#------------------------------------------------------------------------------
#$Date: 2016-03-25 22:23:42 +0200 (Fri, 25 Mar 2016) $
#$Revision: 180010 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/04/7030408.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7030408
loop_
_publ_author_name
'Furukawa, Shunsuke'
'Kobayashi, Junji'
'Kawashima, Takayuki'
_publ_section_title
;
 Application of the sila-Friedel-Crafts reaction to the synthesis of
 π-extended silole derivatives and their properties.
;
_journal_issue                   39
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9329
_journal_page_last               9336
_journal_paper_doi               10.1039/c0dt00136h
_journal_volume                  39
_journal_year                    2010
_chemical_formula_sum            'C40 H48 Si'
_chemical_formula_weight         556.87
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_Int_Tables_number      15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.0000(11)
_cell_angle_beta                 107.1954(14)
_cell_angle_gamma                90.0000(11)
_cell_formula_units_Z            12
_cell_length_a                   24.689(8)
_cell_length_b                   15.373(5)
_cell_length_c                   29.430(10)
_cell_measurement_reflns_used    9294
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      27.4835
_cell_measurement_theta_min      3.0402
_cell_volume                     10671(6)
_computing_cell_refinement       'CrystalClear (Rigaku Corp., 2000)'
_computing_data_collection       'CrystalClear (Rigaku Corp., 2000)'
_computing_data_reduction        'CrystalClear (Rigaku Corp., 2000)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      120(2)
_diffrn_detector_area_resol_mean 14.5666
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device
;
Mercury CCD (2x2 bin mode)
;
_diffrn_measurement_method       dtprofit.ref
_diffrn_radiation_detector       CCD
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.0354
_diffrn_reflns_av_sigmaI/netI    0.0446
_diffrn_reflns_limit_h_max       25
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_number            33325
_diffrn_reflns_theta_full        24.99
_diffrn_reflns_theta_max         24.99
_diffrn_reflns_theta_min         3.02
_diffrn_source                   'fine-focus sealed tube'
_diffrn_source_current           40.0000
_diffrn_source_power             2.0000
_diffrn_source_voltage           50.0000
_exptl_absorpt_coefficient_mu    0.090
_exptl_absorpt_correction_T_max  0.9735
_exptl_absorpt_correction_T_min  0.9735
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
Jacobson, R. (1998), Rigaku, Private communication
;
_exptl_crystal_density_diffrn    1.040
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3624
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.30
_platon_squeeze_details
;
;
_refine_diff_density_max         3.844
_refine_diff_density_min         -1.146
_refine_diff_density_rms         0.115
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.058
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     598
_refine_ls_number_reflns         9294
_refine_ls_number_restraints     12
_refine_ls_restrained_S_all      1.073
_refine_ls_R_factor_all          0.1117
_refine_ls_R_factor_gt           0.1011
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1914P)²+46.5284P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2964
_refine_ls_wR_factor_ref         0.3082
_reflns_number_gt                7822
_reflns_number_total             9294
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c0dt00136h.txt
_cod_data_source_block           spiro2
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7030408
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Si1 Si 0.26756(4) 0.44062(6) 0.13180(3) 0.0204(3) Uani 1 1 d . . .
Si2 Si 0.0000 0.54806(9) 0.2500 0.0207(3) Uani 1 2 d S . .
C1 C 0.19025(16) 0.4648(2) 0.10721(12) 0.0221(8) Uani 1 1 d . . .
C2 C 0.14342(16) 0.4272(2) 0.11658(12) 0.0225(8) Uani 1 1 d . . .
H1 H 0.1492 0.3843 0.1407 0.027 Uiso 1 1 calc R . .
C3 C 0.08852(16) 0.4509(2) 0.09152(13) 0.0227(8) Uani 1 1 d . . .
C4 C 0.08189(17) 0.5166(3) 0.05719(14) 0.0287(8) Uani 1 1 d . . .
H2 H 0.0447 0.5347 0.0400 0.034 Uiso 1 1 calc R . .
C5 C 0.12786(17) 0.5558(2) 0.04754(14) 0.0269(8) Uani 1 1 d . . .
H3 H 0.1219 0.6004 0.0243 0.032 Uiso 1 1 calc R . .
C6 C 0.18259(15) 0.5299(2) 0.07182(12) 0.0209(7) Uani 1 1 d . . .
C7 C 0.23537(16) 0.5592(2) 0.06205(12) 0.0216(8) Uani 1 1 d . . .
C8 C 0.23844(17) 0.6183(2) 0.02743(14) 0.0261(8) Uani 1 1 d . . .
H4 H 0.2054 0.6488 0.0100 0.031 Uiso 1 1 calc R . .
C9 C 0.28966(17) 0.6333(2) 0.01807(13) 0.0263(8) Uani 1 1 d . . .
H5 H 0.2908 0.6736 -0.0061 0.032 Uiso 1 1 calc R . .
C10 C 0.33939(16) 0.5908(2) 0.04308(13) 0.0244(8) Uani 1 1 d . . .
C11 C 0.33619(16) 0.5341(2) 0.07929(13) 0.0228(8) Uani 1 1 d . . .
H6 H 0.3697 0.5057 0.0976 0.027 Uiso 1 1 calc R . .
C12 C 0.28587(15) 0.5180(2) 0.08938(12) 0.0217(8) Uani 1 1 d . . .
C13 C 0.29895(15) 0.4503(2) 0.19760(13) 0.0235(8) Uani 1 1 d . . .
C14 C 0.30078(16) 0.5191(3) 0.22864(13) 0.0272(8) Uani 1 1 d . . .
H7 H 0.2867 0.5744 0.2161 0.033 Uiso 1 1 calc R . .
C15 C 0.32302(18) 0.5089(3) 0.27827(14) 0.0327(9) Uani 1 1 d . . .
