#------------------------------------------------------------------------------
#$Date: 2016-03-25 22:48:39 +0200 (Fri, 25 Mar 2016) $
#$Revision: 180016 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/10/7031051.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7031051
loop_
_publ_author_name
'Rahanyan, Nelli'
'Duttwyler, Simon'
'Linden, Anthony'
'Baldridge, Kim K.'
'Siegel, Jay S.'
_publ_section_title
;
 Cu(i) and Ag(i) complexes of 7,10-bis-N-heterocycle-diazafluoranthenes:
 programmed molecular grids?
;
_journal_issue                   28
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              11027
_journal_page_last               11038
_journal_paper_doi               10.1039/c4dt01460j
_journal_volume                  43
_journal_year                    2014
_chemical_formula_moiety         'C56 H52 Ag2 N8 S4 2+, 2(F6 P -), C3 H6 O'
_chemical_formula_sum            'C59 H58 Ag2 F12 N8 O P2 S4'
_chemical_formula_weight         1529.06
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     heavy
_atom_sites_solution_secondary   difmap
_audit_creation_date             10-04-28
_audit_creation_method           SHELXL-97
_cell_angle_alpha                101.1047(13)
_cell_angle_beta                 100.4256(15)
_cell_angle_gamma                94.9228(11)
_cell_formula_units_Z            2
_cell_length_a                   11.32263(18)
_cell_length_b                   11.56854(13)
_cell_length_c                   24.0375(4)
_cell_measurement_reflns_used    33462
_cell_measurement_temperature    160(1)
_cell_measurement_theta_max      29.5
_cell_measurement_theta_min      3.5
_cell_volume                     3014.78(8)
_computing_cell_refinement
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.55 (release 05-01-2010 CrysAlis171 .NET)
(compiled Jan  5 2010,16:28:46)
;
_computing_data_collection
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.55 (release 05-01-2010 CrysAlis171 .NET)
(compiled Jan  5 2010,16:28:46)
;
_computing_data_reduction
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.55 (release 05-01-2010 CrysAlis171 .NET)
(compiled Jan  5 2010,16:28:46)
;
_computing_molecular_graphics    'ORTEPII (Johnson, 1976)'
_computing_publication_material  'SHELXL97 and PLATON (Spek, 2003)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'DIRDIF94 (Beurskens et al., 1994)'
_diffrn_ambient_temperature      160(1)
_diffrn_detector                 'Atlas CCD camera on \k goniostat'
_diffrn_detector_area_resol_mean 10.3801
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.878
_diffrn_measurement_device_type
'Oxford Diffraction SuperNova, Dual radiation diffractometer'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_source         'SuperNova (Mo) X-ray Source'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.033
_diffrn_reflns_av_sigmaI/netI    0.0278
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            53400
_diffrn_reflns_theta_full        26.3
_diffrn_reflns_theta_max         29.54
_diffrn_reflns_theta_min         3.51
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.926
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.75298
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.33.55 (release 05-01-2010 CrysAlis171 .NET)
(compiled Jan  5 2010,16:28:46)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.684
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1544
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         1.972
_refine_diff_density_min         -1.964
_refine_diff_density_rms         0.209
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.175
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     894
_refine_ls_number_reflns         14806
_refine_ls_number_restraints     741
_refine_ls_restrained_S_all      1.148
_refine_ls_R_factor_all          0.1042
_refine_ls_R_factor_gt           0.0967
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0085P)²+59.9430P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2416
_refine_ls_wR_factor_ref         0.2441
_reflns_number_gt                13022
_reflns_number_total             14806
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c4dt01460j1.cif
_cod_data_source_block           IX
_cod_depositor_comments
'Adding full bibliography for 7031040--7031051.cif.'
_cod_original_cell_volume        3014.77(8)
_cod_original_sg_symbol_H-M      'P -1         '
_cod_database_code               7031051
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.02355(7) 0.05754(6) 0.40875(3) 0.02841(17) Uani 1 1 d . . .
Ag2 Ag -0.06141(7) 0.37199(6) 0.39620(3) 0.03327(18) Uani 1 1 d . . .
S1 S -0.2675(2) 0.3867(2) 0.47709(11) 0.0334(5) Uani 1 1 d . . .
S2 S 0.2700(2) 0.0450(2) 0.49232(11) 0.0371(6) Uani 1 1 d . . .
S3 S -0.4022(2) 0.3152(3) 0.24601(12) 0.0444(7) Uani 1 1 d . . .
S4 S 0.1330(3) -0.1144(3) 0.23710(11) 0.0438(7) Uani 1 1 d . . .
N1 N 0.0421(7) 0.1863(6) 0.4937(3) 0.0229(14) Uani 1 1 d . . .
N2 N -0.0326(7) 0.2701(6) 0.4900(3) 0.0217(14) Uani 1 1 d . . .
N3 N -0.1181(7) 0.5377(6) 0.5559(3) 0.0246(15) Uani 1 1 d . . .
N4 N 0.1860(7) 0.0097(7) 0.5805(4) 0.0306(17) Uani 1 1 d . . .
N5 N -0.0430(7) 0.1152(6) 0.3210(3) 0.0251(15) Uani 1 1 d . . .
N6 N -0.1167(7) 0.1986(6) 0.3216(3) 0.0270(16) Uani 1 1 d . . .
N7 N -0.2274(7) 0.3960(7) 0.3316(3) 0.0254(15) Uani 1 1 d . . .
N8 N 0.0793(7) -0.0669(6) 0.3362(3) 0.0230(14) Uani 1 1 d . . .
C1 C -0.0505(7) 0.3382(7) 0.5386(3) 0.0182(15) Uani 1 1 d . . .
C2 C 0.0063(7) 0.3293(7) 0.5938(3) 0.0173(14) Uani 1 1 d . . .
C3 C 0.0955(7) 0.2496(7) 0.5972(3) 0.0189(15) Uani 1 1 d . . .
C4 C 0.1068(8) 0.1759(7) 0.5453(3) 0.0226(16) Uani 1 1 d . . .
C5 C 0.0003(7) 0.3867(7) 0.6530(3) 0.0178(14) Uani 1 1 d . . .
C6 C -0.0722(8) 0.4635(7) 0.6786(3) 0.0210(15) Uani 1 1 d . . .
H6 H -0.1375 0.4897 0.6555 0.025 Uiso 1 1 calc R . .
C7 C -0.0472(8) 0.5024(7) 0.7401(4) 0.0229(16) Uani 1 1 d . . .
C8 C 0.0475(9) 0.4641(8) 0.7742(4) 0.0273(19) Uani 1 1 d . . .
H8 H 0.0644 0.4926 0.8150 0.033 Uiso 1 1 calc R . .
C9 C 0.1201(8) 0.3821(7) 0.7487(3) 0.0221(16) Uani 1 1 d . . .
C10 C 0.2185(9) 0.3368(9) 0.7791(4) 0.0302(19) Uani 1 1 d . . .
H10 H 0.2396 0.3594 0.8201 0.036 Uiso 1 1 calc R . .
