#------------------------------------------------------------------------------
#$Date: 2018-07-10 12:13:45 +0300 (Tue, 10 Jul 2018) $
#$Revision: 208944 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/03/08/7030857.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7030857
loop_
_publ_author_name
'Chen, Wen-Bin'
'Li, Zhi-Xin'
'Yu, Xin-Wei'
'Yang, Meng'
'Qiu, Yan-Xuan'
'Dong, Wen'
'Sun, Ya-Qiu'
_publ_section_title
;
 Syntheses, structures and properties of 5-azotetrazolyl salicylic acid
 and its dilanthanide complexes.
;
_journal_issue                   24
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              9090
_journal_page_last               9097
_journal_paper_doi               10.1039/c4dt00278d
_journal_volume                  43
_journal_year                    2014
_chemical_formula_sum            'C32 H46 Eu2 N24 O26'
_chemical_formula_weight         1486.87
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                99.9840(10)
_cell_angle_beta                 95.9560(10)
_cell_angle_gamma                110.3260(10)
_cell_formula_units_Z            2
_cell_length_a                   11.8805(2)
_cell_length_b                   14.6591(3)
_cell_length_c                   16.4889(3)
_cell_measurement_reflns_used    11918
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.58
_cell_measurement_theta_min      1.27
_cell_volume                     2609.93(9)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SMART'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_detector_area_resol_mean none
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0212
_diffrn_reflns_av_unetI/netI     0.0212
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            41058
_diffrn_reflns_theta_full        27.58
_diffrn_reflns_theta_max         27.58
_diffrn_reflns_theta_min         1.27
_diffrn_standards_decay_%        none
_diffrn_standards_interval_count none
_diffrn_standards_interval_time  none
_diffrn_standards_number         none
_exptl_absorpt_coefficient_mu    2.491
_exptl_absorpt_correction_T_max  0.451
_exptl_absorpt_correction_T_min  0.285
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.892
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1480.0
_exptl_crystal_size_max          0.52
_exptl_crystal_size_mid          0.46
_exptl_crystal_size_min          0.32
_refine_diff_density_max         1.472
_refine_diff_density_min         -0.713
_refine_diff_density_rms         0.079
_refine_ls_extinction_coef       0.0011(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     762
_refine_ls_number_reflns         12090
_refine_ls_number_restraints     44
_refine_ls_restrained_S_all      1.041
_refine_ls_R_factor_all          0.0292
_refine_ls_R_factor_gt           0.0244
_refine_ls_shift/su_max          0.012
_refine_ls_shift/su_mean         0.005
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0274P)²+2.8236P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0594
_refine_ls_wR_factor_ref         0.0621
_reflns_number_gt                10514
_reflns_number_total             12090
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4dt00278d2.cif
_cod_data_source_block           1
_cod_depositor_comments
;Adding full bibliography for 7030851--7030857.cif.

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 

2018-05-30
Z value and formula fixed to values more according to usual
chemical conventions.                 miguel
;
_cod_original_formula_weight         2973.74
_cod_original_formula_units_Z            1
_cod_original_sg_symbol_H-M      P-1
_cod_original_formula_sum        'C64 H92 Eu4 N48 O52 '
_cod_database_code               7030857
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.844263(11) 1.048387(9) 0.404693(8) 0.02402(4) Uani 1 1 d .
Eu2 Eu 0.347660(11) 0.547551(9) 0.923298(8) 0.02589(4) Uani 1 1 d .
O18 O 0.40988(18) 0.71909(14) 0.91411(13) 0.0364(5) Uani 1 1 d D
O20 O 0.19470(18) 0.57970(16) 0.99395(13) 0.0400(5) Uani 1 1 d D
O11 O 0.29461(17) 0.40418(14) 0.97812(12) 0.0339(4) Uani 1 1 d .
O10 O 0.56116(16) 0.60119(14) 0.92855(12) 0.0336(4) Uani 1 1 d .
O7 O 0.21673(16) 0.56576(14) 0.80466(11) 0.0313(4) Uani 1 1 d .
O8 O 0.14815(17) 0.42214(14) 0.84042(12) 0.0371(5) Uani 1 1 d .