C16 C 0.34280(19) 0.4267(3) 0.29453(14) 0.0366(10) Uani 1 1 d . . .
H8 H 0.3573 0.4177 0.3279 0.044 Uiso 1 1 calc R . .
C17 C 0.34244(19) 0.3572(3) 0.26450(14) 0.0344(9) Uani 1 1 d . . .
H9 H 0.3567 0.3022 0.2773 0.041 Uiso 1 1 calc R . .
C18 C 0.32096(16) 0.3685(2) 0.21543(13) 0.0255(8) Uani 1 1 d . . .
C19 C 0.31845(15) 0.3005(2) 0.17910(13) 0.0233(8) Uani 1 1 d . . .
C20 C 0.34087(17) 0.2171(2) 0.18794(14) 0.0280(8) Uani 1 1 d . . .
H10 H 0.3593 0.1993 0.2197 0.034 Uiso 1 1 calc R . .
C21 C 0.33642(17) 0.1594(2) 0.15049(14) 0.0284(8) Uani 1 1 d . . .
H11 H 0.3520 0.1027 0.1572 0.034 Uiso 1 1 calc R . .
C22 C 0.30971(16) 0.1826(2) 0.10342(13) 0.0268(8) Uani 1 1 d . . .
C23 C 0.28680(15) 0.2667(2) 0.09509(13) 0.0236(8) Uani 1 1 d . . .
H12 H 0.2680 0.2842 0.0634 0.028 Uiso 1 1 calc R . .
C24 C 0.29080(15) 0.3251(2) 0.13195(13) 0.0216(7) Uani 1 1 d . . .
C25 C 0.03640(16) 0.4041(2) 0.09798(13) 0.0254(8) Uani 1 1 d . . .
C26 C 0.04892(18) 0.3565(3) 0.14518(14) 0.0322(9) Uani 1 1 d . . .
H13 H 0.0139 0.3309 0.1483 0.048 Uiso 1 1 calc R . .
H14 H 0.0643 0.3976 0.1713 0.048 Uiso 1 1 calc R . .
H15 H 0.0767 0.3103 0.1464 0.048 Uiso 1 1 calc R . .
C27 C 0.0170(2) 0.3370(3) 0.05779(15) 0.0391(10) Uani 1 1 d . . .
H16 H 0.0480 0.2963 0.0592 0.059 Uiso 1 1 calc R . .
H17 H 0.0064 0.3669 0.0270 0.059 Uiso 1 1 calc R . .
H18 H -0.0157 0.3048 0.0614 0.059 Uiso 1 1 calc R . .
C28 C -0.01234(18) 0.4690(3) 0.09431(16) 0.0341(9) Uani 1 1 d . . .
H19 H -0.0446 0.4384 0.1000 0.051 Uiso 1 1 calc R . .
H20 H -0.0240 0.4950 0.0625 0.051 Uiso 1 1 calc R . .
H21 H 0.0006 0.5149 0.1182 0.051 Uiso 1 1 calc R . .
C29 C 0.39482(17) 0.6009(3) 0.02993(14) 0.0292(9) Uani 1 1 d . . .
C30 C 0.4022(2) 0.5203(3) 0.00120(18) 0.0451(12) Uani 1 1 d . . .
H22 H 0.3703 0.5166 -0.0280 0.068 Uiso 1 1 calc R . .
H23 H 0.4031 0.4678 0.0203 0.068 Uiso 1 1 calc R . .
H24 H 0.4377 0.5252 -0.0070 0.068 Uiso 1 1 calc R . .
C31 C 0.44564(18) 0.6077(3) 0.07435(16) 0.0375(10) Uani 1 1 d . . .
H25 H 0.4398 0.6560 0.0941 0.056 Uiso 1 1 calc R . .
H26 H 0.4801 0.6181 0.0650 0.056 Uiso 1 1 calc R . .
H27 H 0.4497 0.5533 0.0924 0.056 Uiso 1 1 calc R . .
C32 C 0.39386(19) 0.6822(3) -0.00065(17) 0.0409(11) Uani 1 1 d . . .
H28 H 0.3641 0.6760 -0.0311 0.061 Uiso 1 1 calc R . .
H29 H 0.4307 0.6889 -0.0065 0.061 Uiso 1 1 calc R . .
H30 H 0.3861 0.7337 0.0161 0.061 Uiso 1 1 calc R . .
C33 C 0.3283(2) 0.5841(3) 0.31344(15) 0.0395(10) Uani 1 1 d . . .
C34 C 0.2985(3) 0.6673(4) 0.29022(19) 0.0589(15) Uani 1 1 d . . .
H31 H 0.2994 0.7106 0.3149 0.088 Uiso 1 1 calc R . .
H32 H 0.2590 0.6541 0.2727 0.088 Uiso 1 1 calc R . .
H33 H 0.3179 0.6906 0.2683 0.088 Uiso 1 1 calc R . .
C35 C 0.3002(3) 0.5583(4) 0.35184(18) 0.0577(14) Uani 1 1 d . . .
H34 H 0.3202 0.5084 0.3699 0.087 Uiso 1 1 calc R . .
H35 H 0.2604 0.5428 0.3366 0.087 Uiso 1 1 calc R . .
H36 H 0.3020 0.6075 0.3735 0.087 Uiso 1 1 calc R . .
C36 C 0.3907(3) 0.6048(4) 0.3359(2) 0.0693(17) Uani 1 1 d . . .
H37 H 0.4100 0.5539 0.3534 0.104 Uiso 1 1 calc R . .
H38 H 0.3944 0.6539 0.3579 0.104 Uiso 1 1 calc R . .
H39 H 0.4079 0.6201 0.3109 0.104 Uiso 1 1 calc R . .
C37 C 0.3051(2) 0.1212(3) 0.06159(14) 0.0363(10) Uani 1 1 d . . .