C11 C 0.2847(8) 0.2591(8) 0.7492(4) 0.0257(17) Uani 1 1 d . A .
C12 C 0.2503(8) 0.2209(7) 0.6877(4) 0.0229(16) Uani 1 1 d . . .
H12 H 0.2942 0.1666 0.6674 0.028 Uiso 1 1 calc R . .
C13 C 0.1533(7) 0.2631(7) 0.6580(3) 0.0192(15) Uani 1 1 d . . .
C14 C 0.0916(8) 0.3448(7) 0.6889(3) 0.0198(15) Uani 1 1 d . . .
C15 C -0.1364(7) 0.4255(7) 0.5281(3) 0.0200(15) Uani 1 1 d . . .
C16 C -0.3034(9) 0.5277(9) 0.4952(5) 0.038(2) Uani 1 1 d . . .
H16 H -0.3753 0.5548 0.4781 0.046 Uiso 1 1 calc R . .
C17 C -0.2161(9) 0.5947(9) 0.5368(4) 0.0306(19) Uani 1 1 d . . .
H17 H -0.2207 0.6757 0.5523 0.037 Uiso 1 1 calc R . .
C18 C 0.1828(8) 0.0797(7) 0.5431(4) 0.0234(16) Uani 1 1 d . . .
C19 C 0.3152(9) -0.0690(9) 0.5228(5) 0.038(2) Uani 1 1 d . . .
H19 H 0.3696 -0.1208 0.5095 0.046 Uiso 1 1 calc R . .
C20 C 0.2632(9) -0.0759(8) 0.5686(4) 0.032(2) Uani 1 1 d . . .
H20 H 0.2780 -0.1344 0.5910 0.039 Uiso 1 1 calc R . .
C21 C -0.1321(9) 0.5835(8) 0.7677(4) 0.0302(19) Uani 1 1 d . . .
C22 C -0.1694(18) 0.6737(14) 0.7312(6) 0.083(6) Uani 1 1 d . . .
H22A H -0.2128 0.6318 0.6925 0.125 Uiso 1 1 calc R . .
H22B H -0.0971 0.7228 0.7278 0.125 Uiso 1 1 calc R . .
H22C H -0.2224 0.7245 0.7497 0.125 Uiso 1 1 calc R . .
C23 C -0.2413(12) 0.5079(13) 0.7740(8) 0.075(5) Uani 1 1 d . . .
H23A H -0.2913 0.5577 0.7952 0.112 Uiso 1 1 calc R . .
H23B H -0.2154 0.4473 0.7953 0.112 Uiso 1 1 calc R . .
H23C H -0.2885 0.4692 0.7356 0.112 Uiso 1 1 calc R . .
C24 C -0.0696(11) 0.6549(12) 0.8278(5) 0.051(3) Uani 1 1 d . . .
H24A H -0.1217 0.7124 0.8420 0.077 Uiso 1 1 calc R . .
H24B H 0.0076 0.6971 0.8254 0.077 Uiso 1 1 calc R . .
H24C H -0.0547 0.6009 0.8544 0.077 Uiso 1 1 calc R . .
C25 C 0.4003(8) 0.2177(7) 0.7820(3) 0.0297(19) Uani 1 1 d D . .
C26A C 0.3818(16) 0.1815(16) 0.8377(6) 0.034(3) Uani 0.57(2) 1 d PDU A 1
H26A H 0.4589 0.1646 0.8586 0.051 Uiso 0.57(2) 1 calc PR A 1
H26B H 0.3224 0.1102 0.8285 0.051 Uiso 0.57(2) 1 calc PR A 1
H26C H 0.3521 0.2462 0.8620 0.051 Uiso 0.57(2) 1 calc PR A 1
C27A C 0.4950(16) 0.3270(14) 0.7966(8) 0.049(5) Uani 0.57(2) 1 d PDU A 1
H27A H 0.5638 0.3158 0.8255 0.074 Uiso 0.57(2) 1 calc PR A 1
H27B H 0.4592 0.3972 0.8123 0.074 Uiso 0.57(2) 1 calc PR A 1
H27C H 0.5229 0.3382 0.7615 0.074 Uiso 0.57(2) 1 calc PR A 1
C28A C 0.4451(19) 0.1164(15) 0.7439(7) 0.052(5) Uani 0.57(2) 1 d PDU A 1
H28A H 0.4806 0.1468 0.7145 0.078 Uiso 0.57(2) 1 calc PR A 1
H28B H 0.3770 0.0550 0.7249 0.078 Uiso 0.57(2) 1 calc PR A 1
H28C H 0.5064 0.0822 0.7679 0.078 Uiso 0.57(2) 1 calc PR A 1
C26B C 0.397(2) 0.232(2) 0.8461(5) 0.034(4) Uani 0.43(2) 1 d PDU A 2
H26D H 0.4631 0.1954 0.8652 0.052 Uiso 0.43(2) 1 calc PR A 2
H26E H 0.3193 0.1944 0.8503 0.052 Uiso 0.43(2) 1 calc PR A 2
H26F H 0.4064 0.3172 0.8641 0.052 Uiso 0.43(2) 1 calc PR A 2
C27B C 0.5164(16) 0.285(2) 0.7753(10) 0.051(5) Uani 0.43(2) 1 d PDU A 2
H27D H 0.5329 0.3621 0.8028 0.076 Uiso 0.43(2) 1 calc PR A 2
H27E H 0.5073 0.2984 0.7357 0.076 Uiso 0.43(2) 1 calc PR A 2
H27F H 0.5838 0.2391 0.7831 0.076 Uiso 0.43(2) 1 calc PR A 2
C28B C 0.396(3) 0.0861(11) 0.7555(10) 0.052(5) Uani 0.43(2) 1 d PDU A 2
H28D H 0.3854 0.0747 0.7134 0.079 Uiso 0.43(2) 1 calc PR A 2
H28E H 0.3288 0.0408 0.7653 0.079 Uiso 0.43(2) 1 calc PR A 2
H28F H 0.4725 0.0584 0.7709 0.079 Uiso 0.43(2) 1 calc PR A 2
C29 C -0.1821(8) 0.2176(7) 0.2722(4) 0.0249(17) Uani 1 1 d . . .
C30 C -0.1734(9) 0.1507(7) 0.2188(4) 0.0266(18) Uani 1 1 d . . .
C31 C -0.1024(8) 0.0533(7) 0.2186(4) 0.0246(17) Uani 1 1 d . . .
C32 C -0.0348(8) 0.0417(7) 0.2718(4) 0.0233(16) Uani 1 1 d . . .
C33 C -0.2246(8) 0.1538(8) 0.1586(4) 0.0232(16) Uani 1 1 d . . .
C34 C -0.2912(8) 0.2287(8) 0.1307(4) 0.0287(19) Uani 1 1 d . . .
H34 H -0.3149 0.2969 0.1529 0.034 Uiso 1 1 calc R . .