O19 O 0.4432(2) 0.61826(16) 1.06705(13) 0.0457(5) Uani 1 1 d D
O5 O 0.79939(17) 0.91577(14) 0.47465(11) 0.0318(4) Uani 1 1 d .
O16 O 0.69702(17) 1.08555(16) 0.48294(12) 0.0361(4) Uani 1 1 d D
O14 O 0.91444(19) 1.22234(14) 0.41419(13) 0.0404(5) Uani 1 1 d D
O4 O 1.05485(16) 1.07152(15) 0.42430(12) 0.0356(5) Uani 1 1 d D
O1 O 0.69236(17) 1.05927(15) 0.30043(12) 0.0343(4) Uani 1 1 d .
O15 O 0.9307(2) 1.12298(16) 0.55674(13) 0.0449(5) Uani 1 1 d D
O2 O 0.62924(18) 0.91662(15) 0.33772(12) 0.0391(5) Uani 1 1 d .
C7 C 0.6138(2) 0.9733(2) 0.29151(16) 0.0290(5) Uani 1 1 d .
C1 C 0.5045(2) 0.93598(19) 0.22499(15) 0.0263(5) Uani 1 1 d .
C6 C 0.4905(2) 0.9937(2) 0.16949(16) 0.0277(5) Uani 1 1 d .
H6 H 0.5489 1.0573 0.1755 0.033 Uiso 1 1 calc R
C2 C 0.4154(3) 0.8407(2) 0.21576(17) 0.0328(6) Uani 1 1 d .
C31 C 0.3325(2) 0.36553(18) 1.03265(16) 0.0255(5) Uani 1 1 d .
C25 C 0.2422(2) 0.27450(18) 1.05046(15) 0.0244(5) Uani 1 1 d .
C26 C 0.1225(2) 0.22730(19) 1.00427(16) 0.0279(5) Uani 1 1 d .
C17 C 0.0263(2) 0.44449(19) 0.72802(16) 0.0273(5) Uani 1 1 d .
C23 C 0.1359(2) 0.48042(19) 0.79410(16) 0.0273(5) Uani 1 1 d .
C22 C 0.0113(2) 0.5029(2) 0.67310(16) 0.0279(5) Uani 1 1 d .
H22 H 0.0703 0.5661 0.6784 0.033 Uiso 1 1 calc R
C29 C 0.1977(2) 0.15055(19) 1.13369(16) 0.0273(5) Uani 1 1 d .
C30 C 0.2773(2) 0.23450(19) 1.11365(16) 0.0270(5) Uani 1 1 d .
H30 H 0.3565 0.2647 1.1437 0.032 Uiso 1 1 calc R
C28 C 0.0788(2) 0.1063(2) 1.08925(18) 0.0328(6) Uani 1 1 d .
H28 H 0.0239 0.0507 1.1029 0.039 Uiso 1 1 calc R
C27 C 0.0423(2) 0.1441(2) 1.02551(18) 0.0332(6) Uani 1 1 d .
H27 H -0.0373 0.1136 0.9960 0.040 Uiso 1 1 calc R
C21 C -0.0903(2) 0.4681(2) 0.61047(17) 0.0312(6) Uani 1 1 d .
C20 C -0.1796(3) 0.3737(2) 0.6028(2) 0.0432(7) Uani 1 1 d .
H20 H -0.2482 0.3505 0.5610 0.052 Uiso 1 1 calc R
C18 C -0.0639(3) 0.3497(2) 0.71906(18) 0.0354(6) Uani 1 1 d .
C5 C 0.3912(2) 0.9583(2) 0.10530(16) 0.0286(5) Uani 1 1 d .
C4 C 0.3024(3) 0.8628(2) 0.09647(18) 0.0359(6) Uani 1 1 d .
H4 H 0.2352 0.8386 0.0534 0.043 Uiso 1 1 calc R
O12 O 0.08228(18) 0.25896(15) 0.93914(13) 0.0396(5) Uani 1 1 d .
H8 H 0.1357 0.3100 0.9341 0.048 Uiso 1 1 calc R
O3 O 0.4235(2) 0.78118(16) 0.26789(14) 0.0477(6) Uani 1 1 d .
H2 H 0.4873 0.8088 0.3018 0.057 Uiso 1 1 calc R
O9 O -0.0547(2) 0.28902(17) 0.77006(16) 0.0531(6) Uani 1 1 d .
