#------------------------------------------------------------------------------
#$Date: 2016-03-25 22:48:39 +0200 (Fri, 25 Mar 2016) $
#$Revision: 180016 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/10/7031047.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7031047
loop_
_publ_author_name
'Rahanyan, Nelli'
'Duttwyler, Simon'
'Linden, Anthony'
'Baldridge, Kim K.'
'Siegel, Jay S.'
_publ_section_title
;
 Cu(i) and Ag(i) complexes of 7,10-bis-N-heterocycle-diazafluoranthenes:
 programmed molecular grids?
;
_journal_issue                   28
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11027
_journal_page_last               11038
_journal_paper_doi               10.1039/c4dt01460j
_journal_volume                  43
_journal_year                    2014
_chemical_formula_moiety
'C128 H120 Ag4 N16 4+, 4(F6 P -), 3(C6 H6), 4(C2 H3 N)'
_chemical_formula_sum            'C154 H150 Ag4 F24 N20 P4'
_chemical_formula_weight         3292.34
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     heavy
_atom_sites_solution_secondary   difmap
_audit_creation_date             09-02-06
_audit_creation_method           SHELXL-97
_cell_angle_alpha                102.2393(6)
_cell_angle_beta                 106.5617(7)
_cell_angle_gamma                112.3483(7)
_cell_formula_units_Z            1
_cell_length_a                   13.9336(2)
_cell_length_b                   16.3976(2)
_cell_length_c                   19.5316(3)
_cell_measurement_reflns_used    63153
_cell_measurement_temperature    160(1)
_cell_measurement_theta_max      30.0
_cell_measurement_theta_min      2.0
_cell_volume                     3688.74(10)
_computing_cell_refinement       'DENZO-SMN (Otwinowski & Minor, 1997)'
_computing_data_collection       'COLLECT (Nonius, 2000)'
_computing_data_reduction
'DENZO-SMN and SCALEPACK (Otwinowski & Minor, 1997)'
_computing_molecular_graphics    'ORTEPII (Johnson, 1976)'
_computing_publication_material  'SHELXL97 and PLATON (Spek, 2006)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'DIRDIF94 (Beurskens et al., 1994)'
_diffrn_ambient_temperature      160(1)
_diffrn_detector                 '65 mm CCD camera on \k goniostat'
_diffrn_detector_area_resol_mean 9
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type
'Nonius KappaCCD area-detector diffractometer'
_diffrn_measurement_method       'φ and ω scans with κ offsets'
_diffrn_radiation_monochromator  'horizontally mounted graphite crystal'
_diffrn_radiation_source         'Nonius FR590 sealed tube generator'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0643
_diffrn_reflns_av_sigmaI/netI    0.0580
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            100836
_diffrn_reflns_theta_full        30.06
_diffrn_reflns_theta_max         30.06
_diffrn_reflns_theta_min         2.12
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.654
_exptl_absorpt_correction_T_max  0.920
_exptl_absorpt_correction_T_min  0.836
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(Blessing, 1995)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.482
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1678
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.334
_refine_diff_density_min         -0.872
_refine_diff_density_rms         0.098
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1097
_refine_ls_number_reflns         21456
_refine_ls_number_restraints     816
_refine_ls_restrained_S_all      1.156
_refine_ls_R_factor_all          0.0886
_refine_ls_R_factor_gt           0.0520
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0532P)²+5.7526P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1158
_refine_ls_wR_factor_ref         0.1328
_reflns_number_gt                14801
_reflns_number_total             21456
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c4dt01460j1.cif
_cod_data_source_block           V
_cod_depositor_comments
'Adding full bibliography for 7031040--7031051.cif.'
_cod_original_cell_volume        3688.74(9)
_cod_original_sg_symbol_H-M      'P -1         '
_cod_database_code               7031047
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag -0.23067(2) -0.156302(19) 0.361221(15) 0.02808(7) Uani 1 1 d . . .
Ag2 Ag -0.01106(2) 0.076384(19) 0.361501(15) 0.02871(8) Uani 1 1 d . . .
N1 N -0.0374(2) -0.09937(19) 0.42602(15) 0.0211(5) Uani 1 1 d . . .
N2 N 0.0390(2) -0.01873(19) 0.42566(15) 0.0221(6) Uani 1 1 d . . .
N3 N 0.2931(2) 0.1771(2) 0.53309(16) 0.0239(6) Uani 1 1 d . . .
N4 N -0.0954(2) -0.2318(2) 0.53515(16) 0.0241(6) Uani 1 1 d . . .
N5 N -0.1959(2) -0.0127(2) 0.26206(16) 0.0233(6) Uani 1 1 d . . .
N6 N -0.2733(2) -0.0911(2) 0.26299(15) 0.0236(6) Uani 1 1 d . . .
N7 N -0.3954(2) -0.2758(2) 0.25835(16) 0.0266(6) Uani 1 1 d . . .
N8 N -0.0060(2) 0.1248(2) 0.25537(16) 0.0278(6) Uani 1 1 d . . .
C1 C 0.1492(3) 0.0166(2) 0.46854(17) 0.0203(6) Uani 1 1 d . . .
C2 C 0.1906(3) -0.0267(2) 0.51531(18) 0.0222(6) Uani 1 1 d . . .
C3 C 0.3048(3) -0.0066(2) 0.5639(2) 0.0247(7) Uani 1 1 d . . .
C4 C 0.4140(3) 0.0614(3) 0.5840(2) 0.0304(8) Uani 1 1 d . . .
H4 H 0.4268 0.1121 0.5655 0.036 Uiso 1 1 calc R . .
C5 C 0.5070(3) 0.0560(3) 0.6319(3) 0.0385(9) Uani 1 1 d . A .
C6 C 0.4881(3) -0.0187(3) 0.6585(3) 0.0444(11) Uani 1 1 d . . .
H6 H 0.5512 -0.0215 0.6909 0.053 Uiso 1 1 calc R . .
C7 C 0.3768(3) -0.0908(3) 0.6381(2) 0.0367(9) Uani 1 1 d . . .
C8 C 0.3453(4) -0.1713(3) 0.6593(3) 0.0474(11) Uani 1 1 d . . .
H8 H 0.4029 -0.1803 0.6914 0.057 Uiso 1 1 calc R . .
C9 C 0.2330(4) -0.2372(3) 0.6344(3) 0.0414(10) Uani 1 1 d . B .
C10 C 0.1455(3) -0.2251(3) 0.5862(2) 0.0317(8) Uani 1 1 d . . .
H10 H 0.0683 -0.2706 0.5689 0.038 Uiso 1 1 calc R . .
C11 C 0.1730(3) -0.1472(2) 0.5646(2) 0.0256(7) Uani 1 1 d . . .
C12 C 0.1109(3) -0.1115(2) 0.51544(18) 0.0225(6) Uani 1 1 d . . .
C13 C -0.0030(3) -0.1446(2) 0.46917(18) 0.0211(6) Uani 1 1 d . . .
C14 C 0.2884(3) -0.0811(2) 0.5913(2) 0.0269(7) Uani 1 1 d . . .
C15 C 0.2295(3) 0.1050(2) 0.46547(19) 0.0222(6) Uani 1 1 d . . .
C16 C 0.3738(3) 0.2560(3) 0.5341(2) 0.0299(8) Uani 1 1 d . . .
H16 H 0.4194 0.3082 0.5812 0.036 Uiso 1 1 calc R . .
C17 C 0.3938(3) 0.2648(3) 0.4700(2) 0.0366(9) Uani 1 1 d . . .
H17 H 0.4529 0.3213 0.4735 0.044 Uiso 1 1 calc R . .
C18 C 0.3262(4) 0.1903(3) 0.4009(2) 0.0379(9) Uani 1 1 d . . .
H18 H 0.3380 0.1949 0.3560 0.046 Uiso 1 1 calc R . .
C19 C 0.2412(3) 0.1088(3) 0.3977(2) 0.0299(8) Uani 1 1 d . . .
H19 H 0.1923 0.0569 0.3506 0.036 Uiso 1 1 calc R . .
C20 C 0.6283(3) 0.1335(3) 0.6556(3) 0.0518(12) Uani 1 1 d D . .