C35 C -0.3240(8) 0.2047(8) 0.0699(4) 0.0280(18) Uani 1 1 d . . .
C36 C -0.2891(9) 0.1042(9) 0.0376(4) 0.031(2) Uani 1 1 d . . .
H36 H -0.3128 0.0875 -0.0034 0.038 Uiso 1 1 calc R . .
C37 C -0.2194(8) 0.0267(8) 0.0644(4) 0.0266(18) Uani 1 1 d . . .
C38 C -0.1777(9) -0.0755(9) 0.0365(4) 0.032(2) Uani 1 1 d . . .
H38 H -0.1964 -0.0975 -0.0046 0.038 Uiso 1 1 calc R . .
C39 C -0.1097(8) -0.1452(8) 0.0675(4) 0.0278(18) Uani 1 1 d . . .
C40 C -0.0786(8) -0.1114(8) 0.1284(4) 0.0273(18) Uani 1 1 d . . .
H40 H -0.0320 -0.1591 0.1496 0.033 Uiso 1 1 calc R . .
C41 C -0.1148(8) -0.0098(8) 0.1578(3) 0.0233(16) Uani 1 1 d . . .
C42 C -0.1873(8) 0.0552(8) 0.1244(4) 0.0254(17) Uani 1 1 d . . .
C43 C -0.2593(8) 0.3123(8) 0.2843(4) 0.0252(17) Uani 1 1 d . . .
C44 C -0.4168(10) 0.4381(10) 0.2950(4) 0.038(2) Uani 1 1 d . . .
H44 H -0.4854 0.4802 0.2926 0.046 Uiso 1 1 calc R . .
C45 C -0.3179(9) 0.4670(8) 0.3373(4) 0.033(2) Uani 1 1 d . . .
H45 H -0.3108 0.5321 0.3691 0.039 Uiso 1 1 calc R . .
C46 C 0.0499(8) -0.0455(7) 0.2837(3) 0.0219(16) Uani 1 1 d . . .
C47 C 0.2083(10) -0.1759(10) 0.2907(4) 0.040(2) Uani 1 1 d . . .
H47 H 0.2693 -0.2266 0.2867 0.048 Uiso 1 1 calc R . .
C48 C 0.1665(8) -0.1404(8) 0.3396(4) 0.0280(18) Uani 1 1 d . . .
H48 H 0.1964 -0.1652 0.3744 0.034 Uiso 1 1 calc R . .
C49 C -0.3998(10) 0.2837(10) 0.0377(4) 0.038(2) Uani 1 1 d . . .
C50 C -0.4328(18) 0.3869(14) 0.0790(6) 0.084(6) Uani 1 1 d . . .
H50A H -0.4841 0.3564 0.1030 0.126 Uiso 1 1 calc R . .
H50B H -0.4768 0.4381 0.0567 0.126 Uiso 1 1 calc R . .
H50C H -0.3588 0.4328 0.1038 0.126 Uiso 1 1 calc R . .
C51 C -0.5198(12) 0.2082(13) 0.0030(6) 0.063(4) Uani 1 1 d . . .
H51A H -0.5019 0.1433 -0.0257 0.095 Uiso 1 1 calc R . .
H51B H -0.5708 0.2585 -0.0167 0.095 Uiso 1 1 calc R . .
H51C H -0.5626 0.1753 0.0296 0.095 Uiso 1 1 calc R . .
C52 C -0.3343(15) 0.3255(16) -0.0062(8) 0.077(5) Uani 1 1 d . . .
H52A H -0.2588 0.3757 0.0141 0.115 Uiso 1 1 calc R . .
H52B H -0.3860 0.3713 -0.0286 0.115 Uiso 1 1 calc R . .
H52C H -0.3159 0.2565 -0.0324 0.115 Uiso 1 1 calc R . .
C53 C -0.0688(10) -0.2577(9) 0.0350(4) 0.038(2) Uani 1 1 d . . .
C54 C -0.1740(14) -0.3396(13) -0.0034(8) 0.085(6) Uani 1 1 d . . .
H54A H -0.1448 -0.3970 -0.0317 0.128 Uiso 1 1 calc R . .
H54B H -0.2293 -0.2935 -0.0236 0.128 Uiso 1 1 calc R . .
H54C H -0.2168 -0.3819 0.0202 0.128 Uiso 1 1 calc R . .
C55 C 0.0124(15) -0.2189(16) -0.0058(7) 0.076(5) Uani 1 1 d . . .
H55A H 0.0875 -0.1722 0.0175 0.114 Uiso 1 1 calc R . .
H55B H -0.0309 -0.1706 -0.0300 0.114 Uiso 1 1 calc R . .
H55C H 0.0317 -0.2896 -0.0306 0.114 Uiso 1 1 calc R . .
C56 C 0.0088(19) -0.3187(16) 0.0735(6) 0.090(7) Uani 1 1 d . . .
H56A H -0.0404 -0.3567 0.0961 0.135 Uiso 1 1 calc R . .
H56B H 0.0728 -0.2608 0.0997 0.135 Uiso 1 1 calc R . .
H56C H 0.0454 -0.3792 0.0501 0.135 Uiso 1 1 calc R . .
O1 O 0.4452(16) 0.2822(14) 0.3895(7) 0.125(6) Uani 1 1 d . . .
C57 C 0.4274(19) 0.0937(18) 0.3387(10) 0.100(6) Uani 1 1 d . . .
H57A H 0.3890 0.0825 0.2977 0.150 Uiso 1 1 calc R . .
H57B H 0.4061 0.0223 0.3528 0.150 Uiso 1 1 calc R . .
H57C H 0.5155 0.1080 0.3429 0.150 Uiso 1 1 calc R . .
C58 C 0.3875(16) 0.1903(11) 0.3705(5) 0.059(4) Uani 1 1 d . . .
C59 C 0.2797(13) 0.1691(11) 0.3747(6) 0.054(3) Uani 1 1 d . . .
H59A H 0.2673 0.2160 0.4113 0.080 Uiso 1 1 calc R . .
H59B H 0.2608 0.0844 0.3738 0.080 Uiso 1 1 calc R . .
H59C H 0.2264 0.1904 0.3423 0.080 Uiso 1 1 calc R . .
P1 P 0.5395(3) 0.2907(2) 0.59256(12) 0.0349(6) Uani 1 1 d . . .
F1 F 0.5369(7) 0.1545(6) 0.5923(4) 0.066(2) Uani 1 1 d . . .
F2 F 0.5441(7) 0.4310(6) 0.5950(4) 0.066(2) Uani 1 1 d . . .
F3 F 0.5713(9) 0.3196(9) 0.6611(3) 0.078(3) Uani 1 1 d . . .
F4 F 0.5064(6) 0.2657(7) 0.5239(3) 0.0474(16) Uani 1 1 d . . .
F5 F 0.3980(6) 0.2861(6) 0.5942(3) 0.0504(17) Uani 1 1 d . . .
F6 F 0.6811(6) 0.3003(7) 0.5911(3) 0.0544(18) Uani 1 1 d . . .