H7 H 0.0089 0.3168 0.8043 0.064 Uiso 1 1 calc R
N2 N 0.3058(2) 0.99388(17) -0.00844(14) 0.0305(5) Uani 1 1 d .
N14 N -0.1858(2) 0.50148(18) 0.50089(14) 0.0348(5) Uani 1 1 d .
N1 N 0.3906(2) 1.02568(17) 0.05406(14) 0.0305(5) Uani 1 1 d .
N13 N -0.0942(2) 0.53450(18) 0.55827(14) 0.0330(5) Uani 1 1 d .
N19 N 0.2291(2) 0.10511(17) 1.19720(14) 0.0312(5) Uani 1 1 d .
N3 N 0.3981(2) 1.15782(17) -0.04088(14) 0.0302(5) Uani 1 1 d .
N6 N 0.2324(2) 1.04705(18) -0.12394(14) 0.0332(5) Uani 1 1 d .
H1 H 0.1706 0.9928 -0.1452 0.040 Uiso 1 1 calc R
N15 N -0.1026(2) 0.66112(18) 0.45943(14) 0.0346(5) Uani 1 1 d .
N18 N -0.2711(2) 0.54542(19) 0.38442(15) 0.0375(5) Uani 1 1 d .
H18 H -0.3330 0.4902 0.3670 0.045 Uiso 1 1 calc R
N7 N 0.7614(2) 0.62765(17) 0.70183(14) 0.0328(5) Uani 1 1 d .
N20 N 0.3352(2) 0.15075(17) 1.23788(14) 0.0312(5) Uani 1 1 d .
N21 N 0.2985(2) 0.02443(19) 1.32309(15) 0.0373(6) Uani 1 1 d .
C8 C 0.3138(2) 1.06618(19) -0.05567(15) 0.0268(5) Uani 1 1 d .
C24 C -0.1840(2) 0.5699(2) 0.45056(16) 0.0307(6) Uani 1 1 d .
C13 C 0.7247(2) 0.66868(19) 0.63707(16) 0.0286(5) Uani 1 1 d .
C9 C 0.7558(2) 0.79214(19) 0.55301(15) 0.0244(5) Uani 1 1 d .
C32 C 0.3669(2) 0.1058(2) 1.30047(16) 0.0304(6) Uani 1 1 d .
C10 C 0.6368(2) 0.7385(2) 0.50673(17) 0.0305(6) Uani 1 1 d .
C3 C 0.3146(3) 0.8052(2) 0.15118(19) 0.0391(7) Uani 1 1 d .
H3 H 0.2554 0.7420 0.1453 0.047 Uiso 1 1 calc R
C12 C 0.6083(3) 0.6166(2) 0.59096(19) 0.0364(6) Uani 1 1 d .
H12 H 0.5593 0.5577 0.6035 0.044 Uiso 1 1 calc R
C11 C 0.5645(3) 0.6507(2) 0.52709(19) 0.0388(7) Uani 1 1 d .
H11 H 0.4860 0.6151 0.4971 0.047 Uiso 1 1 calc R
C15 C 0.8394(2) 0.88442(19) 0.53375(15) 0.0250(5) Uani 1 1 d .
C14 C 0.7970(2) 0.75612(19) 0.61751(16) 0.0271(5) Uani 1 1 d .
H14 H 0.8751 0.7914 0.6484 0.032 Uiso 1 1 calc R
C16 C 0.8974(3) 0.6287(2) 0.80376(17) 0.0320(6) Uani 1 1 d .
N5 N 0.2677(2) 1.13073(18) -0.15237(14) 0.0337(5) Uani 1 1 d .
N17 N -0.2416(2) 0.62500(19) 0.35100(15) 0.0380(6) Uani 1 1 d .
N4 N 0.3669(2) 1.19652(17) -0.10302(14) 0.0333(5) Uani 1 1 d .
N16 N -0.1410(2) 0.69444(18) 0.39582(15) 0.0378(5) Uani 1 1 d .
N8 N 0.8684(2) 0.67421(17) 0.74028(14) 0.0317(5) Uani 1 1 d .
N24 N 0.4783(2) 0.14723(19) 1.34564(15) 0.0379(6) Uani 1 1 d .