C38 C 0.3266(2) 0.1658(4) 0.02341(18) 0.0527(14) Uani 1 1 d . . .
H40 H 0.3044 0.2186 0.0124 0.079 Uiso 1 1 calc R . .
H41 H 0.3223 0.1260 -0.0034 0.079 Uiso 1 1 calc R . .
H42 H 0.3666 0.1811 0.0370 0.079 Uiso 1 1 calc R . .
C39 C 0.2439(2) 0.0958(4) 0.03862(19) 0.0543(14) Uani 1 1 d . . .
H43 H 0.2292 0.0663 0.0621 0.082 Uiso 1 1 calc R . .
H44 H 0.2415 0.0565 0.0119 0.082 Uiso 1 1 calc R . .
H45 H 0.2213 0.1481 0.0271 0.082 Uiso 1 1 calc R . .
C40 C 0.3427(4) 0.0417(5) 0.0768(2) 0.102(3) Uani 1 1 d . . .
H46 H 0.3794 0.0594 0.0984 0.153 Uiso 1 1 calc R . .
H47 H 0.3485 0.0137 0.0487 0.153 Uiso 1 1 calc R . .
H48 H 0.3245 0.0005 0.0931 0.153 Uiso 1 1 calc R . .
C41 C 0.02441(15) 0.6120(2) 0.20555(12) 0.0224(8) Uani 1 1 d . . .
C42 C -0.00240(16) 0.6770(2) 0.17375(12) 0.0234(8) Uani 1 1 d . . .
H49 H -0.0393 0.6955 0.1731 0.028 Uiso 1 1 calc R . .
C43 C 0.02405(16) 0.7159(2) 0.14266(13) 0.0252(8) Uani 1 1 d . . .
C44 C 0.07876(17) 0.6871(2) 0.14506(13) 0.0266(8) Uani 1 1 d . . .
H50 H 0.0975 0.7122 0.1243 0.032 Uiso 1 1 calc R . .
C45 C 0.10618(16) 0.6234(2) 0.17667(13) 0.0257(8) Uani 1 1 d . . .
H51 H 0.1433 0.6055 0.1775 0.031 Uiso 1 1 calc R . .
C46 C 0.07957(16) 0.5851(2) 0.20744(12) 0.0224(8) Uani 1 1 d . . .
C47 C 0.10408(16) 0.5160(2) 0.24243(13) 0.0245(8) Uani 1 1 d . . .
C48 C 0.15733(17) 0.4789(3) 0.24985(14) 0.0291(8) Uani 1 1 d . . .
H52 H 0.1815 0.4990 0.2322 0.035 Uiso 1 1 calc R . .
C49 C 0.17532(18) 0.4131(3) 0.28272(14) 0.0339(9) Uani 1 1 d . . .
H53 H 0.2118 0.3885 0.2871 0.041 Uiso 1 1 calc R . .
C50 C 0.14162(19) 0.3811(3) 0.30981(15) 0.0372(10) Uani 1 1 d . A .
C51 C 0.08802(17) 0.4199(3) 0.30218(14) 0.0307(9) Uani 1 1 d . . .
H54 H 0.0642 0.4002 0.3202 0.037 Uiso 1 1 calc R . .
C52 C 0.06881(16) 0.4858(2) 0.26924(13) 0.0237(8) Uani 1 1 d . . .
C53 C -0.00529(17) 0.7830(3) 0.10531(13) 0.0280(8) Uani 1 1 d . . .
C54 C -0.06239(18) 0.8130(3) 0.11099(15) 0.0344(9) Uani 1 1 d . . .
H55 H -0.0873 0.7625 0.1089 0.052 Uiso 1 1 calc R . .
H56 H -0.0803 0.8544 0.0857 0.052 Uiso 1 1 calc R . .
H57 H -0.0560 0.8412 0.1420 0.052 Uiso 1 1 calc R . .
C55 C 0.0323(2) 0.8646(3) 0.10950(16) 0.0375(10) Uani 1 1 d . . .
H58 H 0.0119 0.9089 0.0870 0.056 Uiso 1 1 calc R . .
H59 H 0.0674 0.8490 0.1022 0.056 Uiso 1 1 calc R . .
H60 H 0.0417 0.8876 0.1419 0.056 Uiso 1 1 calc R . .
C56 C -0.01494(18) 0.7421(3) 0.05642(14) 0.0336(9) Uani 1 1 d . . .
H61 H -0.0383 0.6897 0.0539 0.050 Uiso 1 1 calc R . .
H62 H 0.0217 0.7263 0.0520 0.050 Uiso 1 1 calc R . .
H63 H -0.0344 0.7838 0.0318 0.050 Uiso 1 1 calc R . .
C57 C 0.1634(2) 0.3094(4) 0.34523(17) 0.0623(17) Uani 1 1 d D . .
