#------------------------------------------------------------------------------
#$Date: 2018-08-11 18:04:49 +0300 (Sat, 11 Aug 2018) $
#$Revision: 209574 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/03/05/7030586.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7030586
loop_
_publ_author_name
'Shin, Kyong-Soon'
'Son, Kyung-In'
'Kim, Jae Il'
'Hong, Chang Seop'
'Suh, Myungkoo'
'Noh, Dong-Youn'
_publ_section_title
;
 Heteroleptic binuclear palladium(II) and platinum(II) complexes
 containing 1,2-bis(diphenylphosphino)acetylene and
 1,2-benzenedithiolates: syntheses, crystal structures,
 electrochemistry and photoluminescence properties
;
_journal_coden_ASTM              DTARAF
_journal_issue                   10
_journal_name_full               'Dalton Transactions'
_journal_page_first              1767
_journal_page_last               1775
_journal_paper_doi               10.1039/b815013c
_journal_year                    2009
_chemical_formula_sum            'C67 H51 Cl9 P4 Pd2 S4'
_chemical_formula_weight         1640.05
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 93.5380(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.7965(3)
_cell_length_b                   14.0504(3)
_cell_length_c                   36.1985(8)
_cell_measurement_reflns_used    5733
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      24.995
_cell_measurement_theta_min      3.54
_cell_volume                     7003.6(3)
_computing_cell_refinement       'Bruker SMART APEXll'
_computing_data_collection       'Bruker SMART APEXll'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    WingX
_computing_publication_material  WingX
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    SHELXTL
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'omega & phi scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0633
_diffrn_reflns_av_sigmaI/netI    0.0843
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       47
_diffrn_reflns_limit_l_min       -48
_diffrn_reflns_number            69043
_diffrn_reflns_theta_full        28.39
_diffrn_reflns_theta_max         28.39
_diffrn_reflns_theta_min         1.13
_exptl_absorpt_coefficient_mu    1.108
_exptl_absorpt_correction_T_max  0.9467
_exptl_absorpt_correction_T_min  0.6912
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.555
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             3288
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.532
_refine_diff_density_min         -0.734
_refine_diff_density_rms         0.096
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.023
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     775
_refine_ls_number_reflns         17498
_refine_ls_number_restraints     36
_refine_ls_restrained_S_all      1.026
_refine_ls_R_factor_all          0.1173
_refine_ls_R_factor_gt           0.0525
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0702P)²+2.4323P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1301
_refine_ls_wR_factor_ref         0.1538
_reflns_number_gt                9528
_reflns_number_total             17498
_reflns_threshold_expression     >2sigma(I)
_cod_duplicate_entry             7000686
_cod_data_source_file            b815013c.txt
_cod_data_source_block           pd_bdt_[Pd(bdt)]2(u-dppa)2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'MULTI-SCAN' changed to
'multi-scan' according to
/usr/data/users/saulius/automatic-downloads/retrospective/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               7030586
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Pd1 Pd 0.16000(2) 0.60183(2) 0.084412(9) 0.03712(10) Uani 1 1 d .
Pd2 Pd 0.54422(2) 0.30471(3) 0.151901(10) 0.04128(11) Uani 1 1 d .
P1 P 0.12884(8) 0.47207(9) 0.12059(3) 0.0401(3) Uani 1 1 d .
P2 P 0.27673(8) 0.52771(9) 0.05243(3) 0.0396(3) Uani 1 1 d .
P3 P 0.38735(8) 0.28128(9) 0.16778(3) 0.0424(3) Uani 1 1 d .
P4 P 0.52477(8) 0.46444(9) 0.14262(3) 0.0395(3) Uani 1 1 d .
C1 C 0.2300(3) 0.4056(3) 0.13757(13) 0.0421(11) Uani 1 1 d .
C2 C 0.2974(3) 0.3609(3) 0.15053(13) 0.0430(11) Uani 1 1 d .
C3 C 0.3730(3) 0.4929(3) 0.08304(12) 0.0427(11) Uani 1 1 d .
C4 C 0.4367(3) 0.4838(3) 0.10647(12) 0.0404(11) Uani 1 1 d .
C5 C 0.2358(3) 0.4198(4) 0.02921(12) 0.0443(11) Uani 1 1 d .
C6 C 0.2885(4) 0.3371(4) 0.03123(15) 0.0601(14) Uani 1 1 d .
H6 H 0.3477 0.3348 0.0449 0.072 Uiso 1 1 calc R
C7 C 0.2526(5) 0.2568(5) 0.01264(18) 0.0799(19) Uani 1 1 d .
