#------------------------------------------------------------------------------
#$Date: 2016-03-25 22:20:16 +0200 (Fri, 25 Mar 2016) $
#$Revision: 180008 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/02/7030213.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7030213
loop_
_publ_author_name
'Yang, Xiaoping'
'Chan, Christopher'
'Lam, Daniel'
'Schipper, Desmond'
'Stanley, Julie M.'
'Chen, Xiaoyan'
'Jones, Richard A.'
'Holliday, Bradley J.'
'Wong, Wai-Kwok'
'Chen, Shengchun'
'Chen, Qun'
_publ_section_title
;
 Anion-dependent construction of two hexanuclear 3d-4f complexes with a
 flexible Schiff base ligand.
;
_journal_issue                   37
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11449
_journal_page_last               11453
_journal_paper_doi               10.1039/c2dt31268a
_journal_volume                  41
_journal_year                    2012
_chemical_formula_sum            'C22 H20 Cl Cu Eu N6 O6'
_chemical_formula_weight         715.39
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                95.39(3)
_cell_angle_beta                 104.23(3)
_cell_angle_gamma                112.35(3)
_cell_formula_units_Z            3
_cell_length_a                   10.765(2)
_cell_length_b                   12.646(3)
_cell_length_c                   19.068(4)
_cell_measurement_temperature    293(2)
_cell_volume                     2275.7(11)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0568
_diffrn_reflns_av_sigmaI/netI    0.0715
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            19984
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.13
_exptl_absorpt_coefficient_mu    2.878
_exptl_crystal_density_diffrn    1.566
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1053
_refine_diff_density_max         1.923
_refine_diff_density_min         -1.384
_refine_diff_density_rms         0.294
_refine_ls_extinction_coef       0.0022(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.185
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     515
_refine_ls_number_reflns         7993
_refine_ls_number_restraints     342
_refine_ls_restrained_S_all      1.185
_refine_ls_R_factor_all          0.0846
_refine_ls_R_factor_gt           0.0586
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0854P)²+12.1517P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1693
_refine_ls_wR_factor_ref         0.2069
_reflns_number_gt                6039
_reflns_number_total             7993
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2dt31268a.txt
_cod_data_source_block           y
_cod_original_cell_volume        2275.9(8)
_cod_database_code               7030213
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.93555(6) 0.26082(5) 0.19410(3) 0.0376(2) Uani 1 1 d U