C68 C 0.1296(5) 0.2995(9) 0.3805(3) 0.020(3) Uani 0.468(11) 1 d PD A 1
H64 H 0.1236 0.3569 0.3927 0.030 Uiso 0.468(11) 1 calc PR A 1
H65 H 0.1506 0.2625 0.4070 0.030 Uiso 0.468(11) 1 calc PR A 1
H66 H 0.0929 0.2727 0.3646 0.030 Uiso 0.468(11) 1 calc PR A 1
C69 C 0.2222(3) 0.3372(7) 0.3783(3) 0.053(3) Uani 0.468(11) 1 d PD A 1
H67 H 0.2183 0.3913 0.3947 0.079 Uiso 0.468(11) 1 calc PR A 1
H68 H 0.2482 0.3466 0.3592 0.079 Uiso 0.468(11) 1 calc PR A 1
H69 H 0.2372 0.2914 0.4018 0.079 Uiso 0.468(11) 1 calc PR A 1
C70 C 0.1246(5) 0.2334(6) 0.3207(4) 0.118(8) Uani 0.532(11) 1 d PD A 2
H70 H 0.0848 0.2497 0.3156 0.176 Uiso 0.532(11) 1 calc PR A 2
H71 H 0.1334 0.1816 0.3409 0.176 Uiso 0.532(11) 1 calc PR A 2
H72 H 0.1308 0.2210 0.2899 0.176 Uiso 0.532(11) 1 calc PR A 2
C71 C 0.1731(6) 0.2259(5) 0.3218(4) 0.055(4) Uani 0.468(11) 1 d PD A 1
H73 H 0.1955 0.2380 0.3001 0.083 Uiso 0.468(11) 1 calc PR A 1
H74 H 0.1364 0.2010 0.3039 0.083 Uiso 0.468(11) 1 calc PR A 1
H75 H 0.1935 0.1846 0.3462 0.083 Uiso 0.468(11) 1 calc PR A 1
C72 C 0.2200(3) 0.2678(7) 0.3479(4) 0.057(3) Uani 0.532(11) 1 d PD A 2
H76 H 0.2282 0.2215 0.3718 0.085 Uiso 0.532(11) 1 calc PR A 2
H77 H 0.2500 0.3119 0.3567 0.085 Uiso 0.532(11) 1 calc PR A 2
H78 H 0.2185 0.2432 0.3168 0.085 Uiso 0.532(11) 1 calc PR A 2
C73 C 0.1477(6) 0.3130(12) 0.3914(3) 0.052(4) Uani 0.532(11) 1 d PD A 2
H79 H 0.1103 0.3398 0.3856 0.078 Uiso 0.532(11) 1 calc PR A 2
H80 H 0.1760 0.3476 0.4149 0.078 Uiso 0.532(11) 1 calc PR A 2
H81 H 0.1469 0.2538 0.4037 0.078 Uiso 0.532(11) 1 calc PR A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C24 Si1 C13 92.31(16) . .
C24 Si1 C1 117.96(16) . .
C13 Si1 C1 116.70(16) . .
C24 Si1 C12 118.13(16) . .
C13 Si1 C12 122.16(16) . .
C1 Si1 C12 92.04(16) . .
C41 Si2 C41 116.7(2) 2 .
C41 Si2 C52 91.64(16) 2 2
C41 Si2 C52 120.28(15) . 2
C41 Si2 C52 120.27(15) 2 .
C41 Si2 C52 91.64(16) . .
C52 Si2 C52 119.0(2) 2 .
C2 C1 C6 120.1(3) . .
C2 C1 Si1 130.9(3) . .
C6 C1 Si1 109.0(3) . .
C3 C2 C1 121.7(3) . .
C3 C2 H1 119.2 . .
C1 C2 H1 119.2 . .
C2 C3 C4 117.3(3) . .
C2 C3 C25 122.3(3) . .
C4 C3 C25 120.2(3) . .
C5 C4 C3 122.1(4) . .
C5 C4 H2 118.9 . .
C3 C4 H2 118.9 . .
C4 C5 C6 120.1(3) . .
C4 C5 H3 120.0 . .
C6 C5 H3 120.0 . .
C5 C6 C1 118.7(3) . .
C5 C6 C7 126.1(3) . .
C1 C6 C7 115.0(3) . .
C8 C7 C12 118.7(3) . .
C8 C7 C6 125.7(3) . .
C12 C7 C6 115.5(3) . .
C7 C8 C9 120.4(4) . .
C7 C8 H4 119.8 . .
C9 C8 H4 119.8 . .
C8 C9 C10 121.9(3) . .
C8 C9 H5 119.0 . .
C10 C9 H5 119.0 . .
C9 C10 C11 117.1(3) . .
C9 C10 C29 122.0(3) . .
C11 C10 C29 120.7(3) . .
C12 C11 C10 122.2(3) . .
C12 C11 H6 118.9 . .
C10 C11 H6 118.9 . .
C11 C12 C7 119.6(3) . .
C11 C12 Si1 131.7(3) . .
C7 C12 Si1 108.4(3) . .
C14 C13 C18 120.1(3) . .
C14 C13 Si1 131.7(3) . .
C18 C13 Si1 108.1(3) . .
C13 C14 C15 121.6(4) . .
C13 C14 H7 119.2 . .
C15 C14 H7 119.2 . .
C16 C15 C14 116.7(4) . .
C16 C15 C33 120.2(4) . .
C14 C15 C33 123.0(4) . .
C17 C16 C15 123.2(4) . .
C17 C16 H8 118.4 . .
C15 C16 H8 118.4 . .
C16 C17 C18 119.6(4) . .
C16 C17 H9 120.2 . .
C18 C17 H9 120.2 . .
C17 C18 C13 118.9(4) . .
C17 C18 C19 125.5(3) . .
C13 C18 C19 115.6(3) . .
C20 C19 C24 118.9(3) . .
C20 C19 C18 125.8(3) . .
C24 C19 C18 115.2(3) . .
C19 C20 C21 120.3(3) . .
C19 C20 H10 119.8 . .
C21 C20 H10 119.8 . .
C22 C21 C20 121.8(3) . .
C22 C21 H11 119.1 . .
C20 C21 H11 119.1 . .
C21 C22 C23 117.2(3) . .
C21 C22 C37 122.9(3) . .
C23 C22 C37 119.9(3) . .
C24 C23 C22 121.8(3) . .
C24 C23 H12 119.1 . .
C22 C23 H12 119.1 . .
C23 C24 C19 119.9(3) . .
C23 C24 Si1 131.5(3) . .
C19 C24 Si1 108.5(3) . .
C26 C25 C3 112.8(3) . .
C26 C25 C27 108.3(3) . .
C3 C25 C27 107.6(3) . .
C26 C25 C28 108.6(3) . .
C3 C25 C28 110.7(3) . .
C27 C25 C28 108.8(3) . .