H7 H 0.2890 0.2011 0.0133 0.096 Uiso 1 1 calc R
C8 C 0.1649(5) 0.2590(5) -0.00655(18) 0.0776(18) Uani 1 1 d .
H8 H 0.1406 0.2044 -0.0184 0.093 Uiso 1 1 calc R
C9 C 0.1132(4) 0.3404(5) -0.00838(16) 0.0758(18) Uani 1 1 d .
H9 H 0.0538 0.3419 -0.0220 0.091 Uiso 1 1 calc R
C10 C 0.1465(4) 0.4203(4) 0.00932(14) 0.0586(14) Uani 1 1 d .
H10 H 0.1094 0.4756 0.0081 0.070 Uiso 1 1 calc R
C11 C 0.3424(3) 0.5972(3) 0.01981(13) 0.0448(11) Uani 1 1 d .
C12 C 0.3276(4) 0.5862(4) -0.01773(14) 0.0621(15) Uani 1 1 d .
H12 H 0.2850 0.5397 -0.0272 0.075 Uiso 1 1 calc R
C13 C 0.3752(5) 0.6433(5) -0.04151(18) 0.082(2) Uani 1 1 d .
H13 H 0.3636 0.6359 -0.0669 0.098 Uiso 1 1 calc R
C14 C 0.4389(6) 0.7102(5) -0.0283(2) 0.091(2) Uani 1 1 d .
H14 H 0.4714 0.7482 -0.0446 0.109 Uiso 1 1 calc R
C15 C 0.4553(5) 0.7218(5) 0.0093(2) 0.086(2) Uani 1 1 d .
H15 H 0.4989 0.7678 0.0184 0.103 Uiso 1 1 calc R
C16 C 0.4075(4) 0.6659(4) 0.03348(16) 0.0659(15) Uani 1 1 d .
H16 H 0.4187 0.6740 0.0589 0.079 Uiso 1 1 calc R
C17 C 0.4775(3) 0.5251(4) 0.18147(14) 0.0484(12) Uani 1 1 d .
C18 C 0.4096(4) 0.5959(4) 0.17800(18) 0.0713(17) Uani 1 1 d .
H18 H 0.3857 0.6151 0.1546 0.086 Uiso 1 1 calc R
C19 C 0.3762(5) 0.6393(6) 0.2092(3) 0.102(3) Uani 1 1 d .
H19 H 0.3289 0.6865 0.2069 0.123 Uiso 1 1 calc R
C20 C 0.4135(8) 0.6118(7) 0.2432(3) 0.118(4) Uani 1 1 d .
H20 H 0.3919 0.6417 0.2640 0.142 Uiso 1 1 calc R
C21 C 0.4810(7) 0.5424(6) 0.2476(2) 0.102(3) Uani 1 1 d .
H21 H 0.5064 0.5257 0.2711 0.123 Uiso 1 1 calc R
C22 C 0.5116(5) 0.4967(5) 0.21660(16) 0.0721(17) Uani 1 1 d .
H22 H 0.5554 0.4466 0.2193 0.086 Uiso 1 1 calc R
C23 C 0.6231(3) 0.5388(3) 0.12824(13) 0.0435(11) Uani 1 1 d .
C24 C 0.6967(4) 0.5658(5) 0.15265(16) 0.0705(17) Uani 1 1 d .
H24 H 0.6959 0.5474 0.1773 0.085 Uiso 1 1 calc R
C25 C 0.7720(4) 0.6197(5) 0.14136(18) 0.082(2) Uani 1 1 d .
H25 H 0.8220 0.6370 0.1584 0.098 Uiso 1 1 calc R
C26 C 0.7746(4) 0.6483(5) 0.10566(19) 0.0744(17) Uani 1 1 d .
H26 H 0.8260 0.6852 0.0984 0.089 Uiso 1 1 calc R
C27 C 0.7016(4) 0.6228(4) 0.08049(17) 0.0704(17) Uani 1 1 d .
H27 H 0.7028 0.6423 0.0560 0.084 Uiso 1 1 calc R
C28 C 0.6254(4) 0.5674(4) 0.09178(15) 0.0618(15) Uani 1 1 d .
H28 H 0.5757 0.5494 0.0747 0.074 Uiso 1 1 calc R
C29 C 0.0562(3) 0.3836(4) 0.09570(13) 0.0454(11) Uani 1 1 d .