N9 N 0.8239(2) 0.5498(2) 0.82634(16) 0.0406(6) Uani 1 1 d .
N23 N 0.4788(2) 0.0877(2) 1.39851(16) 0.0428(6) Uani 1 1 d .
N22 N 0.3719(2) 0.0148(2) 1.38501(16) 0.0433(6) Uani 1 1 d .
C19 C -0.1668(3) 0.3154(2) 0.6564(2) 0.0452(8) Uani 1 1 d .
H19 H -0.2267 0.2526 0.6512 0.054 Uiso 1 1 calc R
N12 N 1.0084(2) 0.66462(19) 0.84958(16) 0.0399(6) Uani 1 1 d .
N11 N 1.0027(3) 0.6045(2) 0.90241(16) 0.0463(7) Uani 1 1 d .
N10 N 0.8927(3) 0.5362(2) 0.88852(17) 0.0470(7) Uani 1 1 d .
O6 O 0.58862(19) 0.76711(16) 0.44361(14) 0.0433(5) Uani 1 1 d .
H5 H 0.6378 0.8197 0.4376 0.052 Uiso 1 1 calc R
O17 O 0.84984(18) 0.88924(15) 0.31140(12) 0.0386(5) Uani 1 1 d D
O21 O 0.3918(2) 0.46230(19) 0.80203(13) 0.0531(6) Uani 1 1 d D
O13 O 0.92506(18) 1.08163(16) 0.26718(12) 0.0421(5) Uani 1 1 d D
O25 O 0.5916(2) 0.42092(19) 0.78096(17) 0.0579(6) Uani 1 1 d D
O26 O 0.2401(2) 0.7988(2) 0.8724(2) 0.0730(8) Uani 1 1 d D
O24 O 0.0622(3) 0.9080(2) 0.2329(2) 0.0925(11) Uani 1 1 d D
O22 O 0.7590(3) 0.2542(2) 0.2954(2) 0.1007(12) Uani 1 1 d D
O23 O 0.5921(3) 0.3451(2) 0.28946(19) 0.0966(11) Uani 1 1 d D
H10 H 0.9655 1.0549 0.2555 0.116 Uiso 1 1 d RD
H9 H 0.9377 1.1311 0.2502 0.116 Uiso 1 1 d RD
H13 H 0.9683 1.2618 0.4510 0.116 Uiso 1 1 d RD
H15 H 0.8905 1.2494 0.3831 0.116 Uiso 1 1 d RD
H16 H 0.9472 1.0855 0.5801 0.116 Uiso 1 1 d RD
H17 H 0.9792 1.1780 0.5689 0.116 Uiso 1 1 d RD
H24 H 0.8086 0.8826 0.2678 0.116 Uiso 1 1 d RD
H23 H 0.8175 0.8426 0.3325 0.116 Uiso 1 1 d RD
H21 H 0.6331 1.0839 0.4614 0.116 Uiso 1 1 d RD
H25 H 0.6889 1.0622 0.5244 0.116 Uiso 1 1 d RD
H26 H 0.3598 0.7426 0.9085 0.116 Uiso 1 1 d RD
H29 H 0.4709 0.7581 0.9457 0.116 Uiso 1 1 d RD
H31 H 0.5065 0.6637 1.0772 0.116 Uiso 1 1 d RD
H32 H 0.4224 0.6035 1.1104 0.116 Uiso 1 1 d RD
H33 H 0.1759 0.5470 1.0289 0.116 Uiso 1 1 d RD
H34 H 0.1383 0.5873 0.9705 0.116 Uiso 1 1 d RD
H36 H 0.3412 0.4312 0.7620 0.116 Uiso 1 1 d RD
H35 H 0.4549 0.4563 0.8003 0.116 Uiso 1 1 d RD
H37 H 0.7436 0.2798 0.3501 0.116 Uiso 1 1 d RD
H40 H 0.5191 0.3112 0.2882 0.116 Uiso 1 1 d RD
H42 H 0.1334 0.9324 0.2583 0.116 Uiso 1 1 d RD
H41 H 0.0142 0.8975 0.2648 0.116 Uiso 1 1 d RD
H43 H 0.5675 0.4070 0.7313 0.116 Uiso 1 1 d RD
H44 H 0.6638 0.4505 0.7906 0.116 Uiso 1 1 d RD
H45 H 0.2523 0.7817 0.8178 0.116 Uiso 1 1 d RD
H38 H 0.7169 0.1942 0.2963 0.116 Uiso 1 1 d RD
H46 H 0.1633 0.7648 0.8611 0.116 Uiso 1 1 d RD
H39 H 0.6325 0.3139 0.2706 0.116 Uiso 1 1 d RD
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
O5 Eu1 O14 148.05(7) .
