 C46 1.399(10) .
C45 H45 0.9300 .
C46 C47 1.383(11) .
C46 H46 0.9300 .
C47 C48 1.511(10) .
C48 O14 1.256(9) .
C48 O13 1.284(8) .
C48 Eu3 2.915(7) 1_655
C49 O18 1.250(10) .
C49 O17 1.252(10) .
C49 C50 1.530(10) .
C50 C54 1.383(11) .
C50 C51 1.393(11) .
C51 C52 1.389(10) .
C51 H51 0.9300 .
C52 C53 1.393(12) .
C52 H52 0.9300 .
C53 N9 1.324(11) .
C53 H53 0.9300 .
C54 N9 1.361(9) .
C54 C55 1.501(11) .
C55 N10 1.346(10) .
C55 C59 1.391(10) .
C56 N10 1.350(11) .
C56 C57 1.391(10) .
C56 H56 0.9300 .
C57 C58 1.386(11) .
C57 H57 0.9300 .
C58 C59 1.379(12) .
C58 H58 0.9300 .
C59 C60 1.526(11) .
C60 O20 1.258(9) .
C60 O19 1.263(9) .
N1 Cu5 2.048(6) .
N2 Cu5 2.004(6) .
N3 Cu5 2.008(7) .
N4 Cu5 2.654(10) .
N5 Cu6 2.000(6) .
N6 Cu6 2.049(7) .
N7 Cu6 2.391(7) 2_655
N8 Cu6 2.014(6) 2_655
N9 Cu5 2.268(7) 2
N10 Cu5 2.024(6) 2
O1 Cu6 1.950(6) 4_466
O5 Eu1 2.587(5) .
O6 Eu1 2.575(5) .
O7 Eu3 2.708(5) .
O8 Eu3 2.408(5) .
O9 Eu1 2.362(5) .
O10 Eu3 2.336(5) 1_655
O13 Eu3 2.533(5) 1_655
O14 Eu3 2.565(5) 1_655
O15 Eu1 2.441(5) .
O16 Eu1 2.656(5) .
O17 Eu1 2.346(5) .
O18 Eu3 2.364(5) .
O21 Eu1 2.409(6) .
O21 H21A 0.8541 .
O21 H21B 0.8536 .
O22 Eu1 2.429(5) .
O22 H22A 0.8588 .
O22 H22B 0.8600 .
O23 Eu1 2.450(5) .
O23 H23A 0.8604 .
O23 H23B 0.8606 .
O24 Eu3 2.458(5) .
O24 H24A 0.8637 .
O24 H24B 0.8628 .
O25 Eu3 2.429(5) .
O25 H25A 0.8682 .
O25 H25B 0.8686 .
O26 Eu3 2.441(6) .
O26 H26A 0.8763 .
O26 H26B 0.8749 .
Cu5 N10 2.024(6) 2_545
Cu5 N9 2.268(7) 2_545
Cu6 O1 1.950(6) 4_665
Cu6 N8 2.014(6) 2_645
Cu6 N7 2.391(7) 2_645
Cu6 O35 2.559(7) .
Eu3 O10 2.336(5) 1_455
Eu3 O13 2.533(5) 1_455
Eu3 O14 2.565(5) 1_455
Eu3 C48 2.915(7) 1_455
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 0.150 0.852 0.371 7 1 ' '
2 0.150 0.648 0.871 7 1 ' '
3 0.499 0.648 0.076 34 6 ' '
4 0.501 0.148 0.424 34 6 ' '
5 0.499 0.852 0.576 34 6 ' '
6 0.501 0.352 0.924 34 6 ' '
7 0.850 0.352 0.129 7 1 ' '
8 0.850 0.148 0.629 7 1 ' '