C21A C 0.7037(6) 0.1548(5) 0.7388(3) 0.089(3) Uani 0.777(7) 1 d PDU A 1
H211 H 0.7107 0.0985 0.7427 0.133 Uiso 0.777(7) 1 calc PR A 1
H212 H 0.6691 0.1720 0.7729 0.133 Uiso 0.777(7) 1 calc PR A 1
H213 H 0.7790 0.2073 0.7538 0.133 Uiso 0.777(7) 1 calc PR A 1
C22A C 0.6770(6) 0.1000(5) 0.6034(4) 0.100(3) Uani 0.777(7) 1 d PDU A 1
H221 H 0.6707 0.0384 0.6036 0.150 Uiso 0.777(7) 1 calc PR A 1
H222 H 0.7571 0.1457 0.6212 0.150 Uiso 0.777(7) 1 calc PR A 1
H223 H 0.6352 0.0938 0.5513 0.150 Uiso 0.777(7) 1 calc PR A 1
C23A C 0.6304(5) 0.2264(4) 0.6527(4) 0.076(2) Uani 0.777(7) 1 d PDU A 1
H231 H 0.7091 0.2770 0.6765 0.113 Uiso 0.777(7) 1 calc PR A 1
H232 H 0.5875 0.2420 0.6806 0.113 Uiso 0.777(7) 1 calc PR A 1
H233 H 0.5958 0.2199 0.5993 0.113 Uiso 0.777(7) 1 calc PR A 1
C21B C 0.6874(18) 0.2204(10) 0.7279(8) 0.088(4) Uani 0.223(7) 1 d PDU A 2
H214 H 0.7637 0.2611 0.7327 0.132 Uiso 0.223(7) 1 calc PR A 2
H215 H 0.6930 0.2011 0.7725 0.132 Uiso 0.223(7) 1 calc PR A 2
H216 H 0.6437 0.2553 0.7253 0.132 Uiso 0.223(7) 1 calc PR A 2
C22B C 0.7011(17) 0.0830(15) 0.6591(14) 0.108(6) Uani 0.223(7) 1 d PDU A 2
H224 H 0.6659 0.0283 0.6115 0.162 Uiso 0.223(7) 1 calc PR A 2
H225 H 0.7070 0.0616 0.7026 0.162 Uiso 0.223(7) 1 calc PR A 2
H226 H 0.7771 0.1267 0.6655 0.162 Uiso 0.223(7) 1 calc PR A 2
C23B C 0.6232(18) 0.1660(15) 0.5871(8) 0.088(4) Uani 0.223(7) 1 d PDU A 2
H234 H 0.6981 0.2167 0.5983 0.132 Uiso 0.223(7) 1 calc PR A 2
H235 H 0.5675 0.1894 0.5778 0.132 Uiso 0.223(7) 1 calc PR A 2
H236 H 0.6009 0.1126 0.5416 0.132 Uiso 0.223(7) 1 calc PR A 2
C24 C 0.2006(4) -0.3224(3) 0.6594(3) 0.0561(13) Uani 1 1 d D . .
C25A C 0.3027(6) -0.3365(7) 0.6967(6) 0.083(3) Uani 0.574(6) 1 d PDU B 1
H251 H 0.3535 -0.2850 0.7463 0.125 Uiso 0.574(6) 1 calc PR B 1
H252 H 0.3435 -0.3366 0.6633 0.125 Uiso 0.574(6) 1 calc PR B 1
H253 H 0.2765 -0.3970 0.7044 0.125 Uiso 0.574(6) 1 calc PR B 1
C26A C 0.1394(8) -0.3182(7) 0.7107(5) 0.081(2) Uani 0.574(6) 1 d PDU B 1
H261 H 0.0675 -0.3201 0.6827 0.122 Uiso 0.574(6) 1 calc PR B 1
H262 H 0.1864 -0.2594 0.7555 0.122 Uiso 0.574(6) 1 calc PR B 1
H263 H 0.1242 -0.3724 0.7274 0.122 Uiso 0.574(6) 1 calc PR B 1
C27A C 0.1202(8) -0.4115(5) 0.5858(4) 0.088(3) Uani 0.574(6) 1 d PDU B 1
H271 H 0.0999 -0.4681 0.5994 0.131 Uiso 0.574(6) 1 calc PR B 1
H272 H 0.1587 -0.4150 0.5512 0.131 Uiso 0.574(6) 1 calc PR B 1
H273 H 0.0514 -0.4077 0.5602 0.131 Uiso 0.574(6) 1 calc PR B 1
C25B C 0.2649(10) -0.2804(8) 0.7480(4) 0.084(3) Uani 0.426(6) 1 d PDU B 2
H254 H 0.2504 -0.2287 0.7692 0.126 Uiso 0.426(6) 1 calc PR B 2
H255 H 0.3465 -0.2561 0.7616 0.126 Uiso 0.426(6) 1 calc PR B 2
H256 H 0.2384 -0.3298 0.7689 0.126 Uiso 0.426(6) 1 calc PR B 2
C26B C 0.0742(5) -0.3706(8) 0.6443(7) 0.085(3) Uani 0.426(6) 1 d PDU B 2
H264 H 0.0581 -0.4222 0.6640 0.127 Uiso 0.426(6) 1 calc PR B 2
H265 H 0.0283 -0.3960 0.5890 0.127 Uiso 0.426(6) 1 calc PR B 2
H266 H 0.0556 -0.3243 0.6701 0.127 Uiso 0.426(6) 1 calc PR B 2
C27B C 0.2323(11) -0.3958(7) 0.6285(7) 0.087(3) Uani 0.426(6) 1 d PDU B 2
H274 H 0.2040 -0.4485 0.6459 0.131 Uiso 0.426(6) 1 calc PR B 2
H275 H 0.3151 -0.3677 0.6471 0.131 Uiso 0.426(6) 1 calc PR B 2
H276 H 0.1986 -0.4190 0.5724 0.131 Uiso 0.426(6) 1 calc PR B 2
C28 C -0.0920(3) -0.2328(2) 0.46665(19) 0.0225(6) Uani 1 1 d . . .
C29 C -0.1707(3) -0.3117(3) 0.5369(2) 0.0310(8) Uani 1 1 d . . .
H29 H -0.1741 -0.3125 0.5846 0.037 Uiso 1 1 calc R . .
C30 C -0.2431(3) -0.3924(3) 0.4725(2) 0.0363(9) Uani 1 1 d . . .
H30 H -0.2951 -0.4473 0.4762 0.044 Uiso 1 1 calc R . .
C31 C -0.2390(3) -0.3923(3) 0.4028(2) 0.0349(9) Uani 1 1 d . . .
H31 H -0.2881 -0.4471 0.3579 0.042 Uiso 1 1 calc R . .
C32 C -0.1621(3) -0.3109(2) 0.3993(2) 0.0281(7) Uani 1 1 d . . .
H32 H -0.1577 -0.3087 0.3521 0.034 Uiso 1 1 calc R . .
C33 C -0.3551(3) -0.1616(2) 0.19732(18) 0.0220(6) Uani 1 1 d . . .
C34 C -0.3566(3) -0.1583(2) 0.12618(18) 0.0230(7) Uani 1 1 d . . .
C35 C -0.4233(3) -0.2285(2) 0.04692(18) 0.0241(7) Uani 1 1 d . . .
C36 C -0.5094(3) -0.3207(2) 0.0117(2) 0.0271(7) Uani 1 1 d . . .
H36 H -0.5398 -0.3534 0.0414 0.033 Uiso 1 1 calc R . .
C37 C -0.5527(3) -0.3669(2) -0.0690(2) 0.0296(8) Uani 1 1 d . C .
C38 C -0.5052(3) -0.3210(3) -0.1120(2) 0.0294(8) Uani 1 1 d . . .
H38 H -0.5342 -0.3527 -0.1657 0.035 Uiso 1 1 calc R . .
C39 C -0.4134(3) -0.2269(3) -0.07714(19) 0.0267(7) Uani 1 1 d . . .
C40 C -0.3555(3) -0.1731(3) -0.11388(19) 0.0293(8) Uani 1 1 d . . .
H40 H -0.3792 -0.1992 -0.1677 0.035 Uiso 1 1 calc R . .
C41 C -0.2650(3) -0.0831(3) -0.07290(19) 0.0276(7) Uani 1 1 d . D .
C42 C -0.2287(3) -0.0430(2) 0.00747(19) 0.0254(7) Uani 1 1 d . . .
H42 H -0.1651 0.0180 0.0356 0.030 Uiso 1 1 calc R . .
C43 C -0.2853(3) -0.0922(2) 0.04494(18) 0.0230(7) Uani 1 1 d . . .
C44 C -0.2745(3) -0.0764(2) 0.12460(18) 0.0220(6) Uani 1 1 d . . .
C45 C -0.1977(3) -0.0027(2) 0.19481(19) 0.0228(6) Uani 1 1 d . . .
C46 C -0.3765(3) -0.1838(2) 0.00178(19) 0.0242(7) Uani 1 1 d . . .
C47 C -0.4382(3) -0.2437(2) 0.20587(19) 0.0233(7) Uani 1 1 d . . .
C48 C -0.4676(3) -0.3555(3) 0.2621(2) 0.0309(8) Uani 1 1 d . . .
H48 H -0.4379 -0.3802 0.2978 0.037 Uiso 1 1 calc R . .
C49 C -0.5823(3) -0.4031(3) 0.2170(2) 0.0346(8) Uani 1 1 d . . .
H49 H -0.6301 -0.4602 0.2204 0.042 Uiso 1 1 calc R . .
C50 C -0.6264(3) -0.3660(3) 0.1666(2) 0.0336(8) Uani 1 1 d . . .
H50 H -0.7056 -0.3957 0.1364 0.040 Uiso 1 1 calc R . .
C51 C -0.5534(3) -0.2848(3) 0.1608(2) 0.0283(7) Uani 1 1 d . . .
H51 H -0.5817 -0.2579 0.1267 0.034 Uiso 1 1 calc R . .