C30 C 0.0795(4) 0.2877(4) 0.09695(15) 0.0613(15) Uani 1 1 d .
H30 H 0.1345 0.2677 0.1110 0.074 Uiso 1 1 calc R
C31 C 0.0224(5) 0.2216(5) 0.07775(19) 0.0786(18) Uani 1 1 d .
H31 H 0.0388 0.1573 0.0787 0.094 Uiso 1 1 calc R
C32 C -0.0593(5) 0.2516(6) 0.05700(18) 0.085(2) Uani 1 1 d .
H32 H -0.0982 0.2074 0.0439 0.102 Uiso 1 1 calc R
C33 C -0.0829(4) 0.3448(6) 0.05568(18) 0.087(2) Uani 1 1 d .
H33 H -0.1377 0.3643 0.0415 0.105 Uiso 1 1 calc R
C34 C -0.0264(4) 0.4123(4) 0.07529(16) 0.0702(17) Uani 1 1 d .
H34 H -0.0443 0.4761 0.0746 0.084 Uiso 1 1 calc R
C35 C 0.0713(3) 0.4885(3) 0.16414(13) 0.0441(11) Uani 1 1 d .
C36 C -0.0246(4) 0.4651(4) 0.16783(16) 0.0675(16) Uani 1 1 d .
H36 H -0.0623 0.4431 0.1474 0.081 Uiso 1 1 calc R
C37 C -0.0651(5) 0.4739(5) 0.2015(2) 0.088(2) Uani 1 1 d .
H37 H -0.1302 0.4592 0.2038 0.106 Uiso 1 1 calc R
C38 C -0.0086(6) 0.5042(5) 0.23117(19) 0.087(2) Uani 1 1 d .
H38 H -0.0350 0.5077 0.2542 0.105 Uiso 1 1 calc R
C39 C 0.0847(5) 0.5294(5) 0.22812(16) 0.082(2) Uani 1 1 d .
H39 H 0.1219 0.5514 0.2487 0.098 Uiso 1 1 calc R
C40 C 0.1248(4) 0.5223(4) 0.19397(15) 0.0687(16) Uani 1 1 d .
H40 H 0.1888 0.5408 0.1915 0.082 Uiso 1 1 calc R
C41 C 0.3255(3) 0.1723(4) 0.15256(15) 0.0491(12) Uani 1 1 d .
C42 C 0.2620(4) 0.1262(4) 0.17451(17) 0.0639(15) Uani 1 1 d .
H42 H 0.2575 0.1448 0.1990 0.077 Uiso 1 1 calc R
C43 C 0.2052(4) 0.0525(5) 0.1602(2) 0.0776(18) Uani 1 1 d .
H43 H 0.1621 0.0221 0.1751 0.093 Uiso 1 1 calc R
C44 C 0.2117(5) 0.0244(5) 0.1250(2) 0.085(2) Uani 1 1 d .
H44 H 0.1734 -0.0254 0.1156 0.102 Uiso 1 1 calc R
C45 C 0.2754(5) 0.0695(5) 0.10290(18) 0.084(2) Uani 1 1 d .
H45 H 0.2794 0.0503 0.0785 0.101 Uiso 1 1 calc R
C46 C 0.3336(5) 0.1434(4) 0.11687(17) 0.0708(16) Uani 1 1 d .
H46 H 0.3775 0.1728 0.1021 0.085 Uiso 1 1 calc R
C47 C 0.3766(3) 0.2919(3) 0.21735(13) 0.0464(12) Uani 1 1 d .
C48 C 0.2964(4) 0.3343(4) 0.23198(15) 0.0609(14) Uani 1 1 d .
H48 H 0.2449 0.3564 0.2165 0.073 Uiso 1 1 calc R
C49 C 0.2950(5) 0.3430(5) 0.27024(17) 0.0753(17) Uani 1 1 d .
H49 H 0.2418 0.3716 0.2803 0.090 Uiso 1 1 calc R
C50 C 0.3688(5) 0.3109(5) 0.29303(16) 0.0762(18) Uani 1 1 d .
H50 H 0.3666 0.3177 0.3185 0.091 Uiso 1 1 calc R
C51 C 0.4461(5) 0.2688(5) 0.27855(18) 0.083(2) Uani 1 1 d .
H51 H 0.4962 0.2455 0.2944 0.100 Uiso 1 1 calc R
C52 C 0.4524(4) 0.2596(4) 0.24056(15) 0.0643(15) Uani 1 1 d .