P2 P 0.3204(3) 0.0662(3) 0.14727(12) 0.0469(7) Uani 1 1 d D . .
F7A F 0.1960(9) 0.0517(13) 0.1018(5) 0.103(2) Uani 0.475(8) 1 d PDU B 1
F8A F 0.4454(9) 0.0807(13) 0.1928(5) 0.104(2) Uani 0.475(8) 1 d PDU B 1
F9A F 0.3377(13) 0.2055(6) 0.1491(6) 0.103(2) Uani 0.475(8) 1 d PDU B 1
F10A F 0.3038(13) -0.0730(6) 0.1456(6) 0.103(2) Uani 0.475(8) 1 d PDU B 1
F11A F 0.2496(13) 0.0888(13) 0.1993(5) 0.104(2) Uani 0.475(8) 1 d PDU B 1
F12A F 0.3918(13) 0.0436(13) 0.0954(5) 0.103(2) Uani 0.475(8) 1 d PDU B 1
F7B F 0.2709(13) 0.0162(11) 0.0796(3) 0.105(2) Uani 0.525(8) 1 d PDU B 2
F8B F 0.3688(13) 0.1162(11) 0.2151(3) 0.103(2) Uani 0.525(8) 1 d PDU B 2
F9B F 0.3269(12) 0.1988(7) 0.1371(6) 0.104(2) Uani 0.525(8) 1 d PDU B 2
F10B F 0.3135(12) -0.0663(7) 0.1576(6) 0.102(2) Uani 0.525(8) 1 d PDU B 2
F11B F 0.1843(7) 0.0721(12) 0.1565(6) 0.103(2) Uani 0.525(8) 1 d PDU B 2
F12B F 0.4559(7) 0.0605(12) 0.1383(6) 0.103(2) Uani 0.525(8) 1 d PDU B 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_number_in_cell
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 118 0.0033 0.0016
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
H H 116 0.0000 0.0000
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
Ag Ag 4 -0.8971 1.1015
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
F F 24 0.0171 0.0103
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
N N 16 0.0061 0.0033
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
O O 2 0.0106 0.0060
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
P P 4 0.1023 0.0942
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
S S 8 0.1246 0.1234
; International Tables for Crystallography (1992). 
Vol. C, Tables 4.2.6.8 and 6.1.1.4
;
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ag1 N8 158.7(3) . .
N1 Ag1 N5 120.6(2) . .
N8 Ag1 N5 70.7(3) . .
N1 Ag1 N4 87.1(3) . 2_556
N8 Ag1 N4 111.2(3) . 2_556
N5 Ag1 N4 94.0(3) . 2_556
N1 Ag1 S2 69.49(18) . .
N8 Ag1 S2 90.18(19) . .
N5 Ag1 S2 138.8(2) . .
N4 Ag1 S2 127.2(2) 2_556 .
N3 Ag2 N7 142.2(3) 2_566 .
N3 Ag2 N6 131.0(3) 2_566 .
N7 Ag2 N6 70.5(3) . .
N3 Ag2 N2 79.3(2) 2_566 .
N7 Ag2 N2 133.2(3) . .
N6 Ag2 N2 99.5(2) . .
N3 Ag2 S1 112.72(19) 2_566 .
N7 Ag2 S1 78.91(19) . .
N6 Ag2 S1 108.6(2) . .
N2 Ag2 S1 60.68(16) . .
C16 S1 C15 89.6(5) . .
C19 S2 C18 89.9(5) . .
C44 S3 C43 89.8(5) . .
C46 S4 C47 90.7(4) . .
N2 N1 C4 121.3(7) . .
N2 N1 Ag1 112.1(5) . .
C4 N1 Ag1 126.0(5) . .
C1 N2 N1 119.1(7) . .
C15 N3 C17 109.5(8) . .
C15 N3 Ag2 123.1(6) . 2_566
C17 N3 Ag2 125.1(6) . 2_566
C18 N4 C20 109.8(8) . .
C18 N4 Ag1 110.8(6) . 2_556
C20 N4 Ag1 118.6(6) . 2_556
N6 N5 C32 121.8(7) . .
N6 N5 Ag1 117.2(5) . .
C32 N5 Ag1 118.0(5) . .
N5 N6 C29 121.3(7) . .
N5 N6 Ag2 117.6(6) . .
C29 N6 Ag2 113.6(5) . .
C43 N7 C45 110.6(8) . .
C43 N7 Ag2 115.9(6) . .
C45 N7 Ag2 131.7(6) . .
C46 N8 C48 111.8(7) . .
C46 N8 Ag1 116.9(5) . .
C48 N8 Ag1 128.5(6) . .
N2 C1 C2 123.6(7) . .
N2 C1 C15 113.4(7) . .
C2 C1 C15 123.0(7) . .
C1 C2 C3 116.9(7) . .
C1 C2 C5 135.2(7) . .
C3 C2 C5 107.9(7) . .
C4 C3 C2 117.2(7) . .
C4 C3 C13 134.4(7) . .
C2 C3 C13 108.3(6) . .
N1 C4 C3 121.3(7) . .
N1 C4 C18 115.6(7) . .
C3 C4 C18 123.1(7) . .
C6 C5 C14 118.6(7) . .
C6 C5 C2 136.1(7) . .
C14 C5 C2 105.2(6) . .
C5 C6 C7 119.2(7) . .
C5 C6 H6 120.4 . .
C7 C6 H6 120.4 . .
C8 C7 C6 120.7(7) . .
C8 C7 C21 121.0(7) . .
C6 C7 C21 118.2(7) . .
C7 C8 C9 120.7(8) . .
C7 C8 H8 119.7 . .
C9 C8 H8 119.7 . .
C14 C9 C10 117.6(8) . .
C14 C9 C8 116.9(8) . .
C10 C9 C8 125.6(8) . .
C11 C10 C9 120.4(8) . .
C11 C10 H10 119.8 . .
C9 C10 H10 119.8 . .
C10 C11 C12 120.1(8) . .
C10 C11 C25 120.6(7) . .
C12 C11 C25 119.3(7) . .
C13 C12 C11 119.8(8) . .
C13 C12 H12 120.1 . .
C11 C12 H12 120.1 . .
C12 C13 C14 118.9(7) . .
C12 C13 C3 135.7(7) . .
C14 C13 C3 105.3(7) . .
C9 C14 C13 123.3(8) . .
C9 C14 C5 123.8(7) . .
C13 C14 C5 113.0(7) . .
N3 C15 C1 123.8(7) . .
N3 C15 S1 114.8(6) . .
C1 C15 S1 121.4(6) . .
C17 C16 S1 110.6(7) . .
C17 C16 H16 124.7 . .
S1 C16 H16 124.7 . .
C16 C17 N3 115.6(8) . .
C16 C17 H17 122.2 . .
N3 C17 H17 122.2 . .
N4 C18 C4 120.9(8) . .
N4 C18 S2 114.6(6) . .
C4 C18 S2 124.4(7) . .
C20 C19 S2 110.8(7) . .