C52 C -0.6533(3) -0.4679(2) -0.10648(18) 0.0346(9) Uani 1 1 d D . .
C53A C -0.6192(7) -0.5348(5) -0.0748(4) 0.066(2) Uani 0.574(5) 1 d PDU C 1
H531 H -0.6843 -0.5983 -0.0977 0.099 Uiso 0.574(5) 1 calc PR C 1
H532 H -0.5949 -0.5120 -0.0190 0.099 Uiso 0.574(5) 1 calc PR C 1
H533 H -0.5567 -0.5369 -0.0872 0.099 Uiso 0.574(5) 1 calc PR C 1
C54A C -0.6957(6) -0.5086(5) -0.1937(3) 0.0507(19) Uani 0.574(5) 1 d PDU C 1
H541 H -0.6322 -0.5049 -0.2075 0.076 Uiso 0.574(5) 1 calc PR C 1
H542 H -0.7282 -0.4721 -0.2163 0.076 Uiso 0.574(5) 1 calc PR C 1
H543 H -0.7540 -0.5748 -0.2133 0.076 Uiso 0.574(5) 1 calc PR C 1
C55A C -0.7513(5) -0.4665(6) -0.0875(4) 0.067(2) Uani 0.574(5) 1 d PDU C 1
H551 H -0.8168 -0.5299 -0.1127 0.101 Uiso 0.574(5) 1 calc PR C 1
H552 H -0.7718 -0.4217 -0.1056 0.101 Uiso 0.574(5) 1 calc PR C 1
H553 H -0.7285 -0.4471 -0.0319 0.101 Uiso 0.574(5) 1 calc PR C 1
C53B C -0.6902(8) -0.5084(6) -0.0494(4) 0.056(2) Uani 0.426(5) 1 d PDU C 2
H534 H -0.7493 -0.5744 -0.0765 0.084 Uiso 0.426(5) 1 calc PR C 2
H535 H -0.7201 -0.4715 -0.0245 0.084 Uiso 0.426(5) 1 calc PR C 2
H536 H -0.6248 -0.5053 -0.0107 0.084 Uiso 0.426(5) 1 calc PR C 2
C54B C -0.6213(8) -0.5332(6) -0.1516(5) 0.060(3) Uani 0.426(5) 1 d PDU C 2
H544 H -0.6866 -0.5966 -0.1782 0.091 Uiso 0.426(5) 1 calc PR C 2
H545 H -0.5578 -0.5365 -0.1165 0.091 Uiso 0.426(5) 1 calc PR C 2
H546 H -0.5989 -0.5088 -0.1893 0.091 Uiso 0.426(5) 1 calc PR C 2
C55B C -0.7536(7) -0.4653(8) -0.1615(5) 0.068(3) Uani 0.426(5) 1 d PDU C 2
H554 H -0.7302 -0.4358 -0.1966 0.102 Uiso 0.426(5) 1 calc PR C 2
H555 H -0.7797 -0.4285 -0.1323 0.102 Uiso 0.426(5) 1 calc PR C 2
H556 H -0.8154 -0.5299 -0.1908 0.102 Uiso 0.426(5) 1 calc PR C 2
C56 C -0.2020(3) -0.0251(2) -0.11307(17) 0.0323(8) Uani 1 1 d D . .
C57A C -0.2929(5) -0.0303(6) -0.1830(4) 0.052(2) Uani 0.533(6) 1 d PDU D 1
H571 H -0.3345 0.0003 -0.1657 0.077 Uiso 0.533(6) 1 calc PR D 1
H572 H -0.3458 -0.0966 -0.2154 0.077 Uiso 0.533(6) 1 calc PR D 1
H573 H -0.2565 0.0022 -0.2123 0.077 Uiso 0.533(6) 1 calc PR D 1
C58A C -0.1403(6) -0.0735(5) -0.1427(4) 0.048(2) Uani 0.533(6) 1 d PDU D 1
H581 H -0.1077 -0.0425 -0.1742 0.072 Uiso 0.533(6) 1 calc PR D 1
H582 H -0.1939 -0.1402 -0.1737 0.072 Uiso 0.533(6) 1 calc PR D 1
H583 H -0.0794 -0.0691 -0.0993 0.072 Uiso 0.533(6) 1 calc PR D 1
C59A C -0.1206(6) 0.0770(3) -0.0642(4) 0.051(2) Uani 0.533(6) 1 d PDU D 1
H591 H -0.0885 0.1097 -0.0951 0.077 Uiso 0.533(6) 1 calc PR D 1
H592 H -0.0593 0.0810 -0.0214 0.077 Uiso 0.533(6) 1 calc PR D 1
H593 H -0.1608 0.1070 -0.0443 0.077 Uiso 0.533(6) 1 calc PR D 1
C57B C -0.2541(7) -0.0670(6) -0.1999(3) 0.048(2) Uani 0.467(6) 1 d PDU D 2
H574 H -0.3292 -0.0707 -0.2194 0.072 Uiso 0.467(6) 1 calc PR D 2
H575 H -0.2615 -0.1306 -0.2168 0.072 Uiso 0.467(6) 1 calc PR D 2
H576 H -0.2052 -0.0269 -0.2196 0.072 Uiso 0.467(6) 1 calc PR D 2
C58B C -0.0794(5) -0.0103(7) -0.0850(5) 0.051(2) Uani 0.467(6) 1 d PDU D 2
H584 H -0.0384 0.0277 -0.1097 0.077 Uiso 0.467(6) 1 calc PR D 2
H585 H -0.0805 -0.0718 -0.0981 0.077 Uiso 0.467(6) 1 calc PR D 2
H586 H -0.0413 0.0227 -0.0293 0.077 Uiso 0.467(6) 1 calc PR D 2
C59B C -0.1934(8) 0.0737(4) -0.0886(5) 0.054(3) Uani 0.467(6) 1 d PDU D 2
H594 H -0.1433 0.1083 -0.0341 0.080 Uiso 0.467(6) 1 calc PR D 2
H595 H -0.2690 0.0675 -0.0971 0.080 Uiso 0.467(6) 1 calc PR D 2
H596 H -0.1625 0.1082 -0.1189 0.080 Uiso 0.467(6) 1 calc PR D 2
C60 C -0.1109(3) 0.0893(2) 0.20125(18) 0.0234(7) Uani 1 1 d . . .
C61 C 0.0755(3) 0.2049(3) 0.2583(2) 0.0361(9) Uani 1 1 d . . .
H61 H 0.1506 0.2293 0.2950 0.043 Uiso 1 1 calc R . .
C62 C 0.0557(4) 0.2534(3) 0.2107(2) 0.0379(9) Uani 1 1 d . . .
H62 H 0.1161 0.3089 0.2141 0.046 Uiso 1 1 calc R . .
C63 C -0.0534(3) 0.2196(3) 0.1581(2) 0.0343(8) Uani 1 1 d . . .
H63 H -0.0702 0.2530 0.1262 0.041 Uiso 1 1 calc R . .
C64 C -0.1383(3) 0.1359(2) 0.1528(2) 0.0280(7) Uani 1 1 d . . .
H64 H -0.2140 0.1107 0.1166 0.034 Uiso 1 1 calc R . .
P1 P 0.42215(8) 0.40732(7) 0.32473(6) 0.0305(2) Uani 1 1 d . . .
F1 F 0.5080(2) 0.43425(19) 0.28380(15) 0.0521(7) Uani 1 1 d . . .
F2 F 0.3361(2) 0.38060(17) 0.36552(15) 0.0452(6) Uani 1 1 d . . .
F3 F 0.3839(3) 0.29762(17) 0.28636(16) 0.0615(8) Uani 1 1 d . . .
F4 F 0.4611(2) 0.51663(17) 0.36316(16) 0.0525(7) Uani 1 1 d . . .
F5 F 0.3247(2) 0.3994(2) 0.25268(16) 0.0649(9) Uani 1 1 d . . .
F6 F 0.5193(2) 0.4142(2) 0.39623(15) 0.0522(7) Uani 1 1 d . . .
P2 P 0.04907(9) 0.19321(7) 0.78435(6) 0.0356(2) Uani 1 1 d . . .
F7 F 0.1532(4) 0.2235(4) 0.7624(3) 0.136(2) Uani 1 1 d . . .
F8 F -0.0554(4) 0.1651(4) 0.8052(3) 0.1159(16) Uani 1 1 d . . .
F9 F 0.0292(5) 0.0910(3) 0.7531(3) 0.1293(19) Uani 1 1 d . . .
F10 F 0.0677(4) 0.2974(3) 0.8119(3) 0.1250(18) Uani 1 1 d . . .
F11 F -0.0262(4) 0.1800(4) 0.7012(2) 0.1136(17) Uani 1 1 d . . .
F12 F 0.1267(5) 0.2085(5) 0.8649(2) 0.161(3) Uani 1 1 d . . .
N9 N 0.7899(7) 0.2883(6) 0.9697(5) 0.120(3) Uani 1 1 d . . .
C65 C 0.8544(7) 0.3246(6) 0.9462(4) 0.088(2) Uani 1 1 d . . .
C66 C 0.9348(7) 0.3702(6) 0.9159(4) 0.098(2) Uani 1 1 d . . .