H52 H 0.5068 0.2321 0.2310 0.077 Uiso 1 1 calc R
S1 S 0.04717(9) 0.68484(9) 0.11483(4) 0.0489(3) Uani 1 1 d .
S2 S 0.17316(9) 0.72801(9) 0.04546(4) 0.0506(3) Uani 1 1 d .
C53 C 0.0871(3) 0.8097(3) 0.05954(13) 0.0461(11) Uani 1 1 d .
C54 C 0.0727(4) 0.8947(4) 0.04028(15) 0.0616(14) Uani 1 1 d .
H54 H 0.1092 0.9071 0.0201 0.074 Uiso 1 1 calc R
C55 C 0.0073(5) 0.9594(4) 0.05016(17) 0.0700(16) Uani 1 1 d .
H55 H -0.0012 1.0157 0.0368 0.084 Uiso 1 1 calc R
C56 C -0.0471(5) 0.9422(4) 0.07999(18) 0.0748(18) Uani 1 1 d .
H56 H -0.0921 0.9871 0.0868 0.090 Uiso 1 1 calc R
C57 C -0.0353(4) 0.8579(4) 0.10006(15) 0.0617(14) Uani 1 1 d .
H57 H -0.0725 0.8462 0.1201 0.074 Uiso 1 1 calc R
C58 C 0.0328(3) 0.7913(3) 0.08981(14) 0.0465(12) Uani 1 1 d .
S3 S 0.56695(10) 0.14426(10) 0.15855(5) 0.0646(4) Uani 1 1 d .
S4 S 0.70641(9) 0.32133(10) 0.14493(4) 0.0526(3) Uani 1 1 d .
C59 C 0.7525(4) 0.2063(4) 0.15088(13) 0.0530(13) Uani 1 1 d .
C60 C 0.8525(4) 0.1911(5) 0.14947(15) 0.0694(17) Uani 1 1 d .
H60 H 0.8932 0.2418 0.1447 0.083 Uiso 1 1 calc R
C61 C 0.8913(5) 0.1005(5) 0.15516(17) 0.080(2) Uani 1 1 d .
H61 H 0.9577 0.0908 0.1541 0.096 Uiso 1 1 calc R
C62 C 0.8322(5) 0.0261(5) 0.16219(17) 0.080(2) Uani 1 1 d .
H62 H 0.8586 -0.0343 0.1661 0.097 Uiso 1 1 calc R
C63 C 0.7331(5) 0.0394(4) 0.16356(15) 0.0722(17) Uani 1 1 d .
H63 H 0.6930 -0.0118 0.1684 0.087 Uiso 1 1 calc R
C64 C 0.6933(4) 0.1298(4) 0.15768(14) 0.0570(14) Uani 1 1 d .
C65 C 0.4545(7) 0.8711(8) 0.1350(3) 0.154(3) Uani 1 1 d DU
H65 H 0.4660 0.9284 0.1205 0.185 Uiso 1 1 calc R
Cl1 Cl 0.4383(2) 0.9020(2) 0.17925(8) 0.1504(10) Uani 1 1 d DU
Cl2 Cl 0.3482(3) 0.8148(2) 0.11729(12) 0.242(2) Uani 1 1 d DU
Cl3 Cl 0.5492(3) 0.7940(3) 0.13175(11) 0.2092(16) Uani 1 1 d DU
C66 C 0.7325(5) 0.7625(5) 0.2548(2) 0.097(2) Uani 1 1 d DU
H66 H 0.7405 0.7691 0.2818 0.116 Uiso 1 1 calc R
Cl4 Cl 0.7749(2) 0.8650(2) 0.23564(8) 0.1569(11) Uani 1 1 d DU
Cl5 Cl 0.61224(19) 0.7501(2) 0.24327(11) 0.1876(14) Uani 1 1 d DU
Cl6 Cl 0.79386(19) 0.6622(2) 0.24286(7) 0.1418(9) Uani 1 1 d DU
C67 C 0.6498(7) 0.0273(9) 0.0637(3) 0.195(4) Uani 1 1 d DU
H67 H 0.6636 0.0602 0.0873 0.234 Uiso 1 1 calc R
Cl7 Cl 0.5246(2) 0.0237(3) 0.05114(11) 0.2034(15) Uani 1 1 d DU
Cl8 Cl 0.6872(3) -0.0951(3) 0.06591(15) 0.2334(18) Uani 1 1 d DU