C25 C26 H13 109.5 . .
C25 C26 H14 109.5 . .
H13 C26 H14 109.5 . .
C25 C26 H15 109.5 . .
H13 C26 H15 109.5 . .
H14 C26 H15 109.5 . .
C25 C27 H16 109.5 . .
C25 C27 H17 109.5 . .
H16 C27 H17 109.5 . .
C25 C27 H18 109.5 . .
H16 C27 H18 109.5 . .
H17 C27 H18 109.5 . .
C25 C28 H19 109.5 . .
C25 C28 H20 109.5 . .
H19 C28 H20 109.5 . .
C25 C28 H21 109.5 . .
H19 C28 H21 109.5 . .
H20 C28 H21 109.5 . .
C31 C29 C10 111.1(3) . .
C31 C29 C32 108.2(3) . .
C10 C29 C32 111.7(3) . .
C31 C29 C30 109.0(4) . .
C10 C29 C30 108.3(3) . .
C32 C29 C30 108.5(4) . .
C29 C30 H22 109.5 . .
C29 C30 H23 109.5 . .
H22 C30 H23 109.5 . .
C29 C30 H24 109.5 . .
H22 C30 H24 109.5 . .
H23 C30 H24 109.5 . .
C29 C31 H25 109.5 . .
C29 C31 H26 109.5 . .
H25 C31 H26 109.5 . .
C29 C31 H27 109.5 . .
H25 C31 H27 109.5 . .
H26 C31 H27 109.5 . .
C29 C32 H28 109.5 . .
C29 C32 H29 109.5 . .
H28 C32 H29 109.5 . .
C29 C32 H30 109.5 . .
H28 C32 H30 109.5 . .
H29 C32 H30 109.5 . .
C36 C33 C15 108.9(4) . .
C36 C33 C34 108.1(5) . .
C15 C33 C34 113.3(4) . .
C36 C33 C35 110.7(5) . .
C15 C33 C35 109.5(4) . .
C34 C33 C35 106.3(4) . .
C33 C34 H31 109.5 . .
C33 C34 H32 109.5 . .
H31 C34 H32 109.5 . .
C33 C34 H33 109.5 . .
H31 C34 H33 109.5 . .
H32 C34 H33 109.5 . .
C33 C35 H34 109.5 . .
C33 C35 H35 109.5 . .
H34 C35 H35 109.5 . .
C33 C35 H36 109.5 . .
H34 C35 H36 109.5 . .
H35 C35 H36 109.5 . .
C33 C36 H37 109.5 . .
C33 C36 H38 109.5 . .
H37 C36 H38 109.5 . .
C33 C36 H39 109.5 . .
H37 C36 H39 109.5 . .
H38 C36 H39 109.5 . .
C39 C37 C40 111.5(5) . .
C39 C37 C22 110.2(4) . .
C40 C37 C22 111.5(4) . .
C39 C37 C38 107.6(4) . .
C40 C37 C38 105.2(5) . .
C22 C37 C38 110.7(4) . .
C37 C38 H40 109.5 . .
C37 C38 H41 109.5 . .
H40 C38 H41 109.5 . .
C37 C38 H42 109.5 . .
H40 C38 H42 109.5 . .
H41 C38 H42 109.5 . .
C37 C39 H43 109.5 . .
C37 C39 H44 109.5 . .
H43 C39 H44 109.5 . .
C37 C39 H45 109.5 . .
H43 C39 H45 109.5 . .
H44 C39 H45 109.5 . .
C37 C40 H46 109.5 . .
C37 C40 H47 109.5 . .
H46 C40 H47 109.5 . .
C37 C40 H48 109.5 . .
H46 C40 H48 109.5 . .
H47 C40 H48 109.5 . .
C42 C41 C46 119.9(3) . .
C42 C41 Si2 131.1(3) . .
C46 C41 Si2 109.0(3) . .
C41 C42 C43 121.4(3) . .
C41 C42 H49 119.3 . .
C43 C42 H49 119.3 . .
C44 C43 C42 117.3(3) . .
C44 C43 C53 119.6(3) . .
C42 C43 C53 122.9(3) . .
C45 C44 C43 122.0(3) . .
C45 C44 H50 119.0 . .
C43 C44 H50 119.0 . .
C44 C45 C46 120.3(4) . .
C44 C45 H51 119.9 . .
C46 C45 H51 119.9 . .
C45 C46 C41 119.0(3) . .
C45 C46 C47 125.5(3) . .
C41 C46 C47 115.5(3) . .
C48 C47 C52 119.2(4) . .
C48 C47 C46 125.3(3) . .
C52 C47 C46 115.5(3) . .
C49 C48 C47 120.3(4) . .
C49 C48 H52 119.9 . .
C47 C48 H52 119.9 . .
C48 C49 C50 122.3(4) . .
C48 C49 H53 118.9 . .
C50 C49 H53 118.9 . .
C49 C50 C51 116.7(4) . .
C49 C50 C57 120.1(4) . .
C51 C50 C57 123.2(4) . .
C52 C51 C50 122.2(4) . .
C52 C51 H54 118.9 . .
C50 C51 H54 118.9 . .
C51 C52 C47 119.4(3) . .
C51 C52 Si2 132.3(3) . .
C47 C52 Si2 108.3(3) . .
C56 C53 C43 108.0(3) . .
C56 C53 C54 109.5(3) . .
C43 C53 C54 112.3(3) . .
C56 C53 C55 109.5(3) . .
C43 C53 C55 110.2(3) . .
C54 C53 C55 107.3(3) . .
C53 C54 H55 109.5 . .
C53 C54 H56 109.5 . .
H55 C54 H56 109.5 . .
C53 C54 H57 109.5 . .
H55 C54 H57 109.5 . .
H56 C54 H57 109.5 . .
C53 C55 H58 109.5 . .