C20 C19 H19 124.6 . .
S2 C19 H19 124.6 . .
C19 C20 N4 114.8(9) . .
C19 C20 H20 122.6 . .
N4 C20 H20 122.6 . .
C23 C21 C22 110.6(13) . .
C23 C21 C24 108.1(10) . .
C22 C21 C24 106.6(10) . .
C23 C21 C7 108.9(8) . .
C22 C21 C7 111.0(8) . .
C24 C21 C7 111.5(8) . .
C21 C22 H22A 109.5 . .
C21 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C21 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C21 C23 H23A 109.5 . .
C21 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C21 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C21 C24 H24A 109.5 . .
C21 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C21 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
C26A C25 C28A 109.5(5) . .
C27B C25 C26B 109.5(5) . .
C27B C25 C28B 109.5(6) . .
C26B C25 C28B 109.1(5) . .
C26A C25 C27A 109.2(5) . .
C28A C25 C27A 109.0(5) . .
C27B C25 C11 112.3(12) . .
C26A C25 C11 112.8(9) . .
C28A C25 C11 112.0(9) . .
C26B C25 C11 110.1(11) . .
C28B C25 C11 106.3(11) . .
C27A C25 C11 104.1(10) . .
C25 C26A H26A 109.5 . .
C25 C26A H26B 109.5 . .
C25 C26A H26C 109.5 . .
C25 C27A H27A 109.5 . .
C25 C27A H27B 109.5 . .
C25 C27A H27C 109.5 . .
C25 C28A H28A 109.5 . .
C25 C28A H28B 109.5 . .
C25 C28A H28C 109.5 . .
C25 C26B H26D 109.5 . .
C25 C26B H26E 109.5 . .
H26D C26B H26E 109.5 . .
C25 C26B H26F 109.5 . .
H26D C26B H26F 109.5 . .
H26E C26B H26F 109.5 . .
C25 C27B H27D 109.5 . .
C25 C27B H27E 109.5 . .
H27D C27B H27E 109.5 . .
C25 C27B H27F 109.5 . .
H27D C27B H27F 109.5 . .
H27E C27B H27F 109.5 . .
C25 C28B H28D 109.5 . .
C25 C28B H28E 109.5 . .
H28D C28B H28E 109.5 . .
C25 C28B H28F 109.5 . .
H28D C28B H28F 109.5 . .
H28E C28B H28F 109.5 . .
N6 C29 C30 120.7(8) . .
N6 C29 C43 111.1(7) . .
C30 C29 C43 128.2(8) . .
C29 C30 C31 117.7(8) . .
C29 C30 C33 134.0(8) . .
C31 C30 C33 108.3(7) . .
C32 C31 C30 117.6(8) . .
C32 C31 C41 134.6(8) . .
C30 C31 C41 107.8(7) . .
N5 C32 C31 120.4(7) . .
N5 C32 C46 110.7(7) . .
C31 C32 C46 129.0(7) . .
C34 C33 C42 118.4(8) . .
C34 C33 C30 136.0(8) . .
C42 C33 C30 105.5(7) . .
C33 C34 C35 120.5(8) . .
C33 C34 H34 119.7 . .
C35 C34 H34 119.7 . .
C36 C35 C34 119.5(8) . .
C36 C35 C49 118.4(8) . .
C34 C35 C49 122.1(8) . .
C35 C36 C37 121.6(8) . .
C35 C36 H36 119.2 . .
C37 C36 H36 119.2 . .
C42 C37 C38 116.4(8) . .
C42 C37 C36 116.9(8) . .
C38 C37 C36 126.7(8) . .
C39 C38 C37 121.6(8) . .
C39 C38 H38 119.2 . .
C37 C38 H38 119.2 . .
C38 C39 C40 119.6(8) . .
C38 C39 C53 119.5(8) . .
C40 C39 C53 120.9(8) . .
C41 C40 C39 121.0(8) . .
C41 C40 H40 119.5 . .
C39 C40 H40 119.5 . .
C40 C41 C42 117.1(8) . .
C40 C41 C31 137.3(8) . .
C42 C41 C31 105.5(7) . .
C37 C42 C41 124.2(8) . .
C37 C42 C33 123.0(8) . .
C41 C42 C33 112.8(7) . .
N7 C43 C29 120.4(8) . .
N7 C43 S3 113.7(7) . .
C29 C43 S3 125.4(7) . .
C45 C44 S3 110.4(7) . .
C45 C44 H44 124.8 . .
S3 C44 H44 124.8 . .
C44 C45 N7 115.4(9) . .
C44 C45 H45 122.3 . .
N7 C45 H45 122.3 . .
N8 C46 C32 120.8(7) . .
N8 C46 S4 112.5(6) . .
C32 C46 S4 126.3(6) . .
C48 C47 S4 108.8(8) . .
C48 C47 H47 125.6 . .
S4 C47 H47 125.6 . .
C47 C48 N8 116.1(9) . .
C47 C48 H48 121.9 . .
N8 C48 H48 121.9 . .
C50 C49 C52 111.9(13) . .
C50 C49 C35 111.9(9) . .
C52 C49 C35 110.1(9) . .
C50 C49 C51 107.4(11) . .
C52 C49 C51 106.9(11) . .
C35 C49 C51 108.5(9) . .
C49 C50 H50A 109.5 . .
C49 C50 H50B 109.5 . .
H50A C50 H50B 109.5 . .
C49 C50 H50C 109.5 . .
H50A C50 H50C 109.5 . .
H50B C50 H50C 109.5 . .
C49 C51 H51A 109.5 . .
C49 C51 H51B 109.5 . .
H51A C51 H51B 109.5 . .
C49 C51 H51C 109.5 . .
H51A C51 H51C 109.5 . .
H51B C51 H51C 109.5 . .
C49 C52 H52A 109.5 . .
C49 C52 H52B 109.5 . .
H52A C52 H52B 109.5 . .
C49 C52 H52C 109.5 . .
H52A C52 H52C 109.5 . .
H52B C52 H52C 109.5 . .
C56 C53 C54 112.3(13) . .
C56 C53 C39 113.3(9) . .
C54 C53 C39 111.4(9) . .
C56 C53 C55 105.2(12) . .
C54 C53 C55 106.3(12) . .
C39 C53 C55 107.7(10) . .
C53 C54 H54A 109.5 . .
C53 C54 H54B 109.5 . .
H54A C54 H54B 109.5 . .
C53 C54 H54C 109.5 . .
H54A C54 H54C 109.5 . .
H54B C54 H54C 109.5 . .
C53 C55 H55A 109.5 . .
C53 C55 H55B 109.5 . .
H55A C55 H55B 109.5 . .
C53 C55 H55C 109.5 . .
H55A C55 H55C 109.5 . .
H55B C55 H55C 109.5 . .
C53 C56 H56A 109.5 . .
C53 C56 H56B 109.5 . .
H56A C56 H56B 109.5 . .
C53 C56 H56C 109.5 . .
H56A C56 H56C 109.5 . .