O5 Eu1 O4 91.10(6) .
O14 Eu1 O4 85.25(7) .
O5 Eu1 O1 121.68(6) .
O14 Eu1 O1 78.74(7) .
O4 Eu1 O1 138.66(6) .
O5 Eu1 O16 81.10(7) .
O14 Eu1 O16 81.42(7) .
O4 Eu1 O16 139.78(7) .
O1 Eu1 O16 75.06(6) .
O5 Eu1 O15 72.72(7) .
O14 Eu1 O15 75.92(7) .
O4 Eu1 O15 72.60(7) .
O1 Eu1 O15 137.09(7) .
O16 Eu1 O15 67.38(7) .
O5 Eu1 O17 68.97(7) .
O14 Eu1 O17 139.41(7) .
O4 Eu1 O17 75.78(7) .
O1 Eu1 O17 92.21(6) .
O16 Eu1 O17 134.67(7) .
O15 Eu1 O17 129.02(7) .
O5 Eu1 O2 70.75(6) .
O14 Eu1 O2 127.50(6) .
O4 Eu1 O2 142.11(7) .
O1 Eu1 O2 51.42(6) .
O16 Eu1 O2 71.70(7) .
O15 Eu1 O2 128.18(7) .
O17 Eu1 O2 66.76(7) .
O5 Eu1 O13 136.06(7) .
O14 Eu1 O13 72.38(7) .
O4 Eu1 O13 71.64(6) .
O1 Eu1 O13 67.24(6) .
O16 Eu1 O13 137.27(6) .
O15 Eu1 O13 133.46(7) .
O17 Eu1 O13 67.70(7) .
O2 Eu1 O13 98.24(6) .
O5 Eu1 C7 96.67(7) .
O14 Eu1 C7 103.37(7) .
O4 Eu1 C7 147.49(7) .
O1 Eu1 C7 25.46(7) .
O16 Eu1 C7 72.72(7) .
O15 Eu1 C7 139.78(7) .
O17 Eu1 C7 77.71(7) .
O2 Eu1 C7 26.02(7) .
O13 Eu1 C7 81.11(7) .
O11 Eu2 O10 105.40(6) .
O11 Eu2 O21 91.18(8) .
O10 Eu2 O21 69.77(7) .
O11 Eu2 O20 84.05(7) .
O10 Eu2 O20 142.81(7) .
O21 Eu2 O20 147.07(7) .
O11 Eu2 O19 79.19(7) .
O10 Eu2 O19 72.54(7) .
O21 Eu2 O19 136.85(8) .
O20 Eu2 O19 74.22(8) .
O11 Eu2 O18 161.36(7) .
O10 Eu2 O18 75.34(7) .
O21 Eu2 O18 106.19(9) .
O20 Eu2 O18 84.82(7) .
O19 Eu2 O18 83.43(7) .
O11 Eu2 O7 122.97(6) .
O10 Eu2 O7 119.85(6) .
O21 Eu2 O7 75.33(7) .
O20 Eu2 O7 80.09(7) .
O19 Eu2 O7 144.03(7) .
O18 Eu2 O7 69.41(6) .
O11 Eu2 O8 71.01(6) .
O10 Eu2 O8 142.52(7) .
O21 Eu2 O8 72.99(7) .
O20 Eu2 O8 74.66(7) .
O19 Eu2 O8 138.57(7) .
O18 Eu2 O8 120.01(6) .
O7 Eu2 O8 51.98(6) .
O11 Eu2 C23 97.24(7) .
O10 Eu2 C23 135.96(7) .
O21 Eu2 C23 72.54(7) .
O20 Eu2 C23 75.78(7) .
O19 Eu2 C23 149.99(8) .
O18 Eu2 C23 94.44(7) .