C53 C55 H59 109.5 . .
H58 C55 H59 109.5 . .
C53 C55 H60 109.5 . .
H58 C55 H60 109.5 . .
H59 C55 H60 109.5 . .
C53 C56 H61 109.5 . .
C53 C56 H62 109.5 . .
H61 C56 H62 109.5 . .
C53 C56 H63 109.5 . .
H61 C56 H63 109.5 . .
H62 C56 H63 109.5 . .
C50 C57 C71 112.3(5) . .
C50 C57 C72 118.6(5) . .
C71 C57 C72 53.0(6) . .
C50 C57 C68 113.0(6) . .
C71 C57 C68 114.8(7) . .
C72 C57 C68 127.3(7) . .
C50 C57 C73 117.4(8) . .
C71 C57 C73 123.8(9) . .
C72 C57 C73 116.3(8) . .
C68 C57 C73 19.4(6) . .
C50 C57 C70 100.6(6) . .
C71 C57 C70 46.0(7) . .
C72 C57 C70 98.1(6) . .
C68 C57 C70 81.6(7) . .
C73 C57 C70 99.2(7) . .
C50 C57 C69 108.0(5) . .
C71 C57 C69 106.0(7) . .
C72 C57 C69 53.6(6) . .
C68 C57 C69 101.6(6) . .
C73 C57 C69 82.4(7) . .
C70 C57 C69 146.9(7) . .
C57 C68 H64 109.5 . .
C57 C68 H65 109.5 . .
H64 C68 H65 109.5 . .
C57 C68 H66 109.5 . .
H64 C68 H66 109.5 . .
H65 C68 H66 109.5 . .
C57 C69 H67 109.5 . .
C57 C69 H68 109.5 . .
H67 C69 H68 109.5 . .
C57 C69 H69 109.5 . .
H67 C69 H69 109.5 . .
H68 C69 H69 109.5 . .
C57 C70 H70 109.5 . .
C57 C70 H71 109.5 . .
H70 C70 H71 109.5 . .
C57 C70 H72 109.5 . .
H70 C70 H72 109.5 . .
H71 C70 H72 109.5 . .
C57 C71 H73 109.5 . .
C57 C71 H74 109.5 . .
H73 C71 H74 109.5 . .
C57 C71 H75 109.5 . .
H73 C71 H75 109.5 . .
H74 C71 H75 109.5 . .
C57 C72 H76 109.5 . .
C57 C72 H77 109.5 . .
H76 C72 H77 109.5 . .
C57 C72 H78 109.5 . .
H76 C72 H78 109.5 . .
H77 C72 H78 109.5 . .
C57 C73 H79 109.5 . .
C57 C73 H80 109.5 . .
H79 C73 H80 109.5 . .
C57 C73 H81 109.5 . .
H79 C73 H81 109.5 . .
H80 C73 H81 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Si1 C24 1.866(4) .
Si1 C13 1.867(4) .
Si1 C1 1.868(4) .
Si1 C12 1.874(4) .
Si2 C41 1.873(4) 2
Si2 C41 1.873(4) .
Si2 C52 1.885(4) 2
Si2 C52 1.885(4) .
C1 C2 1.391(5) .
C1 C6 1.415(5) .
C2 C3 1.387(5) .
C2 H1 0.9500 .
C3 C4 1.403(5) .
C3 C25 1.535(5) .
C4 C5 1.387(6) .
C4 H2 0.9500 .
C5 C6 1.387(5) .
C5 H3 0.9500 .
C6 C7 1.485(5) .
C7 C8 1.384(5) .
C7 C12 1.417(5) .
C8 C9 1.391(6) .
C8 H4 0.9500 .
C9 C10 1.393(6) .
C9 H5 0.9500 .
C10 C11 1.396(5) .
C10 C29 1.536(5) .
C11 C12 1.382(5) .
C11 H6 0.9500 .
C13 C14 1.390(5) .
C13 C18 1.409(5) .
C14 C15 1.409(6) .
C14 H7 0.9500 .
C15 C16 1.387(6) .
C15 C33 1.532(6) .
C16 C17 1.385(6) .
C16 H8 0.9500 .
C17 C18 1.394(5) .
C17 H9 0.9500 .
C18 C19 1.483(5) .
C19 C20 1.390(5) .
C19 C24 1.405(5) .
C20 C21 1.394(5) .
C20 H10 0.9500 .
C21 C22 1.393(5) .
C21 H11 0.9500 .
C22 C23 1.404(5) .
C22 C37 1.528(5) .
C23 C24 1.389(5) .
C23 H12 0.9500 .
C25 C26 1.518(5) .
C25 C27 1.535(5) .
C25 C28 1.543(5) .
C26 H13 0.9800 .
C26 H14 0.9800 .
C26 H15 0.9800 .
C27 H16 0.9800 .
C27 H17 0.9800 .
C27 H18 0.9800 .
C28 H19 0.9800 .
C28 H20 0.9800 .
C28 H21 0.9800 .
C29 C31 1.525(6) .
C29 C32 1.536(6) .
C29 C30 1.541(6) .
C30 H22 0.9800 .
C30 H23 0.9800 .
C30 H24 0.9800 .
C31 H25 0.9800 .
C31 H26 0.9800 .
C31 H27 0.9800 .
C32 H28 0.9800 .
C32 H29 0.9800 .
C32 H30 0.9800 .
C33 C36 1.520(7) .
C33 C34 1.532(7) .
C33 C35 1.543(7) .
C34 H31 0.9800 .
C34 H32 0.9800 .
C34 H33 0.9800 .
C35 H34 0.9800 .
C35 H35 0.9800 .
C35 H36 0.9800 .
C36 H37 0.9800 .
C36 H38 0.9800 .
C36 H39 0.9800 .
C37 C39 1.514(7) .
C37 C40 1.520(7) .