H56B C56 H56C 109.5 . .
C58 C57 H57A 109.5 . .
C58 C57 H57B 109.5 . .
H57A C57 H57B 109.5 . .
C58 C57 H57C 109.5 . .
H57A C57 H57C 109.5 . .
H57B C57 H57C 109.5 . .
O1 C58 C59 123.2(17) . .
O1 C58 C57 124(2) . .
C59 C58 C57 112.2(15) . .
C58 C59 H59A 109.5 . .
C58 C59 H59B 109.5 . .
H59A C59 H59B 109.5 . .
C58 C59 H59C 109.5 . .
H59A C59 H59C 109.5 . .
H59B C59 H59C 109.5 . .
F1 P1 F3 89.7(5) . .
F1 P1 F4 91.9(5) . .
F3 P1 F4 178.3(5) . .
F1 P1 F6 90.3(4) . .
F3 P1 F6 90.0(5) . .
F4 P1 F6 90.5(4) . .
F1 P1 F5 91.7(4) . .
F3 P1 F5 89.8(5) . .
F4 P1 F5 89.6(4) . .
F6 P1 F5 178.0(4) . .
F1 P1 F2 178.2(5) . .
F3 P1 F2 88.5(5) . .
F4 P1 F2 89.8(5) . .
F6 P1 F2 89.4(4) . .
F5 P1 F2 88.7(4) . .
F12B P2 F7B 90.3(2) . .
F7A P2 F11A 90.1(2) . .
F12B P2 F9B 90.1(2) . .
F7B P2 F9B 90.1(2) . .
F7A P2 F10A 90.1(2) . .
F11A P2 F10A 90.1(2) . .
F7A P2 F9A 90.1(2) . .
F11A P2 F9A 90.0(2) . .
F10A P2 F9A 179.7(3) . .
F12B P2 F10B 90.1(2) . .
F7B P2 F10B 90.0(2) . .
F9B P2 F10B 179.8(3) . .
F12B P2 F8B 90.2(2) . .
F7B P2 F8B 179.6(3) . .
F9B P2 F8B 90.0(2) . .
F10B P2 F8B 89.9(2) . .
F7A P2 F12A 90.1(2) . .
F11A P2 F12A 179.8(3) . .
F10A P2 F12A 89.9(2) . .
F9A P2 F12A 90.0(2) . .
F7A P2 F8A 179.8(3) . .
F11A P2 F8A 90.0(2) . .
F10A P2 F8A 89.9(2) . .
F9A P2 F8A 89.8(2) . .
F12A P2 F8A 89.7(2) . .
F12B P2 F11B 179.8(3) . .
F7B P2 F11B 89.9(2) . .
F9B P2 F11B 89.9(2) . .
F10B P2 F11B 89.9(2) . .
F8B P2 F11B 89.7(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.247(7) .
Ag1 N8 2.258(7) .
Ag1 N5 2.348(7) .
Ag1 N4 2.506(8) 2_556
Ag1 S2 3.161(3) .
Ag2 N3 2.208(8) 2_566
Ag2 N7 2.285(7) .
Ag2 N6 2.371(7) .
Ag2 N2 2.720(7) .
Ag2 S1 3.292(3) .
S1 C16 1.709(10) .
S1 C15 1.710(8) .
S2 C19 1.700(11) .
S2 C18 1.715(9) .
S3 C44 1.703(11) .
S3 C43 1.717(9) .
S4 C46 1.716(9) .
S4 C47 1.719(11) .
N1 N2 1.346(10) .
N1 C4 1.356(11) .
N2 C1 1.337(10) .
N3 C15 1.320(11) .
N3 C17 1.390(11) .
N4 C18 1.319(12) .
N4 C20 1.399(11) .
N5 N6 1.330(10) .
N5 C32 1.340(10) .
N6 C29 1.348(11) .
N7 C43 1.314(11) .
N7 C45 1.377(11) .
N8 C46 1.322(11) .
N8 C48 1.359(11) .
C1 C2 1.392(11) .
C1 C15 1.487(11) .
C2 C3 1.427(10) .
C2 C5 1.465(10) .
C3 C4 1.402(10) .
C3 C13 1.460(10) .
C4 C18 1.463(11) .
C5 C6 1.393(10) .
C5 C14 1.405(11) .
C6 C7 1.427(11) .
C6 H6 0.9500 .
C7 C8 1.387(12) .
C7 C21 1.546(11) .
C8 C9 1.429(11) .
C8 H8 0.9500 .
C9 C14 1.387(11) .
C9 C10 1.417(11) .
C10 C11 1.396(12) .
C10 H10 0.9500 .
C11 C12 1.429(12) .
C11 C25 1.563(12) .
C12 C13 1.378(11) .
C12 H12 0.9500 .
C13 C14 1.401(11) .
C16 C17 1.338(15) .
C16 H16 0.9500 .
C17 H17 0.9500 .
C19 C20 1.351(15) .
C19 H19 0.9500 .
C20 H20 0.9500 .
C21 C23 1.501(16) .
C21 C22 1.527(15) .
C21 C24 1.530(13) .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
C23 H23A 0.9800 .
C23 H23B 0.9800 .
C23 H23C 0.9800 .
C24 H24A 0.9800 .
C24 H24B 0.9800 .
C24 H24C 0.9800 .
C25 C27B 1.522(9) .
C25 C26A 1.523(9) .
C25 C28A 1.525(9) .
C25 C26B 1.526(9) .
C25 C28B 1.526(9) .
C25 C27A 1.528(9) .
C26A H26A 0.9800 .
C26A H26B 0.9800 .
C26A H26C 0.9800 .
C27A H27A 0.9800 .
C27A H27B 0.9800 .
C27A H27C 0.9800 .
C28A H28A 0.9800 .
C28A H28B 0.9800 .
C28A H28C 0.9800 .
C26B H26D 0.9800 .
C26B H26E 0.9800 .
C26B H26F 0.9800 .
C27B H27D 0.9800 .
C27B H27E 0.9800 .
C27B H27F 0.9800 .
C28B H28D 0.9800 .
C28B H28E 0.9800 .
C28B H28F 0.9800 .
C29 C30 1.391(12) .
C29 C43 1.477(12) .
C30 C31 1.439(12) .
C30 C33 1.467(12) .
C31 C32 1.403(12) .
C31 C41 1.478(11) .
C32 C46 1.482(11) .
C33 C34 1.386(12) .
C33 C42 1.415(12) .
C34 C35 1.407(12) .
C34 H34 0.9500 .
C35 C36 1.398(13) .
C35 C49 1.529(12) .
C36 C37 1.415(12) .
C36 H36 0.9500 .
C37 C42 1.389(12) .
C37 C38 1.406(13) .
C38 C39 1.389(13) .
C38 H38 0.9500 .
C39 C40 1.410(12) .
C39 C53 1.538(12) .
C40 C41 1.384(12) .
C40 H40 0.9500 .
C41 C42 1.407(12) .
C44 C45 1.339(15) .