Cl9 Cl 0.7068(3) 0.0764(4) 0.0301(2) 0.409(5) Uani 1 1 d DU
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
S2 Pd1 S1 89.07(5)
S2 Pd1 P2 87.46(4)
S1 Pd1 P2 176.29(5)
S2 Pd1 P1 173.34(5)
S1 Pd1 P1 88.48(4)
P2 Pd1 P1 95.12(4)
S4 Pd2 P4 89.45(5)
S4 Pd2 S3 89.05(5)
P4 Pd2 S3 177.28(5)
S4 Pd2 P3 171.48(5)
P4 Pd2 P3 94.23(4)
S3 Pd2 P3 87.57(5)
C1 P1 C29 102.3(2)
C1 P1 C35 98.3(2)
C29 P1 C35 105.1(2)
C1 P1 Pd1 116.58(15)
C29 P1 Pd1 112.30(17)
C35 P1 Pd1 119.88(16)
C3 P2 C5 105.3(2)
C3 P2 C11 100.0(2)
C5 P2 C11 107.6(2)
C3 P2 Pd1 109.73(16)
C5 P2 Pd1 114.05(15)
C11 P2 Pd1 118.58(16)
C2 P3 C47 101.6(2)
C2 P3 C41 96.9(2)
C47 P3 C41 107.6(2)
C2 P3 Pd2 118.38(16)
C47 P3 Pd2 111.78(16)
C41 P3 Pd2 118.42(16)
C4 P4 C17 104.0(2)
C4 P4 C23 101.1(2)
C17 P4 C23 105.4(2)
C4 P4 Pd2 109.41(16)
C17 P4 Pd2 113.30(17)
C23 P4 Pd2 121.69(15)
C2 C1 P1 177.3(4)
C1 C2 P3 172.2(4)
C4 C3 P2 169.1(5)
C3 C4 P4 175.7(4)
C6 C5 C10 118.9(5)
C6 C5 P2 122.5(4)
C10 C5 P2 118.6(4)
C5 C6 C7 119.4(5)
C8 C7 C6 120.7(6)
C9 C8 C7 119.7(6)
C8 C9 C10 121.1(6)
C9 C10 C5 120.2(6)
C12 C11 C16 119.0(5)
C12 C11 P2 122.3(4)
C16 C11 P2 118.6(4)
C11 C12 C13 120.6(6)
C14 C13 C12 120.6(6)
C13 C14 C15 119.7(6)
C16 C15 C14 120.4(7)
C15 C16 C11 119.7(6)
C18 C17 C22 119.0(5)
C18 C17 P4 123.5(4)
C22 C17 P4 117.4(4)
C17 C18 C19 120.4(7)
C20 C19 C18 119.0(8)
C21 C20 C19 122.2(8)
C20 C21 C22 118.8(8)
C21 C22 C17 120.5(7)
C24 C23 C28 118.7(5)
C24 C23 P4 121.1(4)
C28 C23 P4 120.2(4)
C23 C24 C25 120.7(5)
C26 C25 C24 121.0(5)
C25 C26 C27 119.8(6)
C26 C27 C28 119.5(6)
C23 C28 C27 120.4(5)
C34 C29 C30 118.9(5)
C34 C29 P1 118.8(4)
C30 C29 P1 122.3(4)
C31 C30 C29 121.0(6)
C30 C31 C32 119.3(6)
C33 C32 C31 120.1(6)
C32 C33 C34 121.1(6)
C29 C34 C33 119.5(6)
C40 C35 C36 119.1(5)
C40 C35 P1 119.2(4)
C36 C35 P1 121.7(4)
C37 C36 C35 120.6(6)
C38 C37 C36 119.0(6)
C39 C38 C37 121.5(6)
C38 C39 C40 119.3(6)
C35 C40 C39 120.4(6)
C46 C41 C42 119.8(5)
C46 C41 P3 118.2(4)
C42 C41 P3 121.5(4)
C43 C42 C41 120.2(6)
C44 C43 C42 120.4(6)
C43 C44 C45 119.9(6)
C44 C45 C46 120.4(6)
C41 C46 C45 119.2(6)
C52 C47 C48 120.1(5)
C52 C47 P3 118.1(4)
C48 C47 P3 121.8(4)
C47 C48 C49 118.5(5)
C50 C49 C48 121.5(6)
C49 C50 C51 119.5(6)
C50 C51 C52 121.6(6)
C47 C52 C51 118.8(5)
C58 S1 Pd1 104.21(17)
C53 S2 Pd1 104.40(17)
C58 C53 C54 119.2(5)