C37 C38 1.537(7) .
C38 H40 0.9800 .
C38 H41 0.9800 .
C38 H42 0.9800 .
C39 H43 0.9800 .
C39 H44 0.9800 .
C39 H45 0.9800 .
C40 H46 0.9800 .
C40 H47 0.9800 .
C40 H48 0.9800 .
C41 C42 1.396(5) .
C41 C46 1.408(5) .
C42 C43 1.405(5) .
C42 H49 0.9500 .
C43 C44 1.403(6) .
C43 C53 1.526(5) .
C44 C45 1.382(6) .
C44 H50 0.9500 .
C45 C46 1.396(5) .
C45 H51 0.9500 .
C46 C47 1.479(5) .
C47 C48 1.390(5) .
C47 C52 1.415(5) .
C48 C49 1.380(6) .
C48 H52 0.9500 .
C49 C50 1.400(6) .
C49 H53 0.9500 .
C50 C51 1.408(6) .
C50 C57 1.504(6) .
C51 C52 1.386(5) .
C51 H54 0.9500 .
C53 C56 1.523(5) .
C53 C54 1.539(6) .
C53 C55 1.544(5) .
C54 H55 0.9800 .
C54 H56 0.9800 .
C54 H57 0.9800 .
C55 H58 0.9800 .
C55 H59 0.9800 .
C55 H60 0.9800 .
C56 H61 0.9800 .
C56 H62 0.9800 .
C56 H63 0.9800 .
C57 C71 1.508(4) .
C57 C72 1.518(4) .
C57 C68 1.520(4) .
C57 C73 1.521(4) .
C57 C70 1.548(4) .
C57 C69 1.550(4) .
C68 H64 0.9800 .
C68 H65 0.9800 .
C68 H66 0.9800 .
C69 H67 0.9800 .
C69 H68 0.9800 .
C69 H69 0.9800 .
C70 H70 0.9800 .
C70 H71 0.9800 .
C70 H72 0.9800 .
C71 H73 0.9800 .
C71 H74 0.9800 .
C71 H75 0.9800 .
C72 H76 0.9800 .
C72 H77 0.9800 .
C72 H78 0.9800 .
C73 H79 0.9800 .
C73 H80 0.9800 .
C73 H81 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
C24 Si1 C1 C2 50.0(4) .
C13 Si1 C1 C2 -58.6(4) .
C12 Si1 C1 C2 173.5(3) .
C24 Si1 C1 C6 -126.4(2) .
C13 Si1 C1 C6 125.0(3) .
C12 Si1 C1 C6 -2.9(3) .
C6 C1 C2 C3 0.9(5) .
Si1 C1 C2 C3 -175.1(3) .
C1 C2 C3 C4 -2.0(5) .
C1 C2 C3 C25 173.9(3) .
C2 C3 C4 C5 1.2(6) .
C25 C3 C4 C5 -174.8(4) .
C3 C4 C5 C6 0.6(6) .
C4 C5 C6 C1 -1.7(5) .
C4 C5 C6 C7 173.4(3) .
C2 C1 C6 C5 1.0(5) .
Si1 C1 C6 C5 177.8(3) .
C2 C1 C6 C7 -174.7(3) .
Si1 C1 C6 C7 2.2(4) .
C5 C6 C7 C8 1.0(6) .
C1 C6 C7 C8 176.3(3) .
C5 C6 C7 C12 -175.2(3) .
C1 C6 C7 C12 0.0(4) .
C12 C7 C8 C9 3.4(5) .
C6 C7 C8 C9 -172.7(3) .
C7 C8 C9 C10 -0.7(6) .
C8 C9 C10 C11 -2.0(5) .
C8 C9 C10 C29 174.5(3) .
C9 C10 C11 C12 2.0(5) .
C29 C10 C11 C12 -174.5(3) .
C10 C11 C12 C7 0.7(5) .
C10 C11 C12 Si1 174.7(3) .
C8 C7 C12 C11 -3.5(5) .
C6 C7 C12 C11 173.1(3) .
C8 C7 C12 Si1 -178.7(3) .
C6 C7 C12 Si1 -2.2(4) .
C24 Si1 C12 C11 -48.2(4) .
C13 Si1 C12 C11 64.7(4) .
C1 Si1 C12 C11 -171.6(4) .
C24 Si1 C12 C7 126.3(2) .
C13 Si1 C12 C7 -120.8(3) .
C1 Si1 C12 C7 2.8(3) .
C24 Si1 C13 C14 -179.9(4) .
C1 Si1 C13 C14 -56.8(4) .
C12 Si1 C13 C14 54.5(4) .
C24 Si1 C13 C18 -3.4(3) .
C1 Si1 C13 C18 119.6(3) .
C12 Si1 C13 C18 -129.1(3) .
C18 C13 C14 C15 -1.6(6) .
Si1 C13 C14 C15 174.5(3) .
C13 C14 C15 C16 -0.2(6) .
C13 C14 C15 C33 177.1(4) .
C14 C15 C16 C17 1.3(7) .
C33 C15 C16 C17 -176.0(4) .
C15 C16 C17 C18 -0.5(7) .
C16 C17 C18 C13 -1.3(6) .
C16 C17 C18 C19 179.3(4) .
C14 C13 C18 C17 2.4(6) .
Si1 C13 C18 C17 -174.5(3) .
C14 C13 C18 C19 -178.2(3) .
Si1 C13 C18 C19 4.9(4) .
C17 C18 C19 C20 -5.2(6) .
C13 C18 C19 C20 175.4(4) .
C17 C18 C19 C24 175.1(4) .
C13 C18 C19 C24 -4.3(5) .
C24 C19 C20 C21 0.7(6) .
C18 C19 C20 C21 -179.1(4) .
C19 C20 C21 C22 0.0(6) .
C20 C21 C22 C23 -0.6(6) .