H661 H 0.9034 0.3986 0.8823 0.147 Uiso 1 1 calc R . .
H662 H 0.9495 0.3233 0.8867 0.147 Uiso 1 1 calc R . .
H663 H 1.0059 0.4196 0.9583 0.147 Uiso 1 1 calc R . .
N10 N 0.1274(5) 0.4148(4) 0.0906(3) 0.0803(15) Uani 1 1 d . . .
C67 C 0.1622(5) 0.3658(4) 0.0730(3) 0.0588(13) Uani 1 1 d . . .
C68 C 0.2086(8) 0.3053(6) 0.0512(4) 0.101(3) Uani 1 1 d . . .
H681 H 0.1697 0.2706 -0.0043 0.152 Uiso 1 1 calc R . .
H682 H 0.1980 0.2605 0.0779 0.152 Uiso 1 1 calc R . .
H683 H 0.2897 0.3436 0.0650 0.152 Uiso 1 1 calc R . .
C69A C 0.8019(9) 0.4060(10) 0.5871(5) 0.074(2) Uani 0.472(9) 1 d PGU E 1
H69A H 0.7561 0.3924 0.5354 0.089 Uiso 0.472(9) 1 calc PR E 1
C70A C 0.8774(12) 0.3696(7) 0.6030(7) 0.073(2) Uani 0.472(9) 1 d PGU E 1
H70A H 0.8832 0.3310 0.5623 0.087 Uiso 0.472(9) 1 calc PR E 1
C71A C 0.9443(9) 0.3895(9) 0.6785(10) 0.069(2) Uani 0.472(9) 1 d PGU E 1
H71A H 0.9959 0.3646 0.6894 0.082 Uiso 0.472(9) 1 calc PR E 1
C72A C 0.9357(8) 0.4460(9) 0.7381(5) 0.071(3) Uani 0.472(9) 1 d PGU E 1
H72A H 0.9814 0.4596 0.7898 0.085 Uiso 0.472(9) 1 calc PR E 1
C73A C 0.8602(12) 0.4824(7) 0.7222(7) 0.073(2) Uani 0.472(9) 1 d PGU E 1
H73A H 0.8543 0.5210 0.7629 0.088 Uiso 0.472(9) 1 calc PR E 1
C74A C 0.7933(9) 0.4625(9) 0.6466(9) 0.074(2) Uani 0.472(9) 1 d PGU E 1
H74A H 0.7417 0.4874 0.6357 0.089 Uiso 0.472(9) 1 calc PR E 1
C69B C 0.7787(7) 0.4247(8) 0.6020(7) 0.077(2) Uani 0.528(9) 1 d PGU E 2
H69B H 0.7214 0.4288 0.5646 0.093 Uiso 0.528(9) 1 calc PR E 2
C70B C 0.8231(10) 0.3660(7) 0.5795(4) 0.074(2) Uani 0.528(9) 1 d PGU E 2
H70B H 0.7962 0.3299 0.5268 0.089 Uiso 0.528(9) 1 calc PR E 2
C71B C 0.9069(9) 0.3600(6) 0.6341(8) 0.070(2) Uani 0.528(9) 1 d PGU E 2
H71B H 0.9372 0.3198 0.6188 0.083 Uiso 0.528(9) 1 calc PR E 2
C72B C 0.9462(7) 0.4128(8) 0.7112(7) 0.069(2) Uani 0.528(9) 1 d PGU E 2
H72B H 1.0035 0.4087 0.7485 0.083 Uiso 0.528(9) 1 calc PR E 2
C73B C 0.9018(10) 0.4715(7) 0.7337(4) 0.072(2) Uani 0.528(9) 1 d PGU E 2
H73B H 0.9287 0.5076 0.7863 0.087 Uiso 0.528(9) 1 calc PR E 2
C74B C 0.8180(9) 0.4775(6) 0.6790(8) 0.075(2) Uani 0.528(9) 1 d PGU E 2
H74B H 0.7877 0.5176 0.6944 0.090 Uiso 0.528(9) 1 calc PR E 2
C75 C 0.4537(9) -0.0564(11) 0.0375(9) 0.116(3) Uani 1 1 d . . .
H75 H 0.4216 -0.0954 0.0631 0.140 Uiso 1 1 calc R . .
C76 C 0.4366(7) -0.0950(8) -0.0373(9) 0.120(3) Uani 1 1 d . . .
H76 H 0.3926 -0.1615 -0.0635 0.144 Uiso 1 1 calc R . .
C77 C 0.4813(10) -0.0402(13) -0.0747(7) 0.126(4) Uani 1 1 d . . .
H77 H 0.4677 -0.0684 -0.1265 0.151 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_number_in_cell
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 154 0.0033 0.0016
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
H H 150 0.0000 0.0000
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
Ag Ag 4 -0.8971 1.1015
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
F F 24 0.0171 0.0103
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
N N 20 0.0061 0.0033
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
P P 4 0.1023 0.0942
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ag1 N7 145.30(10) . .
N1 Ag1 N6 112.31(9) . .
N7 Ag1 N6 72.75(10) . .
N1 Ag1 N3 99.74(9) . 2_556
N7 Ag1 N3 98.54(9) . 2_556
N6 Ag1 N3 134.79(9) . 2_556
N5 Ag2 N2 111.22(9) . .
N5 Ag2 N8 72.45(10) . .
N2 Ag2 N8 142.10(10) . .
N5 Ag2 N4 135.81(10) . 2_556
N2 Ag2 N4 101.35(9) . 2_556
N8 Ag2 N4 99.44(10) . 2_556
C13 N1 N2 120.2(3) . .
C13 N1 Ag1 118.2(2) . .
N2 N1 Ag1 121.4(2) . .
C1 N2 N1 120.1(3) . .
C1 N2 Ag2 115.8(2) . .
N1 N2 Ag2 123.8(2) . .
C15 N3 C16 116.8(3) . .
C15 N3 Ag1 115.5(2) . 2_556
C16 N3 Ag1 127.1(2) . 2_556
C29 N4 C28 117.1(3) . .
C29 N4 Ag2 126.0(2) . 2_556
C28 N4 Ag2 115.8(2) . 2_556
N6 N5 C45 120.5(3) . .
N6 N5 Ag2 121.5(2) . .
C45 N5 Ag2 112.1(2) . .
N5 N6 C33 121.0(3) . .
N5 N6 Ag1 122.4(2) . .
C33 N6 Ag1 109.4(2) . .
C47 N7 C48 117.5(3) . .
C47 N7 Ag1 112.5(2) . .
C48 N7 Ag1 124.6(2) . .
C60 N8 C61 117.5(3) . .
C60 N8 Ag2 111.3(2) . .
C61 N8 Ag2 125.6(2) . .
N2 C1 C2 122.5(3) . .
N2 C1 C15 117.8(3) . .
C2 C1 C15 119.6(3) . .
C1 C2 C12 117.5(3) . .
C1 C2 C3 133.7(3) . .
C12 C2 C3 108.7(3) . .
C4 C3 C14 118.8(3) . .
C4 C3 C2 136.0(3) . .
C14 C3 C2 105.1(3) . .
C3 C4 C5 120.1(4) . .
C3 C4 H4 119.9 . .
C5 C4 H4 119.9 . .
C6 C5 C4 119.9(4) . .
C6 C5 C20 120.3(4) . .
C4 C5 C20 119.8(4) . .
C5 C6 C7 121.6(4) . .
C5 C6 H6 119.2 . .
C7 C6 H6 119.2 . .
C14 C7 C8 116.4(4) . .
C14 C7 C6 116.0(4) . .
C8 C7 C6 127.6(4) . .
C9 C8 C7 121.8(4) . .
C9 C8 H8 119.1 . .
C7 C8 H8 119.1 . .
C8 C9 C10 120.0(4) . .
C8 C9 C24 121.0(4) . .
C10 C9 C24 119.0(4) . .
C11 C10 C9 119.8(4) . .
C11 C10 H10 120.1 . .
C9 C10 H10 120.1 . .
C10 C11 C14 118.6(3) . .
C10 C11 C12 136.4(3) . .
C14 C11 C12 104.9(3) . .
C13 C12 C2 117.0(3) . .
C13 C12 C11 134.6(3) . .
C2 C12 C11 108.3(3) . .
N1 C13 C12 122.7(3) . .
N1 C13 C28 117.1(3) . .
C12 C13 C28 120.3(3) . .
C7 C14 C3 123.7(3) . .
C7 C14 C11 123.3(3) . .
C3 C14 C11 112.9(3) . .
N3 C15 C19 123.8(3) . .
N3 C15 C1 114.9(3) . .
C19 C15 C1 121.2(3) . .
N3 C16 C17 123.3(3) . .
N3 C16 H16 118.4 . .
C17 C16 H16 118.4 . .
C18 C17 C16 118.9(3) . .
C18 C17 H17 120.6 . .
C16 C17 H17 120.6 . .
C17 C18 C19 119.3(4) . .
C17 C18 H18 120.4 . .
C19 C18 H18 120.4 . .
C18 C19 C15 117.9(3) . .
C18 C19 H19 121.0 . .