O7 Eu2 C23 25.74(7) .
O8 Eu2 C23 26.25(6) .
O11 Eu2 H33 69.3 .
O10 Eu2 H33 140.5 .
O21 Eu2 H33 146.4 .
O20 Eu2 H33 15.4 .
O19 Eu2 H33 68.0 .
O18 Eu2 H33 98.0 .
O7 Eu2 H33 92.2 .
O8 Eu2 H33 74.8 .
C23 Eu2 H33 82.7 .
Eu2 O18 H26 119.0 .
Eu2 O18 H29 116.7 .
H26 O18 H29 111.5 .
Eu2 O20 H33 113.4 .
Eu2 O20 H34 122.6 .
H33 O20 H34 112.1 .
C31 O11 Eu2 142.67(17) .
C31 O10 Eu2 152.04(18) 2_667
C23 O7 Eu2 95.04(15) .
C23 O8 Eu2 93.20(15) .
Eu2 O19 H31 118.4 .
Eu2 O19 H32 131.4 .
H31 O19 H32 110.3 .
C15 O5 Eu1 144.06(17) .
Eu1 O16 H21 123.4 .
Eu1 O16 H25 114.5 .
H21 O16 H25 109.9 .
Eu1 O14 H13 122.4 .
Eu1 O14 H15 126.1 .
H13 O14 H15 111.5 .
C15 O4 Eu1 149.50(19) 2_776
C7 O1 Eu1 98.20(15) .
Eu1 O15 H16 112.7 .
Eu1 O15 H17 117.5 .
H16 O15 H17 114.7 .
C7 O2 Eu1 90.01(16) .
O1 C7 O2 120.1(2) .
O1 C7 C1 120.4(2) .
O2 C7 C1 119.5(2) .
O1 C7 Eu1 56.34(13) .
O2 C7 Eu1 63.97(14) .
C1 C7 Eu1 172.90(18) .
C6 C1 C2 119.0(2) .
C6 C1 C7 120.4(2) .
C2 C1 C7 120.5(2) .
C5 C6 C1 121.0(2) .
C5 C6 H6 119.5 .
C1 C6 H6 119.5 .
O3 C2 C3 118.3(3) .
O3 C2 C1 121.8(2) .
C3 C2 C1 119.9(2) .
O10 C31 O11 124.0(2) 2_667
O10 C31 C25 118.9(2) 2_667
O11 C31 C25 117.0(2) .
C30 C25 C26 118.8(2) .
C30 C25 C31 118.8(2) .
C26 C25 C31 122.4(2) .
O12 C26 C27 118.0(2) .
O12 C26 C25 122.7(2) .
C27 C26 C25 119.3(2) .
C22 C17 C18 118.7(2) .
C22 C17 C23 121.0(2) .
C18 C17 C23 120.3(2) .
O7 C23 O8 119.8(2) .
O7 C23 C17 121.6(2) .
O8 C23 C17 118.6(2) .
O7 C23 Eu2 59.22(13) .
O8 C23 Eu2 60.55(13) .
C17 C23 Eu2 179.16(19) .
C21 C22 C17 120.7(3) .
C21 C22 H22 119.6 .
C17 C22 H22 119.6 .
C30 C29 C28 119.0(2) .
C30 C29 N19 124.2(2) .
C28 C29 N19 116.8(2) .
C25 C30 C29 121.7(2) .
C25 C30 H30 119.2 .
C29 C30 H30 119.2 .
C27 C28 C29 120.3(2) .
C27 C28 H28 119.8 .
C29 C28 H28 119.8 .
C28 C27 C26 120.8(3) .
C28 C27 H27 119.6 .
C26 C27 H27 119.6 .
C22 C21 C20 119.8(3) .
C22 C21 N13 115.2(2) .
C20 C21 N13 125.0(2) .
C19 C20 C21 120.3(3) .
C19 C20 H20 119.8 .
C21 C20 H20 119.8 .
O9 C18 C19 117.9(3) .
O9 C18 C17 121.7(2) .
C19 C18 C17 120.4(3) .
C6 C5 C4 119.7(2) .
C6 C5 N1 114.1(2) .
C4 C5 N1 126.2(2) .
C3 C4 C5 119.9(3) .
C3 C4 H4 120.0 .