C20 C21 C22 C37 178.9(4) .
C21 C22 C23 C24 0.5(6) .
C37 C22 C23 C24 -178.9(4) .
C22 C23 C24 C19 0.1(5) .
C22 C23 C24 Si1 177.2(3) .
C20 C19 C24 C23 -0.7(5) .
C18 C19 C24 C23 179.1(3) .
C20 C19 C24 Si1 -178.4(3) .
C18 C19 C24 Si1 1.3(4) .
C13 Si1 C24 C23 -176.2(4) .
C1 Si1 C24 C23 61.7(4) .
C12 Si1 C24 C23 -47.5(4) .
C13 Si1 C24 C19 1.2(3) .
C1 Si1 C24 C19 -120.9(3) .
C12 Si1 C24 C19 129.9(3) .
C2 C3 C25 C26 21.9(5) .
C4 C3 C25 C26 -162.3(3) .
C2 C3 C25 C27 -97.5(4) .
C4 C3 C25 C27 78.3(4) .
C2 C3 C25 C28 143.8(4) .
C4 C3 C25 C28 -40.4(5) .
C9 C10 C29 C31 139.7(4) .
C11 C10 C29 C31 -43.9(5) .
C9 C10 C29 C32 18.8(5) .
C11 C10 C29 C32 -164.9(3) .
C9 C10 C29 C30 -100.6(4) .
C11 C10 C29 C30 75.7(4) .
C16 C15 C33 C36 66.1(6) .
C14 C15 C33 C36 -111.0(5) .
C16 C15 C33 C34 -173.5(4) .
C14 C15 C33 C34 9.3(6) .
C16 C15 C33 C35 -55.1(6) .
C14 C15 C33 C35 127.8(5) .
C21 C22 C37 C39 112.9(5) .
C23 C22 C37 C39 -67.6(5) .
C21 C22 C37 C40 -11.4(7) .
C23 C22 C37 C40 168.1(6) .
C21 C22 C37 C38 -128.1(4) .
C23 C22 C37 C38 51.3(5) .
C41 Si2 C41 C42 -54.6(3) 2
C52 Si2 C41 C42 54.7(4) 2
C52 Si2 C41 C42 -180.0(4) .
C41 Si2 C41 C46 125.2(3) 2
C52 Si2 C41 C46 -125.5(3) 2
C52 Si2 C41 C46 -0.2(3) .
C46 C41 C42 C43 1.1(5) .
Si2 C41 C42 C43 -179.1(3) .
C41 C42 C43 C44 -0.5(5) .
C41 C42 C43 C53 176.1(3) .
C42 C43 C44 C45 -0.2(5) .
C53 C43 C44 C45 -176.9(3) .
C43 C44 C45 C46 0.2(6) .
C44 C45 C46 C41 0.4(5) .
C44 C45 C46 C47 179.4(3) .
C42 C41 C46 C45 -1.1(5) .
Si2 C41 C46 C45 179.1(3) .
C42 C41 C46 C47 179.8(3) .
Si2 C41 C46 C47 0.0(4) .
C45 C46 C47 C48 0.0(6) .
C41 C46 C47 C48 179.0(3) .
C45 C46 C47 C52 -178.8(3) .
C41 C46 C47 C52 0.2(5) .
C52 C47 C48 C49 0.5(6) .
C46 C47 C48 C49 -178.3(4) .
C47 C48 C49 C50 -0.2(6) .
C48 C49 C50 C51 -0.3(7) .
C48 C49 C50 C57 -179.8(4) .
C49 C50 C51 C52 0.7(7) .
C57 C50 C51 C52 -179.9(4) .
C50 C51 C52 C47 -0.4(6) .
C50 C51 C52 Si2 178.4(3) .
C48 C47 C52 C51 -0.2(5) .
C46 C47 C52 C51 178.7(3) .
C48 C47 C52 Si2 -179.2(3) .
C46 C47 C52 Si2 -0.3(4) .
C41 Si2 C52 C51 58.9(4) 2
C41 Si2 C52 C51 -178.6(4) .
C52 Si2 C52 C51 -52.3(4) 2
C41 Si2 C52 C47 -122.2(3) 2
C41 Si2 C52 C47 0.3(3) .
C52 Si2 C52 C47 126.6(3) 2
C44 C43 C53 C56 64.5(4) .
C42 C43 C53 C56 -112.0(4) .
C44 C43 C53 C54 -174.6(3) .
C42 C43 C53 C54 8.9(5) .
C44 C43 C53 C55 -55.1(5) .
C42 C43 C53 C55 128.5(4) .
C49 C50 C57 C71 -63.9(8) .
C51 C50 C57 C71 116.7(7) .
C49 C50 C57 C72 -5.0(8) .
C51 C50 C57 C72 175.5(6) .
C49 C50 C57 C68 164.3(6) .
C51 C50 C57 C68 -15.2(8) .
C49 C50 C57 C73 143.4(8) .
C51 C50 C57 C73 -36.1(9) .
C49 C50 C57 C70 -110.4(7) .
C51 C50 C57 C70 70.1(7) .
C49 C50 C57 C69 52.7(7) .
C51 C50 C57 C69 -126.8(6) .
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 1.000 0.030 0.250 192 16 ' '
2 1.000 -0.030 0.750 192 16 ' '
3 0.125 0.193 0.057 33 1 ' '
4 0.875 0.193 0.443 33 1 ' '
5 0.500 0.470 0.750 192 16 ' '
6 0.625 0.307 0.557 33 1 ' '
7 0.375 0.307 0.943 33 1 ' '
8 0.500 0.530 0.250 192 16 ' '
9 0.625 0.693 0.057 33 1 ' '
10 0.375 0.693 0.443 33 1 ' '
11 0.125 0.807 0.557 33 1 ' '
12 0.875 0.807 0.943 33 1 ' '