C15 C19 H19 121.0 . .
C22A C20 C23A 110.7(3) . .
C21B C20 C22B 108.5(4) . .
C21B C20 C23B 108.3(4) . .
C22B C20 C23B 107.0(4) . .
C22A C20 C5 108.6(4) . .
C21B C20 C5 122.0(9) . .
C23A C20 C5 111.4(4) . .
C22B C20 C5 105.6(9) . .
C23B C20 C5 104.5(8) . .
C22A C20 C21A 109.0(3) . .
C23A C20 C21A 106.3(3) . .
C5 C20 C21A 110.9(4) . .
C20 C21A H211 109.5 . .
C20 C21A H212 109.5 . .
C20 C21A H213 109.5 . .
C20 C22A H221 109.5 . .
C20 C22A H222 109.5 . .
C20 C22A H223 109.5 . .
C20 C23A H231 109.5 . .
C20 C23A H232 109.5 . .
C20 C23A H233 109.5 . .
C20 C21B H214 109.5 . .
C20 C21B H215 109.5 . .
H214 C21B H215 109.5 . .
C20 C21B H216 109.5 . .
H214 C21B H216 109.5 . .
H215 C21B H216 109.5 . .
C20 C22B H224 109.5 . .
C20 C22B H225 109.5 . .
H224 C22B H225 109.5 . .
C20 C22B H226 109.5 . .
H224 C22B H226 109.5 . .
H225 C22B H226 109.5 . .
C20 C23B H234 109.5 . .
C20 C23B H235 109.5 . .
H234 C23B H235 109.5 . .
C20 C23B H236 109.5 . .
H234 C23B H236 109.5 . .
H235 C23B H236 109.5 . .
C26A C24 C9 112.5(5) . .
C27B C24 C9 116.5(6) . .
C26A C24 C25A 110.6(3) . .
C9 C24 C25A 112.3(4) . .
C27B C24 C26B 109.3(4) . .
C9 C24 C26B 112.2(5) . .
C26A C24 C27A 108.3(3) . .
C9 C24 C27A 107.1(4) . .
C25A C24 C27A 105.6(3) . .
C27B C24 C25B 107.9(4) . .
C9 C24 C25B 104.9(5) . .
C26B C24 C25B 105.2(3) . .
C24 C25A H251 109.5 . .
C24 C25A H252 109.5 . .
C24 C25A H253 109.5 . .
C24 C26A H261 109.5 . .
C24 C26A H262 109.5 . .
C24 C26A H263 109.5 . .
C24 C27A H271 109.5 . .
C24 C27A H272 109.5 . .
C24 C27A H273 109.5 . .
C24 C25B H254 109.5 . .
C24 C25B H255 109.5 . .
H254 C25B H255 109.5 . .
C24 C25B H256 109.5 . .
H254 C25B H256 109.5 . .
H255 C25B H256 109.5 . .
C24 C26B H264 109.5 . .
C24 C26B H265 109.5 . .
H264 C26B H265 109.5 . .
C24 C26B H266 109.5 . .
H264 C26B H266 109.5 . .
H265 C26B H266 109.5 . .
C24 C27B H274 109.5 . .
C24 C27B H275 109.5 . .
H274 C27B H275 109.5 . .
C24 C27B H276 109.5 . .
H274 C27B H276 109.5 . .
H275 C27B H276 109.5 . .
N4 C28 C32 123.3(3) . .
N4 C28 C13 114.6(3) . .
C32 C28 C13 122.0(3) . .
N4 C29 C30 123.1(3) . .
N4 C29 H29 118.4 . .
C30 C29 H29 118.4 . .
C31 C30 C29 119.1(3) . .
C31 C30 H30 120.4 . .
C29 C30 H30 120.4 . .
C30 C31 C32 119.0(3) . .
C30 C31 H31 120.5 . .
C32 C31 H31 120.5 . .
C28 C32 C31 118.3(3) . .
C28 C32 H32 120.8 . .
C31 C32 H32 120.8 . .
N6 C33 C34 121.1(3) . .
N6 C33 C47 116.0(3) . .
C34 C33 C47 122.8(3) . .
C33 C34 C44 118.1(3) . .
C33 C34 C35 133.3(3) . .
C44 C34 C35 108.3(3) . .
C36 C35 C46 118.4(3) . .
C36 C35 C34 136.6(3) . .
C46 C35 C34 105.0(3) . .
C35 C36 C37 120.2(3) . .
C35 C36 H36 119.9 . .
C37 C36 H36 119.9 . .
C38 C37 C36 120.0(3) . .
C38 C37 C52 121.6(3) . .
C36 C37 C52 118.4(3) . .
C37 C38 C39 121.3(3) . .
C37 C38 H38 119.3 . .
C39 C38 H38 119.3 . .
C46 C39 C40 116.7(3) . .
C46 C39 C38 116.3(3) . .
C40 C39 C38 127.0(3) . .
C41 C40 C39 121.3(3) . .
C41 C40 H40 119.4 . .
C39 C40 H40 119.4 . .
C40 C41 C42 120.1(3) . .
C40 C41 C56 121.1(3) . .
C42 C41 C56 118.8(3) . .
C43 C42 C41 120.2(3) . .
C43 C42 H42 119.9 . .
C41 C42 H42 119.9 . .
C42 C43 C46 118.3(3) . .
C42 C43 C44 136.6(3) . .
C46 C43 C44 105.0(3) . .
C45 C44 C34 117.6(3) . .
C45 C44 C43 133.6(3) . .
C34 C44 C43 108.7(3) . .
N5 C45 C44 121.3(3) . .
N5 C45 C60 115.4(3) . .
C44 C45 C60 123.3(3) . .
C39 C46 C35 123.7(3) . .
C39 C46 C43 123.3(3) . .
C35 C46 C43 113.0(3) . .
N7 C47 C51 122.7(3) . .
N7 C47 C33 116.3(3) . .
C51 C47 C33 121.0(3) . .
N7 C48 C49 123.3(3) . .
N7 C48 H48 118.3 . .
C49 C48 H48 118.3 . .
C48 C49 C50 118.6(3) . .
C48 C49 H49 120.7 . .
C50 C49 H49 120.7 . .
C49 C50 C51 119.1(3) . .
C49 C50 H50 120.5 . .
C51 C50 H50 120.5 . .
C50 C51 C47 118.6(3) . .
C50 C51 H51 120.7 . .
C47 C51 H51 120.7 . .
C54B C52 C55B 108.9(3) . .
C55A C52 C53A 108.7(3) . .
C54B C52 C53B 108.6(3) . .
C55B C52 C53B 108.2(3) . .
C55A C52 C54A 108.0(3) . .
C53A C52 C54A 107.6(3) . .
C54B C52 C37 109.2(4) . .
C55A C52 C37 108.8(4) . .
C55B C52 C37 108.0(5) . .
C53A C52 C37 110.0(4) . .
C53B C52 C37 113.9(4) . .
C54A C52 C37 113.7(4) . .
C52 C53A H531 109.5 . .
C52 C53A H532 109.5 . .
C52 C53A H533 109.5 . .
C52 C54A H541 109.5 . .
C52 C54A H542 109.5 . .
C52 C54A H543 109.5 . .
C52 C55A H551 109.5 . .
C52 C55A H552 109.5 . .
C52 C55A H553 109.5 . .
C52 C53B H534 109.5 . .
C52 C53B H535 109.5 . .
H534 C53B H535 109.5 . .
C52 C53B H536 109.5 . .
H534 C53B H536 109.5 . .
H535 C53B H536 109.5 . .
C52 C54B H544 109.5 . .
C52 C54B H545 109.5 . .
H544 C54B H545 109.5 . .
C52 C54B H546 109.5 . .
H544 C54B H546 109.5 . .
H545 C54B H546 109.5 . .
C52 C55B H554 109.5 . .
C52 C55B H555 109.5 . .
H554 C55B H555 109.5 . .
C52 C55B H556 109.5 . .
H554 C55B H556 109.5 . .
H555 C55B H556 109.5 . .
C59A C56 C58A 110.2(3) . .
C57B C56 C59B 108.2(3) . .
C59A C56 C57A 109.0(3) . .
C58A C56 C57A 107.5(3) . .
C59A C56 C41 114.9(4) . .
C57B C56 C41 116.0(4) . .
C58A C56 C41 108.1(4) . .
C59B C56 C41 109.0(4) . .
C57A C56 C41 106.8(4) . .
C57B C56 C58B 107.9(3) . .
C59B C56 C58B 106.4(3) . .
C41 C56 C58B 109.1(4) . .
C56 C57A H571 109.5 . .
C56 C57A H572 109.5 . .
C56 C57A H573 109.5 . .
C56 C58A H581 109.5 . .
C56 C58A H582 109.5 . .
C56 C58A H583 109.5 . .
C56 C59A H591 109.5 . .
C56 C59A H592 109.5 . .
C56 C59A H593 109.5 . .
C56 C57B H574 109.5 . .
C56 C57B H575 109.5 . .
H574 C57B H575 109.5 . .
C56 C57B H576 109.5 . .
H574 C57B H576 109.5 . .