C5 C4 H4 120.0 .
C26 O12 H8 109.5 .
C2 O3 H2 109.5 .
C18 O9 H7 109.5 .
N1 N2 C8 111.7(2) .
N13 N14 C24 112.1(2) .
N2 N1 C5 116.1(2) .
N14 N13 C21 114.6(2) .
N20 N19 C29 114.1(2) .
C8 N3 N4 104.6(2) .
C8 N6 N5 104.7(2) .
C8 N6 H1 127.6 .
N5 N6 H1 127.6 .
C24 N15 N16 104.8(2) .
C24 N18 N17 104.8(2) .
C24 N18 H18 127.6 .
N17 N18 H18 127.6 .
N8 N7 C13 115.2(2) .
N19 N20 C32 114.3(2) .
C32 N21 N22 104.2(2) .
N6 C8 N3 111.8(2) .
N6 C8 N2 120.9(2) .
N3 C8 N2 127.3(2) .
N15 C24 N18 111.8(2) .
N15 C24 N14 128.0(2) .
N18 C24 N14 120.2(3) .
C12 C13 C14 119.0(2) .
C12 C13 N7 116.6(2) .
C14 C13 N7 124.4(2) .
C14 C9 C10 118.9(2) .
C14 C9 C15 118.7(2) .
C10 C9 C15 122.4(2) .
N24 C32 N21 112.6(2) .
N24 C32 N20 118.8(2) .
N21 C32 N20 128.6(3) .
O6 C10 C11 117.4(2) .
O6 C10 C9 123.4(2) .
C11 C10 C9 119.2(2) .
C4 C3 C2 120.5(3) .
C4 C3 H3 119.8 .
C2 C3 H3 119.8 .
C11 C12 C13 120.9(3) .
C11 C12 H12 119.6 .
C13 C12 H12 119.6 .
C12 C11 C10 120.6(3) .
C12 C11 H11 119.7 .
C10 C11 H11 119.7 .
O4 C15 O5 122.5(2) 2_776
O4 C15 C9 120.1(2) 2_776
O5 C15 C9 117.4(2) .
C9 C14 C13 121.5(2) .
C9 C14 H14 119.2 .
C13 C14 H14 119.2 .
N9 C16 N12 111.9(2) .
N9 C16 N8 127.3(3) .
N12 C16 N8 120.8(3) .
N4 N5 N6 109.4(2) .
N16 N17 N18 109.4(2) .
N5 N4 N3 109.5(2) .
N17 N16 N15 109.2(2) .
N7 N8 C16 111.6(2) .
C32 N24 N23 104.0(2) .
C16 N9 N10 104.7(3) .
N22 N23 N24 109.7(2) .
N23 N22 N21 109.6(2) .
C20 C19 C18 120.0(3) .
C20 C19 H19 120.0 .
C18 C19 H19 120.0 .
C16 N12 N11 104.5(3) .
N10 N11 N12 109.4(2) .
N11 N10 N9 109.5(2) .
C10 O6 H5 109.5 .
Eu1 O17 H24 104.5 .
Eu1 O17 H23 107.5 .
H24 O17 H23 109.3 .
Eu2 O21 H36 122.4 .
Eu2 O21 H35 123.1 .
H36 O21 H35 114.0 .
Eu1 O13 H10 113.0 .
Eu1 O13 H9 126.7 .
H10 O13 H9 113.8 .
H43 O25 H44 109.6 .
H45 O26 H46 94.6 .
H42 O24 H41 111.3 .
H37 O22 H38 92.2 .
H40 O23 H39 115.4 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O5 2.3620(17) .
Eu1 O14 2.3621(19) .
Eu1 O4 2.3840(18) .
Eu1 O1 2.4268(18) .
Eu1 O16 2.431(2) .
Eu1 O15 2.504(2) .
Eu1 O17 2.588(2) .
Eu1 O2 2.593(2) .
Eu1 O13 2.610(2) .
Eu1 C7 2.886(3) .
Eu2 O11 2.3427(17) .
Eu2 O10 2.3674(18) .
Eu2 O21 2.375(2) .
Eu2 O20 2.393(2) .
Eu2 O19 2.399(2) .
Eu2 O18 2.3993(18) .
Eu2 O7 2.4811(17) .