Eu2 Eu 0.96680(7) 0.38172(5) 0.40700(3) 0.0461(2) Uani 1 1 d U
Cu1 Cu 0.89283(14) 0.15601(11) 0.01114(7) 0.0367(3) Uani 1 1 d U
C23 C 1.1995(16) 0.1920(15) 0.3814(8) 0.074(4) Uani 1 1 d U
H23A H 1.1602 0.1120 0.3863 0.112 Uiso 1 1 calc R
H23B H 1.2108 0.2422 0.4257 0.112 Uiso 1 1 calc R
H23C H 1.2897 0.2108 0.3737 0.112 Uiso 1 1 calc R
O2 O 1.0503(8) 0.2408(7) 0.1012(4) 0.0420(18) Uani 1 1 d U
O3 O 0.7951(8) 0.1098(6) 0.0876(4) 0.0384(17) Uani 1 1 d U
N1 N 1.0228(9) 0.1328(7) -0.0417(5) 0.0348(19) Uani 1 1 d U
O6 O 0.8814(9) 0.3735(7) 0.1133(4) 0.049(2) Uani 1 1 d U
O5 O 0.8626(8) 0.3124(7) -0.0043(4) 0.0444(18) Uani 1 1 d U
N2 N 0.7129(9) 0.0552(8) -0.0704(5) 0.039(2) Uani 1 1 d U
O4 O 0.7878(8) 0.0315(6) 0.2075(4) 0.0401(17) Uani 1 1 d U
C14 C 0.6076(11) -0.0684(9) 0.0090(6) 0.033(2) Uani 1 1 d U
O9 O 0.7070(9) 0.2287(7) 0.2052(4) 0.050(2) Uani 1 1 d U
C18 C 0.6894(11) -0.0470(9) 0.1427(6) 0.040(3) Uani 1 1 d U
C19 C 0.7014(11) 0.0028(9) 0.0796(6) 0.034(2) Uani 1 1 d U
O11 O 0.9821(9) 0.4330(7) 0.2810(4) 0.052(2) Uani 1 1 d U
O1 O 1.1984(9) 0.4177(8) 0.2149(5) 0.060(2) Uani 1 1 d U
O8 O 1.0162(9) 0.2497(7) 0.3283(4) 0.051(2) Uani 1 1 d U
C7 C 1.1786(12) 0.3134(9) 0.1019(6) 0.039(2) Uani 1 1 d U
C22 C 0.8645(11) 0.3837(10) 0.0463(6) 0.041(3) Uani 1 1 d U
C5 C 1.3731(12) 0.3765(11) 0.0488(7) 0.047(3) Uani 1 1 d U
H5A H 1.4119 0.3654 0.0117 0.057 Uiso 1 1 calc R
O7 O 1.1065(9) 0.1818(8) 0.2531(4) 0.052(2) Uani 1 1 d U
C6 C 1.2332(11) 0.2954(9) 0.0437(6) 0.036(2) Uani 1 1 d U
C15 C 0.5056(12) -0.1786(10) 0.0064(6) 0.043(3) Uani 1 1 d U
H15A H 0.4402 -0.2235 -0.0387 0.052 Uiso 1 1 calc R
C8 C 1.1568(12) 0.2011(10) -0.0204(6) 0.039(2) Uani 1 1 d U
H8A H 1.2090 0.1876 -0.0496 0.047 Uiso 1 1 calc R
C2 C 1.2631(12) 0.4107(10) 0.1604(6) 0.040(3) Uani 1 1 d U
C13 C 0.6124(12) -0.0280(9) -0.0609(6) 0.036(2) Uani 1 1 d U
H13A H 0.5332 -0.0682 -0.1019 0.043 Uiso 1 1 calc R
O14 O 1.0626(13) 0.2863(11) 0.5027(6) 0.079(3) Uani 1 1 d U
O15 O 1.2235(10) 0.4879(10) 0.4335(5) 0.074(3) Uani 1 1 d U
C3 C 1.3941(12) 0.4860(10) 0.1619(6) 0.045(3) Uani 1 1 d U
H3A H 1.4469 0.5500 0.2011 0.054 Uiso 1 1 calc R
C17 C 0.5968(12) -0.1559(9) 0.1389(6) 0.042(3) Uani 1 1 d U
H17A H 0.5971 -0.1866 0.1813 0.050 Uiso 1 1 calc R
C16 C 0.5004(13) -0.2227(10) 0.0710(6) 0.046(3) Uani 1 1 d U
H16A H 0.4325 -0.2966 0.0684 0.056 Uiso 1 1 calc R
C26 C 0.6668(12) 0.2643(10) 0.2564(6) 0.042(3) Uani 1 1 d U
O12 O 0.9728(13) 0.5605(9) 0.3636(5) 0.082(3) Uani 1 1 d U
O10 O 0.7388(9) 0.3000(9) 0.3230(5) 0.063(2) Uani 1 1 d U
C24 C 1.1051(14) 0.2084(12) 0.3185(7) 0.052(3) Uani 1 1 d U
C4 C 1.4498(12) 0.4692(11) 0.1066(7) 0.049(3) Uani 1 1 d U
H4A H 1.5399 0.5211 0.1088 0.059 Uiso 1 1 calc R