H575 C57B H576 109.5 . .
C56 C58B H584 109.5 . .
C56 C58B H585 109.5 . .
H584 C58B H585 109.5 . .
C56 C58B H586 109.5 . .
H584 C58B H586 109.5 . .
H585 C58B H586 109.5 . .
C56 C59B H594 109.5 . .
C56 C59B H595 109.5 . .
H594 C59B H595 109.5 . .
C56 C59B H596 109.5 . .
H594 C59B H596 109.5 . .
H595 C59B H596 109.5 . .
N8 C60 C64 122.2(3) . .
N8 C60 C45 117.0(3) . .
C64 C60 C45 120.8(3) . .
N8 C61 C62 123.5(4) . .
N8 C61 H61 118.2 . .
C62 C61 H61 118.2 . .
C63 C62 C61 118.7(3) . .
C63 C62 H62 120.6 . .
C61 C62 H62 120.6 . .
C62 C63 C64 118.7(4) . .
C62 C63 H63 120.6 . .
C64 C63 H63 120.6 . .
C63 C64 C60 119.1(3) . .
C63 C64 H64 120.4 . .
C60 C64 H64 120.4 . .
F4 P1 F6 90.31(16) . .
F4 P1 F5 90.26(17) . .
F6 P1 F5 179.41(19) . .
F4 P1 F3 179.6(2) . .
F6 P1 F3 89.36(17) . .
F5 P1 F3 90.07(18) . .
F4 P1 F2 90.69(14) . .
F6 P1 F2 90.07(14) . .
F5 P1 F2 90.05(15) . .
F3 P1 F2 89.54(14) . .
F4 P1 F1 89.19(14) . .
F6 P1 F1 90.10(15) . .
F5 P1 F1 89.79(16) . .
F3 P1 F1 90.59(15) . .
F2 P1 F1 179.79(17) . .
F12 P2 F9 91.5(3) . .
F12 P2 F8 91.5(3) . .
F9 P2 F8 94.5(3) . .
F12 P2 F7 89.6(3) . .
F9 P2 F7 86.7(3) . .
F8 P2 F7 178.3(3) . .
F12 P2 F10 91.2(3) . .
F9 P2 F10 177.0(3) . .
F8 P2 F10 86.6(3) . .
F7 P2 F10 92.1(3) . .
F12 P2 F11 177.7(4) . .
F9 P2 F11 89.1(3) . .
F8 P2 F11 90.7(3) . .
F7 P2 F11 88.2(3) . .
F10 P2 F11 88.1(3) . .
N9 C65 C66 179.4(8) . .
C65 C66 H661 109.5 . .
C65 C66 H662 109.5 . .
H661 C66 H662 109.5 . .
C65 C66 H663 109.5 . .
H661 C66 H663 109.5 . .
H662 C66 H663 109.5 . .
N10 C67 C68 178.8(7) . .
C67 C68 H681 109.5 . .
C67 C68 H682 109.5 . .
H681 C68 H682 109.5 . .
C67 C68 H683 109.5 . .
H681 C68 H683 109.5 . .
H682 C68 H683 109.5 . .
C70A C69A C74A 120.0 . .
C70A C69A H69A 120.0 . .
C74A C69A H69A 120.0 . .
C71A C70A C69A 120.0 . .
C71A C70A H70A 120.0 . .
C69A C70A H70A 120.0 . .
C72A C71A C70A 120.0 . .
C72A C71A H71A 120.0 . .
C70A C71A H71A 120.0 . .
C71A C72A C73A 120.0 . .
C71A C72A H72A 120.0 . .
C73A C72A H72A 120.0 . .
C74A C73A C72A 120.0 . .
C74A C73A H73A 120.0 . .
C72A C73A H73A 120.0 . .
C73A C74A C69A 120.0 . .
C73A C74A H74A 120.0 . .
C69A C74A H74A 120.0 . .
C70B C69B C74B 120.0 . .
C70B C69B H69B 120.0 . .
C74B C69B H69B 120.0 . .
C71B C70B C69B 120.0 . .
C71B C70B H70B 120.0 . .
C69B C70B H70B 120.0 . .
C70B C71B C72B 120.0 . .
C70B C71B H71B 120.0 . .
C72B C71B H71B 120.0 . .
C73B C72B C71B 120.0 . .
C73B C72B H72B 120.0 . .
C71B C72B H72B 120.0 . .
C72B C73B C74B 120.0 . .
C72B C73B H73B 120.0 . .
C74B C73B H73B 120.0 . .
C73B C74B C69B 120.0 . .
C73B C74B H74B 120.0 . .
C69B C74B H74B 120.0 . .
C76 C75 C77 118.4(11) . 2_655
C76 C75 H75 120.8 . .
C77 C75 H75 120.8 2_655 .
C77 C76 C75 121.4(11) . .
C77 C76 H76 119.3 . .
C75 C76 H76 119.3 . .
C76 C77 C75 120.2(12) . 2_655
C76 C77 H77 119.9 . .
C75 C77 H77 119.9 2_655 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.317(3) .
Ag1 N7 2.330(3) .
Ag1 N6 2.425(3) .
Ag1 N3 2.496(3) 2_556
Ag2 N5 2.371(3) .
Ag2 N2 2.376(3) .
Ag2 N8 2.381(3) .
Ag2 N4 2.450(3) 2_556
N1 C13 1.340(4) .
N1 N2 1.349(4) .
N2 C1 1.334(4) .
N3 C15 1.342(4) .
N3 C16 1.345(4) .
N4 C29 1.346(4) .
N4 C28 1.349(4) .
N5 N6 1.335(4) .
N5 C45 1.353(4) .
N6 C33 1.348(4) .
N7 C47 1.343(4) .
N7 C48 1.344(4) .
N8 C60 1.343(4) .
N8 C61 1.347(5) .
C1 C2 1.399(5) .
C1 C15 1.484(4) .
C2 C12 1.412(4) .
C2 C3 1.466(5) .
C3 C4 1.377(5) .
C3 C14 1.402(5) .
C4 C5 1.412(5) .
C4 H4 0.9500 .
C5 C6 1.393(6) .
C5 C20 1.536(5) .
C6 C7 1.420(6) .
C6 H6 0.9500 .
C7 C14 1.395(5) .
C7 C8 1.414(6) .
C8 C9 1.382(6) .
C8 H8 0.9500 .
C9 C10 1.422(5) .
C9 C24 1.526(6) .
C10 C11 1.380(5) .
C10 H10 0.9500 .
C11 C14 1.410(5) .
C11 C12 1.471(5) .
C12 C13 1.396(5) .
C13 C28 1.485(4) .
C15 C19 1.391(5) .
C16 C17 1.381(5) .
C16 H16 0.9500 .
C17 C18 1.380(6) .
C17 H17 0.9500 .
C18 C19 1.383(5) .
C18 H18 0.9500 .
C19 H19 0.9500 .
C20 C22A 1.497(4) .
C20 C21B 1.515(5) .
C20 C23A 1.526(4) .
C20 C22B 1.531(5) .
C20 C23B 1.534(5) .
C20 C21A 1.541(4) .
C21A H211 0.9800 .
C21A H212 0.9800 .
C21A H213 0.9800 .
C22A H221 0.9800 .
C22A H222 0.9800 .
C22A H223 0.9800 .
C23A H231 0.9800 .
C23A H232 0.9800 .
C23A H233 0.9800 .
C21B H214 0.9800 .
C21B H215 0.9800 .
C21B H216 0.9800 .
C22B H224 0.9800 .
C22B H225 0.9800 .
C22B H226 0.9800 .
C23B H234 0.9800 .
C23B H235 0.9800 .
C23B H236 0.9800 .
C24 C26A 1.495(4) .
C24 C27B 1.502(4) .
C24 C25A 1.529(4) .
C24 C26B 1.536(4) .
C24 C27A 1.551(4) .
C24 C25B 1.552(4) .
C25A H251 0.9800 .
C25A H252 0.9800 .
C25A H253 0.9800 .
C26A H261 0.9800 .
C26A H262 0.9800 .
C26A H263 0.9800 .
C27A H271 0.9800 .
C27A H272 0.9800 .
C27A H273 0.9800 .
C25B H254 0.9800 .
C25B H255 0.9800 .
C25B H256 0.9800 .
C26B H264 0.9800 .
C26B H265 0.9800 .
C26B H266 0.9800 .
C27B H274 0.9800 .
C27B H275 0.9800 .
C27B H276 0.9800 .
C28 C32 1.388(5) .
C29 C30 1.381(5) .
C29 H29 0.9500 .
C30 C31 1.379(6) .
C30 H30 0.9500 .
C31 C32 1.388(5) .
C31 H31 0.9500 .
C32 H32 0.9500 .
C33 C34 1.396(4) .
C33 C47 1.484(4) .
C34 C44 1.407(4) .
C34 C35 1.482(4) .
C35 C36 1.380(5) .
C35 C46 1.407(5) .
C36 C37 1.424(5) .
C36 H36 0.9500 .
C37 C38 1.384(5) .
C37 C52 1.542(5) .
C38 C39 1.427(5) .
C38 H38 0.9500 .