C44 H44 0.9500 .
C45 H45 0.9500 .
C47 C48 1.349(13) .
C47 H47 0.9500 .
C48 H48 0.9500 .
C49 C50 1.517(17) .
C49 C52 1.522(17) .
C49 C51 1.552(17) .
C50 H50A 0.9800 .
C50 H50B 0.9800 .
C50 H50C 0.9800 .
C51 H51A 0.9800 .
C51 H51B 0.9800 .
C51 H51C 0.9800 .
C52 H52A 0.9800 .
C52 H52B 0.9800 .
C52 H52C 0.9800 .
C53 C56 1.481(17) .
C53 C54 1.496(18) .
C53 C55 1.559(18) .
C54 H54A 0.9800 .
C54 H54B 0.9800 .
C54 H54C 0.9800 .
C55 H55A 0.9800 .
C55 H55B 0.9800 .
C55 H55C 0.9800 .
C56 H56A 0.9800 .
C56 H56B 0.9800 .
C56 H56C 0.9800 .
O1 C58 1.163(18) .
C57 C58 1.39(2) .
C57 H57A 0.9800 .
C57 H57B 0.9800 .
C57 H57C 0.9800 .
C58 C59 1.25(2) .
C59 H59A 0.9800 .
C59 H59B 0.9800 .
C59 H59C 0.9800 .
P1 F1 1.573(7) .
P1 F3 1.584(8) .
P1 F4 1.589(6) .
P1 F6 1.605(7) .
P1 F5 1.606(7) .
P1 F2 1.608(8) .
P2 F12B 1.594(6) .
P2 F7A 1.594(6) .
P2 F7B 1.595(6) .
P2 F11A 1.595(6) .
P2 F9B 1.596(6) .
P2 F10A 1.596(6) .
P2 F9A 1.597(6) .
P2 F10B 1.597(6) .
P2 F8B 1.598(6) .
P2 F12A 1.598(6) .
P2 F8A 1.599(6) .
P2 F11B 1.600(6) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
N8 Ag1 N1 N2 143.6(7) .
N5 Ag1 N1 N2 26.5(7) .
N4 Ag1 N1 N2 -66.4(6) 2_556
N8 Ag1 N1 C4 -45.0(12) .
N5 Ag1 N1 C4 -162.1(7) .
N4 Ag1 N1 C4 105.0(7) 2_556
C4 N1 N2 C1 -5.3(12) .
Ag1 N1 N2 C1 166.6(6) .
N1 Ag1 N5 N6 -29.0(7) .
N8 Ag1 N5 N6 171.0(7) .
N4 Ag1 N5 N6 59.9(6) 2_556
N1 Ag1 N5 C32 170.0(6) .
N8 Ag1 N5 C32 10.0(6) .
N4 Ag1 N5 C32 -101.0(7) 2_556
C32 N5 N6 C29 -3.8(13) .
Ag1 N5 N6 C29 -164.0(7) .
C32 N5 N6 Ag2 -151.7(7) .
Ag1 N5 N6 Ag2 48.1(8) .
N3 Ag2 N6 N5 29.7(8) 2_566
N7 Ag2 N6 N5 173.0(7) .
N3 Ag2 N6 C29 -120.7(7) 2_566
N7 Ag2 N6 C29 22.6(6) .
N3 Ag2 N7 C43 124.9(7) 2_566
N6 Ag2 N7 C43 -7.8(6) .
N3 Ag2 N7 C45 -71.9(10) 2_566
N6 Ag2 N7 C45 155.4(9) .
N1 Ag1 N8 C46 -124.8(8) .
N5 Ag1 N8 C46 0.9(6) .
N4 Ag1 N8 C46 87.6(7) 2_556
N1 Ag1 N8 C48 34.9(12) .
N5 Ag1 N8 C48 160.6(8) .
N4 Ag1 N8 C48 -112.7(8) 2_556
N1 N2 C1 C2 1.4(12) .
N1 N2 C1 C15 -179.1(7) .
N2 C1 C2 C3 5.4(12) .
C15 C1 C2 C3 -174.0(7) .
N2 C1 C2 C5 -176.9(9) .
C15 C1 C2 C5 3.7(15) .
C1 C2 C3 C4 -8.3(11) .
C5 C2 C3 C4 173.4(7) .
C1 C2 C3 C13 173.7(7) .
C5 C2 C3 C13 -4.6(9) .
N2 N1 C4 C3 2.0(13) .
Ag1 N1 C4 C3 -168.6(6) .
N2 N1 C4 C18 179.0(7) .
Ag1 N1 C4 C18 8.3(11) .
C2 C3 C4 N1 4.9(12) .
C13 C3 C4 N1 -177.8(9) .
C2 C3 C4 C18 -171.8(8) .
C13 C3 C4 C18 5.5(16) .
C1 C2 C5 C6 8.3(17) .
C3 C2 C5 C6 -173.8(9) .
C1 C2 C5 C14 -174.0(9) .
C3 C2 C5 C14 3.8(9) .
C14 C5 C6 C7 3.6(12) .
C2 C5 C6 C7 -179.1(9) .
C5 C6 C7 C8 -0.4(13) .
C5 C6 C7 C21 -177.6(8) .
C6 C7 C8 C9 -1.8(14) .
C21 C7 C8 C9 175.4(9) .
C7 C8 C9 C14 0.6(13) .
C7 C8 C9 C10 -179.8(9) .
C14 C9 C10 C11 1.1(14) .
C8 C9 C10 C11 -178.5(9) .
C9 C10 C11 C12 -2.6(15) .
C9 C10 C11 C25 174.6(8) .
C10 C11 C12 C13 1.5(14) .
C25 C11 C12 C13 -175.8(8) .
C11 C12 C13 C14 1.1(12) .
C11 C12 C13 C3 176.9(9) .
C4 C3 C13 C12 9.8(17) .
C2 C3 C13 C12 -172.7(9) .
C4 C3 C13 C14 -174.0(9) .
C2 C3 C13 C14 3.5(9) .
C10 C9 C14 C13 1.6(13) .
C8 C9 C14 C13 -178.8(8) .
C10 C9 C14 C5 -176.8(8) .
C8 C9 C14 C5 2.8(13) .
C12 C13 C14 C9 -2.7(13) .
C3 C13 C14 C9 -179.7(8) .
C12 C13 C14 C5 175.8(8) .
C3 C13 C14 C5 -1.1(10) .
C6 C5 C14 C9 -5.0(13) .
C2 C5 C14 C9 176.9(8) .
C6 C5 C14 C13 176.5(8) .
C2 C5 C14 C13 -1.6(9) .
C17 N3 C15 C1 -178.9(8) .
Ag2 N3 C15 C1 17.8(11) 2_566
C17 N3 C15 S1 2.2(9) .
Ag2 N3 C15 S1 -161.0(4) 2_566
N2 C1 C15 N3 -135.9(8) .
C2 C1 C15 N3 43.6(12) .
N2 C1 C15 S1 42.9(9) .