C12 C 0.6912(14) 0.0841(13) -0.1430(7) 0.058(3) Uani 1 1 d U
H12A H 0.6340 0.1281 -0.1464 0.070 Uiso 1 1 calc R
H12B H 0.6368 0.0116 -0.1796 0.070 Uiso 1 1 calc R
C21 C 0.8413(14) 0.4880(11) 0.0291(7) 0.053(3) Uani 1 1 d U
H21A H 0.8293 0.4883 -0.0224 0.079 Uiso 1 1 calc R
H21B H 0.9213 0.5575 0.0584 0.079 Uiso 1 1 calc R
H21C H 0.7582 0.4857 0.0403 0.079 Uiso 1 1 calc R
C25 C 0.5223(15) 0.2595(14) 0.2366(8) 0.067(4) Uani 1 1 d U
H25A H 0.5063 0.2899 0.2799 0.101 Uiso 1 1 calc R
H25B H 0.4547 0.1799 0.2169 0.101 Uiso 1 1 calc R
H25C H 0.5125 0.3056 0.2001 0.101 Uiso 1 1 calc R
C1 C 1.293(2) 0.5007(18) 0.2835(10) 0.108(6) Uani 1 1 d U
H1A H 1.3813 0.5473 0.2761 0.162 Uiso 1 1 calc R
H1B H 1.3099 0.4588 0.3217 0.162 Uiso 1 1 calc R
H1C H 1.2515 0.5505 0.2980 0.162 Uiso 1 1 calc R
C9 C 0.9679(13) 0.0452(10) -0.1081(6) 0.043(3) Uani 1 1 d U
H9A H 0.8934 -0.0239 -0.1028 0.052 Uiso 1 1 calc R
H9B H 1.0422 0.0236 -0.1149 0.052 Uiso 1 1 calc R
C10 C 0.9094(14) 0.0858(11) -0.1770(6) 0.049(3) Uani 1 1 d U
H10A H 0.8509 0.0180 -0.2168 0.059 Uiso 1 1 calc R
H10B H 0.9875 0.1353 -0.1924 0.059 Uiso 1 1 calc R
C11 C 0.8219(13) 0.1536(11) -0.1644(7) 0.049(3) Uani 1 1 d U
H11A H 0.8817 0.2227 -0.1257 0.058 Uiso 1 1 calc R
H11B H 0.7925 0.1796 -0.2094 0.058 Uiso 1 1 calc R
C28 C 0.9681(18) 0.5238(13) 0.3000(8) 0.072(4) Uani 1 1 d U
C20 C 0.7730(17) -0.0060(13) 0.2761(7) 0.073(4) Uani 1 1 d U
H20A H 0.7186 -0.0891 0.2658 0.110 Uiso 1 1 calc R
H20B H 0.7261 0.0327 0.2979 0.110 Uiso 1 1 calc R
H20C H 0.8647 0.0135 0.3098 0.110 Uiso 1 1 calc R
C32 C 1.2420(16) 0.5603(14) 0.4900(8) 0.071(4) Uani 1 1 d U
C31 C 1.3847(18) 0.6442(17) 0.5351(10) 0.096(6) Uani 1 1 d U
H31A H 1.3894 0.7220 0.5397 0.144 Uiso 1 1 calc R
H31B H 1.4520 0.6389 0.5116 0.144 Uiso 1 1 calc R
H31C H 1.4057 0.6265 0.5833 0.144 Uiso 1 1 calc R
C27 C 0.947(3) 0.598(2) 0.2415(12) 0.130(8) Uani 1 1 d U
H27A H 1.0361 0.6428 0.2345 0.195 Uiso 1 1 calc R
H27B H 0.9096 0.6499 0.2584 0.195 Uiso 1 1 calc R
H27C H 0.8824 0.5472 0.1955 0.195 Uiso 1 1 calc R
O13 O 0.8383(12) 0.1974(10) 0.4443(6) 0.079(3) Uani 1 1 d U
C30 C 0.955(2) 0.2160(17) 0.4949(10) 0.086(5) Uani 1 1 d U
C29 C 0.928(3) 0.122(2) 0.5427(14) 0.148(9) Uani 1 1 d U
H29A H 1.0083 0.1046 0.5567 0.223 Uiso 1 1 calc R
H29B H 0.8462 0.0528 0.5147 0.223 Uiso 1 1 calc R
H29C H 0.9114 0.1516 0.5863 0.223 Uiso 1 1 calc R
O16 O 1.1385(9) 0.5522(8) 0.5125(5) 0.062(2) Uani 1 1 d U
O2W O 0.671(3) -0.310(2) 0.3540(15) 0.109(8) Uani 0.50 1 d PU
O1W O 0.558(3) 0.008(3) 0.4016(17) 0.131(10) Uani 0.50 1 d PU
O1W' O 0.383(4) -0.139(3) 0.3807(19) 0.149(12) Uani 0.50 1 d PU
O2W' O 0.602(2) -0.2769(15) 0.3037(10) 0.065(5) Uani 0.50 1 d PU
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O6 Eu1 O3 81.4(3) . .