C39 C46 1.396(5) .
C39 C40 1.415(5) .
C40 C41 1.384(5) .
C40 H40 0.9500 .
C41 C42 1.418(5) .
C41 C56 1.538(5) .
C42 C43 1.380(5) .
C42 H42 0.9500 .
C43 C46 1.408(5) .
C43 C44 1.475(4) .
C44 C45 1.402(4) .
C45 C60 1.482(4) .
C47 C51 1.388(5) .
C48 C49 1.378(5) .
C48 H48 0.9500 .
C49 C50 1.382(6) .
C49 H49 0.9500 .
C50 C51 1.385(5) .
C50 H50 0.9500 .
C51 H51 0.9500 .
C52 C54B 1.520(4) .
C52 C55A 1.521(4) .
C52 C55B 1.522(4) .
C52 C53A 1.525(4) .
C52 C53B 1.526(4) .
C52 C54A 1.530(4) .
C53A H531 0.9800 .
C53A H532 0.9800 .
C53A H533 0.9800 .
C54A H541 0.9800 .
C54A H542 0.9800 .
C54A H543 0.9800 .
C55A H551 0.9800 .
C55A H552 0.9800 .
C55A H553 0.9800 .
C53B H534 0.9800 .
C53B H535 0.9800 .
C53B H536 0.9800 .
C54B H544 0.9800 .
C54B H545 0.9800 .
C54B H546 0.9800 .
C55B H554 0.9800 .
C55B H555 0.9800 .
C55B H556 0.9800 .
C56 C59A 1.504(4) .
C56 C57B 1.516(4) .
C56 C58A 1.521(4) .
C56 C59B 1.535(4) .
C56 C57A 1.535(4) .
C56 C58B 1.540(4) .
C57A H571 0.9800 .
C57A H572 0.9800 .
C57A H573 0.9800 .
C58A H581 0.9800 .
C58A H582 0.9800 .
C58A H583 0.9800 .
C59A H591 0.9800 .
C59A H592 0.9800 .
C59A H593 0.9800 .
C57B H574 0.9800 .
C57B H575 0.9800 .
C57B H576 0.9800 .
C58B H584 0.9800 .
C58B H585 0.9800 .
C58B H586 0.9800 .
C59B H594 0.9800 .
C59B H595 0.9800 .
C59B H596 0.9800 .
C60 C64 1.396(5) .
C61 C62 1.381(6) .
C61 H61 0.9500 .
C62 C63 1.378(6) .
C62 H62 0.9500 .
C63 C64 1.389(5) .
C63 H63 0.9500 .
C64 H64 0.9500 .
P1 F4 1.590(3) .
P1 F6 1.592(3) .
P1 F5 1.594(3) .
P1 F3 1.598(3) .
P1 F2 1.599(2) .
P1 F1 1.600(3) .
P2 F12 1.537(4) .
P2 F9 1.542(4) .
P2 F8 1.551(4) .
P2 F7 1.559(4) .
P2 F10 1.571(4) .
P2 F11 1.579(4) .
N9 C65 1.146(11) .
C65 C66 1.447(12) .
C66 H661 0.9800 .
C66 H662 0.9800 .
C66 H663 0.9800 .
N10 C67 1.128(7) .
C67 C68 1.430(9) .
C68 H681 0.9800 .
C68 H682 0.9800 .
C68 H683 0.9800 .
C69A C70A 1.3900 .
C69A C74A 1.3900 .
C69A H69A 0.9500 .
C70A C71A 1.3900 .
C70A H70A 0.9500 .
C71A C72A 1.3900 .
C71A H71A 0.9500 .
C72A C73A 1.3900 .
C72A H72A 0.9500 .
C73A C74A 1.3900 .
C73A H73A 0.9500 .
C74A H74A 0.9500 .
C69B C70B 1.3900 .
C69B C74B 1.3900 .
C69B H69B 0.9500 .
C70B C71B 1.3900 .
C70B H70B 0.9500 .
C71B C72B 1.3900 .
C71B H71B 0.9500 .
C72B C73B 1.3900 .
C72B H72B 0.9500 .
C73B C74B 1.3900 .
C73B H73B 0.9500 .
C74B H74B 0.9500 .
C75 C76 1.375(14) .
C75 C77 1.380(14) 2_655
C75 H75 0.9500 .
C76 C77 1.355(14) .
C76 H76 0.9500 .
C77 H77 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
N7 Ag1 N1 C13 -73.6(3) .
N6 Ag1 N1 C13 -165.3(2) .
N3 Ag1 N1 C13 47.3(2) 2_556
N7 Ag1 N1 N2 111.6(2) .
N6 Ag1 N1 N2 19.9(2) .
N3 Ag1 N1 N2 -127.5(2) 2_556
C13 N1 N2 C1 -0.3(4) .
Ag1 N1 N2 C1 174.4(2) .
C13 N1 N2 Ag2 -173.9(2) .
Ag1 N1 N2 Ag2 0.7(3) .
N5 Ag2 N2 C1 163.5(2) .
N8 Ag2 N2 C1 75.1(3) .
N4 Ag2 N2 C1 -46.9(2) 2_556
N5 Ag2 N2 N1 -22.5(3) .
N8 Ag2 N2 N1 -110.9(2) .
N4 Ag2 N2 N1 127.1(2) 2_556
N2 Ag2 N5 N6 23.8(3) .
N8 Ag2 N5 N6 163.7(3) .
N4 Ag2 N5 N6 -110.8(2) 2_556
N2 Ag2 N5 C45 -129.1(2) .
N8 Ag2 N5 C45 10.8(2) .
N4 Ag2 N5 C45 96.3(2) 2_556
C45 N5 N6 C33 -0.3(5) .
Ag2 N5 N6 C33 -151.0(2) .
C45 N5 N6 Ag1 146.8(2) .
Ag2 N5 N6 Ag1 -3.9(3) .
N1 Ag1 N6 N5 -18.3(3) .
N7 Ag1 N6 N5 -161.7(3) .
N3 Ag1 N6 N5 113.4(2) 2_556
N1 Ag1 N6 C33 132.2(2) .
N7 Ag1 N6 C33 -11.3(2) .
N3 Ag1 N6 C33 -96.1(2) 2_556
N1 Ag1 N7 C47 -115.2(2) .
N6 Ag1 N7 C47 -10.7(2) .
N3 Ag1 N7 C47 123.6(2) 2_556
N1 Ag1 N7 C48 91.7(3) .
N6 Ag1 N7 C48 -163.8(3) .
N3 Ag1 N7 C48 -29.4(3) 2_556
N5 Ag2 N8 C60 10.1(2) .
N2 Ag2 N8 C60 112.4(2) .
N4 Ag2 N8 C60 -125.1(2) 2_556
N5 Ag2 N8 C61 162.8(3) .
N2 Ag2 N8 C61 -95.0(3) .
N4 Ag2 N8 C61 27.6(3) 2_556
N1 N2 C1 C2 -0.3(5) .
Ag2 N2 C1 C2 173.9(2) .
N1 N2 C1 C15 179.5(3) .
Ag2 N2 C1 C15 -6.3(4) .
N2 C1 C2 C12 0.6(5) .
C15 C1 C2 C12 -179.1(3) .
N2 C1 C2 C3 176.3(3) .
C15 C1 C2 C3 -3.5(6) .
C1 C2 C3 C4 1.4(7) .
C12 C2 C3 C4 177.3(4) .
C1 C2 C3 C14 -175.8(4) .
C12 C2 C3 C14 0.1(4) .
C14 C3 C4 C5 -0.6(6) .
C2 C3 C4 C5 -177.6(4) .
C3 C4 C5 C6 0.5(6) .
C3 C4 C5 C20 -178.5(4) .
C4 C5 C6 C7 0.4(7) .
C20 C5 C6 C7 179.3(4) .
C5 C6 C7 C14 -1.0(7) .
C5 C6 C7 C8 178.4(5) .
C14 C7 C8 C9 0.4(7) .
C6 C7 C8 C9 -179.0(5) .
C7 C8 C9 C10 0.1(8) .
C7 C8 C9 C24 -178.5(4) .
C8 C9 C10 C11 -0.3(7) .
C24 C9 C10 C11 178.3(4) .
C9 C10 C11 C14 0.0(6) .
C9 C10 C11 C12 177.7(4) .
C1 C2 C12 C13 -0.5(5) .
C3 C2 C12 C13 -177.1(3) .
C1 C2 C12 C11 176.8(3) .
C3 C2 C12 C11 0.1(4) .
C10 C11 C12 C13 -1.6(7) .
C14 C11 C12 C13 176.3(4) .
C10 C11 C12 C2 -178.2(4) .
C14 C11 C12 C2 -0.3(4) .
N2 N1 C13 C12 0.4(5) .
Ag1 N1 C13 C12 -174.5(2) .
N2 N1 C13 C28 179.9(3) .
Ag1 N1 C13 C28 5.0(4) .
C2 C12 C13 N1 0.0(5) .
C11 C12 C13 N1 -176.4(3) .
C2 C12 C13 C28 -179.5(3) .
C11 C12 C13 C28 4.1(6) .