C2 C1 C15 S1 -137.6(7) .
C16 S1 C15 N3 -1.9(7) .
C16 S1 C15 C1 179.2(7) .
C15 S1 C16 C17 1.0(8) .
S1 C16 C17 N3 0.0(12) .
C15 N3 C17 C16 -1.4(12) .
Ag2 N3 C17 C16 161.4(7) 2_566
C20 N4 C18 C4 178.9(8) .
Ag1 N4 C18 C4 45.9(9) 2_556
C20 N4 C18 S2 0.7(10) .
Ag1 N4 C18 S2 -132.3(5) 2_556
N1 C4 C18 N4 -135.3(9) .
C3 C4 C18 N4 41.6(13) .
N1 C4 C18 S2 42.7(11) .
C3 C4 C18 S2 -140.4(8) .
C19 S2 C18 N4 -0.6(8) .
C19 S2 C18 C4 -178.7(8) .
C18 S2 C19 C20 0.4(8) .
S2 C19 C20 N4 0.0(12) .
C18 N4 C20 C19 -0.4(12) .
Ag1 N4 C20 C19 128.4(8) 2_556
C8 C7 C21 C23 -94.3(12) .
C6 C7 C21 C23 82.9(12) .
C8 C7 C21 C22 143.6(12) .
C6 C7 C21 C22 -39.2(14) .
C8 C7 C21 C24 24.9(13) .
C6 C7 C21 C24 -157.9(9) .
C10 C11 C25 C27B -100.7(14) .
C12 C11 C25 C27B 76.6(13) .
C10 C11 C25 C26A 45.3(12) .
C12 C11 C25 C26A -137.5(10) .
C10 C11 C25 C28A 169.3(11) .
C12 C11 C25 C28A -13.4(12) .
C10 C11 C25 C26B 21.6(14) .
C12 C11 C25 C26B -161.2(12) .
C10 C11 C25 C28B 139.7(13) .
C12 C11 C25 C28B -43.1(13) .
C10 C11 C25 C27A -73.0(12) .
C12 C11 C25 C27A 104.2(11) .
N5 N6 C29 C30 -0.5(14) .
Ag2 N6 C29 C30 148.6(7) .
N5 N6 C29 C43 178.4(8) .
Ag2 N6 C29 C43 -32.5(9) .
N6 C29 C30 C31 6.2(14) .
C43 C29 C30 C31 -172.5(9) .
N6 C29 C30 C33 -175.5(10) .
C43 C29 C30 C33 5.8(17) .
C29 C30 C31 C32 -7.7(13) .
C33 C30 C31 C32 173.6(8) .
C29 C30 C31 C41 175.4(8) .
C33 C30 C31 C41 -3.3(10) .
N6 N5 C32 C31 1.9(13) .
Ag1 N5 C32 C31 162.0(7) .
N6 N5 C32 C46 -177.7(8) .
Ag1 N5 C32 C46 -17.6(10) .
C30 C31 C32 N5 3.8(13) .
C41 C31 C32 N5 179.7(9) .
C30 C31 C32 C46 -176.7(9) .
C41 C31 C32 C46 -0.8(17) .
C29 C30 C33 C34 7.3(19) .
C31 C30 C33 C34 -174.3(10) .
C29 C30 C33 C42 -175.8(10) .
C31 C30 C33 C42 2.6(10) .
C42 C33 C34 C35 2.1(14) .
C30 C33 C34 C35 178.6(10) .
C33 C34 C35 C36 0.1(15) .
C33 C34 C35 C49 178.6(9) .
C34 C35 C36 C37 -1.2(15) .
C49 C35 C36 C37 -179.8(9) .
C35 C36 C37 C42 0.0(14) .
C35 C36 C37 C38 -179.0(10) .
C42 C37 C38 C39 1.0(14) .
C36 C37 C38 C39 -179.9(10) .
C37 C38 C39 C40 -1.8(15) .
C37 C38 C39 C53 178.6(9) .
C38 C39 C40 C41 0.1(15) .
C53 C39 C40 C41 179.6(9) .
C39 C40 C41 C42 2.2(13) .
C39 C40 C41 C31 179.5(10) .
C32 C31 C41 C40 9.1(19) .
C30 C31 C41 C40 -174.8(11) .
C32 C31 C41 C42 -173.4(10) .
C30 C31 C41 C42 2.7(10) .
C38 C37 C42 C41 1.5(14) .
C36 C37 C42 C41 -177.7(9) .
C38 C37 C42 C33 -178.6(9) .
C36 C37 C42 C33 2.2(14) .
C40 C41 C42 C37 -3.1(14) .
C31 C41 C42 C37 178.9(9) .
C40 C41 C42 C33 177.0(8) .
C31 C41 C42 C33 -1.1(10) .
C34 C33 C42 C37 -3.3(14) .
C30 C33 C42 C37 179.1(9) .
C34 C33 C42 C41 176.6(8) .
C30 C33 C42 C41 -0.9(10) .
C45 N7 C43 C29 -173.5(8) .
Ag2 N7 C43 C29 -6.9(11) .
C45 N7 C43 S3 -1.3(10) .
Ag2 N7 C43 S3 165.3(4) .
N6 C29 C43 N7 27.2(12) .
C30 C29 C43 N7 -154.0(10) .
N6 C29 C43 S3 -144.0(7) .
C30 C29 C43 S3 34.8(14) .
C44 S3 C43 N7 2.0(8) .
C44 S3 C43 C29 173.7(9) .
C43 S3 C44 C45 -2.1(9) .
S3 C44 C45 N7 1.8(12) .
C43 N7 C45 C44 -0.3(12) .
Ag2 N7 C45 C44 -164.1(7) .
C48 N8 C46 C32 -174.0(8) .
Ag1 N8 C46 C32 -11.0(10) .
C48 N8 C46 S4 -1.3(9) .
Ag1 N8 C46 S4 161.7(4) .
N5 C32 C46 N8 19.1(12) .
C31 C32 C46 N8 -160.4(9) .
N5 C32 C46 S4 -152.6(7) .
C31 C32 C46 S4 27.9(14) .
C47 S4 C46 N8 0.9(7) .
C47 S4 C46 C32 173.2(8) .
C46 S4 C47 C48 -0.3(9) .
S4 C47 C48 N8 -0.4(12) .
C46 N8 C48 C47 1.1(12) .
Ag1 N8 C48 C47 -159.4(7) .
C36 C35 C49 C50 178.5(12) .
C34 C35 C49 C50 0.0(16) .
C36 C35 C49 C52 -56.4(14) .
C34 C35 C49 C52 125.1(12) .
C36 C35 C49 C51 60.2(13) .
C34 C35 C49 C51 -118.3(11) .
C38 C39 C53 C56 176.6(13) .
C40 C39 C53 C56 -2.9(17) .
C38 C39 C53 C54 -55.6(15) .
C40 C39 C53 C54 124.9(13) .
C38 C39 C53 C55 60.6(13) .
C40 C39 C53 C55 -118.9(12) .