O6 Eu1 O9 81.9(3) . .
O3 Eu1 O9 81.3(3) . .
O6 Eu1 O11 79.8(3) . .
O3 Eu1 O11 152.8(3) . .
O9 Eu1 O11 76.6(3) . .
O6 Eu1 O2 76.3(3) . .
O3 Eu1 O2 63.8(2) . .
O9 Eu1 O2 140.9(3) . .
O11 Eu1 O2 129.3(3) . .
O6 Eu1 O7 147.7(3) . .
O3 Eu1 O7 100.2(3) . .
O9 Eu1 O7 130.4(3) . .
O11 Eu1 O7 106.2(3) . .
O2 Eu1 O7 75.7(3) . .
O6 Eu1 O8 145.5(3) . .
O3 Eu1 O8 130.3(3) . .
O9 Eu1 O8 89.4(3) . .
O11 Eu1 O8 65.7(3) . .
O2 Eu1 O8 126.1(3) . .
O7 Eu1 O8 51.8(3) . .
O6 Eu1 O1 82.2(3) . .
O3 Eu1 O1 125.4(2) . .
O9 Eu1 O1 146.0(3) . .
O11 Eu1 O1 71.2(3) . .
O2 Eu1 O1 61.8(3) . .
O7 Eu1 O1 70.5(3) . .
O8 Eu1 O1 87.0(3) . .
O6 Eu1 O4 132.8(3) . .
O3 Eu1 O4 59.3(2) . .
O9 Eu1 O4 68.2(3) . .
O11 Eu1 O4 124.2(2) . .
O2 Eu1 O4 104.6(2) . .
O7 Eu1 O4 70.5(3) . .
O8 Eu1 O4 71.9(2) . .
O1 Eu1 O4 140.8(3) . .
O6 Eu1 C24 156.6(3) . .
O3 Eu1 C24 118.3(3) . .
O9 Eu1 C24 111.9(3) . .
O11 Eu1 C24 85.1(3) . .
O2 Eu1 C24 100.3(3) . .
O7 Eu1 C24 25.6(3) . .
O8 Eu1 C24 26.3(3) . .
O1 Eu1 C24 76.0(3) . .
O4 Eu1 C24 70.6(3) . .
O6 Eu1 Cu1 65.59(19) . .
O3 Eu1 Cu1 34.05(17) . .
O9 Eu1 Cu1 108.0(2) . .
O11 Eu1 Cu1 143.6(2) . .
O2 Eu1 Cu1 33.19(18) . .
O7 Eu1 Cu1 97.80(19) . .
O8 Eu1 Cu1 147.87(19) . .
O1 Eu1 Cu1 92.30(18) . .
O4 Eu1 Cu1 89.29(15) . .
C24 Eu1 Cu1 123.2(3) . .
O6 Eu1 Eu2 113.25(19) . .
O3 Eu1 Eu2 144.14(17) . .
O9 Eu1 Eu2 69.42(19) . .
O11 Eu1 Eu2 36.26(19) . .
O2 Eu1 Eu2 149.37(18) . .
O7 Eu1 Eu2 84.34(19) . .
O8 Eu1 Eu2 33.77(19) . .