Eu2 O8 2.5090(19) .
Eu2 C23 2.877(3) .
Eu2 H33 2.8160 .
O18 H26 0.7892 .
O18 H29 0.8090 .
O20 H33 0.8134 .
O20 H34 0.7898 .
O11 C31 1.265(3) .
O10 C31 1.241(3) 2_667
O7 C23 1.254(3) .
O8 C23 1.274(3) .
O19 H31 0.7900 .
O19 H32 0.8193 .
O5 C15 1.264(3) .
O16 H21 0.7949 .
O16 H25 0.8168 .
O14 H13 0.8084 .
O14 H15 0.7863 .
O4 C15 1.255(3) 2_776
O1 C7 1.253(3) .
O15 H16 0.7884 .
O15 H17 0.7872 .
O2 C7 1.266(3) .
C7 C1 1.480(3) .
C1 C6 1.384(3) .
C1 C2 1.400(4) .
C6 C5 1.381(3) .
C6 H6 0.9300 .
C2 O3 1.345(3) .
C2 C3 1.396(4) .
C31 O10 1.241(3) 2_667
C31 C25 1.491(3) .
C25 C30 1.377(3) .
C25 C26 1.410(3) .
C26 O12 1.348(3) .
C26 C27 1.389(4) .
C17 C22 1.388(4) .
C17 C18 1.400(4) .
C17 C23 1.481(3) .
C22 C21 1.384(4) .
C22 H22 0.9300 .
C29 C30 1.384(3) .
C29 C28 1.391(4) .
C29 N19 1.419(3) .
C30 H30 0.9300 .
C28 C27 1.369(4) .
C28 H28 0.9300 .
C27 H27 0.9300 .
C21 C20 1.396(4) .
C21 N13 1.415(3) .
C20 C19 1.364(4) .
C20 H20 0.9300 .
C18 O9 1.349(3) .
C18 C19 1.394(4) .
C5 C4 1.402(4) .
C5 N1 1.409(3) .
C4 C3 1.367(4) .
C4 H4 0.9300 .
O12 H8 0.8200 .
O3 H2 0.8200 .
O9 H7 0.8200 .
N2 N1 1.260(3) .
N2 C8 1.404(3) .
N14 N13 1.255(3) .
N14 C24 1.405(4) .
N19 N20 1.252(3) .
N3 C8 1.330(3) .
N3 N4 1.333(3) .
N6 C8 1.326(3) .
N6 N5 1.335(3) .
N6 H1 0.8600 .
N15 C24 1.322(4) .
N15 N16 1.334(3) .
N18 C24 1.327(3) .
N18 N17 1.329(3) .
N18 H18 0.8600 .
N7 N8 1.251(3) .
N7 C13 1.414(3) .
N20 C32 1.403(3) .
N21 C32 1.329(3) .
N21 N22 1.332(3) .
C13 C12 1.386(4) .
C13 C14 1.386(3) .
C9 C14 1.384(3) .
C9 C10 1.412(3) .
C9 C15 1.483(3) .
C32 N24 1.325(4) .
C10 O6 1.335(3) .
C10 C11 1.395(4) .
C3 H3 0.9300 .
C12 C11 1.371(4) .
C12 H12 0.9300 .
C11 H11 0.9300 .
C15 O4 1.255(3) 2_776
C14 H14 0.9300 .
C16 N9 1.324(4) .
C16 N12 1.326(4) .
C16 N8 1.410(3) .
N5 N4 1.311(3) .
N17 N16 1.312(3) .
N24 N23 1.337(3) .
N9 N10 1.330(3) .
N23 N22 1.311(4) .
C19 H19 0.9300 .
N12 N11 1.333(3) .
N11 N10 1.309(4) .
O6 H5 0.8200 .
O17 H24 0.7983 .
O17 H23 0.8139 .
O21 H36 0.7928 .
O21 H35 0.7880 .
O13 H10 0.7377 .
O13 H9 0.7948 .
O25 H43 0.8047 .
O25 H44 0.7986 .
O26 H45 0.9322 .
O26 H46 0.8551 .
O24 H42 0.8261 .
O24 H41 0.8102 .
O22 H37 0.9756 .
O22 H38 0.8515 .
O23 H40 0.8324 .
O23 H39 0.8186 .