C8 C7 C14 C3 -178.7(4) .
C6 C7 C14 C3 0.8(6) .
C8 C7 C14 C11 -0.8(6) .
C6 C7 C14 C11 178.7(4) .
C4 C3 C14 C7 0.0(6) .
C2 C3 C14 C7 177.8(4) .
C4 C3 C14 C11 -178.1(3) .
C2 C3 C14 C11 -0.3(4) .
C10 C11 C14 C7 0.6(6) .
C12 C11 C14 C7 -177.7(4) .
C10 C11 C14 C3 178.7(3) .
C12 C11 C14 C3 0.4(4) .
C16 N3 C15 C19 -1.4(5) .
Ag1 N3 C15 C19 170.9(3) 2_556
C16 N3 C15 C1 174.5(3) .
Ag1 N3 C15 C1 -13.3(4) 2_556
N2 C1 C15 N3 121.6(3) .
C2 C1 C15 N3 -58.6(4) .
N2 C1 C15 C19 -62.4(4) .
C2 C1 C15 C19 117.4(4) .
C15 N3 C16 C17 -0.7(5) .
Ag1 N3 C16 C17 -171.9(3) 2_556
N3 C16 C17 C18 1.6(6) .
C16 C17 C18 C19 -0.4(6) .
C17 C18 C19 C15 -1.5(6) .
N3 C15 C19 C18 2.5(6) .
C1 C15 C19 C18 -173.1(3) .
C6 C5 C20 C22A 83.9(6) .
C4 C5 C20 C22A -97.2(5) .
C6 C5 C20 C21B -88.0(11) .
C4 C5 C20 C21B 90.9(11) .
C6 C5 C20 C23A -154.0(5) .
C4 C5 C20 C23A 24.9(6) .
C6 C5 C20 C22B 36.4(10) .
C4 C5 C20 C22B -144.7(10) .
C6 C5 C20 C23B 149.1(10) .
C4 C5 C20 C23B -32.0(10) .
C6 C5 C20 C21A -35.9(6) .
C4 C5 C20 C21A 143.0(5) .
C8 C9 C24 C26A 112.4(6) .
C10 C9 C24 C26A -66.3(6) .
C8 C9 C24 C27B -68.7(7) .
C10 C9 C24 C27B 112.6(7) .
C8 C9 C24 C25A -13.2(7) .
C10 C9 C24 C25A 168.1(5) .
C8 C9 C24 C26B 164.3(6) .
C10 C9 C24 C26B -14.4(7) .
C8 C9 C24 C27A -128.8(6) .
C10 C9 C24 C27A 52.6(6) .
C8 C9 C24 C25B 50.5(7) .
C10 C9 C24 C25B -128.1(6) .
C29 N4 C28 C32 0.6(5) .
Ag2 N4 C28 C32 -168.6(3) 2_556
C29 N4 C28 C13 -176.7(3) .
Ag2 N4 C28 C13 14.1(4) 2_556
N1 C13 C28 N4 -121.7(3) .
C12 C13 C28 N4 57.8(4) .
N1 C13 C28 C32 61.0(4) .
C12 C13 C28 C32 -119.5(4) .
C28 N4 C29 C30 -0.4(5) .
Ag2 N4 C29 C30 167.6(3) 2_556
N4 C29 C30 C31 0.1(6) .
C29 C30 C31 C32 0.0(6) .
N4 C28 C32 C31 -0.6(5) .
C13 C28 C32 C31 176.5(3) .
C30 C31 C32 C28 0.3(6) .
N5 N6 C33 C34 4.9(5) .
Ag1 N6 C33 C34 -146.0(3) .
N5 N6 C33 C47 -178.1(3) .
Ag1 N6 C33 C47 31.0(3) .
N6 C33 C34 C44 -4.0(5) .
C47 C33 C34 C44 179.2(3) .
N6 C33 C34 C35 169.9(3) .
C47 C33 C34 C35 -6.8(6) .
C33 C34 C35 C36 2.2(7) .
C44 C34 C35 C36 176.6(4) .
C33 C34 C35 C46 -174.4(4) .
C44 C34 C35 C46 -0.1(4) .
C46 C35 C36 C37 -3.0(5) .
C34 C35 C36 C37 -179.3(4) .
C35 C36 C37 C38 2.9(6) .
C35 C36 C37 C52 -176.7(3) .
C36 C37 C38 C39 -0.7(6) .
C52 C37 C38 C39 178.9(3) .
C37 C38 C39 C46 -1.3(5) .
C37 C38 C39 C40 178.2(4) .
C46 C39 C40 C41 1.5(5) .
C38 C39 C40 C41 -177.9(4) .
C39 C40 C41 C42 -0.1(6) .
C39 C40 C41 C56 179.8(3) .
C40 C41 C42 C43 -1.9(5) .
C56 C41 C42 C43 178.2(3) .
C41 C42 C43 C46 2.3(5) .
C41 C42 C43 C44 179.4(4) .
C33 C34 C44 C45 -1.2(5) .
C35 C34 C44 C45 -176.6(3) .
C33 C34 C44 C43 174.7(3) .
C35 C34 C44 C43 -0.6(4) .
C42 C43 C44 C45 -1.2(7) .
C46 C43 C44 C45 176.1(4) .
C42 C43 C44 C34 -176.2(4) .
C46 C43 C44 C34 1.1(4) .
N6 N5 C45 C44 -5.1(5) .
Ag2 N5 C45 C44 148.1(3) .
N6 N5 C45 C60 177.2(3) .
Ag2 N5 C45 C60 -29.5(4) .
C34 C44 C45 N5 5.7(5) .
C43 C44 C45 N5 -169.0(3) .
C34 C44 C45 C60 -176.8(3) .
C43 C44 C45 C60 8.6(6) .
C40 C39 C46 C35 -178.4(3) .
C38 C39 C46 C35 1.1(5) .
C40 C39 C46 C43 -1.0(5) .
C38 C39 C46 C43 178.5(3) .
C36 C35 C46 C39 1.0(5) .
C34 C35 C46 C39 178.4(3) .
C36 C35 C46 C43 -176.6(3) .
C34 C35 C46 C43 0.8(4) .
C42 C43 C46 C39 -0.9(5) .
C44 C43 C46 C39 -178.8(3) .
C42 C43 C46 C35 176.8(3) .
C44 C43 C46 C35 -1.1(4) .
C48 N7 C47 C51 5.3(5) .
Ag1 N7 C47 C51 -149.8(3) .
C48 N7 C47 C33 -173.8(3) .
Ag1 N7 C47 C33 31.1(4) .
N6 C33 C47 N7 -44.3(4) .
C34 C33 C47 N7 132.6(3) .
N6 C33 C47 C51 136.5(3) .
C34 C33 C47 C51 -46.6(5) .
C47 N7 C48 C49 -2.1(5) .
Ag1 N7 C48 C49 149.7(3) .
N7 C48 C49 C50 -1.9(6) .
C48 C49 C50 C51 2.8(6) .
C49 C50 C51 C47 0.1(6) .
N7 C47 C51 C50 -4.3(5) .
C33 C47 C51 C50 174.7(3) .
C38 C37 C52 C54B 55.7(6) .
C36 C37 C52 C54B -124.8(5) .
C38 C37 C52 C55A -122.4(5) .
C36 C37 C52 C55A 57.1(5) .
C38 C37 C52 C55B -62.6(6) .
C36 C37 C52 C55B 117.0(5) .
C38 C37 C52 C53A 118.7(5) .
C36 C37 C52 C53A -61.8(5) .
C38 C37 C52 C53B 177.2(5) .
C36 C37 C52 C53B -3.3(6) .
C38 C37 C52 C54A -2.1(5) .
C36 C37 C52 C54A 177.5(4) .
C40 C41 C56 C59A 169.2(4) .
C42 C41 C56 C59A -10.9(5) .
C40 C41 C56 C57B 7.4(6) .
C42 C41 C56 C57B -172.7(5) .
C40 C41 C56 C58A -67.2(5) .
C42 C41 C56 C58A 112.7(4) .
C40 C41 C56 C59B 129.7(5) .
C42 C41 C56 C59B -50.4(5) .
C40 C41 C56 C57A 48.2(5) .
C42 C41 C56 C57A -131.9(4) .
C40 C41 C56 C58B -114.5(5) .
C42 C41 C56 C58B 65.3(5) .
C61 N8 C60 C64 -4.5(5) .
Ag2 N8 C60 C64 150.5(3) .
C61 N8 C60 C45 175.5(3) .
Ag2 N8 C60 C45 -29.5(4) .
N5 C45 C60 N8 41.8(4) .
C44 C45 C60 N8 -135.8(3) .
N5 C45 C60 C64 -138.2(3) .
C44 C45 C60 C64 44.2(5) .
C60 N8 C61 C62 2.4(6) .
Ag2 N8 C61 C62 -148.8(3) .
N8 C61 C62 C63 1.3(6) .
C61 C62 C63 C64 -2.8(6) .
C62 C63 C64 C60 0.7(6) .
N8 C60 C64 C63 3.0(5) .
C45 C60 C64 C63 -176.9(3) .