C58 C53 S2 121.1(4)
C54 C53 S2 119.7(4)
C55 C54 C53 121.6(6)
C54 C55 C56 119.8(5)
C55 C56 C57 120.5(5)
C58 C57 C56 119.4(5)
C53 C58 C57 119.4(5)
C53 C58 S1 121.1(4)
C57 C58 S1 119.5(4)
C64 S3 Pd2 104.0(2)
C59 S4 Pd2 104.12(19)
C64 C59 C60 118.8(5)
C64 C59 S4 121.9(4)
C60 C59 S4 119.3(5)
C61 C60 C59 120.3(6)
C62 C61 C60 120.2(6)
C61 C62 C63 120.5(6)
C62 C63 C64 119.8(6)
C59 C64 C63 120.3(5)
C59 C64 S3 120.8(4)
C63 C64 S3 118.9(5)
Cl1 C65 Cl3 112.1(6)
Cl1 C65 Cl2 107.9(6)
Cl3 C65 Cl2 108.3(6)
Cl5 C66 Cl6 110.2(4)
Cl5 C66 Cl4 109.8(4)
Cl6 C66 Cl4 113.7(4)
Cl9 C67 Cl7 109.2(6)
Cl9 C67 Cl8 106.6(6)
Cl7 C67 Cl8 105.0(7)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
Pd1 S2 2.2795(13)
Pd1 S1 2.2820(12)
Pd1 P2 2.2908(12)
Pd1 P1 2.3008(13)
Pd2 S4 2.2793(12)
Pd2 P4 2.2827(13)
Pd2 S3 2.2867(15)
Pd2 P3 2.2970(12)
P1 C1 1.758(5)
P1 C29 1.803(5)
P1 C35 1.823(5)
P2 C3 1.746(5)
P2 C5 1.807(5)
P2 C11 1.817(5)
P3 C2 1.756(5)
P3 C47 1.815(5)
P3 C41 1.821(5)
P4 C4 1.751(5)
P4 C17 1.801(5)
P4 C23 1.815(5)
C1 C2 1.194(6)
C3 C4 1.190(6)
C5 C6 1.369(7)
C5 C10 1.388(6)
C6 C7 1.390(8)
C7 C8 1.357(9)
C8 C9 1.347(9)
C9 C10 1.359(8)
C11 C12 1.370(7)
C11 C16 1.388(7)
C12 C13 1.373(8)
C13 C14 1.354(10)
C14 C15 1.376(10)
C15 C16 1.375(8)
C17 C18 1.366(7)
C17 C22 1.387(7)
C18 C19 1.387(9)
C19 C20 1.360(12)
C20 C21 1.350(12)
C21 C22 1.381(9)
C23 C24 1.357(7)
C23 C28 1.382(7)
C24 C25 1.369(8)
C25 C26 1.356(8)
C26 C27 1.364(8)
C27 C28 1.389(7)
C29 C34 1.380(7)
C29 C30 1.385(7)
C30 C31 1.378(7)
C31 C32 1.382(9)
C32 C33 1.350(10)
C33 C34 1.393(8)
C35 C40 1.356(7)
C35 C36 1.378(7)
C36 C37 1.376(8)
C37 C38 1.357(9)
C38 C39 1.347(9)
C39 C40 1.389(8)
C41 C46 1.365(7)
C41 C42 1.380(7)
C42 C43 1.380(8)
C43 C44 1.341(9)
C44 C45 1.380(9)
C45 C46 1.387(9)
C47 C52 1.377(7)
C47 C48 1.390(7)
C48 C49 1.392(7)
C49 C50 1.348(8)
C50 C51 1.353(9)
C51 C52 1.389(8)
S1 C58 1.753(5)
S2 C53 1.750(5)
C53 C58 1.390(7)
C53 C54 1.391(7)
C54 C55 1.345(7)
C55 C56 1.374(8)
C56 C57 1.394(8)
C57 C58 1.392(7)
S3 C64 1.758(5)
S4 C59 1.745(5)
C59 C64 1.380(7)
C59 C60 1.400(7)
C60 C61 1.391(8)
C61 C62 1.358(9)
C62 C63 1.385(8)
C63 C64 1.395(7)
C65 Cl1 1.686(9)
C65 Cl3 1.707(9)
C65 Cl2 1.753(10)
C66 Cl5 1.695(7)
C66 Cl6 1.712(7)
C66 Cl4 1.717(7)
C67 Cl9 1.641(10)
C67 Cl7 1.759(10)
C67 Cl8 1.796(11)