O1 Eu1 Eu2 89.85(18) . .
O4 Eu1 Eu2 89.99(15) . .
C24 Eu1 Eu2 58.9(3) . .
Cu1 Eu1 Eu2 177.37(3) . .
O10 Eu2 O16 84.3(3) . 2_766
O10 Eu2 O8 86.2(3) . .
O16 Eu2 O8 160.1(3) 2_766 .
O10 Eu2 O15 150.1(3) . .
O16 Eu2 O15 117.1(3) 2_766 .
O8 Eu2 O15 78.7(3) . .
O10 Eu2 O12 82.5(4) . .
O16 Eu2 O12 80.3(3) 2_766 .
O8 Eu2 O12 115.7(3) . .
O15 Eu2 O12 81.1(4) . .
O10 Eu2 O13 74.6(4) . .
O16 Eu2 O13 78.8(4) 2_766 .
O8 Eu2 O13 81.8(3) . .
O15 Eu2 O13 127.5(4) . .
O12 Eu2 O13 150.3(4) . .
O10 Eu2 O14 125.7(4) . .
O16 Eu2 O14 90.7(4) 2_766 .
O8 Eu2 O14 80.7(3) . .
O15 Eu2 O14 77.3(4) . .
O12 Eu2 O14 149.6(4) . .
O13 Eu2 O14 51.5(4) . .
O10 Eu2 O16 143.7(3) . .
O16 Eu2 O16 65.2(3) 2_766 .
O8 Eu2 O16 128.7(3) . .
O15 Eu2 O16 51.8(3) . .
O12 Eu2 O16 73.5(3) . .
O13 Eu2 O16 115.5(3) . .
O14 Eu2 O16 76.4(4) . .
O10 Eu2 O11 71.4(3) . .
O16 Eu2 O11 127.6(3) 2_766 .
O8 Eu2 O11 64.8(3) . .
O15 Eu2 O11 78.8(3) . .
O12 Eu2 O11 51.6(3) . .
O13 Eu2 O11 133.1(3) . .
O14 Eu2 O11 141.1(3) . .
O16 Eu2 O11 111.1(3) . .
O10 Eu2 C30 102.4(5) . .
O16 Eu2 C30 83.2(5) 2_766 .
O8 Eu2 C30 81.9(4) . .
O15 Eu2 C30 100.8(5) . .
O12 Eu2 C30 162.2(4) . .
O13 Eu2 C30 27.9(5) . .
O14 Eu2 C30 23.8(4) . .
O16 Eu2 C30 93.6(5) . .
O11 Eu2 C30 146.2(4) . .
O10 Eu2 C28 73.4(4) . .
O16 Eu2 C28 103.2(4) 2_766 .
O8 Eu2 C28 90.7(4) . .
O15 Eu2 C28 81.1(4) . .
O12 Eu2 C28 25.8(4) . .
O13 Eu2 C28 147.5(4) . .
O14 Eu2 C28 158.0(5) . .
O16 Eu2 C28 93.9(4) . .
O11 Eu2 C28 26.0(3) . .
C30 Eu2 C28 171.7(5) . .
O10 Eu2 C32 157.8(4) . .
O16 Eu2 C32 91.1(4) 2_766 .
O8 Eu2 C32 104.0(4) . .
O15 Eu2 C32 26.0(3) . .
O12 Eu2 C32 75.3(5) . .
O13 Eu2 C32 125.9(4) . .
O14 Eu2 C32 75.9(5) . .
O16 Eu2 C32 25.9(3) . .
O11 Eu2 C32 94.8(4) . .
C30 Eu2 C32 98.6(6) . .
C28 Eu2 C32 86.7(5) . .
O2 Cu1 N1 91.1(3) . .
O2 Cu1 O3 79.9(3) . .
N1 Cu1 O3 146.6(3) . .
O2 Cu1 N2 170.4(3) . .
N1 Cu1 N2 95.9(4) . .
O3 Cu1 N2 90.6(3) . .
O2 Cu1 O5 91.5(3) . .
N1 Cu1 O5 112.1(3) . .
O3 Cu1 O5 100.3(3) . .
N2 Cu1 O5 91.9(3) . .
O2 Cu1 Eu1 43.2(2) . .
N1 Cu1 Eu1 133.5(3) . .
O3 Cu1 Eu1 41.5(2) . .
N2 Cu1 Eu1 128.6(3) . .
O5 Cu1 Eu1 82.6(2) . .
C7 O2 Cu1 124.0(7) . .
C7 O2 Eu1 125.8(6) . .
Cu1 O2 Eu1 103.7(3) . .
C19 O3 Cu1 121.2(6) . .
C19 O3 Eu1 131.6(6) . .
Cu1 O3 Eu1 104.5(3) . .
C8 N1 C9 117.9(9) . .
C8 N1 Cu1 121.6(7) . .
C9 N1 Cu1 120.3(7) . .
C22 O6 Eu1 142.2(7) . .
C22 O5 Cu1 124.2(7) . .
C13 N2 C12 117.0(10) . .
C13 N2 Cu1 123.5(8) . .
C12 N2 Cu1 119.4(8) . .
C18 O4 C20 115.2(9) . .
C18 O4 Eu1 116.5(6) . .
C20 O4 Eu1 125.9(7) . .
C15 C14 C19 118.8(10) . .
C15 C14 C13 118.8(10) . .
C19 C14 C13 122.4(9) . .
C26 O9 Eu1 133.0(8) . .
C17 C18 O4 125.7(10) . .
C17 C18 C19 123.3(10) . .
O4 C18 C19 111.0(9) . .
O3 C19 C18 119.9(9) . .
O3 C19 C14 123.0(9) . .
C18 C19 C14 117.2(9) . .
C28 O11 Eu1 153.6(10) . .
C28 O11 Eu2 89.1(8) . .
Eu1 O11 Eu2 110.0(3) . .
C2 O1 C1 114.1(10) . .
C2 O1 Eu1 118.9(7) . .
C1 O1 Eu1 126.2(8) . .
C24 O8 Eu2 147.3(8) . .
C24 O8 Eu1 93.7(7) . .
Eu2 O8 Eu1 110.9(3) . .
O2 C7 C2 120.7(10) . .
O2 C7 C6 121.0(10) . .
C2 C7 C6 118.2(10) . .
O5 C22 O6 125.1(11) . .
O5 C22 C21 119.6(10) . .
O6 C22 C21 115.3(10) . .
C4 C5 C6 121.4(11) . .
C24 O7 Eu1 95.8(8) . .
C7 C6 C5 117.8(10) . .
C7 C6 C8 124.0(10) . .
C5 C6 C8 118.2(10) . .
C14 C15 C16 120.9(10) . .
N1 C8 C6 127.1(10) . .
C3 C2 O1 125.8(10) . .
C3 C2 C7 121.5(10) . .
O1 C2 C7 112.7(9) . .
N2 C13 C14 126.4(10) . .
C30 O14 Eu2 92.3(12) . .
C32 O15 Eu2 96.0(8) . .
C2 C3 C4 121.2(11) . .
C18 C17 C16 119.6(11) . .
C17 C16 C15 120.0(11) . .
O10 C26 O9 124.7(11) . .
O10 C26 C25 117.2(11) . .
O9 C26 C25 118.0(11) . .
C28 O12 Eu2 94.4(9) . .
C26 O10 Eu2 145.6(8) . .
O7 C24 O8 118.3(11) . .
O7 C24 C23 121.3(12) . .
O8 C24 C23 120.4(11) . .
O7 C24 Eu1 58.6(6) . .
O8 C24 Eu1 60.0(6) . .
C23 C24 Eu1 175.1(10) . .
C5 C4 C3 119.8(11) . .
N2 C12 C11 117.6(11) . .
N1 C9 C10 112.9(9) . .
C9 C10 C11 113.3(9) . .
C12 C11 C10 114.6(11) . .
O12 C28 O11 123.9(14) . .
O12 C28 C27 117.3(15) . .
O11 C28 C27 118.7(14) . .
O12 C28 Eu2 59.8(8) . .
O11 C28 Eu2 64.9(7) . .
C27 C28 Eu2 171.8(14) . .
O16 C32 O15 119.6(13) . .
O16 C32 C31 119.2(13) . .
O15 C32 C31 120.8(14) . .
O16 C32 Eu2 61.5(7) . .
O15 C32 Eu2 58.1(7) . .
C31 C32 Eu2 175.5(14) . .
C30 O13 Eu2 89.0(11) . .
O14 C30 O13 126.7(18) . .
O14 C30 C29 123(2) . .
O13 C30 C29 110.3(19) . .
O14 C30 Eu2 63.9(11) . .
O13 C30 Eu2 63.2(9) . .
C29 C30 Eu2 172.2(16) . .
C32 O16 Eu2 152.5(9) . 2_766
C32 O16 Eu2 92.6(8) . .
Eu2 O16 Eu2 114.8(3) 2_766 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O6 2.313(8) .
Eu1 O3 2.372(7) .
Eu1 O9 2.403(8) .
Eu1 O11 2.414(8) .
Eu1 O2 2.440(7) .
Eu1 O7 2.498(8) .
Eu1 O8 2.529(8) .
Eu1 O1 2.671(9) .
Eu1 O4 2.799(7) .
Eu1 C24 2.913(13) .
Eu1 Cu1 3.4669(17) .
Eu1 Eu2 4.0870(13) .
Eu2 O10 2.342(9) .
Eu2 O16 2.382(8) 2_766
Eu2 O8 2.432(8) .
Eu2 O15 2.462(10) .
Eu2 O12 2.463(11) .
Eu2 O13 2.489(11) .
Eu2 O14 2.506(11) .
Eu2 O16 2.538(9) .
Eu2 O11 2.573(8) .
Eu2 C30 2.789(19) .
Eu2 C28 2.842(15) .
Eu2 C32 2.884(15) .
Cu1 O2 1.953(8) .
Cu1 N1 2.003(9) .
Cu1 O3 2.005(7) .
Cu1 N2 2.016(9) .
Cu1 O5 2.158(8) .
C23 C24 1.457(18) .
O2 C7 1.333(13) .
O3 C19 1.311(12) .
N1 C8 1.300(14) .
N1 C9 1.431(13) .
O6 C22 1.271(13) .
O5 C22 1.248(13) .
N2 C13 1.256(13) .
N2 C12 1.451(15) .
O4 C18 1.401(12) .
O4 C20 1.457(14) .
C14 C15 1.395(15) .
C14 C19 1.433(14) .
C14 C13 1.476(15) .
O9 C26 1.273(13) .
C18 C17 1.340(15) .
C18 C19 1.422(15) .
O11 C28 1.245(17) .
O1 C2 1.399(13) .
O1 C1 1.459(19) .
O8 C24 1.293(15) .
C7 C2 1.407(15) .
C7 C6 1.416(15) .
C22 C21 1.484(16) .
C5 C4 1.358(17) .
C5 C6 1.436(15) .
O7 C24 1.266(14) .
C6 C8 1.442(15) .
C15 C16 1.404(16) .
C2 C3 1.360(15) .
O14 C30 1.12(2) .
O15 C32 1.269(16) .
C3 C4 1.371(16) .
C17 C16 1.390(16) .
C26 O10 1.249(14) .
C26 C25 1.484(17) .
O12 C28 1.240(16) .
C12 C11 1.526(17) .
C9 C10 1.533(16) .
C10 C11 1.539(16) .
C28 C27 1.55(3) .
C32 O16 1.261(16) .
C32 C31 1.47(2) .
O13 C30 1.30(2) .
C30 C29 1.55(3) .
O16 Eu2 2.382(8) 2_766
O2W O2W' 1.27(3) .
